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* Exposure Controls/Personal Protection *
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
NECESSARY.
Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP
AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS.
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE
SHOWER . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN
EXPOSURE.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE
CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
Supplemental Safety and Health
MATLS TO AVOID: MATERIALS AND COMBUSTIBLES. FIRST AID PROC: IMMED. IF
NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. GET MED
AID. NOTES TO MD: TREAT SYMPTOMATICALLY & SUPPORTIVELY. NO SPEC
IFIC ANTIDOTE EXISTS.
* Product Identification *
* Composition/Information on Ingredients *
OSHA PEL:2 PPM
ACGIH TLV:2 PPM/4 STEL
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS: NONE. ACUTE: EYE: SEV
EYE BURNS. MAY CAUSE IRREVERSIBLE EYE INJURY. SKIN: MAY CAUSE SEV
IRRIT. CAUSES SKIN BURNS. MAY CAUSE DEEP, PENETRATING ULCERS OF
SKIN. INGEST: GI TRACT BURNS. MAY CAUSE PERFORATION OF DIGESTIVE
TRACT. INHAL: MAY BE FATAL IF INHALED. EFTS MAY BE DELAYED. MAY
CAUSE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: IRRIT OF RESP TRACT W/BURNING PAIN IN
NOSE & THROAT, COUGHING, WHEEZING, SHORTNESS OF BRTH & PULM EDEMA.
CHRONIC: RPTD INHAL MAY CAUSE CHRONIC BRONCHITIS. REPEATED EXPOSURE
MAY CAUSE EROSION OF TEETH.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
OCCAS0LIFTING UPPER 'O O @O O O O @O O O O
O O @ O O @O @O O @ O O OHO O
O O OF@O O O O O OHO @O O O O
O O @ @O O OO @O @O O O
O OHO O OO @O @O O O O OC
OBOOOOO
* Fire Fighting Measures *
Extinguishing Media:SUBSTANCE IS NON-COMBUSTIBLE; USE AGENT MOST
APPROPRIATE TO EXTINGUISH SURROUNDING FIRE.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . USE WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL.
SUBSTANCE IS NON-COMBUSTIBLE.
Unusual Fire/Explosion Hazard:STRONG OXIDIZER. CONTACT WITH COMBUSTIBLE
MATERIALS MAY CAUSE A FIRE.
* Accidental Release Measures *
Spill Release Procedures: O O OO OC @ @AO O
OO BAO O OO O O O @O O
O O OHO PRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE
CONTROL MEASURES SECTI ON).
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:USE WITH ADEQUATE VENTILATION. DO NOT
GET IN EYES OR ON SKIN. DO NOT INGEST OR INHALE.
Other Precautions:STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM
INCOMPATIBLE SUBSTANCES.
* Physical/Chemical Properties *
Vapor Pres:6.8
pH:1.0
Solubility in Water:SOLUBLE
Appearance and Odor:TRANSPARENT, CLEAR OR YELLOWISH LIQUID. STRONG,
ACRID ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
FOR SPECIFICS. REACTS VIOLENTLY W/ORG (SUP DAT)
Stability Condition to Avoid:HIGH TEMPS, INCOMPATIBLE MATERIALS,
MOISTURE, REDUCING AGENTS. DECOMPOSES WHEN IN CONTACT W/AIR,
LIGHT/ORGANIC MATTER.
Hazardous Decomposition Products:NITROGEN OXIDES.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE, AND LOCAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:SUPPLIED AIR W/FULL FACEPIECE,HELMET OR HOOD
Ventilation:LOCAL EXHAUST
Other Protective Equipment:FULL CLOTHING TO PREVENT SKIN CONTACT
Supplemental Safety and Health
OVEREXPOS:CAN CAUSE FORMATION OF CYSTS,CAUSES STILLBIRTHS.IRRITATES
EYES,NOSE THROAT.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:POLYCHLORINATED BIPHENYLS (PCBS) (SARA III)
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
* Hazards Identification *
Effects of Overexposure:ABSORBED THRU SKIN,LUNGS,INTESTINE.CAUSES
CANCER,LIVER,KIDNEY,STOMACH,EYE,HEARING DISORDER(SUP DATA)
* First Aid Measures *
First Aid:EYES:FLUSH W/WATER IMMEDIATELY.SKIN:WASH W/SOAP
IMMEDIATELY.INHAL:REMOVE TO FRESH AIR,GIVE ART.RESPIR. AS
NEEDED.INGEST:GET MEDICAL ATTN.GIVE LARGE QTY OF SALT WATER,INDUCE
VOMITING,BUT DO NOT MAKE UN CONSCIOUS PERSON VOMIT.
* Accidental Release Measures *
Spill Release Procedures:USE ABSORBENT & DIKES TO PREVENT
RUNOFF.ISOLATE & NOTIFY PROPER AUTHORITIES.
*Handling and Storage *
Handling and Storage Precautions:STORAGE MUST FOLLOW RCRA REQUIREMENTS.
* Physical/Chemical Properties *
HCC:Z3
Appearance and Odor:LIGHT STRAW-COLORED LIQUID,AROMATIC ODOR
* Stability and Reactivity Data *
STRONG OXIDIZERS
* Disposal Considerations *
Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-GENERALLY HIGH
TEMPERATURE INCINERATION.ONLY APPROVED DISPOSAL OPERATOR PERMITTED.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
OTHER PROTECTIVE EQUIPMENT.
Work Hygienic Practices:WASH THOROUGHLY AFTER USE.
Supplemental Safety and Health
FIRE/EXPLO HAZS: HAZARD WHEN USED IN THE PRESENCE OF VOLATILE OR
FLAMMABLE MIXTURES.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:CELLULOSE; (ABICEL)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY BE HARMFUL IF INHALED. MAY
CAUSE EYE AND SKIN IRRITATION.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:EYES: IN CASE OF CONTACT, IMMEDIATELY FLUSH WITH COPIOUS
INHALATION: REMOVE TO FRESH AIR. INGESTION: WASH OUT MOUTH WITH
WATER PROVIDE D PERSON IS CONSCIOUS. CALL A PHYSICIAN.
* Fire Fighting Measures *
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL POWDER OR
APPROPRIATE FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . PREVENT CONTACT WITH SKIN AND EYES.
Unusual Fire/Explosion Hazard:THIS MATL, LIKE MOST MATLS IN POWDER
FORM, IS CAPABLE OF CREATING A DUST EXPLO. EMITS TOX FUMES UNDER
FIRE CNDTNS. STATIC CHG BUILDUP CAN BE POTNTL FIRE(SUPDAT)
* Accidental Release Measures *
Spill Release Procedures:NONE SPECIFIED BY MANUFACTURER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STROE IN A COOL DRY PLACE. KEEP
TIGHTLY CLOSED. PREVENT FORMATION OF STATIC ELECTRICITY. WASH
THOROUGHLY AFTER HANDLING.
Other Precautions:DO NOT BREATHE DUST. AVOID CONTACT WITH EYES, SKIN
AND CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE.
* Physical/Chemical Properties *
Appearance and Odor:WHITE POWDER
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE.
* Disposal Considerations *
Waste Disposal Methods:DISSOLVE OR MIX MATERIAL WITH A COMBUSTIBLE
SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:GENERAL VENTILATION.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING & BEFORE SMOKING
OR EATING.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
Kit Part:Y
Preparer's Name:JCS
* Composition/Information on Ingredients *
Ingred Name:MANGANESE DIOXIDE
OSHA PEL:5 MG MN/M3 CEILING
ACGIH TLV:5 MG MN/M3
Ingred Name:GUANIDINE,1,3-DIPHENYL-; (1,3 DIPHENYL GUANIDINE)
Fraction by Wt: 5%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:TERPHENYLS, HYDROGENATED; (HYDROGENATED TERPHENYLS)
OSHA PEL:0.5 PPM
ACGIH TLV:0.5 PPM
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: IRRITATION. SKIN: LOCAL
IRRITATION. INHAL: ALTHOUGH THE MAIN HAZARD OF MAGANESE COMPOUNDS
IS BY BREATHING DUST, INGESTION SHOULD BE AVOIDED AS A PRECAUTION
AGAINST MANGANESE POISONING. SYMPTOMS OF MANGANESE POISONING ARE
WEAKNESS & SLEEPINESS.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:
* First Aid Measures *
SYMPTOMS PERSIST, CONSULT MD. SKIN: WASH W/SOAP & WATER. IF
SYMPTOMS PERSIST, CONSULT MD. INHAL: REMOVE TO FRESH AIR. IF
SYMPTOMS ARE PRESENT CONSULT MD. INGEST: CONSULT MD.
* Fire Fighting Measures *
Flash Point:NOT FLAMMABLE
Extinguishing Media:CO*2, DRY CHEMICAL, FOAM, WATER.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT. USE WATER TO COOL HEAT EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:NONE KNOWN.
* Accidental Release Measures *
Spill Release Procedures:SCOOP INTO CONTAINERS. CLEAN-UP RESIDUE
W/1,1,1-TRICHLOROETHANE.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:AVOID INGESTION.
Other Precautions:
* Physical/Chemical Properties *
Spec Gravity:2.0
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BLACK LIQUID.
Percent Volatiles by Volume:0
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
EASILY OXIDIZABLE MATERIALS.
Stability Condition to Avoid:
Hazardous Decomposition Products:OXIDES OF CARBON, MANGANESE COMPOUNDS.
* Disposal Considerations *
Waste Disposal Methods:NOT A HAZARDOUS WASTE ACCORDING TO EPA
REGULATIONS. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE & FEDERAL
REGULATIONS PRIOR TO DISPOSAL OF SPILLAGE.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF EXPOSURE ABOVE THE PEL OR TLV, NIOSH APPROVED
RESPIRATOR FOR FUME OR DUST, DEPENDENT UPON THE SOURCE OF AIRBORNE
CONTAMINANT.
Ventilation:LOCAL EXHAUST/MECHANICAL (GENERAL) REQUIRED IF DUST OR
FUMES ARE CREATED.
Other Protective Equipment:AS REQUIRED FOR THE WORK DONE ON OR WITH THE
METAL. I.E. FACE SHIELDS & SPECIALLY TINTED GLASSES.
Work Hygienic Practices:EVALUATE THE JOBS DONE ON THIS PRODUCT IN
ACCORDANCE W/OSHA, STATE, FEDERAL, OR LOCAL STANDARDS.
Supplemental Safety and Health
UNDER NORMAL HANDLING CONDITIONS THE SOLID ALLOY PRESENTS NO
SIGNIFICANT HEALTH HAZARDS. PROCESSING OF THE ALLOY BY DUST OR FUME
PRODUCING OPERATIONS (GRINDING, BUFFING, HEATING, WELDING, ETC.)
MAY RE SULT IN THE POTENTIAL FOR EXPOSURE TO AIRBORNE METAL
PARTICULATES OR FUMES.
* Product Identification *
CAGE:COPPE
CAGE:COPPE
* Composition/Information on Ingredients *
Ingred Name:COPPER (DUST & MIST), BRONZE POWDER
Other REC Limits:1 MG(CU)/M3 (DUST)
OSHA PEL:0.1 MG(CU)/M3 (FUME)
ACGIH TLV:0.2 MG/M3 (FUME)
Ingred Name:ZINC OXIDE
Fraction by Wt: 5%
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: METAL FUME FEVER W/FLU
SYMPTOMS, FEET/HAND KERATINIZATION, UPPER RESPIRATORY TRACT
IRRITATION, METALLIC TASTE, NAUSEA, NOSE/MOUTH/THROAT IRRITATION,
COUGH, HEADACHE, VOMITING, CHILLS, FEVE R, MUSCLE/JOINT/STOMACH
PAIN, THIRST, BRONCHITIS & PNEUMONIA. SKIN: BLUISH
TINT/DISCOLORATION. HAIR: DISCOLORATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: METAL FUME FEVER W/FLU SYMPTOMS,
FEET/HAND KERATINIZATION, UPPER RESPIRATORY TRACT IRRITATION,
METALLIC TASTE, NAUSEA, NOSE/MOUTH/THROAT IRRITATION, COUGH,
HEADACHE, VOMITING, CHILLS, FEVE R, MUSCLE/JOINT/STOMACH PAIN,
THIRST, BRONCHITIS & PNEUMONIA. ACCUMALATIVE POSION.
* First Aid Measures *
First Aid:EYES: FLUSH W/PLENTY OF WATER. SKIN: VACUUM OFF EXCESS DUST.
WASH WELL W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR.
INGESTION: OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Extinguishing Media:SPECIAL MIXTURES OF DRY CHEMICAL OR SAND.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:NON COMBUSTIBLE. MODERATE WHEN MATERIAL
IS IN THE FORM OF DUST & EXPOSED TO HEAT, FLAMES, CHEMICAL REACTION
OR IN CONTACT W/POWERFUL OXIDIZERS.
* Accidental Release Measures *
Spill Release Procedures:DUST: VACUUM OR WET SWEEP. VENTILATE AREA.
LIQUIDS (ACIDS/BASES) CONTAINING SOLUBILIZED METAL, EVACUATE
UNPROTECTED PERSONNEL. ABSORB W/VERMICULITE, DRY SAND, OR SIMILAR
MATERIAL. CLEANUP PERSONNEL SH OULD WEAR RESPIRATORS & PROTECTIVE
CLOTHING.
*Handling and Storage *
Handling and Storage Precautions:AVOID INCOMPATIBLE MATERIALS & KEEP
DUST FROM SOURCES OF IGNITION.
Other Precautions:MOLTEN METAL MAY REACT VIOLENTLY W/WATER.
* Physical/Chemical Properties *
Solubility in Water:INSOLUBLE
Appearance and Odor:SOLID, SILVER OR YELLOW TO RED, ODORLESS
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ACIDS, BASES & OXIDIZERS.
Stability Condition to Avoid:HEAT, FLAME, CHEMICAL REACTION & OTHER
IGNITION SOURCES WHEN MATERIAL IS IN DUST FORM.
Hazardous Decomposition Products:METAL FUME
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, &
FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WHEN EXPOSURE LIMITS ARE EXCEEDED, USE PROPER,
NIOSH/MSHA APPROVED RESPIRATOR VENTILATION.
Ventilation:USE LOCAL EXHAUST WHEN CUTTING, GRINDING, OR WELDING.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
Product ID:NICKEL-BASE ALLOYS
* Composition/Information on Ingredients *
Ingred Name:NICKEL (SARA III)
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
Ingred Name:COPPER (SARA III)
OSHA PEL:0.1MG/M3 FUME;1 DUST
ACGIH TLV:0.2MG/M3 FUME
Ingred Name:IRON (III) OXIDE
Ingred Name:MOLYBDENUM
Ingred Name:CHROMIUM (SARA III)
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:COBALT (SARA III)
OSHA PEL:0.1 MG/M3;AS CO
Ingred Name:TUNGSTEN
Fraction by Wt: 0-5%
Ingred Name:COLUMBIUM
Fraction by Wt: 0-5%
Ingred Name:TANTALUM
Fraction by Wt: 0-5%
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3; DUST
Ingred Name:ALUMINUM (SARA III)
Fraction by Wt: 0-3%
Ingred Name:TITANIUM, METAL
Ingred Name:MANGANESE (SARA III)
OSHA PEL:(C) 5 MG/M3 DUST
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:METALLIC TASTE; NAUSEA;
TIGHTNESS OF CHEST; FEVER; IRRITAITON OF EYES, NOSE, THROAT, AND
SKIN; LOSS OF CONSCIOUSNESS/DEATH FROM WELDING GASES OR LACK OF
OXYGEN. CHRONIC:ADVERSE EFFECTS MAY RESUL T FROM LONG-TERM EXPOSURE
TO WELDING FUMES, GASES, OR DUSTS. THESE EFTS MAY INCL SKIN SENSIT,
(EFTS OF OVEREXPOUSRE)
Explanation of Carcinogenicity:NICKEL:GROUP 1 (IARC),ANTICIPATED TO BE
A CARCIN(NTP): COBALT GROUP 2B (IARC).
Effects of Overexposure:HLTH HAZ:NEUROLOGICAL DMG, & RESPIRATOR DISEASE
SUCH AS BRONCHIAL ASTHMA, LUNG FIBROSIS, OR PNEUMOCONIOSIS.
MANGANESE CAN CAUSE COMPULSIVE BEHAVIOR, A MASK-LIKE FACE, AND A
PARKINSON- LIKE SYNDROME.
Medical Cond Aggravated by Exposure:AGGRAVATION OF PREEXISTING
RESPIRATORY OR ALLERGIC CONDITIONS MAY OCCUR IN SOME WORKERS.
* First Aid Measures *
First Aid:INHAL:MOVE TO FRESH AIR & GET MD IMMEDIATELY. IF UNCONSCIOUS,
GIVE OXYGEN. IF NOT BREATHING, RESUSCITATE IMMEDIATELY. SKIN:FLUSH
WITH COPIOUS AMOUNTS OF WATER. CALL MD . EYE: FLUSH WITH POTABLE
IMMEDIATELY .
* Fire Fighting Measures *
Flash Point:NON-FLAMMABLE
Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:
* Accidental Release Measures *
Spill Release Procedures:NOT APPLICABLE.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:
Other Precautions:
* Physical/Chemical Properties *
HCC:N1
Appearance and Odor:ODORLESS SOLIDS WITH METALLIC LUSTER
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:TAKE CAUTION WHEN WELDING.
Hazardous Decomposition Products:
* Disposal Considerations *
Waste Disposal Methods:NOT APPLICABLE; HOWEVER IT IS RECOMMENDED THAT
ALL SCRAP GENERATED BE RECLAIMED AND SUBSEQUENTLY RECYCLED.
DISPOSAL MUST BE IN ACCORDANCE WITH ALL LOCAL, STATE, AND FEDERAL
REGULATIONS .
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WHERE TLVS MAY BE EXCEEDED/SPRAY MIST IS
PRESENT, USE NIOSH/MSHA APPROVED RESPIRATORY PROTECTION. IN
CONFINED AREAS, USE NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATORS.
Ventilation:GENERAL DILUTION/LOCAL EXHAUST IN VOLUME & PATTERN TO KEEP
Other Protective Equipment:PROTECTIVE CLOTHING, SAFETY SHOWER, EYE
BATH, WASHING FACILITIES
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
UNUSUAL FIRE HAZ CONT'D: CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO
EXTREME HEAT. HEALTH HAZ CONT'D: OVEREXPOSURE TO SOLVENTS MAY CAUSE
PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. DON'T TAKE INTERNALL Y.
DON'T DELIBERATELY CONCENTRATE THIS PRODUCT & INHALE VAPORS. VAPORS
ARE >AIR & MAY COLLECT IN LOW/CONFINED AREAS.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:2-HEPTANONE, METHYL N-AMYL KETONE
Ingred Name:CYCLOHEXANONE, KETOHEXAMETHYLENE
Fraction by Wt: 5%
Ingred Name:2-BUTANONE (METHYL ETHYL KETONE) (MEK)
Fraction by Wt: 5%
Fraction by Wt: <5%
Fraction by Wt: <5%
Ingred Name:ALIPHATIC POLYISOCYANATE, HEXAMETHYLENE DIISOCYANATE
Other REC Limits:1 MG/CUM
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: NASAL & RESPIRATORY
IRRITATION/CNS DEPRESSION/ASPHYXIATION. ISOCYANATES CAUSES ALLERGIC
SENSITIZATION/IRRITATION TO MUCOUS MEMBRANE & RESPIRATORY TRACT.
SKIN: IRRITATION/DERMATITIS/SENSITI ZATION. EYES: IRRITATION.
INGESTION: GIIRRITATION, ASPIRATION INTO THE LUNGS MAY CAUSE
CHEMICAL PNEUMONITIS/FATAL.(SUPP
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, HEADACHE, DIZZINESS, STAGGERING
GAIT, CONFUSION, UNCONSCIOUSNESS, ASPHYXIATION.
ISOCYANATES-TIGHTNESS IN CHEST, IRRITATION, COUGHING, HEADACHE,
SHORTNESS OF BREATH, ASTHMA-LIKE ATTACKS. DE FATTING, NAUSEA,
VOMITING, DIARRHEA, CONCENTRATION DIFFICULTIES,
DIMINISHEDDEXTERITY, MEMORY LOSS
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN, LUNG & EYE
CONDITIONS
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF
NECESSARY. KEEP WARM & QUIET. SKIN: WASH W/SOAP & WATER. DON'T USE
HAZARD. OBTAIN M EDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point Method:SCC
Lower Limits:1
Extinguishing Media:CO2, DRY CHEMICAL/FOAM
Fire Fighting Procedures:WATER SPRAY MAY BE INEFFECTIVE. COOL FIRE
EXPOSED CONTAINERS W/WATER. FOG NOZZLES ARE PREFERRABLE. WEAR
NIOSH/MSHA APPROVED SCBA & PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:FLAMMABLE. VAPORS MAY ACCUMULATE IN
INADEQUATELY VENTILATED/CONFINED AREAS. MAY FORM EXPLOSIVE MIXTURES
W/AIR/TRAVEL LONG DISTANCES & FLASHBACK. (SEE SUPP)
* Accidental Release Measures *
Spill Release Procedures:REMOVE IGNITION SOURCES. WEAR PROTECTIVE
EQUIPMENT, USE NON-SPARKING TOOLS. SMALL: DIKE & ABSORB W/INERT
MATERIAL. COLLECT MATERIAL IN OPEN TOP DRUM & TAKE TO ISOLATED
DETERGENT, & 3-8% AMMONIA
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. DON'T
HEAT/SPARKS/FLAME, HOT SURFACES & OTHER IGNITION SOURCES.
Other Precautions:GROUNDING & BONDING PROCEDURES SHOULD BE FOLLOWED
WHEN TRANSFERRING THIS MATERIAL. DON'T SMOKE. EMPTY DRUMS MAY
CONTAIN EXPLOSIVE VAPORS. DON'T CUT/PUNCTURE/WELD ON/NEAR DRUM.
AVOID FREE FALL OF LIQUI D. PROTECT FROM MOISTURE. (SEE SUPP)
* Physical/Chemical Properties *
Vapor Density:>1
Evaporation Rate & Reference:SLOWER THAN N-BU AC
Appearance and Odor:CLEAR LIQUID W/SOLVENT ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
WATER, ALCOHOLS & AMINES
Stability Condition to Avoid:HEAT, SPARKS, FLAME, TEMPS >STORAGE TEMPS,
HOT SURFACES, MOISTURE & OTHER IGNITION SOURCES
Hazardous Decomposition Products:CO, CO2, OXIDES OF NITROGEN & TRACES
OF HYDROGEN CHYANIDE & ISOCYANATE MONOMER
* Disposal Considerations *
Waste Disposal Methods:WHEN DISPOSING OF THIS MATERIAL, ENSURE THAT IT
IS PACKAGED, STORED, TRANSPORTED & MANAGED IN ACCORDANCE W/LOCAL,
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:AIRBORNE CONC SHOULD BE KEPT TO LOWEST LEVELS
POSSIBLE.VAP/MIST/DUST GENERATED & OCCUPAT EXPO LIMIT OF PROD/COMPO
EXCEEDED USE APPRO NIOSH/MSHA APPROV AIR PURIFY/AIR SUPPL RES AFT
DETERM AIRBORNE CONT AM CONC.AIR SUPPL RES-CONTAM CON/OXY UNK
Ventilation:EXPLO-PROOF EQPMT-MAINTAIN ADEQ VENTI TO MEET OCCUP EXP
LIMITS.PREVENT EXPO AIR-GAS MIX ACCUMM,AVOID SIGN OXY DISPLACE.
Other Protective Equipment:PROTECGIVE CLOTH-COVERALLS,BOOTS.OXY LEVELS
Work Hygienic Practices:REMOVE/DRY CLEAN(MORE EFFECTIVE)/LAUNDER CLOTH
SOAK/SOIL W/MATL BEF REUSE.INFORM CLOTH CLEANERS OF POT HAZ
W/CONTAM CLOT
Supplemental Safety and Health
HEALTH:SEVERAL MOUTHFULS SWALLOW ABD DISCOMFT,NAU,DIARR MAY
OCCUR.ASPIRATION MAY OCCUR DURING SWALLO/VOMIT RESULT IN LUNG DMG.
1STAID:DISTRESS CLEAR AIRWAY,START ART RESP.W/DR ADVICE GIVE SUPPL
OXY W/ BAG-VALV MASK/MANUAL TRIG OXY SUPPLY.STOMACH EVAC-USE METHOD
LEAST LIKELY TO CAUSE ASPIRATION. DISPO:ENTER DRAIN/SEWERS.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:OXYGENATES,MAY OR MAY NOT CONTAIN ANY COMBINATION OF THESE
Fraction by Wt: SEE ING
Other REC Limits:NONE RECOMMENDED
Ingred Name:GASOLINE CONSISTS OF STRAING/BRANCHED PARAFFINIC
Fraction by Wt: SEE ING
Other REC Limits:NONE RECOMMENDED
Fraction by Wt: SEE ING
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Fraction by Wt: SEE ING
Other REC Limits:NONE RECOMMENDED
Fraction by Wt: SEE ING
Other REC Limits:NONE RECOMMENDED
Fraction by Wt: SEE ING
Other REC Limits:NONE RECOMMENDED
Fraction by Wt: SEE ING
Other REC Limits:NONE RECOMMENDED
Fraction by Wt: SEE ING
Other REC Limits:NONE RECOMMENDED
Fraction by Wt: SEE ING
Other REC Limits:NONE RECOMMENDED
Fraction by Wt: SEE ING
Other REC Limits:NONE RECOMMENDED
Fraction by Wt: SEE ING
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Fraction by Wt: SEE ING
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:EYE:MAY CAUSE IRRIT,EXPERIENCE MILD
DISCOMFT,SLIGHT EXCESS REDNESS.SKIN:BRIEF CONTACT MAY CAUSE SLIGHT
IRRIT.PROLONG CONTACT MAY CAUSE MORE SEVERE IRRIT,DISCOMFT,LOCAL
REDNESS,SWELLING.PROL/WIDEPSREAD /REP CONTACT MAY RESULT IN ABSORPT
OF POT HARMFUL AMTS OF MATL.INHAL:VAP/MIST IRRTI
NOSE/THROAT.INGEST:MORE THAN (SUPPL)
Explanation of Carcinogenicity:PER MSDS:PRODUCT &/OR COMPONENET(S)
Effects of Overexposure:INHAL:DIZZ,DROWS,EUPHORIA,LOSS OF
COORD,DISORIENT,HEAD,NAU,VOMIT.POORLY VENTI AREA/CONF SPACE
UNCONSC,ASPHYXIATION.PROL/REP OVEREXPO ABSORPT OF POT HARMFUL AMTS
OF MATL.SEE HEALTH HAZ ABOVE.CHRONIC:PR OL/REP ETHANOL VAP
EXPO-HEAD,LACK OF COORD,SLEEPINESS,FTG,DIFF CONC.CHRONIC ALCOHOLIC
BEV-LIVER/STOM/HEART/NERV SYS DMG.
Medical Cond Aggravated by Exposure:BECAUSE OF ITS IRRIT
PROPERTIES,REPEATED SKIN CONTACT MAY AGGRAVATE EXISTING DERM(SKIN
CONDITION).
* First Aid Measures *
APART.GET MED ATTN.SKIN:WASH W/LOTS OF SOAP/H2O SEVERAL MINS.IRRIT
DVLPS/PERSIST GET MED ATTN.INGEST:CONSC/CAN SWALLO GIVE 2GLASSES
AGAIN.DETERMINE STOMAC EVACUATION/VOMIT INDUCTION BY MED
PERSONNEL.DONT GIVE ANYTHING BY MOUTH IF UNCONSC/CONVULS.INHAL:MOVE
TO FRESH AIR.NOT BREATH/RESP(SUP)
* Fire Fighting Measures *
Flash Point Method:PMCC
Lower Limits:1.4
Upper Limits:7.6
Extinguishing Media:H2O INEFFECTIVE ON FLAMES.USE WATER SPRAY,DRY
CHEMICAL,ALCOHOL RESISTANT FOAM,CO2 TO EXTINGUISH FIRE.
Fire Fighting Procedures:H2O SHOULD BE USED TO COOL FIRE-EXPO
CNTNR/PROVIDE PROTECTION FOR PERSONS ATTEMPTING TO STOP LEAK.WEAR
FULL PROTECTIVE CLOTH & POSITIVE PRESSURE BREATH APPARATU
Unusual Fire/Explosion Hazard:VAP HEAVIER THAN AIR,TRAVEL CONSIDERABLE
DISTANCE TO IGN SOURCE-FLASHBK.FLOWING MATL GENERATE STATIC
ELECT,CAUSE FIRE EXPO W/SPARK IN FLAM VAP-AIR ATM.EXT FLAMM
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL IGN SOURCE INCLUDE INTERNAL COMBUST
ENGINES/POWER TOOLS.VENTI AREA.BARRICADE AREA.STAY UPWIND,WARN OF
POSSIBLE DOWNWIDE EXPLO HAZ.AVOID BREATH VAP/SKIN/EYE/CLOTH
CONTACT.PRESSURE DEMAND AIR SUP RESP-CONTAM/OXY UNK
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:MATL MAY BE @ELEVATED TEMP &/OR
PRESSURES.EXERCISE ARE WHEN OPN BLEEDERS/SMPL PORTS.GROUND/BOND
SHIP CNTNR,TRANSF LINE,REC CNTNR.
Other Precautions:KEEP AWAY FRM HEAT/SPARK/FLAME/OTHER IGN SOURCES.PROD
INTENDED FO9R USE AS MOTOR FUEL ONLY.USE NONSPARK TOOLS,GROUND/BOND
ALL CNTNRS. DISPO:ALLOW TO ENTER DRAIN/SEWER.CAN CAUSE
* Physical/Chemical Properties *
HCC:F1
Vapor Density:3-4
pH:NA
Evaporation Rate & Reference:NONE SPECIFIED BY MANUFA.
Solubility in Water:0.1-1, SLIGHT
Appearance and Odor:LIGHT RED TO LIGHT STRAW LIQUID, PETROLEUM ODOR
Percent Volatiles by Volume:NP
Corrosion Rate:NP
* Stability and Reactivity Data *
HEAT, STRONG OXIDIZERS
Stability Condition to Avoid:HEAT,IGN SOURCES.
Hazardous Decomposition Products:TOXIC LEVELS OF CARBON MONOXIDE,
CARBON DIOXIDE, IRRIT ALDEHYDES & KETONES.
* Disposal Considerations *
Waste Disposal Methods:MATL PRESENTLY CONSTITUTED HAS RCRA CLASSIF OF
BENZENE TOXIC/IGN.DISCARD IN PRESENT FORM HAZ WASTE
CRITERIA FOR HAZ WASTE @DISPO TIME.US E/TRANSFORM/MIX/ETC CHANGE
CLASSIF.DONT(OTH PREC)
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE NORMALLY REQUIRED. IF DUSTY CONDITIONS
PREVAIL, WORK IN VENTILATION HOOD OR WEAR NIOSH-APPROVED DUST
RESPIRATOR.
Ventilation:ADEQUATE
Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER,
FIRE-RESISTANT CLOTHING AND/OR UNIFORM
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
Supplemental Safety and Health
* Product Identification *
Product ID:MAGNESIUM METAL
Preparer's Name:ALEXANDER A. PICCIRILLI
* Composition/Information on Ingredients *
Ingred Name:MAGNESIUM
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, RESPIRATORY
TRACT. HEALTH HAZARDS ARE DUE TO DUSTS/FUMES. ACUTE- EYE:MAY CAUSE
BURNS. SKIN:PARTICLES OF MAGNESIUM EMBEDED IN SKIN CAN CAUSE
LESIONS. INHALE:FUMES MAY CAUSE CHI LLS & METAL FUME FEVER. DUSTS
MAY CAUSEIRRITATION. ORAL:UNLIKELY. CHRONIC- UNKNOWN.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, NAUSEA, VOMITING, COUGHING, CHILLS,
FEVER, WEAKNESS, MUSCULAR PAIN
* First Aid Measures *
First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:REMOVE TO FRESH
MINUTES, HOLDING EYELIDS OPEN. GET IMMEDIAATE MEDICAL ATTENTION.
SKIN:FLUS H THOROUGHLY WITH WATER. ORAL:IF SWALLOWED, IF CONSCIOUS,
INDUCE VOMITING & CALL PHYSICIAN. NEVER GIVE ANYTHING BY MOUTH TO
AN UNCONSCIOUS PERSON.
* Fire Fighting Measures *
Extinguishing Media:SMOTHER WITH DRY SAND, DRY GRAPHITE/DRY POWDER
(ABC). DO NOT USE FOAM, HALOGENATED EXTINGUISHING AGENTS/CARBON
DIOXIDE.
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS. WEAR FIRE GLASSES. PREVENT
WATER CONTACT WITH MOLTEN MAGNESIUM.
Unusual Fire/Explosion Hazard:DUST FORMS EXPLOSIVE MIXTURE WITH AIR.
FINE POWDER, THIN SHEETS, CHIPS AND TURNINGS ARE EASILY IGNITED AND
BURNS. MOLTEN METAL MAY REACT VIOLENTLY WITH WATER.
* Accidental Release Measures *
Spill Release Procedures:USE APPROPRIATE SAFETY EQUIPMENT. CLEAN UP
USING NON-SPARKING TOOLS. NO SMOKING/OPEN FLAME. RECOVER FOR USE IF
NOT CONTAMINATED. CLEAN, DRY PRODUCT MAY BE RETURNED TO DRY
CONTAINER AND SEALED. PLACE C ONTAMINATED SPILL IN VENTED CONTAINER
FOR DISPOSAL
Neutralizing Agent:NOT RELEVANT
*Handling and Storage *
Handling and Storage Precautions:STORE AT ROOM TEMPERATURE IN DRY
PLACE, AWAY FROM INCOMPATIBLE MATERIALS. KEEP CONTAINER TIGHTLY
CLOSED. GROUND ALL HANDLING & TRANSFERRING OPERATIONS
Other Precautions:AVOID CREATING DUSTS OR FUMES. AVOID EYE CONTAT.
AVOID INHALATION OF DUST OR FUME. KEEP OUT OF REACH OF SMALL
CHILDREN. STORE AWAY FROM OTHER COMBUSTIBLE MATERIALS. STORAGE IN
HIGH HUMIDITY AREA WILL LEAD TO CORROSION OF THE PRODUCT.
* Physical/Chemical Properties *
HCC:F8
NRC/State Lic Num:NOT RELEVANT
Viscosity:NOT RELEVANT
Evaporation Rate & Reference:NOT RELEVANT
Solubility in Water:NEGLIGIBLE (DECOMP.)
Appearance and Odor:SILVERY/GRAY METAL RIBBON, CHIPS, TURNINGS -
ODORLESS
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, ACIDS, WATER, CHLORINE, BROMINE, IODINE
Stability Condition to Avoid:HEAT, MOISTURE, SPARKS, FLAME
Hazardous Decomposition Products:MAY FORM MAGNESIUM OXIDE. HYDROGEN
WILL BE PRODUCED WHEN EXPOSED FOR LONG TIME TO WATER AND ACIDS.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE
AND FEDERAL REGULATIONS. DISPOSE OF IN AN APPROVED INCINERATOR OR
IN AN APPROVED CHEMICAL LANDFILL OR CONTRACT WITH A LICENSED WASTE
DISPOSAL FACILITY.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:A PROPERLY FITTED, NIOSH/MSHA APPRVD FULL-FACE
OR A HALF-MASK (W/GAS PROOF GOGGS) RESP EFTIVE FOR PARTICULATES,
ORG SOLVS & FORMALDEHYDE OR A NIOSH/MSHA APPRVD AIR SUPPLIED RESP
Ventilation:LOCAL EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS TO MATLS IN
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
FIRE FIGHT PROC:CONTRS TO PVNT PRESS BUILD- UP & POSS AUTOIGNITION OR
EXPLOS WHEN EXPOSED TO EXTREME HEAT. EXPLO HAZ: SURF REQS SPEC
PRECS. DURING EMER CNDTNS, OVEREXPOS TO DECOMP PRODS MAY CAUSE A HL
TH HAZ. SYMPS MAY NOT BE IMMED APPARENT. EXPLAN OF CARCIN:ANTIC TO
BE CARCIN. OSHA REGULATED .
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ING 9:EXPOS. CHRONIC: FORMALDEHYDE HAS BEEN SHOWN TO CAUSE
Ingred Name:WASTE DISP METH:FACILITY. DO NOT INCIN CLSD CONTR. DISPOSE
OF I/A/W FED, STATE & LOCAL REGS REGARDING POLLUTION.
Ingred Name:OTHER PREC:OSHA'S STD FOR OCCUP EXPOS TO FORMALDEHYDE
PRESENT AT HAZ LEVELS ONLY DURING SANDING/ABRADING OF DRIED FILM.
Ingred Name:RESP PROT:VAP/MIST CONC BELOW PERMISSIBLE LIMITS. WHEN
FROM THIS PRODUCT, UNDERLYING PAINT OR THE ABRASIVE.
Ingred Name:XYLENE (SARA III). VP:5.9
Fraction by Wt: 1%
Fraction by Wt: 5%
Ingred Name:ISOBUTYL ALCOHOL; (2-METHYL-1-PROPANOL) (SARA III). VP:8.7
Fraction by Wt: 2%
Fraction by Wt: <1%
ACGIH TLV:0.3 PPM, C
Ingred Name:ACETIC ACID, ISOBUTYL ESTER; (ISOBUTYL ACETATE). (MFR CAS
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:EFTS OF OVEREXP:VAPORS/SPRAY MISTS. REDNESS & ITCHING OR
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
NAVY LISTING OF OCCUP CHEM REPROD HAZARDS. SEEK CONSULTATION FROM
APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZARD LIST INFO & SAFE
HNDLNG & EXPOS INFO . E XPOS MAY BE BY INHAL &/OR SKIN/EYE CONT,
DEPENDING ON CNDTNS OF USE. ALCOHOLS & ACETATES CAN BE (EFTS OF
OVEREXP)
Explanation of Carcinogenicity:FORMALDEHYDE:IARC MONOGRAPHS,
Effects of Overexposure:HLTH HAZ:ABSORBED THRU SKIN. TO MINIMIZE EXPOS,
FOLLOW RECOMMENDATIONS FOR PROPER USE, VENT & PERSONAL PROT EQUIP.
ACUTE: IRRIT OF EYES, SKIN & UPPER RESP SYS. MAY CAUSE NERV SYS
DEPRESS. EXTREME OVER EXPOS MAY RSLT IN UNCON & POSS DEATH. HDCH,
DIZZ, NAUS & LOSS OF COORD ARE INDICATIONS OF EXCESSIVE EXPOS TO
(ING 9)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
* First Aid Measures *
First Aid:INHAL:IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING.
KEEP WARM & QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY W/ SOAP &
WATER. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. EYES:
ATTENTION. INGEST:NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERSON.
DO NOT INDUCE VOMITING. GIVE SEVERAL GLASSES OF WATER. SEEK MEDICAL
ATTENTION.
* Fire Fighting Measures *
Lower Limits:1%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL OR FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. WATER SPRAY MAY BE INEFT. IF WATER IS USED, FOG NOZZ ARE PREF.
WATER MAY BE USED TO COOL CLSD (SUPP DATA)
Unusual Fire/Explosion Hazard:KEEP CONTRS TIGHTLY CLSD. ISOLATE FROM
HEAT, ELEC EQUIP, SPARKS & OPEN FLAME. CLSD CONTRS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT. APPLICATN TO HOT (SUPP DATA)
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE &
REMOVE W/INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:CONTENTS ARE FLAMM. KEEP AWAY FROM
HEAT/ SPARKS/OPEN FLAMES. CONSULT NFPA CODE. USE APPRVD BONDING &
GROUNDING PROCS. KEEP CONTRS CLSD WHEN NOT IN USE
Other Precautions:TRANSFER ONLY TO APPRVD CONTRS W/COMPLETE & APPROP
LABELING. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN.
INTENTIONAL MISUSE BY DELIB CONCENTRATING & INHALING CONTENTS CAN
* Physical/Chemical Properties *
HCC:F3
Vapor Pres:SEE INGRED
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE & CARBON
MONOXIDE.
* Disposal Considerations *
Waste Disposal Methods:WASTE FROM PRODUCT MAY BE HAZ AS DEFINED UNDER
APPLIC EPA HAZ WASTE NO. WASTE FROM PRODS CONTAINING METHYL ETHYL
KETONE MAY REQ TESTING FOR EXTRACTIBILITY. INCIN IN APPRVD (ING
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE REQUIRED UNDER NORMAL USE. NIOSH/MSHA
APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:NONE.
Other Protective Equipment:NONE REQUIRED UNDER NORMAL USE.
Work Hygienic Practices:INHALATION SHOULD BE AVOIDED.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
CAGE:MATSU
CAGE:MATSU
* Composition/Information on Ingredients *
Ingred Name:ACRYLIC ACID BUTYL ESTER POLYMER W/STYRENE; (STYRENE
ACRYLATE COPOLYMER)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:BLACK IRON OXIDE; (MAGNETITE)
ACGIH TLV:5 MG/M3 (FE)
Ingred Name:POLYPROPYLENE
Fraction by Wt: 5%
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MINIMAL IRRITATION TO RESPIRATORY
TRACT MAY OCCUR AS WITH EXPOSURE TO ANY NON-TOXIC DUST.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:ACCUMULATION OF DUST IN THE
RESPIRATORY SYSTEM.
* First Aid Measures *
First Aid:INGEST:CALL MD IMMEDIATELY . SKIN:FLUSH W/COPIOUS AMOUNTS OF
MINUTES. INHAL:REMOVE TO FRESH AIR. IF EFFECTS OCCUR, CONSULT L
OCAL MEDICAL PERSONNEL.
* Fire Fighting Measures *
Extinguishing Media:WATER FOG, FOAM, CO*2 OR DRY CHEMICALS.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NOT A FIRE HAZARD BUT CAN BURN IN A FIRE.
* Accidental Release Measures *
Spill Release Procedures:SWEEP UP OR CLEAR UP W/VACUUM CLEANER.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:NONE.
Other Precautions:NONE.
* Physical/Chemical Properties *
Spec Gravity:1.8 (H*2O=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:FINE BLACK POWDER; ODORLESS.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:CO, CO*2 & NO*X.
* Disposal Considerations *
Waste Disposal Methods:INCINERATE OF DUMP UNDER THE CONDITIONS WHICH
MEET ALL FEDERAL, STATE & LOCAL ENVIRONMENTAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
SIZE.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:NON HAZARDOUS INGREDIENTS
Fraction by Wt: <0.9%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:POTASSIUM IODIDE; (POTASSIUM IODIDE SOLUTION.)
OSHA PEL:N/K
ACGIH TLV:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY BE HARMFUL BY INGESTION OR SKIN
ABSORPTION.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR.
SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:IMMEDIATELY FLUSH
( ). SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD .
* Fire Fighting Measures *
Extinguishing Media:OXIDIZABLE. MEDIA SUITABLE FOR SURROUNDING FIRE
CONDITIONS .
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:WATER SOLUTION WILL NOT BURN OR EXPLODE.
* Accidental Release Measures *
Spill Release Procedures:WIPE UP WITH PAPER TOWEL WEARING PROTECTIVE
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Other Precautions:NONE.
* Physical/Chemical Properties *
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:NOT KNOWN
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING & REDUCING MATERIALS, STEEL, ALUMINUM, OTHER METALS.
Stability Condition to Avoid:OXIDIZABLE.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
* Disposal Considerations *
Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS .
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE REQUIRED
Ventilation:MECHANICAL/GENERAL
Other Protective Equipment:FULL PROTECTIVE CLOTHING
Work Hygienic Practices:WASH AFTER EVERY USE. LAUNDER CONTAMINATED
CLOTHING BEFORE REUSE. CLEAN CONTAMINATED FOOTWEAR.
Supplemental Safety and Health
* Product Identification *
Product ID:GIBRALTAR
* Composition/Information on Ingredients *
Ingred Name:SODIUM HYDROXIDE, CAUSTIC SODA, LYE
Other REC Limits:2MG/M3 CEILING NIOSH
OSHA PEL:2 MG/M3
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: CORROSIVE, BURNS, DAMAGE &
IRRITATION. SKIN: CORROSIVE, BURNS TISSUE & IRRITATION. INHALATION:
PULMONARY IRRITATION. INGESTION: CORROSIVE, FATAL,
ESOPHOGICAL/GASTRIC PERFORATION, BURNS MOUTH, TH ROAT & MUCOUS
MEMBRANES.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES: CORROSIVE, BURNS, DAMAGE & IRRITATION.
SKIN: CORROSIVE, BURNS TISSUE & IRRITATION. INHALATION: PULMONARY
IRRITATION. INGESTION: CORROSIVE, FATAL, ESOPHOGICAL/GASTRIC
PERFORATION, BURNS MOUTH, TH ROAT & MUCOUS MEMBRANES.
Medical Cond Aggravated by Exposure:DERMATITIS & RELATED SKIN
CODITIONS.
* First Aid Measures *
WASH W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. INGESTION:
DRINK SEVERAL GLASSES OF MILK/EGG WHITES/GELATIN OR WATER. DON'T
INDUCE VOMIT ING. NEVER GIVE ANYTHING BY MOUTH TO ANUNCONSCIOUS
PERSON. OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Extinguishing Media:WATER
* Accidental Release Measures *
Spill Release Procedures:SWEEP UP. DILUTE W/WATER & FLUSH TO SEWER.
WASH SPILL AREAS THOROUGHLY. PLACE CAP FROM NEW UNIT ON EMPTY
CONTAINER.
*Handling and Storage *
Handling and Storage Precautions:DON'T TAKE INTERNALLY. KEEP CONTAINER
CLOSED UNTIL READY TO USE. SEE CONTAINER INSTRUCTIONS FOR PLACING
IN SAF-FEED DISPENSER.
Other Precautions:KEEP OUT OF REACH OF CHILDREN. DON'T SET PARTIALLY
USED CONTAINERS ON STAINLESS STEEL MACHINE PARTS AS DISCOLORATION
OF METAL MAY RESULT.
* Physical/Chemical Properties *
Appearance and Odor:WHITE SOLID W/SLIGHT DETERGENT ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ACIDS & STRONG OXIDIZING AGENTS
* Disposal Considerations *
Waste Disposal Methods:DISCARD IN TRASH. UNUSED SOLID IN CONTAINER
SHOULD BE RETURNED TO SHUR-FEED UNIT & MACHINE OPERATED UNTIL ALL
CHEMICALS ARE DISSOLVED BY DISHWASHER.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF TLV IS EXCEEDED, WEAR NIOSH/MSHA APPROVED
ORGANIC RESPIRATOR OR NIOSH/MSHA APPROVED AIR-SUPPLIED RESPIRATOR.
WHEN SPRAYING INDOORS WITHOUT ADEQUATE VENTILATION, AN NIOSH/MSHA
APPROVED AIR- SUPPLIED RESP MUST BE WORN.
Ventilation:PROVIDE LOCAL EXHAUST TO STAY BELOW TLV.
Other Protective Equipment:AVOID EYE AND SKIN CONT. EYE WASH SYSTEM &
SAFETY SHOWERS SHOULD BE AVAILABLE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
ATM. DO NOT SEAL DRUMS OR CONTAINERS. DRAIN DRUMS & PUNCTURE TO
PREVENT REUSE. DISPOSE OF AS ORDINARY INDUSTRIAL WASTE. CAUTION:
UNDER NO CIRCUMSTANCES SHOULD EMPTY DRUMS BE BURNED OR CUT OPEN
WITH AN ELECTRIC OR GAS TORCH.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ISOCYANIC ACID, METHYLENEDI-P-PHENYLENE ESTER;
(DIPHENYLMETHANE DIISOCYANATE)
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:HIGHER MOLECULAR WEIGHT POLYMERS OF MDI; (HIGHER POLYMERS
OF SIMILAR STRUCTURE)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY CAUSE SKIN OR EYE IRRITATION UPON
CONTACT. INHAL OF MDI VAPORS MAY CAUSE BREATHLESSNESS, CHEST
DISCOMFORT, COUGHING AND REDUCED PULMONARY FUNCTIONS. EXPOSURE MAY
PRODUCE ASTHMA-LIKE SYMPTOMS, ALSOMAY LEAD TO ALLERGIC
SENSITIVITY.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
OBTAIN MED ATTN. SKIN: REMOVE CONTAMINATED CLOTHING AND WASH OFF
WITH SOAP AND WATER. INHAL: REMOVE TO FRESH AIR, ADMINISTER O2 IF
NEC. INGEST: DRINK LARGE AMOUNTS OF WATER. SEE PHYS.
* Fire Fighting Measures *
Flash Point Method:PMCC
Extinguishing Media:WATER, DRY CHEMICALS, CO2.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
DECOMPOSE CAUSING PRESS BUILD-UP IN CLSD CONTR & POSS RUPTURE.
AVOID H2O CONTAM IN CLSD CONTR WHICH MAY CAUSE (SUPP DATA
* Accidental Release Measures *
Spill Release Procedures:CNTN SPILL. ABSORB W/SAWDUST, ETC. & SHOVEL
INTO OPEN TOP DRUM. DECONTAM ABSORB & SPILL AREA W/2% DETERGENT/H2O
SOLN. LET WASTE STAND FOR 1-2 DAYS, THEN DISPOSE OF WASTE IN
LICENSED FACILITY. RESP PRO T/VENT IS RECOM DURING CLEAN-UP.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
KEEP TIGHTLY SEALED TO PVNT MOISTURE CONTAM. RELIEVE PRESS SLOWLY
WHEN OPENING CONTR.
Other Precautions:ONCE OPENED, PROTECT CONTENTS FROM H2O W/DRY ATM
ISOCYANATE DRUMS/OTHER CONTR SHOULD BE DECONTAMD BY FILLING
W/H2O/DECONTAM SOLN, PRE F OUTDOORS. ALLOW TO STAND (SUPP DATA)
* Physical/Chemical Properties *
HCC:T6
Solubility in Water:INSOLUBLE, REACTS
Appearance and Odor:BROWN LIQUID, SLIGHTLY AROMATIC ODOR.
Percent Volatiles by Volume:NONE
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
WATER, ALCOHOLS, AMINES, STRONG BASES.
Stability Condition to Avoid:CONTAMINATION WITH WATER.
Hazardous Decomposition Products:BY HIGH HEAT OR FIRE; CO, CO2, NOX,
BENZENE, TOLUENE, ALIPHATIC FRAGMENTS, TRACES OF HCN.
