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===================== Product Identification ===================== Product ID:SODIUM PHOSPHATE MONOBASIC, 3820 Resp. Party Other MSDS Num.:S4750 CAGE:70829 CAGE:DO803 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM PHOSPHATE MONOBASIC, MONOHYDRATE; (SODIUM BIPHOSPHATE) CAS:7558-80-7 RTECS #:WA1900000 Minumum % Wt:98. Maxumum % Wt:100. ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT): 8290 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION: MAY CAUSE IRRITATION TO THE RESPIRATORY TRACT. SYMPTOMS MAY INCLUDE COUGHING AND SHORTNESS OF BREATH. INGESTION: PHOSPHATES ARE SLOWLY AND INCOMPLETELY ABSORBED WHEN INGESTED, AND S ELDOM RESULT IN SYSTEMIC EFFECTS. SUCH EFFECTS, HOWEVER, HAVE OCCURRED. SYMPTOMS MAY INCLUDE VOMITING, LETHARGY, DIARRHEA, BLOOD CHEMISTRY EFFECTS, HEART DISTURBANCES AND CENTRAL NERVOUS SYSTEM EFFECT S. THE TOXICITY OF PHOSPHATES IS BECAUSE OF THEIR ABILITY TO SEQUESTER CALCIUM. SKIN CONTACT: IRRITANT DUE TO ITS ACIDIC NATURE. MAY CAUSE INFLAMMATION AND PAIN ON PROLONGED CONTACT, ESPECIALLY WITH M OIST SKIN. (EFTS OF OVEREXP) Effects of Overexposure:HLTH HAZ: EYE CONTACT: MAY CAUSE IRRITATION, REDNESS AND PAIN. CHRONIC: MAY SEQUESTER CALCIUM AND CAUSE CALCIUM PHOSPHATE DEPOSITS IN THE KIDNEYS. J.T.BAKER SAF-T-DATA RATINGS HEALTH RATING: 1-SLIGHT. FLAMMABILITY RATING: 0-NONE. REACTIVITY RATING: 1-SLIGHT. CONTACT RATING: 2-MODERATE. LAB PROTECTIVE EQUIP: Medical Cond Aggravated by Exposure:NO INFORMATION FOUND. ======================= First Aid Measures ======================= First Aid:IINHALATION: REMOVE TO FRESH AIR. GET MEDICAL ATTENTION FOR ANY BREATHING DIFFICULTY. INGESTION: GIVE LARGE AMOUNTS OF WATER TO DRINK. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICA L ATTENTION. SKIN CONTACT: IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE REUSE. THOROUGHLY CLEAN SHOES BEFORE REUSE. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS. EYE CONTACT: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, LIFTING UPPER AND LOWER EYELIDS OCCASIONALLY. GET MEDICAL ATTENTION IF IRRIT ATION PERSISTS. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING SURRROUNDING FIRE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE AN EXPLOSION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT AS SPECIFIED IN SECTION 8. SPILL: SWEEP UP AND CONTAINERIZE FOR RECLAMATION OR DISPOSAL. VACUUMING OR WET SWEEPING MAY B E USED TO AVOID DUST DISPERSAL. SMALL AMOUNTS OF RESIDUE MAY BE FLUSHED TO SEWER WITH PLENTY OF WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED CONTAINER, STORED IN A COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL DAMAGE. CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTY SINCE THEY RETAIN PRODUCT RESIDUES(DUST, SOLIDS); OBSERVE ALL WARNINGS AND PRECAUTIONS LISTED FOR THE PRODUCT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOR CONDITIONS OF USE WHERE EXPOSURE TO THE DUST OR MIST IS APPARENT, A NIOSH APPROVED HALF-FACE DUST/MIST RESPIRATOR MAY BE WORN. FOR EMERGENCIES/INSTANCES WHERE EXPOSURE LEVELS ARE NOT KNOWN, USE A NIOSH APPROVED FULL-FACE POSITIVE-PRESSURE, AIR-SUPPLIED RESPIRATOR. WARNING: AIR-PURIFYING RESPIRATORS DO NOT PROTECT WORKERS IN OXYGEN-DEFICIENT ATMOSPHERES. Ventilation:SYS OF LOCAL &/GENL EXHST IS REC TO KEEP EMPLOYEE EXPOS AS LOW AS POSS. LOC EXHST VENT IS GENERALLY PREFERRED BECAUSE IT CAN CONTROL EMISSIONS (SUPDAT) Other Protective Equipment:EYE WASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health VENT: OF THE CONTAMINANT AT IS SOURCE, PREVENTING DISPERSION OF IT INTO THE GENERAL WORK AREA. PLEASE REFER TO ACGIH DOCUMENT, INDUSTRIAL VENTILATION, A MANUAL OF RECOMMENDED PRACTICES, MOST RECENT ED ITION, FOR DETAILS. PHYSICAL DATA: VAP DENS: NO INFORMATION FOUND. ================== Physical/Chemical Properties ================== Boiling Pt:=203.9C, 399.F Melt/Freeze Pt:=100.C, 212.F M.P/F.P Text:LOSES WATER Vapor Pres:NO INFO FOUND. Vapor Density:SUPDAT Spec Gravity:2.04 pH:4.5 Evaporation Rate & Reference:NO INFO FOUND. Solubility in Water:59.9 G/100G @ 0C (32F) Appearance and Odor:WHITE CRYSTALLINE POWDER; ODORLESS. Percent Volatiles by Volume:@ 21C(70F):0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NO INCOMPATIBILITY DATA FOUND. Stability Condition to Avoid:SLIGHTLY HYGROSCOPIC. Hazardous Decomposition Products:PHOSPHORUS OXIDES MAY FORM WHEN HEATED TO DECOMPOSITION. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information=================== Toxicological Information:ANHYDROUS: ORAL RAT LD50: 8290 MG/KG. ===================== Ecological Information ===================== Ecological:ENVIRONMENTAL FATE: NO INFORMATION FOUND. ENVIRONMENTAL TOXICITY: NO INFORMATION FOUND. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY/RECYCLING SHOULD BE MANAGED IN AN APPROPRIATE & APPROVED WASTE DISPOSAL FACILITY. PROCESSING, USE/CONTAMINATION OF THIS PRODUCT MAY CHANGE WASTE MANAGEMENT OPTIO N. STATE & LOCAL DISPOSAL REGS MAY DIFFER FROM FEDERAL DISPOSAL REGS. DISPOSE OF CONTAINER & UNUSED CONTENTS I/A/W FED, STATE & LOCAL REQUIREMENTS. . =================== MSDS Transport Information =================== Transport Information:NOT REGULATED. ===================== Regulatory Information ===================== SARA Title III Information:SODIUM BIPHOSPHATE (7558-80-7) SARA 302 RQ: NO, TPQ: NO; SARA 313 LIST: NO, CHEMICAL CATG.: NO. SARA 311/312: ACUTE: YES, CHRONIC: NO, FIRE: NO, PRESSURE: NO; REACTIVITY: NO (MIXTURE/SOLID) Federal Regulatory Information:CHEMICAL INVENTORY STATUS PART 1: SODIUM BIPHOSPHATE (7558-80-7) TSCA:YES , EC: YES , JAPAN: YES, AUSTRALIA: YES. CHEMICAL INVENTORY STATUS PART 2: SODIUM BIPHOSPHATE (7558-80-7) KOREA:YES, DSL: YES , NDSL: NO, PHIL: YES. FED, ST & INTERNATIONAL REGS PART 2: SODIUM BIPHOSPHATE CERCLA: NO, RCRA 261.33: NO, TSCA 8(D):NO. CHEMICAL WEAPONS CONVENTION: NO, TSCA 12(B): NO, CDTA: NO. WHMIS: THIS MSDS H AS BEEN PREPARED ACCORD TO HAZ CRITERIA OF THE CTL PROD REG (CPR) AND MSDS CONTAINS ALL OF INFO REQU IRED BY THE CPR. State Regulatory Information:OTHER INFO: IF SWALLOWED, GIVE LARGE AMOUNTS OF WATER TO DRINK. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION. PRODUCT USE: LABORATORY REAGENT. REVSION INFORMATION: NEW 16 SECTION MSDS FORMAT, ALL SECTIONS HAVE BEEN REVISED. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:OXYGEN IN THE CYLINDER (NSN IS FOR THE EMPTY CYLINDER) CAGE:99227 CAGE:99227 ============= Composition/Information on Ingredients ============= Ingred Name:OXYGEN CAS:7782-44-7 RTECS #:RS2060000 Fraction by Wt: 100% % Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT GIVEN FOR PRODUCT AS A WHOLE Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS. CONTACT WITH LIQUID OXYGEN CAN CAUSE SEVERE FROSTBITE/FREEZE BURNS. MAY CAUSE VISUAL DISTURBANCES. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:CNS EFFECTS, FROSTBITE, FREEZE BURNS, VISUAL DISTURBANCES. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH TEPID WATER. GET MEDICAL ASSISTANCE. SKIN: FLUSH AFFECTED AREAS WITH LOTS OF TEPID WATER. DO NOT RUB FROZEN AREA. GET MEDICAL ASSISTANCE. INHALATION: CONSCIOUS PERSON SHOULD BE ASSIST ED TO FRESH AIR. PATIENT SHOULD BE KEPTWARM AND QUIET. UNCONSCIOUS PERSONS SHOULD BE MOVED TO AN UNCONTAMINATED AREA AND ARTIFICIAL RESPIRATION SHOULD BE PERFORMED. GET MEDICAL ATTENTION AT ONCE. ===================== Fire Fighting Measures ===================== Flash Point:FLAMMABLE Lower Limits:NOT GIVEN Upper Limits:NOT GIVEN Extinguishing Media:FOAM, ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG Fire Fighting Procedures:DANGEROUSLY EXPLOSIVE. COOL ALL AFFECTED CONTAINERS WITH FLOODING QUANTITIES OF WATER. APPLY WATER FROM AS FAR AWAY AS POSSIBLE. WEAR PROPER PERSONAL PROTECTION Unusual Fire/Explosion Hazard:APPROACH FIRE WITH CAUTION. IF FIRE IS UNCONTROLLABLE OR CONTAINER IS EXPOSED TO DIRECT FLAME, EVACUATE AREA FOR A RADIUS OF 1,500 FEET. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE ALL PERSONNEL FROM THE DANGER AREA. PROVIDE OPTIMUM EXHAUST VENTILATION. SHUT OFF THE SOURCE OF OXYGEN LEAK IF YOU CAN DO SO WITHOUT RISK. REMOVE SOURCES OF HEAT AND IGNITION. SEPARATE COMBUS TIBLES FROM THE LEAK IF POSSIBLE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE OXYGEN CONTAINERS IN A CLEAN, COOL, DRY, WELL-VENTILATED, LOW FIRE RISK AREA, AWAY FROM COMBUSTIBLE MATERIALS AND ACETYLENE CYLINDERS. Other Precautions:PROTECT CONTAINERS AGAINST PHYSICAL DAMAGE. FOLLOW GENERAL SAFETY PROCEDURES FOR HANDLING COMPRESSED GAS CYLINDERS. NEVER EXPOSE ANY PART OF THE CYLINDER TO TEMPERATURES ABOVE 125F. GROUND EQUIPMENT T O ELIMINATE BUILDUP OF STATIC CHARGE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURE MAY OR DOES EXCEED OCCUPATION EXPOSURE LIMITS USE A NIOSH-APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. IN ACCORD WITH 29 CFR 1910.134 USE EITHER AN ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AI R-PURIFYING RESPIRATOR. Ventilation:PROVIDE VENTILATION TO PREVENT ACCUMULATION ABOVE 23% BY VOLUME. Other Protective Equipment:CHEMICAL RESISTANT CLOTHING AS NECESSARY TO PREVENT SKIN CONTACT. AN EMERGENCY EYEWASH AND SHOWER SHOULD BE AVAILABLE. Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES. Supplemental Safety and Health THIS HMIS ENTRY IS FOR OXYGEN PLACED IN THE CYLINDER. THIS NSN IS FOR THE EMPTY CYLINDER. ================== Physical/Chemical Properties ================== HCC:G3 Boiling Pt:B.P. Text:-297F,-183C Melt/Freeze Pt:M.P/F.P Text:-360F,-218C Vapor Pres:NOT GIVEN Vapor Density:1.1 Spec Gravity:NOT GIVEN Evaporation Rate & Reference:NOT GIVEN Solubility in Water:MODERATE Appearance and Odor:COLORLESS, ODORLESS GAS Percent Volatiles by Volume:100% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES PRODUCT IS STRONG OXIDIZER. REACTS WITH MANY ORGANIC COMPOUNDS AT CONCENTRATIONS GREATER THAN 23% BY VOLUME. Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, OPEN FLAMES Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:REMOVE WASTE CONTAINERS OR LEAKING CYLILNDERS TO AN OPEN OUTDOOR AREA AWAY FROM COMBUSTIBLES AND ALLOW THE OXYGEN TO DISCHARGE AT A MODERATE RATE. TAG A LEAKING CYLINDER TO INDICATE DEFECT, CLOSE VALV E AND RETURN CYLINDER TO ITS SUPPLIER.
1
eyes_protection_mandatory
======================================================= Product ID: STRONG ALUMINUM (ACTIVATOR), 60450 (5 OZ TUBE) Cage: 66724 ======================================================= Contractor Summary ======================================================= Cage: 66724 ======================================================= Ingredients ======================================================= Cas: 68953-36-6 % Wt: 5-10 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ----------------------------- Cas: 112-57-2 RTECS #: KH8585000 (TETRAETHYLENEPENTAMINE) % Wt: 1-2 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 68082-29-1 % Wt: 20-30 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 67762-90-7 % Wt: 1-2 OSHA PEL: 6 MG/M3 ACGIH TLV: 10 MG/M3 ------------------------------ Cas: 90-72-2 RTECS #: SN3500000 METHYL) PHENOL % Wt: 2-3 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 37244-96-5 % Wt: 50-60 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE:INHALTION:IRRITATION TO UPPER RESPIRATORY TRACT. EYES:EXTREMELY IRRITATING WITH POSSIBLE PERMANENT EYE INJURY. SKIN:CORROSIVE, EXPECTED TO CAUSE SEVERE SKIN DAMAGE WITH BURNS & BLISTERING. INGES TION:MAY CAUSE BURNS OF MOUTH & THROAT.MAY CAUSE GASTROINTESTINAL IRRITATION OR ULCERATION. CHRONIC: (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: HLTH HAZ:PROLONGED OR REPEATED EXPOSURE MAY CAUSE RESPIRATORY AND SKIN SENSITIZATION OR OTHER ALLERGIC RESPONSE. Medical Cond Aggravated By Exposure: ASTHMA, CHRONIC RESPIRATORY DISEASE (E.G. BRONCHITIS, EMPHYSEMA). First Aid: INHAL:REMOVE PERSON TO FRESH AIR. GET MED ATTN IF EFTS PERSIST. ADMIN OXYG IF NEC. EYES:FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS, LIFTING UPPER & LOWER LIDS. SEEK IMMED MED ATTN. SKIN:REMOVE CONTA MD CLTHG & WASH CONT AREA W/SOAP & WATER THORO. WASH CLTHG BEFORE REUSE & DISCARD CONTAMD LEATHER ARTICLES. GET MED ATTN IF SWELLING/REDDENING OCCURS. INGEST:SEEK MED ATTN. DO NOT INDUCE (SUPDAT) ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: DIKE SPILL. ABSORB WITH INERT MATERIAL AND COLLECT FOR DISPOSAL. FLUSH AREA WITH WATER. PREVENT WASHING FROM ENTERING WATERWAYS. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSE OF AS A HAZARDOUS WASTE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. Handling And Storage Precautions: NONE SPECIFIED BY MANUFACTURER. Other Precautions: THIS PROD HAS BEEN REVIEWED ACCORDING TO EPA (HAZ CATEGORIES" PROMULGATED UNDER SECTIONS 311 & 312 OF SUPERFUND AMENDMENT & REAUTHORIZATION ACT OF 1986 (SARA TITLE III) & IS CONSIDERED UNDER APPLIC DE FINITIONS, TO MEET FOLLOWING (SUPDAT) ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: PMCC Flash Point Text: >240F,>116C Extinguishing Media: USE WATER FOG, FOAM, CARBON DIOXIDE (CO*2) OR DRY CHEMICAL. Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). REMOVE ALL IGNITION SOURCES. USE A WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard: CLOSED CONTAINERS MAY RUPTURE (DUE TO BUILDUP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT. TOXIC FUMES WILL BE EVOLVED IF THIS MATERIAL BURNS. ======================================================= Control Measures ======================================================= Respiratory Protection: WEAR A PROPERLY FITTED NIOSH APPRVD RESPIRATOR WHENEVER EXPOS TO VAP/MIST IS LIKELY. Ventilation: LOC EXHAUST IS REC WHEN APPROP TO CONTROL EMPLOYEE EXPOS. MECH IS NOT REC AS SOLE MEANS OF CONTROLLING EMPLOYEE EXPOS. Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N). FOR OPERATIONS WHERE CONT CAN OCCUR, COVERALLS, APRON & RUBBER (SUPDAT) Work Hygienic Practices: WASH HANDS W/SOAP & WATER AFTER USE AND/OR BEFORE BREAKS, LUNCH & AT END OF WORK PERIODS. REMOVE CONTAMD CLTHG (SUPDAT) Supplemental Safety and Health: MATLS TO AVOID:W/EPOXY RESINS IN MASSES >2 INCHES THICK. FIRST AID PROC:VOMIT. DILUTE BY GIVING WATER/MILK TO DRINK IF VICTIM IS CONSCIOUS. OTHER PREC:CATEGORIES:IMMED HLTH HAZ. EYE PROT:& FULL LENGTH FSHLD (FP N). OTHER PROT EQUIP:FOOT COVERING ARE REC. HYGIENE PRACT:& LAUNDER BEFORE REUSE. DISCARD CONTAMD SHOES. ======================================================= Physical/Chemical Properties ======================================================= Vapor Density: >1 Solubility in Water: SLIGHT Appearance and Odor: WHITE PASTE, AMINE ODOR. Percent Volatiles by Volume: 0 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: EXCESSIVE HEAT. Materials To Avoid: STRONG OXIDIZING AGENTS, MINERAL ACIDS, HALOGENATED ORG, ALDEHYDES, KETONES, & ACRYLATES. UNCONTROLLED CURING (SUPDAT) Hazardous Decomposition Products: FUMES PRODUCED WHEN HEATED TO DECOMPOSITION MAY INCLUDE:CARBON MONOXIDE, CARBON DIOXIDE, AMMONIA, AND NITROGEN OXIDES. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: STRONG ALUMINUM (ACTIVATOR), 60450 (5 OZ TUBE) Cage: 66724 Company Name: LPS LABORATORIES, INC. Street: 4647 HUGH HOWELL ROAD Zipcode: 30085-5052 Label Required IND: Y Date Of Label Review: 08/30/1996 Status Code: C Label Date: 08/30/1996 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Severe Fire Hazard: Slight Reactivity Hazard: Slight Hazard And Precautions: DECOMPOSITION PRODUCTS MAY BE HARMFUL. ACUTE:INHALTION:IRRITATION TO UPPER RESPIRATORY TRACT. EYES:EXTREMELY IRRITATING WITH POSSIBLE PERMANENT EYE INJURY. SKIN:CORROSIVE, EXPECTED TO CAUSE SEVERE SKI N DAMAGE WITH BURNS & BLISTERING. INGESTION:MAY CAUSE BURNS OF MOUTH & THROAT. MAY CAUSE GASTROINTESTINAL IRRITATION OR ULCERATION. CHRONIC:PROLONGED OR REPEATED EXPOSURE MAY CAUSE RESPIRATORY AND SKI N SENSITIZATION OR OTHER ALLERGIC RESPONSE. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GLYCEROL, 2135 Resp. Party Other MSDS Num.:G4774 CAGE:70829 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:GLYCEROL; (GLYCERIN MIST) CAS:56-81-5 RTECS #:MA8050000 Minumum % Wt:90. Maxumum % Wt:100. OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (ORAL, RAT) 12,600 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: DUE TO THE LOW VAPOR PRESSURE, INHALATION OF VAPORS AT ROOM TEMPERATURES IS UNLIKELY. INHALATION OF MIST MAY CAUSE IRRITATION OF RESPIRATORY TRACT. INGESTION: LOW TOXICITY. MAY CAUSE NAUSE A, HEADACHE, DIARRHEA. SKIN CONTACT: MAY CAUSE IRRITATION. EYE CONTACT: MAY CAUSE IRRITATION. CHRONIC EXPOSURE: MAY CAUSE KIDNEY INJURY. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS OR EYE PROBLEMS OR IMPAIRED LIVER OR KIDNEY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. GET MEDICAL ATTENTION FOR ANY BREATHING DIFFICULTY. INGESTION: INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSC IOUS PERSON. GET MEDICAL ATTENTION. SKINCONTACT: IMMEDIATELY FLUSH SKIN W/PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE REUSE. THOROUGHLY CLEAN SHOES BEFORE REUSE. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS. EYE CONTACT: IMMEDIATELY FLUSH EYES W/PLENTY OF WATER FOR AT LEAST 15 MINUTES, LIFTING UPPER AND LOWER EYELIDS OCCASIONALLY. GET MEDIC AL ATTENTION IF IRRITATION PERSISTS. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:=198.9C, 390.F Autoignition Temp:=370.C, 698.F Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING SURROUNDING FIRE. WATER SPRAY MAY BE USED TO EXTING SURROUNDING FIRE & COOL EXPOS CNTNRS. WATER SPRAY WILL ALSO REDUCE FUME & IRRITANT GASES. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:SLIGHT FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. ABOVE FLASH POINT, VAPOR-AIR MIXTURES ARE EXPLOSIVE WITHIN FLAMMABLE LIMITS NOTED ABOVE. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT AS SPECIFIED IN EXPOSURE CONTROLS/PERSONAL PROTECTION. CONTAIN & RECOVER LIQUID WHEN POSSIBLE. COLLECT LIQUID IN AN APPR OPRIATE CONTAINER OR ABSORB WITH AN INERT MATERIAL (EG VERMICULITE, DRY SAND, EARTH), & PLACE IN A CHEMICAL WASTE CONTAINER. DO NOT USE COMBUSTIBLE MATERIALS, SUCH AS SAW DUST. DO NOT FLUSH TO SEWER! ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED CONTAINER, STORED IN A COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL DAMAGE. ISOLATE FROM INCOMPATIBLE SUBSTANCES. Other Precautions:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTY SINCE THEY RETAIN PRODUCT RESIDUES (VAPORS, LIQUID); OBSERVE ALL WARNINGS AND PRECAUTIONS LISTED FOR THE PRODUCT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF THE EXPOS LIMIT IS EXCEEDED, A NIOSH APPRVD HALF-FACE DUST/MIST RESP MAY BE WORN FOR UP TO TEN TIMES THE EXPOS LIMIT OR MAX USE CONC SPECIFIED BY THE APPROP REGULATORY AGENCY OR RESP SUPPLIER, WHIC HEVER IS LOWEST. A NIOSH APPRVD FULL-FACE PIECE DUST/MIST RESP MAY BE WORN UP TO 50 TIMES THE EXPOS LIMIT OR THE MAX USE CONCENTRATION SPECIFIED BY THE (SUPDAT) Ventilation:A SYSTEM OF LOCAL &/OR GENERAL EXHAUST IS RECOM TO KEEP EMPLOYEE EXPOS BELOW AIRBORNE EXPOS LIMITS. LOCAL EXHAUST VENT GENERALLY PREF BECAUSE (TRANSPORT INFO) Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER . WEAR CLEAN BODY-COVERING CLOTHING. Supplemental Safety and Health RESP PROT: APPROP REGULATORY AGENCY OR RESP SUPPLIER, WHICHEVER IS LOWEST. FOR EMERS OR INSTANCES WHERE EXPOS LEVELS ARE NOT KNOWN, USE A NIOSH APPRVD FULL-FACEPIECE POS-PRESS, AIR SUPPLIED RESP. WARN ING: AIR-PURIFYING RESPS DO NOT PROTECT WORKERS IN OXYGEN-DEFICIENT ATMOSPHERES. ================== Physical/Chemical Properties ================== Boiling Pt:=290.C, 554.F Melt/Freeze Pt:=18.C, 64.4F Vapor Pres:0.0025 @ 50C(122F) Vapor Density:3.17 AIR=1 Spec Gravity:1.26 @ 20C/4C pH:NEUT TO LITMUS Evaporation Rate & Reference:NO INFO FOUND Solubility in Water:MISCIBLE Appearance and Odor:CLEAN OILY LIQUID; ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. CAN REACT VIOLENTLY WITH ACETIC ANHYDRIDE, CALCIUM OXYCHLORIDE, CHROMIUM OXIDES AND ALKALI METAL HYDRIDES. Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE AND STORAGE. AVOID HEAT, FLAMES, IGNITION SOURCES AND INCOMPATIBLES. Hazardous Decomposition Products:TOXIC GASES AND VAPORS MAY BE RELEASED IF INVOLVED IN A FIRE. GLYCERIN DECOMPOSES UPON HEATING ABOVE 290C, FORMING CORROSIVE GAS (ACROLEIN). =================== Toxicological Information=================== Toxicological Information:LD50: (ORAL, RAT) 12,600 MG/KG. INVESTIGATED AS A MUTAGEN, REPRODUCTIVE EFFECTOR. CANCER LISTS: GLYCERIN MIST (56-81-5): NTP CARCINOGEN - KNOWN: NO, ANTICIPATED: NO. IARC CATEGORY: NONE. ===================== Ecological Information ===================== Ecological:WHEN RELEASED INTO SOIL, THIS MATERIAL IS EXPECTED TO READILY BIODEGRADE. WHEN RELEASED INTO SOIL, THIS MATERIAL IS NOT EXPECTED TO EVAPORATE SIGNIFICANTLY. WHEN RELEASED INTO WATER, THIS MATERIAL