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===================== Product Identification =====================
Product ID:6604105 4B4-FITC
Preparer's Name:S HEALY
CAGE:FO645
CAGE:FO645
CAGE:6Z677
============= Composition/Information on Ingredients =============
Ingred Name:SODIUM AZIDE, AZIDE *96-4*
CAS:26628-22-8
RTECS #:VY8050000
Other REC Limits:0.1 PPM
ACGIH TLV:C 0.29 MG/CUM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: NASAL IRRITATION. SKIN:
IRRITATION, ABSORPTION, ALLERGIC REACTION. EYES: IRRITATIONS,
CONJUNCTIVITIS. INGESTION: BRONCHIAL IRRITATION, RESPIRATORY
IRRITATION, RESPIRATORY FAILURE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, HEADACHE, DIZZINESS, FAINTNESS,
NAUSEA, LOW BLOOD PRESSURE, BLURRED VISION, SHORTNESS OF BREATH,
COLLAPSE, BRONCHITIS, PALPITATION, WEAKNESS & UNSTEADINESS, COMA,
CONVULSIONS.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE CPR.
IF BREATHING IS DIFFICULT GIVE OXYGEN. SKIN: WASH OFF THOROUGHLY
FOR 15 MINS. EYES: RINSE THOROUGHLY W/WATER & GIVE PLENTY OF WATER
TO DRIN K. INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:DRY CHEMICALS SUCH AS AN SODIUM CARBONATE/SAND.
Fire Fighting Procedures:BURNING SODIUM AZIDE WILL EXPLODE IF WATER IS
USED AS AN EXTINGUISHING MEDIA. SCBA MUST BE WORN.
Unusual Fire/Explosion Hazard:MAY EXPLODE & RELEASE TOXIC FUMES UPON
HEATING. DON'T ALLOW TO CONTACT METALS AT HIGH TEMPS.
(SUPP)
================== Accidental Release Measures ==================
Spill Release Procedures:DILUTE W/RUNNING WATER BEFORE DISCHARGE.
DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE AWAY FROM METALS & ACIDS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED
Ventilation:GENERAL/LOCAL EXHAUST TO MEET TLV REQUIREMENTS
Other Protective Equipment:ADEQUATE LABORATORY ATTIRE
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
UNUSUAL FIRE CONT'D: FORMS HIGHLY SENSITIVE EXPLOSIVE COMPOUNDS W/HEAVY
METALS SUCH AS LEAD, SILVER & COPPER. WHEN HEATED TO 662F IT
DECOMPOSES EXOTHERMICALLY, BURNING W/A VERY HOT FLAME & PRODUCING N
ITROGEN & MOLTEN SODIUM.
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:527F
Spec Gravity:1.85
Solubility in Water:40.16
Appearance and Odor:WHITE-COLORLESS CRYSTALS/POWDER, ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
METALS, ACIDS, ACID CHLORIDES & STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HEAT
Hazardous Decomposition Products:NITROGEN OXIDES, HYDRAZOIC ACID
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:CRONEX X-RAY LIQUID FIXER-PART A/XLF-A
CAGE:DO962
CAGE:18873
CAGE:DO962
============= Composition/Information on Ingredients =============
Ingred Name:AMMONIUM THIOSULFATE; CAS #7783-18-8
CAS:7783-18-8
RTECS #:XN6465000
Fraction by Wt: 45.0%
Ingred Name:SODIUM ACETATE; CAS #127-09-3
CAS:126-96-5
RTECS #:AJ4375000
Fraction by Wt: <5.0%
Ingred Name:BORIC ACID; CAS #10043-35-3
CAS:10043-35-3
RTECS #:ED4550000
Fraction by Wt: <5.0%
Ingred Name:SODIUM BISULFITE (SASA III)
CAS:7631-90-5
RTECS #:VZ2000000
Fraction by Wt: <5.0%
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3; 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:GLUCONIC ACID; CAS #526-95-4
CAS:526-95-4
RTECS #:LZ5057100
Fraction by Wt: <5.0%
===================== Hazards Identification =====================
Effects of Overexposure:EYES/SKIN:CAUSES IRRITATION;INHAL:MIST/DRY
POWDER MAY CAUSE RESP TRACT IRRIT;INGEST:GI IRRIT,DIARR.
======================= First Aid Measures =======================
First Aid:SKIN:WASH W.SOAP & H*2O. EYES:FLUSH W. H*2O. INGESTED:DON'T
INDUCE VOMITING. INHALED:REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF
NEED. KEEP WARM & QUIET. REMOVE CONTAMINATED CLOTHING. NEVER GIVE
ANYTHING BY MOUTH TO UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:EXTINGUISH WITH AGENT SUITABLE FOR SURROUNDING FIRE
Fire Fighting Procedures:EVACUATE PERSONS TO SAFE AREA&KEEP UNWIND.WEAR
SCBA.COOL CON
Unusual Fire/Explosion Hazard:NONE NOTED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:USE APPROPRIATE PERSONA PROTECTIVE EQUIP
DURING CLEAN UP.DIKE SPILL.PREVENT LIQUID FROM ENTERING
SEWERS,WATERWAYS OR LOW AREAS.SOAK UP WITH SAWDUST,SAND,OIL DRY OR
OTHER ABSORBENT MATERIAL.SPILL MAY B E NEUTRALIZE W SODIUM
BICARBONATE BEFOREDISPOSL.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED
AREA. PROTECT FROM PHYSICAL DAMAGE.AVOID ANY PHYSICAL CONTACT. KEEP
CONTAINERS TIGHTLY CLOSED
Other Precautions:USE ONLY W/ADEQUAT VENTILATION.DO NOT MIX W/STRONG
BASES.DO NOT STORE OR CONSUME FOOD IN AREA WHERE THEY MAY BECOME
CONTAMNTD WITH THIS MATL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF NEEDED,USE CHEMICAL CARTRIDGE RESPIRATOR
W/ORGANIC VAP CARTRIDGE
Ventilation:NO SPECIAL REQUIREMENTS W ADEQUATE VENT.
Other Protective Equipment:FULL WORK CLOTHING TO PREVENT REPEATED OR
PROLONGED CONTACT.
Supplemental Safety and Health
MSDS FROM DUPONT CO MEETS OSHA STDS BUT NOT DATED;THIS DESCRIBES PART A
OF A 2 PARTS PRODUCT;SEE PNI-B FOR OTHER PART.KEY1:N1.
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:>212F/>100C
Spec Gravity:1.3
Solubility in Water:COMPLETE
Appearance and Odor:LIGHT AMBER,CLEAR LIQUID,SLIGHT SO*2 ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG BASES
Stability Condition to Avoid:EXCESSIVE HEAT
Hazardous Decomposition Products:OXIDES OF S, &/OR CARBON.
==================== Disposal Considerations ====================
Waste Disposal Methods:RECOVER NONUSABLE FREE LIQUID AND/OR
CONTAMINATED WATER,AND DISPOSE OF IN AN APPRVD BIOLOGICAL TREATMENT
SYSTEM OR AN APPRVD DEEPWELL.RMV NONUSABLE SOLID MATL &/OR
CONTAMNTD SOIL,FOR DISPOSAL IN AN AP PRVD LANDFILL.FED,STATE,LOCAL
REGS TAKEPRECEDENCE
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:SPRAY PAINT, 7862 PEANUT BEIGE
CAGE:54636
CAGE:54636
============= Composition/Information on Ingredients =============
Ingred Name:PROPANE; (PROPANE (PROPELLANT)) VP: 760.0
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: 15%
OSHA PEL:1000 PPM
ACGIH TLV:ASPHYXIANT; 9495
Ingred Name:PROPANE, 2-METHYL-; (2-METHYLPROPANE (PROPELLANT)) VP:
760.0
CAS:75-28-5
RTECS #:TZ4300000
Fraction by Wt: 15%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:TOLUENE (SARA 313) (CERCLA) VP: 22.0
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 21%
OSHA PEL:200 PPM; Z-2
ACGIH TLV:S, 50 PPM; 9495
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:BENZENE, ETHYL-; (ETHYL BENZENE) (SARA 313) VP: 7.1
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: 2%
OSHA PEL:100 PPM
ACGIH TLV:100 PPM/125STEL;9495
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:XYLENES (SARA 313) (CERCLA) VP: 5.9
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 6%
OSHA PEL:100 PPM
ACGIH TLV:100 PPM/150STEL;9495
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:ACETONE (SARA 313) (CERCLA) VP: 180.0
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 17%
OSHA PEL:1000 PPM
ACGIH TLV:750PPM/1000STEL;9495
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:PROPIONIC ACID, 3-ETHOXY-, ETHYL ESTER;
(ETHYL-3-ETHOXYPROPIONATE) VP: 1.1
CAS:763-69-9
RTECS #:UF3325000
Fraction by Wt: 4%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 11%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9495
Ingred Name:EFTS OF OVEREXP:CHRONIC:TOLUENE APPEARS ON NAVY LISTING OF
OCCUP CHEM REPRO HAZ. SEEK CONSULTATION FROM APPROP (ING 10)
RTECS #:9999999ZZ
Ingred Name:ING 9:HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO &
SAFE HDLG & EXPOS INFO . (ING 11)
RTECS #:9999999ZZ
Ingred Name:ING 10:CHRONIC OVEREXP TO LEAD MAY RESULT IN DMG TO (ING
12)
RTECS #:9999999ZZ
Ingred Name:ING 11:BLOOD-FORMING, NERVOUS, URINARY, & REPRO SYS (INCL
EMBRYOTOXIC EFTS). SYMPS INCL ABDOM DISCOMFORT/PAIN, (ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12:CONSTIPATION, LOSS OF APPETITE, METALLIC TASTE,
NAUS, INSOMNIA, NERVOUS IRRITABILITY, WEAK, MUSCLE & (ING 14)
RTECS #:9999999ZZ
Ingred Name:ING 13:JOINT PAINS, HDCH & DIZZ. CHROMATES ARE LISTED BY
IARC & NTP. ALTHOUGH STUDIES HAVE ASSOC EXPOS TO (ING 15)
RTECS #:9999999ZZ
Ingred Name:ING 14:CHROMIUM VI CMPDS W/INCR RISK OF RESP CANCER, AVAIL
EVID INDICATES THAT LEAD CHROMATE (CHROM YELLOW, (ING 16)
RTECS #:9999999ZZ
Ingred Name:ING 15:MOLYBDATE ORANGE) DOES NOT PRESENT THIS HAZ. PRLNG &
RPTD EXPOS TO HEXANE MAY CAUSE DMG TO NERVE TISSUE (ING 17)
RTECS #:9999999ZZ
Ingred Name:ING 16:OF ARMS & LEGS (PERIPHERAL NEUROPATHY), RESULTING IN
MUSCULAR WEAK & LOSS OF SENSATION. THIS EFT MAY (ING 18)
RTECS #:9999999ZZ
Ingred Name:ING 17:BE INCRD BY PRESENCE OF METHYL ETHYL KETONE. METHYL
ETHYL KETONE MAY INCR NERVOUS SYS EFFECTS OF OTHER (ING 19)
RTECS #:9999999ZZ
Ingred Name:ING 18:SOLVS. PRLNG OVEREXP TO SOLV INGRED IN SECTION II
MAY CAUSE ADVERSE EFTS TO THE LIVER, URINARY, BLOOD (ING 20)
RTECS #:9999999ZZ
Ingred Name:ING 19:FORMING, CARDIO-VASCULAR, & REPRO SYS. RATS EXPOS TO
TITANIUM DIOXIDE DUST AT 250 MG/M3 DEVELOPED LUNG (ING 21)
RTECS #:9999999ZZ
Ingred Name:ING 20:CANCER, HOWEVER, SUCH EXPOSURE LEVELS ARE NOT
ATTAINABLE IN THE WORKPLACE. REPORTS HAVE ASSOCIATED (ING 22)
RTECS #:9999999ZZ
Ingred Name:ING 21:REPEATED AND PROLONGED OVEREXPOSURE TO SOLVENTS WITH
PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE.