Conditions to Avoid Polymerization:MAY OCCUR IF IN CONTACT WITH WATER
OR OTHER ISOCYANATE REACTIVE MATERIALS.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL REGULAIONS .
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR GAS MASK W/USBM APPRVD CANISTER IF USING IN
CONFINER AREA.
Ventilation:MECHANICAL(GEN)
Supplemental Safety and Health
PER MSDS,THE BALANCE OF PRODUCT IS WATER.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SODIUM SILICATE
Fraction by Wt: <0.5%
Ingred Name:ANIONIC & NONIONIC WETTING AGENTS
Fraction by Wt: <5.0%
Ingred Name:2-BUTOXYETHANOL
Fraction by Wt: <5.0%
Ingred Name:HEXYLENE GLYCOL
Fraction by Wt: <5.0%
Ingred Name:SODIUM CHROMATE (SARA III)
Fraction by Wt: 0.1%
OSHA PEL:0.1 PPM CRO3;CEILING
* Hazards Identification *
Effects of Overexposure:EYES:SEV IRRIT;ING:NAUSEA;SKIN:DEFAT,IRRIT,POSS
INFAM;INH:IRRIT OF RESP TRACT;ACUTE:HEAT POSS DIZZ
* First Aid Measures *
First Aid:EYES:FLUSH WELL W/WATER.OBTAIN MED ATTN;SKIN:WASH WELL W/SOAP
& WATER;INH:MOVE TO FRESH AIR.IF DIFFICULTY IN BREATHING,GIVE
OXYGEN.ING:GIVE EMETICS TO INDUCE VOMITING.
* Fire Fighting Measures *
Flash Point:NONE
Lower Limits:UNK
Upper Limits:UNK
Fire Fighting Procedures:NONE KNOWN
Unusual Fire/Explosion Hazard:NONE KNOWN
* Accidental Release Measures *
Spill Release Procedures:COLLECT & CONTAIN THE SPILLAGE IN SEALABLE
CONTAINER THE SUITABLE FOR SHIPMENT TO DISPOSAL AREA.WEAR PROTEC
EQUIP BEFORE CLEAN-UP.
*Handling and Storage *
Handling and Storage Precautions:STORE & TRNSP AT TEMPERATURE BETWEEN
* Physical/Chemical Properties *
HCC:N1
Vapor Density:>1.0
Evaporation Rate & Reference:>1.0(BU-ACETATE)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR YELLOW LIQ.BUTYL CELLOSOLVE ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS
Hazardous Decomposition Products:OXIDES OF CARBON
* Disposal Considerations *
Waste Disposal Methods:TREAT PRODUCT TO REMOVE/REDUCE CROMIUM(VI) TO
CHROMIUM(III).TREATED SPILLS MAY BE DISCHARGED TO SEWER OR LANDFILL
IAW LOCAL,STATE & FED REGULATION.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR FOR METAL
FUMES.
Other Protective Equipment:EAR PROTECTION AS REQD.
Supplemental Safety and Health
NITRIC OXIDE AND OZONE RESPECTIVELY.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ALUMINUM (SARA III)
* Hazards Identification *
Effects of Overexposure:LONG TERM INHALATION MAY CAUSE
DERMATITIS,BRONCHIAL ASTHMA,LOSS OF APPETITE, (SEE SUPPLEMENTAL
DATA)
* First Aid Measures *
First Aid:EYE:FLUSH W/COPIOUS AMOUNT OF WATER;SKIN:WASH WITH SOAP &
WATER;INHAL:REMOVE TO FRESH AIR,GIVE ARTFICIAL RESPIRATION IF
NEEDED;IF IRRITATION PERSISTS,CONSULT A PHYSICIAN.
* Fire Fighting Measures *
Extinguishing Media:SPECIAL DRY POWDER FOR CLASS D FIRE.
Fire Fighting Procedures:FLAMMABLE SOLID.DO NOT USE WATER
Unusual Fire/Explosion Hazard:MODERATE FIRE HAZARD IN THE FORM OF DUST
WHEN EXPOSED TO HEAT OR ON CONTACT W/STRONG OXIDIZERS.
* Accidental Release Measures *
Spill Release Procedures:GOOD HOUSE KEEPING BY SWEEPING THE AREA CLEAN
IS NECESSARY TO REMOVE THESE MATERIALS FROM BECOMING A SOURCE OF
AIR CONTAMINATION.
*Handling and Storage *
Handling and Storage Precautions:AVOID EXCESSIVE SKIN CONTACT & ORAL
INGESTION.
Other Precautions:AVOID BREATHING DUST DURING SPRAYING
* Physical/Chemical Properties *
HCC:F8
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
WHEN WET,COULD RELEASE HYDROGEN.
Stability Condition to Avoid:CHLORINATED HYDROCARBON VAPOR NEAR PLASMA
FLAME MAY BE"SUPP"
Hazardous Decomposition Products:OZONE,NITRIC OXIDE FORMED BY PLASMA
FLAME.
Conditions to Avoid Polymerization:AVOID EXCEED TLV OF
* Disposal Considerations *
Waste Disposal Methods:KEEP IN COVERED DRUMS,PENDING DISPOSAL. HANDLE &
DISPOSE IN FULL COMPLIANCE WITH ALL APPLICABLE
INTERNATIONAL,FEDERAL,STATE, & LOCAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IN AREAS WHERE TLVS MAY BE EXCEEDED OR IF SPRAY
MIST IS PRESENT, USE NIOSH/MSHA APPRVD RESP PROT APPROP FOR
INDICATED COMPONENTS. IN CONFINED AREAS, USE NIOSH/MSHA APPRVD AIR
Ventilation:WHERE EMPLOYEES MAY BE EXPOSED, PROVIDE GEN DILUTION OR LOC
Other Protective Equipment:AVOID SKIN CONTACT BY USE OF OTHER PROT
CLTHG. A SAFETY SHOWER, AN EYE BATH & WASHING FACILITIES SHOULD BE
AVAIL.
Work Hygienic Practices:PREVENT PROLONGED CONTACT W/CONTAMINATED
CLOTHING. WASH CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
EXPLO HAZ:OCCUR. CLSD CONTRS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT.
THERMAL DECOMP PRODS MAY INCL HCL & PHOSGENE . EFTS OF
OVEREXP:CHLOROCARBON MATLS HAVE PRDCED SENSIT OF MYOCARDIUM TO
EPINE PHRINE IN LAB ANIMALS & COULD HAVE SIMILAR EFT IN HUMANS.
ADRENOMIMETICS (E.G. EPINEPHRINE) MAY BE (ING 9)
* Product Identification *
* Composition/Information on Ingredients *
THAT IS IN CONTACT W/CHLORINATED SOLVENTS.
Ingred Name:VENT:INGREDS BELOW RECOMMENDED (ACGIH TLV) OR REGULATED
Ingred Name:BUTYL ALCOHOL; (N-BUTANOL). VP:4.4
Fraction by Wt: <5%
Fraction by Wt: <5%
Ingred Name:BENZENE, ETHYL-; (ETHYL BENZENE) (SARA III). VP:7.1
Fraction by Wt: <5%
Ingred Name:POLYAMIDE; (POLYAMINE RESIN)
Ingred Name:PHENOL, 2,4,6-TRIS(DIMETHYLAMINOMETHYL)-; (ALIPHATIC AMINE)
Fraction by Wt: <5%
Ingred Name:SUPP DATA:CONTRAINDICATED EXCEPT FOR LIFE-SUSTAINING USES
IN HUMANS ACUTELY/CHRONICALLY EXPOSED TO CHLOROCARBONS .
Ingred Name:SPILL PROC:ABSORB W/INERT MATERIAL.
Ingred Name:OTHER PREC:NEAR DRUM. DO NOT TAKE INTERNALLY. DO NOT DELIB
Ingred Name:ETHANE, 1,1,1-TRICHLORO-; (TRICHLOROETHANE) (SARA III).
Ozone Depleting Chemical:1
Ingred Name:P-DIOXANE; (DIETHYLENE DIOXIDE) (SARA III).
Fraction by Wt: <5%
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHAL:MAY CAUSE NASAL & RESP IRRIT &
ACUTE CNS DEPRESS CHARACT BY HDCH, DIZZ, STAG GAIT, CONFUSN OR
UNCON. ASPHY MAY RSLT FROM BRTHG O*2 DEFICIENT AIR.
SKIN:PRLNGD/RPTD CONT MAY CAUSE IRRIT, DEFATTING , DERM OR SKIN
SENSIT IN SOME INDIV. EYES:CAUSES IRRIT. INGEST:MAY CAUSE GI IRRIT,
NAUS, VOM & DIARR. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:DIOXANE (1,4):ANTICIPATED TO BE
CARCINOGEN.(NTP); GROUP 2B (IARC)
Effects of Overexposure:HLTH HAZ:ASPIR OF MATL INTO LUNGS CAN CAUSE
CHEM PNEUM WHICH CAN BE FATAL. OTHER:RPTS HAVE ASSOC RPTD/PRLNGD
OCCUP OVEREXPOS TO SOLV W/PERM BRAIN & NERV SYS DAM. EFTS INCL CONC
DFCLTIES, DIMINISHED MA NUAL DEXTERITY & MEMORY LOSS. EXPOS TO A
COMPONENT IN THIS PORD MAY INCL "MYOCARDIAL IRRITABILITY". (SUPP
DATA)
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN, LUNG & EYE
CONDITIONS.
* First Aid Measures *
First Aid:INHAL:REMOVE TO FRESH AIR. GIVE ARTF RESP OR CPR IF REQUIRED.
IF BREATHING IS DIFFICULT, GIVE O*2. KEEP WARM & QUIET. GET MED
ATTN. SKIN:WASH AFFECTD AREAS W/SOAP & WATER. DO NOT USE SOLVENTS.
REMOVE CONTAMINATED CLOTHING & WASH BEFORE REUSE. GET MED ATTN.
FROM AN OPTHALMOLOGIST. INGEST:GET MED ATTN.
* Fire Fighting Measures *
Flash Point Method:SCC
Lower Limits:1%
Extinguishing Media:EXTINGUISHERS (CARBON DIOXIDE, DRY CHEMICAL OR
FOAM).
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD PRESS DEMAND SCBA &
FULL PROT EQUIP . WATER SPRAY MAY BE INEFT. COOL FIRE EXPOSED
CONTRS W/WATER. FOG NOZZ ARE PREFERABLE.
Unusual Fire/Explosion Hazard:VAPS MAY ACCUM IN INADEQ VENTD/CONFINED
AREAS. VAPS MAY FORM EXPLOS MIX W/AIR. VAPS MAY TRAVEL LONG
DISTANCES. FLASHBACK/FLAME TO HNDLNG SITE MAY (SUPP DATA)
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT. WEAR PERSONAL
PROT EQUIP TO AVOID BRTHG VAPS & SKIN/EYE CONT W/SPILLED MATL. USE
NON-SPRKG TOOLS. USE EMER RESPONSE PROFESSIONAL IF MANAGING RELS IS
BEYOND CAPABILITY OF I N-HOUSE PERS. FOR SMALL SPILLS, DIKE & (ING
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
I/A/W APPLIC NFPA CODES & GOVTL REGS. KEEP CONTR TIGHTLY CLSD.
ISOLATE FROM HEAT, ELEC EQUIP, SPARKS & FLAME.
Other Precautions:GROUNDING/BONDING PROC SHOULD BE FOLLOWED WHEN
TRANSFERRING MATL. AVOID FREE FALL OF LIQ. DO NOT SMOKE WHERE MATL
IS USED/STORED. DO NOT APPLY TO HOT SURF. EMPTY DRUMS MAY CONTAIN
* Physical/Chemical Properties *
HCC:F3
Vapor Pres:SEE INGRED
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER/N-BUTYL ACETATE
Appearance and Odor:AMBER LIQUID; SOLVENT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE RECOGNIZED.
Stability Condition to Avoid:NONE RECOGNIZED.
Hazardous Decomposition Products:PRODS OF COMBUST ARE HAZ INCL CO &
CO*2. MAY ALSO INCL HCL & POSS SMALL AMTS OF PHOSGENE & CHLORINE
* Disposal Considerations *
Waste Disposal Methods:WHEN DISPOSING OF THIS MATL, ENSURE THAT IT IS
PACKAGED, STORED, TRANSPORTED & OTHERWISE MANAGED I/A/W LOC, STATE
& FED REGS. NO DISP METH IS TO BE USED THAT WOULD POSE AN ENVIRON
OR HUMAN HLTH THREAT INCL ANY WHICH WOULD CONTAM GROUND/SURF
WATER.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE RESPIRABLE FUME RESPIRATOR OR AIR SUPPLIED
RESPIRATORY WHEN WELDING IN CONFINED SPACE OR WHERE LOCAL EXHAUST
OR VENTILATION DOES NOT KEEP EXPOSURE BELOW TLV.
Ventilation:LOCAL EXHAUST AT THE ARC TO KEEP THE FUMES & GASES BELOW
THE TLV.
Other Protective Equipment:HELMET, ARM PROTECTORS, APRONS, HATS,
Supplemental Safety and Health
THE PRODUCT AS SUPPLIED IS NON-HAZARDOUS. HEALTH HAZARDS OCCUR DURING
OPERATIONS. THE COMPOSTION & QUANTITY OF WELDING FUMES ARE
DEPENDENT ON THE PROCESS, PROCEDURES, MEDIA, CONTAMINENTS IN THE
ATMOSP HERE, & ELECTRODES USED.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:MOLYBDENUM (SOLUBLE COMPOUND), LEAD MOLYBDATE
Ingred Name:CHROMIUM METAL, CHROMIUM, CHROME (SUSPECTED A1 HUMAN
CARCINOGEN BY IARC, NTP & ACGIH)
OSHA PEL:1 MG/CUM (CEILING)
ACGIH TLV:0.5 MG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:NICKEL (SOLUBLE) (SUSPECTED HUMAN CARCINOGEN BY NTP, IARC,
ACGIH) INTENDED CHANGE (IC)
Other REC Limits:1 MG/CUM
OSHA PEL:1 MG/CUM
Ingred Name:IRON
ACGIH TLV:5 MG/CUM
Ingred Name:SILICON
Ingred Name:MANGANESE, MN COMPOUNDS
OSHA PEL:(C) 5 MG/M3 DUST
Ingred Name:CALCIUM FLUORIDE, FLUORSPAR, CALCIUM DIFLUORIDE, IRTRAN 3,
LIPARITE
Other REC Limits:2.5 MG/CUM (AS F)
OSHA PEL:2.5 MG/CUM (AS F)
ACGIH TLV:2.5 MG/CUM (AS F)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:IRRITATION OF NOSE, THROAT, EYES. MAY
LEAD TO SIDEROSIS WHICH MAY AFFECT PULMONARY FUNCTION. ARC RAYS CAN
INJURE EYES & BURN SKIN. ELECTRIC SHOCK CAN KILL. SEE SUPP.
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:INHALATION: DIZZINESS, NAUSEA, IRRITATION OF
NOSE & THROAT. EYES: IRRITATION. SKIN: DRYNESS & BURNS.
Medical Cond Aggravated by Exposure:RESPIRATORY OR ALLERGIC CONDITIONS.
* First Aid Measures *
First Aid:EMPLOY FIRST AID TECHNIQUES RECOMMENDED BY THE AMERICAN RED
CROSS. OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point:NON-FLAMMABLE
Unusual Fire/Explosion Hazard:WELDING ARC & SPARKS CAN IGNITE
COMBUSTIBLES.
*Handling and Storage *
Handling and Storage Precautions:KEEP HEAD OUT OF FUMES, DON'T TOUCH
LIVE ELECTRICAL PARTS, INSULATE FROM WORK & GROUND.
Other Precautions:TO DETERMINE COMPOSITION & QUANTITY OF FUMES & GASES
TO WHICH WORKERS ARE EXPOSED IS TO TAKE AN AIR SAMPLE INSIDE THE
WELDERS HELMET OR IN THE WORKER'S BREATHING ZONE.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
SEE SUPP
Stability Condition to Avoid:SEE SUPP
Hazardous Decomposition Products:CO, CO2, OZONE & NITROGEN OXIDES
FORMED BY THE RADIATION FROM ARC. WELDING FUMES - COMPLEX OXIDES
FROM THE INGREDIENTS.
* Disposal Considerations *
Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER OR
LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE
W/FEDERAL, STATE & LOC AL REGULATIONS.
| 1 | gloves_mandatory |
Control Measures
*
*
Preparer Co. when other than Responsible Party Co.
*
Assigned Ind: Y
*
Contractor Summary
*
*
Ingredients
*
CHLOROTHENE
Ozone Depleting Chemical: 1
------------------------------
-----------------------------
% Wt: <1
Other REC Limits: 1 MG(CU)/M3 (DUST)
OSHA PEL: 0.1 MG(CU)/M3 (FUME)
ACGIH TLV: 0.2 MG/M3 (FUME)
------------------------------
CHANGES (IC)
% Wt: <4
------------------------------
% Wt: <1
------------------------------
% Wt: <1
ACGIH TLV: 0.2 MG/CUM
------------------------------
ACGIH TLV: SIMPLE ASPHYXIANT
------------------------------
------------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYES: IRRITATION. INGESTION: HEADACHE, NAUSEA, DIZZINESS.
NARCOSIS AT HIGH CONCENTRATIONS.
Explanation Of Carcinogenicity: NONE
Signs And Symptions Of Overexposure: INHALATION: PULMONARY EFFECTS.
First Aid: INGESTION: DON'T INDUCE VOMITING. INHALATION: REMOVE TO FRESH AIR.
OBTAIN MEDICAL ATTENTION IN ALL CASES.
*
Handling and Disposal
*
Spill Release Procedures: SOAK UP IN AN INERT ABSORBENT.
Waste Disposal Methods: LANDFILL OR INCINERATE IN ACCORDANCE W/EPA & LOCAL
Other Precautions: AVOID CONTACT W/EYES. AVOID PROLONGED BREATHING OF VAPOR.
*
Fire and Explosion Hazard Information
*
Flash Point Method: TCC
Extinguishing Media: CO2, FOAM, DRY CHEMICAL
*
*
Ventilation: LOCAL TO MAINTAIN VAPOR CONCENTRATION BELOW TLV.
Work Hygienic Practices: WASH HANDS THOROUGHLY AFTER HANDLING.
*
Physical/Chemical Properties
*
Vapor Density: 2.9
Solubility in Water: NEGLIGIBLE
Appearance and Odor: METALLIC PASTE, PUNGENT ODOR
*
Reactivity Data
*
Stability Indicator: YES
Materials To Avoid: CAUSTICS, ACTIVE METALS, STRONG OXIDIZERS
Hazardous Decomposition Products: TOXIC CHLORIDES, METAL VAPORS
Hazardous Polymerization Indicator: NO
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Assigned IND: Y
Company Name: LOCTITE CORP AUTOMOTIVE & CONSUMER GROUP
Label Required IND: Y
Status Code: C
Origination Code: F
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: CAUTION
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: EYES: IRRITATION. INGESTION: HEADACHE, NAUSEA,
DIZZINESS. NARCOSIS AT HIGH CONCENTRATIONS. TARGET ORGANS: EYES, DIGESTIVE
TRACT, LUNGS. EYES/SKIN: IRRITATION. INHALATION: MUCOUS
MEM BRANE IRRITATION. INGESTION: HARMFUL, MAY CAUSE BLURRED VISION. TARGET
ORGANS: EYES.
*
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE NORMALLY REQUIRED. IF WORKPLACE EXPOSURE
LIMIT IS EXCEEDED, A NIOSH APPROVED AIR SUPPLIED RESPIRATOR OR A
RESPIRATOR FOR TOXIC DUST IS ADVISED.
Ventilation:PROVIDE SUFFICIENT MECHANICAL VENTILATION TO MAINTAIN
EXPOSURE BELOW TLV(S).
Other Protective Equipment:EYE WASH STATION, EMERGENCY SHOWER,
APPROPRIATE LABORATORY COAT TO COVER EXPOSED SKIN
Work Hygienic Practices:DO NOT PERMIT EATING OR DRINKING NEAR THIS
MATERIAL. AVOID INGESTION OF THIS MATERIAL.
Supplemental Safety and Health
* Product Identification *
Product ID:COPPER SULFATE
CAGE:PHELP
CAGE:PHELP
* Composition/Information on Ingredients *
Ingred Name:CUPRIC SULFATE,PENTAHYDRATE
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1MG/M3(CU)DUST/MIST.
ACGIH TLV:1MG/M3(CU)DUST/MIST.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE- DUST MAY CAUSE NOSE IRRITATION.
ULCERATION OF NASAL SEPTUM MAY OCCUR. MAY CAUSE EYE IRRITATION AND
SKIN ITCHING. HARMFUL IF SWALLOWED. MAY CAUSE SEVERE GI TRACT
IRRITATION. CHRONIC- REPEATED OR PROLONGED SKIN CONTACT MAY CAUSE
DERMATITIS. TARGET ORGANS:EYES, SKIN, RESPIRATORY AND
GASTROINTESTINAL TRACTS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:LOCALIZED SKIN DISCOLORATION, ITCHING, EYE
IRRITATION, ULCERATION OF NASAL SEPTUM, UPPER RESPIRATORY TRACT
IRRITATION
Medical Cond Aggravated by Exposure:WILSON'S DISEASE (INDIVISUAL
ABSORBS, RETAINS AND STORES COPPER EXCESSIVELY).
* First Aid Measures *
First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYE:FLUSH WITH
AT LEAST 5 MINUTES. REMOVE CONTAMINATED CLOTHING. INHALED:REMOVE TO
FRESH A IR & PROVIDE OXYGEN/CPR IF NEEDED. ORAL:IF CONSCIOUS, DRINK
2-3 GLASSES OF MILK OR WATER & INDUCE VOMITING. SEEK MEDICAL
ATTENTION.
* Fire Fighting Measures *
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM, DRY CHEMICAL FOR
SURROUNDING FIRE. DO NOT USE DIRECT WATER STREAM ON MOLTEN
MATERIAL.
Fire Fighting Procedures:WEAR NIOSH-APPROVED SELF-CONTAINED BREATHING
APPARATUS. USE WATER SPRAY TO DISPERSE VAPOR AND COOL FIRE-EXPOSED
CONTAINERS.
WILL FORM SULFUR DIOXIDE. IF WATER IS USED, CARE SHOULD BE USED TO
KEEP SUCH WATER OUT OF STREAMS OR OTEHR WATER BODIES.
* Accidental Release Measures *
Spill Release Procedures:SWEEP UP CRYSTALS OR POWDER. VACUUMING IS
PREFERRED. DO NOT RAISE DUST. WASH AND VENTILATE SPILL SITE AFTER
PICKUP IS COMPLETE. IF PRODUCT IS IN SOLUTION, ADD LIME OR SODA ASH
TO FORM INSOLUBLE COPPER SALTS AND THEN DISPOSE IN AN APPROVED
LANDFILL.
Neutralizing Agent:SODA ASH OR LIME FOR SOLUTION
*Handling and Storage *
Handling and Storage Precautions:STORE IN CLOSED CONTAINERS IN A COOL,
DRY, WELL VENTILATED AREA AWAY FROM INCOMPATIBLE MATERIALS.
Other Precautions:TOXIC. DO NOT RAISE DUST. AVOID CONTACT WITH EYES AND
SKIN. AVOID BREATHING DUST. WASH THOROUGHLY AFTER HANDLING
MATERIAL. KEEP AWAY FROM REACH OF CHILDREN.
* Physical/Chemical Properties *
HCC:N1
NRC/State Lic Num:NOT RELEVANT
Evaporation Rate & Reference:NOT RELEVANT
Appearance and Odor:TRANSPARENT BLUE CRYSTALS, GRANULES OR POWDER - NO
ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
CONTACT WITH MAGNESIUM METAL MAY GENERATE DANGEROUS LEVELS OF HYDROGEN
GAS. KEEP AWAY FROM HYDROXYLAMINE. REDUCING AGENT
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS OR CONTACT AN APPROVED/LICENSED DISPOSAL
AGENCY.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IN NORMAL CONDITIONS,NOT NEEDED.USE AIR SUPPLD
MASK WHEN NEEDED
Ventilation:MECHANICAL (GEN) PREFERRED
Other Protective Equipment:RUBBER OR PLASTIC COVERALLS OR APRON
Supplemental Safety and Health
* Product Identification *
Product ID:EPOLITE RESIN T
* Composition/Information on Ingredients *
* First Aid Measures *
First Aid:INHALE:REMOVE TO FRESH AIR, GIVE CPR/O*2 IF
GET MEDICAL ATTENTION FOR EYES, BREATHING DIFFICULTY, OR OTHER
SYMPTOMS OF OVEREXPOSURE.
* Fire Fighting Measures *
Extinguishing Media:CO*2, FOAM, DRY CHEM & H*2O FOG.
CONTR.
Unusual Fire/Explosion Hazard:NONE NOTED BY MANUFACTURER.
* Accidental Release Measures *
Spill Release Procedures:VENTILATE AREA.USE PROTECTIVE
EQUIPMENTS.ABSORB LIQ IN SAWDUST OR OTHER ABSORBENT.ELIM IGNITION
SOURCES DURING CLEAN UP.STORE TEMPORARILY IN AN OPEN CONTAINER,&
MARK ACCORDINGLY.
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED
AREA. PROTECT FROM PHYSICAL DAMAGE.AVOID ANY PHYSICAL CONTACT. KEEP
CONTAINERS TIGHTLY CLOSED
Other Precautions:AVOID SKIN,EYE,& CLOTHING CONTACT.LAUNDER
CONTAMINATED CLOTHING BEFORE REUSE.CONTAMINATED SHOES SHOULD BE
CLEANED THOROUGHLY OR DISCARDED.
* Physical/Chemical Properties *
HCC:N1
Evaporation Rate & Reference:<1.0(WATER=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BLUE COLOR LIQUID,VERY LIGHT ODOR.
Percent Volatiles by Volume:<0.1
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:EXCESSIVE HEAT/IGNITION SOURCES.
Hazardous Decomposition Products:INCOMPLETELY BURNED CARBON PRODUCTS,
CO*2, CO.
* Disposal Considerations *
Waste Disposal Methods:INCINERATE IN APPROVED INCINERATOR OR DISPOSE OF
IN APPROVED CHEMICAL DUMP IN ACCORDANCE WITH LOCAL,STATE & FEDERAL
REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF PERS EXPOS CANNOT BE CONTROLLED BELOW APPLIC
LIMITS BY VENT, WEAR PROPERLY FITTED ORGANIC VAP/PARTICULATE RESP
APPRVD BY NIOSH/MSHA FOR PROT AGAINST MATLS IN ING SECTION. WHEN
Ventilation:LOCAL EXHAUST PREF. GEN EXHAUST ACCEPTABLE IF EXPOS TO
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
MFR TRADE NAME/PART #:BULKS-1 RT-B/KRI1, DEEP BLUE. FIRE FIGHT
PROC:USED TO COOL CLSD CNTNRS TO PRVNT PRESS BUILD-UP & POSS
AUTOIGNITION OR EXPOS WHEN EXPOSED TO EXTREME HEAT. EXPLO HAZ:PREC.
DURING E MERGENCY CNDTNS EXPOS TO DECOMP PRODS MAY CAUSE HLTH HAZ.
SYMPS MAY NOT BE IMMED APPARENT. OBTAIN MED ATTEN.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:RESP PROT: RESP APPRVD BY NIOSH/MSHA FOR PROT AGAINST
NON-VOLATILE MATERIALS IN INGREDIENTS SECTION.
Ingred Name:MINERAL SPIRITS; VP:2.0 MM HG
Ingred Name:TITANIUM DIOXIDE; (TITANIUM DIOXIDE)
Fraction by Wt: 6%
Ingred Name:EFTS OF OVEREXP:(SILICOSIS) & POSS CANCER. PRLNGD OVEREXPOS
TO SOLV INGRED IN ING SECTION MAY CAUSE ADVERSE EFTS (ING 5)
Ingred Name:ING 4:TO LIVER & URINARY SYS. RATS EXPOSED TO TITANIUM
Ingred Name:ING 5:SUCH EXOS LEVELS ARE NOT ATTAINABLE IN WORKPLACE.
RPTS HAVE ASSOC RPTD & PRLNGD OVEREXP TO SOLV W/PERM (ING 7)
Ingred Name:ING 6:BRAIN AND NERVOUS SYSTEM DAMAGE.
Ingred Name:DISP METH:OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL
REGULATIONS REGARDING POLLUTION.
Ingred Name:HNDLG/STOR PREC:PARTICULATES (LISTED "AS DUST" IN ING
Ingred Name:ING 9:SANDING/ABRADING OF DRIED FILM. IF NO SPECIFIC DUSTS
Ingred Name:OTHER PREC:KEEP AREA VENT. DO NOT SMOKE-EXTINGUISH ALL
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TO MINIMIZE EXPOS, FOLLOW
RECOMMENDATIONS FOR PROPER USE, VENT, & PERS PROT EQUIP.
ACUTE:IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERVOUS SYS
DEPRESS. EXTREME OVEREXPOS MAY RESULT IN UNCONSCIOUSNESS & POSS
DEATH. HDCH, DIZZ, NAUS, & LOSS OF COORD ARE INDICATIONS OF EXCESS
EXPOS TO VAP OR SPRAY MISTS.(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:REDNESS & ITCHING OR BURNING SENSATION
MAY INDICATE EYE/EXCESS SKIN EXPOS. CHRONIC:CERTAIN PRODS CONTAIN
QUARTZ. QUARTZ, ALSO KNOWN AS CRYSTALLINE SILICA, IS LISTED BY
IARC. LONG TERM EXPOS T O HIGH LEVELS OF SILICA DUST, WHICH
CANOCCUR ONLY WHEN SANDING OR ABRADING DRY FILM, MAY CAUSE LUNG
DAMAGE (ING 4)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
* First Aid Measures *
First Aid:INHAL:IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING.
KEEP WARM AND QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY WITH SOAP
AND WATER. EYES:FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT LEAST
* Fire Fighting Measures *
Flash Point Method:PMCC
Lower Limits:1.0
Upper Limits:6.0
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS
USED, FOG NOZZ ARE PREF. WATER MAY BE (SUPP DATA)
Unusual Fire/Explosion Hazard:ISOLATE FROM HEAT, ELECT EQUIP, SPARKS,
AND OPEN FLAME. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO
EXTREME HEAT. APPLIC TO HOT SURF REQ SPECIAL (SUPP DATA)
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENT AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:USE ONLY W/ADEQ VENT. AVOID BRTHG VAP
& SPRAY MIST. AVOID CONTACT WITH SKIN AND EYES. THESE COATINGS MAY
CONTAIN MATLS CLASSIFIED AS NUISANCE (ING 9)
Other Precautions:INTENTIONAL MISUSE BY DELIB CONC & INHALING CONTENTS
CAN BE HARMFUL/FATAL. CONTENTS ARE COMBUST. KEEP AWAY FROM HEAT,
SPARKS, & OPEN FLAME. VAPS WILL ACCUMULATE READILY & MAY IGNITE
* Physical/Chemical Properties *
HCC:F4
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE:CARBON DIOXIDE, CARBON
MONOXIDE.
* Disposal Considerations *
Waste Disposal Methods:WASTE FROM PROD MAY BE HAZ AS DEFINED UNDER
BE TESTED FOR IGNITABILITY TO DETERMINE APPLIC EPA HAZ WASTE
NUMBERS. INCIN IN APPRVD FA CILITY. DO NOT INCIN CLSD CNTNR.
DISPOSE (ING 8)
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WHERE RESPIRATORY PROTECTION IS REQUIRED, USE
ONLY NIOSH/MSHA APPROVED RESPIRATORS TO KEEP BELOW TLV.
Ventilation:PROVIDE MECHANICAL OR LOCAL EXHAUST VENTILATION TO PREVENT
BUILD-UP OF VAPORS & TO KEEP BELOW TLV.
Other Protective Equipment:EYE WASH & SAFETY SHOWER
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH HANDS THOROUGHLY AFTER HANDLING, BEFORE EATING &
SMOKING.
Supplemental Safety and Health
CON'T INHALATION: PERMANENT BRAIN/NERVOUS SYSTEM/LIVER/KIDNEY DAMAGE.
CARDIAC/BLOOD ABNORMALITIES. DEATH. SKIN:
DERMATITIS/DEFATTING/ALLERGIC REACTION/BURNS/SENSITIZATION. EYES:
BLURRED VISION/TEARING /REDNESS/BURNS/CORNEAL INJURY. INTENTIONAL
MISUSE BY CONCENTRATING AND INHALING THE CONTENTS MAY BE HARMFUL OR
FATAL.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:XYLENE, DIMETHYLBENZENE, XYLOL
Ingred Name:ORGANOPHILIC CLAY; QUARTERNARY AMMONIUM CMPDS,
BIS(HYDROGENATED TALLOW ALKYL)DIMETHYL, CHLORIDES, COMPDS
W/BECTORITE.
Fraction by Wt: 1-5%
Ingred Name:ALIPHATIC AMINE & POLYETHYLENE POLYAMINE ADDUCT MIXTURE
Ingred Name:CLAY (KAOLIN)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: IRRITATION OF RESPIRATORY
TRACT. SKIN/EYES: IRRITATION. INGESTION: LARGE AMOUNTS MAY CAUSE
LUNG INFLAMMATION & DAMAGE DUE TO ASPIRATION OF MATERIAL INTO
LUNGS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: MUCOUS MEMBRANE
IRRITATION/FATIGUE/DROWSINESS/DIZZINESS/LIGHTHEADEDNESS/HEADACHE/UN
COORDINATION/NAUSEA/VOMITING/COUGHING/SPEECH DIFFICULTY/MENTAL
APATHY/CNS DEPRESSION/INTOXICATION/CONFUSI ON/ANESTHETIC
EFFECT/NARCOSIS/BREATHINGDIFFICULTY/RESPIRATORY TRACT
SENSITIZATION. SEE SUPPLEMENTAL FOR CON'T.
Medical Cond Aggravated by Exposure:EYE, SKIN, RESPIRATORY, LUNG,
ASTHMA-LIKE CONDITIONS, CARDIAC ABNORMALITIES, KIDNEY, LIVER &
NERVOUS SYSTEM DISORDERS.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED
BREATHING. HAVE TRAINED PERSON GIVE OXYGEN IF NECESSARY. SKIN: WASH
W/PLENTY OF SOAP & WATER. EYES: FLUSH W/LARGE AMOUNTS OF WATER FOR
CASES.
* Fire Fighting Measures *
Lower Limits:1%
Extinguishing Media:DRY CHEMICAL OR FOAM
Fire Fighting Procedures:WATER MAY BE USED TO COOL & PROTECT EXPOSED
CONTAINERS.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT OR FIRE. VAPORS CAN FORM EXPLOSIVE MIXTURES
IN AIR AT ELEVATED TEMPERATURES. FLAMMABLE LIQUID.
* Accidental Release Measures *
Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. VENTILATE
AREA W/EXPLOSION PROOF EQUIPMENT. SPILLS MAY BE COLLECTED
W/NON-COMBUSTIBLE ABSORBENT MATERIALS.
*Handling and Storage *
VENTILATION. DON'T TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN.
AVOID CONTACT W/SKIN, EYES, & BREATHING VAPORS.
Other Precautions:KEEP CONTAINERS TIGHTLY CLOSED & UPRIGHT WHEN NOT IN
USE. EMPTY CONTAINERS MAY CONTAIN HAZARDOUS RESIDUES. GROUND
EQUIPMENT WHEN TRANSFERRING TO PREVENT ACCUMULATION OF STATIC
CHARGE. AVOID SPRAYING O R ABRADING PAINTED SURFACES.
* Physical/Chemical Properties *
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OXIDIZERS, ACIDS, BASES, AMINES, ALDEHYDES, REDUCING AGENTS,
ISOCYANATES
Stability Condition to Avoid:ELEVATED TEMPERATURES, HEAT, SPARKS, OPEN
FLAME OR OTHER SOURCES OF IGNITION
Hazardous Decomposition Products:CO, CO2
* Disposal Considerations *
Waste Disposal Methods:DISPOSE IN ACCORDANCE W/ALL APPLICABLE
REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS. FLAMMABLE LIQUID.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE SHOULD BE NEEDED.
SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS
Other Protective Equipment:IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO
MINIMIZE SKIN CONTACT. EYE BATH, WASHING FACILITIES, SAFETY SHOWER.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
LOW HAZARD FOR RECOMMENDED HANDLING. KEEP OUT OF REACH OF CHILDREN.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:WATER
Other REC Limits:NONE RECOMMENDED
Ingred Name:AMMONIUM THIOSULFATE
Other REC Limits:NONE RECOMMENDED
Ingred Name:SODIUM BISULFITE (SASA III) (CERCLA)
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5 MG/M3
Ingred Name:AMMONIUM BISULFITE (CERCLA)
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:AMMONIUM ACETATE (CERCLA)
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION-EXPECTED TO BE A LOW HAZARD
FOR RECOMMENDED HANDLING. EYES-NO SPECIFIC HAZARD KNOWN. SKIN-LOW
HAZARD FOR RECOMMENDED HANDLING. INGESTION-EXPECTED TO BE A LOW
INGESTION HAZARD.
Explanation of Carcinogenicity:NOT CARCINOGENIC.
Effects of Overexposure:EYES-MAY CAUSE TRANSIENT IRRITATION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHALATION-IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL
ATTENTION IF SYMPTOMS PERSISTS. EYES-ANY MATERIAL THAT CONTACTS THE
EYE SHOULD BE WASHED OUT IMMEDIATELY WITH WATER. GET MEDICAL
ATTENTION IF SYMPTOMS OCCUR. SKIN-WASH WITH SOAP ANDWATER. GET
MEDICAL ATTENTION IF SYMPTOMS OCCUR. INGESTION-DRINK 1-2 GLASSES OF
WATER. SEEK MEDICAL ATTENTION.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:USE APPROPIATE AGENT FOR ADJACENT FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY CAUSE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL,
THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP
AWAY FROM INCOMPATIBLE SUBSTANCES.
Other Precautions:USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER
HANDLING. KEEP FROM CONTACT WITH OXIDIZING MATERIALS.
* Physical/Chemical Properties *
HCC:N1
Vapor Density:0.6
pH:4.9
Solubility in Water:COMPLETE
Appearance and Odor:LIQUID. COLORLESS -LIGHT YELLOW. VINEGAR ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
BASES, SODIUM HYPOCHLORITE, STRONG OXIDDIZING AGENTS, STRONG ACIDS.
CONTACT WITH BASE LIBERATES FLAMMABLE MATERIAL.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:AMMONIA, CHLORAMINE, SULFUR DIOXIDE,
NITROGEN OXIDES.
* Disposal Considerations *
Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE AMOUNTS
OF WATER.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF EXPOSURES EXCEED ESTABLISHED LIMITS, A
NIOSH/MSHA APPROVED RESPIRATOR FOR ASBESTOS SHOULD BE USED.
CONSULT YOUR SAFETY OFFICE/IH PERSONNEL FOR GUIDANCE FOR THE TASK
AT HAND.
Ventilation:LOCAL EXHAUST IS RECOMMENDED IN SITUATIONS WHERE DUST IS
GENERATED BY ABRASIVE ACTIONS, ABRASION OR OTHER MEANS.
Other Protective Equipment:AS REQUIRED FOR TASK AT HAND, AND THE
GUIDANCE SET FORTH BY YOUR SAFETY OFFICE OR IH PERSONNEL
Work Hygienic Practices:DONOT INHALE DUST CREATED BY ABRADING ACTIONS.
USE FULL PROTECTION AGAINST AIRBORNE FIBERS. AVOID AIRBORNE DUST
CREATION
Supplemental Safety and Health
GENERIC "MSDS" CREATED FOR "NSN" IDENTIFIED BY "DISC" AS CONTAINING
ASBESTOS.WHEN A MANUFACTURER'S SPECIFIC "MSDS" IS PROVIDED FOR
MATERIAL PROCURED UNDER THIS NSN, THIS GENERIC "MSDS" WILL BE
REMOVED.
* Product Identification *
Preparer's Name:DOD HMIS/DGSC-SSH
* Composition/Information on Ingredients *
Ingred Name:ASBESTOS, CHRYSOTILE
OSHA PEL:0.2 FIBERS/CC
Ingred Name:ASBESTOS & NATURAL/SYNTHETIC RUBBER COMPOSITION
Ingred Name:GENERIC "MSDS". SPECIFIC ASBESTOS TYPE NOT KNOWN. ONE
CITED IS ASSUMED. INFORMATION BASED ON SEGMENT "M" OF "DLSC TIR"
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: NO ACUTE EFFECTS ARE KNOWN;
CHRONIC: DUST FROM ABRASIVE ACTIONS(EG. CUTTING, MACHINING,
FILING, ETC.) MAYCONTAIN ASBESTOS FIBERS. CHRONIC OVEREXPOSURE
TO AIRBORNE FIBERS MAY LEAD TO ASBESTOSIS & MESOTHELIOMA.
SMOKINGCOMBINED W/FIBER INHALATION GREATLY INCREASES LUNG
CANCER RISK!
Explanation of Carcinogenicity:OVEREXPOSURE TO AIRBORNE CONCENTRATIONS
OF ASBESTOS MAY LEAD TO ASBESTOSIS AND MESOTHELIOMA.
Effects of Overexposure:INHAL: INHALATION OF AIRBORNE DUST CONTAINING
ASBESTOS FIBERS ON REPEATED EXPOSURE MAY CAUSE OR CAN LEAD TO
ASBESTOSIS/ MESOTHELIOMA; SKIN: N/K; EYE: POTENTIAL IRRITATION
FROM AIRBORNE DUST; INGEST: N/K.
Medical Cond Aggravated by Exposure:RESPIRATORY DEFICIENCIES DUE TO
REPEATED INHALATION OF AIRBORNE FIBERS.
* First Aid Measures *
First Aid:INHAL: REMOVE TO FRESH AIR. OBTAIN MEDICAL ADVICE; SKIN:
WASH EXPOSED AREA WITH SOAP & WATER; EYE: FLOOD W/ WATER. IF
IRRITATION OCCURS, GET MEDICAL ATTN; INGEST: CONSULT A
PHYSICIAN; OTHER: CHANGE CLOTHING AS REQUIRED TO AVOIDCARRYING
DUST PARTICLES INTO OTHER AREAS
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:MATERIAL IS NOT FLAMMABLE ; USE MEDIA APPROPRIATE
FOR SURROUNDING FIRE.
Fire Fighting Procedures:COMBUSTION PRODUCTS OF THIS MATERIAL MAY BE
TOXIC. USE A SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRES
INVOLVING CHEMICAL PRODUCTS.
Unusual Fire/Explosion Hazard:NONE KNOWN
* Accidental Release Measures *
Spill Release Procedures:USE PROPER PERSONAL PROTECTION. VACUUM OR WET
CLEAN IF DUST IS INVOLVED. ANY VACUUM SYSTEM SHOULD BE EQUIPPED W/
AN OUTLET "HEPA" FILTER TO PREVENT REINTRODUCING ASBESTOS FIBERS TO
THE ATMOSPHERE.
*Handling and Storage *
Handling and Storage Precautions:HANDLE IN A MATTER TO MINIMIZE
FORMATION OR RETENTION OF AIRBORNE DUST. USE PROPER PERSONAL
PROTECTION FOR TASK AT HAND. CHECK W/YOUR SAFETY OFFICE!!!
Other Precautions:AS MANUFACTURED, LOCKED-IN ASBESTOS DOES NOT PRESENT
A HAZARD. ONLY WHEN THE ITEM IS SUBJECTED TO ABRASIVE ACTIONS &
DUST IS GENERATED, THEN ASBESTOS FIBERS MAY BE RELEASED & BECOME
AIRBORNE.
* Physical/Chemical Properties *
HCC:T6
Evaporation Rate & Reference:NONE
Solubility in Water:NOT SOLUBLE
Appearance and Odor:MANUFACTURED COMMODITY DESCRIBED BY LOGISTICS:
"ITEM-NAME"
Percent Volatiles by Volume:NONE
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN
Stability Condition to Avoid:NONE KNOWN
* Disposal Considerations *
Waste Disposal Methods:DUST SHOULD BE HANDLED AS A HAZARDOUS AIR
LANDFILLS APPROVED FOR ASBESTOS DISPOSAL. NOTE IF ITEM UNDER
CONSIDERATION FOR DISPOSAL IS "FRIABLE OR NON-FRIABLE".
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NOT REQUIRED UNDER NORMAL PRODUCT USAGE.
Ventilation:NOT REQUIRED UNDER NORMAL PRODUCT USAGE.
Work Hygienic Practices:GOOD PERSONAL HYGIENE SHOULD BE PRACTICED.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:PREPARED PLATED SELECTIVE MEDIA
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:THIS PRODUCT CONTAINS NO HAZARDOUS
MATERIALS AS DEFINED BY OSHA HAZARD COMMUNICATION STANDARD.
INDIVIDUALS W/KNOWN/SUSPECTED ALLERGIES SHOULD ADVISE PHYSICIAN OF
INCIDENT THAT MAY HAVE RESULTED IN EXP OSURE TO ANTIBIOTIC TREATED
MEDIA.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:THIS PRODUCT CONTAINS NO HAZARDOUS MATERIALS AS
DEFINED BY THE OSHA HAZARD COMMUNICATION STANDARD. INDIVIDUALS
W/KNOWN/SUSPECTED ALLERGIES SHOULD ADVISE PHYSICIAN OF INCIDENT
THAT MAY HAVE RESULTED IN EXPOSURE TO ANTIBIOTIC TREATED MEDIA.
Medical Cond Aggravated by Exposure:INDIVIDUALS W/ALLERGIC CONDITIONS.
* First Aid Measures *
First Aid:OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Extinguishing Media:WATERSPRAY
Fire Fighting Procedures:IF PRODUCT BECOMES INVOLVED IN A FIRE
SITUATION EXTINGUISHING MEDIA FOR SURROUNDING MATERIAL SHOULD BE
APPROPRIATE.
Unusual Fire/Explosion Hazard:PRODUCT WILL NOT BURN.
* Accidental Release Measures *
Spill Release Procedures:USE PAPER TOWELS TO PICK UP GELLED MATERIAL.
WASH AREA W/SOAP & WATER AFTER CLEANUP IS COMPLETED.
*Handling and Storage *
Handling and Storage Precautions:DIRECTIONS FOR USE SHOULD BE READ &
FOLLOWED CAREFULLY.
Other Precautions:1/K
* Physical/Chemical Properties *
Appearance and Odor:GELLED MEDIA OF VARYING COLORS
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
* Disposal Considerations *
Waste Disposal Methods:OBSERVE ASEPTIC TECHNIQUES & ESTABLISH
PRECAUTIONS AGAINST MICROBIOLOGICAL HAZARDS. AFTER USE, PREPARED
PLATES & OTHER CONTAMINATED MATERIALS MUST BE STERILIZED BY
AUTOCLAVING. DISPOSE OF IAW/LOCAL, S TATE & FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
Control Measures
*
*
Contractor Summary
*
*
Ingredients
*
< Wt: .1
OSHA PEL: 1 MG/M3
ACGIH TLV: 1 MG/M3
ACGIH STEL: NOT ESTABLISHED
------------------------------
% low Wt: 2.
ACGIH STEL: NOT ESTABLISHED
------------------------------
% low Wt: 1.
% high Wt: 7.
-----------------------------
% low Wt: 4.
OSHA PEL: 1 MG/M3
ACGIH TLV: 0.5 MG/M3
ACGIH STEL: NOT ESTABLISHED
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
------------------------------
% low Wt: 0.
ACGIH STEL: NOT ESTABLISHED
------------------------------
< Wt: .4
OSHA PEL: C5 MG/M3
ACGIH TLV: 5 MG/M3
ACGIH STEL: NOT ESTABLISHED
------------------------------
% Wt: BALANCE
OSHA PEL: 1 MG/M3
ACGIH TLV: 1 MG/M3
------------------------------
% low Wt: 8.
ACGIH TLV: 5 MG/M3
ACGIH STEL: NOT ESTABLISHED
*
Health Hazards Data
*
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE: HIGH CONCENTRATIONS INHALATION OF METALLIC FUMES
& DUSTS MAY BE IRRITATING TO THE EYES, NOSE, & THROAT. EXCESSIVE
INHALATION OF METAL FUMES FROM METAL OXIDES INCLUDING COPPER ZINC &
MANGANESE C AN PRODUCE AN ACUTE REACTION KNOWN AS "METAL FUME FEVER".
CHRONIC: EXTENDED EXPOSURE TO EXCESSIVE CONCENTRATIONS OF METAL FUMES &
DUSTS CAN BE ASSOCIATED WITH PERMANENT CHANGES IN THE LUNG FUNCTION &
PULMONARY DISEASES. SENSITIZATION REACTIONS CAN OCCUR TO SOME ELEMENTS &
COMPOUNDS. SYSTEMIC HEALTH EFFECT POTENTIALS ARE NOTED WITH THE SPECIFIC
ELEMENTS.
Explanation Of Carcinogenicity: THIS PRODUCT, AS A MIXTURE OF ALLOYING
ELEMENTS, HAS NOT BEEN DETERMINED TO BE CARCINOGENIC. HOWEVER, SOME FORMS OF
CHROMIUM, NICKEL, AND IRON HAVE BEEN ASSOCIATED WITH HUMAN CARCINOGENICITY.
Signs And Symptions Of Overexposure: SYMPTOMS CONSIST OF CHILLS AND FEVER
SIMILAR TO FLU SYMPTOMS, A METALLIC TASTE, AND DRYNESS AND IRRITATION OF THE
THROAT. SYMPTOMS MAY APPEAR SEVERAL HOURS AFTER INITIAL EXPOSURES.
Medical Cond Aggravated By Exposure: EXPOSURES TO METAL FUMES & DUSTS MAY
AGGRAVATE EXISTING DISORDERS OF THE RESPIRATORY SYSTEM. INDIVIDUALS WITH
PRE-EXISTING SKIN PROBLEMS OR SENSITIZATIONS MAY BE ADVERSELY AFFECTED.