IS EXPECTED TO READILY BIODEGRADE. THIS MATERIAL IS NOT EXPECTED TO SIGNIFICANTLY BIOACCUMULATE. WHEN RELEASED INTO AIR, THIS MATERIAL MY BE MODERATELY DEGRADED BY REACTION WITH PHOTOCHEMICALLY PRODUCED HYDROXYL RADICALS. WHEN RELEASED INTO THE AIR, THIS MATERIAL MAY BE REMOVED FROM THE ATMOSPHERE TO A MODERATE EXTENT BY WET DEPOSITION. ENVIRONMENTAL TOXICITY: THIS MATERIAL IS NOT EXPECTED TO BE TOXI C TO AQUATIC LIFE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY OR RECYCLING SHOULD BE MANAGED IN AN APPROPRIATE & APPROVED WASTE DISPOSAL FACILITY. PROCESSING, USE OR CONTAMINATION OF THIS PRODUCT MAY CHANGE WASTE MANAGEMENT OPTIONS. STATE & LOCAL DISPOSAL REGS MAY DIFFER FROM FEDERAL DISPOSAL REGS. DISPOSE OF CONTAINER & U NUSED CONTENTS I/A/W FEDERAL, STATE & LOCAL REQS. =================== MSDS Transport Information =================== Transport Information:NOT REGULATED. VENT: IT CAN CONTROL EMISSIONS OF CONTAMINANT AT ITS SOURCE, PREVENTING DISPERSION OF IT INTO THE GENERAL WORK AREA. PLEASE REFER TO THE ACGIH DOCUMENT, INDUSTRIAL VENTILATION, A MANUAL OF RECOMMENDED PRACTICES, MOST RECENTEDITION, FOR DETAILS. EXPOS CONTROLS/PERSONAL PROT: AIRBORNE EXPOS LIMITS: FOR GLYCERINE MIST: -OSHA PERMISSIBLE EXPOSURE LIMIT (PEL): TOTAL DUST: 15 MG/M3 (TWA);RESPIRABLE FRACTION: 5 MG/M3 (TWA). -ACGIH THRESHOLD LIMIT VALUE (TLV): 10 MG/M3. ===================== Regulatory Information ===================== SARA Title III Information:GLYCERIN MIST (56-81-5): FEDERAL, STATE & INTERNATIONAL REGULATIONS - PART 1: SARA 302 - RQ-NO, TPQ-NO. SARA 313 - LIST-NO, CHEMICAL CATG-NO. SARA 311/312: ACUTE:YES, CHRONIC:YES, FIRE:NO, PRESSURE:NO , REACTIVITY:NO (PURE/LIQUID) Federal Regulatory Information:GLYCERIN MIST (56-81-5): CHEMICAL INVENTORY STATUS - PART 1: TSCA-YES. EC-YES. JAPAN-YES. AUSTRALIA-YES. CHEMICAL INVENTORY STATUS - PART 2: KOREA:YES. CANADA - DSL-YES, NDSL-YES. PHIL-YES. FEDERAL, S TATE & INTERNATIONAL REGULATIONS - PART 2: CERCLA-NO. RCRA 261.33-NO. TSCA 8(D)-NO. CHEMICAL WEAPONS CONVENTION: NO. TSCA 12(B): NO. CDTA: NO. AUSTRALIAN HAZCHEM CODE: NO INFO FOUND. POISON SCHEDULE: NO INFO FOUND. WHMIS: THIS MSDS HAS BEEN PREPARED ACCORDING TO THE HAZARD CRITERIAL OF THE CONTROLLE D PRODUCTS REGULATIONS (CPR) & THE MSDS CONTAINS ALL OF THE INFO REQUIRED BY THE CPR. State Regulatory Information:N/P. OTHER INFO: STRATEGIC SERVICES RATINGS (PROVIDED HERE FOR YOUR CONVENIENCE): HEALTH RATING: 1-SLIGHT, FLAMMABILITY RATING: 1-SLIG HT, REACTIVITY RATING: LAB COAT. STORAGE COLOR CODE: ORANGE (GENERAL STORAGE). ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DYNAGARD BLUE, WIRE ROPE LUBRICANT, WINTER GRADE CAGE:1E969 CAGE:1E969 CAGE:0AHK0 ============= Composition/Information on Ingredients ============= Ingred Name:ZINC DITHIOPHOSPHATE CAS:19210-06-1 RTECS #:TE4800000 Fraction by Wt: 1.5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:BENZENE, 1,2,4-TRIMETHYL-; (PSEUDOCUMENE) (SARA 313) CAS:95-63-6 RTECS #:DC3325000 OSHA PEL:25 PPM ACGIH TLV:25 PPM Ingred Name:LITHIUM HYDROXIDE CAS:1310-65-2 RTECS #:OJ6307070 Fraction by Wt: 0.72% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:XYLENE (SARA 313) (CERCLA). %:0.09-0.14. CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: <0.14% OSHA PEL:100 PPM ACGIH TLV:100 PPM;150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ZINC; (ZINC (ELEMENTAL ANALYSIS)) (SARA 313) (CERCLA) CAS:7440-66-6 RTECS #:ZG8600000 Fraction by Wt: 0.14% OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:CASTOR OIL, HYDROGENATED CAS:8001-78-3 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:BASE OILS (CONTAINING TWO OR MORE OF INGS 8 - 15) RTECS #:9999999ZZ Fraction by Wt: >75% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SOLVENT DEWAXED RESIDUAL OIL (PETROLEUM); (RESIDUAL OILS (PETROLEUM), SOLVENT-DEWAXED) CAS:64742-62-7 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:MINERAL OIL; (LUBRICATING OILS (PETROLEUM), C>25 HYDROTREATED BRIGHT STOCK-BASED) CAS:72623-83-7 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:MINERAL OIL, PETRO DISTILLATES, HYDROTREATED (SEVERE) HEAVY NAPHTHENIC; (DISTILS (PETRO), HYDROTREATED HEAVY