RTECS #:9999999ZZ
Ingred Name:WASTE DISP METH:DO NOT INCINERATE. DEPRESSURIZE CNTNR.
DISPOSE OF I/A/W/FED, STATE, & LOCAL REGS REGARDING POLLUTION.
RTECS #:9999999ZZ
Ingred Name:RESP PROT:DRIED FILM, WEAR A PARTICULATE RESP APPRVD BY
NIOSH FOR PROT AGAINST NON-VOLATILE MATERIALS IN SECTION II.
RTECS #:9999999ZZ
Ingred Name:OTHER PREC:GROUNDING PROCEDURES. CONTENTS UNDER PRESS. FOR
MORE SPECIFIC INFORMATION CONTACT NEHC .
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EXPOS MAY BE BY INHAL &/SKIN/EYE
CNTCT, DEPENDING ON CNDTNS OF USE. ALCOHOLS & ACETATES CAN BE
ABSORBED THRU SKIN. FOLLOW RECOMMENDATIONS FOR PROPER USE, VENTS, &
PERS PROT EQUIP TO MINIMIZE EXPOS. AC UTE:IRRIT OF EYES, SKIN &
RESP SYS. MAYCAUSE NERVOUS SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:UNCONSCIOUSNESS & POSS DEATH.
ACUTE:OCCUP EXPOS TO LEAD IS UNCOMMON, BUT RSLTS IN EFTS & SYMPS
SIMILAR TO CHRONIC OVEREXP DESCRIBED BELOW. SIGNS & SYMPS OF
OVEREXP:HEADACHE, DIZZ, NAUS, & LOS S OF COORDINATION ARE
INDICATIONS OF EXCESSIVE EXPOS TO VAPS/SPRAY MISTS. REDNESS &
ITCHING/BURNING (SUPDAT)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
======================= First Aid Measures =======================
First Aid:INHAL:IN AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING.
KEEP WARM & QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY WITH SOAP &
H*2O. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE RE-USE.
EYES:FLUSH WIT H LARGE AMOUNTS OF H*2O FOR AT LEAST 15MINUTES. GET
MEDICAL ATTENTION. INGEST:NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. DO NOT INDUCE VOMIT. GIVE SEVERAL GLASSES OF
H*2O. SEEK MED ATTN.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:<0F,<-18C
Lower Limits:0.7%
Upper Limits:6.0%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFT. IF H*2O IS USED, FOG NOZZLES ARE PREF.
H*2O MAY BE USED TO COOL CLSD CNTNRS (SUPDAT)
Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM
HEAT, ELEC EQUIP, SPARKS, & OPEN FLAME. CLSD CNTNRS MAY EXPLODE
WHEN EXPOSED TO EXTREME HEAT. APPLICATION TO HOT (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:CONTENTS ARE EXTREMELY FLAMMABLE. KEEP
AWAY FROM HEAT, SPARKS, AND OPEN FLAME. VAPORS WILL ACCUMULATE
READILY AND MAY IGNITE EXPLOSIVELY.
Other Precautions:DURING USE & UNTIL ALL VAP ARE GONE:KEEP AREA VENT-DO
NOT SMOKE-EXTING ALL FLAMES, PILOT LIGHTS, & HEATERS-TURN OFF
STOVES, ELECTRIC TOOLS & APPLIANCES, & ANY OTHER SOURCES OF IGNIT.
CONSULT NEPA CODE . USE APPRVD BONDING & (ING 25)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF PERS EXPOS CANNOT BE CONTROLLED BELOW APPLIC
LIMITS BY VENT, WEAR PROPERLY FITTED ORG VAP/PARTICULATE RESP
APPRVD BY NIOSH FOR PROT AGAINST MATLS IN INGRED SECTION. WHEN
SANDING, WIREBRUSHING, ABRA DING, BURNING/WELDING (ING 24)
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS TO MATLS IN
SECTION II IS MAINTAINED BELOW APPLIC EXPOSURE LIMITS.
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA. .
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
FIRE FIGHT PROC:TO PVNT PRESS BUILD-UP & POSS AUTOIGNITION/EXPLOSION
WHEN EXPOS TO EXTREME HEAT. EXPLO HAZ:SURFS REQS SPECIAL PRECS.
DURING EMER CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMP
MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN. EFTS OF
OVEREXP:SENSATION MAY INDICATE EYE/EXCESSIVE SKIN EXPOSURE. (ING 9)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:<0F,<-18C
Vapor Pres:SEE ING
Vapor Density:HVR/AIR
Evaporation Rate & Reference:FASTER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:>75
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE, OXIDES OF METALS IN INGREDIENT SECTION.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE FROM THIS PROD MAY BE HAZ AS DEFINED UNDER
RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERM
APPLIC EPA HAZ WASTE NUMBERS. WASTE FROM PROD CNTNG METHYL ETHYL
KETONE MAY ALSO REQ T ESTING FOR EXTRACTABILITY. (ING 23)
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:X189 TRIS HYDROCHLORIDE
CAGE:016E9
CAGE:016E9
============= Composition/Information on Ingredients =============
Ingred Name:TRIS HYDROCHLORIDE*96-2*
CAS:1185-53-1
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:NO EFFECTS/HEALTH HAZARDS IDENTIFIED.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:NO EFFECTS/HEALTH HAZARDS IDENTIFIED.
Medical Cond Aggravated by Exposure:NONE
======================= First Aid Measures =======================
First Aid:INGESTION: IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING.
INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NECESSARY.
SKIN: FLUSH W/WATER. EYES: IMMEDIATELY FLUSH W/PLENTY OF WATER FOR
15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING
FIRE.
Fire Fighting Procedures:WEAR PROPER PROTECTIVE EQUPMENT & SELF
CONTAINED BREATHING APPARATUS W/FULL FACEPIECE OPERATED IN POSITIVE
PRESSURE MODE.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR SELF CONTAINED BREATHING APPARATUS & FULL
PROTECTIVE CLOTHING. W/CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO
CLEAN, DRY CONTAINER & COVER; REMOVE FROM AREA. FLUSH AREA W/WATER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED.
SUITABLE FOR ANY GENERAL CHEMICAL STORAGE AREA.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF AIRBORNE CONCENTRATION IS HIGH, USE AN
APPROPRIATE RESPIRATOR/DUST MASK.
Ventilation:USE ADEQUATE GENERAL/LOCAL EXHAUST TO KEEP FUME/DUST LEVELS
AS LOW AS POSSIBLE.
Other Protective Equipment:UNIFORM
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Solubility in Water:>10%
Appearance and Odor:WHITE CRYSTALS W/NO ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:AMMONIA, HYDROGEN CHLORIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:DIESEL/DOT ENGINE STARTING FLUID,1909400,QK-2107-C 49
CAGE:78280
CAGE:45152
CAGE:78280
============= Composition/Information on Ingredients =============
Ingred Name:ETHYL ETHER (CERCLA)
CAS:60-29-7
RTECS #:KI5775000
Fraction by Wt: 91%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:400 PPM
ACGIH TLV:400PPM/500STEL; 9596
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:ETHYLENE (SARA 313)
CAS:74-85-1
RTECS #:KU5340000
Fraction by Wt: 6.5%
Other REC Limits:NONE RECOMMENDED
ACGIH TLV:ASPHYXIANT; 9596
Ingred Name:ETHYL ALCOHOL (ETHANOL)
CAS:64-17-5
RTECS #:KQ6300000
Fraction by Wt: 2%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM; 9596
Ingred Name:BTH/2,6-DI-TERT-BUTYL-P-CRESOL
CAS:128-37-0
RTECS #:GO7875000
Fraction by Wt: 1% PPM
Other REC Limits:NONE RECOMMENDED
OSHA PEL:10 MG/M3
ACGIH TLV:10 MG/M3; 9596
===================== Hazards Identification =====================
LD50 LC50 Mixture:TLV FOR DIETHYL ETHER IS 400 PPM.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, CNS,
RESPIRATORY & GI TRACTS. ACUTE- EYES:MAY CAUSE IRRITATION/REDNESS.