First Aid: INHALATION: FOR OVEREXPOSURES TO METAL FUMES AND GASES, REMOVE TO
FRESH AIR. IF BREATHING IS DIFFICULT OR HAS STOPPED, ADMINISTER ARTIFICIAL
RESPIRATION AS NECESSARY. SEEK MEDICAL ATTENTION. EYE CONTA CT: FLUSH WELL
WITH RUNNING WATER TO REMOVE PARTICULATE. GET MEDICAL ATTENTION. SKIN
CONTACT: BRUSH OFF EXCESS DUST. WASH AREA THOROUGHLY WITH SOAP AND WATER.
INGESTION: SEEK MEDICAL ATTENTION.
*
Handling and Disposal
*
Spill Release Procedures: PRECAUTIONS ARE NOT NECESSARY FOR SOLID CASTINGS. IF
LARGE QUANTITIES OF DUST ARE SPILLED, COLLECT THE MATERIAL IN LABELED
CONTAINERS AND DISPOSE OF ACCORDING TO LOCAL, STATE, AND FEDERAL GUIDELINES.
RESIDUES SHOULD BE EVALUATED ACCORDING TO THE TOXIC CHARACTERISTIC LEACHING
PROCEDURE. DO NOT USE COMPRESSED AIR FOR CLEANUP. WEAR PROTECTIVE CLOTHING
AND RESPIRATORS.
Waste Disposal Methods: PRECAUTIONS ARE NOT NECESSARY FOR SOLID CASTINGS. IF
LARGE QUANTITIES OF DUST ARE SPILLED, COLLECT THE MATERIAL IN LABELED
CONTAINERS AND DISPOSE OF ACCORDING TO LOCAL, STATE, AND FEDERAL GUIDELINES.
RESIDUES SHOULD BE EVALUATED ACCORDING TO THE TOXIC CHARACTERISTIC LEACHING
PROCEDURE. DO NOT USE CO MPRESSED AIR FOR CLEANUP.
Handling And Storage Precautions: USE GOOD HOUSEKEEPING PRACTICES TO PREVENT
ACCUMULATIONS OF DUST AND TO KEEP AIRBORNE DUST CONCENTRATIONS AT A MINIMUM.
AVOID BREATHING DUST AND FUMES. STORE MATERIAL AWAY FROM INCOMPATIBLE
MATERIALS, AND KEEP DUST AWAY FROM SOURCES OF IGNITION.
*
Fire and Explosion Hazard Information
*
Flash Point Text: NA/SOLID FORM
Lower Limits: NA
Upper Limits: NA
Extinguishing Media: USE SPECIAL MIXTURES OF DRY CHEMICAL, OR SAND. DO NOT USE
WATER.
Fire Fighting Procedures: FIRE FIGHTERS SHOULD WEAR SELF-CONTAINED BREATHING
APPARATUS AND PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard: SOLID, MASSIVE FORM OF MATERIAL IS NOT
COMBUSTIBLE. FIRE AND EXPLOSION HAZARDS ARE MODERATE WHEN MATERIAL IS IN THE
FORM OF DUST AND EXPOSED TO HEAT OR FLAMES, OR BY CHEMICAL REACTION.
*
*
Respiratory Protection: WHEN MECHANICAL CONTROLS ARE NOT SUFFICIENT TO REDUCE
EXPOSURE, USE MSHA OR NIOSH APPROVED RESPIRATORS. SELECT FILTERS AND
CARTRIDGES APPROVED FOR PROTECTION AGAINST "DUST OR FUMES"," DUST, FUMES, MIS
TS AND RADIONUCLIDES", OR AIR-SUPPLIED SYSTEMS APPROPRIATE TO PROVIDE THE
NECESSARY DEGREE OF PROTECTION FOR THE EXPOSURE.
Ventilation: USE GENERAL & LOCAL MECHANICAL EXHAUST VENTILATION TO KEEP
AIRBORNE CONCENTRATIONS OF GASES, DUST & FUMES BELOW THE ACCEPTABLE
EXPOSURE LIMITS.
GENERATING DUST.
Other Protective Equipment: PROTECT SKIN & EYES FROM INTENSE ULTRAVIOLET,
INFRARED & VISIBLE LIGHT GENERATED DURING WELDING & CUTTING. PROTECTIVE
CLOTHING SHOULD BE WORN TO PROTECT SKIN AGAINST IRRITATION.
Work Hygienic Practices: SHOWERING IS RECOMMENDED BEFORE CHANGING INTO STREET
CLOTHES.
Supplemental Safety and Health: CONSULT WITH A HEALTH AND SAFETY PROFESSIONAL
FOR PROPER RESPIRATOR SELECTION. ASSIGN REPIRATORS ONLY TO PROPERLY TRAINED
*
Physical/Chemical Properties
*
HCC: N1
Spec Gravity: 7.7-9.2
Solubility in Water: INSOLUBLE
Appearance and Odor: DEPENDENT ON METAL, TYPE OF FINISH AND ANY COATINGS.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: MASSIVE MATERIAL IS STABLE AT ORDINARY
TEMPERATURES. FINELY DIVIDED DUSTS PRESENT FIRE AND EXPLOSION HAZARDS.
Materials To Avoid: MATERIAL MAY BE INCOMPATIBLE WITH ACIDS, GASES, AND
OXIDIZERS. MOLTEN METAL REACTS VIOLENTLY WITH WATER. STORE AWAY FROM
OXIDIZERS, CAN RACT VIOLENTLY.
*
Toxicological Information
*
Toxicological Information: CHROMIUM METAL: OSHA-NO, NTP-YES, IARC-3, TARGET
ORGANS-LUNG. CR (VI): OSHA-NO, NTP-YES, IARC-1, TARGET ORGAN-LUNG. IRON
OXIDE: OSHA-NO, NTP-NO, IARC-3, TARGET ORGAN-LUNG. NICKEL: OSHA-NO, NTP-YES,
IA RC-1, TARGET ORGAN-LUNG, NASAL. YES-LISTED AS HUMAN CARCINOGEN. NO-NOT
LISTED AS HUMAN CARCINOGEN. IARC CLASSIFICATION: 1-POSITIVE; 2-PROBABLE;
3-NOT CLASSIFIED; 4-PROBABLY NEGATIVE.
*
Regulatory Information
*
ONE OR MORE OF THE FOLLOWING TOXIC CHEMICALS WHICH ARE SUBJECT TO THE
LISTED BELOW ARE PRESENT AT A CONCENTRATION NOT EXCEEDING THE UPER BOUND
VALUE): ALUMINUM, CHROMIUM, COBALT, COPPER, MANGANESE, MO LYBDENUM, NICKEL,
IRON. ELEMENTAL PERCENTAGE VARY FROM EACH CASTING. SOME ELEMENTS MAY NOT BE
PRESENT IN ALL CASTINGS.
*
Other Information
*
Other Information: GENERAL: PRODUCTS DO NOT PRESENT AN INHALATION, INGESTION OR
SKIN CONTACT HEALTH HAZARD UNDER NORMAL HANDLING & USE. HOWEVER,
PROCESSES SUCH AS WELDING, GRINDING, BURNING, MELTING OR OTHERWISE GENERAT
ING DUST, FUMES, & GASES MAY PRESENT A HEALTH HAZARD. THE AIRBORNE
EXPOSURE LEVELS GIVEN IN THE HAZARDOUS INGREDIENTS SECTION ARE RELEVANT TO
PROCESSES GENERATING FUMES & DUSTS, & NOT TO THE SOLID CAS TING. THE
FOLLOWING TOXICITY INFORMATION IS APPLICABLE ONLY TO THE PROCESSING OF THE
PRODUCT.
*
Transportation Information
*
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: CY
Type Of Container: CYLINDER
*
Detail DOT Information
*
DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
Detail IMO Information
*
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
*
Detail IATA Information
*
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
Detail AFI Information
*
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
HAZCOM Label
*
Company Name: PCC AIRFOILS, INC
Label Required IND: Y
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: NONE
Respiratory Protection IND: YES
Health Hazard: None
Contact Hazard: None
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: HIGH CONCENTRATIONS INHALATION OF METALLIC FUMES
& DUSTS MAY BE IRRITATING TO THE EYES, NOSE, & THROAT. EXCESSIVE
INHALATION OF METAL FUMES FROM METAL OXIDES INCLUDING COPPER ZINC &
MANGANESE C AN PRODUCE AN ACUTE REACTION KNOWN AS "METAL FUME FEVER".
CHRONIC: EXTENDED EXPOSURE TO EXCESSIVE CONCENTRATIONS OF METAL FUMES &
DUSTS CAN BE ASSOCIATED WITH PERMANENT CHANGES IN THE LUNG FUNCTION &
PULMONARY DISEASES. SENSITIZATION REACTIONS CAN OCCUR TO SOME ELEMENTS &
COMPOUNDS. SYSTEMIC HEALTH EFFECT POTENTIALS ARE NOTED WITH THE SPECIFIC
ELEMENTS.
*
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF VENT IS INADEQ, USE NIOSH APPRVD RESP THAT
WILL PROT AGAINST DUST/MIST. CURRENTLY NO HLTH STDS EXIST FOR
REC STD FOR FIBROUS GLAS S BE APPLIED TO OTHER MAN-MADE (ING 9)
Ventilation:NO SPECIAL CONTROLS NECESSARY. LOCAL EXHAUST VENTILATION
MAY BE NECESSARY FOR SOME OPERATIONS.
Other Protective Equipment:ANSI APPRVD EYE WASH FOUNTAIN & DELUGE
SHOWER. LONG SLEEVE-GARMENTS W/TIGHT-FITTING CUFFS & USE OF
BARRIER(SUPDAT)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO:HIGH & ULTRA-HIGH MODULUS FIBER. OTHER PROT
EQUIP:CREAMS/TALCUM PROVIDE ADDNL PROT TO SKIN. EXPLO HAZ:FIBERS
ARE ELECTRONICALLY CONDUCTIVE & MAY CAUSE SHORT CIRCUITS WHICH RSL
T IN DMG TO/MALFUNCTIONING ELEC EQUIP. ALL FORMS OF ELEC EQUIP,
ENCLOSURES & CIRCUITS IN/NEAR AREAS WHERE FIBERS (ING 2)
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:CARBON; (CARBON FIBER, PITCH BASED)
ACGIH TLV:2 MG/M3 TDUST
Ingred Name:SUPDAT:ARE USED/HNDLD SHOULD BE PROPERLY PROTECTED AGAINST
INFILTRATION OF/CONT W/AIRBORNE PARTICLES/FILAMENTS.
Ingred Name:EFTS OF OVEREXP:INVOLVING CHRONIC APPLICATION OF PITCH
BASED FIBERS SUSPENDED IN BENZENE TO SKIN OF MICE PRDCD (ING 4)
Ingred Name:ING 3:WEAK LOC TUMORIGENIC RESPONSE. BENZENE EXTRACT OF
PITCH BASED CARBON FIBER CAUSED IN VITRO (TEST TUBE) (ING 5)
Ingred Name:ING 4:GENETIC EFTS.
Ingred Name:WASTE DISP METH:MEETS CRITERIA FOR BEING TOX, CORR,
7)
Ingred Name:ING 6:SUBPART C). THIS MATL COULD ALSO BECOME HAZ WASTE IF
IT IS MIXED WITH/COMES INTO CONT W/LISTED HAZ WASTE. (ING 8)
Ingred Name:RESP PROT:FIBERS. NIOSH REC EXPOS LIM OF 3 FIBERS/CC FOR
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:THIS PROD HAS BEEN EVAL & DOES NOT REQ
ANY HAZ WARNING ON LBL UNDER OSHA CRITERIA. HNDLG &/OR PROCESSING
OF THIS MATL MAY GENERATE AIRBORNE FIBERS & PARTICLES WHICH CAN
CAUSE MECH IRRIT OF EYES, SKIN, NOSE & THROAT. EYE/SKIN CONT:NO
SIGNIFICANT HLTH HAZS IDENTIFIED. PARTICLES/FIBERS MAY CAUSE SLIGHT
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:DISCOMFORT SIMILAR TO GETTING DUST IN
EYE/RUBBING SAND AGAINST SKIN. INHAL:NO SIGNIFICANT IRRIT EXPECTED
OTHER THAN POSS MECH IRRIT. INGEST:NO SIGNIFICANT HLTH HAZS
IDENTIFIED. TOX INFO:DENSEDUST GENERATED BY HNDLG &/OR PROCESSING
OF THIS MATL MAY BE IRRIT TO EYES, SKIN, NOSE & THROAT. STUDIES
(ING 3)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
MEDICAL ATTENTION IF IRRITATION PERSISTS. SKIN:WASH EXPOSED SKIN
W/SOAP & WATER. INHAL:REMOVE TO UNCONTAMINATED AREA. GET MEDICAL
ATTENTION. I NGEST:IF LARGE AMOUNT IS SWALLOWED, GETMEDICAL
ATTENTION.
* Fire Fighting Measures *
Extinguishing Media:AGENTS APPROVED FOR CLASS A HAZARDS (E.G., FOAM,
STEAM) OR WATER FOG.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:FIBER, DUST & FIBROUS PARTICLES ARE
ELECTRICALLY CONDUCTIVE & CAN CAUSE SHORTING IN ELEC EQUIP. EXPLO
SHORTING OF HIGH VOLTAGE SYSTEMS IS POSS. CARBON (SUPDAT)
* Accidental Release Measures *
Spill Release Procedures:CONTAIN & REMOVE BY MECHANICAL MEANS. VACUUM
OR SWEEP OUT; AVOID PRODUCING DUST.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:MINIMIZE DUST GENERATION &
ACCUMULATION. NO SPECIAL STORAGE REQUIREMENTS.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
* Physical/Chemical Properties *
Solubility in Water:NEGLIGIBLE; <0.1%.
Appearance and Odor:BLACK CARBON FIBER, FABRIC OR CLOTH.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE IDENTIFIED.
Stability Condition to Avoid:AVOID GENERATING DUST.
Hazardous Decomposition Products:NONE IDENTIFIED.
* Disposal Considerations *
Waste Disposal Methods:DISP MUST BE I/A/W APPLIC FED, STATE/LOC REGS.
DO NOT INCIN. BURIAL AT PERMITTED LANDFILL IS REC. RCRA:THIS UNUSED
MATL, WHEN DISCARDED/DISP OF, IS NOT SPECIFICALLY LISTED AS HAZ
WASTE IN FED REGS; HO WEVER, IT COULD BE CONSIDERED HAZ IF IT(ING
6)
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IN INADEQUATELY VENTILATED AREAS, NIOSH/MSHA
APPROVED (TC-9C) SUPPLIED AIR RESPIRATOR OR SELF-CONTAINED
BREATHING APPARATUS IS REQUIRED.
Ventilation:USE W/ADEQ VENT. CHECK AIR FOR CONTAMINANT & FOR OXYGEN
Other Protective Equipment:PROTECT ALL EXPOSED SKIN AND LIQUID CONTACT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ: RELEASING IRRIT, TOX & CORR GASES. CNTNR MAY EXPLODE IF
HEATED DUE TO RSLTG PRESS RISE. SOME MIXS OF HCFCS &/OR HFCS &
AIR/OXYGEN MAY BE COMBUST IF PRESSURIZED & EXPOS TO EXTREME
HEAT/FLAME . CNDTNS TO AVOID: LIGHTS, STATIC ELECTRICITY,
COMBUSTION ENGINES, IGNITION SOURCES, ETC.
* Product Identification *
CAGE:0STM5
* Composition/Information on Ingredients *
Ingred Name:ETHANE, 1,1-DICHLORO-1-FLUORO-;
OSHA PEL:N/K
ACGIH TLV:N/K
Ozone Depleting Chemical:2
Ingred Name:MATL TO AVOID: SUCH AS ALUMINUM, MAGNESIUM/ZINC & STRONG
OXIDIZERS SINCE THEY MAY REACT W/OR ACCELERATE DECOMP OF MATL.
Ingred Name:HAZ DECOMP PRODS: DIOXIDE AND CHLORINE.
Ingred Name:EFTS OF OVEREXP:IN RAPID HEARTBEAT (TACHYCARDIA), IRREGULAR
HEARTBEAT (CARD ARRHY) & DEPRESS OF CARD FUNC. EXPOS (ING 5)
MATERNAL TOX W/ACCOMPANYING REDUCTION IN LITTER SIZE & (ING 6)
Ingred Name:ING 5:PUP WT. NO EVID OF BIRTH DEFECTS. SIMILAR MATERNAL
TOX WAS NOTED IN PREGNANT RABBIT BUT NOT ADVERSE EFT ON (ING 7)
Ingred Name:ING 6: FETAL DEVELOPMENT. IN VITRO CHROMOSOME ABERRATION
Ingred Name:ING 7: MICRONUCLEUS ASSAY WAS NEG AT EXPOS LEVELS UP TO
Ingred Name:ING 8: FOR 1 YR CAUSED MINOR REDUCTIONS IN BODY WT GAIN &
Ingred Name:ING 9: BENIGN TESTICULAR TUMORS HAVE BEEN SEEN IN RATS
Ingred Name:SPILL PROC: COLLECT REMAINDER OF SPILL W/ABSORB MATL &
Ingred Name:VENT: DESIGNED FOR FLAMMABLE GAS ATMOSPHERES TO REMOVE
VAPORS.
FROM COLD.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:CHLOROFLUOROCARBON (CFC) MATLS HAVE
PRDCED SENSIT OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD
HAVE SIMILAR EFT IN HUMANS. ADRENOMIMETICS (IE, EPINEPHRINE) MAY BE
CONTRA-INDICATED EXCEPT FOR LI FE-SUSTAINING USES IN HUMANS
ACUTELY/CHRONICALLY EXPOS TO CFCS . EYE: VAP & LIQ ARE IRRIT. SKIN:
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: CNTCT W/LIQ MAY CAUSE DRYING. CHEM IS
NOT IRRIT/SENSITIZER. TARGET ORGAN: CNS, RESP SYS, HEART. TOX
COMMENTS:DENSE VAP DISPLACES BRTHG AIR IN CONFINED/NONVENT AREAS.
INHAL CONC VAPS CAN CAUS E DROW, UNCON, HDCH, RESP DEPRESS & DEATH
DUE TO ASPHY. ALSO INCRS SENSITIVITY OF HEART TO ADRENALIN, POSS
RSLTG (ING 4)
Medical Cond Aggravated by Exposure:PERSONS WITH PREEXISTING HEART
DISEASE MAY BE AT INCREASED RISK FROM EXPOSURE.
* First Aid Measures *
First Aid:INGEST: DO NOT INDUCE VOMIT. GIVE WATER TO DRINK. GET MED
ATTN. NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. SKIN:
FLUSH AREA W/PLENTY OF WATER. REMOVE CONTAMD CLTHG. WASH CLTHG
BEFORE REUSE. G ET MED ATTN. EYES: IMMED FLUSH W/PLENTYOF CLEAN
AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN.
GET MED ATTN.
* Fire Fighting Measures *
Flash Point Method:TCC
Flash Point:NONE
Lower Limits:7.4%
Extinguishing Media:USE WATER SPRAY OR FOG, CARBON DIOXIDE, DRY
CHEMICAL OR WATER STREAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
AND FULL PROTECTIVE EQUIPMENT . KEEP CONTAINERS COOL.
Unusual Fire/Explosion Hazard:THERMAL DECOMP PRODS MAY INCL FLUORIDES,
CHLORIDES & PHOSGENE . MAY DECOMPOSE DURING CNTCT W/FLAMES, HEATING
ELEMENTS OR IN COMBUST ENGINES (SUPDAT)
* Accidental Release Measures *
Spill Release Procedures:REMOVE/EXTING IGNIT/COMBUST SOURCES. EVACUATE
ENCLSD SPACES UNTIL GAS IS DISPERSED. KEEP UPWIND. STOP LEAK IF
POSS W/OUT RISK. DISPERSE GAS W/FLOOR LEVEL FORCED-AIR VENT. EXHST
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:DO NOT GET IN EYES, ON SKIN/CLTHG. DO
NOT BREATHE VAP, MIST/GAS. KEEP CNTNR CLSD. KEEP AWAY FROM HEAT,
SPK & FLAMES. STORE IN TIGHTLY CLSD CNTNRS.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN GEN VICIN OF
ARC WELDING/OPEN FLAMES/HOT SURFS. HEAT &/OR UV RADIA MAY CAUSE
FORM OF CHLORIDES/FLUORIDES/PHOSGENE . EMPTY CNTNR MAY CNTN HAZ
* Physical/Chemical Properties *
Vapor Density:4.0
Solubility in Water:SLIGHT
Appearance and Odor:CLEAR, COLORLESS, LIQUID AND GAS WITH FAINT
ETHEREAL (ETHER-LIKE) ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ALKALIS, STRONG OXIDIZERS. AVOID CNTCT W/STRONG ALKALI/ALKALINE
EARTH METALS, FINELY POWDERED METALS (ING 2)
Stability Condition to Avoid:THERMAL DECOMP DUE TO EXPOS TO HEAT
ELEMENTS, PILOT (SUPDAT)
Hazardous Decomposition Products:PHOSGENE . THERMAL DECOMP PRODS INCL
HYDROGEN FLUORIDE, HYDROGEN CHLORIDE, CARBON MONOXIDE, CARBON (ING
3)
* Disposal Considerations *
Waste Disposal Methods:RECYCLE OR RECLAIM IF POSSIBLE. RECLAIMED
MATERIAL MAY BE INCINERATED BUT TOXIC & CORROSIVE COMBUSTIBLE
PRODUCTS (HP & HCL) MUST BE HANDLED APPROPRIATELY. CONSULT FEDERAL,
STATE AND LOCAL AUTHORITIES FOR PROPER DISPOSAL PROCEDURES.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Ventilation:ADEQUATE
Supplemental Safety and Health
* Product Identification *
Product ID:ODORLESS OVER&GRILL CLEANER
* Composition/Information on Ingredients *
Ingred Name:"NO HAZARDOUS INGREDIENTS"
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Effects of Overexposure:CHAPPING AND OR IRRITATION.
* First Aid Measures *
First Aid:IF MATERIAL IS SWALLOWED,DRINK LARGE AMOUNTS OF WATER,INDUCE
VOMITING,FOLLOW WITH RAW EGG WHITES OR VEGETABLE OIL.IF SPLASHED
INTO EYES,FLUSH WITH WATER AND FOLLOW WITH A BORIC ACID
SOLUTION.CALL A PH YSICIAN.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:NON-FLAMMABLE
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:NORMAL CLEAN-UP WITH MOP AS FOR ANY WATER
BASED CLEANER-FOR SAFE AND EFFICIENT WORKING CONDITIONS.
*Handling and Storage *
Handling and Storage Precautions:SAME AS FOR ANY ALKALINE LIQUID
DETERGENT.
* Physical/Chemical Properties *
Vapor Density:1
Evaporation Rate & Reference:<1
Solubility in Water:COMPLETE PH
Appearance and Odor:STRAW COLOR-LIQUID.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Hazardous Decomposition Products:NONE
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR FOR DUST OR
FUME IF CONCENTRATIONS EXCEED TLV OR PEL.
Ventilation:PROVIDE GENERAL VENTILATION AND/OR LOCAL EXHAUST IF
NECESSARY TO MAINTAIN CONCENTRATIONS BELOW TLV OR PEL.
Other Protective Equipment:WEAR PROT APRONS & GAUNTLETS IF ARC-AIR
DBA, (SUPDAT)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
BP: VARIABLE DEPENDING ON CASTING GRADE. EYE PROT: &/OR FACESHIELDS FOR
PROT EQUIP: HEARING PROT REQD. EXPLAN OF CARCIN:HUMAN/ANIMAL: LU NG
CANCER, SKIN.CHROMIUM (VI): IARC MONOGRAPHS ON EVAL OF CARCIN RISK
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:CHROMIUM (SARA III)
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:CHROMIUM (VI) CERTAIN SOLUBLE FORMS
Ingred Name:COBALT (SARA III)
Ingred Name:COPPER (SARA III) (AS DUST) (AS FUME)
OSHA PEL:0.1MG/M3 FUME;1 DUST
ACGIH TLV:0.2 MG/M3 FUME
Ingred Name:IRON (AS FUME)
Fraction by Wt: 1.0%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:MANGANESE (SARA III) (AS DUST) (AS FUME)
OSHA PEL:5 MG/M3, C
ACGIH TLV:5 MG/M3, DUST
Ingred Name:NICKEL (SARA III)
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
Ingred Name:SILICON
Ingred Name:TANTALUM
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3; DUST
Ingred Name:TUNGSTEN
Fraction by Wt: 7.0%
OSHA PEL:N/K
ACGIH TLV:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
BE CARCINOGEN. HUMAN: LUNGS, NASAL CAVITIES.
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:EFTS OF OVEREXP: WELDING FUME IS CONTROLLED. (THE ALLOY AND
ITS DUST DOES NOT CONTAIN INSOLUBLE HEXAVALENT CHROMIUM.)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:OTHER PREC: CHROMIUM AND NICKEL DUST & FUME. WELDING/FLAME
OSHA PEL:N/K
ACGIH TLV:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:THERE ARE NO CHEM HAZS FROM THESE
CASTINGS IN SOLID FORM AT ROOM TEMP. EYES: METAL PARTICLES IN EYES
MAY CAUSE IRRIT IF NOT REMOVED. SKIN: NONE KNOWN. INHAL: BRTHG HIGH
CONCS OF CHROMIUM &/OR NICKEL D UST OR FUME MAY CAUSE LUNG IRRIT.
SOME FORMS OF METALS MAY CAUSE CANCER; REFER TO ING SECTION. HIGH
(EFTS OF OVEREXP)
CARCIN(SUPDAT)
Effects of Overexposure:HLTH HAZS: EXPOS TO COPPER FUMES MAY CAUSE
METAL FUME FEVER, WHICH RESEMBLES FLU. INGEST: NONE KNOWN. WATER
INSOLUBLE HEXAVALENT CHROMIUM IS CLASSIFIED AS HUMAN CARCIN. APPROX
OFTHAT IS INSOLUBLE. OVEREXP TO HEXAVALENT CHROMIUM IS NOT LIKELY
Medical Cond Aggravated by Exposure:NICKEL DERMATITIS, IN INDIVIDUALS
WITH KNOWN NICKEL SENSITIZATION, MAY OCCUR.
* First Aid Measures *
First Aid:EYES: METAL PARTICLES SHOULD BE REMOVED BY TRAINED
INDIVIDUALS SUCH AS NURSE OR PHYSICIAN. IF DISCOMFORT OR IRRITATION
PERSISTS, OBTAIN MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND WATER.
INHALATION: ( FUMES FROM WELDING) MOVE TO FRESH AIR. INGESTION: IF
LARGE AMOUNTS INGESTED, OBTAIN MEDICAL ATTENTION.
* Fire Fighting Measures *
Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE CONDITIONS
.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:CASTINGS WILL NOT BURN OR EXPLODE.
* Accidental Release Measures *
Spill Release Procedures:IF DAMAGED, RETURN CASTINGS TO VENDOR OR SEND
TO SCRAP RECLAIMER. COLLECTED DUST FROM MACHINING, WELDING, ETC.,
MAY BE CLASSED AS "HAZARDOUS WASTE" DEPENDING ON CIRCUMSTANCES.
CONSULT LOCAL AUTHORITIE S REGARDING DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:BECAUSE OF POTENTIAL HAZARD FROM METAL
DUST AND FUMES, MACHINING, GRINDING, WELDING OPERATIONS ETC. SHOULD
BE DONE UNDER LOCAL EXHAUST VENTILATION.
Other Precautions:IF VENT IS NOT ADEQ, WEAR NIOSH/MSHA APPRVD DUST/FUME
RESP. MACHINING, GRINDING, FLAME CUTTING, OR WELDING ON CASTINGS
WILL CREATE AIR CONTAMS. SINCE CASTING CONTAINS MOSTLY CHROMIUM
* Physical/Chemical Properties *
Boiling Pt:B.P. Text:SUPP DATA
Spec Gravity:8.9 (ING 7)
Appearance and Odor:SOLID, SILVER GRAY IN COLOR, NO ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
CHROMIUM METAL DUST MAY BURN OR EXPLODE WHEN IN CONTACT WITH AMMONIUM
NITRATE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS .
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* Exposure Controls/Personal Protection *
Respiratory Protection:NOT REQUIRED
Ventilation:NOT REQUIRED
Other Protective Equipment:EYEWASH EQUIPMENT
Work Hygienic Practices:WASH HANDS AFTER HANDLING.
Supplemental Safety and Health
* Product Identification *
Kit Part:Y
Preparer's Name:M SEINO
* Composition/Information on Ingredients *
Ingred Name:SILICON DIOXIDE, CRYSTALLINE QUARTZ, SAND (ANIMAL CARC,
OSHA PEL:0.1 MG/CUM RESP DUST
ACGIH TLV:0.1 MG/CUM RESP DUST
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:SKIN/EYES: MAY CAUSE SLIGHT
IRRITATION.
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:IRRITATION
* First Aid Measures *
First Aid:SKIN: REMOVE PASTE W/DRY CLOTH/TOWEL & WASH W/DETERGENT.
DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL AREAS.
* Fire Fighting Measures *
Flash Point Method:OC
Extinguishing Media:FOAM, DRY CHEMCIAL/CO2
Fire Fighting Procedures:NOT REQUIRED
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:CONTAIN. SCRAPE UP W/CARDBOARD/RAG & PLACE IN
CONTAINER. IN SUCH A CASE, PAY ATTENTION TO GENERATION OF HYDROGEN
GAS BY CONTAMINANTS.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE.
VENT CONTAINER PROPERLY TO ELIMINATE INTERNAL PRESSURE. STORE IN A
COOL PLACE & AWAY FROM IGNITION SOURCES.
Other Precautions:DON'T LAY CONTAINER ON IT'S SIDE. AVOID CONTACT
W/ACIDIC, BASIC & OXIDIZING MATERIALS. AVOID CONTACT W/EYES &
PROLONGED/REPEATED SKIN CONTACT.
* Physical/Chemical Properties *
Vapor Pres:NEGLIGIBLE
Spec Gravity:1.4
Evaporation Rate & Reference:(BU AC=1): NEGLIGIBLE
Solubility in Water:INSOLUBLE
Appearance and Odor:GRAYISH WHITE PASTE W/NO ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:NO
ACIDIC, BASIC & OXIDIZING MATERIALS
Stability Condition to Avoid:HEAT, FLAME & OTHER IGNITION SOURCES
Hazardous Decomposition Products:FLAMMABLE HYDROGEN GAS
* Disposal Considerations *
Waste Disposal Methods:WASTE CAN BE BURNED/DISPOSED OF IN ACCORDANCE
W/LOCAL, STATE & FEDERAL REGULATIONS.
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* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH APPROVED RESPIRATOR.
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DO NOT GET IN
EYES, ON SKIN, OR ON CLOTHING.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:TRIS(HYDROXYMETHYL)AMINOMETHANE
Ingred Name:HYDROCHLORIC ACID
OSHA PEL:C7 MG/M3;C5 PPM
ACGIH STEL:C7.5 MG/M3;C5 PPM
Ingred Name:ETHYLENEDIAMINETETRAACETIC ACID
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION: MAY BE HARMFUL. EYE
CONTACT: MAY CAUSE IRRITATION. SKIN CONTACT: MAY CAUSE IRRITATION.
INGESTION: MAY BE HARMFUL. ADDITIONAL INFORMATION: THE PRODUCT
SHOULD BE HANDLED WITH NORMAL C AUTION ACCORDED CHEMICALS.
ADDITIONAL HARMFUL PROPERTIES CANNOT BE RULED OUT.CHEMICAL
TRIS(HYDROXYMETHYL)AMINOMETHANE/HYDROCHLORIC ACID, 1 MM ETHYLENEDIA
MINETETRAACETIC ACID, PH 8.0.
* First Aid Measures *
First Aid:EYE CONT: IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR
EYELIDS WITH FINGERS. SKIN CONT: IMMEDIATELY WASH WITH SOAP AND
COPIOU S AMOUNTS OF WATER. INHAL: REMOVE TO FRESH AIR. IF NOT
BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT,
GIVE OXYGEN. INGEST: WASH OUT MOUTH WITH WATER PROVIDED PERSON IS
CONSCIOUS.
* Fire Fighting Measures *
Extinguishing Media:NONCOMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE
TO SURROUNDING FIRE CONDITIONS.
Fire Fighting Procedures:USE NIOSH APRPOVED SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT TO PREVENT CONTACT WITH
SKIN AND EYES.
* Accidental Release Measures *
Spill Release Procedures:PRECAUTIONARY MEASURES: WEAR NIOSH APPRVD
OR VERMICULITE AND PLAC E IN CLOSED CONTAINERS FOR DISPOSAL.
VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS
COMPLETE.
*Handling and Storage *
PRODUCT SHOULD BE HANDLED WITH THE NORMAL CAUTION ACCORDED
CHEMICALS. ADDITIONAL HARMFUL PROPERTIES CANNOT BE RULED OUT.
A MIX WHICH CNTNS <1% BY WT/VOLUME OF NON-CARCINOGENIC HAZ
COMPONENT IS NOT CONSIDERED HAZARDOUS, UNLESS THERE IS EVID TO
CONTRARY. WE DO NOT CONSI DER BUFFER TE TO BE HAZ, HOWEVER, WE REC
CHEM REAGENTS.
* Physical/Chemical Properties *
pH:8.0
Solubility in Water:SOLUBLE
Appearance and Odor:COLORLESS LIQUID. NO ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Hazardous Decomposition Products:TOXIC FUMES OF CARBON MONOXIDE AND
CARBON DIOXIDE.
* Disposal Considerations *
Waste Disposal Methods:FOR SMALL QUANTITIES FLUSH DOWN SINK WITH WATER.
OBSERVE ALL FEDERAL, STATE, AND LOCAL LAWS.
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* Exposure Controls/Personal Protection *
Respiratory Protection:ENSURE VENTILATION CONTROLS, VAPOR EXHAUST, OR
Ventilation:GENERAL DILUTION OR LOCAL EXHAUST VENTILATION IN VOLUME AND
PATTERNED TO KEEP INGREDIENTS BELOW SUGGESTED LIMITS IN THIS MSDS.
Other Protective Equipment:CLEAN OR DISCARD CONTAMINATED CLOTHING AND
SHOES.
Supplemental Safety and Health
* Product Identification *
Product ID:ENAMEL, NONFLAMING (DRY) CHLORINATED ALKYD SEMI-GLOSS
* Composition/Information on Ingredients *
Ingred Name:BARIUM METABORATE
Other REC Limits:5 MG/M3
OSHA PEL:TOTAL DUST
ACGIH TLV:TOTAL DUST
Ingred Name:TITANIUM DIOXIDE
OSHA PEL:TOTAL DUST
ACGIH TLV:TOTAL DUST
Ingred Name:ZINC PHOSPHATE
Other REC Limits:NONE RECOMMENDED
Ingred Name:POLYMER BASE CHLOROENDIC ALKYLOID
Code:F
RESIN SOLUTION
Code:F
Ingred Name:PAINT THINNER
Fraction by Wt: 9.0%
Ingred Name:DRIERS
Fraction by Wt: 3.0%
Ingred Name:LEVELING AGENT
Code:F
Ingred Name:ANTISKINNING AGENT
Fraction by Wt: 1.0%
Ingred Name:THIXATROPIC AGENT
Code:F
* Hazards Identification *
Health Hazards Acute and Chronic:ACUTE: EYES: SEVERE IRRITATION. SKIN:
PRIMARY IRRITATION. HARMFUL IF ABSORBED THRU SKIN.
PROLONGED/REPEATED CONTACT: ALLERGIC SKIN REACTION. INHAL: HARMFUL
IF INHALED. IRRITATES EYES/NOSE/THROAT & LU NGS. HIGH VAPOR
CONCENTRATIONS MAY CAUSE IRRITATION OF RESPIRATORY SYSTEM &
PERMANENT BRAIN/NERVOUS SYSTEM DAMAGE. INTENTIONAL MIUSE CAN BE
HARMFUL OR FATAL. CHRONIC: AVOID LONG TERM/REPEATED CONTACT .
Explanation of Carcinogenicity:SEE TOXICOLOGICAL SECTION FOR DETAILS
Effects of Overexposure:EYE WATERING, HEADACHES, NAUSEA, DIZZINESS,
LOSS OF COORDINATION ARE INDICATIONS THAT SOLVENT LEVELS ARE TOO
HIGH. REDNESS/ITCHING/BURNING SENSATION/VISUAL DISTURBANCES MAY
INDICATE EXCESSIVE EYE CONT ACT. DRINESS/ITCHING/CRACKING/BURNING
REDNESS/SWELLING: EXCESSIVE SKIN CONTACT.
* First Aid Measures *
First Aid:IF SWALLOWED: GIVE 1 OR 2 GLASSES OF WATER. DO NOT INDUCE
VOMITING. KEEP PERSON WARM, QUIET, AND GET IMMED MEDICAL ATTEN.
EYE. CALL DR IMMED. SKIN: FLUSH W/COPIOUS AMOUNTS OF WATER, THEN
FOLLOW W/ SOAP & WATER. CALL DR. INHALATION: REMOVE TO FRESH AIR.
APPLYSUPPORTIVE MEASURES AS REQUIRED. OTHER: IF INGEST: ANY TYPE
OF OVEREXPO SURE/SYMPTOMS OF OVEREXPOSURE OCCUR DURING/FOLLOWING
USE OF PRODUCT, CONTACT POISON CONTROL CENTER, EMERENCY ROOM, OR
PHYSICIAN IMMED. HAVE MSDS INFO AVAILABLE.
* Fire Fighting Measures *
Flash Point Method:TCC
Autoignition Temp:Autoignition Temp Text:NA
Extinguishing Media:USE NATIONAL FIRE PROTECTION ASSOCIATION (NFPA)
CLASS B EXTINGUISHERS (FOAM, CO2, DRY CHEMICAL) DESIGNED TO
EXTINGUISH NFPA CLASS IC FLAMMABLE LIQUID FIRE.
Fire Fighting Procedures:WATER SPRAY MAY BE INEFFECTIVE. WATER SPRAY
MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD UP
AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME
HEAT. IF WATER IS USED, FO G NOZZLES ARE PREFERABLE. FIRE FIGHTERS
WEAR SCBA.
Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE
FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS, OPEN FLAMES. CLOSED
CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. DO NOT APPLY
ON HOT SURFACES. TOXIC GASES MAY FORM WHEN PRODUCT IS CONTACTED BY
FLAME OR HOT SURFACES.
* Accidental Release Measures *
Spill Release Procedures:PROVIDE MAXIMUM VENTILATION. ONLY PERSONEL
AREA. REMOVE ALL SOURCES OF IGNITION. PICK UP SPILLED MATERIAL
W/SAWDUST, VERMICULITE, OR OT HER ABSORBENT & PLACE INTO CONTAINERS
FOR DISPOSAL.
*Handling and Storage *
QUANTITIES IN BUILDING DESIGNED AND PROTECTED FOR STORAGE OF NFPA
CLASS IC FLAMMABLE LIQUIDS.
Other Precautions:IF THIS MATERIAL IS PART OF A MULTIPLE COMPONENT
SYSTEM, READ THE MATERIAL SAFETY DATA SHEET FOR THE OTHER
COMPONENT(S) BEFOER BLENDING, AS THE RESULTING MIXTURE MAY HAVE THE
HAZARDS OF ALL OF ITS PAR TS. CONTAINERS SHOULD BE GROUNDED WHEN
POURED. AVOID FREE FALL OF LIQUIDS IN EXCESS OF FEW INCHES.
* Physical/Chemical Properties *
Melt/Freeze Pt:M.P/F.P Text:NA
Vapor Density:4.9 AIR =1
pH:NA
VOC Grams/Liter:2.8
Corrosion Rate:NA
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ALKALIES, STRONG MINERAL ACIDS, OR STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products:MAY PRODUCE HAZ DECOMP PRODUCTS WHEN
HEATED. WELDING, BRAZING, OR FLAME CUTTING MAY PRODUCE FUMES,
INCLUDING CABON MONOXIDE, HYDROGEN CHLORIDE GAS.
* Toxicological Information*
Toxicological Information:AVOID LONG TERM AND REPEATED CONTACT. THIS
PRODUCT CONTAINS TITANIUM DIOXIDE. ANIMALS INHALING MASSIVE
QUANTITIES OF TITANIUM DIOXIDE DUST IN A LONG TERM STUDY DEVELOPED
LUNG TUMORS. STUDIES W/ HUMANS INVOLVED W/ MANUFACTURE OF THIS
PIGMENT INDICATE NO INCREASED RISK OF CANCER FROM EXPOSURE.
POTENTIAL FOR INHALATION OF TITANIUM DIOXIDE DUSTS FROM COATINGS IS
VERY LIMITED. SINCE OVEREXPOSURES ARE N OT EXPECTED, THERE ARE NO
SIGNIFICANT HAZARD FOR MAN. *CONTINUED UNDER ECOLOGICAL SECTION
* Ecological Information *
Ecological:THIS PRODUCT CONTAINS A LOW LEVEL OF FORMALDEHYDE ON THE
BASIS OF LONG TERM EXPOSURE OF ANIMALS TO HIGH LEVELS NTP, IARC,
AND OSHA ASSOCIATE FORMALDEHYDE WITH AN INCREASED RISK OF CANCER.
RECENT STUDI ES WITH HUMANS SHOW NO CORRELATION BETWEEN EXPOSURE TO
FORMALDEHYDE AND INCREASED CANCER RISK.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE IN ACCORDANCE W/LOCAL, STATE, FEDERAL
REGULATIONS. EMPTY CONTAINERS SHOULD BE RECYCLED OR DISPOSED OF
THROUGH APPROVED WASTE MANAGEMENT FACILITY.
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* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR WITH ORGANIC
VAPOR CARTRIDGE WHEN HANDLING BULK. NONE NECESSARY UNDER NORMAL USE
CONDITIONS.
Ventilation:MECHANICAL VENTILATION.
Other Protective Equipment:NONE REQUIRED. EMERGENCY EYEWASH & DELUGE
SHOWER MEETING ANSI DESIGN CRITERIA .
Work Hygienic Practices:STANDARD GOOD INDUSTRIAL HYGIENE PRACTICE
RECOMMENDED.
Supplemental Safety and Health
* Product Identification *
CAGE:WTEPR
* Composition/Information on Ingredients *
Ingred Name:MINERAL SPIRITS; (PETROLEUM NAPHTHA)
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: SKIN: MAY INDUCE SKIN
IRRITATION IN SENSITIVE INDIVIDUALS. EYES: IRRITATION. INHALATION:
NOT HAZARDOUS UNDER NORMAL USE CONDITIONS.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:CENTRAL NERVOUS SYSTEM DEPRESSION. DELIBERATELY
CONCENTRATING AND INHALING THE CONTENTS CAN LEAD TO UNCONSCIOUSNESS
AND/OR DEATH.
Medical Cond Aggravated by Exposure:EXISTING PULMONARY OR DERMAL
* First Aid Measures *
First Aid:SKIN: WASH WITH SOAP AND WATER. CONSULT MD IF IRRITATION
MINUTES. CONSULT MD IF IRRITATION OCCURS. INGESTION: CONSULT MD AT
ONCE. DO NOT IND UCE VOMITING. INHALATION: REMOVE VICTIMFROM
EXPOSURE. ALERT EMERGENCY MEDICAL PERSONNEL. ADMINISTER ARTIFICIAL
RESPIRATION IF BREATHING IS STOPPED.
* Fire Fighting Measures *
Flash Point Method:SCC
Lower Limits:1.2%-1.9%
Extinguishing Media:USE CARBON DIOXIDE, FOAM, DRY CHEMICAL.
Fire Fighting Procedures:FLAMMABLE LIQUID. WEAR NIOSH/MSHA APPROVED
SCBA & FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:TOXIC COMBUSTION GAS MAY BE FORMED AS
DECOMPOSITION PRODUCTS.
* Accidental Release Measures *
Spill Release Procedures:HANDLE AS FLAMMABLE LIQUID AND DISPOSE OF
PROPERLY. VENTILATE AREA.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE AND TRANSPORT IN CLOSED
CONTAINER. STORE IN VENTILATED AREA. AVOID HEAT, FIRE AND FUMES.
Other Precautions:KEEP AWAY FROM CHILDREN.
SOL IN H*2O: PRACTICALLY INSOLUBLE (0.5-0.8 G/L).
* Physical/Chemical Properties *
Vapor Density:3.4
Evaporation Rate & Reference:1.1-1.5 (BUTYL ACETATE=1)
Solubility in Water:SUP DAT
Appearance and Odor:FREE FLOWING LIQUID, WITH PETROLEUM SOLVENT ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING OR REDUCING AGENTS.
Stability Condition to Avoid:HEAT SOURCE, SPARKS OR FLAME.
Hazardous Decomposition Products:TOXIC FUMES OR GASES.
* Disposal Considerations *
Waste Disposal Methods:IN ACCORDANCE WITH STATE OR FEDERAL GUIDELINES.
DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS .
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:ANY DUST & MIST RESPIRATOR. ANY AIR-PURIFYING
RESPIRATOR WITH HIGH-EFFICIENCY PARTICULATE FILTER. ANY POWDER
AIR-PURIFYING RESPIRATOR WITH A DUST & MIST FILTER. ANY
SELF-CONTAINED BREATHING APPARATUS.
Ventilation:PROVIDE LOCAL EXHAUST VENTILATION SYSTEM.
Other Protective Equipment:MUST WEAR APPRPIATE PROTECTIVE CLOTHING &
EQUIPMENT TO PREVENT REPEATED OR PROLONGED SKIN CONTACT WITH THIS
SUBSTANCE.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EMERGENCY EYE WASH: WHERE THERE IS ANY POSSIBILITY THAT AN EMPLOYEE'S
EYES MAY BE EXPOSED TO THIS SUBSTANCE, THE EMPLOYER SHOULD PROVIDE
AN EYE WASH FOUNTAIN WITHIN THE IMMEDIATE WORK AREA FOR EMERGEN CY
USE.
* Product Identification *
Product ID:BORIC ACID
* Composition/Information on Ingredients *
Ingred Name:BORIC ACID
Other REC Limits:NONE NORMALLY REQUI.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION-IRRITATION OF THE
MUCOUS MEMBRANES & MAY BE ABSORBED TO CAUSE SYSTEMIC POISONING.
SKIN-RRITATION. EYE-NONIRRITATING. CHRONIC: POISONING,
HALLUCINATIONS OF VISION, KIDNEY DAMAGE, SKIN RASH, ALOPECIA,
CONVULSION & ANEMIA.
Explanation of Carcinogenicity:NOT CARCINOGENIC.
Effects of Overexposure:INHALATION-FEVER, ANURIA. INGESTION-MAY CAUSE
NAUSEA, EPIGASTRIC PAIN, HEMORRHAGIC GASTRITIS, BLOODY VOMIT &
DIARRHEA, WEAKNESS, LETHARGY, HEADACHE, RESTLESSNESS, TREMORS &
TWITCHING OF FACIAL MUSCLES AND EXTREMITIES, INTERMITTENT
CONVULSION, & EVENTUAL CENTRAL NERVOUS SYSTEM DEPRESSION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHALATION-REMOVE FROM EXPOSURE AREA TO FRESH AIR
IMMEDIATELY. PERFORM CPR IF NEEDED. GET MEDICAL AID. SKIN-REMOVE
SOILED CLOTHING/SHOES IMMEDIATELY. WASH WITH SOAP & MILD DETERGENT
& WATER. GET MEDIC AL AID. EYE-WASH EYES WITH LARGE AMOUNTS OF
WATER/NORMAL SALINE. GET MEDICAL AID. INGESTION-MAINTAIN
RESPIRATION. REMOVE BY IPECAC EMESIS FOLLOWED BY ACTIVATED
CHARCOAL, GASTRIC LAVAGE, TREAT ANURIA.
* Fire Fighting Measures *
Extinguishing Media:EXTINGUISH USING AGENT SUITABLE FOR TYPR OF
SURROUNDING FIRES.
Fire Fighting Procedures:NO ACUTE HAZARDS. MOVE CONTAINERS FROM FIRE
AREA IF POSSIBLE. AVOID BREATHING VAPORS; KEEP UPWIND.
Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO
HEAT OR FLAME.
* Accidental Release Measures *
Spill Release Procedures:SWEEP UP AND PLACE IN SUITABLE CLEAN, DRY
CONTAINER FOR RECLAMATION OR LATER DISPOSAL. DO NOT FLUSH SPILLED
MATERIAL INTO SEWER. KEEP UNNECESSARY PEOPLE AWAY.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLE
SUBSTANCES.
Other Precautions:NO OCCUPATIONAL EXPOSURE LIMITS ESTABLISHED BY OSHA,
ACGIG OR NIOSH.
* Physical/Chemical Properties *
HCC:N1
Melt/Freeze Pt:M.P/F.P Text:DECOMPOSES
Vapor Pres:2.6 MMHG
pH:5.1
Appearance and Odor:ODORLESS, COLORLESS, TRANSPARENT CRYSTALS OR WHITE
GRANULES OR POWDER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ACETIC ANHYDRIDE, POTASSIUM, & IRON.
Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND
PRESSURE.
Hazardous Decomposition Products:THE SUBSTANCE GRADUALLY LOSES WATER,
FORMING METABORIC ACID, THEN PYROBORIC ACID & FINALLY BORIC
ANHYDRIDE.
* Disposal Considerations *
Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS
WHEN STORING OR DISPOSING OF THIS SUBSTANCE.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:CONCENTRAION-IN-AIR DETERMINES PROTECTION
NEEDED. USE ONLY NIOSH/MSHA APPROVED RESPIRATORY PROTECTION.
RESPIRATORY PROTECTION USUALLY NOT NEEDED UNLESS PRODUCT IS HEATED
OR MISTED.
Ventilation:VENTIALATE AS NEEDED TO COMPLY WITH EXPOSURE LIMIT.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
* Product Identification *
Product ID:SUNOCO MULTI-PURPOSE 2EP
* Composition/Information on Ingredients *
Ingred Name:POLYBUTENYL SUCCINIMIDE/AMIDE
Fraction by Wt: <1%
Fraction by Wt: <1%
Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-DEWAXED HEAVY
PARAFFINIC;(MINERAL OILS)
Ingred Name:ZINC DIAMYLDITHIOCARBAMATE
Ingred Name:SULFURIZED ISOBUTYLENE
Ingred Name:ASPHALT (PETROLEUM)
Fraction by Wt: <1%
Ingred Name:ZINC DIALKYL DITHIOPHOSPHATE
Fraction by Wt: <1%
Ingred Name:CHLORINATED PARAFFINS
Fraction by Wt: <1%
Ingred Name:ALKENE CARBOXYLATE
Fraction by Wt: <1%
Ingred Name:BORIC ACID/ALKANOAMINE COMPLES.