NAPHTHENIC) CAS:64742-52-5 RTECS #:PY8035001 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:MINERAL OIL, PETRO DISTILLATES, SOLV-REFINED (SEVERE) HEAVY NAPHTHENIC; (DISTILS (PETRO), SOLV-REFINED HEAVY NAPHENIC) CAS:64741-96-4 RTECS #:PY8040001 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:MINERAL OIL, PETRO DISTILS, SOLVENT-DEWAXED HEAVY PARAFFINIC (SEVERE SOLVENT-REFINING AND/OR HYDROTREATMENT); (ING 13) CAS:64742-65-0 RTECS #:PY8038501 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ING 12:(DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC) RTECS #:9999999ZZ OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:MINERAL OIL, PETRO DISTILS, HYDROTREATED (SEVERE) HEAVY PARAFFINIC; (DISTILS (PETRO), HYDROTREATED HEAVY PARAFFINIC) CAS:64742-54-7 RTECS #:PY8035501 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SOLVENT REFINED RESIDUM; (RESIDUAL OILS (PETROLEUM), SOLVENT-REFINED) CAS:64742-01-4 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:BUTENE, POLYMERS; (BUTENE, HOMOPOLYMER) CAS:9003-29-6 RTECS #:EM9032000 Fraction by Wt: <8% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:LITHIUM 12 HYDROXYSTEARATE; (OCTADECANOIC ACID, 12-HYDROXY-, MONOLITHIUM SALT) CAS:7620-77-1 Ingred Name:SUPDAT:INTERMITTENT DRY CREEKS. RPT SPILLS TO COAST GUARD TOLL FREE NUMBER (800)424-8802. IN CASE OF ACCIDENT/ (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18:SPILL NOTIFY CHEMTREC (800) 424-9300. RTECS #:9999999ZZ Ingred Name:WASTE DISP METH:RECYCLING FACILITY/CAN BE DISP OF AT ANY GOVT APPRVD WASTE DISP FACILITY. USE OF THESE METHS IS (ING 21) RTECS #:9999999ZZ Ingred Name:ING 20:SUBJECT TO USER COMPLIANCE W/APPLIC LAWS & REGS & CONSIDERATION OF PROD CHARACTS AT TIME OF DISP. RCRA: (ING 22) RTECS #:9999999ZZ Ingred Name:ING 21:UNUSED PROD, IN MFR'S OPINION, IS NOT SPECIFICALLY LISTED BY EPA AS HAZ WASTE (40 CFR, PART 261D); DOES (ING 23) RTECS #:9999999ZZ Ingred Name:ING 22:NOT EXHIBIT HAZ CHARACTS OF IGNITABILITY, CORROSIVITY/REACTIVITY, & IS NOT FORMULATED W/CONTAMS LISTED IN(ING 24) RTECS #:9999999ZZ Ingred Name:ING 23:TOX CHARACTS (TC) RULE AS DETERMINED BY TOX CHARACTS LEACHING PROC (TCLP). HOWEVER, USED PROD MAY BE REGULATED. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SLIGHT EYE IRRITATION. ACUTE TOXICITY:ORAL (RATS)/DERMAL (RABBITS) TOXICITY:SLIGHTLY TOXIC - BASED ON TESTING OF SIMILAR PRODUCTS &/OR COMPONENTS. EYE IRRITATION (RABBITS):MAY CAUSE SLIGHT IRRITATION - BASED ON TESTING OF SIMILAR PRODUCTS &/OR COMPONENTS. CHRONIC TOXICITY:THE BASE OILS IN THIS PRODUCT (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:ARE SEVERELY SOLVENT REFINED &/OR SEVERELY HYDROTREATED. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR. SUPPORT BRTHG (GIVE O*2/ARTF RESP) . EYES:FLUSH THORO W/WATER FOR AT LST 15 MINS. IF IRRIT PERSISTS, CALL MD. SKIN:WASH CONT AREAS W/SOAP & WATER. HIGH PRESS ACCIDENTA L INJECTION THRU SKIN REQS IMMED MED ATTN FOR POSS INCISION, IRRIGATION &/OR DEBRIDEMENT. INGEST:IF >1/2 LITER (PINT) INGESTED, IMMED GIVE 1-2 GLASSES OF WATER & CALL MD, HOSPITAL EMER ROOM/ (SUPDAT) ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:>400F,>204C Lower Limits:0.6% Upper Limits:7% Extinguishing Media:CARBON DIOXIDE, FOAM, DRY CHEMICAL & WATER FOG. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP. WATER/FOAM MAY CAUSE FROTHING. USE WATER TO KEEP FIRE EXPOS CNTNRS COOL. WATER SPRAY MAY BE USED TO FLUSH(SUPDAT) Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:ADSORB ON FIRE RETARDANT TREATED SAWDUST, DIATOMACEOUS EARTH, ETC. SHOVEL UP & DISP OF AT APPROP WASTE DISP FACILITY I/A/W CURRENT APPLIC LAWS & REGS & PROD CHARACTS AT TIME OF DISP. RPT SPILLS AS REQ D TO APPROP AUTHS. U.S. COAST GUARD REGS (SUPDAT) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NO SPECIAL PRECAUTIONS REQUIRED. Other Precautions:AVOID REPEATED SKIN CONTACT. BASED ON AVAILABLE TOXICOLOGICAL INFORMATION, IT HAS BEEN DETERMINED THAT THIS PRODUCT POSES LITTLE OR NO ADVERSE EFFECTS ON HEALTH WHEN PROPERLY HANDLED & USED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . NO SPECIAL REQUIREMENTS UNDER ORDINARY CONDITIONS OF USE & W/ADEQUATE VENTILATION. Ventilation:NO SPECIAL REQUIREMENTS UNDER ORDINARY CONDITIONS OF USE & W/ADEQUATE VENTILATION. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . NO SPECIAL EQUIPMENT REQUIRED. Work Hygienic Practices:GOOD PERSONAL HYGIENE PRACTICES SHOULD ALWAYS BE FOLLOWED. Supplemental Safety and Health FIRE FIGHT PROC:SPILLS AWAY FROM EXPOS. PVNT RUNOFF FROM FIRE CONTROL/DILUTION FROM ENTERING STREAMS, SEWERS/DRINKING WATER SUPPLY. FIRST AID PROC:POIS CTL CTR FOR ASSISTANCE. DO NOT INDUCE VOMIT/GIVEANYTHING BY MOUTH TO UNCON PERS. SPILLPROC:REQ IMMED REPORTING OF SPILLS THAT COULD REACH ANY WATERWAY INCL (ING 18) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>600F,>316C Solubility in Water:NEGLIGIBLE Appearance and Odor:BLUE GREASE; MILD ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:EXTREME HEAT. Hazardous Decomposition Products:CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISP MUST BE I/A/W FED, STATE & LOC REGS . PROD IS SUITABLE FOR BURNING IN ENCLSD, CONTROLLED BURNER FOR FUEL VALUE/DISP BY SUPERVISED INCIN. SUCH BURNING MAY BE LTD PURSUANT TO RCRA. IN ADDN, P ROD IS SUITABLE FOR PROCESSING BY APPRVD (ING 20)
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ENAMEL, INTERIOR SEMI-GLOSS WHITE 27778 Preparer's Name:ED DOENGES CAGE:60189 CAGE:60189 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL SPIRITS (STODDARD SOLVENT) CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: 24.9% Other REC Limits:NONE SPECIFIED OSHA PEL:500 PPM ACGIH TLV:100 PPM; 9293 Ingred Name:CALCIUM CARBONATE (LIMESTONE) CAS:1317-65-3 RTECS #:EV9580000 Fraction by Wt: 21.8% Other REC Limits:NONE SPECIFIED OSHA PEL:10 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:MAGNESIUM SILICATE (TALC) CAS:14807-96-6 RTECS #:WW2710000 Fraction by Wt: 4.4% Other REC Limits:NONE SPECIFIED OSHA PEL:10 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:TITANIUM DIOXIDE (TITANIUM OXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 21.8% Other REC Limits:NONE SPECIFIED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: IRRITATION OF EYES AND SKIN MAY OCCUR WITH OVEREXPOSURE. CONTINUED BREATHING OF VAPORS MAY IRRITATE RESPIRATORY TRACT. CHRONIC: REPORTS HAVE ASSOCIATED PROLONGED OCCUPATIONAL OVEREXPOSURE TO SO LVENTS WITH PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. Effects of Overexposure:HEADACHE, NAUSEA, AND DIZZINESS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE VICTIM TO FRESH AIR. RESTORE RESPIRATION, IF NECESSARY, TREAT SYMPTOMATICALLY. EYE CONTACT: FLUSH IMMEDIATELY WITH COPIOUS AMOUNTS OF WATER FOR 15 MINUTES. CONSULT A PHYSICIAN. SKIN CONTACT: WASH AFFECTED AREA WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. INGESTION: DO NOT INDUCE VOMITING. CONTACT PHYSICIAN IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:105F,41C Lower Limits:1.0 Upper Limits:6.0 Extinguishing Media:CO2, DRY CHEMICAL Fire Fighting Procedures:USE SCBA. WATER SPRAY MAY BE USEFUL IN MINIMIZING VAPORS & COOLING CONTAINERS EXPOSED TO HEAT AND FLAMES. Unusual Fire/Explosion Hazard:NO INFORMATION FOUND. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. WEAR APPROPRIATE PERSONAL PROTECTION EQUIPMENT AND APPROVED RESPIRATOR. CONTAIN SPILL & PUT IN VAPOR TIGHT CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN AREAS TO COMPLY WITH ANSI-NFPA 30 FLAMMABLE AND COMBUSTIBLE LIQUIDS CODE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE APPROVED NIOSH/MSHA ORGANIC VAPOR RESPIRATOR. Ventilation:SUFFICIENT VENT TO KEEP HAZARDOUS MATERIALS BELOW APPLICABLE EXPOSURE LEVELS. Work Hygienic Practices:WASH HANDS PROPERLY BEFORE EATING, DRINKING, OR USING WASHROOM FACILITIES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:323F,162C Vapor Pres:2 Vapor Density:>1 Spec Gravity:1.375 Viscosity:77 - 89 KU Evaporation Rate & Reference:<1 (BU AC=1) Solubility in Water:N/L Appearance and Odor:LIQUID, ALIPHATIC ODOR Percent Volatiles by Volume:49.9 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS Stability Condition to Avoid:HEAT, OPEN FLAME Hazardous Decomposition Products:CO, CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER: D001. IGNITABILITY.
1
eyes_protection_mandatory