SKIN:IRRITATION & DEFATTING WITH PROLONGED/REPEATED CONTACT.
INHALE:MAY CAUSE DIZZINESS, NARCOSIS, UNCO NCIOUSNESS. ORAL:MAY
CAUSE NAUSEA, VOMITING & IRRITATION OF GI TRACT. ASPIRATION HAZARD.
CHRONIC- UNKNOWN.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, TEARING, REDNESS, DRYNESS OF SKIN
AND DEFATTING, DIZZINESS, HEADACHE, NAUSEA, VOMITING, BLURRED
VISION
======================= First Aid Measures =======================
First Aid:GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH WATER FOR
15 MINUTES. HOLD EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER.
INHALED:MOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NECESSARY. ORAL:DO
NOT INDUCEVOMITING EXCEPT ON ADVICE OF COMPETENT MEDICAL
PERSONNEL. IF CONSCIOUS, DRINK 1-2 GLASSES OF WATER/MILK. DO NOT
INDUCE VOMITING OR GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:-49F,-45C
Lower Limits:1.9%
Upper Limits:48%
Extinguishing Media:USE FOAM, DRY CHEMICAL OR CARBON DIOXIDE. WATER MAY
BE INEFFECTIVE BUT SHOULD BE USED TO COOL FIRE-EXPOSED CONTAINERS.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND
NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL
FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:EXTREMELY FLAMMABLE. OVERHEATED, CLOSED
CONTAINERS COULD EXPLODE DUE TO INTERNAL PRESSURE BUILDUP. VAPORS
MAY TRAVEL TO AN IGNITION SOURCE AND FLASH BACK.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. ELIMINATE SOURCES
OF IGNITION. VENTILATE AREA. PICK UP SPILL WITH NON-FLAMMABLE
ABSORBENT SUCH AS SAND, EARTH, VERMICULITE. GROUND ALL HANDLING
EQUIPMENTS. PREVENT LIQUID FR OM ENTERING SEWERS OR WATERWAYS.
Neutralizing Agent:NOT RELEVANT
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, WELL VENTILATED AREA
AWAY FROM SPARKS, FLAME, OTHER SOURCES OF IGNITION & INCOMPATIBLE
MATERIALS. DO NOT STORE ABOVE 175F.
Other Precautions:PROTECT CYLINDERS FROM PHYSICAL DAMAGE. AVOID
BREATHING VAPOR/MIST. AVOID CONTACT WITH EYES & SKIN. FOR
INDUSTRIAL USE ONLY. VAPORS CAN BE IGNITED EASILY. KEEP OUT OF
REACH OF CHILDREN. SMOKING SHOULD BE PROHIBITED IN STORAGE AREAS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NORMALLY REQUIRED. IF TLV IS EXCEEDED OR
FOR SYMPTOMS OF OVER EXPOSURE, WEAR NIOSH-APPROVED ORGANIC VAPOR
RESPIRATOR OR AIR-PURIFYING RESPIRATOR. IN EMERGENCY, WEAR A
NIOSH-APPROVED POSITIVE-PRES SURE SELF-CONTAINED BREATHING
APPARATUS.
Ventilation:MECHANICAL (GENERAL AND/OR LOCAL EXHAUST, EXPLOSION-PROOF)
VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER.
INDUSTRIAL-TYPE WORK CLOTHING, APRON, AND BOOTS IF SPILLS OR
SPLASHING CAN OCCUR.
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. WASH AFTER HANDLING AND BEFORE EATING OR
DRINKING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:G2
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:=34.4C, 94.F
Vapor Pres:5548
Vapor Density:2.6
Spec Gravity:0.695
Evaporation Rate & Reference:6.9 (N-BUTYL ACETATE=1)
Solubility in Water:MODERATE
Appearance and Odor:COLORLESS LIQUID - STRONG ETHEREAL ODOR
Percent Volatiles by Volume:99.5
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HEAT, SPARKS, HOT SURFACES, FLAME, AIR,
LIGHT, EVAPORATION TO DRYNESS (LONG STANDING FORMS PEROXIDE.)
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
ALDEHYDES
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS. ALLOW SPILL TO EVAPORATE. ALLOW CYLINDER TO BE
USED COMPLETELY, THEN DISPOSE OF IN NORMAL TRASH. DO NOT PUT IN
COMPACTORS. DO NOT P UNCTURE, MUTILATE OR INCINERATE CYLINDERS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:DC-348 ORANGE SOFT TOUCH
Preparer's Name:REGULATORY DEPARTMENT
CAGE:HO922
CAGE:HO922
============= Composition/Information on Ingredients =============
Ingred Name:BENZOIC ACID, P-HYDROXY-, PROPYL ESTER; (PROPYL PARABEN)
CAS:94-13-3
RTECS #:DH2800000
Ingred Name:GLUTARONITRILE, 2-BROMO-2-(BROMOMETHYL)-;
(1,2-DIBROMO-2,4-DICYANOBUTANE)
CAS:35691-65-7
RTECS #:MA5599000
Ingred Name:9-OCTADECENOIC ACID,(Z)-; (9-OCTADECENOIC ACID)
CAS:112-80-1
RTECS #:RG2275000
Fraction by Wt: 2-9%
Ingred Name:CLAY KAOLIN; (CLAY)
CAS:1332-58-7
RTECS #:GF1670500
Fraction by Wt: 1-6%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:2 MG/M3 TDUST; 9293
Ingred Name:CYCLOHEXENE, 1-METHYL-4-(1-METHYLETHYLENYL)-, (R)-;
(D'LIMONENE)
CAS:5989-27-5
RTECS #:GW6360000
Ingred Name:PARAFFIN-NAPTHANES; (ADEPSINE OIL)
CAS:64742-88-7
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3
Ingred Name:BENZOIC ACID, P-HYDROXY-, METHYL ESTER; (METHYL PARABEN)
CAS:99-76-3
RTECS #:DH2450000
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY CAUSE DERMATITIS, NERVOUS SYSTEM
DEPRESSION, AND IRRITATION TO EYES. USE PROPER HYGIENE TO AVOID
THESE HAZARDS.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:IRRITATION OF EYES. INGESTION MAY CAUSE NERVOUS
SYSTEM DEPRESSION.
Medical Cond Aggravated by Exposure:PERSON WITH PRE-EXISTING SKIN
DISORDERS MAY BE SUSCEPTIBLE TO EXPOSURE OF THIS PRODUCT.
======================= First Aid Measures =======================
First Aid:INGESTION: DO NOT INDUCE VOMITING, CALL DOCTOR IMMEDIATELY.
EYES: IRRIGATE FOR AT LEAST 15 MINUTES. SEE PHYSICIAN. INHALATION:
GET TO FRESH AIR. SKIN: WASH OFF WITH WATER OR WIPE OFF.
===================== Fire Fighting Measures =====================
Flash Point:NONE TO BOILING
Extinguishing Media:DRY CHEMICAL, FOAM, CARBON DIOXIDE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . KEEP EXPOSED CONTAINERS COOL WITH WATER
SPRAY TO PREVENT CONTAINER FAILURE.
Unusual Fire/Explosion Hazard:NONE KNOWN.
================== Accidental Release Measures ==================
Spill Release Procedures:CAUTION: MAY CREATE SLIP HAZARD. SHOVEL INTO
SUITABLE CONTAINERS. PICK UP REMAINDER ON CLAY. WASH WITH WATER
(RETAIN IF HAZARDOUS ACCORDING TO RELEVANT STATUTES).
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE BETWEEN 40F AND 130F. KEEP AWAY
FROM CHILDREN.
Other Precautions:FOLLOW LABEL DIRECTIONS CAREFULLY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT USUALLY NECESSARY.
Ventilation:LOCAL EXHAUST ACCEPTABLE.
Other Protective Equipment:NOT NECESSARY.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:212F,100C
Melt/Freeze Pt:M.P/F.P Text:135F,57C
Spec Gravity:0.9 (H*2O=1)
Solubility in Water:EMULSIFIABLE
Appearance and Odor:OPAQUE ORANGE RINGING GEL WITH CITRUS FRAGRANCE.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:EXCESSIVE HEAT OR COLD.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONSULT LOCAL, STATE AND FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:AMOCO LDO ALL-SEASON MOTOR OIL SAE 10W-30
CAGE:15958
CAGE:15958
CAGE:2V812
============= Composition/Information on Ingredients =============
Ingred Name:PETROLEUM OILS
Fraction by Wt: UNK
===================== Hazards Identification =====================
Effects of Overexposure:EYES:MINIMALLY IRRITATING;SKIN:SLIGHTLY
IRRITATING;INH:NONE;ING:PRACTICALL NONTOXIC FOR ACUTE.