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN:MILD IRRITATION WITH PROLONGED OR
REPEATED CONTACT. EYE:MAY CAUSE MILD IRRITATION. INGEST/INHAL:NO
EFFECTS EXPECTED.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHAL:REMOVE TO FRESH AIR. SKIN:WASH WITH SOAP AND WATER
UNTIL NO ODOR REMAINS. IF REDNESS OR SWELLING DEVELOPS, GET MD.
MINUTES. IF IR RITATION PERSISTS, GET MD. INGEST:DO NOT INDUCE
VOMITING. DO NOT GIVE LIQUIDS. GET MD. SMALL AMOUNTS WHICH
ACCIDENTALLY ENTER MOUTH SHOULD BE RINSED OUT UNTIL TASTE OF IT IS
GONE.
* Fire Fighting Measures *
Extinguishing Media:WATER FOG, MECHANICAL FOAM, DRY CHEMICAL POWDER,
CARBON DIOXIDE, SAND/DIRT.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:CAN BE MADE TO BURN (FLASH POINT GREATER
* Accidental Release Measures *
Spill Release Procedures:ABSORB ON INERT MATERIAL. SHOVEL, SWEEP OR
VACUUM SPILL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:NFPA CLASS IIIB STORAGE.
Other Precautions:WASH THOROUGHLY AFTER HANDLING.
* Physical/Chemical Properties *
HCC:V6
Evaporation Rate & Reference:SEE SUPP DATA
Solubility in Water:NIL
Appearance and Odor:SEMI-SOLID GREASE. BLAND COLOR.
Percent Volatiles by Volume:NIL
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:COMBUSTION WILL PRODUCE CARBON
MONOXIDE, ASPHYXIANTS AND FUMES OF LITHIUM OXIDE.
* Disposal Considerations *
Waste Disposal Methods:FOLLOW FEDERAL, STATE AND LOCAL REGULATIONS. DO
NOT FLUSH TO DRAIN/STORM SEWER. CONTRACT TO AUTHORIZED DISPOSAL
SERVICE.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL EXHAUST IS PREFERRED TO KEEP VAPOR OR DUST BELOW THE
TLV VALUE. MECHANICAL AREAWIDE VENTILATION IS ACCEPTABLE.
Other Protective Equipment:SAFETY SHOWER & EYE BATH.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
HAZ DECOMP PROD:CARBON DIOXIDE, CARBON MONOXIDE, WATER VAPOR, OXIDES OF
NITROGEN OR A WIDE VARIETY OF INNOCUOUS OR TOXIC FUMES. WASTE DISP
METH:THIS PRODUCT WOULD NOT BE CLASSIFIED AS A HAZARDOUS WAST E
UNDER U.S FEDERAL REGULATIONS IN EFFECT AT THE TIME THIS MSDS WAS
CREATED.
* Product Identification *
Product ID:TILEMATE FLOORS GRAY
Preparer's Name:R. SONTAG
* Composition/Information on Ingredients *
Ingred Name:SILICATE, PORTLAND CEMENT; (PORTLAND CEMENT)
Ingred Name:SILICA
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:FORMIC ACID,CALCIUM SALT (CALCIUM FORMATE)
Other REC Limits:NONE RECOMMENDED
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:BENZENESULFONE ACID,4,4'-OXYBIS-,DIHYDRAZIDE
Other REC Limits:NONE RECOMMENDED
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SULFITE LIQUORS AND COOKING LIQUORS,SPENT,ALKALI TREATED
Other REC Limits:NONE RECOMMENDED
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS: EYES, RESPIRATORY
SYSTEM, SKIN & LUNGS. INHAL:HAZARDOUS IF INHALED. INGRED HAS AN
PEL. EYE/SKIN CONTACT: INGRED CAUSE S EYE &/OR SKIN IRRITATION. NO
ABSORPTION HAZARD KNOWN AT THIS TIME. INGEST:NO HAZARD KNOWN AT
THIS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:TIME. SYMPTOMS OF OVEREXPOSURE MAY
INCLUDE IRRITATION, MUCOUS MEMBRANE IRRITATION, COUGHING & POSSIBLE
CHEMICAL BURN. CHRONIC: LONG TERM OVEREXPOSURE TO THE HAZARDOUS
MATERIALS IN THIS PRODUC T HAVE BEEN ASSOCIATED W/DERMATITIS &
CUMULATIVE LUNG DAMAGE.
Medical Cond Aggravated by Exposure:DERMATITIS.
* First Aid Measures *
First Aid:INHAL:REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION, PREFERABLY MOUTH TO MOUTH. IF BREATHING IS DIFFICULT,
GIVE OXYGEN. CALL MD. EYES:IMMEDIATELY FLUSH W/PLENTY OF WATER FOR
CALL MD . INGEST:CALL MD IMMEDIATELY .
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:WATER SPRAY, FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE KNOWN TO BOSTIK.
* Accidental Release Measures *
Spill Release Procedures:SWEEP UP MATERIAL USING SWEEPING COMPOUND &
PACKAGE THE SOLID PRODUCT IN STEEL DRUMS WHICH ARE IN GOOD
CONDITION. THOROUGHLY CLEAN AREA WHERE SPILL OCCURRED.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
FROM SUNLIGHT & ANY SOURCE OF HEAT. KEEP CONTAINER TIGHTLY CLOSED
WHEN NOT BEING USED.
Other Precautions:USE W/ADEQUATE VENTILATION. AVOID PROLONGED OR
REPEATED BREATHING OF VAPORS. AVOID SKIN CONTACT.
* Physical/Chemical Properties *
HCC:V7
Solubility in Water:0.1%
Appearance and Odor:A COLORED CAULK W/LITTLE ODOR.
Percent Volatiles by Volume:0.0
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:UNKNOWN DUE TO COMPLEX NATURE OF THIS
MATL. FUMES FROM COMPLETE/INCOMPLETE COMBUST OF THIS MATL MAY INCL
(SUPP DATA)
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF I/A/W FED, STATE & LOCAL RULES. BE
AWARE THAT STATE & LOCAL REQUIREMENTS MAY DIFFER WIDELY DEPENDING
ON LOCATION & MAY IN MANY CASES BE DIFFERENT FROM FED RULES. WHEN
INTENDING TO DISPOSE O F THIS MATL, THE USER IS ADVISED THAT (SUP
DAT)
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:ADEQUATE VENTILATION IS USUALLY ADEQUATE.
Ventilation:MECHANICAL-ACCEPTABLE
Supplemental Safety and Health
* Product Identification *
Product ID:O.V. CLEANER
* Composition/Information on Ingredients *
Ingred Name:SODIUM HYDROXIDE (SARA III)
Fraction by Wt: 9%
OSHA PEL:2 MG/M3
Ingred Name:SODIUM METASILICATE
Fraction by Wt: 3%
* Hazards Identification *
Effects of Overexposure:POSSIBLE IRRITATION OR BURNS TO SKIN & EYES ON
CONTACT.
* First Aid Measures *
CONTAMINATED AREAS OF BODY W/SOAP & WATER. FOR INGESTION, GIVE
CITRUS DRINK OR VINEGAR W/LG AMTS OF WATER.GIVE MEDICAL ATTENTION.
* Fire Fighting Measures *
Flash Point:NONE
* Accidental Release Measures *
Spill Release Procedures:HOSE AREA WITH WATER
* Physical/Chemical Properties *
HCC:B1
Solubility in Water:COMPLETE
Appearance and Odor:CREAMY-WHITE SOFT PAST-NO ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
* Disposal Considerations *
Waste Disposal Methods:SUMP TANK OR RINSE DOWN, DRAIN W/ PLENTY OF
WATER.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Other Protective Equipment:PROTECTIVE CLOTHING, SAFETY SHOWER & EYE
BATH.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF INGESTED, INHALED/ABSORBED
THROUGH SKIN. IRRITATING TO EYES/MUCOUS MEMBRANES & UPPER
RESPIRATORY TRACT. SKIN: IRRITATION. REPRODUCTIVE DISORDERS.
INGESTION: PULMONARY EDEMA/HYPOCALCEMIC TET ANY & SEVERE METABOLIC
DEVELOP BRAIN & LIVER DAMAGE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, NERVOUS SYSTEM DISTURBANCES,
NAUSEA, HEADACHE, VOMITING, ALCOHOL INEBRIATION, ABDOMINAL PAIN,
WEAKNESS, MUSCLE TENDERNESS, RESPIRATORY FAILURE, CONVULSIONS,
CARDIOVASCULAR COLLAPSE, RENAL FAILURE.
* First Aid Measures *
INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED.
INGESTION: WASH OUT MOUTH W/WATER IF CONSCIOUS. OBTAIN MEDICAL
ATTENTION IN ALL CAS ES.
* Fire Fighting Measures *
Lower Limits:3.2
Extinguishing Media:WATER SPRAY, CO2, DRY CHEMICAL/APPROPRIATE FOAM.
Fire Fighting Procedures:WEAR SCBA & PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
* Accidental Release Measures *
PLACE IN CLOSED CONTAINERS FOR DISPOSAL. VENTILATE AREA & WASH SITE
AFTER MATERIAL PICKUP IS COMPLETE.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL DRY PLACE. KEEP
TIGHTLY CLOSED.
Other Precautions:AVOID CONTACT W/EYES, SKIN/CLOTHING. DON'T BREATHE
VAPORS. HYGROSCOPIC. REPRODUCTIVE HAZARD.
* Physical/Chemical Properties *
Boiling Pt:B.P. Text:(SEE SUPP)
Melt/Freeze Pt:M.P/F.P Text:8.6F
Vapor Density:2.1
Appearance and Odor:VISCOUS COLORLESS LIQUID
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG BASES.
Stability Condition to Avoid:MOISTURE.
Hazardous Decomposition Products:COMBUSTION: CO, CO2.
* Disposal Considerations *
Waste Disposal Methods:DISSOLVE/MIX W/A COMBUSTIBLE SOLVENT & BURN IN A
CHEMICAL INCINERATOR EQUIPPED W/AN AFTERBURNER & SCRUBBER,
IAW/FEDERAL, STATE & LOCAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF EXPOSURE EXCEEDS TLV USE A NIOSH APPROVED
RESPIRATOR TO PREVENT OVEREXPOSURE.
Ventilation:REQUIRED
Other Protective Equipment:EYE WASH FOUNTAINS & SAFETY SHOWERS,
SYNTHETIC APRON.
Work Hygienic Practices:REMOVE CONTAMINATED CLOTHING & SHOES, DON'T
REUSE UNTIL THOROUGHLY DECONTAMINATED.
Supplemental Safety and Health
WASH W/SOAP & WATER BEFORE EATING, DRINKING, SMOKING/USING TOILET
FACILITIES. HLTH HZRD-INGESTION: MAY CAUSE RED BLOOD CELL
HEMOLYSIS, KIDNEY & LIVER DAMAGE. LIQUID ASPIRATED INTO THE LUNGS
DURING ING ESTION/VOMITING MAY RESULT IN SEVERE LUNG DAMAGE. GI
TRACT IRRITATION. SPILLS: SOAK UP RESIDUE W/ABSORBENT & DISPOSE OF.
* Product Identification *
* Composition/Information on Ingredients *
Fraction by Wt: 1-5%
Ingred Name:PROPYLENE GLYCOL METHYL ETHER (1-METHOXY-2-PROPANOL)
Ingred Name:DIACETONE ALCOHOL
Ingred Name:COLUMBIA CARBON, CARBON BLACK, LAMPBLACK, BLACK PEARLS
Other REC Limits:3.5 MG/CUM (NIOSH)
OSHA PEL:3.5 MG/CUM
ACGIH TLV:3.5 MG/CUM
Fraction by Wt: 1-5%
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: IRRITATING, CORNEAL INJURY.
SKIN: MODERATELY IRRITATING, MAY CAUSE DAMAGE, ABSORPTION &
DERMATITIS.INHALATION: IRRITATION TO NOSE, THROAT, RESPIRATORY
TRACT & MUCOUS MEMBRANES, CNS DEPRESSION, L EAD POISONING, SEVERE
DAMAGE TO THE BLOOD-FORMING, NERVOUS, URINARY, REPRODUCTIVE SYSTEMS
& DAMAGE TO LUNGS. (SEE SUPP)
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, DEFATTING, DRYNESS, HEADACHE,
DIZZINESS, NAUSEA, INTOXICATION, UNCONSCIOUSNESS, LOSS OF APPETITE,
METALLIC TASTE IN THE MOUTH, ANXIETY, CONSTIPATION, PALLOR,
EXCESSIVE TIREDNESS, WEAKNESS, INSOMNIA, NERVOUS IRRITABILITY,
MUSCLE& JOINT PAIN, FINE TREMORS, NUMBNESS, HYPERACTIVITY, COLIC.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN, EYE,
RESPIRATORY, IMPAIRED CNS FUNCTION DISORDERS. PRE-EXISTING
SKIN/LUNG ALLERGIES.
* First Aid Measures *
W/WATER USING SOAP. INHALATION: REMOVE TO FRESH AIR & TREAT
SYMPTOMATICALLY. GIVE OXYGEN/CPR IF NEEDED. INGESTION: DON'T INDUCE
VOMITING. IF VOMITING SPONTANEOUSLY OCCURS, KEEP HEAD BELOW THE
HIPS TO PREVENT ASPIRATION INTO THE LUNGS. WHETHER/NOT TO INDUCE
VOMITING SHOULD BE MADE BY A PHYSICIAN. OBTAIN MEDICAL ATTENTION IN
ALL CASES.
* Fire Fighting Measures *
Flash Point Method:SCC
Extinguishing Media:WATER FOG, FOAM, DRY CHEMICAL/CO2.
Fire Fighting Procedures:EVACUATE AREA. DON'T ENTER CONFINED FIRE SPACE
W/O PROPER PROTECTIVE EQUIPMENT & POSITIVE PRESSURE NIOSH APPROVED
SCBA. COOL CONTAINERS W/LARGE AMOUNTS OF WATER
Unusual Fire/Explosion Hazard:FLAMMABLE. CONTAINERS EXPOSED TO INTENSE
HEAT COULD RESULT IN CONTAINER RUPTURE. VAPORS MAY ACCUMULATE &
TRAVEL TO IGNITION SOURCES DISTANT FROM HANDLING SITE.
* Accidental Release Measures *
Spill Release Procedures:LARGE: EVACUATE AREA. WEAR APPROPRIATE
RESPIRATOR & PROTECTIVE CLOTHING. SHUT OFF SOURCES OF LEAK SAFELY,
DIKE & CONTAIN. IF VAPOR CLOUD FORMS, WATER FOG MAY BE USED TO
SUPPRESS. CONTAIN RUN-OFF. REMO VE W/VACUUM TRUCKS/PUMP TO
STORAGE/SALVAGE VESSELS
*Handling and Storage *
Handling and Storage Precautions:KEEP LIQUID AWAY FROM HEAT, SPARKS,
FLAME & OTHER SOURCES OF IGNITION. KEEP CONTAINERS CLOSED WHEN NOT
IN USE. USE W/ADEQUATE VENTILATION.
Other Precautions:CONTAINERS, EVEN IF EMPTY CAN CONTAIN EXPLOSIVE
VAPORS. DON'T CUT, DRILL, GRIND/WELD NEAR CONTAINERS. INTENTIONAL
MISUSE BY DELIBERATELY CONCENTRATING & INHALING THE CONTENTS MAY BE
HARMFUL/FATAL. HOTSURFACES MAY IGNITE W/O SPARKS/FLAME.
* Physical/Chemical Properties *
Vapor Density:>1
Percent Volatiles by Volume:(SUPP)
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OXIDIZING MATERIALS.
Stability Condition to Avoid:HEAT, SPARKS, FLAME, HOT SURFACES &
SOURCES OF IGNTION.
Hazardous Decomposition Products:COMBUSTION: LEAD OXIDE FUMES, CO2, CO
& UNIDENTIFIED ORGANIC COMPOUNDS.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
| 1 | gloves_mandatory |
Control Measures
*
Proprietary Ind: Y
*
Preparer Co. when other than Responsible Party Co.
*
*
Contractor Summary
*
*
Item Description Information
*
Item Manager: S9G
Item Name: LUBRICATING OIL,AIRCRAFT TURBINE ENGINE,SYNTHETIC
Type/Grade/Class: TYPE C/I
Unit of Issue: QT
UI Container Qty: 1
*
Ingredients
*
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: BASED ON TESTING OF SIMILAR PRODUCTS &/OR
COMPONENTS:ORAL/DERMAL/INHAL TOXICITY:PRACTICALLY NON-TOXIC.EYE/SKIN
IRRIT:PRACTICALLY NON-TOXIC.UNDER NORMAL USE UNLIKELY TO PRODUCE NEUROTOXIC
EFFECTS BY DE RM/INHAL EXPO BUT MAY PRODUCE SUCH EFFECTS IF ORALLY INGESTED.
Signs And Symptions Of Overexposure: NOT EXPECTED TO PRODUCE NEUROTOXIC EFFECTS
UNDER NORMAL CONDITIONS OF USE & W/APPRP PERS HYG PRAC.CONTAINS TRICRESYL
PHOSPHATE(TCP).OVEREXPO TO TCP BY INGEST/PROL/REP INHAL PROL/REP SKIN CONTACT
MAY P RODUCE NERV SYS DISORDERS INCLUDE GI DISTRUB,NUMBNESS,MUSC
CRAMPS,WEAK,PARALYSIS.PARALYSIS MAY BE DELAYED.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYE:FLUSH WELL W/H2O.IRRIT OCCURS CALL DR.SKIN:WASH W/SOAP/H2O.DONT
WEAR ORDINARY CLOTH WET W/PROD.REMOVE CONTAM CLOTH.INHAL:REMOVE FRM EXPO.RESP
IRRIT/DIZZ/NAU/UNCONSC OCCURS GET IMMED MED ASSIST/CAL L DR.BREATH STOP USE
MOUTT-TO-MOUTH RESUSC.INGEST:GET IMMED MED ATTN;DELAYE ATTN CONTACT REG POIS
CNTR/EMERG MED PROFESS REGARDING INDUCTION OF VOMIT/USE OF ACTIVATED
CHARCOAL.DONT INDUCE VOMIT(SUPPL)
*
Handling and Disposal
*
Spill Release Procedures: REPORT AS REQUIRE TO APPROP AUTHORITIES.REPORT IMMED
COAST GUARD REGS.ADSORB ON FIRERETARDANT TREAT SAWDUST/DIATOMACEOUS EARTH
,ETC.SHOVELUP/DISPO @APPROP WASTE DISPO(OTH PREC)
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. DISPO:MATLS.USED PROD MAY
BE REG.NO SARA CHEMS.
Waste Disposal Methods: PROD SUITABLE FORBURNING IN ENCLSD CNTRL BURNER FOR
FUEL VALUE/DISPO BY SUPERVISED INCINERATION.SUCH BURNING MAY BE LIMITED
PURSUANT OT RCRA.ALSO SUITABLE FOR PROCESS BY APPROV RECYCL FAC/DISPO OF @AP
PRP GOVT WASTE DISPO FACI.METHODS SUBJ TO(OTHPREC)
Handling And Storage Precautions: DONT USE ON FOOD PRCESSING MACHINERY.STORE IN
COOL DRY WELL VENTI AREA AWAY FROM HEAT.
Other Precautions: SPILL:FACIL IAW CURRENT APPLIC LAWS/REGS/PROD CHARACT @DISPO
TIME.PREVENT SPILL FRM ENTER STORM SEWER/DRAIN/CONTACT SOIL. DISPO:UER
COMPLIANCE W/APPLIC LAWS/REGS/PROD CHARACTER @DISPO TIME.UNUSED NOT EPA HAZ
WASTE/NOT FORMULATED W/HAZ(NEUT)
*
Fire and Explosion Hazard Information
*
Flash Point Method: COC
Autoignition Temp Text: NE
Lower Limits: NA
Upper Limits: NA
Extinguishing Media: CARBON DIOXIDE, FOAM,DRY CHEMICAL,WATER FOG.
Fire Fighting Procedures: COOL FIRE-EXPO CNTNR W/H2O.USE H2OSPRAY TO FLUSH
SPILLS AWAY FRM EXPO.PREVENT RUNOFF FRM FIRE CNTRL/DIL FRM ENTER
STREAM/SEWERS/DRINKG H2O SUPPLY.WEAR SCBA.
Unusual Fire/Explosion Hazard: NONE.WATER OR FOAM MAY CAUSE FROTHING.
*
*
Respiratory Protection: APPROVED RESP PROTECTIVE EQPMT SHOULD BE USED IF
VENTILATION IS INADEQUATE & BREATHING OF MISTS/VAPORS IS LIKELY.
Ventilation: USE IN WELL VENTI AREA W/LOC EXHAU VENTILATION.
Other Protective Equipment: GOOD PERSONAL HYG PRACTICES SHOULD ALWAYS BE
FOLLOWED.
Work Hygienic Practices: WASH CONTAM CLOTH BEF REUSE.AVOID INGEST/INHAL
MIST/PROL REP SKIN CONTACT.WASH WELL BEF EAT/SMOKE.KEEP AWAY FRM FEED/FOO
Supplemental Safety and Health: 1STAID:/GIVE ANYTHING BY MOUTH IF
GROGGY/UNCONSC.DR:PROD NOT EXPECT TO PRODUCE ADVERSE EFFECTS UNDER NORM USE
CONDITIONS/APPROP PERS HYG.CONTAINS TCP-SYMPT ASSOC W/CHOLINESTERASE
INHIBITION(W/IN HRS), PRODUCES NEUROTOXICITY ASSOC W/INHIBI OF NEUROPATHY
TARGET ESTERASE(NTE)(SEVERAL DAYS).TREAT APPROPR.
*
Physical/Chemical Properties
*
HCC: V6
B.P. Text: NE
M.P/F.P Text: NA
Vapor Pres: NE
Vapor Density: NE
PH: NA
Evaporation Rate & Reference: NE
Solubility in Water: NEGLIGIBLE
Appearance and Odor: LIQUID, AMBER COLOR, MILD ODOR
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: EXTREME HEAT.
Materials To Avoid: STRONG OXIDIZERS.
Hazardous Decomposition Products: CARBON MONOXIDE.
Hazardous Polymerization Indicator: NO
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
Transportation Information
*
Net Unit Weight: 2.1 LBS
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: QT
Container QTY: 1
Additional Data: PER MSDS:DOT/RID/ADR/IMO/IATA:NOT REGULATED. CAN HERMETICALLY
SEALED.
*
Detail DOT Information
*
DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
Detail IMO Information
*
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
*
Detail IATA Information
*
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
Detail AFI Information
*
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
HAZCOM Label
*
Company Name: MOBIL OIL CORP, NORTH AMERICAS MARKETING AND REFINING
Label Required IND: Y
Status Code: C
Origination
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: CONTAINS TRICRESYL PHOSPHATE.INGEST CAN CAUSE NERV SYST
DISORDERS INCLUDE PARALYSIS.PROL/REP BREATH OF OIL MIST/PROL/REP SKIN CONTACT
CAN CAUSE NERV SYS EFFECTS.1SATAID:EYE:FLUSH WELL W/H2O.IRRIT OCCU RS CALL
DR.SKIN:WASH W/SOAP/H2O.REMOVE CONTAM CLOTH.INHAL:REMOVE FRM EXPO.RESP
IRRIT/DIZZ/NAU/UNCONSC OCCURS GET IMMED MED ASSIST/CALL DR.BREATH STOP USE
MOUTT-TO-MOUTH RESUSC.INGEST:GET IMMED MED ATT N;DELAYE ATTN CONTACT REG POIS
CNTR/EMERG MED PROFESS REGARDING INDUCTION OF VOMIT/USE OF ACTIVATED
CHARCOAL.DONT INDUCE VOMIT/GIVE ANYTHING BY MOUTH IF GROGGY/UNCONSC.TARGET
ORGANS:CNS.
*
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WHERE TLVS MAY BE EXCEEDED/IF SPRAY MIST IS
PRESENT, USE NIOSH/MSHA APPROVED RESPIRATORY PROTECTION. IN
CONFINED AREAS, USE NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATORS.
Ventilation:GENERAL DILUTION/LOCAL EXHAUST IN VOLUME & PATTERN TO KEEP
Other Protective Equipment:PROTECTIVE CLOTHING, SAFETY SHOWER, EYE BATH
& WASHING FACILITIES
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
FIRE HAZ CONT'D: VAPORS MAY TRAVEL LONG DISTANCES; FLASHBACK/FLAME TO
HANDLING SITE MAY OCCUR. VAPORS ARE >AIR & MAY COLLECT IN
LOW/CONFINED AREAS. DON'T ENTER SUCH AREAS W/OUT FOLLOWING
APPROPRIATE P ROCEDURES. PREVENT PROLONGED CONTACT W/CONTAMINATED
* Product Identification *
Kit Part:Y
Preparer's Name:SHERRIE M STEVENSON
* Composition/Information on Ingredients *
Ingred Name:SILICON DIOXIDE, CRYSTALLINE QUARTZ, SAND (ANIMAL CARC,
OSHA PEL:0.1 MG/CUM RESP DUST
ACGIH TLV:0.1 MG/CUM RESP DUST
Ingred Name:CYCLOHEXANONE, KETOHEXAMETHYLENE
Fraction by Wt: <5%
Ingred Name:NON-HAZARDOUS ADDITIVES, RESINS & PIGMENTS
Ingred Name:STRONTIUM CHROMATE (SUSPECTED HUMAN CARCINOGEN BY ACGIH,
Other REC Limits:1 UG/CUM A1
OSHA PEL:1 MG/CUM
Ingred Name:TITANIUM DIOXIDE, TIO2 (SUSPECTED ANIMAL CARCINOGEN, IARC
Fraction by Wt: <5%
Ingred Name:2-BUTANONE (METHYL ETHYL KETONE) (MEK)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION: NASAL/RESPIRATORY
IRRITANT, CNS DEPRESSION, ASPHYXIANT MAY RESULT FROM BREATHING
OXYGEN DEFICIENT AIR. SKIN: IRRITANT, DERMATITIS. EYES: IRRITANT.
INGESTION: GI IRRITANT. ASPIRATION INTO T HE LUNGS CAN CAUSE
CHEMICAL PNEUMONITIS/FATAL. OVEREXPOSURE TO SOLVENTS MAY CAUSE
PERMANENT BRAIN/NERVOUS SYSTEM DAMAGE.
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:IRRITATION, HEADACHE, DIZZINESS, STAGGERING
GAIT, CONFUSION, UNCONSCIOUSNESS, ASPHYXIATION, DEFATTING, NAUSEA,
VOMITING, DIARRHEA. OVEREXPOSURE TO SOLVENTS: CONCENTRATION
DIFFICULTIES, DIMINISHED MANU AL DEXTERITY, MEMORY LOSS
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN, LUNG & EYE
CONDITIONS.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF
NECESSARY. KEEP WARM & QUIET. SKIN: WASH W/SOAP & WATER. DON'T USE
HAZARD. OBTAIN M EDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Extinguishing Media:CO2, DRY CHEMICAL/FOAM
Fire Fighting Procedures:WATER SPRAY MAY BE INEFFECTIVE. COOL FIRE
EXPOSED CONTAINERS W/WATER. FOG NOZZLES ARE PREFERRED. WEAR
NIOSH/MSHA APPROVED SCBA & PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:VAPORS MAY ACCUMULATE IN INADEQUATELY
VENTILATED/CONFINED AREAS/FORM EXPLOSIVE MIXTURES W/AIR. CLOSED
CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT.(SUPP)
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL IGNITION SOURCES. WEAR PROTECTIVE
EQUIPMENT. USE NON-SPARKING TOOLS. SMALL: DIKE & ABSORB W/INERT
MATERIAL. DON'T CONTAMINATE GROUND/SURFACE WATER.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED & AWAY
PROCEDURES SHOULD BE USED WHEN TRANFERRING MATERIAL
Other Precautions:STORE FLAMMABLE LIQUIDS IAW/APPLICABLE NFPA CODES &
GOVERNMENTAL REGULATIONS. AVOID FREE FALL OF LIQUID. DON'T SMOKE
WHERE MATERIAL IS USED/STORED. DON'T TAKE INTERNALLY. DON'T
DELIBERATELY CONCENTRAT E/INHALE VAPORS. AVOID SKIN CONTACT.
* Physical/Chemical Properties *
Vapor Density:>1
Evaporation Rate & Reference:SLOWER THAN N-BU ACETATE
Appearance and Odor:LIQUID W/SOLVENT ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:HEAT, ELECTRICAL EQUIPMENT, SPARKS, FLAME,
HOT SURFACES & OTHER IGNITION SOURCES
Hazardous Decomposition Products:CO, CO2
* Disposal Considerations *
Waste Disposal Methods:WHEN DISPOSING OF MATERIAL, ENSURE THAT IT'S
PACKAGED, STORED, TRANSPORTED & OTHERWISE MANAGED IAW/LOCAL, STATE
& FEDERAL REGULATIONS. EMPTY DRUMS MAY CONTAIN EXPLOSIVE VAPORS.
| 1 | gloves_mandatory |
Control Measures
*
Cage: 0A4S7
*
Contractor Summary
*
Cage: 0A4S7
*
Ingredients
*
-----------------------------
OSHA PEL: 1 MG/M3
ACGIH TLV: 0.5 MG/M3
ACGIH STEL: NOT ESTABLISHED
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
------------------------------
% low Wt: 8.
Other REC Limits: TLV:0.1 MG/M3 (M)
OSHA PEL: 1 MG/M3
ACGIH TLV: 1 MG/M3
ACGIH STEL: NOT ESTABLISHED
-----------------------------
% low Wt: .5
% high Wt: 1.5
Other REC Limits: TLV:5 MG/M3 (MFR)
OSHA PEL: 5 MG/M3
ACGIH STEL: NOT ESTABLISHED
------------------------------
% low Wt: 3.3
Other REC Limits: TLV:1 MG/M3 (M)
OSHA PEL: C5 MG/M3
ACGIH TLV: 5 MG/M3
ACGIH STEL: 3 MG/M3
------------------------------
% low Wt: .3
ACGIH TLV: 0.1 MG/M3
ACGIH STEL: NOT ESTABLISHED
------------------------------
PEL:0.1 MG/M3; ACGIH TLV: 0.2 MG/M3.
OSHA PEL: 1 MG/M3
ACGIH TLV: 1 MG/M3
ACGIH STEL: NOT ESTABLISHED
------------------------------
% Wt: BALANCE
------------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: WELDING GENERATES FUMES, GASES & ELECTROMAGNETIC RADIA
W/KNOWN ADVERSE HLTH EFTS. COMPOSITION OF WELDING EMISSIONS VARIES
SUBSTANTIALLY W/WELDING PROCESS. ACUTE: SHORT TERM EXPOS TO WELDING FUME MAY
R SLT IN DISCOMFORT, DIZZ, NAUS & DRYNESS/IRRIT OF THROAT. CHRONIC: LONG
TERM EXPOS TO WELDING FUME, GASES/DUST MAY CONTRIBUTE TO PULM
IRRIT/PNEUMOCONIOSIS. LONG TERM EXPOS TO IRON FUME MAY PRDCE SIDERO SIS,
WHICH IS GENRLY REGARDED AS BENIGN. NICKEL & CHROMIUM SHOULD BE
BEEN IMPLICATED BASED ON EXPER IN SOME NICKEL REFINING OPERATIONS.
SPECIFIC(EFTS OF OVEREXP)
ANIMAL CARCIN. ANIMAL: LUNGS, NASAL CAVITIES. SILICA, CRYSTALLINE-FUSED: IARC
Signs And Symptions Of Overexposure: HLTH HAZ:CMPDS, HOWEVER, HAVE NOT BEEN
DETERMINED & DIRECT ASSOC BTWN NICKEL IN WELDING FUME & CANCER HAS
NOT BEEN DEMONSTRATED. SOME CMPDS OF HEXAVALENT CHROMIUM HAVE BEEN REPORTED
TO BE CARCINOGENIC . NO CLEAR ASSOC, HOWEVER, HAS BEEN ESTABLISHED BTWN
CHROMIUM IN WELDING FUME & DEVELOPMENT OF CANCER. EXPOS LIMITS SHOULD BE
MAINTAINED BELOW LEVELS LISTED IN INGREDIENTS SECTION. ROUTES OF ENTRY: (1 )
INHALATION OF FUME. (2) BURNS FROM ELECTROMAGNETIC RADIATION. IMPORTANT -
WELDING ELECTRODES ARE A NON-HAZARDOUS SOLID AT AMBIENT TEMPERATURES.
Medical Cond Aggravated By Exposure: INDIVIDUALS WITH IMPAIRED PULMONARY
FUNCTION OR ILLNESS MAY HAVE SYMPTOMS EXACERBATED BY IRRITANTS CONTAINED IN
WELDING FUMES.
First Aid: INHALATION: REMOVE FROM DUST OR FUME EXPOSURE. IF BREATHING HAS
STOPPED PERFORM ARTIFICIAL RESPIRATION. SUMMON MEDICAL AID IMMEDIATELY.
INGESTION: CALL MD IMMEDIATELY (FP N). SKIN: FLUSH W/COPIOUS AMO UNTS OF
WATER. CALL MD (FP N). EYES:IMMEDIATELY FLUSH W/POTABLE WATER FOR A MINIMUM
*
Handling and Disposal
*
Waste Disposal Methods: PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER OR LINER IN
AN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE WITH FEDERAL, STATE
& LOCAL REGULATIONS.
Handling And Storage Precautions: TRAIN EMPLOYEE TO KEEP HIS HEAD OUT OF FUMES
& NOT TO TOUCH LIVE ELEC PARTS & TO INSULATE HIMSELF FROM WORK &
GROUND. READ & UNDERSTAND MFR'S INSTRUCTIONS & PRECAUTIONARY LBL ON
PROD. USE EXHST SYS TO CLEAR WELDING FUMES. MAKE SURE THAT INHALED AIR DOES
NOT CONTAIN FUME CONSTITUENTS ABOVE PEL'S.
Other Precautions: NOTE:FOR OTHER PRECS/ADDNL SFTY INFO ON WELDING &
"WELDING HANDBOOK", VOL 1, CHAPTER 9, "SAFE PRACTICES IN WELDING &
*
Fire and Explosion Hazard Information
*
Flash Point Text: NONE
Lower Limits: NONE
Upper Limits: NONE
Extinguishing Media: THIS ALLOY IS NONCOMBUSTIBLE. USE EXTINGUISHING MEDIA
APPROPRIATE TO THE SURROUNDING FIRE. TO EXTINGUISH A METAL POWDER FIRE USE
DRY SAND, DRY GRAPHITE/OTHER CLASS "D" EXTINGUISHER.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). IF THIS MATERIAL IS REDUCED TO POWDER FORM, CAUTION MUST BE
USED TO PREVENT FIRE OR EXPLOSION.
Unusual Fire/Explosion Hazard: NO UNUSUAL FIRE OR EXPLOSION HAZARDS ARE
ASSOCIATED WITH THIS MATERIAL. NFPA RATING: HEALTH = 2; FLAMMABILITY = 0;
REACTIVITY = 0.
*
*
Respiratory Protection: USE NIOSH APPROVED RESPIRABLE FUME RESPIRATOR OR AIR
SUPPLIED RESPIRATOR WHEN WELDING, BRAZING OR SOLDERING IN CONFINED SPACE OR
WHERE LOCAL EXHAUST OR VENTILATION DOES NOT KEEP EXPOSURE BELOW PEL, TL V OR
STEL.
Ventilation: USE ENOUGH VENT, LOC EXHST AT ARC, FLAME/BOTH, TO KEEP FUMES &
GASES BELOW PEL'S, TLV'S/STEL'S IN WORKER'S BRTHG ZONE & GEN AREA. SEE
LENS OF (SUPDAT)
Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N). WEAR
HEAD & BODY PROT WHICH HELP TO PVNT INJURY FROM RADIA, SPKS, FLAME & ELEC
DATA)
SHIELD OTHERS. OTHER PROT EQUIP:SHOULDER PROT, AS WELL (OTHER INFO)
*
Physical/Chemical Properties
*
Appearance and Odor: SOLID WIRE OR ROD, GREY TO SILVER IN COLOR.
*
Reactivity Data
*
Stability Indicator: YES
Materials To Avoid: AVOID CONTACT WITH MINERAL ACIDS & OXIDIZING AGENTS WHICH
MAY GENERATE HYDROGEN GAS; THE EVOLUTION OF HYDROGEN MAY BE AN EXPLOSION
HAZARD.
Hazardous Decomposition Products: VARIOUS ELEMENTAL METALS & METAL OXIDES MAY
BE GENERATED FROM MELTING/DROSS HNDLG OPERATIONS . WELDING FUMES & GASES
CANNOT BE CLASSIFIED SIMPLY. COMPOSITION & QTY OF BOTH ARE DEPENDENT
UPON(OTHER INFO)
Hazardous Polymerization Indicator: NO
*
Toxicological Information
*
Toxicological Information: OTHER INFO:GENERATED ARE DIFF IN PERCENT & FORM
FROM INGS LISTED. FUME & GAS DECOMP PRODS, & NOT INGS IN ELECTRODE,
ARE IMPORTANT. CONC OF GIVEN FUME/GAS COMPONENT MAY DECR/INCR BY MANY TIMES
ORIGINAL CONC IN ELECTRODE. ALSO, NEW CMPDS NOTIN ELECTRODES MAY FORM.
DECOMP PRODS OF NORMAL OPERATION INCL THOSE ORIGINATING FROM VOLATILIZATION,
RXN/OXIDATION OF MATLS SHOWN IN INGS SECTION, PLUS THOSE FRO M BASE METAL
& COATING, ETC, AS NOTED. MOST WELDING, EVEN W/PRIMITIVE VENT, DOES NOT
PRDCE EXPOSURES INSIDE WELDING HELMET ABOVE 5 MG/M3. THAT WHICH DOES, SHOULD
BE CONTROLLED.
*
Ecological Information
*
NATIONAL STD. EFFECTS OF WELDING ON HEALTH - VI, PREPAR ED FOR: SAFETY &
HEALTH COMMITTEE OF THE AMERICAN WELDING SOCIETY.
*
Regulatory Information
*
*
Other Information
*
Other Information: SUPP DATA:DARK SUBSTANTIAL CLTHG. WELDERS SHOULD NOT WEAR
SHORT SLEEVE SHIRTS, SHORT PANTS/CUTOFFS. HAZ DECOMP PROD:METAL BEING WELDED,
PROCESS, PROC & ELECTRODES USED. OTHER CNDTNS WHICH ALSO INFLUEN CE
COMPOSITION & QTY OF FUMES & GASES TO WHICH WORKERS MAY BE EXPOS INCL
COATINGS ON METAL BEING WELDED (SUCH AS PAINT, PLATING/GALVANIZING), NUMBER
OF WELDERS & VOL OF WORK AREA. QUALITY & AMT OF VEN T, POSITION OF
WELDER'S HEAD W/RESPECT TO FUME PLUME, AS WELL AS PRESENCE OF CONTAMS IN ATM
(SUCH AS CHLORINATED HYDROCARBON VAPS FROM CLEANING & DEGREASING
ACTIVITIES). WHEN ELECTRODE IS CONSUMED, FU ME & GAS DECOMP PRODS (TOX
INFO)
*
HAZCOM Label
*
Cage: 0A4S7
Company Name: PERFORMANCE ALLOYS
Label Required IND: Y
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: WELDING GENERATES FUMES, GASES & ELECTROMAGNETIC
RADIA WITH KNOWN ADVERSE HEALTH EFFECTS. ACUTE: EXPOSURE TO FUME MAY RESULT
IN DISCOMFORT, DIZZINESS, NAUSEA, AND DRYNESS/IRRITATION OF THROAT. CHRONI
C: CANCER HAZARD. CONTAINS NICKEL WHICHIS LISTED AS AN ANIMAL LUNG AND NASAL
CAVITY CARCINOGEN AND CONTAINS SILICA, CRYSTALLINE-FUSED WHICH IS LISTED AS A
HUMAN LUNG CARCINOGEN (FP N). LONG TERM EXPOS URE TO IRON FUME MAY PRODUCE
SIDEROSIS.
*
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH APPROVED DUST MASK OR RESPIRATOR.
Ventilation:LOCAL EXHAUST IN CONFINED SITUATIONS.
Other Protective Equipment:NONE.
Work Hygienic Practices:AVOID RAISING DUST. AVOID CONTACT WIYH SKIN,
EYE AND CLOTHING.
Supplemental Safety and Health
NONE
* Product Identification *
Product ID:SILICA GEL
* Composition/Information on Ingredients *
Ingred Name:SILICA, AMORPHOUS, PRECIPITATED AND GEL
Other REC Limits: RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY CAUSE EYE, SKIN & MUCOUS
MEMBRANE IRRITATION. CHRONIC: MAY CAUSE EYE, SKIN AND MUCOUS
MEMBRANE IRRITATION.
Explanation of Carcinogenicity:THIS PRODUCT AND ITS COMPONENTS ARE NOT
LISTED ON THE IARC, NTP OR OSHA CARCINOGENS LISTS.
Effects of Overexposure:DRYING AND DISCOMFORT.
Medical Cond Aggravated by Exposure:ASTHMATICS.
* First Aid Measures *
First Aid:EYES: FLUSH EYES WITH WATER. GET MEDICAL ATTENTION. SKIN:
WASH WITH LARGE AMOUNTS OF WATER. INHALATION: REMOVE TO FRESH AIR.
INGESTION: MATERIAL WILL PASS THROUGH BODY NORMALLY.
* Fire Fighting Measures *
Extinguishing Media:NON-FLAMMABLE, USE EXTINGUISHING MEDIA FOR
SURROUNDING FIRE.
Fire Fighting Procedures:SILICA GEL WILL GET HOT WHEN IT ABSORBS
MOISTURE RAPIDLY. USE AN EXCESS OF WATER TO COOL THE SILICA GEL.
Unusual Fire/Explosion Hazard:.
* Accidental Release Measures *
Spill Release Procedures:SWEEP OR VACUUM UP SPILLED MATERIAL AND
DISPOSE OF PROPERLY.
Neutralizing Agent: REQUIRED
*Handling and Storage *
Handling and Storage Precautions:COVER PROPERLY TO AVOID BREATHING
DUST.
* Physical/Chemical Properties *
HCC:N1
Spec Gravity:2.1
Solubility in Water:INSOLUBLE
Appearance and Odor:WHITE/CLEAR, DRY GRANULES, BEADS OR POWDER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:.
* Disposal Considerations *
Waste Disposal Methods:DISPOSAL IN AN APPROVED LANDFILL ACCORDING TO
LOCAL, STATE AND FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Other Protective Equipment:SAFETY SHOWER & EYE WASH.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
* Product Identification *
Product ID:PUREGENE DNA ISOLATION KIT/RBC LYSIS SOLUTION
* Composition/Information on Ingredients *
Ingred Name:EDTA DISODIUM DIHYDRATE
Ingred Name:SODIUM BICARBONATE
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY BE HARMFUL BY INHALATION,
INGESTION/SKIN ABSORPTION. EYES/SKIN: IRRITATION. INHALATION:
IRRITATING TO MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION.
* First Aid Measures *
WASH W/COPIOUS AMOUNTS OF WATER. INHALATION: REMOVE TO FRESH AIR.
GIVE CPR/OXYGEN IF NEEDED. INGESTION: WASH OUT MOUTH W/WATER IF
CONSCIOUS. O BTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Extinguishing Media:WATER SPRAY, CO2, DRY CHEMICAL POWDER/APPROPRIATE
FOAM.
Fire Fighting Procedures:WEAR SCBA & PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO HEAT/FLAME.
* Accidental Release Measures *
Spill Release Procedures:WEAR PROPER SAFETY EQUIPMENT. SWEEP UP, PLACE
IN A BAG & HOLD FOR WASTE DISPOSAL. VENTILATE AREA & WASH SITE
AFTER MATERIAL PICKUP IS COMPLETE.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER CLOSED. STORE IN A COOL
DRY PLACE.
Other Precautions:AVOID CONTACT W/EYES, SKIN & CLOTHING.
* Physical/Chemical Properties *
pH:7-8
Appearance and Odor:CLEAR LIQUID; ODORLESS
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, ACIDS, BASES.
Stability Condition to Avoid:HEAT/FLAME.
Hazardous Decomposition Products:COMBUSTION: HYDROGEN CHLORIDE GAS,
AMMONIA, CO, CO2.
* Disposal Considerations *
Waste Disposal Methods:FLUSH THE AQUEOUS SOLUTION DOWN THE DRAIN
W/PLENTY OF WATER, IAW/FEDERAL, STATE & LOCAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:FOR ORGANIC VAPOR ENVIRONMENT (AIR PURIFIED/AIR
SUPPLIED). IF DOCUMENTED BELOW TLV/PEL, YOU MAY NOT NEED AN AIR
SUPPLIED RESPIRATOR; OTHER OSHA/NIOSH RESPIRATOR MAY BE USED.
Ventilation:EXHAUST VENTILATION.
Other Protective Equipment:USE LONG SLEEVE AND LEG CLOTHES.
Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING, OR USING
WASHROOM. SMOKE IN SMOKING AREAS ONLY.
Supplemental Safety and Health
NK
* Product Identification *
Kit Part:Y
Preparer's Name:NORM GAUL
* Composition/Information on Ingredients *
Fraction by Wt: <5.0%
Other REC Limits:NOT RECOMMENED
Ingred Name:DISPERSION AGENT (VAPOR PRESSURE 0 MM HG)
Fraction by Wt: <1%
Other REC Limits:NOT RECOMMENED
Other REC Limits:NOT RECOMMENED
Ingred Name:ANTI-FLOAT AGENT
Fraction by Wt: <1%
Other REC Limits:NOT RECOMMENED
Fraction by Wt: 5.0%
Other REC Limits:NONE SPECIFIED
Ingred Name:ANTI MAR AGENT (VAPOR PRESSURE 0 MM HG)
Fraction by Wt: <1%
Other REC Limits:NOT RECOMMENED
Other REC Limits:NOT RECOMMENED
Fraction by Wt: <0.1%
Other REC Limits:NOT RECOMMENED
ACGIH TLV:0.1 MG/M3
Fraction by Wt: <5%
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHAL: RESPIRATORY TRACT IRRITATION &
NS DEPRESSION (HEADACHE, DIZZY, STAGGERING, CONFUSION, UNCONSCIOUS,
COMA). DIFFICULT BREATHING. SKIN: IRRITATION, SWELLING, REDNESS,
RASH. EYE: IRRITATION, TEARIN G, REDNESS, SWELLING, STINGING.
INGEST:CORROSIVE ACTION IN THE MOUTH, STOMACH TISSUE, DIGESTIVE
TRACT.*
Effects of Overexposure:*VOMITING MAY CAUSE ASPIRATION OF THE SOLVENT,
RESULTING IN CHEMICAL PNEUMONITIS. CHRONIC: CONTACT WILL CAUSE SKIN
DRYING & CRACKING, DUE TO DEFATTING ACTION. SKIN SENSITIZATION,
ASTHMA/OTHER ALLERGIC RESPONSES.
Medical Cond Aggravated by Exposure:ASTHMA AND ANY OTHER RESPIRATORY
DISORDERS. SKIN ALLERGIES, ECZEMA AND DERMATITIS.
* First Aid Measures *
First Aid:INHAL: MOVE TO FRESH AIR. RESTORE BREATHING. SYMPTOMS MAY BE
DELAYED. GET MED AID. SKIN: REMOVE CLOTHING. WASH W/SOAP & WATER.
LIFTI NG LIDS. GET MED AID. INGEST: DONT INDUCE VOMIT. GET MED AID.
* Fire Fighting Measures *
Flash Point Method:TCC
Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG,
WATER SPRAY.
Fire Fighting Procedures:FULL FIRE FIGHT EQUIP W/SCBA & FULL PROTECTIVE
CLOTHING. WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT
PRESSURE BUILD UP, AUTO IGNITION OR EXPLOSION.
Unusual Fire/Explosion Hazard:KEEP CONTAINERS CLOSED. KEEP FROM
HEAT/IGNIT SOURCE. CLOSED CONTAINERS MAY EXPLODE W/HEAT.
OVEREXPOSURE TO DECOMP PRODUCTS HEALTH HAZARD.
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE
AREA. CONTAIN AND REMOVE WITH INERT ABSORBENT AND NON-SPARKING
TOOLS.
*Handling and Storage *
Handling and Storage Precautions:STORE IN BLDG DESIGNED TO COMPLY
STORE IN CLOSED CONTAINERS IN VENTED AREA.
Other Precautions:KEEP CONTAINERS TIGHT & UPRIGHT TO PREVENT LEAKAGE.
DONT HANDLE UNTILL SAFETY PRECAUTIONS HAVE BEEN READ AND
UNDERSTOOD.
* Physical/Chemical Properties *
Vapor Density:>AIR
pH:NA
Solubility in Water:INSOLUBLE
Appearance and Odor:GRAY LIQUID, W/ SOLVENT ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, OR OPEN FLAMES.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
OXIDES OF NITROGEN.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE IN ACCORDANCE W/FEDERAL, STATE, & LOCAL
REGULATIONS. EMPTY CONTAINERS HAVE PRODUCT RESIDUE & FLAMMABLE
* Other Information *
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE AIR-PURIFYING RESPIRATOR W/ORGANIC
PROTECTION/SUPPLIED AIR FOR MORE CONCENTRATED VAPORS.
Ventilation:MECHANICAL VENTILATION
Other Protective Equipment:CHEMICAL RESISTANT CLOTHING
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES
BEFORE REUSE.
Supplemental Safety and Health
* Product Identification *
Product ID:DMF
* Composition/Information on Ingredients *
Ingred Name:DIMETHYLFORMAMIDE
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:HARMFUL BY INHALATION,
INGESTION/ABSORPTION THROUGH SKIN. INHALATION: IRRITATING TO MUCOUS
MEMBRANES & UPPER RESPIRATORY TRACT. CAUSES SKIN IRRITATION. EYES:
MAY DAMAGE. INGESTION: DANGEROUS.
Effects of Overexposure:IRRITATION
* First Aid Measures *
MINS. INSURE GOOD FLUSH BY HOLDING EYE LIDS OPEN. SKIN: WASH
W/LARGE AMOUNTS OF WATER FOLLOWED BY SOAP & WATER WASH. INGESTION:
RINSE MOUTH W /WATER, INSURING THAT RINSE IS NOT SWALLOWED. GIVE
1/2 PINT OF MILK/WATER TO DILUTE STOMACH CONTENTS. INHALATION:
REMOVE TO FRESH AIR. REST & KEEP AT A COMFORTABLE TEMPERATURE. GIVE
OXYGEN IF BREATHIN G SEEMS DIFFICULT/MOUTH-TO-MOUTH RESUSCITATION
IF NECESSARY. OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point Method:CC
Extinguishing Media:CO2, FOAM/DRY CHEMICAL EXTINGUISHER
Fire Fighting Procedures:WEAR FULL PROTECTIVE EQUIPMENT W/RESPIRATORY
PROTECTION.
* Accidental Release Measures *
Spill Release Procedures:WEAR FULL PRTOECTIVE EQUIPMENT W/CHEMICAL
SUPPLIED AIR. SMALL LEAKS MAY BE HANDLED W/AIR PURIFYING RESPIRATOR
USE ABSORBENT/OIL DRY TO CLEAN UP LIQUIDS & PLACE CONTAMINATED
ABSORBENT IN PROPER CONTAINER FOR DISPOSAL.
*Handling and Storage *
Handling and Storage Precautions:KEEP TIGHTLY CLOSED.
* Physical/Chemical Properties *
Evaporation Rate & Reference:(WATER=1): >1
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR LIQUID
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:FLAME, EXCESSIVE HEAT
Hazardous Decomposition Products:CO2, CO, NITROGEN OXIDES
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF BY EPA APPROVED METHODS INCLUDING
RCRA INCINERATION. PURE MATERIAL MAY BE SENT FOR RCRA
INCINERATION/FUEL BLENDING IF APPROPRIATE. DISPOSE OF IN ACCORDANCE
W/LOCAL, STATE & FEDERAL REGULATI ONS.
| 1 | gloves_mandatory |
Control Measures
*
Proprietary Ind: Y
*
Contractor Summary
*
*
Ingredients
*
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: INHAL:IRRIT OF RESP TRACT. PRLNG INHAL MAY LEAD TO FATG,
DROW, DIZZ &/OR LT HEAD, HDCH, LACK OF COORD, NAUS, VOMIT, CNS DEPRESS,
ANESTH EFT/NARCOS. SKIN CONT:IRRIT. PRLNG/RPTD CONT CAN CAUSE DERM, DEF AT.
EYE CONT:IRRIT. PRLNG/RPTD CONT CANCAUSE BLURRED VISION, REDNESS, TEARING,
SEV IRRIT. INGEST:AMTS (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ:INGESTED INCIDENTAL TO CONSUMER
& INDUS HNDLG ARE NOT LIKELY TO CAUSE INJURY; HOWEVER, LGR AMTS MAY CAUSE
LUNG INFLAMM & DMG DUE TO ASPIR OF MATL INTO LUNGS. NOTICE:RPTS HAVE
ASSOC RPTD & PRL NG OCCUP OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS
DMG. INTENTIONAL MISUSE BY DELIB CONC & INHAL CONTENTS MAY BE
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INHAL:REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED
BREATHING. HAVE TRAINED PERSON GIVE OXYGEN IF NECESSARY. GET EMERGENCY
MEDICAL ATTENTION. SKIN:WASH OFF QUICKLY W/PLENTY OF WATER, THEN SOAP &
WA TER; REMOVE & WASH CONTAMINATED CLOTHING BEFORE REUSE. EYES:FLUSH
EMER MED TREATMENT. INGEST:OBTAIN MED TREATMENT IMMED.
*
Handling and Disposal
*
Spill Release Procedures: REMOVE ALL SOURCES OF IGNITION (FLAME, HOT SURFACES
& ELECTRICAL, STATIC SPARKS). VENTILATE AREA & AVOID BREATHING
VAPORS. CONTAIN & REMOVE W/INERT ABSORBENT MATERIAL USING NON-SPARKING
TOOLS.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE I/A/W LOCAL, STATE & FEDERAL REGULATIONS.
AVOID DISCHARGE TO NATURAL WATERS.
IN BLDGS DESIGNED FOR STOR OF FLAMM/COMBUST LIQS. DO NOT TAKE INTERNALLY.
KEEP OUT OF REACH OF CHILDREN.
Other Precautions: DO NOT WELD/FLAME CUT W/OUT PROPER VENT TO INSURE AREA IS
FREE OF FLAMM VAPS. DO NOT CUT, PUNCTURE/WELD ON/NEAR CNTNR. ENTRANCE INTO
CLSD STOR TANKS - USE APPROP NIOSH APPRVD RESP/AIRLINE FOR POSS EXP OS TO
SOLV/CHEM FUMES. RAGS/ (SUPDAT)
*
Fire and Explosion Hazard Information
*
Flash Point Method: SCC
Extinguishing Media: DRY CHEMICAL OR FOAM.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). WATER MAY BE USED TO COOL & PROTECT EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard: FLAMM LIQ-CLASS IB. CLSD CNTNRS MAY EXPLODE WHEN
EXPOS TO EXTREME HEAT/FIRE. VAPS CAN FORM EXPLO MIXTS IN AIR AT ELEVATED
TEMPS. MAY DECOMP UNDER FIRE (SUPDAT)
*
*
Respiratory Protection: CONTROL ENVIRON CONCS BELOW APPLIC STDS. NIOSH APPRVD
PROPERLY FITTED AIR PURIFYING/SUPPLIED AIR RESP PROVEN TO BE EFTIVE IN
PARTICULATE, ORG VAP & ISOCYANATE CNTNG SPRAY PAINT ENVIRONS MAY BE NEC.
Ventilation: ALL APPLICATION AREAS SHOULD BE VENTILATED I/A/W OSHA REGULATION
Other Protective Equipment: EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI
DESIGN CRITERIA (FP N).
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: NOTE:USERS OF "L" VERSION SHOULD CONSULT "LR"
VERSION FOR ADDNL INFO (FP N). EXPLO HAZ:CNDTNS EMITTING IRRIT &/OR TOX
THATPRESENT LG AIR-TO-OIL INTERFACE WILL OXIDIZE & MAY IGNITE SPONT
& SHOULD BE PLACE IN METAL CNTNR.
*
Physical/Chemical Properties
*
Vapor Pres: SEE INGS
Evaporation Rate & Reference: SLOWER THAN ETHYL ETHER
Appearance and Odor: NONE SPECIFIED BY MANUFACTURER.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: ELEVATED TEMPERATURES. CONTACT W/OXIDIZING
AGENTS.
Materials To Avoid: OXIDIZERS, ACIDS, BASES, AMINES.
Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Company Name: M A BRUDER & SONS INC
Label Required IND: Y
Status Code: C
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: EXTREMELY FLAMM. ACUTE:INHAL:IRRIT OF RESP TRACT. PRLNG
INHAL MAY LEAD TO FATG, DROW, DIZZ &/OR LT HEAD, HDCH, LACK OF COORD,
NAUS, VOMIT, CNS DEPRESS, ANESTH EFT/NARCOS. SKIN:IRRIT. PRLNG/RPTD CONT C AN
CAUSE DERM, DEFAT. EYE:IRRIT. PRLNG/RPTD CONT CAN CAUSE BLURRED VISION,
REDNESS, TEARING, SEV IRRIT. INGEST:LG AMTS MAY CAUSE LUNG INFLAMM & DMG
DUE TO ASPIR INTO LUNGS. CHRONIC:RPTS HAVE ASSOC RPT D & PRLNG OCCUP
OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS DMG. INTENTIONAL MISUSE BY DELIB
CONC & INHAL CONTENTS MAY BE HARMFUL/FATAL. FREE ISOCYANATES MAY CAUSE
ALLERGIC SKIN/RESP RXN IN SUSCEPTIBLE P ERS. RESP SENSIT MAY RSLT IN
ASTHMA-LIKE SYMPS.
*
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:HIGH EFFICIENCY PARTICULATE RESPIRATOR
(<2.5MG/CUM). SCBA.
Ventilation:LOCAL EXHAUST: REQUIRED AT DUST PRODUCING OPERATIONS.
Other Protective Equipment:CLOTHING & FOOT COVERINGS TO PREVENT URANIUM
CONTAMINATION.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:DEPLETED URANIUM (AS URANIUM)
OSHA PEL:0.2MG/M3/0.6STEL (U)
ACGIH TLV:0.2MG/M3/0.6STEL (U)
* Hazards Identification *
Effects of Overexposure:PROLONGED SKIN CONTACT CAN CAUSE RADIATION
DAMAGE. INCREASE IN LYMPHATIC AND BLOOD CANCER.
* First Aid Measures *
First Aid:EYE: WASH W/LARGE AMOUNTS OF WATER. SEEK MEDICAL ATTENTION.
SKIN: WASH W/SOAP & MILD DETERGENT & WATER. INHALATION: MOVE
EXPOSED TO FRESH AIR, OBTAIN MEDICAL ASSISTANCE. INGESTION: DRINK
W/LARGE QUANT ITIES OF WATER. INDUCE VOMITING. GET MED ATT.
* Fire Fighting Measures *
Extinguishing Media:COPIOUS AMOUNTS OF WATER, CLASS D
Fire Fighting Procedures:TREAT AS STRONG METAL FIRE. SCBA & PROTECTIVE
CLOTHING.
Unusual Fire/Explosion Hazard:DECONTAMINATE EQUIPMENT WHEN DONE.
EXTREMELY PYROPHORIC WHEN FINELY DIVIDED (DUST).
* Accidental Release Measures *
Spill Release Procedures:COLLECT SPILLED MATERIAL IN THE MOST
CONVENIENT & SAFE MANNER & DEPOSIT IN SEALED COAINERS FOR
RECLAMATION OR DISPOSAL. URANIUM CHIPS OR TURNINGS SHOULD BE VERED
WITH OIL. AVOID INHALATION OF DUST.
*Handling and Storage *
Handling and Storage Precautions:LOW LEVEL RADIOACTIVE MATERIAL,
EXCESSIVE EXPOSURE TO DUST & SOLID MATERIAL MAY CREATE AN EXCEIVE
RADIATION EXPOSURE. FOLLOW NRC GUIDELINES.
* Physical/Chemical Properties *
HCC:A3
Solubility in Water:INSOLUBLE
Appearance and Odor:SILVERY WHITE METAL, OXIDATION TURNS BLACK
Percent Volatiles by Volume:0%
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
CONTACT W/CO2, CCL4, OR NITRIC WILL CAUSE EXPLOSION.
Stability Condition to Avoid:ACCUMULATIONS OF DUST OR METAL CHIPS.
Hazardous Decomposition Products:TOXIC BY PRODUCTS WILL BE RELEASED
FROM PYROLYSIS.
* Disposal Considerations *
Waste Disposal Methods:MATERIALS SHOULD BE DISPOSED OF AS A LOW LEVEL
RADIOACTIVE WASTE CONSISTENT WITH DOT & NRC REQUIREMENTS. METAL
WASTE SHOULD BE STABILIZED BY MIXING WITH CONCRETE OR OTHER
ACCEPTABLE STABILIZING MATERI AL.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN . NOT REQUIRED.
Ventilation:LOCAL EXHAUST:NOT REQUIRED. MECHANICAL
(GENERAL):RECOMMENDED.
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER . PLASTIC APRON, FABRIC LABORATORY COAT RECOMMENDED.
Work Hygienic Practices:DO NOT CONTAMINATE SMOKING MATERIALS; WASH
HANDS AFTER EXPOSURE.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
Product ID:TRIBOLUBE-2
* Composition/Information on Ingredients *
Ingred Name:NON-HAZARDOUS INGREDIENTS
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:NONE. PROLONGED EXPOSURE CAUSES
NO KNOWN ADVERSE EFFECTS. CHRONIC:NONE.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NO KNOWN MEDICAL CONDITIONS THAT
MIGHT BE AGGRAVATED BY EXPOSURE.
* First Aid Measures *
First Aid:INGESTION:CALL MD IMMEDIATELY . INHALATION:REMOVE TO FRESH
AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:FLUSH WITH WATER
* Fire Fighting Measures *
Extinguishing Media:CO*2, DRY CHEMICAL, FOAM, WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:TOXIC FLUORINE GASES.
* Accidental Release Measures *
Spill Release Procedures:USE ABSORBENT MATERIALS TO COLLECT AND CONTAIN
FOR SALVAGE OR DISPOSAL.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:USE REASONABLE CARE.
VENTILATION IF USED ABOVE THIS TEMPERATURE.
* Physical/Chemical Properties *
Vapor Pres:<5
Solubility in Water:NIL
Appearance and Odor:YELLOW
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OXIDIZING MATERIALS CAN CAUSE A REACTION.
Hazardous Decomposition Products:FLUORINE PRODUCTS, SILICON DIOXIDE,
CO*2, TRACES OF INCOMPLETELY BURNED CARBON.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE ORGANIC VAPOR RESPIRATOR (AIR
PURIFYING/FRESH AIR). OBSERVE OSHA REGULATIONS (RESPIRATOR USE).
PROVIDE VENT (KEEP EXPOSURE LEVELS BELOW OSHA LIMITS). VAPOR PARTIC
LIMITS
Ventilation:EXHAUST VENT SUFFICIENT TO KEEP AIRBORNE CONC
(SOLVENT/POLYISOCYANATES/HDI) BELOW TLV'S. REMOVE ALL IGNITION
SOURCES.
Other Protective Equipment:FACE SHIELDS. THE USE OF LONG SLEEVE AND
LONG LEG CLOTHING IS RECOMMENDED.
Work Hygienic Practices:REMOVE AND WASH CONTAMINATED CLOTHING BEFORE
REUSE. WASH HANDS BEFORE EATING, SMOKING OR USING WASHROOM.
Supplemental Safety and Health
* Product Identification *
Kit Part:Y
Preparer's Name:NORM GAUL
* Composition/Information on Ingredients *
Ingred Name:TOLUENE (SARA III)
Other REC Limits:NONE SPECIFIED
Ingred Name:ALIPHATIC ISOCYANATE (VAPOR PRESSURE 0 MM HG)*
Other REC Limits:MOBAY TLV: 1 MG/M3
MONOMER CONTENT LESS THAN 0.7% BASED ON RESIN SOLIDS AT TIME**
Other REC Limits:NONE SPECIFIED
Ingred Name:**OF MFR. AFTER 3-6 MO STORAGE FREE MONOMER CONTENT MAY
Other REC Limits:NONE SPECIFIED
Other REC Limits:NONE SPECIFIED
Ingred Name:METHYL ISOBUTYL KETONE (SARA III)
Other REC Limits:NONE SPECIFIED
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: VAPORS IRRITATING TO
EYES/NOSE/THROAT. INHALATION: IRRITATION, ACUTE NERVOUS SYSTEM
DEPRESSION. CHRONIC: PROLONGED CONTACT WILL CAUSE DEFATTING ACTION.
INGESTION: IRRITATION. ASPIRATION CAN CAU SE CHEMICAL PNEUMONITIS.
AS A RESULT OFPREVIOUS REPEATED OVEREXPOSURE OR SINGLE LARGE DOSE,
CERTAIN INDIVIDUALS WILL**
Effects of Overexposure:INHAL: DIFFICULT BREATHING, HEADACHE,
DIZZINESS, STAGGERING GAIT, CONFUSION, UNCONSCIOUSNESS, COMA. SKIN:
IRRIT (SWELLING/REDNESS/RASH). EYES: REDNESS, TEARING, SWELLING
W/STINGING. SKIN: SWELL/REDNES S/RASH. PROLONG/REPEAT--MOD IRRIT,
DRYING, SKIN CRACKING. INGEST: VOMIT. IRRIT. CORROSIVE TO
MOUTH/STOMACH/DIGEST TRACT.
Medical Cond Aggravated by Exposure:ASTHMA AND ANY OTHER RESPIRATORY
DISORDERS. SKIN ALLERGIES, ECZEMA, AND DERMATITIS.
* First Aid Measures *
First Aid:INHALATION: MOVE TO FRESH AIR. RESTORE BREATHING. ASTHMATIC
TYPE SYMPTOMS MAY DEVELOP (IMMED/DELAYED BY SEVERAL HRS). GET MED
AID. SKIN: REMOVE CONTAM CLOTHING. WASH AREA W/SOAP & WATER. WASH
CONTAM C LOTHING BEFORE REUSE. EYES: FLUSH WITH LUKEWARM WATER (LOW
INGESTION: DON'T INDUCE VOMIT. NOTHING BY MOUTH TO UNCONSCIOUS
PERSON. GET MED AID.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:1%
Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:FULL FIRE FIGHT EQUIP W/SCBA & FULL PROTECT
CLOTH. USE WATER TO COOL CLOSED CNTNRS/PREVENT PRESSURE
BUILD-UP/AUTO IGNITE/EXPLOSION. HDI/IRRIT VAPORS GENERATED.
Unusual Fire/Explosion Hazard:KEEP FROM IGNITE SOURCES. CLOSED CNTNR
MAY EXPLODE W/HEAT. USE SPECIAL PRECAUTION W/APPLIC TO HOT SRFCS.
DURING EMERG COND, OVEREXPOS TO DECOMP PROD/HEALTH HZD.
* Accidental Release Measures *
Spill Release Procedures:EVACUATE ALL NON-ESSENTIAL PERSONNEL. REMOVE
ALL SOURCES OF IGNITION (FLAME, SPARK SOURCES, HOT SURFACES).
VENTILATE AREA. CONTAIN AND REMOVE WITH INERT ABSORBENT AND
NON-SPARKING TOOLS.
*Handling and Storage *
Handling and Storage Precautions:STORE IN BLDG IN COMPLIANCE W/OSHA
CLOSED CONTAINERS. STORE IN WELL VENT AREAS.
Other Precautions:KEEP CNTNRS TIGHT/UPRIGHT (PREVENT LEAKAGE). NO
PROLONGED BREATHING OF VAPORS/SPRAY MISTS. AVOID CONTACT
W/SKIN/EYES. DO NOT TAKE INTERNALLY. DO NOT HANDLE UNTIL THE SAFETY
PRECAUTIONS HAVE BEEN READ/ UNDERSTOOD. SMOKE ONLY IN SMOKING
AREAS.
**DEVELOP ISOCYANATE SENSITIZATION WHICH WILL CAUSE THEM TO REACT TO A
LATER EXPOSURE OF ISOCYANATES LEVELS WELL BELOW THE TLV VALUE OF
ISOCYANATES.
* Physical/Chemical Properties *
HCC:F5
Vapor Density:> AIR
Viscosity:*
Solubility in Water:INSOLUBLE
Appearance and Odor:AMBER LIQUID WITH SOLVENT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
WATER, AMINES, STRONG BASES, ALCOHOLS, METAL COMPOUNDS AND SURFACE
ACTIVE MATERIALS.
Stability Condition to Avoid:CONTACT WITH MOISTURE, MATERIALS WHICH
REACT WITH ISOCYANATES AND HIGH TEMPERATURES.
Hazardous Decomposition Products:BY HIGH HEAT/TEMPERATURE: CARBON
MONOXIDE, CARBON DIOXIDE, AND OXIDES OF NITROGEN, TRACES OF HCN AND
HDI.
* Disposal Considerations *
Waste Disposal Methods:WASTE MUST BE DISPOSED IN ACCORD W/FEDERAL,
STATE & LOCAL ENVIRONMENTAL CONTROL REGULATIONS. EMPTY CONTAINERS
MUST BE HANDLED W/CARE (PRODUCT RESIDUE/FLAMMABLE VAPOR). DON'T
| 1 | gloves_mandatory |
Control Measures
*
Product ID: BIO T FOAMAX XX
Cage: 0XYG0
Proprietary Ind: Y
*
Contractor Summary
*
Cage: 0XYG0
*
Ingredients
*
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: EYES: MAY CAUSE IRRITATION. SKIN: CAUSES
IRRITATION. INHALATION: PROLONGED INHALATION OF AEROSOL/VAPOR MAY RESULT IN
DROWSINESS, HEADACHE AND UNCOORDINATION IF USED EXTENSIVELY IN ABSENCE OF GE
NERAL VENTILATION.
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
SEE MD. SKIN: WASH WITH MILD SOAP AND WATER. INHALATION: MOVE VICTIM TO FRESH
AIR. INGESTION: DO NOT INDUCE VOMITING. RINSE MOUTH WIT H WATER, THEN DRINK
ONE GLASS OF WATER.CONTACT MD IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH IF
VICTIM IS UNCONSCIOUS, IS RAPIDLY LOSING CONSCIOUSNESS, OR IS CONVULSING.
*
Handling and Disposal
*
Spill Release Procedures: AVOID USE OF ANY IGNITION SOURCE NEAR SPILL. CONTAIN
PRODUCT WITH INERT MATERIAL OR ABSORBENT MEDIUM SUCH AS ACTIVATED CARBON OR
KITTY LITTER.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: HAZARDOUS SUBSTANCES CLEANED WITH THIS PRODUCT MAY BE
CONSIDERED HAZARDOUS WASTE. UNUSED PORTIONS OF THIS PRODUCT MUST BE DISPOSED
OF AS IGNITABLE WASTE. DISPOSE OF HAZARDOUS WASTE IN ACCORDANCE WITHALL
LOCAL, STATE AND FEDERAL REGULATIONS.
Handling And Storage Precautions: STORE IN A WELL-VENTILATED AREA AT
Other Precautions: AVOID CONTACT WITH SKIN, EYES AND MUCOUS MEMBRANES.
*
Fire and Explosion Hazard Information
*
Extinguishing Media: PRODUCT EXTINGUISHES FLAME. USE DRY CHEMICAL, CARBON
DIOXIDE OR HALON.
Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N). DO NOT USE WATER.
Unusual Fire/Explosion Hazard: GUARD AGAINST SPONTANEOUS COMBUSTION OF
IMPROPERLY DISCARDED OILY RAGS.
*
*
Respiratory Protection: NOT REQUIRED IN PRESENCE OF GOOD GENERAL VENTILATION.
IF CONDITIONS WARRANT, USE NIOSH APPROVED RESPIRATOR.
Ventilation: GENERAL MECHANICAL VENTILATION.
Other Protective Equipment: EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA (FP N).
Work Hygienic Practices: AVOID WEARING CLOTHES SATURATED WITH CLEANER.
Supplemental Safety and Health: NONE SPECIFIED BY MANUFACTURER.
*
Physical/Chemical Properties
*
PH: 9.8
Evaporation Rate & Reference: 1 (H*2O=1)
Solubility in Water: SOLUBLE
Appearance and Odor: FOAM/GEL WITH CITRUS ODOR
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: AVOID USE OF ANY IGNITION SOURCES NEAR SPILL.
Materials To Avoid: AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products: CARBON MONOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Product ID: BIO T FOAMAX XX
Cage: 0XYG0
Company Name: BIOCHEM SYSTEMS INC
Label Required IND: Y
Status Code: C
Origination Code: G
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: EYES: MAY CAUSE IRRITATION. SKIN: CAUSES
IRRITATION. INHALATION: PROLONGED INHALATION OF AEROSOL/VAPOR MAY RESULT IN
DROWSINESS, HEADACHE AND UNCOORDINATION IF USED EXTENSIVELY IN ABSENCE OF GE
NERAL VENTILATION. CHRONIC: NONE SPECIFIED BY MANUFACTURER.
*
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF EXPOS LIM IS EXCEEDED, A NIOSH APPRVD
HALF-FACE DUST/MIST RESP MAY BE WORN FOR UP TO TEN TIMES EXPOS
LIM/MAX USE CONC SPECIFIED BY APPROP REGULATORY AGENCY/RESP
SUPPLIER, WHICHEVER IS LOWEST. A NIO SH APPRVD FULL-FACEPIECE
SPECIFIED BY APPROP REGULATORY AGENCY/RESP SUPPLIER, (SUP DAT)
Ventilation:A SYS OF LOC &/OR GEN EXHST IS REC TO KEEP EXPLOYEES EXPOS
BELOW AIRBORNE EXPOS LIMS. LOC EXHST VENT IF GEN PREF BECAUSE IT
CAN CTL EMISSIONS OF (OTHER INFO)
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE
SHOWER . LAB COAT, APRON OR COVERALLS.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
RESP PROT: WHICHEVER IS LOWEST. FOR EMERS/INSTANCES WHERE EXPOS LEVELS
ARE NOT KNOWN, USE NIOSH APPRVD FULL-FACEPIECE POS-PRESS,
AIR-SUPPLIED RESP. WARNING: AIR-PURIFYING RESPS DO NOT PROTECT
WORKERS IN OXYGEN-DEFICIENT ATMS. PHYSICAL/CHEM PROPERTIES: SOL IN
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:CALCIUM CARBONATE
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION: EXCESSIVE
CONCENTRATIONS OF A NUISANCE DUST MAY CAUSE NUISANCE CONDITION SUCH
AS COUGHING, SNEEZING, AND NASAL IRRITATION. INGESTION: NON-TOXIC.
SKIN: NOT EXPECTED TO BE A HEALTH HA ZARD FROM SKIN EXPOSURE. EYES:
NO INFORMATION FOUND, BUT PRESUMED TO CAUSE MECHANICAL IRRITATION.
CHRONIC: EXCESSIVE ORAL DOSES OF CALCIUM CARBONATE MAY PRODUCE
ALKALOSIS AND HYPERCALCEMIA.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NO INFORMATION FOUND.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. GET MEDICAL ATTENTION FOR
ANY BREATHING DIFFICULTY. INGESTION: IF LARGE AMOUNTS WERE
SWALLOWED, GIVE WATER TO DRINK AND GET MEDICAL ADVICE. SKIN: WASH
EXPOSED AREA WIT H SOAP AND WATER. GET MEDICAL ADVICE IF IRRITATION
MINUTES. GET MEDICAL ADVICE IF IRRITATION DEVELOPS.
* Fire Fighting Measures *
Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING
SURROUNDING FIRE.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE A FIRE HAZARD. NOT
CONSIDERED TO BE AN EXPLOSION HAZARD.
* Accidental Release Measures *
Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL. WEAR
APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT AS SPECIFIED IN CONTROL
MEASURES SECTION. SPILLS: SWEEP UP AND CONTAINERIZE FOR RECLAMATION
OR DISPOSAL. VACUUMING OR WE T SWEEPING MAY BE USED TO AVOID DUST
DISPERSAL.
*Handling and Storage *
Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED CONTAINER,
STORED IN A COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL
DAMAGE. CONTAINERS OF THIS PRODUCT MAY BE HAZARDOUS WHEN EMPTY
SINCE THEY RETAIN PRODUCT RESIDUES ( DUST, SOLIDS); OBSERVE ALL
WARNINGS AND PRECAUTIONS LISTED FOR THE PRODUCT.
Other Precautions:AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID
BREATHING DUST. KEEP CONTAINER CLOSED. USE WITH ADEQUATE
VENTILATION.
* Physical/Chemical Properties *
Appearance and Odor:FINE, WHITE POWDER; ODORLESS.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ACIDS, FLUORINE, MAGNESIUM WITH HYDROGEN.
Stability Condition to Avoid:HEAT, INCOMPATIBLES.
EMITS CALCIUM OXIDE FUMES AND LIBERATES CARBON DIOXIDE.
* Toxicological Information*
NORMAL ROUTES OF OCCUPATIONAL EXPOSURE.
* Ecological Information *
Ecological:ENVIRONMENTAL FATE: NO INFORMATION FOUND. ENVIRONMENTAL
TOXICITY: NO INFORMATION FOUND.
* Disposal Considerations *
Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY/RECYCLING
SHOULD BE MANAGED IN APPROPRIATE & APPROVED WASTE DISPOSAL
FACILITY. PROCESSING, USE/CONTAMINATION OF PRODUCT MAY CHANGE WASTE
MANAGEMENT OPTIONS. STATE & LOCAL DISPOSAL REGULATIONS MAY DIFFER
FROM FEDERAL DISPOSAL REGULATIONS. DISPOSE OF CONTAINER & U NUSED
PRODUCT I/A/W FEDERAL, STATE & LOCAL REGS.
* MSDS Transport Information *
Transport Information:NOT REGULATED.
* Regulatory Information *
NO; FIRE: NO; PRESSURE: NO; REACTIVITY: NO (PURE/SOLID).
LISTED IN TSCA, EC, JAPAN, AUSTRALIA, KOREA, CANADA DSL,
NO. AUSTRALIAN HAZCHEM CODE: NO INFORMATION FOUND. POISON SCHEDULE:
NO INFORMATION FOUND. WHMIS: THIS MSDS HAS BEEN PREPARED ACCORDING
TO THE HAZARD CRITERIA OF THE CONTROLLED PRO DUCTS REGULATIONS
(CPR) AND THE MSDS CONTAINS ALL OF THE INFORMATION REQUIRED BY THE
CPR.
* Other Information *
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION
EXOSURES BELOW PEL (TLV), USE NIOSH/MSHA APPROVED RESPIRATOR AS PER
SELECTION.
Ventilation:PROVIDE SUFFICIENT GENERAL/LOCAL EXHAUST VENTILATION IN
PATTERN/VOLUME TO CONTROL INHALATION EXPOSURES BELOW TLV'S
Other Protective Equipment:WEAR INDUSTRIAL-TYPE CLOTHING AND SAFETY
FOOTWEAR
Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT
AND BEFORE EATING DRINKING OR SMOKING.
Supplemental Safety and Health
NOTES TO PHYSICIAN: THERE IS NO SPECIFIC ANTIDOTE FOR EFFECTS FROM
OVEREXPOSURE TO THIS MATERIAL. TREATMENT SHOULD BE DIRECTED AT THE
CONTROL OF SYMPTOMS AND THE CLINICAL CONDITION.
* Product Identification *
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:N-BUTYL ALCOHOL (SARA III) (PERCENTAGE IS TOTAL FOR
PRODUCT)
Other REC Limits:NONE RECOMMENDED
Ingred Name:TITANIUM DIOXIDE (PERCENTAGE TOTAL FOR PRODUCT)
Other REC Limits:NONE RECOMMENDED
Ingred Name:TALC (CONTAINING ASBESTOS)(PERCENTAGE TOTAL FOR PRODUCT)
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.2 FIBERS/CC
Ingred Name:NAPHTHA, LIGHT AROMATIC (PERCENTAGE TOTAL FOR PRODUCT)
Other REC Limits:NONE RECOMMENDED
Ingred Name:EPOXY-POLYAMIDE RESIN (PERCENTAGE TOTAL FOR PRODUCT)
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:BISPHENOL A DIGLYCIDYL ETHER RESIN (PERCENTAGE TOTAL FOR
PRODUCT)
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE IRRITATION, SKIN IRRITATION,
DERMATITIS, GASTROINTESTINAL DISTURBANCES, PNUEMONITIS, RESPIRATORY
TRACT IRRITATION, CENTRAL NERVOUS SYSTEM DEPRESSION.
Explanation of Carcinogenicity:PRODUCT CONTAINS NO INGREDIENTS
CURRENTLY CLASSIFIED AS CARCINOGENIC BY NTP, IARC OR OSHA.
Effects of Overexposure:EYE IRRITATION, PROLONGED OR REAPEATED SKIN
CONTACT MAY CAUSE DEFATTING OF SKIN, REDNESS, CRACKING,
BLISTERING--SENESITIZATION MAY OCCUR. HEADACHE, WEAKNESS,
DIZZINESS, INCOORDINATION, POSSIBLE COLLAP SE, ASPIRATION HAZARD,
NAUSEA, VOMITING,DIARRHEA.
Medical Cond Aggravated by Exposure:INDIVIDUAL S WITH PRE-EXISTING
DISEASE IN OR A HISTORY OF AILMENTS INVOLVING THE SKIN, EYE,
RESPIRATORY TRACT, LIVER, KIDNEY, CENTRAL NERVOUS SYSTEM ARE AT A
GREATER THAN NORMAL RISK OF ADVERSE REACTN
* First Aid Measures *
First Aid:EYES: IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER. SEEK
MEDICAL AID. SKIN: WASH THOROUGHLY WITH SOAP AND WATER. IF
IRRITATION PERSISTS, CONTACT A PHYSICIAN. INHALATION: REMOVE TO
FRESH AIR. RESUSCIT ATE IF NECESSARY. SEEK MEDICAL AID. INGESTION:
DO NOT INDUCE VOMITING. GIVE 1 GLASS OF MILK OR 1 TO 2 OZ OF
ACTIVATED CHARCOAL IN WATER TO VICTIM AS TOLERATED. SEEK MEDICAL
AID.
* Fire Fighting Measures *
Flash Point Method:CC
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM
Fire Fighting Procedures:WATER MAY BE INEFFECTIVE. WEAR COMPLETE FIRE
SERVICE PROTECTIVE EQUIPMENT, INCLUDING FULL FACE SCBA. USE WATER
TO COOL FIRE-EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:VAPORS FORM FLAMMABLE/EXPLOSIVE MIXTURES
IN AIR. VAPORS HEAVY MAY TRAVEL TO IGNITION SOURCES AND FLASH. MAY
EMIT IRRITATING/TOXIC GASES IN FIRE CONDITIONS.
* Accidental Release Measures *
Spill Release Procedures:STOP SPILL/LEAK IF NO RISK INVOLVED. AVOID
BREATHING VAPORS. ELIMINATE ALL SOURCES OF IGNITION. VENTILATE
AREA. AVOID CONTACT WITH HOT LIQUID AND FUMES. USE AN INERT
ABSORBENT TO COMPLETE CLEANUP.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:USE WITH ADEQUATE VENTILATION. AVOID
Other Precautions:GROUND AND BOND DRUMS. DO NOT USE PRESSURE TO EMPTY
DRUMS. DO NOT WEAR CONTAMINATED CLOTHING. DISCARD CONTAMINATED
. KEEP AWAY FROM HEAT AND OPEN FLAME.
* Physical/Chemical Properties *
HCC:F3
Vapor Pres:NOT GIVEN
Vapor Density:> 1
Spec Gravity:1.4
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:NEGLIGIBLE
Appearance and Odor:WHITE VISCOUS LIQUID WITH TYPICAL SOLVENT ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, HEAT, SPARKS, AND OPEN FLAMES
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE
* Disposal Considerations *
Waste Disposal Methods:THIS PRODUCT IS A US EPA DEFINED IGNITABLE
HAZARDOUS WASSTE. DISPOSE OF A S AN IGNITABLE HAZARDOUS WASTE IN
ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NOT NEEDED IN NORMAL CONDITIONS OR USES. USE AN
ORGANIC VAPOR CHEMICAL CARTRIDGE OR CANISTER WHEN TLV IS EXCEEDED.
Ventilation:LOCAL EXHAUST OR MECHANICAL(GENERAL) AS REQUIRED TO
MAINTAIN TLV OR BELOW TLV.
Other Protective Equipment:APRONS TO PREVENT CLOTHING/SKIN CONTACT.
Work Hygienic Practices:WASH HANDS WITH SOAP & WATER BEFORE
EATING,SMOKING OR USING TOILET FACILITIES; DO NOT EAT/DRINK IN
VAPOR CONTMNTD AREA.
Supplemental Safety and Health
THESE 3 DEVELOPERS ALSO QUALIFY FOR TYPE I,FORM D; THIS NSN
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III)
Ozone Depleting Chemical:1
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:MAY CAUSE IRRITATION TO
RESPIRATORY SYSTEM,EYES & SKIN.MAY ALSO CAUSE VOMITING.
Effects of Overexposure:INHALATION:CAUSES CENTRAL NERVOUS SYSTEM
DEPRESSION.MAY CAUSE IRRITATION TO RESP TRACT SYSTEM; EYES/SKIN:CAN
CAUSE PAIN,IRRITATION,DISCOMFORT AND/OR DERMATITIS;INGESTION:CAUSE
HEADACHE,NAUSEA,IRRIT TO MOUTH & VOMITING.
* First Aid Measures *
First Aid:INHALATION:REMOVE TO FRESH AIR.IF NOT BREATHING GIVE
ARTIFICIAL RESPIRATION; EYES/SKIN:FLUSH WITH RUNNING WATER FOR AT
ASSISTANCE; INGESTI ON:DO NOT INDUCE VOMITING.NOTHING BY MOUTH IF
VICTIM IS UNCONSCIOUS.GET MEDICAL ASSISTANCE.
* Fire Fighting Measures *
Flash Point:NONE
Lower Limits:7.0
Extinguishing Media:WATER,DRY CHEMICALS,OR CARBON DIOXIDE
Fire Fighting Procedures:WEAR NIOSH APPROVED PRESSURE-DEMAND SELF
CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:VAPORS CONCENTRATED IN A CONFINED AREA OR
POORLY VENTILATED LOCATION CAN BE IGNITED UPON CONTACT WITH HIGH
ENERGY SPARK,FLAME,OR HIGH INTENSITY SOURCE OF HEAT.
* Accidental Release Measures *
Spill Release Procedures:PROVIDE MAXIMUM VENTILATION.DURING CLEAN
UP,WEAR APPROPRIATE PROTECTIVE GEARS TO PROTECT EYES,SKIN & RESP
SYSTEM;RECOVER SPILLED LIQUID WITH ABSORBENTS SUCH AS SAWDUST OR
VERMICULITE.SWEEP INTO CLOSED CONTAINERS.
*Handling and Storage *
Handling and Storage Precautions:KEEP AWAY FROM HEAT/IGNITION SOURCES.
STORE IN DRY,COOL & WELL VENTILATED AREA. DO NOT STORE NEAR
OXIDIZING MATERIALS. AVOID PHYSICAL DAMAGE TO CANS.
Other Precautions:AVOID BREATHING VAPORS. USE ONLY WITH ADEQUATE
VENTILATION. AVOID CONTACT WITH EYES. AVOID REPEATED CONTACT WITH
SKIN.
* Physical/Chemical Properties *
HCC:T4
Solubility in Water:NEGLIGIBLE
Appearance and Odor:MILKY WHITE LIQUID WITH ETHER-LIKE ODOR.
* Stability and Reactivity Data *
OXIDIZING MATERIALS,STRONG ALKALI/BASES
Stability Condition to Avoid:HOT GLOWING SURFACES,OR ELECTRIC ARCS
Hazardous Decomposition Products:HYDROGEN CHLORIDE OR POSSIBLY TRACES
OF PHOSGENS.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN A PERMITTED HAZARDOUS WASTE
MANAGEMENT FACILITY.COMPLY WITH ALL FEDERAL,STATE & LOCAL LAWS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:SCBA IF EXPOSURE LEVELS ARE EXCEEDED.
Ventilation:LOCAL:YES.MECHANICAL:NO.
Other Protective Equipment:WASH THOROUGHLY AFTER CONTACT.
Work Hygienic Practices:WASH THOROUGHLY AFTER CONTACT.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:BENZENE, 1,1'-METHYLENEBIS(ISOCYANATO-
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE HEALTH HAZARDS:INHAL:RUNNY
NOSE,SORE THROAT,COUGHING,CHEST
PAIN.SKIN:REDDENING,SWELLING,RASH,BLISTERING.INGEST:SORE
THROAT,NAUSEA,VOMITING,DIARRHEA.EYE:IRRITAION.
Explanation of Carcinogenicity:PER MSDS:PROD CONTAINS CHEM KNOWN TO BE
CARCINOGEN BY NTP/IARC/OSHA:NO.
Effects of Overexposure:RUNNY NOSE,SORE THROAT,COUGHING,CHEST
PAIN,SKIN-REDDENING,SWELLING,RASH,BLISTERING.INGEST-SORE
THROAT,NAUSEA,VOMITING,DIARRHEA, EYE IRRIT.
* First Aid Measures *
First Aid:INHAL:REMOVE TO FRESH AIR.ADMINISTER CPR IF NEEDED.SEEK MED
ATTN.SKIN:WASH AFFECTED AREA W/SOAP/WATER.IF IRRIT DEVELOPS SEEK
MED ATTN.INGEST:DONT INDUCE VOMIT.GIVE 2 GLASSE OF WATER TO
ATTN.
* Fire Fighting Measures *
Flash Point Method:TCC
Autoignition Temp:Autoignition Temp Text:NP
Extinguishing Media:DRY CHEMICAL,CO2,HIGH EXPANSION CHEM
FOAM.WATERSPRAY FOR LG FIRES.
Fire Fighting Procedures:FULL EMERGENCY EQPMT W/SELF-CONTAINED
BREATHING APPARATUS & FULL PROTECTIVE CLOTHING SHOULD BE WORN.
Unusual Fire/Explosion Hazard:TOXIC VAPORS & GASES MAY BE GENERATED BY
THERMAL DECOMPOSITION OR COMBUSTION.
* Accidental Release Measures *
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:AVOID CONTACT W/SKIN/EYES.AVOID
VAPORS.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
* Physical/Chemical Properties *
HCC:N1
Melt/Freeze Pt:M.P/F.P Text:NA
Decomp Temp:Decomp Text:NP
Vapor Pres:1.4
Vapor Density:8.5
pH:NP
Viscosity:NP
Evaporation Rate & Reference:NA
Solubility in Water:NEGLIGIBLE
Appearance and Odor:DARK BROWN, AROMATIC ODOR
Percent Volatiles by Volume:NEG
Corrosion Rate:NP
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
WATER, AMINES, STRONG BASES, ALCOHOLS.
Stability Condition to Avoid:MOISTURE
Hazardous Decomposition Products:CO2,CARBON MONOXIDE,OXIDES OF
NITROGEN,TRACES OF HCN,MDI VAPORS.
* Disposal Considerations *
Waste Disposal Methods:IAW ALL APLICABLE LOCAL, STATE AND FEDERAL
REGULATIONS.INCINERATION IS PREFERRED METHOD.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR DUST MASK.
Ventilation:LOCAL EXHAUST: AS REQUIRED. MECHANICAL (GENERAL): VENT FAN.
Supplemental Safety and Health
SOLUBILITY IN WATER: POWDERS-APPRECIABLE. LIQUIDS-MISCIBLE.
* Product Identification *
Product ID:TRYPSIN
* Composition/Information on Ingredients *
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY CAUSE SKIN, EYE/RESPIRATORY TRACT
IRRITATION UPON CONTACT. ALLERGIC REACTIONS IN CERTAIN SENSITIVE
INDIVIDUALS MAY DEVELOP.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, ALLERGIC REACTIONS.
Medical Cond Aggravated by Exposure:ALLERGIES, ASTHMA.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. EYES/SKIN: WASH THOROUGHLY
W/WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:AVOID PHYSICAL CONTACT & DUST DURING REMOVAL.
USE NORMAL CLEAN-UP PROCEDURES & WASH THOROUGHLY W/WATER.
*Handling and Storage *
Handling and Storage Precautions:NONE
Other Precautions:NONE
* Physical/Chemical Properties *
Solubility in Water:(SEE SUPP)
Appearance and Odor:POWDERS- WHITE TO TAN. LIQUIDS-WHITE TO BROWN. BOTH
HAVE TYPICAL ENZYME ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
* Disposal Considerations *
Waste Disposal Methods:FLUSH IN SEWERAGE SYSTEM W/WATER IAW/FEDERAL,
STATE & LOCAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . WEAR SUITABLE PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ACETONITRILE-D; (ACETONITRILE-D3)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:HARMFUL BY INHALATION,
INGESTION, SKIN ABSORPTION. VAPOR OR MIST IRRITATING TO EYES,
MUCOUS MEMBRANES AND RESPIRATORY TRACT. POTENTIAL HEALTH
EFFECTS:BEHAVIORAL, GASTROINTESTINAL, DEVELOPMENTAL ABNORMALITIES.
SYMPTOMS OF EXPOSURE:PERSISTANT RUNNY NOSE, WEAKNESS, DIZZINESS,
HEADACHE, NAUSEA. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:CHRONIC:POSSIBLE CORNEAL DAMAGE.
TARGET ORGANS:LIVER, LUNGS, KIDNEYS & BLOOD.
Medical Cond Aggravated by Exposure:
* First Aid Measures *
MINUTES. (SEPARATE EYELIDS W/FINGERS WHEN FLUSHING). INHAL:MOVE
PERSON TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GI VE ARTIFICIAL RESPIRATION. CALL MD. INGEST:WASH OUT
MOUTH W/WATER IF PERSON IS CONSCIOUS. SKIN:IMMEDIATELY WASH W/LOTS
OF SOAP & WATER. WASH CONTAMINATED CLOTHING BEFORE RE-USE.
* Fire Fighting Measures *
Lower Limits:4.4%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE
FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . PREVENT CONTACT W/SKIN & EYES.
Unusual Fire/Explosion Hazard:
* Accidental Release Measures *
Spill Release Procedures:EVACUATE AREA. SHUT OFF IGNITION SOURCES. WEAR
PROTECTIVE EQUIPMENT & CLOTHING. COVER W/ACTIVATED CARBON
ABSORBANT, PLACE IN CLOSED CONTAINER & TRANSPORT OUTDOORS.
VENTILATE AREA & WASH SPILL SITE AFT ER MATERIAL PICKUP IS
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:FLAMMABLE TOXIC LIQUID; POISON. STORE
TIGHTLY CLOSED, IN A COOL, DRY PLACE UNDER NITROGEN. AVOID CONTACT
W/EYES, SKIN & CLOTHING.
Other Precautions:DO NOT BREATHE VAPOR.
* Physical/Chemical Properties *
Solubility in Water:MISCIBLE
Appearance and Odor:COLORLESS LIQUID; AROMATIC ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, ACIDS, REDUCING AGENTS, WATER OR STEAM.
Stability Condition to Avoid:HEAT; IGNITION SOURCES.
Hazardous Decomposition Products:ACETIC ACID, AMMONIA, HYDROGEN
CYANIDE.
* Disposal Considerations *
Waste Disposal Methods:BURN IN A CHEMICAL INCINERATOR W/AFTERBURNER &
SCRUBBER. EXERT EXTRA CARE IN IGNITING AS THIS MATERIAL IS HIGHLY
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR RESPIRATOR.
Ventilation:USE GOOD GENERAL MECHANICAL VENTILATION AND LOCAL EXHAUST.
Other Protective Equipment:EYE BATH AND SAFETY SHOWER SHOULD BE
AVAILABLE.
Work Hygienic Practices:WEAR BREATHING APPARATUS (MSHA/NIOSH APPROVED,
PRESSURE DEMAND, SELF-CONTAINED OR EQUIVALENT) AND FULL PROTECTIVE
GEAR.
Supplemental Safety and Health
NONE
* Product Identification *
Kit Part:Y
Preparer's Name:ERNEST CARTER
* Composition/Information on Ingredients *
Ingred Name:ETHANOL, 2-(DIMETHYLAMINO)-
Ingred Name:DIMETHYLAMINOETHANOL
Ingred Name:ANYHYDRIDE REACTION PRODUCT
* Hazards Identification *
Health Hazards Acute and Chronic:VAPOR OR MIST CAN CAUSE SEVERE
IRRITATION TO THE NOSE AND THROAT. SUBSTANCE CAN BE CORROSIVE TO
EYES AND CAUSES PERMANENT, IRREVERSIBLE EYE INJURY. CORROSIVE TO
SKIN AND CAUSE CHEMICAL BURNS.
Explanation of Carcinogenicity:
Effects of Overexposure:
Medical Cond Aggravated by Exposure:ECZEMA, ALLERGY, EYE CONDITIONS AND
RESPIRATORY DISEASE.
* First Aid Measures *
First Aid:INGESTION: IF SWALLOWED DILUTE WITH WATER OR MILK. SKIN: WASH
AFFECTED AREAS WITH PLENTY OF WATER, AND SOAP IF AVAILABLE, FOR
SEVERAL MINUTES. INHALATION: REMOVE FROM AREA TO FRESH AIR. EYES:
EYELIDS APART TO ENSURE RINSING OF THE ENTIRE EYE SURFACE AND LIDS
WITH WATER.
* Fire Fighting Measures *
Flash Point Method:TCC
Autoignition Temp:Autoignition Temp Text:
Lower Limits:
Upper Limits:
Extinguishing Media:CARBON DIOXIDE, FOAM, DRY CHEMICAL, WATER SPRAY.
Fire Fighting Procedures:USE SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:KEEP FIRE-EXPOSED CONTAINERS COOL WITH
WATER. DO NOT USE A SOLID STREAM OF WATER CAN SPREAD FIRE.
* Accidental Release Measures *
Spill Release Procedures:WEAR FULL PROTECTIVE EQUIPMENT. DIKE AND
ABSORB SPILL WITH INERT MATERIAL (SAND, EARTH, ETC.). TRANSFER TO
CONTAINERS SUITABLE FOR DISPOSAL.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINERS CLOSED WHEN NOT IN
USE. STORE INDOORS IN A COOL, DRY AREA.
Other Precautions:
* Physical/Chemical Properties *
Boiling Pt:B.P. Text:
Melt/Freeze Pt:M.P/F.P Text:
Decomp Temp:Decomp Text:
Vapor Density:AIR=1
Evaporation Rate & Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:SLIGHT
Appearance and Odor:LIQUID AMBER MILD AMMONIACAL
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, MINERAL ACIDS, AND BASES.
Stability Condition to Avoid:ELEVATED TEMPERATURES AND EPOXY RESINS IN
BULK.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, AND
OXIDES OF NITROGEN.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
* Disposal Considerations *
Waste Disposal Methods:MATERIAL IN ACCORDANCE WITH LOCAL, STATE, AND
FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WHERE MIST IS PRESENT, PROVIDE LOCAL VENTILATION
OR A NIOSH/MSHA APPROVED RESPIRATOR CERTIFIED FOR MIST.
Ventilation:USE LOCAL EXHAUST VENTILALTION.
Other Protective Equipment:CLOTHING SUITABLE TO PREVENT SKIN CONTACT.
Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING
W/CHEMICAL.
Supplemental Safety and Health
MATLS TO AVOID:RELEASING HYDROGEN GAS. EYE PROT:MAY ADD FULL LENGTH
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:POTASSIUM HYDROXIDE (SARA III)
Fraction by Wt: <1%
OSHA PEL:C, 2 MG/M3
Ingred Name:WATER
Ingred Name:POTASSIUM BORATES
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ALKALINE SOLUTION. MAY CAUSE SEVERE
IRRITATION OR CAUSTIC BURNS TO EYES AND MUCOUS MEMBRANES. SOLUTION
4-HOUR RABBIT SKIN TEST OF HIGHES T COMMERCIAL CONCENTRATION OF
PRODUCT WAS NEGATIVE FOR CORROSION.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHAL:CALL MD IF IRRITATION OF RESP PASSAGES OCCURS.