======================= First Aid Measures =======================
First Aid:EYES:FLUSH W/PLENTY OF H*2;SKIN:NONE REQD FOR UNUSED
OIL.CONTACT W/USED MOTOR OIL-WASH EXPOSED SKIN THOROUGHLY W/SOAP &
WATER;INGESTION:IF A LARGE AMT IS SWALLOWED,INDUCE VOMITING.GET
MEDICAL ATTENTIO N
===================== Fire Fighting Measures =====================
Flash Point:400F,MIN (COC)
Extinguishing Media:AGENTS FOR CL B FIRES(DRY
CHEM,CO*2,FOAM,HALOCARBN,STEAM),FO
Fire Fighting Procedures:NONE KNOWN
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE IGN SOURCES.STOP LEAK W/O RISK.USE
SPILL;SM SPILL:ABSORB W/COMMERCIAL ABSORBENT & CONTAIN IN COVERED
DRUM;LG SPILL:DIKE LIQ.PUMP INTO SALVAGE TANK.SHOVEL RESIDUE TO
COVERED DRUM.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED
AREA. PROTECT FROM PHYSICAL DAMAGE.AVOID ANY PHYSICAL CONTACT. KEEP
CONTAINERS TIGHTLY CLOSED
Other Precautions:CAUTION:CONTINUOUS LONG TERM CONTCT W/USED OIL HAS
CAUSED CANCER IN ANIMAL TESTS;USE WATERLESS HAND CLEANER TO REMOVE
OILS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED
Ventilation:GENERAL(MECH)/AREA
Supplemental Safety and Health
MSDS FM MFR IAW OSHA HAZ COMMUNICATION STD IS DATED:20-3-85; SPEC REF:
MIL-L-46152B,GRADE 10W-30; VISCOSITY AT 210F.
================== Physical/Chemical Properties ==================
HCC:V6
Spec Gravity:0.88
Viscosity:59.7-63-4 SUS
Solubility in Water:NEGLIGIBLE
Appearance and Odor:PALE TO LIGHT RED COLORED OILY LIQUID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN
Stability Condition to Avoid:IGNITION SOURCES
Hazardous Decomposition Products:C, CO, CO*2, VARIOUS HYDROCARBONS &
THEIR DERIVATIVES.
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE IN APPROVED INCINERATOR OR DISPOSE OF
IN APPROVED CHEMICAL DUMP IN ACCORDANCE WITH LOCAL,STATE & FEDERAL
REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:QUEST II, 9272
CAGE:NCHEM
CAGE:NCHEM
============= Composition/Information on Ingredients =============
Ingred Name:NONE (MFR).
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN: CORROSIVE TO SKIN. EYE:
CORROSIVE TO EYES. INHAL: MAY BE IRRITATING TO THROAT, NASAL
PASSAGES AND MUCOUS MEMBRANES. INGEST: CORROSIVE TO THROAT AND
STOMACH.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:SKIN: RINSE IMMED WITH WATER. SEEK MEDICAL ATTENTION. EYE:
FLUSH IMMEDIATELY WITH PLENTY OF WATER FOR AT LEAST 15 MIN. CONSULT
PHYSICIAN. INHAL: MOVE TO FRESH AIR. IF IRRIT PERSISTS, SEEK
MEDICAL ATTE NTION. INGEST: RINSE MOUTH AND GIVE PLENTY OF WATER,
FOLLOWED BY MILK, EGG WHITE OR GRUEL. DO NOT INDUCE VOMITING.
IMMEDIATELY SEEK MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:EXTINGUISHING MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.
================== Accidental Release Measures ==================
Spill Release Procedures:ABSORB SPILL WITH AN ABSORBENT MATERIAL (I. E.
SELIG'S AP ABSORBENT); PICK UP AND DEPOSIT IN A SEALABLE CONTAINER
FOR DISPOSAL AS A HAZARDOUS WASTE. THOROUGHLY CLEAN AREA WITH A
DETERGENT SOLUTION. RI NSE AREA THOROUGHLY WITH CLEAN WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP OUT OF REACH OF CHILDREN. HARMFUL
IF SWALLOWED. AVOID CONTACT WITH SKIN AND EYES. KEEP CONTAINER
CLOSED WHEN NOT IN USE.
Other Precautions:CONTAINER MAY BURST IF HEATED ABOVE 120F. DO NOT USE,
STORE, POUR OR SPILL NEAR HEAT SOURCE OR OPEN FLAME.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:GOOD VENTILATION IS ALL THAT IS REQUIRED.
Other Protective Equipment:CUBBER APRON. EMERGENCY EYEWASH AND DELUGE
SHOWER MEETING ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
WASTE DISP: CONSULT LOCAL, STATE AND FEDERAL AGENCIES FOR PROPER
DISPOSAL PROCEDURES IN YOUR AREA. IF COMPANY EFFLUENT IS ULTIMATELY
TREATED BY A PUBLICLY OWNED SEWAGE TREATMENT PLANT, SPENT PRODUCT M
AY BE NEUTRALIZED AND DISCARDED TO SEWER.
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:212F,100C
Spec Gravity:1.005
pH:4.0
Solubility in Water:100 %
Appearance and Odor:COLORLESS, ODORLESS LIQUID.
Percent Volatiles by Volume:97%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:AVOID FREEZING TEMPERATURES. DO NOT
EVAPORATE AND BURN.
Hazardous Decomposition Products:MAY DECOMPOSE TO FORM TOXIC/CORROSIVE
GASES IF EXPOSED TO HIGH HEAT.
==================== Disposal Considerations ====================
Waste Disposal Methods:UNUSED PROD MAY HAVE TO BE ABSORBED ON AN INERT
MATL (SELIG'S AP ABSORBENT) & DISP OF AS HAZ WASTE. SML HAZ WASTE
GENERATOR SHLD CONSULT CFR TITLE 40, PART 261.5 FOR POSSIBLE
EXEMPTION. SINCE REGS VAR Y CONCERNING THE DISP OF THESE CHEMS,
(SUPP DATA)
| 1 | gloves_mandatory |
=======================================================
NIIN: 01-386-8419
Product ID: ELECTRONIC SOLV #631-914 (BULK FORMULATED)
Cage: 3T389
=======================================================
Item Description Information
=======================================================
Item Manager: S9G
Item Name: CLEANING COMPOUND,SOLVENT
Specification Number: NONE
Type/Grade/Class: NONE
Unit of Issue: DR
Quantitative Expression: 00000000055GL
UI Container Qty: 0
Type of Container: STEEL DRUM
=======================================================
Ingredients
=======================================================
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NOT PROVIDED
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: NONE KNOWN.
Explanation Of Carcinogenicity: NOT LISTED IN NTP OR IARC MONOGRAPH. NOT
REGULATED BY OSHA.
Signs And Symptions Of Overexposure: INHALATION: DIZZINESS, POSSIBLE CARDIAC
ARRHYTHMIA AT VERY HIGH CONCENTRATIONS. EYES: IRRITATION. SKIN: DEFATTING,
IRRITATION. INGESTION: GASTRO-INTESTINAL IRRITATION.
Medical Cond Aggravated By Exposure: NONE KNOWN.
First Aid: INHALATION: REMOVE TO FRESH AIR; IF BREATHING DIFFICULT, GET MEDICAL
ATTENTION. FIRST AID-ARTIFICIAL RESPIRATION. EYES: FLUSH WITH WATER FOR 15
MINUTES. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION. SKIN: WASH WITH
SOAP/WATER. INGESTION: DO NOT INDUCE VOMITING; GET MEDICAL ATTENTION.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: PRODUCT WILL EVAPORATE UPON CONTACT WITH SURFACE.
VENTILATE AREA AND EVACUATE PERSONNEL UNTIL CONCENTRATION BELOW TLV. VAPORS
WILL ACCUMULATE IN LOW AREAS. DO NOT FLUSH TO SEWER.
Neutralizing Agent: NOT RELEVANT
Waste Disposal Methods: DOT APPROVED CONTAINERS FOR DISPOSAL. IN ACCORDANCE
WITH ALL REGULATIONS.
Handling And Storage Precautions: KEEP CONTAINER CLOSED WHEN NOT IN USE. DO NOT
STORE IN OPEN UNLABELED, OR MISLABELED CONTAINERS. STORE IN COOL, DRY AREA.
Other Precautions: NOT PROVIDED
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: PMCC
Flash Point Text: NONE
Lower Limits: 7.6
Upper Limits: 17.7
Extinguishing Media: WATER, DRY CHEMICAL, CO2.
Fire Fighting Procedures: NIOSH APPROVED SELF CONTAINED BREATHING APPARATUS
(POSITIVE PRESSURE).
Unusual Fire/Explosion Hazard: USE WATER SPRAY TO KEEP CONTAINERS COOL.
=======================================================
Control Measures
=======================================================
Respiratory Protection: IN INADEQUATELY VENTILATED AREA OR WHERE TLV IS ABOVE
LIMITS USE AIR SUPPLIED RESPIRATOR.
Ventilation: LOCAL EXHAUST: ADEQUATE. MECHANICAL (GENERAL): ADEQUATE.
Other Protective Equipment: NOT REQUIRED.
Work Hygienic Practices: AVOID FOOD CONTAMINATION. WASH AFTER USING.
Supplemental Safety and Health: ABBREVIATION: N/A = NOT APPLICABLE. N/AV = NOT
AVAILABLE. N/K = UNKNOWN. N/P = NOT PROVIDED. N/R = NOT RELEVANT. N/D = NOT
DETERMINED. N/E = NOT ESTABLISHED.
=======================================================
Physical/Chemical Properties
=======================================================
HCC: V1
NRC/State LIC No: NOT RELEVANT
Boiling Point: =32.8C, 91.F
M.P/F.P Text: NOT AVAILABLE
Decomp Text: NOT PROVIDED
Vapor Pres: 532 @ 70F
Vapor Density: 4.00
Spec Gravity: 1.23
Viscosity: NOT PROVIDED
Evaporation Rate & Reference: >1 (ETHER=1)
Solubility in Water: SLIGHT
Appearance and Odor: CLEAR, COLORLESS LIQUID; SLIGHT ETHERAL ODOR
Percent Volatiles by Volume: 100
Corrosion Rate: NOT PROVIDED
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: OPEN FLAMES, SOURCES OF IGNITION.
Materials To Avoid: POWDERED METALS (ALUMINUM, MAGNESIUM, CALCIUM, ZINC).