SKIN:IMMED REMOVE CONTAMD CLTHG & WASH AFFECTED AREA. CALL MD IF
IRRIT OCCURS. INGEST:IF CONSCIOUS, GIVE WATER OR MILKTO DILUTE
STOMACH CONTENTS. DO NOT INDUCE VOMITING. CALL MD.
* Fire Fighting Measures *
Extinguishing Media:NON-FLAMMABLE - COMPATIBLE WITH EXTINGUISHING
AGENTS.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
* Accidental Release Measures *
Spill Release Procedures:WEARING APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT, CONTAIN SPILL, COLLECT ONTO INERT ABSORBENT. PLACE IN
SUITABLE CONTAINER. RINSE RESIDUAL W/WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
* Physical/Chemical Properties *
HCC:C2
Evaporation Rate & Reference:ABOUT SAME AS WATER.
Solubility in Water:SOLUBLE.
Appearance and Odor:COLORLESS LIQUID, LITTLE OR NO ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS. PROD EXPECTED, BY TEST/ANALOGY, TO SLOWLY ATTACK
ALUMINUM/PERHAPS OTHER NONFERROUS METALS, (SEE SUPP DATA)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:PROD EXPECTED, BY TEST OR ANALOGY, TO
SLOWLY ATTACK ALUMINUM & PERHAPS OTHER NONFERROUS METALS, RELEASING
HYDROGEN GAS.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF OR INCINERATE I/A/W REGULATIONS.
PRODUCT WOULD BE CONSIDERED A HAZARDOUS WASTE UNDER CERCLA DUE TO
HIGH PH UNLESS NEUTRALIZED PRIOR TO DISPOSAL.
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Control Measures
*
*
Preparer Co. when other than Responsible Party Co.
*
*
Contractor Summary
*
*
Ingredients
*
Other REC Limits: 5 MG/M3 RESP DUST
------------------------------
% Wt: <2
OSHA PEL: 5 MG/CUM
------------------------------
% Wt: <5
ACGIH TLV: 0.1 MG/CUM RESP DUST
------------------------------
% Wt: <2
------------------------------
------------------------------
Other REC Limits: 2.5 MG/CUM (AS F)
OSHA PEL: 2.5 MG/CUM (AS F)
ACGIH TLV: 2.5 MG/CUM (AS F)
------------------------------
% Wt: <5
------------------------------
-----------------------------
% Wt: 1-5
OSHA PEL: 5 MG/CUM
ACGIH TLV: 5 MG/CUM (DUST)
------------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: SHORT TERM EXPOSURE TO WELDING FUMES: DIZZINESS, NAUSEA,
DRYNESS/IRRITATION OF NOSE/THROAT/LUNGS/EYES. LONG TERM EXPOSURE TO WELDING
FUMES: RESPIRATORY PROBLEMS, IRON BUILD-UP IN THE LUNGS, BONE EROSI ON,
REDUCED PULMONARY FUNCTIONS & NERVOUS DISORDERS.
Explanation Of Carcinogenicity: SEE INGREDIENTS.
Signs And Symptions Of Overexposure: SHORT TERM EXPOSURE TO WELDING FUMES:
DIZZINESS, NAUSEA, DRYNESS/IRRITATION OF NOSE/THROAT/LUNGS/EYES. LONG TERM
EXPOSURE TO WELDING FUMES: RESPIRATORY PROBLEMS, IRON BUILD-UP IN THE LUNGS,
BONE EROSI ON, REDUCED PULOMARY FUNCTIONS & NERVOUS DISORDERS.
Medical Cond Aggravated By Exposure: PRE-EXISTING RESPIRATORY/ALLERGIC
CONDITONS.
First Aid: IF OVERCOME BY SMOKE/FUMES, REMOVE VICTIM TO FRESH AIR & EMPLOY
FIRST AID TECHNIQUES RECOMMENDED BY THE RED CROSS. OBTAIN LATTENTION IN
ALL CASES.
*
Handling and Disposal
*
Waste Disposal Methods: PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER/LINER IN AN
ENVIRONMENTALLY ACCEPTABLE MANNER IAW/LOCAL, STATE & FEDERAL REGULATIONS.
Handling And Storage Precautions: MONITOR THE AIR TO ENSURE THE LEVELS ARE
<THE RECOMMENDED LIMITS. WEAR APPROPRIATE EQUIPMENT TO PREVENT INJURY FROM
RADIATION/SPARKS/ELECTRIC SHOCK.
Other Precautions: TRAIN WELDER NOT TO TOUCH LIVE ELECTRICAL PARTS &
INSULATE THEMSELVES FROM WORK & GROUND.
*
Fire and Explosion Hazard Information
*
Flash Point Text: NON-FLAMMABLE
Unusual Fire/Explosion Hazard: WELDING ARC & SPARKS CAN IGNITE COMBUSTIBLE
& FLAMMABLE PRODUCTS.
*
*
Respiratory Protection: WEAR RESPIRABLE FUME RESPIRATOR/AIR SUPPLIED RESPIRATOR
WHEN WELDING IN CONFINED SPACE, WHERE LOCAL EXHAUST/VENTILATION DOES NOT KEEP
EXPOSURE <TLV.
Ventilation: LOCAL EXHAUST AT ARC TO KEEP FUMES/GASES <TLV IN WORKERS
BREATHING ZONE & GENERAL AREA.
Other Protective Equipment: ARM PROTECTOR, APRON, HAT, SHOULDER PROTECTION,
DARK SUBSTANTIAL CLOTHING.
Supplemental Safety and Health: PRODUCT IS NON-HAZARDOUS UNTIL USED AS IN
WELDING PURPOSES. THE COMPOSITION & QUANTITY OF FUMES/GASES DEPENDS ON
METAL BEING WELDED, PROCESS, PROCEDURES, ELECTRODES USED, COATINGS, POSITION
OF WELDERS HEAD W/RESPECT TO THE PLUME & AS WELL AS THE PRESENCE OF
CONTAMINANTS IN THE ATMOSPHERE.
*
Physical/Chemical Properties
*
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: WELDING ARCS & SPARKS CAN IGNITE COMBUSIBLES &
FLAMMABLE PRODUCTS.
Materials To Avoid: (SEE SUPPLEMENTAL DATA)
Hazardous Decomposition Products: OXIDES OF IRON, MANGANESE, SILICON, CHROMIUM,
NICKEL, MOLYBDENUM, CALCIUM, MAGNESIUM, TITANIUM (SEE SUPP)
Hazardous Polymerization Indicator: NO
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Company Name: HOBART BROTHERS CO
Label Required IND: Y
Status Code: A
Origination Code: G
Hazard And Precautions: SHORT TERM EXPOSURE TO WELDING FUMES: DIZZINESS,
NAUSEA, DRYNESS/IRRITATION OF NOSE/THROAT/LUNGS/EYES. LONG TERM EXPOSURE TO
WELDING FUMES: RESPIRATORY PROBLEMS, IRON BUILD-UP IN THE LUNGS, BONE EROSI
ON, REDUCED PULMONARY FUNCTIONS & NERVOUS DISORDERS.
*
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE NORMALLY REQUIRED. USE NIOSH APPROVED
SELF-CONTAINED BREATHING APPARATUS IF TLV IS EXCEEDED OR WHEN
SPRAYING OR USING IN CONFINED SPACES.
Ventilation:USE THIS MATERIAL ONLY IN WELL VENTILATED AREAS.
Other Protective Equipment:WEAR PROTECTIVE CLOTHINGS.
Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER HANDLING THIS
PRODUCT.
Supplemental Safety and Health
NONE
* Product Identification *
Product ID:DIESEL FUEL;NO. 2 DIESEL FUEL;NO. 2 OIL;NO.
CAGE:PRIMA
CAGE:PRIMA
* Composition/Information on Ingredients *
Ingred Name:DISTILLATES,STREIGHT RUN MIDDLE
Other REC Limits: RECOMMENDED
Ingred Name:SATURATED HYDROCARBONS
Other REC Limits: RECOMMENDED
Ingred Name:UNSATURATED HYDROCARBONS
Fraction by Wt: 1-6%
Other REC Limits: RECOMMENDED
Ingred Name:AROMATIC HYDROCARBONS
Other REC Limits: RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES:IRRITATION. SKIN:SKIN IRRITANT.
INHALATION:LUNG IRRITATION, CNS EFFECTS. INGESTION:PRACTICALLY
NON-TOXIC TO INTERNAL ORGANS. HOWEVER, IF ASPIRATED INTO LUNGS IT
MAY CAUSE CHEMICAL PNEUMONITIS WHI CH CAN BE FATAL. CHRONIC:MIDDLE
DISTILLATE HAS CAUSED SKIN CANCER WHEN REPEATEDLY APPLIED TO MICE
OVER LIFETIME,KIDNEY.
Explanation of Carcinogenicity:WHOLE DIESEL ENGINE EXHAUST IS LISTED AS
A PROBABLE CARCINOGEN BY IARC AND NIOSH.
Effects of Overexposure:SKIN:IRRITAION, DRYING EFFECT. INHALATION:
HEADACHE, DIZZINESS, LOSS OF APPETITE, WEAKNESS AND LOSS OF
COORDINATION.
Medical Cond Aggravated by Exposure: SPECIFIED BY MANUFACTURER.
* First Aid Measures *
CONTAMINATED CLOTHING. WASH SKIN THOROUGHLY WITH SOAP AND WATER.
SEE A DOCTOR IF SYMPTOMS DEVELOP. INHALATION: REMOVE TO FRESH AIR.
INGESTION:GIVE WATER OR MILK TO DRINK AND GET IMMEDIATE MEDICAL
ATTENTION. DO NOT MAKE PERSON VOMIT UNLESS DIRECTED TO DO SO BY
MEDICAL PERSONNEL.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:0.7
Upper Limits:5.0
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. EVACUATE AREA. COOL
FIRE EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS. LIQUID EVAPORATES AND
FORMS VAPORS WHICH CAN CATCH FIRE WITH VIOLENT BURNING
* Accidental Release Measures *
Spill Release Procedures:THIS MATERIAL IS CONSIDERED TO BE A WATER
POLLUTANT AND RELEASES OF THIS PRODUCT SHOULD BE PREVENTED.
ELIMINATE ALL OPEN FLAMES. STOP SOURCE OF THE LEAK. CONTAIN LIQUID.
CLEAN UP SPILL USING APPROPRIA TE TECHNIQUES SUCH AS ABSORBENT
MATERIALS.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL AREA. KEEP CONTAINER
LID TIGHTLY CLOSED.
Other Precautions:DO NOT INHALE VAPORS OR EXHUST FUMES, AVOID SKIN
CONTACT.
* Physical/Chemical Properties *
HCC:F4
Vapor Pres:1
Vapor Density:4-5
Spec Gravity:0.8
Viscosity:1.9 CST
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR LIGHT AMBER LIQUID, FUEL OIL ODOR
Percent Volatiles by Volume:NIL
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:TOXIC CARBON MONOXIDE AND CARBON
DIOXIDE, AND SULFUR DIOXIDE.
* Disposal Considerations *
Waste Disposal Methods:PLACE CONTAMINATED MATERIALS IN DISPOSABLE
CONTAINERS AND DISPOSE OF IN A MANNER CONSISTENT WITH APPLICABLE
REGULATIONS. CANTACT LOCAL ENVIRONMENTAL OR HEALTH AUTHORITIES FOR
APPROVED DISPOSAL OF THIS MATERIAL.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE
Ventilation:NONE
Other Protective Equipment:NONE
Work Hygienic Practices:WASH HANDS
Supplemental Safety and Health
* Product Identification *
Product ID:DILUENT FOR ALLERGENIC EXTRACTS
* Composition/Information on Ingredients *
Ingred Name:GLYCERINE, 1,2,3,-TRIHYDROXYPROPANE, GLYCEROL, ANHYDROUS
GLYCERINE, GLYCERIN
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Explanation of Carcinogenicity:NONE
* First Aid Measures *
First Aid:OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point:NON-FLAMMABLE
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:WIPE UP. WASH W/SOAP & WATER.
*Handling and Storage *
Handling and Storage Precautions:NONE
* Physical/Chemical Properties *
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, COLORLESS, ODORLESS
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
* Disposal Considerations *
Waste Disposal Methods:SECURE LANDFILL/INCINERATE IN ACCORDANCE
W/LOCAL, STATE & FEDERAL REGULATIONS.
| 0 | gloves_not_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:SCBA IF INVOLVED IN FIRE, OTHERWISE GAS MASK.
Ventilation:PROVIDE MECHAN(GEN/LOCAL EXHAUST)VENT TO MAINTN <TLV
Other Protective Equipment:EYE WASH STATION. APRONS. SPECIAL IMPERVIOUS
CLOTHING.
Supplemental Safety and Health
BY DGSC-STF.
* Product Identification *
* Composition/Information on Ingredients *
* Hazards Identification *
Effects of Overexposure:HAZ DEGREE DEPENDS ON TYPE/QUANT OF RADIATION.
LATENT EFFECTS:SOMATIC/GENETIC DAMAGE.
* First Aid Measures *
First Aid:USE FIRST AID. CALL MEDICAL EMERGENCY CARE. REMOVE/ISOLATE
COMTAMINATED CLOTHING.SHOWER VICTIM(S) W. SOAP & H*2O. DETAIN
PERSONNEL/EQUIPMENT EXPOSED. ADVISE MEDICAL PERSONNEL THAT
VICTIM(S) MAY BE CON TAMINATED.
* Fire Fighting Measures *
Extinguishing Media:EXTINQUISH W. AGENT SUITABLE FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR CHEMICAL PROTECTIVE SUIT WITH SELF CONTD
BRTHG APP.
Unusual Fire/Explosion Hazard:SOME OF MATL MAY BURN. CONT MAY EXPLODE
IN HEAT OF FIRE.
* Accidental Release Measures *
*Handling and Storage *
Handling and Storage Precautions:SHIELD ACCORDING TO EMITTED RADIATION.
PROTECT FROM FILM/FILM PLATES. KEEP CONTAINERS CLOSED. STORE IN
AREA FOR RADIOACTIVE MATERIALS.
* Physical/Chemical Properties *
HCC:A3
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ISOLATE,SEGREGATE FROM MOST OTHER TYPE MATERIAL
Hazardous Decomposition Products:DEPENDS ON CHEMICAL COMPOSITION;
FISSION PRODUCTS
* Disposal Considerations *
Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-IN ACCORDANCE WTH
DOD REGULATIONS AND FEDERAL,STATE & LOCAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE REQUIRED. USE NIOSH APPROVED RESPIRATOR
APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:N/P. EXPOSURE LIMITS: NONE.
Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER .
SPECIAL CLOTHING AND EQUIPMENT: NOT REQUIRED.
Work Hygienic Practices:NOTE: AGAROSE IS GENERALLY USED AFTER
DISSOLUTION BY BOILING. SAFETY PRECAUTIONS FOR THIS STEP ARE
AVAILABLE FROM FMC UPON REQUEST.
Supplemental Safety and Health
FICIENT: NO DATA AVAILABLE.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:HYDROXYETHYL (DERIVATIZED) AGAROSE
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY IRRITATE EYES. ALSO, SEE
TOXICOLOGICAL INFORMATION.
Effects of Overexposure:SEE HEALTH HAZARDS.
* First Aid Measures *
First Aid:EYES: FLUSH W/PLENTY OF WATER. GET MEDICAL ATTENTION IF
IRRITATION OCCURS AND PERSISTS. SKIN: WASH WITH PLENTY OF SOAP AND
WATER. GET MEDICAL ATTENTION IF IRRITATION OCCURS AND PERSISTS.
INHAL: REMOVE TO FRESH AIR. IF BREATHING DIFFICULTY OR DISCOMFORT
OCCURS AND PERSISTS, OBTAIN MEDICAL ATTENTION. INGESTION: DRINK
PLENTY OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. IF ANY DISC OMFORT PERSISTS, OBTAIN MEDICAL ATTENTION. NOTE
TO MD: HYDROXYETHYL AGAROSE HAS LOW ORAL TOXICITY AND MAY BE
MINIMALLY IRRITATING TO EYES. TREATMENT IS CONTROLLED REMOVAL OF
EXPOSURE FOLLOWED BY SYMPT OMATIC AND SUPPORTIVE CARE.
* Fire Fighting Measures *
Lower Limits:SUPDAT
Upper Limits:SUPDAT
Extinguishing Media:WATER, CARBON DIOXIDE OR DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:FINE, AIRBORNE ORGANIC DUSTS AT OR ABOVE
IGNITION SOURCE. BURNING MAY PRODUCE CARBON MONOXIDE AND/OR CARBON
DIOXIDE. EXPLOSIVE PROPERT IES: NOT APPLICABLE. OXIDIZING
PROPERTIES: NOT OXIDIZING.
* Accidental Release Measures *
Spill Release Procedures:SWEEP UP POWDER. COLLECT AND PLACE IN SOLID
TRASH. DISPOSE OF IN SOLID TRASH IN ACCORDANCE WITH APPROPRIATE
LOCAL STATE/PROVINCIAL AND FEDERAL/NATIONAL REGULATIONS FOR INERT,
NUISANCE WASTE MATERIAL. AVOID CONTACT WITH SKIN AND EYES.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED
PLACE.
* Physical/Chemical Properties *
Appearance and Odor:WHITE, AMORPHOUS POWDER; NO ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
CONTACT WITH STRONG OXIDANTS AND ACIDS.
Hazardous Decomposition Products:WILL NOT OCCUR.
* Toxicological Information*
Toxicological Information:SKIN CONTACT: NO DATA AVAILABLE. SKIN
ABSORPTION: NO DATA AVAILABLE. INHALATION: NO DATA AVAILABLE.
OVEREXPOSURE: THIS MATERIAL IS EXPECTED TO HAVE LOW ORAL TOXICITY
AND MAY BE IRRITATING TO THE EYES. A RELATED MATERIAL, AGAR, IS
GENERALLY RECOGNIZED AS SAFE (GRAS) BY THE US FOOD AND DRUG
ADMINISTRATION. CHRONIC EFFECTS FROM OVEREXPOSURE: NO DATA
AVAILABLE FOR THE FORMULATION. AGAR, A RELATED MATERIAL, WAS
NEGATIVE IN A NTP CARCINOGENISIS RODENT BIOASSAY.
* Ecological Information *
Ecological:ENVIRONMENTAL FATE: NO DATA AVAILABLE. ENVIRONMENTAL
EFFECTS: NO DATA AVAILABLE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF POWDER OR GEL IN SOLID TRASH. DISPOSE
OF SOLID TRASH IN ACCORDANCE WITH APPROPRIATE LOCAL,
STATE/PROVINCIAL AND FEDERAL/NATIONAL REGULATIONS FOR INERT,
NUISANCE WASTE MATERIAL.
* MSDS Transport Information *
FEDERAL REGULATIONS AS A HAZARDOUS MATERIAL. UN: NOT APPLICABLE.
MARPOL DESIGNATION: NONE. CANADA (TDG): NOT APPLICABLE.
* Regulatory Information *
SARA Title III Information:US SARA TITLE III: NOT LISTED. SECTION
Federal Regulatory Information:THIS DOCUMENT HAS BEEN PREPARED TO MEET
REQUIREMENTS. US TSCA INVENT ORY: LISTED. CANADA WHMIS: NOT A
CONTROLLED PRODUCT UNDER THE CANADIAN WORKPLACE HAZARDOUS MATERIALS
INFORMATION SYSTEM (WHMIS). EEC FINECS NO: NONE. EEC RISK PHRASES:
NOT CLASSIFIED AS DANGEROUS. EEC SYMBOLS: NOT CLASSIFIED AS
DANGEROUS. EEC SAFETY ADVISE PHRASES: NOT CLASSIFIED AS DANGEROUS.
ADDIT IONAL REGULATORY INFORMATION: NONE.
DOES NOT CONTAIN ANY CHEMICALS CURRENTLY ON THE CALIFORNIA LIST OF
KNOWN CARCINOGENS AND REPRODUCTIVE TOXINS.
* Other Information *
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION
EXPOSURES BELOW PEL, USE NIOSH APPROVED CANISTER-TYPE RESPIRATOR.
IN CONFINED OR POORLY VENTILATED AREAS OR FOR EMERGENCY USE AN
APPROVED POSITIVE-PRESSURE, SELF CONTAINED BREATHING APPARATUS.
Ventilation:MECHANICAL (GENERAL) VENTILATION IS USUALLY ADEQUATE. LOCAL
EXPLOSION PROOF EXHAUST VENTILATION MAY BE NEEDED.
Other Protective Equipment:SAFETY SHOWER AND EYE BATH. INDUSTRIAL TYPE
WORK CLOTHING AND APRON AS REQUIRED TO AVOID PROLONGED OR REPEATED
CONTACT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING OR DRINKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
PRODUCT UNDER THE FOLLOWING P/N IND: A, B, C, D OR E ARE LISTED IN
* Product Identification *
Preparer's Name:SHEREE L. KINZEL
* Composition/Information on Ingredients *
Ingred Name:WHITE MINERAL OIL
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE-EYES:IRRITANT.
SKIN:IRRITANT/DERMATITIS. INHALE:THROAT/LUNGS IRRITANT.
INGEST:NONFATAL UNLESS ASPIRATION OCCURS. CHRONIC-EYES:IRRITANT.
SKIN:DERMATITIS. INHALE:NON-SPECIFIC SYMPTOMS RELATED TO T HE
NERVOUS SYSTEM, GASTROINTESTINAL TRACT & LUNG. INGEST:BURNING
THROAT, UNCONSCIOUSNESS, CONVULSIONS FOLLOWED BY DEATH.
Explanation of Carcinogenicity:NONE OF THE CHEMICALS IN THIS PRODUCT IS
LISTED BY IARC, NTP OR OSHA AS A CARCINOGEN.
Effects of Overexposure:EYES:IRRITATION. SKIN:DRYNESS, CHAPPING, AND
REDDENING. INHALE:IRRITATION OF THROAT AND LUNGS.
INGEST:DROWSINESS, DULLNESS, NUMBNESS AND HEADACHE FOLLOWED BY
DIZZINESS, WEAKNESS AND NAUSEA.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
CONDITIONS MAY BE AT INCREASED RISK FROM EXPOSURE.
* First Aid Measures *
MINUTES. SEE DOCTOR. SKIN: WASH WITH SOAP AND WATER. INHALATION:
REMOVE TO FRESH AIR. IF NOT BREATHING GIVE CPR. IF BREATHING HARD,
GIVE OX YGEN. KEEP WARM & AT REST. SEE DOCTOR. INGESTION: DO NOT
INDUCE VOMITING. IF CONSCIOUS, GIVE LARGE AMOUNTS OF WATER. SEE
DOCTOR.
* Fire Fighting Measures *
Flash Point Method:PMCC
Lower Limits:1.1
Upper Limits:6.0
Extinguishing Media:USE CARBON DIOXIDE, FOAM, OR DRY CHEMICAL.
Fire Fighting Procedures:WATER CAN BE USED TO COOL CNTNRS EXPOSED TO
HEAT/FLAME. USE CAUTION WITH WATER/FOAM AS FROTHING MAY OCCUR,
ESPECIALLY IF SPRAYED IN CNTNR OF HOT BURNING LIQUID.
Unusual Fire/Explosion Hazard:DENSE SMOKE MAY BE GENERATED WHILE
BURNING. CARBON MONOXIDE, CARBON DIOXIDE AND OTHER OXIDES MAY BE
GENERATED AS PRODUCTS OF COMBUSTION.
* Accidental Release Measures *
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. ABSORB SMALL SPILL
WITH NON-COMBUSTIBLE INORGANIC MATERIAL OR DIKE TO RETAIN LARGE
SPILL. PLACE WASTE IN DOT APPROVED CONTAINER FOR DISPOSAL.
*Handling and Storage *
Handling and Storage Precautions:STORAGE-KEEP COOL, DRY & AWAY FROM
IGNITION SOURCES. KEEP FROM DIRECT SUNLIGHT, HIGH TEMP. OR BELOW
FREEZING AREAS. KEEP CONTAINER TIGHTLY CLOSED.
Other Precautions:PROTECT FROM PHYSICAL DAMAGE. USE AND STORE WITH
ADEQUATE VENTILATION. DO NOT CUT, GRIND, WELD OR DRILL ON OR NEAR
THIS CONTAINER. GROUND ALL EQUIPMENT. WASH THOROUGHLY AFTER USE.
* Physical/Chemical Properties *
HCC:N1
Evaporation Rate & Reference:<1
Solubility in Water:MODERATE
Appearance and Odor:FLUORESCENT YELLOW GREEN MOBILE LIQUID. MILD ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:CARBON DIOXIDE AND CARBON MONOXIDE
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | gloves_mandatory |
Control Measures
*
Product ID: SEPTI-KLEEN
Proprietary Ind: Y
*
Preparer Co. when other than Responsible Party Co.
*
*
Contractor Summary
*
*
Ingredients
*
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYES: IRRITATION. SKIN: DERMATITIS UPON PROLONGED OR
REPEATED CONTACT W/PRODUCT.
Explanation Of Carcinogenicity: NONE
Medical Cond Aggravated By Exposure: SENSITIVITY
First Aid: EYES: FLUSH W/LARGE AMOUNTS OF WATER. SKIN: WASH THOROUGHLY W/SOAP
& WATER UNTIL SLICK FEELING IS GONE. REMOVE CONTAMINATED CLOTHING &
LAUNDER BEFORE USE. INGESTION: GIVE LARGE QUANTITIES OF WATER. DO N'T INDUCE
VOMITING. IF VOMITING OCCURS, GIVE ADDITIONAL FLUIDS. NEVER GIVE ANYTHING BY
MOUTH IF UNCONSCIOUS. INHALATION: REMOVE TO FRESH AIR. IF NECESSARY, GIVE
OXYGEN. OBTAIN MEDICAL ATTENTION.
*
Handling and Disposal
*
Spill Release Procedures: ONLY TRAINED PERSONNEL EQUIPPED W/PROPER PROTECTIVE
GEAR SHOULD BE PERMITTED IN AREA. STOP SPILL AT SOURCE. COLLECT ANY POSSIBLE
MATERIAL FOR REUSE. AFTER ALL VISIBLE TRACES HAVE BEEN REMOVED, FLUSH A REA
THOROUGLY W/FRESH WATER.
Waste Disposal Methods: DISPOSE OF ALL WASTE IN ACCORDANCE
W/LOCAL/STATE/FEDERAL REGUALTIONS. CARE MUST BE TAKEN IN DISPOSAL OF
PRODUCT/CONTAINER TO PREVENT ENVIRONMENTAL CONTAMINATION. COMBUSTIBLE.
Handling And Storage Precautions: KEEP OUT OF REACH OF CHILDREN. ALL PRODUCT
CONTAINERS MUST BE LABELED. CLOSE CONTAINER AFTER EACH USE. STORE AWAY FROM
IGNITION SOURCES.
THAT MAY BE CONTAMINATED W/PRODUCT. NEVER USE WELDING/CUTTING TORCH ON EMPTY
DRUM.
*
Fire and Explosion Hazard Information
*
Flash Point Method: CC
Extinguishing Media: WATER, FOAM, DRY CHEMICAL, CO2
Fire Fighting Procedures: WEAR SELF-CONTAINED, POSITIVE PRESSURE BREATHING
APPARATUS & FULL FIRE FIGHTING CLOTHING.
Unusual Fire/Explosion Hazard: VAPORS MAY TRAVEL ALONG GROUND/MOVE BY
VENTILATION/IGNITE BY IGNITION SOURCE DISTANT FROM HANDLING POINT.
COMBUSTIBLE.
*
*
Respiratory Protection: REQUIRED IF TLV OF PRODUCT/COMPONENT THEREOF IS
EXCEEDED.
Ventilation: LOCAL EXHAUST
Other Protective Equipment: IMPERVIOUS CLOTHING, EYE WASH FOUNTAIN
Work Hygienic Practices: WASH HANDS THOROUGHLY BEFORE
EATING/DRINKING/SMOKING/USING TOILET FACILITIES.
*
Physical/Chemical Properties
*
Spec Gravity: 1
PH: 7-9
Solubility in Water: COMPLETE
Appearance and Odor: DARK BLUE LIQUID, POWDERY ODOR.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: IGNITION SOURCES
Hazardous Polymerization Indicator: NO
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Product ID: SEPTI-KLEEN
Company Name: CH2O INC
Street: UNKNOWN
Label Required IND: Y
Status Code: C
Origination Code: F
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: Moderate
Reactivity Hazard: Slight
Hazard And Precautions: EYES: IRRITATION. SKIN: DERMATITIS UPON PROLONGED OR
REPEATED CONTACT W/PRODUCT. TARGET ORGANS: EYES, SKIN.
INHALATION: IRRITATION OF THE NOSE & THROAT. SKIN: MILD IRRITATION, DERMA
TITIS. EYES: IRRITATION, CONJUNCTIVITIS, INCREASED CORNEAL PERMEABILITY. INGE
*
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NOT REQUIRED IF LOCAL VENTILATION IS ADEQUATE.
NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN
.
Ventilation:VAPORS AND FUMES LIBERATED DURING HOT PROCESSING SHOULD BE
EXHAUSTED FROM WORK AREAS TO MAINTAIN HYDROGEN (ING 4)
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
CAUSE SEVERE BURNS, SOMETIMES W/SYMPS DELAYED FOR SEVERAL HOURS .
HNDLG PARTS/EQUIP AFTER EXPOS TO SUCH HIGH (ING 2)
* Product Identification *
Preparer's Name:W. H. MARTIN
* Composition/Information on Ingredients *
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SUPP DATA:TEMPS. IF CONDENSATE IS EXPECTED, WASH EQUIP &
PARTS WELL W/LIMEWATER (CALCIUM HYDROXIDE SOLN). (ING 3)
Ingred Name:VENT:FLUORIDE CONCENTRATION BELOW OSHA PEL OF 3 PPM.
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:INGEST:NOT PROBABLE ROUTE OF
EXPOSURE. LOW TOXICITY. SKIN:PROLONGED CONTACT MAY PRODUCE SKIN
IRRITATION. AVOID SKIN CONTACT. EYE:MECHANICAL IRRITATION.
INHAL:TOXIC AND CORROSIVE HYDROGEN FLUORID E MAY BE LIBERATED
CONTAMINATED W/ (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:RESIN DUST. THESE VAPORS CAN IRRITATE
THE EYES, NOSE, THROAT, AND LUNGS. LUNG EFFECTS MAY BE DELAYED FOR
SEVERAL HOURS. CHRONIC:NONE KNOWN.
Medical Cond Aggravated by Exposure:NONE KNOWN.
* First Aid Measures *
First Aid:INHAL:MOVE TO FRESH AIR. CALL MD IF SYMPTOMS PERSIST.
SKIN:WASH WITH SOAP & WATER. IF MOLTEN POLYMER CONTACTS SKIN, COOL
RAPIDLY WITH COLD WATER. DO NOT ATTEMPT TO PEEL POLYMER FROM SKIN.
GET MD FOR T HERMAL BURN. EYE:FLUSH WITH PLENTY OF WATER. CALL MD
IF SYMPTOMS PERSIST. INGEST:CALL MD IMMEDIATELY .
* Fire Fighting Measures *
Flash Point Method:OC
Extinguishing Media:WATER, CARBON DIOXIDE, FOAM, DRY CHEMICALS.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . DOES NOT BURN W/OUT AN EXTERNAL FLAME.
Unusual Fire/Explosion Hazard:PELLET FORM MAY ACCUMULATE STATIC CHARGE
WHEN POURED FROM ONE CONTAINER TO ANOTHER.
* Accidental Release Measures *
Spill Release Procedures:SWEEP UP TO PREVENT SLIPPING HAZARDS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL DRY PLACE. KEEP
CONTAINERS TIGHTLY CLOSED TO PREVENT MOISTURE ABSORPTION AND
CONTAMINATION.
Other Precautions:DO NOT TOUCH DECOMPOSED PARTS OF VITON EVEN WHEN
COOL. PROVIDE GROUNDING OF EQUIPMENT WHEN HANDLING PELLET FORM TO
PREVENT STATIC BUILDUP. AVOID CONTAMINATION OF CIGARETTES OR
TOBACCO WITH POLYMER DUS T.
* Physical/Chemical Properties *
HCC:N1
Solubility in Water:INSOLUBLE
Appearance and Odor:PELLETS, CHIPS OR SHEETS; NO ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
COMPOUNDING WITH FINELY DIVIDED METALS SUCH AS ALUMINUM PRESENTS AN
EXPLOSION HAZARD.
PRECAUTIONS (SUPDAT)
Hazardous Decomposition Products:HYDROGEN FLUORIDE (HF) AND
PERFLUOROOLEFINS. THE OSHA PEL FOR HF IS 3 PPM. IF VITON IS USED OR
TESTED AT TEMPS (SUPDAT)
* Disposal Considerations *
Waste Disposal Methods:LANDFILL OR INCINERATE IN COMPLIANCE WITH
FEDERAL, STATE AND LOCAL REGULATIONS. INCINERATION REQUIRES
SCRUBBING OF GASEOUS PRODUCTS TO REMOVE HYDROGEN FLUORIDE.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:BUREAU OF MINES APPROVED MASK
Ventilation:MECHANICAL SUFFICIENT TO KEEP AIR SUPPLY ABOVE TLV
Other Protective Equipment:HYPERSENSITIVE PERSONS SHOULD USE PROTECTIVE
CREAM.
Supplemental Safety and Health
ACETATE (5.5%).
* Product Identification *
Product ID:ACRYLOIDS
CAGE:USPAI
CAGE:USPAI
* Composition/Information on Ingredients *
Ingred Name:2-ETHOXYETHYL ACETATE (CELLOSOLVE ACETATE) (EGEEA)
Fraction by Wt: 8.1%
Ingred Name:2-NITROPROPANE (SARA III)
Fraction by Wt: 3.0%
Ingred Name:TOLUENE (SARA III)
Fraction by Wt: 8.1%
Ingred Name:N-BUTYL ALCOHOL (SARA III)
Fraction by Wt: 1.1%
Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)
* Hazards Identification *
Effects of Overexposure:NARCOSIS IN ENCLOSED AREA.
* First Aid Measures *
First Aid:IF EXPOSED TO EXCESSIVE VAPORS, REMOVE TO FRESH AIR AND SEEK
MEDICAL ATTENTION. IF SPLASHED IN EYES, FLUSH WITH WATER AND SEEK
IMMEDIATE MEDICAL ATTENTION.
* Fire Fighting Measures *
Lower Limits:1.0
Upper Limits:7.0
Extinguishing Media:DRY CHEMICAL OR FOAM
Fire Fighting Procedures:NA
Unusual Fire/Explosion Hazard:DO NOT EXPOSE TO SPARK OR OPEN FLAME.
* Accidental Release Measures *
Spill Release Procedures:AFFECTED AREA SHOULD BE TREATED WITH AN
ABSORBING COMPOUND AND THEN MATERIAL PLACED A TIGHTLY CLOSED
CONTAINER.
*Handling and Storage *
Handling and Storage Precautions:KEEP AWAY FROM HEAT SPARKS, AND
FLAMES.
* Physical/Chemical Properties *
HCC:F3
Vapor Density:>AIR
Spec Gravity:1.1
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:NO
Appearance and Odor:NOT OBNOXIOUS
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NA
Stability Condition to Avoid:EXTENSIVE BREATHING
Hazardous Decomposition Products:NONE
Conditions to Avoid Polymerization:EXCESS HEAT AND/OR OXIDIZING
MATERIALS
* Disposal Considerations *
Waste Disposal Methods:IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
ENVIRONMENTAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WHEN SPRAYING THIS MATL USE NIOSH/MSHA APPRVD
CARTRIDGE RESP OR NIOSH/MSHA APPRVD GAS MASK SUITABLE TO KEEP
AIRBORNE MISTS & VAPOR CONC BELOW TIME WEIGHTED THRESHOLD LIMIT
VALUES. WHEN USING IN POORLY VENTILATED & CONFINED SPACES (SUPDAT)
Ventilation:MAINTAIN GOOD VENTILATION TO KEEP PRODUCT VAPOR
CONCENTRATIONS BELOW SPECIFIED TLV VALUES.
Other Protective Equipment:IMPERVIOUS CLOTHING & BOOTS. ANSI APPRVD
EMERGENCY EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:BARRIER CREAMS, DAILY SHOWERS & CHANGE OF
CLOTHES.
Supplemental Safety and Health
RESP PROT:USE NIOSH/MSHA APPRVD FRESH-AIR SUPPLYING RESP OR NIOSH/MSHA
APPRVD SELF-CONTAINED BREATHING APPARATUS.
* Product Identification *
Preparer's Name:ZEKE
* Composition/Information on Ingredients *
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:PROPIONIC ACID, 2-METHYL-, MONOESTER WITH
2,2,4-TRIMETHYL-1,3-PENTANEDIOL; (2,2,4-TRIMETHYLPENTANEDIOL-1,3
(ING 3)
OSHA PEL:N/K
ACGIH TLV:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHALATION:VAPOR OR MIST CAN
CAUSE HEADACHE, NAUSEA & IRRITATION OF NOSE, THROAT & LUNGS. USE
GOOD PERSONAL HYGIENE PRACTICES WHILE WORKING WITH THIS MATERIAL.
DRY CONTAMINATED CLOTHING BEFORE R EUSE. FOR EYE CONTACT, FLUSH
GET (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:MED ATTN. INGESTION:MAY BE HARMFUL IF
SWALLOWED. INGESTION MAY CAUSE NAUSEA, VOMITING, DIARRHEA, AND
GASTROINTESTINAL IRRITATION. CONSULT PHYS. NOTICE:PURSUANT TO PROP
THE STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS/OTHER REPROD
HARM".
Medical Cond Aggravated by Exposure:OVEREXPOSURE TO VAPORS CAN CAUSE
HEADACHES, DIZZINESS AND NAUSEA.
* First Aid Measures *
First Aid:SKIN:CLEAN WITH SOAP AND WATER. INGEST:CONSULT A PHYSICIAN.
MINUTES. CONSULT A PHYSICIAN.
* Fire Fighting Measures *
Lower Limits:2.6%
Extinguishing Media:FOAM, ALCOHOL FOAM, CO*2, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . FOLLOW RECOMMENDED PROCEDURES IN HANDLING FIRE AREAS.
Unusual Fire/Explosion Hazard:POLYMER FILM CAN BURN. MATERIAL CAN
* Accidental Release Measures *
Spill Release Procedures:WIPE UP IMMEDIATELY & SAFELY DISCARD
ABSORBANTS. IN THE EVENT OF LARGE SPILLS, DIKE THE AREA AND PUMP
THE MATERIAL TO AN EPA PERMITTED WASTE TANK.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:USE WITH ADEQUATE VENTILATION. AVOID
PROLONGED OR REPEATED SKIN CONTACT. KEEP AWAY FROM EXCESSIVE HEAT.
AVOID ALL SOURCES OF HEAT.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
* Physical/Chemical Properties *
Vapor Pres:SEE INGS
Vapor Density:LTR/AIR
Spec Gravity:1.2 (H*2O=1)
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:DILUTABLE
Appearance and Odor:WHITE VISCOUS LIQUID, MILD ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID MATERIALS THAT ARE WATER REACTIVE. ALSO AVOID STRONG ALKALINE AND
ACIDIC SUBSTANCES.
Stability Condition to Avoid:EXCESS HEAT MAY CAUSE CONTAINERS TO
CONDITIONS.
Hazardous Decomposition Products:CO, CO*2 OR COMBUSTION.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS CURRENTLY IN FORCE FOR THIS PRODUCT HAZARD
CLASS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Ventilation:LOCAL - PREFERRED
Other Protective Equipment:CONVENTIONAL CLOTHES FOR PAINTING
Supplemental Safety and Health
PIGMENTS CONSIST OF TITANIUM DIOXIDE AND YELLOW OXIDE. VAPOR PRESSURE
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ALKYD RESIN
Ingred Name:NAPHTHA (PETROLEUM SPIRITS OR BENZIN)
Ingred Name:COBALT CALCIUM DRIER
Fraction by Wt: 1%.
Ingred Name:PIGMENTS - SEE SUPPLEMENTAL DATA
* Hazards Identification *
Effects of Overexposure:ANESTHESIA, HEADACHE, NAUSEA, DIZZINESS, ETC.
* First Aid Measures *
First Aid:INHALATION: REMOVE VICTIM FROM EXPOSURE AND RESTORE BREATHING
IF REQUIRED. CALL MD. SKIN: FLUSH W/MILD SOAP & WATER. EYES:
* Fire Fighting Measures *
Lower Limits:1.0
Upper Limits:6.0
Extinguishing Media:CO*2, FOAM, DRY CHEMICALS, WATER FOG.
Fire Fighting Procedures:DO NOT USE WATER. CONSULT FIRE MARSHALL.
Unusual Fire/Explosion Hazard:VAPOR FILM FORMS EXPLOSIVE MIXTURE W/AIR
BETWEEN UPPER & LOWER EXPLOSION LIMITS.
* Accidental Release Measures *
Spill Release Procedures:WIPE UP IMMEDIATELY & DISCARD ABSORBANTS
SAFELY. REMOVE OPEN IGNITION. DIKE LARGE SPILLS AND PUMP TO WASTE
TANK. KEEP VENTILATED AND AVOID BREATHING OF VAPORS.
*Handling and Storage *
Handling and Storage Precautions:AVOID OPEN FLAMES, SPARKS AND
EXCESSIVE HEAT. VENTILATE AREA WELL.
Other Precautions:READ LABEL REGARDING TOXICITY AND APPLICATION. DOT
CLASSIFICATION - COMBUSTIBLE.
* Physical/Chemical Properties *
HCC:F4
Vapor Density:5.3
Solubility in Water:NEGLIGIBLE
Appearance and Odor:THIN CREAM PAINT - VIRTUALLY NO ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:OPEN FLAME
Hazardous Decomposition Products:CO, CO*2
* Disposal Considerations *
Waste Disposal Methods:SPECIAL HAZARDOUS WASTE CARRIER, EPA REGULATED,
STATE OR FEDERAL.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED RESP DEVICE IN ACCORD WITH
EXPOSURE OF CONCERN.
Ventilation:MECHANICAL/GENERAL
Supplemental Safety and Health
CONTAINER SIZE: 4 LITER BOTTLE
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:FORMALDEHYDE
ACGIH TLV:C,2 PPM
Ingred Name:METHYL ALCOHOL (METHANOL) (SARA III)
Ingred Name:WATER
* Hazards Identification *
Effects of Overexposure:EYE: BURNS. SKIN: ALLERGIC REACTION. VAPORS:
HARMFUL. ABSORPTION THRU SKIN: HARMFUL.
* First Aid Measures *
WITH WATER. INHALATION: REMOVE TO FRESH AIR,GIVE ARTIF RESP IF
NEEDED,CONTACT A PHYSICIAN.
* Fire Fighting Measures *
Lower Limits:7
Extinguishing Media:DRY CHEMICAL,ALCOHOL FOAM OR CARBON DIOXIDE.
Fire Fighting Procedures:SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES OF FORMALDEHYDE GAS.
* Accidental Release Measures *
Spill Release Procedures:COVER WITH SODIUM BISULFITE AND SCOOP UP AND
PLACE IN A SUITABLE CONTAINER.
*Handling and Storage *
Handling and Storage Precautions:KEEP WELL CLOSED IN A MODERATELY WARM
* Physical/Chemical Properties *
HCC:F6
Vapor Density:1
Spec Gravity:1.1
Evaporation Rate & Reference:>1 (ETHER)
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS LIQUID,PUNGENT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
HYDROCHLORIC ACID,PERCHLORIC ACID.
Hazardous Decomposition Products:FUMES OF FORMALDEHYDE GAS
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF BY MEANS AS TO COMPLY WITH ALL
LOCAL,STATE AND FEDERAL REGULATIONS OR CONTACT AN APPROVED AND
LICENSED DISPOSAL AGENCY.
| 1 | gloves_mandatory |
Control Measures
*
Proprietary Ind: Y
*
Contractor Summary
*
*
Ingredients
*
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: INHAL: IRRIT OF RESP TRACT. PRLNG INHAL MAY LEAD TO MUC
MEMB IRRIT, DROW, DIZZ &/OR LT-HEAD, HDCH, GI DISTURB, COUGH, APATHY, CNS
DEPRESS, RESP PROBLEMS, ANESTH EFT/NARC, DFCLTY OF BRTHG, BLOOD ABNORM ,
KIDNEY DAM, LOSS OF CONSCIOUSNESS. SKIN: IRRIT OF SKIN. PRLNG/RPTD CONT CAN
CAUSE SEV IRRIT. POSS (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: CRYSTALLINE SILICA-QUARTZ: GROUP 2A(IARC),
ANTICIPATED TO BE A CARCINOGEN (NTP).
Signs And Symptions Of Overexposure: HLTH HAZ:SENSIT TO SKIN. SKIN CONT MAY
RSLT IN DERMAL ABSORP OF COMPONENTS OF PROD WHICH MAY CAUSE GI DISTURB,
APATHY. EYE:IRRIT OF EYES, PRLNG/RPTD CONT CAN CAUSE TEAR, RED, SEV IRRIT.
INGEST: INGEST MAY CAUSE DROW, DIZZ &/OR LT-HEAD, HDCH, NAUS, VOMIT, SEV
ABSDOM PAIN, APATHY, CNS DEPRESS, RESP PROBLEMS (SUPP DATA)
Medical Cond Aggravated By Exposure: EYE, SKIN, RESPIRATORY DISORDERS; KIDNEY
DISORDERS.
First Aid: INHAL: REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED BRTHG.
GET EMER MED ATTN. HAVE TRAINED PERSON GIVE O2 IF NEC. GET MED HELP FOR ANY
BRTHG DIFFICULTY. SKIN: FLUSH W/H2O. THEN WASH THORO W/SOAP & H2O.
REMOVE CONTAMD CLTHG BEFORE RE-USE. EYE: FLUSH IMMED W/LG AMTS OF H2O, ESPEC
INGEST: OBTAIN MED TRTMT IMMED.
*
Handling and Disposal
*
Spill Release Procedures: COMPLY W/ALL APPLIC HLTH & ENVIRONMENTAL REGS.
ELIMINATE ALL SOURCES OF IGNIT. VENT AREA. SPILLS MAY BE COLLECTED W/ ABSORB
MATLS. COMPLETE PERS PROT EQUIP MUST BE USED DURING CLEANUP. LG SPILLS-SHUT
OFF LEAK IF SAFE TO DO SO. DIKE & CNTN
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL,
STATE AND LOCAL REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS.
& OPEN FLAME. KEEP FROM FREEZING.
Other Precautions: USE ONLY W/ADEQ VENT. DO NOT TAKE INTERNALLY. KEEP OUT OF
REACH OF CHILDREN. AVOID CONT W/SKIN/EYES & BRTHG VAP. KEEP CONTR TIGHTLY
CLSD & UPRIGHT WHEN NOT IN USE. AVOID CNDTNS WHICH RSLT IN FORM OF I
NHALABLE PARTICLES SUCH AS
*
Fire and Explosion Hazard Information
*
Extinguishing Media: DRY CHEMICAL OR FOAM.
Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N). H2O MAY BE USED TO COOL & PROTECT EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard: VAP ARE HVR/AIR & MAY TRAVEL LONG DIST TO
SOURCE OF IGNIT & FLASH BACK. CLSD CONTR MAY BURST IF EXPOSED TO EXTREME
HEAT/FIRE.
*
*
Respiratory Protection: CONTROL ENVIRONMENTAL CONCENTRATIONS BELOW APPLICABLE
STANDARDS. WHERE RESPIRATORY PROTECTION IS REQUIRED, USE ONLY NIOSH/MSHA
Ventilation: PROVIDE DILUTION VENTILATION OR LOCAL EXHAUST TO PREVENT BUILD-UP
OF VAPORS.
Other Protective Equipment: EYE WASH, SAFETY SHOWER.
Work Hygienic Practices: WASH HANDS THORO AFTER HNDLG, ESP BEFORE EATING OR
SMOKING.
Supplemental Safety and Health: EFTS OF OVEREXP: INTOXICATION, ANESTH EFT/
NARC, KIDNEY DAM, PULM EDEMA, LOSS OF CONSCIOUSNESS, ACUTE POISONING, RESP
FAILURE, CARDIAC FAILURE, BRAIN DAM, DEATH. CONT W/CONTAMD CLTHG MAY CAUSE
SKIN BU RNS. SOME LAB TEST RSLTS HAVE SHOWN ETHYLENE GLYCOL TO BE AN ANIMAL
TERATOGEN. RPTD & PRLNG INHAL ABOVE RECOM
*
Physical/Chemical Properties
*
HCC: N1
Appearance and Odor: WHITE LIQUID.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: ELEVATED TEMPERATURES, CONTACT WITH OXIDIZING
AGENT, FREEZING, OPEN FLAME.
Materials To Avoid: OXIDIZERS, REDUCING AGENTS, ALUMINUM, ZINC, PEROXIDES,
HYDROFLUORIC ACID, MAGNESIUM, SODIUM, POTASSIUM.
Hazardous Decomposition Products: CO, CO2.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
*
Toxicological Information
*
*
Ecological Information
*
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Regulatory Information
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Other Information
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Transportation Information
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Multiple KIT Number: 0
Review IND: Y
Additional Data: NOT REGULATED FOR TRANSPORTATION
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Detail DOT Information
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DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail IMO Information
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IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
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Detail IATA Information
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IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail AFI Information
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AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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HAZCOM Label
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Company Name: GLIDDEN CO MEMBER OF ICI WORLD PAINTS
Label Required IND: Y
Status Code: C
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Moderate
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: COMBUST.AVOID ELEVATED TEMP & OPEN FLAME.
ACUTE:EYE/SKIN CONT CAN CAUSE SEV IRRIT.MAY CAUSE SKIN SENSIT.MAY BE ABSORB
THRU SKIN CAUSING GI DISTURB,APATHY.INHAL/INGEST MAY CAUSE DROW,DIZZ,HDCH,GI
DISTU RB,CNS DEPRESS,RESP PROBLEMS,LOSS OF CONSCIOUSNESS.INGEST MAY CAUSE
VOMIT,ABDOM PAIN,PULM EDEMA,UNCON,RESP/CARDIAC FAILURE, DEATH.CHRONIC:CANCER
HAZ.OVEREXP CAN CAUSE KIDNEY/BRAIN DAM, BLOOD ABNORM,DE LAYED INJURY TO
LUNGS.CRYSTALLINE SILICA-QUARTZ ISLISTED AS A CARCIN.MERCURY CMPDS APPEAR ON
THE NAVY REPRO HAZ LIST (FP N).SOME LAB TEST RESULTS HAVE SHOWN ETHYLENE
GLYCOL TO BE AN ANIMAL TERATOGEN ( CAUSES BIRTH DEFECTS).