Hazardous Decomposition Products: HALOGEN, HALOGEN ACIDS AND PHOSGENE MAY
POSSIBLY BE PRODUCED DURING THERMAL DECOMPOSITION.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NONE
=======================================================
Toxicological Information
=======================================================
Toxicological Information: NOT PROVIDED
=======================================================
Ecological Information
=======================================================
Ecological: NOT PROVIDED
=======================================================
=======================================================
Transport Information: D.O.T. CLASSIFICATION, CONSUMER COMMODITY ORM-D.
=======================================================
Regulatory Information
=======================================================
Sara Title III Information: NOT PROVIDED
Federal Regulatory Information: RCRA REGULATED # F002 CAS # 1717-00-6 (96%).
State Regulatory Information: NOT PROVIDED
=======================================================
Other Information
=======================================================
Other Information: NONE
=======================================================
Transportation Information
=======================================================
Trans ID NO: 159186
Product ID: ELECTRONIC SOLV #631-914 (BULK FORMULATED)
Review Date: 10/05/2001
Tech Entry NOS Shipping Nm: 1,1-DICHLORO-1-FLUOROETHANE 96 %
Net Unit Weight: 564 LBS
Multiple KIT Number: 0
Unit Of Issue: DR
Container QTY: 0
Type Of Container: STEEL DRUM
Additional Data: DOT PROPER SHIPPING NAME, HAZARD CLASS PER MSDS.
=======================================================
Detail DOT Information
=======================================================
DOT PSN Code: DTJ
Symbols: D
DOT Proper Shipping Name: CONSUMER COMMODITY
Hazard Class: ORM-D
Label: NONE
Non Bulk Pack: 156,306
Bulk Pack: NONE
Max Qty Pass: 30KGGROSS
Max Qty Cargo: 30KGGROSS
Vessel Stow Req: A
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: HWH
IMO Proper Shipping Name: HALOGENATED IRRITATING LIQUID, N.O.S. y
IMDG Page Number: 6157
UN Number: 1610
UN Hazard Class: 6.1
IMO Packaging Group: II/III
Subsidiary Risk Label: -
EMS Number: 6.1-02
MED First Aid Guide NUM: 740
=======================================================
Detail IATA Information
=======================================================
IATA PSN Code: HDW
IATA UN ID Num: 8000
IATA Proper Shipping Name: CONSUMER COMMODITY +
IATA UN Class: 9
IATA Label: MISCELLANEOUS
Packing Note Passenger: 910
Max Quant Pass: 25KG G
Max Quant Cargo: 25KG G
Packaging Note Cargo: 910
Exceptions: A112
=======================================================
Detail AFI Information
=======================================================
AFI PSN Code: HEB
AFI Proper Shipping Name: CONSUMER COMMODITY
AFI Hazard Class: 9
AFI UN ID NUM: UN8000
Special Provisions: P5
Back Pack Reference: A13.13
=======================================================
HAZCOM Label
=======================================================
Product ID: ELECTRONIC SOLV #631-914 (BULK FORMULATED)
Cage: 3T389
Company Name: WESTERN CHEMICAL INTERNATIONAL INC.
Street: 2939 N 67TH PLACE
Zipcode: 85251
Label Required IND: Y
Date Of Label Review: 10/05/2001
Status Code: A
MFG Label NO: NOT PROVIDED
Label Date: 07/07/2000
Year Procured: 2001
Origination
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: NO
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: TARGET ORGANS: NOT PROVIDED. CAUTIONS: KEEP CONTAINER
CLOSED WHEN NOT IN USE. STORE IN COOL DRY AREA. USE WITH ADEQUATE
VENTILATION. AVOID PROLONGED CONTACT WITH SKIN. FIRST AID: EYES: FLUSH WITH
WATE R FOR 15 MINUTES, GET MEDICAL ATTENTION. INHALATION: REMOVE TO FRESH
AIR; IF PROBLEM, GET MEDICAL ATTENTION. SKIN: WASH WITH MILD SOAP AND WATER.
INGESTION: DO NOT INDUCE VOMITING. GET MEDICAL ATTENT ION.
=======================================================
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:ACETONE, A20-1
CAGE:1B464
CAGE:1B464
============= Composition/Information on Ingredients =============
Ingred Name:ACETONE (SARA 313) (CERCLA)
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 99%
OSHA PEL:1000 PPM
ACGIH TLV:750 PPM/1000 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50: (ORAL,RAT) 5800 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE: PRODUCES IRRIT, CHARACT BY
BURNING SENSATION, REDNESS, TEARING, INFLAMM, & POSSIBLE CORNEAL
INJURY. SKIN: MAY CAUSE IRRIT CHARACT BY REDNESS, DRYNESS, &
INFLAMM. INGEST: MAY CAUSE IRRIT OF DIGESTIVE TRACT. MAY CAUSE CNS
DEPRESS, KIDNEY DMG, & LIVER DMG. SYMPS MAY INCL: HDCH, EXCITEMENT,
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: FATG, NAUS, VOMIT, STUPOR, & COMA.
INHAL: HIGH CONCS MAY CAUSE CNS EFTS CHARACT BY HDCH, DIZZ, UNCON &
COMA. CAUSES RESP TRACT IRRIT. MAY CAUSE LIVER & KIDNEY DMG. MAY
CAUSE MOTOR INCOORDINA TION & SPEECH ABNORM. CHRONIC: PRLNGD/RPTD
SKIN CONT MAY CAUSE DERM. CHRONIC INHAL MAY CAUSE EFTS SIMILAR TO
THOSE OF ACUTE INHAL. TARGET ORGANS: KIDNEYS, CNS, LIVER, RESP
SYSTEM.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS, OCCASNLY
LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. SKIN: FLUSH W/PLENTY
OF SOAP & WATER FOR AT LST 15 MINS WHILE REMOVING CONTAMD CLTHG &
SHOES. GET MED AID IF IRRIT DEVELOPS/PERSISTS.INGEST: IF CONSCIOUS
& ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. GET MED AID IMMED. INHAL:
GET MED AID IMMED. REMOVE TO FRESH AIR IMMED. IF NOT BRTHG, GIVE
ARTF RES P. IF BRTHG IS DFCLT, GIVE OXYG. NOTE TO PHYS: TREAT
SYMPTOMATICALLY & SUPPORTIVELY.
===================== Fire Fighting Measures =====================
Flash Point:-4F,-20C
Lower Limits:2.5
Upper Limits:12.8
Extinguishing Media:FOR SM FIRES, USE DRY CHEMICAL, CARBON DIOXIDE,
WATER SPRAY OR ALCOHOL-RESISTANT FOAM. FOR LG FIRES, USE WATER
SPRAY, FOG, OR ALCOHOL-RESISTANT FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . USE WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL.
Unusual Fire/Explosion Hazard:CONTAINERS CAN BUILD UP PRESSURE IF
EXPOSED TO HEAT AND/OR FIRE. VAPORS CAN TRAVEL TO SOURCE OF IGNIT &
FLASH BACK.
================== Accidental Release Measures ==================
Spill Release Procedures:ABSORB SPILL W/INERT MATL, (E.G., DRY
SAND/EARTH), THEN PLACE INTO CHEMICAL WASTE CONTAINER. WEAR
APPROPRIATE PROTECTIVE CLOTHING TO MINIMIZE CONTACT W/SKIN. REMOVE
ALL SOURCES OF IGNITION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM SOURCES OF IGNITION.
STORE IN TIGHTLY CLOSED CONTAINER. WASH THOROUGHLY AFTER HANDLING.
REMOVE CONTAMD CLTHG & WASH BEFORE REUSE.
Other Precautions:USE W/ADEQ VENT. AVOID CONT W/EYES, SKIN, AND CLTHG.
EMPTY CNTNRS RETAIN PROD RESIDUE, (LIQUID AND/OR VAPOR), AND CAN BE
DANGEROUS. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL,
GRIND/EXPOSE EMP TY CNTNRS TO HEAT, SPARKS/OPEN FLAMES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOLLOW OSHA RESPIRATOR REGS FOUND IN 29CFR
1910.134 OR EUROPEAN STD EN 149. ALWAYS USE A NIOSH APPROVED OR
EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY.
Ventilation:USE PROCESS ENCLOSURE, LOC EXHST VENT/OTHER ENGINEERING
CTLS TO CTL AIRBORNE LEVELS BELOW REC EXPOSURE LIMITS.
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . WEAR
APPROP PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE CONTAMD
CLOTHING AND WASH BEFORE REUSE.
Supplemental Safety and Health
MATL TO AVOID: THIODIGLYCOL+HYDROGEN PEROXIDE.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:133F,56C
Melt/Freeze Pt:M.P/F.P Text:-140F,-95C
Vapor Pres:180
Vapor Density:2.0
Spec Gravity:0.79 (WATER =1)
pH:7
Evaporation Rate & Reference:7.7 (N-BUTYL ACETATE=1)
Solubility in Water:SOLUBLE
Appearance and Odor:COLORLESS LIQUID, SWEETISH ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
FORMS EXPLOSIVE MIXTURES W/HYDROGEN PEROXIDE, ACETIC ACID, NITRIC ACID,
NITRIC ACID+SULFURIC ACID, CHROMIC ANHYDRIDE, CHROMYL CHLORIDE,
NITROSYL CHLORIDE, HEXACHLOROMELAMINE, NITROSYL PERCHLORATE, NITRYL
PERCHLORATE, PERMON
Stability Condition to Avoid:HIGH TEMPERATURES, TEMPERATURES ABOVE
220C.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE, AND LOCAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:ZL-55 ZYGLO WATER WASHABLE PENETRANT
Preparer's Name:BRUCE C. GRAHAM
CAGE:37676
CAGE:37676
============= Composition/Information on Ingredients =============
Ingred Name:SECONDARY ETHOXYLATED FATTY ALCOHOLS
CAS:68131-40-8
RTECS #:WZ5200000
Fraction by Wt: 50.0%
Ingred Name:UNIDENTIFIED COMPONENTS
Fraction by Wt: 50.0%
===================== Hazards Identification =====================
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:IRRITATES EYES ON LIQUID/VAPOR
CONTACT.