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Control Measures
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Proprietary Ind: Y
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Contractor Summary
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Ingredients
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-----------------------------
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Health Hazards Data
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Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE:INHAL:IRRIT OF RESP TRACT. PRLNG INHAL MAY LEAD TO
FATG, DROW, DIZZ &/LT HEAD, HDCH, LACK OF COORD, NAUS, VOMIT, CNS
DEPRESS, ANESTH EFT/NARCOS. SKIN:IRRIT. PRLNG/RPTD CONT CAN CAUSE DERM, DEFAT
. EYE:IRRIT. PRLNG/RPTD CONT CAN CAUSE BLURRED VISION, REDNESS, TEARING, SEV
IRRIT. INGEST:AMTS INGEST (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ: INCIDENTAL TO CONSUMER &
INDUS HNDLG ARE NOT LIKELY TO CAUSE INJURY. HOWEVER, INGEST OF LARGER AMTS
MAY CAUSE LUNG INFLAMM & DMG DUE TO ASPIR OF MATL INTO LUNGS. NOTICE:
REPORTS HAVE ASSOC R PTD/PRLNG OCCUP OVEREXP TO SOLVS W/PERMBRAIN & CNS
DMG. INTENTIONAL MISUSE BY DELIBERATELY CONC & INHALING (SUP DAT)
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INHAL: REMOVE TO FRESH AIR. RESTORE & SUPPORT BRTHG. HAVE
TRAINED PERS GIVE OXYGEN IF NEC. GET EMER MED ATTN. SKIN: WASH OFF QUICKLY
W/PLENTY OF WATER, THEN SOAP & WATER. REMOVE CONTAM CLTHG. WASH CON TAM
CLTHG BEFORE REUSE. EYE: FLUSH IMMED W/LGE AMTS OF WATER, ESPECIALLY UNDER
OBTAIN MED TREATMENT IMMED.
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Handling and Disposal
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Spill Release Procedures: REMOVE ALL SOURCES OF IGNITION (FLAME, HOT SURFACES,
AND ELECTRICAL, STATIC SPARKS). VENTILATE AREA AND AVOID BREATHING VAPORS.
CONTAIN AND REMOVE WITH INERT ABSORBENT MATERIAL USING NON-SPARKING TOOL S.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL
REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS.
QTYS IN BLDGS DESIGNED FOR STOR OF FLAM/COMBUST LIQS. DO NOT TAKE INTERNALLY.
KEEP OUT OF REACH OF CHILDREN.
Other Precautions: DO NOT WELD/FLAME CUT W/OUT PROPER VENT TO INSURE AREA IS
FREE OF FLAMM VAPS. DO NOT CUT, PUNCTURE/WELD ON/NEAR CONTR. ENTRANCE INTO
CLSD STOR TANKS- USE APPROP NIOSH/MSHA APPRVD RESP/AIRLINE FOR POSS EXPOS TO
SOLV/CHEM FUMES. (SUP DAT)
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Fire and Explosion Hazard Information
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Flash Point Method: SCC
Lower Limits: SEE INGS
Extinguishing Media: USE DRY CHEMICAL OR FOAM.
Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). WATER MAY BE USED TO COOL AND PROTECT EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard: CLSD CONTRS MAY EXPLODE WHEN EXPOS TO EXTREME
HEAT/FIRE. VAPS CAN FORM EXPLO MIX IN AIR AT ELEVATED TEMPS. MAY DECOMP UNDER
FIRE CNDTNS EMITTING IRRIT (SUP DAT)
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Respiratory Protection: CONTROL ENVIRONMENTAL CONCENTRATIONS BELOW APPLICABLE
STANDARDS. APPROVED CHEMICAL MECHANICAL FILTER RESPIRATOR DESIGNED TO REMOVE
Other Protective Equipment: EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA (FP N).
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: USERS OF "L" VERSION OF TO CONSULT "LR"
VERSION FOR ADDNL INFO (FP N). EXPLO HAZ: &/TOX GASES. EFTS OF OVEREXP:
CONTENTS MAY BE HARMFUL/FATAL. OTHER PREC: RAGS/WASTE CONTAINING OIL BASED
PAINT/VA RNISH THAT PRESENT LGE AIR-TO-OIL INTERFACE WILL OXIDIZE & MAY
IGNITE SPONT & SHOULD BE PLACED IN METAL CONTR.
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Physical/Chemical Properties
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Vapor Pres: SEE INGS
Evaporation Rate & Reference: SLOWER THAN ETHYL ETHER
Appearance and Odor: NONE SPECIFIED BY MANUFACTURER.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: ELEVATED TEMPERATURES.
Materials To Avoid: CONTACT WITH OXIDIZING AGENTS.
Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
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Toxicological Information
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Ecological Information
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Regulatory Information
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Other Information
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HAZCOM Label
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Company Name: M A BRUDER & SONS INC
Label Required IND: Y
Status Code: C
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE. ACUTE: INHALATION: IRRITATION OF
RESPIRATORY TRACT. PROLONGED INHALATION MAY LEAD TO FATIGUE, DROWSINESS,
DIZZINESS AND/OR LIGHT HEADEDNESS, HEADACHE, LACK OF COORDINATION, NAUSEA,
VOMITI NG, CENTRAL NERVOUS SYSTEM DEPRESSION, ANESTHETIC EFFECTS/NARCOSIS.
SKIN: IRRITATION. PROLONGED/REPEATED CONTACT CAN CAUSE DERMATITIS, DEFATTING.
EYE: IRRITATION. PROLONGED/REPEATED CONTACT CAN CAUSE BLURRED VISION,
REDNESS, TEARING, SEVERE IRRITATION. INGESTION: LARGER AMOUNTS MAY CAUSE LUNG
INFLAMMATION & DAMAGE DUE TO ASPIRATION OF MATERIAL INTO LUNGS. CHRONIC:
PROLONGED/REPEATED OVEREXPOSURE T O SOLVENTS MAY CAUSE PERMANENT BRAIN &
CNS DAMAGE.
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* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH APPROVED RESPIRATOR WHEN AIR
CONCENTRATION IS GREATER THAN THE TLV OR PEL. USE FULL FACE
NIOSH-APPROVED FORMALDEHYDE OR ACID GAS CARTRIDGE RESPIRATOR WITHIN
USE LIMITATIONS OF THESE DEVICES; IN ALL OTHER SITUATIONS, USE
NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS (SCBA).
Ventilation:LOCAL EXHAUST RECOMMENDED.
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA . CHEMICALLY RESISTANT COVERALLS, HAT, AND SHOES OR BOOTS.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
FIRST AID PROC: INDUCE VOMIT, GIVE LG AMTS OF WATER. SEEK IMMED MED
ATTN. INHAL: REMOVE PERSON FROM CONTAMD AREA. IF BRTHG HAS STOPPED,
RESUSCITATE & ADMIN OXYG IF AVAIL. SEEK IMMED MED ATTN.
* Product Identification *
Preparer's Name:EARL R DARR
* Composition/Information on Ingredients *
Ingred Name:WATER
OSHA PEL:1 MG/M3
< Wt:2.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: INHALATION: HIGHLY IRRITATING
TO NASAL PASSAGES. CAN CAUSE INFLAMMATION OF LINING OF NOSE,
THROAT, AND LUNGS. OVER EXPOSURE MAY CAUSE HEADACHE, NAUSEA,
DIZZINESS, AND BLURRING OF VISION. SKIN C ONTACT: CAN CAUSE
IRRITATION AND DERMATITIS. EYE CONTACT: VAPOR CAUSES IRRITATION AND
INFLAMMATION OF MOUTH, THROAT, AND STOMACH, AS WELL AS BLINDNESS,
STUPOR, NAUSEA, VOMITING, AND POSSIBLE DEATH. CH RONIC: MAY CAUSE
SENSITIZATION AND REDUCED VISION. LIFETIME INHALATION STUDY OF RATS
EXPOSED TO FORMALDEHYDE GAS INDICATED DEVELOPMENT OF NASAL CANCERS.
Explanation of Carcinogenicity:FORMALDEHYDE: IARC MONOGRAPHS,
Effects of Overexposure:SEE HEALTH HAZARDS.
* First Aid Measures *
MINS. REMOVE CONTAMD CLTHG & FOOTWEAR. WASH CLTHG BEFORE REUSE.
DISCARD FOOTWEAR IF IT CANNOT BE DECONTAMD. SEEK IMMED MED ATTN.
LIDS APART TO ENSURE FLUSHING OF ENTIRE SURF. WASHING EYES W/IN
SEVERAL SECONDS OF EXPOS IS ESSTNL TO MINIMIZE DMG. SEEK IMMED MED
ATTN. INGEST: NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON, OBTAIN
IMMED MED ATTN. IF VOMIT OCCURS SPONTANEOUSLY, KEEP AIRWAY CLEAR.
IF SWALLOWED DO NOT (SUPDAT)
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:USE WATER FOG OR SPRAY. USE CARBON DIOXIDE. USE DRY
CHEMICAL.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:AT HIGH TEMPERATURES MAY RELEASE TOXIC
OXIDES OF NITROGEN AND SULFUR.
* Accidental Release Measures *
Spill Release Procedures:AVOID CONT W/SKIN, EYES, AND CLTHG. WEAR
PROTECTIVE EQUIPMENT (SEE EXPOSURE CONTROLS & PERSONAL PROTECTION
SECTION). DO NOT BREATHE MIST OR VAPORS. CONTAIN SPILL & SOAK UP IN
SUITABLE ABSORBENT. SHOVE L UP INTO PLASTIC-LINED STEEL CONTAINERS
AND COVER. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL, DRY PLACE. KEEP AWAY
FROM ALKALIES AND OXIDIZERS. LOOSEN COVER CAUTIOUSLY WHEN OPENING.
Other Precautions:WASH THOROUGHLY AFTER HANDLING.
* Physical/Chemical Properties *
pH:5.6 CA.
Evaporation Rate & Reference:NON VOLATILE
Solubility in Water:COMPLETE
Appearance and Odor:BLUE LIQUID. PUNGENT, IRRITATING ODOR.
Percent Volatiles by Volume:2 BY WT
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ALKALIS, STRONG ACIDS, AND OXIDIZERS. SECONDARY AMINES.
Stability Condition to Avoid:STABLE UNDER NORMAL CONDITIONS. SEE
INCOMPATIBILITY INFORMATION.
Hazardous Decomposition Products:OXIDES OF CARBON. COPPER SALTS.
* Toxicological Information*
Toxicological Information:N,N,N',N'-TETRAKIS (2-HYDROXYPROPYL)
ETHYLENEDIAMINE: ROUTE-ORAL, SPECIES-RAT,ADULT, EXPSOURE &
* Ecological Information *
Ecological:ECOLOGICAL INFORMATION ON THIS PRODUCT IS NOT AVAILABLE.
* Disposal Considerations *
Waste Disposal Methods:FOR WASTE DISPOSAL OF OPERATING SOLUTIONS
CONSULT ENTHONE-OMI WASTE DISPOSAL PROCEDURES. FOR MAJOR SPILLS
CONSULT ENTHONE-OMI FOR DISPOSAL ASSISTANCE. DISPOSE OF IN
ACCORDANCE WITH LOCAL, STATE, AND F EDERAL REGULATIONS.
* MSDS Transport Information *
Transport Information:PLEASE CONTACT THE REGULATORY AFFAIRS DEPARTMENT
* Regulatory Information *
CONTAINS FOLLOWING TOXIC CHEMS SUBJECT TO RPTG REQUIREMENTS OF
Federal Regulatory Information:ALL INGREDIENTS COMPLY WITH APPLICABLE
RULES OR ORDERS UNDER TSCA. HMIS HAZARD RATING: HEALTH:3, FIRE: 0,
REACTIVITY: 0.
PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO
* Other Information *
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* Exposure Controls/Personal Protection *
Respiratory Protection:SUITABLE NIOSH/MSHA APPROVED RESPIRATOR IF SPRAY
IS GENERATED.
Ventilation:MECHANICAL (GENERAL).
Other Protective Equipment:NONE NORMALLY REQUIRED.
Work Hygienic Practices:LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
HAZ DECOMP PROD: DECOMPOSE TO RELEASE OXIDES OF CARBON & NITROGEN &
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SYNTHETIC ORGANIC DISPERSANT (COPOLYMER OF ACRYLATE &
METHYL ACRYLATE)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN/EYE: MAY CAUSE IRRITATION BY
DIRECT CONTACT. INHAL: MIST/SPRAY MAY BE IRRITATING. INGEST: MAY BE
HARMFUL.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:EYES: IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT
WASH SKIN WELL W/WATER & FINALLY WITH SOAP & WATER. LAUNDER
CONTAMINATED CLO THING BEFORE REUSE. INHAL: REMOVE TO FRESH AIR.
TREAT SYMPTOMS. INGEST: DO NOT INDUCE VOMITING. GIVE WATER OR MILK
TO DRINK (UNLESS UNCONSCIOUS). IMMEDIATELY CALL MD OR THE POISONS
INFORMATION CENTRE.
* Fire Fighting Measures *
Flash Point:NON FLAMMABLE
Extinguishing Media:DETERMINED BY OTHER MATERIALS PRESENT.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:CONTAINERS EXPOSED TO A FIRE SHOULD BE
COOLED W/WATER TO PREVENT VAPOR PRESSURE BUILD-UP LEADING TO A
RUPTURE. CONTAIN RUNOFF FROM FIRE.
* Accidental Release Measures *
Spill Release Procedures:SMALL SPILLS: FLUSH AWAY WITH WATER. LARGE
SPILLS: CONTAIN WITH INERT ABSORBENT, PLACE IN DRUMS OR OTHER
SUITABLE CONTAINERS FOR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL DRY PLACE. KEEP CONTR
CLOSED WHEN NOT IN USE.
Other Precautions:AVOID SKIN/EYE CONTACT & INHALATION OF SPRAY IF
GENERATED. ENSURE ADEQUATE VENTILATION. DO NOT TAKE INTERNALLY.
* Physical/Chemical Properties *
HCC:N1
pH:8.2
Solubility in Water:MISCIBLE.
Appearance and Odor:PALE STRAW LIQUID WITH A SLIGHT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE.
Stability Condition to Avoid:EXCESSIVE HEAT.
Hazardous Decomposition Products:IF STRONGLY HEATED, THE H*2O COMPONENT
MAY EVAP, & EVENTUALLY, IF STRONG HEATING CONTINUED, THE RESIDUE
MAY (SUPP DATA)
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF SMALL QUANTITIES OF MATL TO THE TRADE
WASTE OR EFFLUENT SYSTEM. LARGE QTYS SHLD BE BURIED IN AN APPRVD
LANDFILL AREA. DISPOSE OF I/A/W FEDERAL, STATE, AND LOCAL
GOVERNMENT REGULATIONS (FP N ).
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:THIS CHEMICAL SHOULD BE HANDLED ONLY IN A HOOD.
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . USE APPROP NIOSH/MSHA APPRVD SAFETY EQUIP.
Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN IN THE
LABORATORY.
Supplemental Safety and Health
MATLS TO AVOID:THEIR ALLOYS AS CNTNRS. EXPLAN OF CARCIN:TO BE CARCIN.
ANIMAL:LUNG. FIRST AID PROC:SIGNS OF SHOCK - KEEP WARM & QUIET. GET
MED ATTN IF NEC. IF PATIENT IS IN CARDIAC ARREST ADMIN CPR. CO
NTINUE LIFE SUPPORTING MEASURES UNTIL MED ASSISTANCE HAS ARRIVED.
INGEST:DO NOT ADMIN LIQS/INDUCE VOMIT TO UNCON/(ING 2)
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:BERYLLIUM SULFATE (1:1)
Ingred Name:SUPDAT:CONVULSING PERS. IF SWALLOWED DRINK 1-2 GLASSES OF
WATER. CONT POIS CTL CTR IMMED IF NEC. GET MED ATTN IF (ING 3)
Ingred Name:ING 2:NEC. IF PATIENT IS VOMIT-WATCH CLOSELY TO MAKE SURE
AIRWAY DOES NOT BECOME OBSTRUCTED BY VOMIT. NOTE:AN (ING 4)
Ingred Name:ING 3:ANTIDOTE IS A SUBSTANCE INTENDED TO COUNTERACT EFT OF
A POIS. IT SHOULD BE ADMINISTERED ONLY BY MD/TRAINED (ING 5)
Ingred Name:ING 4:EMERGENCY PERSONNEL. MEDICAL ADVICE CAN BE OBTAINED
FROM A POISON CONTROL CENTER.
Ingred Name:EYE PROT:& FULL LENGTH FACESHIELD .
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ALL CHEMS SHOULD BE CONSIDERED HAZ -
AVOID DIRECT PHYSICAL CONT! VAPS &/OR DIRECT EYE CONT CAN CAUSE SEV
EYE BURNS. CAN CAUSE SKIN IRRIT. CAN BE FATAL IF ABSORBED THRU
SKIN! CAN CAUSE ALLERGIC SKIN RX N. VAPS CAN CAUSE SEV EYE INFLAMM
& SWELL OF ADJOINING TISS. MAY BE RAPIDLY ABSORBED THRU SKIN
W/POTNTL(EFTS OF OVEREXP)
Explanation of Carcinogenicity:BERYLLIUM SULFATE:IARC MONOGRAPHS, SUPP,
Effects of Overexposure:HLTH HAZ:ADVERSE HLTH EFTS. CAN BE FATAL IF
INHALED! CAN CAUSE DELAYED LUNG INJURY. DUST &/OR VAPS CAN CAUSE
IRRIT TO RESP TRACT. CAN CAUSE CYANOSIS. CAN CAUSE DELAYED ADVERSE
HLTH EFTS. MAY BE FATAL IF SWALLOWED! SUSPECTED CARCIN-MAY PRDCE
CANCER. CAN BE IRRITATING TO MUC MEMBS. THIS CMPD IS CONSIDERED TO
BE TOXIC.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
SOAP & WATER TO CLEANSE. REMOVE & WASH CONTAM CLTHG. DO NOT WEAR
SHOES/CLTHG UNT IL ABSOLUTELY FREE OF ALL CHEM ODORS. INHAL:REMOVE
PATIENT TO FRESH AIR. ADMIN OXYG IF PATIENT IS HAVING DFCLTY BRTHG.
IF PATIENT HAS STOPPED BRTHG ADMIN ARTF RESP. IF PATIENT IS
EXHIBITING (SUPDAT)
* Fire Fighting Measures *
Flash Point:NON FLAMMABLE
Extinguishing Media:CARBON DIOXIDE OR DRY CHEMICAL POWDER. DO NOT USE
WATER.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NO EXPLOSION LIMITS ARE AVAILABLE FOR
THIS COMPOUND.
* Accidental Release Measures *
Spill Release Procedures:EVACUATE AREA. WEAR APPROPRIATE OSHA-REGULATED
EQUIPMENT. VENTILATE AREA. SWEEP UP & PLACE IN AN APPROPRIATE
CONTAINER. HOLD FOR DISPOSAL. WASH CONTAMINATED SURFACES TO REMOVE
ANY RESIDUES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:AVOID CONTACT W/SKIN, EYES & CLOTHING.
KEEP TIGHTLY CLOSED & STORE IN A COOL, DRY PLACE. STORE ONLY
W/COMPATIBLE CHEMICALS.
Other Precautions:PERSONS NOT SPECIFICALLY & PROPERLY TRAINED SHOULD
NOT HANDLE THIS CHEM/ITS CNTNR. THIS PROD IS FURNISHED FOR LAB USE
ONLY! PRODS MAY NOT BE USED AS DRUGS, COSMETICS,
AGRICULTURAL/PESTICIDAL PRODS, FO OD ADDITIVES/AS HOUSEHOLD
CHEMICALS.
* Physical/Chemical Properties *
Solubility in Water:SOLUBLE
Appearance and Odor:COLORLESS CRYSTALLINE SOLID.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
REACTS W/ACIDS HALIDES & ANHYDRIDES, PHOSPHORUS HALIDES, THIONYL
CHLORIDE. DO NOT USE MAGNESIUM/ALUMINUM OR (SUPP DATA)
Stability Condition to Avoid:DECOMPOSITION PRODUCTS ARE CORROSIVE.
Hazardous Decomposition Products:DECOMPOSITION LIBERATES TOXIC FUMES.
* Disposal Considerations *
Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS . DISPOSE OF IN AN APPROVED CHEMICAL LANDFILL.
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* Exposure Controls/Personal Protection *
Respiratory Protection:NORMALLY NONE REQUIRED. IF HIGH VAPOR OR MIST
CONCENTRATIONS EXPECTED, USE RESPIRATOR APPROVED FOR ORGANIC VAPOR
OR MISTS.
Ventilation:USE IN WELL VENTILATED AREA. IN CONFINED SPACES, MECHANICAL
VENTILATION MAY BE REQUIRED TO KEEP BELOW PEL/TLV.
Other Protective Equipment:WEAR BODY-COVERING WORK CLOTHES TO AVOID
PROLONGED OR REPEATED EXPOSURE.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. LAUNDER
CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
QUANTITIES, LAVAGE MAY STILL BE ADVISED.
* Product Identification *
Preparer's Name:DONALD BARKER
* Composition/Information on Ingredients *
Ingred Name:RESIDUAL OILS, HYDROTREATED SOLVENT DEWAXED PETROLEUM OILS
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5 MG/M3 (OIL MIST)
ACGIH TLV:5 MG/M3 (OIL MIST)
Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-DEWAXED HEAVY
PARAFFINIC
Other REC Limits:NONE RECOMMENDED
ACGIH TLV:5 MG/M3 (OIL MIST)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: MILD EYE IRRITANT.
TRANSIENT/SLIGHT SKIN IRRITATION. LOW INHALATION HAZARD. MISTS
ABOVE TLV MAY CAUSE CHEMICAL PNEUMONITIS. LOW HAZARD BY INGESTION.
VERY LARGE AMOUNTS MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS.
CHRONIC: PROLONGED/REPEATED CONTACT MAY CAUSE DERMATITIS OR
FOLLICULITIS.
Explanation of Carcinogenicity:NONE OF THE CHEMICALS IN THIS PRODUCT IS
LISTED BY IARC, NTP OR OSHA AS A CARCINOGEN.
Effects of Overexposure:EYE: MILD IRRITATION. SKIN: SLIGHT TRANSIENT
IRRITATION. INHALATION: DROWSINESS, DIZZINESS, HEADACHE, NAUSEA,
LUNG IRRITATION. INGESTION: HEADACHE, DROWSINESS, NAUSEA, VOMITING,
DIARRHEA. INJECTION: E RYTHEMA, EDEMA, IRRITATION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
MINUTES AND CALL A PHYSICIAN IF ANY COMPLICATION ARISE. SKIN:
REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. INHALATION:
REMOVE TO FR ESH AIR. GIVE OXYGEN/CPR IF NEEDED. SEEK MEDICAL AID.
INGESTION: DO NOT INDUCE VOMITING. SEEK MEDICAL AID. INJECTION:
SUBCUTANEOUS INJECTION IS A MEDICAL EMERGENCY. SEEK MEDICAL AID
IMMEDIATELY.
* Fire Fighting Measures *
Flash Point Method:COC
Extinguishing Media:USE CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER FOG.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED
CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:WATER MAY CAUSE FROTHING. COMBUSTION OR
HEAT OF FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS AND
VAPORS.
* Accidental Release Measures *
Spill Release Procedures:CONTACT YOUR LOCAL ENVIRONMENTAL OFFICER.
REMOVE IGNITION SOURDES, PROVIDE ADEQUATE VENTILATION, CONTAIN
LEAK. ABSORB WITH SUITABLE MATERIAL SUCH AS VERMICULITE OR SAND.
PLACE IN APPROPRIATE CONTAINER AND COVER. WASH AREA WITH SOAP AND
WATER.
Neutralizing Agent:NOT APPLICABLE.
*Handling and Storage *
HEAT OR FLAME TO CONTAINER. KEEP SEPARATE FROM STRONG OXIDIZING
AGENTS.
Other Precautions:EMPTY CONTAINERS MAY CONTAIN PRODUCT RESIDUE WHICH
COULD INCLUDE FLAMMABLE OR EXPLOSIVE VAPORS. CONSULT APPROPIATE
AUTHORITIES BEFORE REUSING, RECONDITIONING, RECLAIMING, RECYCLING,
OR DISPOSING OF EM PTY CONTAINERS AND/OR WASTE RESIDUE.
* Physical/Chemical Properties *
HCC:V6
Evaporation Rate & Reference:<1 (BUTYL ACETATE = 1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:PALE COLORED OILY LIQUID
Percent Volatiles by Volume:NEGL.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION.
Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE
FROM BURNING.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPLICABLE LOCAL,
STATE AND FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW TLV .
Other Protective Equipment:AVOID PROLONGED OR REPEATED SKIN CONTACT BY
WEARING PROTECTIVE CLOTHING AS REQUIRED.
Work Hygienic Practices:N/K
Supplemental Safety and Health
ENTRY:INHALATION .
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:PETROLEUM DISTILLATE
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:NO KNOWN CHRONIC EFFECTS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES:MILD IRRITANT.SKIN:MILD
IRRITANT.INGESTION:N/K .INHALATION:UNLIKELY AT AMBIENT
ARE IRRITATING TO RESPIRATORY TRACT,MAY CAUSE HEADACHES AND
DIZZINESS,AND ARE ANESTHETIC.
Medical Cond Aggravated by Exposure:NONE KNOWN.
* First Aid Measures *
MD.SKIN:WASH WITH SOAP AND WATER.INGESTION:DO NOT INDUCE
VOMITING.CONTACT MD IMMEDIATELY.IF VOMITING OCCURS,KEEP HEAD BELOW
HIPS TO PREVENT ASPIRATIONOF LIQUID INTO THE
LUNGS.INHALATION:REMOVE TO FRESH AIR.
* Fire Fighting Measures *
Flash Point Method:COC
Lower Limits:7.0%
Upper Limits:0.6%
Extinguishing Media:CO*2,DRY CHEMICALS,FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.HAZARDOUS DECOMPOSITION
PRODUCTS:OXIDES OF CARBON.
* Accidental Release Measures *
Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES,VENTILATE
AREA.USE NONCOMBUSTIBLE ABSORBANT MATERIAL TO CONFINE SPILL.CLEAN
UP AREA.DISCARD IN SUITABLE CONTAINERS.
Neutralizing Agent:N/K
*Handling and Storage *
Handling and Storage Precautions:KEEP AWAY FROM HEAT,OPEN FLAMES AND
OTHER IGNITION SOURCES.
Other Precautions:N/K
* Physical/Chemical Properties *
Decomp Temp:Decomp Text:N/K
Vapor Pres:<2 MMHG
Vapor Density:>5 (AIR=1)
Evaporation Rate & Reference:<0.1 (BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR,ALMOST COLORLESS LIQUID WITH BLAND ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products:OXIDES OF CARBON.
* Disposal Considerations *
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:SELF CONTAINED BREATHING APPARATUS FOR CONC.
ABOVE TLV.
Ventilation:LOCAL EXHAUST BELOW TLV.
Other Protective Equipment:EYE BATH AND FIRE EXTINGUISHERS.
Supplemental Safety and Health
& PROPANE AS A PROPELLENT
* Product Identification *
Product ID:CRC ZINC IT (AEROSOL)
* Composition/Information on Ingredients *
Ingred Name:ZINC (SARA III)
Ingred Name:RESIN
Fraction by Wt: 2%
Ingred Name:METHYLENE CHLORIDE(SARA III)
Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)
Ingred Name:TOLUENE (SARA III)
* Hazards Identification *
Effects of Overexposure:EYE IRRITATION, DRYING OF SKIN, EXCESSIVE
INHALATION CAUSES DIZZINESS, NAUSEA, HEADACHE.
* First Aid Measures *
First Aid:EYES: FLUSH WITH WATER, CALL A PHYSICIAN. SKIN: WASH WITH
SOAP AND WATER, APPLY SKIN CREAM. INHALATION: REMOVE TO FRESH AIR.
APPLY ARTIFICIAL RESPIRATION IF NEEDED. CALL A PHYSICIAN.
* Fire Fighting Measures *
Extinguishing Media:CO2, DRY CHEMICALS, FOAM
Fire Fighting Procedures:FOLLOW PROCEDURES FOR SOLVENTS.
Unusual Fire/Explosion Hazard:AEROSOL CANS MAY EXPLODE AT TEMPERATURES
* Accidental Release Measures *
Spill Release Procedures:USUALLY NOT APPLICABLE TO AEROSOLS. SMALL
SPILLS MAY BE PICKED UP WITH ABSORBENT MATIAL. PROVIDE RESPIRATORY
PROTECTION. AVOID EXPOSURE TO OPEN FLAMES, SPAR, HEAT.
*Handling and Storage *
DO NOT SPRAY INTO OPEN FLAMES. DO NOT PUNCTURE OR INCINETE AEROSOL
CAN.
* Physical/Chemical Properties *
Solubility in Water:NEGLIGIBLE
Appearance and Odor:GRAY, VISCOUS LIQUID, AROMATIC ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ACIDS
* Disposal Considerations *
Waste Disposal Methods:DO NOT INCINERATE AEROSOL CANS. BURY OR DISCARD
IN CONFORMANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. FULL OR
PARTIALLY FULL CANS MUST BE HANDLED AS "HAZARDOUS WASTE".
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Ventilation:USE IN WELL VENTILATED AREA.
Work Hygienic Practices:HANDLE IN ACCORDANCE W/GOOD PERSONAL HYGIENE &
SAFETY PRACTICES. THESE PRACTICES INCLUDE AVOIDING UNNECESSARY
EXPOSURE.
Supplemental Safety and Health
* Product Identification *
Product ID:CITRICON PUTTY BASE
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:NON-HAZARDOUS FOR INGREDIENTS
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: IRRITATION. SKIN: IRRITATION.
Explanation of Carcinogenicity:NONE
* First Aid Measures *
INGESTION: RINSE MOUTH W/WATER SEVERAL TIMES. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Extinguishing Media:CO2, DRY CHEMICAL
* Accidental Release Measures *
Spill Release Procedures:WIPE, SCRAPE/SOAK UP IN AN INERT MATERIAL &
PUT IN A CONTAINER FOR DISPOSAL. WASH WALKING SURFACES W/DETERGENT
& WATER TO REDUCE SLIPPING HAZARD.
*Handling and Storage *
Handling and Storage Precautions:AVOID CONTACT W/EYES.
* Physical/Chemical Properties *
Spec Gravity:>1.3
Evaporation Rate & Reference:<1
Solubility in Water:INSOLUBLE
Appearance and Odor:MINT GREEN PUTTY W/AN ESTER ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:PREMATURE CONTACT W/MATCHING CATALYST.
Hazardous Decomposition Products:CO, CO2, SILICONE DIOXIDE
* Disposal Considerations *
Waste Disposal Methods:DON'T ADD TO SEWER SYSTEM. DISPOSE OF IN
ACCORDANCE W/FEDERAL, STATE, LOCAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH APPROVED DUST MASK WHEN HANDLING THE
BROKEN BATTERIES.
Ventilation:USE ADEQUATE MECHANICAL (GENERAL) AND LOCAL EXHAUST
VENTILATION WHEN HANDLING BROKEN BATTERIES, OR CELLS.
Other Protective Equipment:WHEN HANDLING LEAKERS, DO NOT WEAR
CONTAMINATED CLOTHING HOME. SHOWER AND CHANGE OR WEAR COVERALLS.
Work Hygienic Practices:WASH AFTER HANDLING LEAKERS AND BEFORE EATING,
DRINKING, OR SMOKING. KEEP FOOD AND TOBACCO AWAY FROM WORK AREA.
Supplemental Safety and Health
* Product Identification *
Product ID:NICKEL-CADMIUM SEALED CELL BATTERY
* Composition/Information on Ingredients *
Ingred Name:CADMIUM (SARA III)-TOTAL PERCENTAGE OF INGREDIENTS 1, 2 AND
Other REC Limits:NONE RECOMMENDED
Ingred Name:CADMIUM HYDROXIDE
Fraction by Wt: SEE #1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:NOT ESTABLISHED.
ACGIH TLV:NOT ESTABLISHED.
Ingred Name:CADMIUM OXIDE (SARA III)
Fraction by Wt: SEE #1%
Other REC Limits:NONE RECOMMENDED
Ingred Name:NICKEL(SARA III)-TOTAL PERCENTAGE OF INGREDIENTS 4, 5 & 6
Fraction by Wt: SEE #3%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3
Ingred Name:NICKEL HYDROXIDE (SARA III)
Fraction by Wt: SEE #3%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG NI/M3
Ingred Name:NICKEL OXIDE
Fraction by Wt: SEE #3%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG NI/M3
Ingred Name:COBALT HYDROXIDE
Fraction by Wt: 0.5%
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:PRODUCT IS SEALED UNIT. HAZARDS ARE
BASED ON BROKEN AND LEAKING CELLS. EYES: IRRITATION. SKIN:
IRRITATION, DEMATITIS. INHALATION/INGESTION: NOSE-THROAT
IRRITATION, SWEATING, WEAKNESS, NAUSEA, VOMITING , DIARRHEA, CHEST
PAINS, EMPHYSEMA, BONE LESIONS, LUNG CANCER, DEATH. INTESTINAL,
PROSTRATE, LIVER, KIDNEY DISORDERS.
Explanation of Carcinogenicity:NICKEL AND CADMIUM AND THEIR COMPOUNDS
ARE LISTED AS CARCINOGENS OR POTENTIAL CARCINOGENS BY NTP, IARC,
AND OSHA.
Effects of Overexposure:SYMPTOMS ARE BASED ON BROKEN OR LEAKING CELLS.
EYES: IRRITATION, SKIN: IRRITATION, DERMATITIS.
INHALATION/INGESTION: NOSE=THROAT IRRITATION, SWEATING, WEAKNESS,
NAUSEA, VOMITING, DIARRHEA, CHEST PAINS , E,[HYSEMA, BONE LESIONS,
LUNG CANCER,DEATH. INTESTINAL, PROSTRATE, LIVER, KIDNEY DISORDERS.
Medical Cond Aggravated by Exposure:PERSON WITH PRE-EXISTING DISEASE
INVOLVING EYES, SKIN, RESPIRATORY SYSTEM, PROSTRATE GLAND, LIVER,
AND KIDNEY MAY BE AT INCREASED RISK FROM EXPOSURE TO INGREDIENTS
SPILLED OR LEAKED FROM THIS PRODUCT.
* First Aid Measures *
First Aid:EYES/SKIN: FLUSH WITH LARGE AMOUNTS OF WATER. IF IRRITATION
PERSISTS, GET MEDICAL ATTENTION. INHALATION: MOVE TO FRESH AIR. GET
MEDICAL ATTENTION. INGESTION: INDUCE VOMITING IF CONSCIOUS. GET
MEDICAL ATTENTION.
* Fire Fighting Measures *
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SELF-CONTAINED
BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING IF INVOLVED IN A
FIRE.
* Accidental Release Measures *
Spill Release Procedures:CONTAIN SPILL. COLLECT SPILLED MATERIAL AND
PLACE IN A PLASTIC-LINED CONTAINER. HEPA VACUUMING IS PREFERRED.
FLUSH THE AREA WITH WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:PROTECT FROM BREAKING, CRUSHING OR
OTHERWISE DESTROYING THE PHYSICAL INTEGRITY OF THE SEALED CELL OR
BATTERY. DO NOT INCINERATE.
Other Precautions:WHEN HANDLING BROKEN OR LEAKING CELLS WEAR NIOSH/MSHA
* Physical/Chemical Properties *
HCC:N1
Spec Gravity:1.6
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:GENERAL STORAGE PROCEDURES FOR HAZARDOUS
MATERIALS ARE ACCEPTABLE.
Hazardous Decomposition Products:METAL OXIDE FUMES MAY BE EVOLVED AT
TEMPERATURES ABOVE MELTING POINT.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL, STATE
AND FEDERAL REGULATIONS. IF DISCARDED, TREAT AS HAZARDOUS WASTE.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE SHOULD BE NEEDED.
HOUR, SHOULD BE USED. RATES SHOULD MATCH CONDITIONS.
Other Protective Equipment:CHEMICAL RESISTANT CLOTHING AS NECESSARY TO
PREVENT SKIN CONTACT. AN EMERGENCY EYEWASH AND SHOWER SHOULD BE
AVAILABLE.
Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER
BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES.
Supplemental Safety and Health
REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:WATER
Other REC Limits:NONE RECOMMENDED
Ingred Name:DIETHYLENE GLYCOL
Other REC Limits:NONE RECOMMENDED
Ingred Name:CARBON BLACK
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:3.5 MG/M3
Ingred Name:SODIUM SALT OF NAPHTHALENE SULFONIC ACID POLYMER MFR GIVES
Fraction by Wt: < 3%
Other REC Limits:NONE RECOMMENDED
Fraction by Wt: 0-0.5%
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EXPECTED TO BE A LOW INHALATION HAZARD
FOR RECOMMENDED HANDLING. EYE CONTACT CAUSES IRRITATION. SKIN
CONTACT CAUSES IRRITATION. HARMFUL IF SWALLOWED. MAY CAUSE
IRRITATION OF THE GASTROINTESTINAL TRACT . CAN CAUSE KIDNEY DAMAGE.
CAN CAUSE CNS EFFECTS. MAY CAUSE BLOOD DISORDERS BASED ON ANIMAL
DATA.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:EYE IRRITATION, SKIN IRRITATION, GI TRACT
IRRITATION, KIDNEY DAMAGE, CNS EFFECTS, BLOOD DISORDERS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL
ATTENTION IF SYMPTOMS PERSIST. EYES: WASH OUT IMMEDIATELY WITH
WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN: WASH WITH
SOAP AND WATER . GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
INGESTION: INDUCE VOMITING AS DIRECTED BY MEDICAL PEROSNNEL. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CALL PHYSICIAN OR
POISON CONTROL ASAP.
* Fire Fighting Measures *
Flash Point:NONFLAMMABLE
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL
FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
* Accidental Release Measures *
Spill Release Procedures:ABSORB SPILL WITH VERMICULITE OR OTHER INERT
MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN
SURFACE TO REMOVE RESIDUAL CONTAMINATION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:AVOID PROLONGED OR REPEATED BREATHING
OF MIST OR VAPOR. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. USE
WITH ADEQUATE VENTILATION.
Other Precautions:KEEP FROM CONTACT WITH OXIDIZING MATERIALS. KEEP
CONTAINER CLOSED.
* Physical/Chemical Properties *
HCC:N1
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Vapor Density:0.6
Spec Gravity:NOT GIVEN
Viscosity:NOT GIVEN
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:NOT GIVEN
Appearance and Odor:BLACK LIQUID, ODOR NOT SPECIFIED
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
OXIDES OF NITROGEN, OXIDES OF SULFUR.
* Disposal Considerations *
Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE OR LOCAL LAWS. MAY REQUIRE NEUTRALIZATION IF PH
FEDERAL, STATE ANDLOCAL REGULATIONS.
| 1 | gloves_mandatory |
Control Measures
*
*
Contractor Summary
*
*
Ingredients
*
------------------------------
------------------------------
% low Wt: 3.
% high Wt: 5.
------------------------------
% low Wt: 1.
% high Wt: 3.
------------------------------
% low Wt: 1.
% high Wt: 3.
------------------------------
% low Wt: 1.
% high Wt: 3.
Other REC Limits: 3 MG/M3 TWA
OSHA PEL: 6 MG/M3 TWA
------------------------------
% low Wt: .1
% high Wt: 1.
------------------------------
% low Wt: .1
% high Wt: .5
Other REC Limits: NONE
ACGIH STEL: NOT ESTABLISHED
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: NO
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: YES
OSHA: NO
Effects of Exposure: EYES ARE LISTED AS A PRIMARY ROUTE OF ENTRY (FP N).
TOXICITY: MILD EYE IRRITANT. PROPYLENE GLYCOL IS A MILD SKIN IRRITANT. SIGNS
AND SYMPTOMS OF EXPOSURE: MAY CAUSE DERMATITIS ON PROLONGED CONTACT IN
SENSITIVE INDIVIDUALS. LITERATURE REFERENCED TARGET ORGAN AND OTHER HEALTH
EFFECTS: POLYGLYCOL DIMETHACRYLATE: ALLERGEN, IRRITANT. POLYGLYCOL OLEATE:
IRRITANT. SACCHARIN: NO TARGET ORGANS. CUMENE HYD ROPEROXIDE: ALLERGEN,
CENTRAL NERVOUS SYSTEM, CORROSIVE, IRRITANT, MUTAGEN. PROPYLENE GLYCOL:
IRRITANT. SILICA, AMORPHOUS, FUMED, CRYSTALLINE FREE: NUISANCE DUST.
N,N-DIALKYLTOLUIDINES: NO TARGET ORGA NS. (SIGNS & SYMPTOMS OF
OVEREXPOSURE)
Explanation Of Carcinogenicity: SACCHARIN: IARC GROUP 2B (POSSIBLE CARCINOGENIC
Signs And Symptions Of Overexposure: HEALTH HAZARDS ACUTE AND CHRONIC (CON'T):
TITANIUM DIOXIDE: IRRITANT, RESPIRATORY.
Medical Cond Aggravated By Exposure: PROPYLENE GLYCOL: DERMATITIS.
First Aid: INGESTION: DO NOT INDUCE VOMITING. KEEP INDIVIDUAL CALM. OBTAIN
MEDICAL ATTENTION. INHALATION: REMOVE TO FRESH AIR. SUPPORT BREATHING.
CONTACT A PHYSICIAN IMMEDIATELY (FP N). SKIN CONTACT: WASH THOROU GHLY WITH
MEDICAL ATTENTION.
*
Handling and Disposal
*
Spill Release Procedures: SOAK UP IN AN INERT ABSORBANT. STORE IN A PARTLY
FILLED, CLOSED CONTAINER UNTIL DISPOSAL.
Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL,
STATE AND FEDERAL REGULATIONS (FP N). INCINERATE FOLLOWING EPA AND LOCAL
REGULATIONS. EPA HAZARDOUS WASTE NUMBER: NH-NOT A RCRA HAZARDOUS WASTE MATE
RIAL.
HANDLING: AVOID PROLONGED SKIN CONTACT. KEEP AWAY FROM EYES.
*
Fire and Explosion Hazard Information
*
Flash Point Method: TCC
Lower Limits: 2.6%
Extinguishing Media: CARBON DIOXIDE, FOAM, DRY CHEMICAL.
Fire Fighting Procedures: USE NIOSH-APPROVED SELF-CONTAINING BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: NONE. HAZARDOUS PRODUCTS FORMED BY FIRE OR
THERMAL DECOMP: IRRITATING ORGANIC VAPORS; OXIDES OF CARBON.
*
*
Respiratory Protection: A NIOSH-APPROVED RESPIRATOR APPROPRIATE FOR THE
EXPOSURE OF CONCERN (FP N).
Ventilation: DOES NOT APPLY.
N).
Other Protective Equipment: EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA (FP N).
*
Physical/Chemical Properties
*
PH: DOES NOT APPLY
Evaporation Rate & Reference: NOT AVAILABLE (ETHER=1)
Solubility in Water: SLIGHT
Appearance and Odor: BLUE LIQUID; MILD ODOR.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: NOT AVAILABLE.
Materials To Avoid: STRONG OXIDIZERS, FREE RADICAL INITIATORS, INERT GASES.
Hazardous Decomposition Products: NONE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
*
Toxicological Information
*
*
Ecological Information
*
Ecological: NO DATA AVAILABLE.
*
*
SHIPPING NAME: UNRESTRICTED.HAZARD CLASS OR DIVISION: UNRESTRICTED.
IDENTIFICATION NUMBER: NONE. MARINE POLLUTANT: NONE. IATA: PROPER SHIPPING
NAME: INRESTRICTED. CLASS OR DIVISION: UNRESTRICTED. UN OR ID NUMBER: NONE.
*
Regulatory Information
*
Sara Title III Information: CUMENE HYDROPEROXIDE IS LISTED AS A SARA SECTION
REASONABLY ANTICIPATED.
*
Other Information
*
Other Information: ESTIMATED NFPA CODE: HEALTH: -1, FIRE -1, REACTIVITY -1;
SPECIFIC HAZARD: DOES NOT APPLY. ESTIMATED CODE: HEALTH -1, FLAMMABILITY -1,
REACTIVITY -1, PERSONAL PROTECTION: SEE CONTROL MEASURES SECT ION. PRODUCT
TYPE: ANAEROBIC. PHYSICAL/CHEMICAL(CONT'D): VOLATILE ORGANIC COMPOUND
EXPLOSIVE LIMITS: (% BY VOLUME IN AIR) LOWER - PROPYLENE GLYCOL: 2.6%. (% BY
*
HAZCOM Label
*
Company Name: LOCTITE CORPORATION
Label Required IND: Y
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: ACUTE: PRIMARY ROUTES OF ENTRY: EYE/SKIN CONTACT.
TOXICITY: MILD EYE IRRITANT. PROPYLENE GLYCOL IS A MILD SKIN IRRITANT. MAY
CAUSE DERMATITIS ON PROLONGED CONTACT IN SENSITIVE INDIVIDUALS. CHRONIC: C
ANCER HAZARD: CONTAINS SACCHARIN WHICHIS LISTED AS A POSSIBLE HUMAN BLOOD
CARCINOGEN (FP N).
*
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:FULL FACEPIECE RESPIRATOR W/APPROPRIATE FILTER
PAD OR CARTRIDGE(S).
Ventilation:LOCAL EXHAUST AND MECHANICAL
Other Protective Equipment:AS REQUIRED TO MEET APPLICABLE OSHA
STANDARDS.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:REFRACTORY CERAMIC OXIDE
* Hazards Identification *
Effects of Overexposure:THIS PROCESS MAY GENERATE RESPIRABLE NUISANCE
DUST, THE TLV/PEL IS 5MG/CUM.
* First Aid Measures *
First Aid:TERMINATE EXPOSURE.
*Handling and Storage *
Handling and Storage Precautions:REMOVAL OF THIS PRODUCT AFTER USE MAY
RESULT IN THE GENERATION OF DUST.
Other Precautions:REPEATED INHALATION OF RESPIRABLE FREE CRYSTALLINE
SILICA DUST MAY CAUSE DELAYED LUNG INJURY (SILICOSIS).
* Physical/Chemical Properties *
Spec Gravity:3.1
Solubility in Water:INSOLUBLE
Appearance and Odor:REFRACTORY SHAPE - NO ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
* Disposal Considerations *
Waste Disposal Methods:ROUTINE HOUSEKEEPING
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR A NIOSH/MSHA APPROVED PROPERLY FITTED
ORGANIC VAPOR/PARTICULATE RESPIRATOR IF PERSONAL EXPOSURE CAN'T BE
CONTROLLED < APPLICABLE LIMITS BY VENTILATION. WEAR A NIOSH/MSHA
APPROVED DUST/MIST RESPIR ATOR WHEN SANDING/ABRADING DRIED FILM.
Ventilation:LOCAL EXHAUST: PREFERABLE. GENERAL EXHAUST: ACCEPTABLE IF
EXPOSURE IS MAINTAINED < APPLICABLE EXPOSURE LIMITS.
Other Protective Equipment:SAFETY GLASSES W/UNPERPORATED SIDESHIELDS.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH HANDS AFTER USING.
Supplemental Safety and Health
PH: 8.2-9.8 FIRE FIGHTING PROC CONT'D: WATER MAY BE USED TO COOL CLOSED
CONTAINERS TO PREVENT PRESSURE BUILD-UP & POSSIBLE
AUTOIGNITION/EXPLOSION WHEN EXPOSED TO EXTREME HEAT.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ETHYLENE GLYCOL, GLYCOL
Fraction by Wt: <3%
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:2-(2-BUTOXYETHYOXY)-ETHANOL, DIETHYLENE GLYCOL MONOBUTYL
ETHER (BUTYL CARBITOL)
Fraction by Wt: 0-1%
Ingred Name:CLAY (KAOLIN), ALUMINUM SILICATE
Ingred Name:CARBONIC ACID, CALCIUM SALT (1:1), CALCIUM CARBONATE,
DURAMITE
Fraction by Wt: 7-9%
Ingred Name:TITANIUM DIOXIDE, TIO2 (SUSPECTED ANIMAL CARCINOGEN, IARC
Ingred Name:WATER
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:IRRITATION OF EYES, SKIN & UPPER
RESPIRATORY SYSTEM. LONG TERM EXPOSURE TO HIGH LEVELS OF SILICA
DUST MAY CAUSE LUNG DAMAGE & POSSIBLE CANCER. PROLONGED
OVEREXPOSURE TO SOLVENTS MAY CAUSE ADVERSE EFFE CTS TO THE LIVER &
URINARY SYSTEMS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, HEADACHE, NAUSEA, DIZZINESS,
REDNESS, ITCHING, BURNING SENSATION.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. KEEP WARM
& QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. EYES:
ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Extinguishing Media:CO2, DRY CHEMICAL, ALCOHOL FOAM
Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT & SCBA SHOULD BE
USED. WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES
ARE PREFERABLE. (SEE SUPP)
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT.
* Accidental Release Measures *
Spill Release Procedures:REMOVE IGNITION SOURCES. VENTILATE & REMOVE
W/INERT ABSORBENT.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE.
TRANSFER ONLY TO APPROVED CONTAINERS W/COMPLETE & APPROPRIATE
LABELING.
Other Precautions:DON'T TAKE INTERNALLY. KEEP OUT OF THE REACH OF
CHILDREN. USE ONLY W/ADEQUATE VENTILATION. AVOID BREATHING VAPOR &
SPRAY MIST. AVOID CONTACT W/SKIN & EYES.
* Physical/Chemical Properties *
Vapor Density:>1
pH:(SUPP)
Evaporation Rate & Reference:SLOWER THAN ETHER
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:EXTREME HEAT & OTHER IGNITION SOURCES
Hazardous Decomposition Products:BY FIRE: CO2, CO
* Disposal Considerations *
Waste Disposal Methods:INCINERATE IN APPROVED FACILITY. DON'T
INCINERATE CLOSED CONTAINERS. DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
* Other Information *
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NO INFORMATION GIVEN BY MFR ON MSDS.