Effects of Overexposure:INHALATION:CAUSES DIZZINESS,DROWSINESS,NAUSEA;
SKIN:LIQUID IRRITATES BY DISSOLVING SKIN OIL; EYES:VAPORS/LIQUID
CAUSES IRRITATION; INGESTION:MANUFACTURER DIDN'T LIST.
Medical Cond Aggravated by Exposure:NOT KNOWN
======================= First Aid Measures =======================
First Aid:INHALATION:REMOVE TO FRESH AIR.IF BREATHING IS DIFFICULT,GIVE
OXYGEN; SKIN:REMOVE CONTAMINATED CLOTHES.WASH OFF WITH FLOWING
WATER.USE SOOTHING LOTION.IF IRRITATION PERSISTS,GET MEDICAL ATTN;
EYES:IMM EDIATELY RINSE/FLUSH WITH COPIOUS AMOUNT OF RUNNING WATER
AND GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:>250F/121C
Extinguishing Media:CARBON DIOXIDE,FOAM
Fire Fighting Procedures:KEEP CONTAINERS COOL WITH WATER SPRAY. DO NOT
SPRAY WATER ON BURNING ZL-55.
Unusual Fire/Explosion Hazard:WHEN INVOLVE IN COMBUSTION,MAY EMIT TOXIC
GASES AT OR ABOVE DECOMPOSITION TEMPERATURE.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE IGNITION SOURCES.SM QTY:WIPE UP OR MOP
UP BUT DO NOT BREATHE VAPORS.PLACE RAGS IN CLOSED DRUMS; LG
QTY:WEAR PERSONAL SAFETY EQUIPMENTS.DIKE AREA FAR AHEAD.ABSORB
LIQUID WITH COMMERCIAL ABSORBEN T.TRANSFER WASTE MATL IN SALVAGE
TANKS.
Neutralizing Agent:NOT KNOWN
======================Handling and Storage ======================
Handling and Storage Precautions:STORE AWAY FROM HEAT SOURCES IN WELL
VENTILATED AREA.AVOID AGAINST PHYSICAL DAMAGE TO CONTAINERS.KEEP
CONTAINERS TIGHTLY CLOSED.
Other Precautions:DO NOT BREATHE VAPORS.DO NOT SMOKE WHILE USING.DO NOT
HEAT ABOVE 130F(54C).AVOID FREQUENT OR PROLONGED SKIN CONTACT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED RESPIRATOR FOR CONFINED
AREAS.
Ventilation:GENERAL ROOM VENTILATION TO KEEP BELOW TLV LIMITS.
Other Protective Equipment:NOT KNOWN
Work Hygienic Practices:WASH OFF PROMPTLY WITH WATER.AVOID SKIN
CONTACT.
Supplemental Safety and Health
NSN OF MIL-I-25135D,TYPE I,METHOD C,LEVEL 3;PER QPL-25135-15,MAGNAFLUX
CORP.,MAY SUPPLY ONE OF THE FOLLOWING PENETRANTS FOR TYPE I,METHOD
C,LEVEL 3,NSN:ZL-22D,ZL-27A,ZL-37,ZL-54A,ZL-55 OR ZL-66A;THIS
ENTRY DESCRIBES ZL-55;PRODUCT NOT AVAILABLE IN AEROSOL CANS;SEE
OTHER P/N IND OF THIS NSN FOR OTHER QUALIFIED ITEMS.
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:400F/204C
Vapor Pres:<0.3MM
Vapor Density:>1.0
Spec Gravity:1.01
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:NEGLIGIBLE(EMULSIFY)
Appearance and Odor:GREEN OILY LIQUID
Percent Volatiles by Volume:5.0%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NOT KNOWN TO MFR.
Stability Condition to Avoid:HEAT,HIGH TEMPERATURES
Hazardous Decomposition Products:EMITS OXIDES OF CARBON AND NITROGEN ON
COMBUSTION
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE OR DISPOSE OF AS EPA HAZARDOUS WASTE
D001 (IGNITABLE WASTE),IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL,STATE,LOCAL REGULATIONS;IF LOCAL AUTHORITIES DO NOT ALLOW
DUMPING RINSINGS DOWN THE SEW ER,PURIFY RINSINGS WITH MAGNAFLUX
TREATMENT SYSTEM
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:24610-7 FLUOROTRIBROMOMETHANE,99%
CAGE:21076
CAGE:60928
CAGE:63181
CAGE:21076
============= Composition/Information on Ingredients =============
Ingred Name:TRIBROMOFLUOROMETHANE
CAS:353-54-8
Fraction by Wt: 99%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY BE HARMFUL BY INHALATION,
INGESTION/SKIN ABSORPTION. EYES: IRRITATING. INHALATION: IRRITATING
TO MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT. SKIN: IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION.
======================= First Aid Measures =======================
First Aid:EYES: IMMEDIATELY FLUSH W/COPIOUS AMOUNTS OF WATER FOR 15
MINS. SKIN: IMMEDIATELY WASH W/SOAP & COPIOUS AMOUNTS OF WATER.
INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED.
INGESTION: WASH OU T MOUTH W/WATER IF CONSCIOUS. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:WATER SPRAY, CO2, DRY CHEMICAL POWDER/APPROPRIATE
FOAM.
Fire Fighting Procedures:WEAR SCBA & PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
COVER W/DRY LIME/SODA ASH, PICKUP, KEEP IN A CLOSED CONTAINER &
HOLD FOR WASTE DISPOSAL. VENTILATE AREA & WASH SITE AFTER MATERIAL
PICKUP IS COMPLETE.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP TIGHTLY CLOSED. STORE IN A COOL
DRY PLACE.
Other Precautions:AVOID CONTACT & INHALATION. DON'T GET IN EYES, SKIN,
ON CLOTHING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED
Other Protective Equipment:SAFETY SHOWER & EYE BATH
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
BOILING POINT: 222.8-224.6F.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:(SEE SUPP)
Melt/Freeze Pt:M.P/F.P Text:-100.48F
Spec Gravity:2.765
Appearance and Odor:COLORLESS LIQUID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Hazardous Decomposition Products:CO, CO2, HYDROGEN FLUORIDE, HYDROGEN
BROMIDE GAS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISSOLVE/MIX THE MATERIAL W/A COMBUSTIBLE
SOLVENT & BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AN AFTERBURNER
& SCRUBBER, IAW/FEDERAL, STATE & LOCAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:RP 79-1
Preparer's Name:M. MUNSELL
CAGE:02684
CAGE:02684
============= Composition/Information on Ingredients =============
Ingred Name:METHYL CHLOROFORM (1,1,1-TRICHLOROETHANE) (CHLOROTHENE NU),
AEROTHANE TT, CHLOROTHENE
CAS:71-55-6
RTECS #:KJ2975000
Fraction by Wt: 70%
Other REC Limits:450 PPM STEL
OSHA PEL:350 PPM
ACGIH TLV:1900 MG/CUM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ozone Depleting Chemical:1
Ingred Name:PROPANE
CAS:74-98-6
RTECS #:TX2275000
Other REC Limits:1800 MG/CUM
OSHA PEL:1000 PPM
ACGIH TLV:SIMPLE ASPHYXIANT
Ingred Name:FREON 113, 1,1,2,-TRICHLORO-1,2,2,-TRIFLUOROETHANE,
TRICHLOROTRIFLUROETHANE
CAS:76-13-1
RTECS #:KJ4000000
Other REC Limits:1000 PPM
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM
Ozone Depleting Chemical:1
Ingred Name:ALEX (TETRAFLUOROETHYLENE-ETHYLENE COPOLYMER) *93-3*
CAS:25038-71-5
Ingred Name:VOL ORGANIC CMPD: <10 GRAMS/LITER
RTECS #:9999999VO
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN & EYE IRRITANT. INHALATION:
ASPHYXIANT, NASAL & RESPIRATORY IRRITANT.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:SKIN: DEFATTING. INHALATION: DIZZINESS,
WEAKNESS, FATIGUE, NAUSEA, HEADACHE, UNCONSCIOUSNESS, ASPHYXIATION.
Medical Cond Aggravated by Exposure:SKIN & EYE CONDITIONS
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. SKIN:
WASH THOROUGHLY W/SOAP & WATER, REMOVE CONTAMINATED CLOTHING.
INGESTION: IF CONSCIOUS, DRINK PLENTY OF WATER & DON'T INDUCE
VOMITING. INHALATI ON: REMOVE TO FRESH AIR, GIVE OXYGEN &/OR
ARTIFICIAL RESPIRATION IF NEEDED. OBTAIN MEDICAL ATTENTION IN ALL
CASES. (SEE SUPPLEMENTAL DATA).
===================== Fire Fighting Measures =====================
Flash Point:NON-FLAMMABLE
Extinguishing Media:CO2, DRY CHEMICAL, FOAM, WATER
Fire Fighting Procedures:USE SELF-CONTAINED BREATHING APPARATUS. MAY
BURST IF EXPOSED TO TEMPERATURES >130 F.
Unusual Fire/Explosion Hazard:ALTHOUGH TRICHLOROETHANE WILL NOT BURN,
CERTAIN MIXTURES IN AIR MAY IGNITE MOMENTARILY IN THE PRESENCE OF
SPARK/FLAME. ACID FUMES BE PRESENT DURING FIRE.
================== Accidental Release Measures ==================
Spill Release Procedures:ABSORB IN ABSORBENT MATERIAL.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID CONTACT W/SKIN, EYES, CLOTHING.
KEEP CONTAINER CLOSED. USE W/ADEQUATE VENTILATION. DO NOT EXPOSE TO
HEAT OR STORE ABOVE 120F. AVOID SUNLIGHT.