Ventilation:GOOD VENTILATION IS RECOMMENDED.
Other Protective Equipment:NO INFORMATION GIVEN BY MFR ON MSDS.
Work Hygienic Practices:MFR: ? HMIS:USE STRICT CHEMICAL HYGIENE
PRACTICE. AVOID UNNECESSARY EXPOSURE. WASH THOROUGHLY BEFORE EATING
OR DRINKING.
Supplemental Safety and Health
NONE
* Product Identification *
Preparer's Name:RICKY A. STACKHOUSE, PHD
* Composition/Information on Ingredients *
FOUND OF THE INGREDIENT(S) HAZARDOUS."
G/L)
Fraction by Wt: <2%
Other REC Limits: RECOMMENDED
OSHA PEL:1 MG/M3
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE TOXICITY STUDIES HAVE BEEN
CONDUCTED ON THIS PRODUCT. THE RESULTS:IRRITATION, ALBINO RABIT,
0.0/8.0 4 HOUR CONTACT. EYE CONTACT:NON-IRRITATING. SKIN
CONTACT:NON-IRRITATING.
Explanation of Carcinogenicity:THIS PRODUCT IS NOT LISTED BY IARC, NTP,
OR OSHA AS A CARCINOGEN.
Effects of Overexposure:A REVIEW OF AVAILABLE DATA DOES NOT IDENTIFY
ANY SYMPTOMS FROM EXPOSURE FOR SUCH A DILUTE SOLUTION.
Medical Cond Aggravated by Exposure:GET IMMEDIATE MEDICAL ATTENTION
* First Aid Measures *
First Aid:FLUSH CONTACTED AREA WITH WATER.
* Fire Fighting Measures *
Flash Point:
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL
FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED
CONTAINERS.
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING.
Unusual Fire/Explosion Hazard:
* Accidental Release Measures *
Spill Release Procedures:ACID SOLUTION SHOULD BE NEUTRALIZED BEFORE
DISCHARGING TO A SANITARY SEWER.
Neutralizing Agent:NO INFORMATION GIVEN BY MFR ON MSDS.
*Handling and Storage *
Handling and Storage Precautions:NO INFORMATION GIVEN BY MFR ON MSDS.
Other Precautions:EMPTY PRODUCT CONTAINERS SHOULD BE PUNCTURED, IF
PLASTIC AND PLACED IN THE GARBAGE COLLECTION CONTAINER.
* Physical/Chemical Properties *
HCC:C1
NRC/State Lic Num:NOT RELEVANT
pH:<1
Viscosity:NOT RELEVANT
Solubility in Water:COMPLETEY
Appearance and Odor:LIQUID WITH NO ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
KNOWN
Stability Condition to Avoid:
Hazardous Decomposition Products:IN EVENT OF COMBUSTION SOX MAY BE
FORMED. DO NOT BREATHE SMOKE OR FUMES. WEAR SUITABLE PROTECTIVE
EQUIPMENT.
* Disposal Considerations *
Waste Disposal Methods:IF THIS PRODUCT BECOMES A WASTE, IT MEETS THE
DISPOSAL OF AN ACID TEST SOLUTION MAY BE ACCOMPLISHED BY FLUSHING
TO A WASTE TREATMENT SY STEM WHICH HAS PH CONTROL SYSTEM IN
OPERATION.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Ventilation:USE ONLY W/ADEQUATE
Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER USE.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SODIUM HYPOCHLORITE, HYPOCHLOROUS ACID SODIUM SALT
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: MODERATE TO SEVERE IRRITATION &
POSSIBLE TISSUE DAMAGE. SKIN: MODERATE IRRITATION & DERMATITIS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INGESTION: NAUSEA, VOMITING, & DIARRHEA. SKIN:
DEFATTING, IRRITATION. EYES: IRRITATION.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. INGESTION: GIVE PLENTY OF
WATER, THEN SEVERAL GLASSES OF MILK. DON'T INDUCE VOMITING. EYES:
SKIN: RE MOVE CONTAMINATED CLOTHING & WASH W/PLENTY OF SOAP &
WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:AS REQUIRED BY SURROUNDING FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:WILL BURN IN THE PRESENCE OF STRONG
IGNITION SOURCE AFTER THE WATER IS REMOVED.
* Accidental Release Measures *
Spill Release Procedures:CONTAIN LARGE SPILLS & PUMP TO RECOVER. SMALL
SPILLS CAN BE ABSORBED.
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL, DRY PLACE. KEEP
CONTAINER CLOSED WHEN NOT IN USE.
Other Precautions:KEEP OUT OF THE REACH OF CHILDREN.
* Physical/Chemical Properties *
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR LIQUID W/CHLORINE ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ACIDS, AMINES, METALS ORGANICS
Stability Condition to Avoid:EXTREME TEMPERATURES
Hazardous Decomposition Products:CHLORINE
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, &
FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH APPROVED RESPIRATORS DESIGNED TO
REMOVE PARTICULATE MATTER AND ORGANIC SOLVENT VAPORS.
Ventilation:GEN DILUTION/LOC EXHST VENT SHOULD BE PROVIDED TO KEEP
EXPOS BELOW ACCEPTABLE LIMS & TO KEEP SOLV VAPS BELOW (SUP DAT)
Other Protective Equipment:ANSI APPRVD EMER EYEWASH & DELUGE SHOWER .
PROPER CLTHG SHOULD BE WORN TO PVNT SKIN CONT. BARRIER CREAM (SUP
DAT)
Work Hygienic Practices:ALWAYS WASH HANDS AFTER USING THIS MATERIAL,
AND BEFORE EATING, DRINKING, OR SMOKING.
Supplemental Safety and Health
WASTE DISP METH: HAZ INFO IN OTHER SECTIONS OF THIS SHEET. VENT: LOWER
EXPLOSION LIMIT. OTHER PROT EQUIP: MAY BE WORN FOR ADDNL SKIN PROT.
IMPERMEABLE CLTHG SHOULD BE WORN TO PVNT PRLNG/RPTD CONT OF W ET
MATL W/SKIN.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
Ingred Name:2-PENTANONE, 4-HYDROXY-4-METHYL-;
Ingred Name:COPPER, (PHTHALOCYANINATO(2-))-; (PHTHALO BLUE)
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: CONT W/VAP MAY RSLT IN
IRRIT, REDNESS, TEARING, & BLURRED VISION. SKIN: CONT W/MATL MAY
RSLT IN IRRIT OF SKIN. INHAL: EXCESS INHAL OF VAPS MAY CAUSE NASAL
& RESP IRRIT. INGEST: MAY CAUSE GI IRRIT, NAUS, DIARR, & VOMIT.
CHRONIC: BRTHG OF VAPS FROM THIS MATL IS IRRITATING TO EYES, NOSE,
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: & THROAT. CONT W/MATL IN EYES/SKIN
CAN CAUSE DRYNESS & IRRIT. OVEREXP TO DIACETONE ALCOHOL HAS BEEN
SUGGESTED AS A CAUSE TO THE FOLLOWING EFFECTS IN LABORATORY
ANIMALS: ANEMIA, LIVER ABNORMA LITIES, KIDNEY DAMAGE.
Medical Cond Aggravated by Exposure:OVEREXPOSURE TO DIACETONE ALCOHOL
MAY AGGRAVATE PREEXISTING DISORDERS OF THESE ORGANS IN HUMANS:
ANEMIA, LIVER ABNORMALITIES, KIDNEY DAMAGE.
* First Aid Measures *
SEE MD FOR MED TREATMENT. SKIN: IMMED WASH AFFECTED AREA W/SOAP &
WATER. REMOVE CONTAM CLTHG. CONSULT MD IF IRRIT PERSISTS. INHAL:
REMOVE PER S TO FRESH AIR. RESTORE BRTHG. KEEP PERS WARM & QUIET.
TREAT SYMPTOMATICALLY. GET MED ATTN. INGEST: KEEP PERS WARM &
QUIET. CONSULT MD OR POISON CONTROL CENTER IMMED.
* Fire Fighting Measures *
Lower Limits:1.8%
Upper Limits:6.9%
Extinguishing Media:FOAM, CARBON DIOXIDE, AND DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . WATER MAY BE USED TO COOL CONTAINERS TO PREVENT
PRESSURE BUILD-UP WHICH MAY RUPTURE CONTAINERS.
Unusual Fire/Explosion Hazard:HANDLE AS A COMBUSTIBLE LIQUID.
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE THE
AREA. WEAR PROTECTIVE EQUIPMENT. AVOID BREATHING VAPORS. CONTAIN
SPILL. COLLECT WITH INERT ABSORBENT AND REMOVE. DISPOSE OF
PROPERLY.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE MATL IN COOL, WELL-VENTILATED
SPKS/OPEN FLAME. KEEP CONTRS TIGHTLY CLOSED.
Other Precautions:AVOID CONT W/INCOMPATIBLE MATLS. IF PROD IS TO BE
KEEP OUT OF REACH OF CHILDREN. DO NOT TAKE INTERNALLY. AVOID CONT
W/EYES & SKIN.
* Physical/Chemical Properties *
Vapor Pres:SEE ING 2
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER THAN ETHYL ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, ALKALI, AND OXIDIZING AGENTS.
Stability Condition to Avoid:HIGH TEMPERATURES, IGNITION SOURCES, AND
CONTACT WITH INCOMPATIBLE MATERIALS.
Hazardous Decomposition Products:FUMES MAY BE PRDCED WHEN MATL IS
HEATED TO DECOMP. FUMES MAY CONTAIN CARBON MONOXIDE & DIOXIDE, &
VARIOUS HYDROCARBONS.
* Disposal Considerations *
Waste Disposal Methods:DISP OF I/A/W FED, STATE, & LOC REGS. WASTE FROM
BE TESTED FOR IGNITABILITY TO DETERMINE APPLIC EPA HAZ WASTE
NUMBERS. BEFORE ATTEMPTI NG CLEAN-UP/DISPOSING OF MATL, REFER
TO(SUP DAT)
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:The following respirators and maximum use
supplied-air respirator. Any powered, air-purifying respirator with
respirator with a full facepiece and organic vapor cartridge(s).
Any air-purifying respirator with a full facepiece and an organic
vapor canister. Any powered, air-purifying respirator with a full
facepiece and organic vapor cartridge(s). Any self-contained
breathing apparatus with a full facepiece. Any supplied-air
respirator with a full facepiece. Escape - Any air-purifying
respirator with a full facepiece and an organic vapor canister. Any
appropriate escape-type, self-contained breathing apparatus. For
Unknown Concentrations or Immediately Dangerous to Life or Health -
Any supplied-air respirator with full facepiece and operated in a
pressure-demand or other positive-pressure mode in combination with
a separate escape supply. Any self-contained breathing apparatus
with a full facepiece.
Ventilation:Provide local exhaust ventilation system. Ventilation
equipment should be explosion-resistant if explosive concentrations
of material are present. Ensure compliance with applicable exposure
limits.
emergency eye wash fountain and quick drench shower in the
immediate work area.
Other Protective Equipment:Wear appropriate chemical resistant
clothing.
Supplemental Safety and Health
recommended ceiling (skin)
* Product Identification *
Product ID:N-BUTYL ALCOHOL
Kit Part:* Responsible Party *
CAGE:Company Name:MATHESON TRI-GAS, INC.
CAGE:
* Composition/Information on Ingredients *
Ingred Name:N-BUTYL ALCOHOL
* Hazards Identification *
Reports of Carcinogenicity:NTP:No IARC:NoOSHA:No
Health Hazards Acute and Chronic:INHALATION: SHORT TERM EXPOSURE:
irritation, nausea, difficulty breathing, headache, drowsiness,
symptoms of drunkenness, lung damage LONG TERM EXPOSURE: hearing
loss SKIN CONTACT: SHORT TERM EXPOSURE: irritation LONG TERM
EXPOSURE: same as effects reported in short term exposure EYE
CONTACT: SHORT TERM EXPOSURE: irritation LONG TERM EXPOSURE:
tearing, blurred vision INGESTION: SHORT TERM EXPOSURE: nausea,
vomiting, diarrhea, stomach pain, symptoms of drunkenness, visual
disturbances LONG TERM EXPOSURE: liver damage
Medical Cond Aggravated by Exposure:
* First Aid Measures *
First Aid: INHALATION: If adverse effects occur, remove to
uncontaminated area. Give artificial respiration if not breathing.
Get immediate medical attention. SKIN CONTACT: Wash skin with soap
clothing and shoes. Get medical attention, if needed. Thoroughly
clean and dry contaminated clothing and shoes before reuse. EYE
Then get immediate medical attention. INGESTION: If vomiting
occurs, keep head lower than hips to help prevent aspiration. If
person is unconscious, turn head to side. Get medical attention
immediately. NOTE TO PHYSICIAN: For ingestion, consider gastric
lavage. Consider oxygen.
* Fire Fighting Measures *
Lower Limits:1.4%
Extinguishing Media:alcohol resistant foam, carbon dioxide, regular dry
chemical, water, alcohol resistant foam Large fires: Use
alcohol-resistant foam or flood with fine water spray.
Fire Fighting Procedures:Move container from fire area if it can be
done without risk. Cool containers with water spray until well
after the fire is out. Stay away from the ends of tanks. For fires
in cargo or storage area: Cool containers with water from unmanned
hose holder or monitor nozzles until well after fire is out. If
this is impossible then take the following precautions: Keep
unnecessary people away, isolate hazard area and deny entry. Let
the fire burn. Withdraw immediately in case of rising sound from
venting safety device or any discoloration of tanks due to fire.
(1/2 mile). Water may be ineffective.
Unusual Fire/Explosion Hazard:Severe fire hazard. The vapor is heavier
than air. Vapors or gases may ignite at distant ignition sources
and flash back. Vapor/air mixtures are explosive above flash point.
* Accidental Release Measures *
Spill Release Procedures:Avoid heat, flames, sparks and other sources
of ignition. Remove sources of ignition. Stop leak if possible
without personal risk. Reduce vapors with water spray. Small
spills: Absorb with sand or other non-combustible material. Collect
spilled material in appropriate container for disposal. Large
spills: Dike for later disposal. Keep unnecessary people away,
isolate hazard area and deny entry. Stay upwind and keep out of low
areas. Notify Local Emergency Planning Committee and State
Emergency Response Commission for release greater than or equal to
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:Store and handle in accordance with
all current regulations and standards. Subject to storage
required. Keep separated from incompatible substances. Store in a
tightly closed container. Avoid contact with air or light.
Other Precautions:
* Physical/Chemical Properties *
pH:Not available
Evaporation Rate & Reference:0.5 (butyl acetate=1)
Solubility in Water:7.7%
Appearance and Odor:PHYSICAL STATE:liquid APPEARANCE:clear
COLOR:colorless ODOR:pungent odor
Corrosion Rate:
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:Stable at normal temperatures
and pressure.
Stability Condition to Avoid:Avoid heat, flames, sparks and other
sources of ignition. Containers may rupture or explode if exposed
to heat.
Hazardous Decomposition Products:Thermal decomposition products: oxides
of carbon Thermal decomposition products: oxides of carbon
Conditions to Avoid Polymerization:Will not polymerize.
* Toxicological Information*
TOXICITY LEVEL: Moderately Toxic: ingestion Slightly Toxic:
inhalation, dermal absorption TARGET ORGANS: central nervous system
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: eye disorders,
respiratory disorders, skin disorders and allergies MUTAGENIC DATA:
Available. REPRODUCTIVE EFFECTS DATA: Available. ADDITIONAL DATA:
Alcohol may enhance the toxic effects.
* Ecological Information *
* Disposal Considerations *
all applicable regulations.
* MSDS Transport Information *
GROUP: II LABELING REQUIREMENTS: Flammable liquid
* Regulatory Information *
* Other Information *
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR NIOSH/MSHA APPROVED AIR SUPPLIED
RESPIRATOR, IF MEK VAPOR EXPOSURE LIMITS ARE EXCEEDED.
Ventilation:PROVIDE SUFFICIENT MECHANICAL VENTILATION TO MAINTAIN
EXPOSURE BELOW TLV.
Other Protective Equipment:AVOID REPEATED OR PROLONGED SKIN CONTACT.
WEAR A CHEMICAL RESISTANT APRON.
Work Hygienic Practices:MFR? HMIS:PRACTICE GOOD INDUSTRIAL HYGIENE.
AVOID UNNECESSARY CONTACT. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
ELIMINATE IGNITION SOURCES. DO NOT WELD OR USE A CUTTING TORCH.
* Product Identification *
Kit Part:Y
Preparer's Name:LARRY W. MINTON
* Composition/Information on Ingredients *
Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)
Ingred Name:FLUORO ELASTOMER RESIN
Other REC Limits:NONE SPECIFIED
Ingred Name:MAGNESIUM OXIDE
Fraction by Wt: 3-4%
Other REC Limits:NONE RECOMMENDED
Ingred Name:CARBON BLACK
Fraction by Wt: 3-4%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:3.5 MG/M3
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE-MAY CAUSE
IRRITATION,REDNESS,TEARING,BLURRED VISION. PROLONGED &/OR REPEATED
SKIN CONTACT MAY CAUSE IRRITATION,DEFATTING,DERMATITIS. INHALATION
MAY CAUSE RESPIRATORY IRRITATION, CNS EFFECTS I.E.
DIZZINESS,WEAKNESS,FATIGUE,NAUSEA,HEADACHE,UNCONSCIOUSNESS,DEATH.
CHRONIC-LIVER OR KIDNEY DAMAGE; LUNG & BRAIN DAMAGE.
Explanation of Carcinogenicity:THIS PRODUCT IS NOT CONSIDERED A
CARCINOGEN BY NTP. IARC OR OSHA.
Effects of Overexposure:EYES:SEVERE IRRITATION, REDNESS, TEARING &
BLURRED VISION. SKIN:IRRITATION, DEFATTING & DERMATITIS.
INHALED:NASAL & RESPIRATORY IRRITATION, HEADACHE, DIZZINESS, WEAK,
FATIGUE, POSSIBLE UNCONSCIOUSNES S & ASPHYXIATION. INGESTION:G/I
IRRITATION, VOMITING, DIARRHEA & NAUSEA.
Medical Cond Aggravated by Exposure:MEK MAY SHORTEN THE TIME OF ONSET
OF PERIPHERAL NEUROPATHY CAUSED BY METHYL N- BUTYL KETONE &
N-HEXANE. MEK BY ITSELF HAS NOT BEEN SHOWN TO CAUSE PERIPHERAL
NEUROPATHY.
* First Aid Measures *
First Aid:EYES:FLUSH W/LG AMNTS OF WATER, LIFTING LIDS, GET MED ATTN.
SKIN:WASH AREA W/SOAP & WATER. REMOVE CONTAMINATED CLOTHES &
LAUNDER CLOTHES BEFORE REUSE. INHALE:IF AFFECTED, REMOVE TO FRESH
AIR. IF BREAT HING IS DIFF, ADMIN OXYGEN. IF BEATHINGHAS STOPPED,
GIVE CPR. GET MED ATTN IMMED. INGESTION:DO NOT INDUCE VOMITING.
KEEP PERSON WARM/ QUIET & GET MED ATTN. ASPIRATION INTO LUNGS MAY
CAUSE PNEUMONITUS
* Fire Fighting Measures *
Lower Limits:2
Extinguishing Media:ALCOHOL FOAM, CARBON DIOXIDE OR DRY CHEMICALS.
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS WITH
FULL FACE PIECE IN POSITIVE PRESSURE MODE. WEAR PROTECTIVE CLOTHING
TO PROTECT FROM HYDROGEN FLOURIDE.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR & MAY TRAVEL
ALONG THE GROUND. IGNITION OF A VAPOR ACCUMULATION MAY CREATE FLASH
OR EXPLOSION.
* Accidental Release Measures *
Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. WEAR
PROTECTIVE CLOTHING. ABSORB MIXTURE WITH SAND, CLAY, EARTH, FLOOR
ABSORBENT OR OTHER ABSORBENT MATERIAL & SHOVEL INTO CONTAINERS.
Neutralizing Agent:MFR GAVE NO INFORMATION ON MSDS.
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL, DRY PLACE. KEEP
CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. DO NOT STORE NEAR HEAT,
SPARKS OR FLAME. GROUND FIXED EQUIPMENT.
Other Precautions:STATIC ELECTRICITY MAY OCCUR & CREATE A FIRE HAZARD.
BOND & GROUND TRANSFER CONTAINERS & EQUIPMENT. EMPTIED CONTAINERS
RETAIN PRODUCT RESIDUES. OBSERVE ALL HAZARD PRECAUTIONS WITH
EMPTIED CONTAINERS.
* Physical/Chemical Properties *
HCC:F2
NRC/State Lic Num:NONE
Vapor Density:2.5
Spec Gravity:1.1
pH:N/AP
Appearance and Odor:DARK GRAY OR BLACK, VISCOUS LIQUID WITH SOLVENT
ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID STRONG OXIDIZING AGENTS
CREATE HYDROGEN FLOURIDE.
Hazardous Decomposition Products:HYDROGEN FLUORIDE,TOXIC FLOUROCARBON
OLEFINS,CO2,CO,VARIOUS HYDROCARBONS MAY EVOLVE DURING COMBUSTION OR
Conditions to Avoid Polymerization:WILL NOT OCCUR.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF I/A/W FEDERAL, STATE & LOCAL
REGULATIONS. INCINERATION REQUIRES SCRUBBING OF GASEOUS PRODUCTS TO
REMOVE HYDROGEN FLOURIDE.
| 1 | gloves_mandatory |
Control Measures
*
Product ID: LAUNDRY DETERGENT
Proprietary Ind: Y
*
Preparer Co. when other than Responsible Party Co.
*
*
Contractor Summary
*
*
Item Description Information
*
Item Manager: GSA
Item Name: DETERGENT,LAUNDRY
Type/Grade/Class: TYPE 3
Unit of Issue: DR
UI Container Qty: 1
Type of Container: FIBER
*
Ingredients
*
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Effects of Exposure: ACUTE: MAY CAUSE SEVERE IRRITATION OF THE EYES, INCLUDING
CORNEAL OPACITIES. DUST IS IRRITATING TO THE SKIN, MUCOUS MEMBRANES AND UPPER
RESPIRATORY TRACT. CHRONIC: MAY CAUSE INFLAMMATION OF THE MUCOUS MEMBRANES
IN THE RESPIRATORY TRACT ANDOF THE SKIN.
SEE AN OPTHALMOLOGIST IF IRRITATION PERSISTS. SKIN: WASH WITH PLENTY OF
WATER. IF IRRITATION OCCURS AND PERSISTS, OBTAIN MEDICAL ATTE NTION.
INGESTION: DRINK A GLASS OF WATER OR MILK.
*
Handling and Disposal
*
Spill Release Procedures: SWEEP UP AS MUCH AS POSSIBLE FOR SALVAGE OR DISPOSAL.
WASH AWAY RESIDUE WITH WATER.
Waste Disposal Methods: IF MATERIAL CANNOT BE SALVAGED, THE PREFERRED METHOD OF
DISPOSAL IS IN A SECURE CHEMICAL LANDFILL IN ACCORDANCE WITH ALL LOCAL, STATE
AND FEDERAL ENVIRONMENTAL REGULATIONS. EMPTY CONTAINERS MAY BE INC INERATED
OR DISCARDED AS GENERAL TRASH.
Handling And Storage Precautions: DO NOT STORE CLOSE TO ACIDS. MINIMIZE THE
FREE FALL WHEN HANDLING TO MINIMIZE THE DUST GENERATED.
TO PREVENT IRRITATION WHERE EXCESSIVE DUST IS PRESENT.
*
Fire and Explosion Hazard Information
*
Extinguishing Media: WATER, FOAM, DRY CHEMICALS.
Unusual Fire/Explosion Hazard: SPONTANEOUS HEATING IS MODERATE WHEN IN CONTACT
WITH WATER.
*
*
IS EXCEEDED OR DISCOMFORT IS PRESENT.
Ventilation: GENERAL VENTILATION-LOCAL EXHAUST IF NEEDED FOR DUST CONTROL.
Other Protective Equipment: FULL COVER CLOTHING.
*
Physical/Chemical Properties
*
HCC: N1
Solubility in Water: APPRECIABLE
Appearance and Odor: WHITE GRANULAR POWDER WITH A SLIGHT SURFACTANT ODOR.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: CONTACT WITH ACIDS EXCEPT UNDER CONTROLLED
CONDITIONS.
Materials To Avoid: CONTACT WITH ACIDS RELEASES LARGE VOLUMES OF CARBON DIOXIDE
GAS AND HEAT. STRONG OXIDIZING AGENTS.
Hazardous Polymerization Indicator: NO
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
Transportation Information
*
Product ID: LAUNDRY DETERGENT
Tech Entry NOS Shipping Nm: LAUNDRY DETERGENT, TYPE III, HIGH SUDSING, LOW
PHOSPHATE.
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: DR
Container QTY: 1
Type Of Container: FIBER
*
Detail DOT Information
*
DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
Detail IMO Information
*
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
*
Detail IATA Information
*
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
Detail AFI Information
*
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
HAZCOM Label
*
Product ID: LAUNDRY DETERGENT
Company Name: GURTLER CHEMICALS INC
Label Required IND: Y
Status Code: C
Origination Code: G
Hazard And Precautions: ACUTE: MAY CAUSE SEVERE IRRITATION OF THE EYES,
INCLUDING CORNEAL OPACITIES. DUST IS IRRITATING TO THE SKIN, MUCOUS MEMBRANES
AND UPPER RESPIRATORY TRACT. CHRONIC: MAY CAUSE INFLAMMATION OF THE MUCOUS
MEMBRANES IN THE RESPIRATORY TRACT ANDOF THE SKIN.
N/K
*
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WHERE VENTILATION IS INADEQUATE, USE A SUITABLE
NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:PROVIDE GEN DILUTION/LOC EXHST VENT IN VOL PATT TO KEEP
Other Protective Equipment:WEAR PROTECTIVE CLOTHING INCLUDING
IMPERMEABLE APRON.
Work Hygienic Practices:CLEAN OR DISCARD CONTAMINATED CLOTHING & SHOES.
Supplemental Safety and Health
EXTING MEDIA:CLASS IIIB COMBUST LIQ FIRES. FIRE FIGHT
PROC:AUTOIGNIT/EXPLO WHEN EXPOSED TO EXTREME HEAT. IF WATER IS
USED, FOG NOZZS ARE PREF. HAZ DECOMP PROD:FUMES INCL CARBON
MONOXIDE & FORMALDEHYDE . EFTS OF OVEREXP:EXCESS AMTS OF
SILICADUST. APPLICATION OF THIS PROD IS NOT EXPECTED TO GEN EXCESS
AMTS OF (ING 9)
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SILICA, CRYSTALLINE - FUSED; (SILICA, AMORPHOUS-FUSED)
OSHA PEL:SEE TABLE Z3
Ingred Name:CALCIUM CARBONATE
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
Ingred Name:CLAY; (KAOLIN) (ALUMINUM SILICATE)
Ingred Name:WATER
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:WATER; (DEIONIZED WATER)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:FILM FORMERS, RESINS & ADDITIVES
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SILICA, CRYSTALLINE - CRISTOBALITE
Fraction by Wt: 2-5%
OSHA PEL:SEE TABLE Z3
Ingred Name:SUPDAT:RESPIRABLE SILICA, SO POTENTIAL HAZARD FOR HUMANS IS
LIMITED.
Ingred Name:FIRST AID PROC:SKIN OR EYE IRRITATION OR BREATHING
DIFFICULTIES.
Ingred Name:VENT:BELOW STATED LIMIT & TO REMOVE DECOMP PRODUCTS DURING
WELDING OR FLAME CUTTING ON SURFACES COATED W/THIS PRODUCT.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INGEST:HARMFUL IF SWALLOWED.
EYE:CAUSES IRRIT. REDNESS, ITCH, BURNING SENSATION & VISUAL
DISTURBS MAY INDICATE EXCESS CONT. SKIN:MAY CAUSE SLIGHT IRRIT.
DRYNESS, ITCH, CRACKING, BURNING, REDNESS & SWELL ARE CNDTNS ASSOC
W/EXCESS CONT. INHAL:VAP & SPRAY MIST MAY BE HARMFUL IF INHALED.
SANDING & (EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE - CRISTOBALITE:GP2A
Effects of Overexposure:HLTH HAZ:GRINDING DUST MAY BE HARMFUL IF
INHALED. CHRONIC:AVOID LONG-TERM & RPTD CONT. THIS PROD CONTAINS
FORM OF CRYSTALLINE SILICA WHICH IARC ASSOC W/INCR RISK OF CANCER
IN LAB ANIMALS. LONG-TERM EX POS TO CRYSTALLINE SILICA MAY ALSO
LEADTO DISABLING INJURY KNOWN AS SILICOSIS. THESE EFTS ARE ASSOC
W/BRTHG (SUPDAT)
* First Aid Measures *
First Aid:INGEST:DO NOT INDUCE VOMIT. EYE:FLUSH IMMED W/PLENTY OF WATER
WASHING W/SOAP & WATER. INHAL:REMOVE TO FRESH AIR. APPLY ARTF RESP
& OTH ER SUPPORTIVE MEASURES AS REQD. IF ANY OF FOLLOWING OCCUR
DURING/FOLLOWING USE OF PROD CONT POIS CTL CTR, EMER ROOM/MD IMMED.
HAVE MSDS INFO AVAIL:INGEST; EXCESS EXPOS TO CORR MATL;
* Fire Fighting Measures *
Flash Point Method:PMCC
Extinguishing Media:USE NFPA CLASS B EXTINGS (CARBON DIOXIDE, DRY
CHEM/UNIVERSAL AQUEOUS FILM FORMING FOAM) DESIGNED TO EXTING NFPA
(SUPDAT)
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
WATER SPRAY MAY BE INEFT. WATER SPRAY MAY BE USED TO COOL CLSD
CNTNRS TO PVNT PRESS BUILD-UP & POSS(SUPDAT)
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE OR BURST
DUE TO BUILD-UP OF STEAM (PRESSURE) WHEN EXPOSED TO EXTREME HEAT.
* Accidental Release Measures *
Spill Release Procedures:PROVIDE MAX VENT. ONLY PERS EQUIPPED W/PROPER
NIOSH/MSHA APPRVD RESP SKIN & EYE PROT SHLD BE PERMITTED IN AREA.
REMOVE ALL SOURCES OF IGNIT. TAKE UP SPILLED MATL W/SAWDUST,
VERMICULITE/OTHER ABSORB MATL & PLACE INTO CNTNRS FOR DISP.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
BLDGS DESIGNED & PROTECTED FOR STORAGE OF NFPA CLASS IIIB
COMBUSTIBLE LIQS. PROTECT FROM FREEZING.
Other Precautions:IF THIS MATL IS PART OF A MULTIPLE COMPONENT COATING
SYSTEM READ MSDS(S) FOR OTHER COMPONENT(S) BEFORE BLENDING AS
RESULTING MIXTURE MAY HAVE HAZARDS OF ALL OF ITS PARTS.
* Physical/Chemical Properties *
Vapor Density:HVR/AIR
Appearance and Odor:VISCOUS LIQ W/ODOR CHARACT OF CHEMCIAL FAMILY & ANY
SOLVS LISTED IN INGS.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT W/STRONG ALKALIES, STRONG MINERAL ACIDS OR STRONG
OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY PRDCE HAZ DECOMP PRODS WHEN
HEATED. WELDING, BRAZING/FLAME-CUTTING ON SURFS COATED W/THIS PROD
MAY PRDCE (SUPDAT)
* Disposal Considerations *
Waste Disposal Methods:WASTE MATL MUST BE DISPOSED OF I/A/W FEDERAL,
STATE, PROVINCIAL & LOCAL ENVIRONMENTAL CONTROL REGULATIONS. EMPTY
CONTAINERS SHOULD BE RECYCLED OR DISPOSED OF THROUGH APPROVED WASTE
MANAGEMENT FACILITY .
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:NONE REQUIRED.
Other Protective Equipment:NONE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
CAGE:0GTM2
CAGE:0GTM2
* Composition/Information on Ingredients *
Ingred Name:ETHYLENE GLYCOL
Fraction by Wt: <2%
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:TOLUENE
Fraction by Wt: <5%
Ingred Name:RESINOUS BINDER (MAY CONTAIN ING 8 & 9)
Ingred Name:SBR LATEX
Ingred Name:METHACRYLIC ACID, POLYMER WITH ETHYL ACRYLATE; (ACRYLIC
POLYMER THICKENER)
Fraction by Wt: 3-5%
Ingred Name:WATER
Ingred Name:ARIEN; (HYDROCARBON RESIN AND PETROLEUM OIL)
Ingred Name:HYDROCARBON RESIN AND PETROLEUM OIL
Ingred Name:VM&P NAPHTHA
Fraction by Wt: <5%
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: VAPORS MAY CAUSE MILD
NAVY LISTING OF OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS. SEEK
CONSULTATION FROM APPROPRIATE H EALTH PROFESSIONALS CONCERNING
LATEST HAZARD LIST INFORMATION AND SAFE HANDLING AND EXPOSURE
INFORMATION .
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:
* First Aid Measures *
PHYSICIAN. SKIN: WASH WITH SOAP AND WATER. INHAL: MOVE TO FRESH
AIR. INGEST: TREAT SYMPTOMATICALLY AND CONTACT PHYSICIAN.
* Fire Fighting Measures *
Flash Point Method:SCC
Lower Limits:1%
Upper Limits:7%
Extinguishing Media:FOAM, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.
* Accidental Release Measures *
Spill Release Procedures:SCRAPE INTO CONTAINERS FOR DISPOSAL. CLEAN
AREA WITH PLENTY OF SOAPY WATER, OR MINERAL SPIRITS IF RESIDUAL
MATERIAL HAS DRIED.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:AVOID EXTREME TEMPERATURES. PROTECT
FROM FREEZING.
Other Precautions:
* Physical/Chemical Properties *
Vapor Density:>1
Evaporation Rate & Reference:>1(BUTYL ACETATE=1)
Solubility in Water:MISCIBLE
Appearance and Odor:CREAM COLORED PASTE, SLIGHT AMMONIACAL ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE
CARBON MONOXIDE AND CARBON DIOXIDE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND
FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED RESP DEVICE IN ACCORD WITH
EXPOSURE OF CONCERN.
Ventilation:LOCAL EXHAUST
Other Protective Equipment:UNPERFORATED SIDE SHIELDS ON GLASSES.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ALIPHATIC HYDROCARBON
Ingred Name:TOLUENE (SARA III)
Ingred Name:ISOBUTYL ACETATE (SARA III)
Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)
Ingred Name:ISOPROPYL ALCOHOL (SARA III)
* Hazards Identification *
Effects of Overexposure:VAPOR: ANESTHETIC,RESP TRACT
IRRIT,LIGHTHEADEDNESS,STAGGER GAIT. EYE/SKIN: IRRITATION.
* First Aid Measures *
First Aid:INHALATION: REMOVE FROM EXPOSURE,RESTORE BREATH,CONSULT
WASH WITH SOAP & WATER,REMOVE CONTAMINATED CLOTHING. INGESTION: DO
NOT INDUCEVOMITING.
* Fire Fighting Measures *
Lower Limits:0.3
Extinguishing Media:CARBON DIOXIDE,DRY CHEMICAL,FOAM
Fire Fighting Procedures:SELF-CONTAIN BREATH APP,WATER FOG TO COOL
EXPOSED CONTAINER.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE FROM
PRESSURE BUILD UP WHEN EXPOSED TO EXTREME HEAT.
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
*Handling and Storage *
Handling and Storage Precautions:STORE IN ORIGINAL CONTAINER AWAY FROM
SOURCES OF IGNITION. AVOID EYE/SKIN CONTACT & BREATH VAPOR/SPRAY
MISTS. USE APPROVED BOND/GROUNDING PROCEDURES.
Other Precautions:DO NOT SMOKE,EXTINGUISH ALL SOURCES OF IGNITION
DURING USE. KEEP LID ON CONTAINER WHEN NOT IN USE. DO NOT TAKE
INTERNALLY,KEEP AWAY FROM CHILDREN.
* Physical/Chemical Properties *
HCC:F3
Vapor Density:>1
Appearance and Odor:<1 (ETHER)
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Hazardous Decomposition Products:CO,CO2,OXIDES OF NITROGEN
* Disposal Considerations *
Waste Disposal Methods:COMPLY WITH LOCAL,STATE AND FEDERAL REGULATIONS.
DO NOT INCINERATE CLOSED CONTAINERS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF AIRBORNE DUST LEVELS ARE HIGH, A NIOSH
APPROVED DUSK MASK IS RECOMMENDED TO AVOID INHALATION.
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH AFTER HANDLING.
Supplemental Safety and Health
CARBON ARE ALSO POSSIBLE.
* Product Identification *
* Composition/Information on Ingredients *
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:UREA
OSHA PEL:N/K
ACGIH TLV:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:DUST, NUISANCE; (NUISANCE DUST)
OSHA PEL:5 MG/M3 T DUST (MFR)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: POSSIBLE NAUSEA, VOMITING,
DIARRHEA - POSSIBLE SKIN OR EYE IRRITATION. CHRONIC: NONE KNOWN.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:SKIN ABRASIONS AND SORES.
INHALATION OF DUST MAY AGGRAVATE ASTHMA.
* First Aid Measures *
EYELIDS OPEN. GET MEDICAL ATTENTION IF IRRITATION PERSISTS.
INGESTION: INDUCE VOMITING OR PERFORM GASTRIC LAVAGE IF LARGE
AMOUNTS ARE INGESTED. S YMPTOMATIC AND SUPPORTIVE CARE. SKIN: WASH
THOROUGHLY. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION.
INHALATION: REMOVE TO FRESH AIR. TREAT SYMPTOMATICALLY.
* Fire Fighting Measures *
Extinguishing Media:DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:SULFUR DUST CAN FORM EXPLOSIVE MIXTURES
WITH AIR. IF PRODUCT IS CONSUMED IN A FIRE, TOXIC SULFUR DIOXIDE
WILL FORM.
* Accidental Release Measures *
Spill Release Procedures:SWEEP US SPILLS. USE GOOD HOUSEKEEPING
PRACTICES. AVOID CONTACT WITH SKIN, EYES, OR CLOTHING. WASH AFTER
HANDLING.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:SEE LABEL. AVOID CONTAINER BREAKAGE,
KEEP AWAY FROM FEED OR FOODSTUFFS. AVOID CONTACT WITH SKIN, EYES,
OR CLOTHING. KEEP OUT OF REACH OF CHILDREN.
Other Precautions:KEEP OUT OF LAKES, STREAMS, OR PONDS.
* Physical/Chemical Properties *
Appearance and Odor:GRANULAR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:IN A FIRE, THERMAL DECOMPOSITION OF
UREA & METHYLENE UREAS WILL GENERATE AMMONIA. OXIDES OF NITROGEN,
SULFUR & (SUPDAT)
* Disposal Considerations *
Waste Disposal Methods:REMOVE TO APPROVED LANDFILL IN ACCORDANCE WITH
FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:AS REQUIRED
Ventilation:AS REQUIRED
Other Protective Equipment:AS REQUIRED
Work Hygienic Practices:PRACTICE GOOD PERSONAL HYGIENE.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:DALE M. OREM
* Composition/Information on Ingredients *
Ingred Name:NON-HAZARDOUS FOR INGREDIENTS
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Explanation of Carcinogenicity:NONE
* Fire Fighting Measures *
Extinguishing Media:WATERSPRAY
Unusual Fire/Explosion Hazard:ANY ORGANIC POWDER CAN BE POTENTIALLY
EXPLOSIVE IF DISBURSED IN AIR IN CERTAIN CONCENTRATIONS. THESE
CONCENTRATIONS HAVE NOT BEEN DETERMINED.
* Accidental Release Measures *
Spill Release Procedures:SWEEP UP.
*Handling and Storage *
Other Precautions:USE OF THIS PRODUCT IN ACCORDANCE W/MANUFACTURER'S
INSTRUCTIONS SHOULD NOT RESULT IN EXPLOSIVE MIXTURES BEING FORMED.
* Physical/Chemical Properties *
Solubility in Water:COMPLETE
Appearance and Odor:LIGHT TAN BROWN POWDER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF W/NORMAL LABORATORY TRASH. FOLLOW ALL
FEDERAL, STATE, & LOCAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
* Product Identification *
Product ID:SOILMASTER
CAGE:0DAC4
CAGE:0DAC4
* Composition/Information on Ingredients *
Ingred Name:SODIUM CARBONATE (2:1); (SODA ASH)
Ingred Name:ENZYME (PROTEASE)
Fraction by Wt: <1%
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN/EYES: CAUSES IRRITATION AND
POSSIBLE SKIN RASH. INGEST: HARMFUL. CAUSES IRRITATION, STOMACH
DISTRESS. INHAL: IRRITATING TO LUNGS AND AIRWAYS, DEPENDING ON
AMOUNT AND DURATION OF EXPOSURE.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS
Medical Cond Aggravated by Exposure:PEOPLE WITH ASTHMA OR OTHER LUNG
PROBLEMS MAY BE MORE SUSCEPTIBLE.
* First Aid Measures *
First Aid:EYES: FLUSH IMMED W/PLENTY OF COOL RUNNING WATER. REMOVE
W/PLENTY OF COOL RUNNING WATER. WASH THOROUGHLY W/SOAP & WATER.
INGEST: RINS E MOUTH; THEN DRINK 1 OR 2 LARGE GLASSES OF WATER. DO
NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. INHAL: MOVE IMMED TO FRESH AIR. IF IRRIT/DISCOMFORT
PERSISTS, CALL MD.
* Fire Fighting Measures *
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:PRODUCT DOES NOT SUPPORT COMBUSTION.
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:USE PROPER PROTECTIVE EQUIPMENT. PICK UP
WITHOUT RAISING DUST. FLUSH AREA WITH WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP PRODUCT DRY. DO NOT STORE IN A
WET OR MOIST AREA.
Other Precautions:AVOID BREATHING DUSTS OR MISTS CONTAINING PRODUCT.
KEEP OUT OF REACH OF CHILDREN.
* Physical/Chemical Properties *
pH:SUPDAT
Solubility in Water:COMPLETE
Appearance and Odor:LIGHT BLUE POWDER; NO SPECIFIC ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
DO NOT MIX WITH ANYTHING BUT WATER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
* Disposal Considerations *
Waste Disposal Methods:CONSULT FEDERAL, STATE AND LOCAL AUTHORITIES FOR
RESTRICTIONS ON DISPOSAL OF CHEMICAL WASTE.
| 1 | gloves_mandatory |
Control Measures
*
*
Contractor Summary
*
*
Ingredients
*
Other REC Limits: NOT PROVIDED
OSHA PEL: 1 MG/M3
ACGIH TLV: 0.5 MG/M3
ACGIH STEL: NOT ESTABLISHED
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
------------------------------
Other REC Limits: NOT PROVIDED
OSHA PEL: NONE
ACGIH TLV: NONE
------------------------------
Percent by Wt: 2.
Other REC Limits: NOT PROVIDED
OSHA PEL: C5 MG/M3
ACGIH TLV: 5 MG/M3
ACGIH STEL: NOT ESTABLISHED
------------------------------
Other REC Limits: NOT PROVIDED
OSHA PEL: 1 MG/M3
ACGIH TLV: 1 MG/M3
------------------------------
Percent by Wt: 2.
Other REC Limits: NOT PROVIDED
ACGIH STEL: NOT ESTABLISHED
*
Health Hazards Data
*
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: EFFECTS OF EXPOSURE TO DUST, WELDING FUME AND GASES: SHORT
TERM EXPOSURE: NAUSEA, TIGHTNESS OF CHEST, FEVER, IRRITATION OF EYES, NOSE,
THROAT, AND SKIN; LOSS OF CONSCIOUSNESS DUE TO WELDING GASES OR L ACK OF
OXYGEN. LONG TERM EXPOSURE: ADVERSE EFFECTS MAY INCLUDE SKIN SENSITIZATION,
NEUROLOGICAL DAMAGE AND RESPIRATORY DISEASES (BRONCHIAL ASHTMA, LUNG FIBROSIS
ARE CONSIDERED POSSIBLE CARCINOGENS. RECENT EPIDEMIOLOGICAL STUDIES OF
WORKERS MELTING AND WORKING ALLOYS CONTAINING NICKEL-CHROMIUM HAVE FOUND NO
INCREASED RISK OF CANCER.
Explanation Of Carcinogenicity: CONTAINS CHROMIUM AND NICKEL.
Signs And Symptions Of Overexposure: UNDER NORMAL HANDLING AND USE, EXPOSURE TO
SOLID, MASSIVE FORMS OF ALLOY PRESENTS FEW HEALTH HAZARDS. THEY MAY INCLUDE
SKIN IRRITATION OR OTHER ALLERGIC REACTIONS IN SENSITIVE INDIVIDUALS. EFFECTS
OF EXPOSURE TO DUST, WELDING FUME AND GASES MAY INCLUDE NAUSEA, TIGHTNESS OF
CHEST, FEVER, IRRITATION OF EYES, NOSE, THROAT, AND SKIN; LOSS OF
CONSCIOUSNESS DUE TO WELDING GASES OR LACK OF OXYGEN.
Medical Cond Aggravated By Exposure: SENSITIVE INDIVIDUALS.
First Aid: REMOVE FROM EXPOSURE AND OBTAIN PROMPT MEDICAL ATTENTION. ADMINISTER
OXYGEN IF VICTIM IS UNCONSCIOUS. IF NOT BREATHING, RESUSCITATE IMMEDIATELY.
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Handling and Disposal
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Spill Release Procedures: UNDER NORMAL HANDLING AND USE, MATERIAL IS NOT
VOLATILE/DUSTY AND DOES NOT PRESENT SPILLAGE AND LEAKAGE PROBLEMS. NO
PROTECTION REQUIRED, EXCEPT AVOID PROLONGED OR REPEATED DIRECT SKIN CONTACT
CUTTING, GRINDING/WELDING OPERATIONS, VACUUM RESIDUE INTO SUITABLE CONTAINERS
AND DISPOSE OF IN ACCORDANCE WITH EPA/LOCAL REGULATIONS.
Neutralizing Agent: NOT RELEVANT
Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH EPA OR LOCAL REGULATIONS.
Handling And Storage Precautions: MATERIAL IN SOLID FORM DOES NOT REQUIRE
SPECIAL PRECAUTIONS IN HANDLING AND STORING. HOWEVER, USE INDUSTRIAL HYGIENE
AIR MONITORING TO ENSURE THAT THE USE OF THIS MATERIAL DOES NOT CREATE
EXPOSURES WH ICH EXCEED THE LEVELS SPECIFIED FOR INGREDIENTS PEL/TLV.
Other Precautions: NOT PROVIDED
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Fire and Explosion Hazard Information
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Flash Point Text: UNFLAMMABLE
Extinguishing Media: MATERIAL IS UNFLAMMABLE; HOWEVER, WELDING ARCS AND SPARKS
CAN IGNITE FLAMMABLE LIQUIDS AND VAPORS AND COMBUSTIBLE SOLIDS.
Fire Fighting Procedures: NONE
Unusual Fire/Explosion Hazard: NONE.
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Respiratory Protection: IF SOLID METAL ALLOYS ARE CONVERTED IN MANUFACTURING
(GRINDING, HIGH TEMPERATURE CUTTING AND WELDING) PROCESSES TO DUSTS, FUMES,
GASES/MISTS AND VENTILATION IS NOT ADEQUATE TO MAINTAIN EXPOSURES BELOW
LIMITS SPECIFIED IN INGREDIENTS' PEL/TLV, THEN RESPIRATORY PROTECTION SHOULD
Ventilation: IF SOLID METAL ALLOYS ARE CONVERTED TO DUSTS, FUMES OR MISTS,
MAINTAIN WORKING ENVIRONMENT BELOW THE EXPOSURE LIMITS WITH ADEQUATE EXHAUST
VENTILATION.
FACE PROTECTION AND FLAME RETARDANT CLOTHING. SELECT WELDING LENSE SHADE FROM
AWS PUBLICATIONS F2.2.
Work Hygienic Practices: NOT PROVIDED
Supplemental Safety and Health: ABBREVIATION: N/A = NOT APPLICABLE. N/AV = NOT
AVAILABLE. N/K = UNKNOWN. N/P = NOT PROVIDED. N/R = NOT RELEVANT. N/D = NOT
DETERMINED. N/E = NOT ESTABLISHED.
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Physical/Chemical Properties
*
HCC: N1
NRC/State LIC No: NOT RELEVANT
M.P/F.P Text: APPROX.
Decomp Text: NOT PROVIDED
Spec Gravity: (H2O=1) 7.9
Solubility in Water: 0
Appearance and Odor: GREY METALLIC WIRE, ROD OR STRIP - ODORLESS
Percent Volatiles by Volume: 0
Corrosion Rate: NOT PROVIDED
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Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: NOT PROVIDED
Materials To Avoid: AVOID ACIDS. CONTACT WITH MINERAL ACIDS WILL RELEASE
HYDROGEN- A READILY COMBUSTIBLE GAS.
Hazardous Decomposition Products: FUMES AND GASES FROM WELDING AND HIGH
TEMPERATURE CUTTING MAY INCLUDE OXIDES OF METALS, CHROMATES, FLUORIDES AND
COMPLEX METALLICS. THE GASES MAY INCLUDE CARBON MONOXIDE, OZONE AND NITROGEN
OXIDES.
Conditions To Avoid Polymerization: NOT PROVIDED
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Toxicological Information
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Toxicological Information: NOT PROVIDED
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Ecological Information
*
Ecological: NOT PROVIDED
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*
Transport Information: NOT PROVIDED
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Regulatory Information
*
Sara Title III Information: NOTE: UNDER SARA, TITLE III, IT IS REQUIRED THAT
SPECIFICALLYIDENTIFIED. THESE ARE: CHROMIUM, COPPER, MANGANESE AND NICKEL.
Federal Regulatory Information: NOT PROVIDED
State Regulatory Information: NOT PROVIDED
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Other Information
*
Other Information: NONE
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Transportation Information
*
Multiple KIT Number: 0
Unit Of Issue: CY
Type Of Container: CYLINDER
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Detail DOT Information
*
DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
Detail IMO Information
*
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
*
Detail IATA Information
*
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
Detail AFI Information
*
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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HAZCOM Label
*
Company Name: HARRISON ALLOYS INC
Status Code: A
Signal Word: NONE
Health Hazard: None
Contact Hazard: None
Fire Hazard: None
Reactivity Hazard: None
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