Other Precautions:DON'T SMOKE WHEN USING THIS PRODUCT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED ORGANIC VAPOR CARTRIDGE
RESPIRATOR.
Ventilation:GENERAL MECHANICAL & LOCAL EXHAUST IN ACCORDANCE W/ACGIH
RECOMMENDATIONS.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. LAUNDER
CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
NOTE TO PHYSICIAN: A TEMPORARY CONDITION KNOWN AS POLYMER FUME FEVER
(CHEST DISCOMFORT & COUGHING) MAY RESULT FROM A COMBINATION OF
SMOKE & INHALED FLOUROPOLYMER.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:117 F
Vapor Pres:70 PSI
Vapor Density:>1
Evaporation Rate & Reference:(BU AC=1): 1.7
Solubility in Water:INSOLUBLE
Appearance and Odor:WHITE LIQUID, SOLVENT ODOR
Percent Volatiles by Volume:>99
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:DIRECT SUNLIGHT, TEMPERATURES >120F (49C),
& OTHER IGNITION SOURCES
Hazardous Decomposition Products:ACID FUMES, HYDROCARBONS
==================== Disposal Considerations ====================
Waste Disposal Methods:CONSULT QUALIFIED PERSONNEL FOR METHOD THAT
COMPLIES W/LOCAL, STATE, & FEDERAL REGULATIONS. UN 1956,
NON-FLAMMABLE GAS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:434-440 INSTANT
Preparer's Name:DICK KARBO
CAGE:KMADD
CAGE:KMADD
============= Composition/Information on Ingredients =============
Ingred Name:BARIUM COMPOUNDS
Fraction by Wt: 11%
Ingred Name:COPPER COMPOUND
Fraction by Wt: 11%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:PROLONGED CONTACT W/SKIN/EYES CAN
CAUSE IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION
======================= First Aid Measures =======================
First Aid:EYES: FLUSH IMMEDIATELY W/WATER. SKIN: WASH AFFECTED AREA
W/SOAP & WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:>200F
Extinguishing Media:FOAM, CO2, DRY CHEMICAL
================== Accidental Release Measures ==================
Spill Release Procedures:SMALL: WIPE UP & STORE WIPERS IN UNDERWRITERS
APPROVED CONTAINERS. LARGE: SCOOP MATERIAL INTO SEALABLE
CONTAINERS. WIPE UP REMAINDER & STORE WIPERS IN UNDERWRITERS
APPROVED CONTAINERS.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN CLOSED CONTAINERS.
Other Precautions:AVOID CONTACT W/SKIN, EYES & CLOTHING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:AS REQUIRED
Ventilation:LOCAL EXHAUST
Work Hygienic Practices:WASH AFTER USE. REMOVE/LAUNDER CONTAMINATED
CLOTHING BEFORE REUSE. DON'T CONSUME FOOD/BEVERAGE WHERE PRODUCT IS
USED.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:470-610F
Evaporation Rate & Reference:SLOWER THAN WATER
Solubility in Water:INSOLUBLE
Appearance and Odor:OILY
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE &
LOCAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:DUAL SHIELD II 101-TM LOW ALLOY T-1 FLUX CORED WELDING ELECT
Resp. Party Other MSDS Num.:7971-2D
CAGE:84021
CAGE:84021
============= Composition/Information on Ingredients =============
Ingred Name:MANGANESE
CAS:7439-96-5
RTECS #:OO9275000
Minumum % Wt:1.
Maxumum % Wt:2.
OSHA PEL:1 MG/M3 (FUME)
OSHA STEL:3 MG/M3
ACGIH TLV:0.2 MG/M3 (FUME)
ACGIH STEL:C 5 MG/M3
Ingred Name:NICKEL
CAS:7440-02-0
RTECS #:QR5950000
Minumum % Wt:1.
Maxumum % Wt:2.
OSHA PEL:0.1 MG/M3(SOLUABLE)
ACGIH TLV:0.1 MG/M3(SOLUABLE)
Ingred Name:SODIUM TITANATE. (MANUFACTURER'S INVALID CAS NUMBER
12034-34-2)
CAS:12034-34-3
OSHA PEL:5 MG/M3 (RESP FRAC)
ACGIH TLV:10 MG/M3 (NUS PART)
Ingred Name:POTASSIUM TITANATE
CAS:12030-97-6
OSHA PEL:5 MG/M3 (RESP FRAC)
ACGIH TLV:10 MG/M3 (NUS PART)
Ingred Name:SILICON
CAS:7440-21-3
RTECS #:VW0400000
OSHA PEL:5 MG/M3 (RESPIRABLE)
ACGIH TLV:10 MG/M3 (DUST)
Ingred Name:SILICA, USE QUARTZ FORMULA. (SIO2)
CAS:14808-60-7
RTECS #:VV7330000
OSHA PEL:0.05 MG/M3 (RESP DST
ACGIH TLV:0.1 MG/M3
Ingred Name:TITANIUM DIOXIDE
CAS:13463-67-7
RTECS #:XR2275000
OSHA PEL:5 MG/M3 (RESPIRABLE)
ACGIH TLV:10 MG/M3 (DUST)
Ingred Name:MAGNESIUM & MAGNESIUM OXIDE
CAS:1309-48-4
RTECS #:OM3850000
OSHA PEL:15 MG/M3 (FUME, PART
ACGIH TLV:10 MG/M3 (OX FUME)
Ingred Name:IRON
CAS:7439-89-6
RTECS #:NO4565500
OSHA PEL:10 MG/M3 (TOT PART)
ACGIH TLV:5 MG/M3 (OX FUME)
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE OVEREXP TO GASES, FUMES & DUSTS
MAY INCL IRRIT OF EYES, LUNGS, NOSE & THROAT. SOME TOX GASES ASSOC
W/WELDING MAY CAUSE PULM EDEMA, ASPHY & DEATH. ACUTE OVEREXP MAY
INCL SIGNS & SYMPS SUCH AS WAT ERY EYES, NOSE & THROAT IRRIT, HDCH,
DIZZ, DFCLTY BRTHG, FREQUENT COUGH OR CHEST PAIN. PRESENCE OF
NICKEL CMPDS IN FUME CAN CAUSE METALLIC TASTE, NAUS, TIGHTNESS OF
CHEST, FEVER & ALLERGIC RXN. CHRONI C OVEREXP TO AIR CONTAMINANTS
MAY LEAD TO THEIR ACCUM IN LUNGS, CNDTN WHICH MAY BE SEEN AS DENSE
AREAS ON CHEST X-RAYS. SEVERITY OF CHG IS PROPORTIONAL TO LENGTH OF
EXPOS. CHGS SEEN ARE NOT NECESSARIL Y (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NICKEL: GROUP 2B, IARC MONOGRAPHS VOL
49, P 257, 1990; ANTIC HUMAN CARCIN, NTP 8TH ANNUAL RPT ON CARCINS,
1998. CRYSTALLINE SILICA-QUARTZ: GROUP 1, IARC MONOGRAPHS VOL 68, P
41, 1997; ANTIC HUMAN CARC IN, NTP 8TH ANNUAL RPT ON CARCINS, 1998.
Effects of Overexposure:HLTH HAZS: ASSOC W/SYMPS OR SIGNS OF REDUCED
LUNG FUNC/DISEASE. IN ADDN, CHGS ON X-RAYS MAY BE CAUSED BY
NON-WORK FACTORS SUCH AS SMKNG, ETC. NICKEL IS CONSIDERED CARCIN.
LONG TERM OVEREXP TO NICKEL F UMES MAY ALSO CAUSE PULM FIBROSIS &
EDEMA. OVEREXP TO MANGANESE CMPDS MAY AFFECT CNS, W/SYMPS OF
LANGUOR, SLEEPINESS, MUSC WEAK, EMOTIONAL DISTURBS & SPASTIC GAIT.
EXPOS LIMS FOR INGREDS ARE LISTED IN SECTION II. 1989 OSHA TWA FOR
WELDING FUME IS 5 MG/M3. TLV-TWAS SHOULD BE USED AS GUIDE IN CTL OF
HLTH HAZS & NOT AS FINE LINES BETWEEN SAFE & EXCESSIVE CONCS. WHEN
PRODS USED AS RECOM BY ESAB GROUP,& PREVENTIVE MEASURES TAUGHT
(SUPDAT)
Medical Cond Aggravated by Exposure:INDIVIDUALS W/ALLERGIES OR IMPAIRED
RESP FUNC MAY HAVE SYMPS WORSENED BY EXPOS TO WELDING FUMES;
HOWEVER, SUCH REACTION CANNOT BE PREDICTED DUE TO VARIATION IN
COMPOSITION & QTY OF DECOMP PRODS.
======================= First Aid Measures =======================
First Aid:INGESTION: CALL MD IMMEDIATELY . EYES: IMMEDIATELY FLUSH EYES
WITH POTABLE WATER FOR AT LEAST 15 MINUTES. SEEK ASSISTANCE FROM MD
. SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER. CALL MD (FP N ). IN
CASE OF EMERGENCY, CALL FOR MEDICAL AID. EMPLOY FIRST AID TECHNIQUE
RECOMMENDED BY RED CROSS. INHALATION: IF BREATHING IS DIFFICULT,
GIVE OXYGEN AND CALL FOR MD. FOR ELECTRIC SHOCK, DISCONNECT A ND
TURN OFF THE POWER. IF NOT BREATHING, BEGIN ARTIFICIAL RESPIRATION,
PREFERABLY MOUTH-TO-MOUTH. IF NO DETECTABLE PULSE, BEGIN CPR.
IMMEDIATELY CALL MD. FOR ARC BURN, APPLY COLD, CLEAN COMPRESSES & C
ALL MD.
===================== Fire Fighting Measures =====================
Extinguishing Media:THIS PROD WILL NOT BURN; HOWEVER, WELDING ARCS &
SPKS CAN IGNITE COMBUST & FLAM MATLS. USE EXTING MEDIA RECOM FOR
BURNING MATLS & FIRE SITUATION. SEE ANSI Z49.1 (TOXICOLOGICAL INFO)
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:FLAMMABLE/EXPLOSIVE: NO. ONLY THE
PACKAGING FOR THIS PRODUCT WILL BURN.
================== Accidental Release Measures ==================
Spill Release Procedures:NOT APPLICABLE.
======================Handling and Storage ======================
Handling and Storage Precautions:READ & UNDERSTAND MFR'S INSTRUCTION &
PREC LABEL ON PROD. SEE ANSI Z-49.1, "SFTY IN WELDING & CUTTING,"
PUB BY AMERICAN WELDING SOCIETY, BOX 351040, MIAMI, FL 33135 & OSHA
PUB 2206 (29 CFR 1910), US G OVT PRINTING OFFICE, SUPERINTENDENT OF
DOCUMENTS, BOX 371954, PITTSBURGH, PA 15250 FOR MORE DETAILS.
Other Precautions:ESAB GROUP REQUESTS USERS OF PRODS STUDY MSDS &
BECOME AWARE OF HAZS & SFTY INFO. TO PROMOTE SAFE USE OF PRODS,
USER SHOULD 1)NOTIFY EMPLOYEES, AGENTS & CONTRACTORS OF INFO ON
MSDS & ANY PROD HAZS & SFTY INFO, 2)FURNISH SAME INFO TO CUSTOMERS
FOR THESE PRODS & 3)REQUEST SUCH CUSTOMERS NOTIFY THEIR (STAB COND
TO AVOID)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED RESPIRABLE FUME RESPIRATOR OR
AIR SUPPLIED RESPIRATOR WHEN WELDING IN CONFINED SPACE OR WHERE
LOCAL EXHAUST OR VENTILATION DOES NOT KEEP EXPOSURE BELOW TLV.
Ventilation:USE ENOUGH VENT, LOCAL EXHAUST AT ARC OR BOTH, TO KEEP
FUMES & GASES BELOW TLVS IN WORKER'S BRTHG ZONE & GEN AREA. TRAIN
WELDER TO KEEP HIS HEAD OUT OF FUMES.
(TOXICOLOGICAL INFO)
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . WEAR
HEAD, HAND & BODY PROT WHICH HELP TO PVNT INJURY FROM RADIA, SPKS &
(TOXICOLOGICAL INFO)
Work Hygienic Practices:TRAIN THE WELDER NOT TO TOUCH LIVE ELECTRICAL
PARTS AND TO INSULATE HIMSELF FROM WORK AND GROUND.
Supplemental Safety and Health
EFTS OF OVEREXP: IN MSDS ARE FOLLOWED, OVEREXP TO HAZ SUBSTANCES WILL
NOT OCCUR. ELEC ARC WORKING MAY CREATE ONE/MORE OF FOLLOWING HLTH
OR PHYSICAL HAZS. FUMES & GASES CAN BE DANGEROUS TO HLTH. ELEC S
HOCK CAN KILL. ARC RAYS CAN INJURE EYES & BURN SKIN. NOISE (OTHER
INFO)
================== Physical/Chemical Properties ==================
Appearance and Odor:TUBULAR STEEL WIRE CONTAINING MINERALS AND ALLOYS;
ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE CURRENTLY KNOWN.
Stability Condition to Avoid:N/P. OTHER PREC:EMPLOYEES AND
CUSTOMERS, FOR THESE PRODUCTS, OF THE SAME PRODUCT HAZARDS AND
SAFETY INFORMATION.
Hazardous Decomposition Products:WELDING FUMES & GASES CANNOT BE
CLASSIFIED SIMPLY. COMPOSITION & QTY OF BOTH DEPEND ON MATL BEING
WORKED, PROCESS, PROCS & CONSUMABLES USED. OTHER CNDTNS INFLUENCING
COMPOSITION & QTY OF (ECOL INFO)
=================== Toxicological Information===================
Toxicological Information:N/P. EXTING MEDIA:"SFTY IN WELDING & CUTTING"
& SAFE PRACTICES" CODE: SP, PUB BY AWS & NFPA 51B "CUTTING &
WELDING PROCESSES, PUB BY NFPA, BATTERYMARCH PARK, QUINCY, MA 02269
FOR ADDNL FIRE PREVENTION & PROT INFO. EYE PROT: USE FILTER LENS.
AS RULE OF THUMB, START W/SHADE WHICH IS TOO DARK TO SEE WELD ZONE.
THEN GO TO NEXT LIGHTER SHADE WHICH GIVES SUFFICIENT VIEW OF WELD
ZONE. PROVIDE PROT SCREEN S & FLASH GOGGS, IF NEC, TO SHIELD
OTHERS. OTHER PROT EQUIP: & PROT FSHLD & MAY INCL ARM PROTECTORS,
APRONS, HAT, SHOULDER PROTECTION AS WELL AS DARK SUBSTANTIAL CLTHG.
===================== Ecological Information =====================
Ecological:N/P. PHYSICAL DATA: AS SHIPPED, THESE PRODS ARE
NONFLAMMABLE, NON-EXPLOSIVE, NON-REACTIVE & NON-HAZARDOUS. PHYSICAL
STATE: SOLID. HAZ DECOMP PRODS: FUMES & GASES TO WHICH WORKERS MAY
BE EXPOSED INCL: COATINGS ON MATL BEING WORKED (SUCH AS PAINT,
PLATING OR GALVANIZING), NUMBER OF WELDING OPERATIONS & VOL OF WORK
AREA, QUALITY & AMT OF VENT, POSITION OF WORKER'S HEAD W/RESPECT TO
FUME PLUME, AS WEL L AS PRESENCE OF CONTAMINANTS IN ATM (SUCH AS
CHLORINATED HYDROCARB VAPS FROM CLEANING OR PAINTING ACTIVITIES).
WHEN MATLS CONSUMED, FUME & GAS DECOMP PRODS GENERATED ARE
DIFFERENT IN PERCENT & FORM F ROM INGREDS LISTED IN (TRANSPORT
INFO)
==================== Disposal Considerations ====================
Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER OR
LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE
WITH FEDERAL, STATE AN D LOCAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:N/P. ECOLOGICAL INFO: SECTION II. DECOMP PRODS OF
NORMAL OPERATION INCL THOSE ORIGINATING FROM VOLATILIZATION, RXN OR
OXIDATION OF INGREDS, PLUS THOSE FROM MATL BEING WORKED & COATINGS
ETC, NOTED ABOV E. REASONABLY EXPECTED DECOMP PRODS FROM NORM USE
OF THESE PRODS INCL COMPLEX OF OXIDES & FLUORIDES OF MATLS LISTED,
AS WELL AS CARBON MONOXIDE, CARBON DIOXIDE, OZONE & NITROGEN OXIDES
(REFER TO "CHAR ACTERIZATION OF ARC WELDING FUME" AVAIL FROM AWS).
TLV FOR MANGANESE (0.2 MG/M3) WILL BE REACHED BEFORE GEN LIMIT FOR
WELDING FUMES OF 5 MG/M3 IS REACHED. ONLY WAY TO DETERMINE TRUE
IDENTITY OF DECOMPPRODS IS BY (SARA REG INFO)
===================== Regulatory Information =====================
SARA Title III Information:MANGANESE & NICKEL ARE TOX CHEMS SUBJECT TO
REPORTING REQS OF SECTION 313 OF EMER PLANNING & COMMUNITY
RIGHT-TO-KNOW ACT OF 1986 (SARA) & 40 CFR 372. TRANSPORT INFO:
SAMPLING & ANLAYSIS. COMPOSITION &QTY OF FUMES & GASES TO WHICH
WORKER MAY BE OVEREXPOSED CAN BE DETERMINED FROM SAMPLE OBTAINED
FROM INSIDE WELDER'S HELMET, IF WORN, OR IN WORKERS BRTHG ZONE. SEE
ANSI/AWS F1.1 "METHOD FOR SAMPLING A IRBORNE PARTICLES GENERATED BY
WELDING & ALLIED PROCESSES," AVAIL FROM AMERICAN WELDING SOCIETY.
Federal Regulatory Information:N/P. HAZARDOUS INGREDS LISTED IN SECTION
II, COVERS MATLS FROM WHICH PROD IS MANUFACTURED. FUMES & GASES
PRODUCED DURING NORMAL USE OF THESE PRODS ARE COVERED IN REACTIVITY
DATA SECTION. TERM HAZARDOU S SHOULD BE INTERPRETED AS TERM
REQUIRED & DEFINED BY LAWS, STATUTES OR REGS & DOES NOT NECESSARILY
IMPLY THE EXISTENCE OF ANY HAZARD WHEN THE PRODUCTS ARE USED AS
DIRECTED BY THE ESAB GROUP.
State Regulatory Information:WARNING: THIS PRODUCT CONTAINS OR PRODUCES
A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND
BIRTH DEFECTS (OR OTHER REPRODUCTIVE HARM) (CALIFORNIA HEALTH &
SAFETY CODE 25249.5 ET SEQ.).
======================= Other Information =======================
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:3C-3001
CAGE:HO183
CAGE:HO183
CAGE:04011
============= Composition/Information on Ingredients =============
Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: 81%
OSHA PEL:200 PPM/300 STEL
ACGIH TLV:200 PPM/300STEL 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:PHENOLIC ADDITIVE (PHENOL)
Fraction by Wt: 7%
ACGIH TLV:S, 5PPM
Ingred Name:BUNA N-COPOLYMER
Fraction by Wt: 12%
===================== Hazards Identification =====================
Effects of Overexposure:DEPRESSANT TO CENTRAL NERVOUS SYSTEM,MAY CAUSE
DIZZINESS.
======================= First Aid Measures =======================
First Aid:INH: REMOVE TO FRESH AIR AWAY FROM FUMES. EYES: FLUSH W/ H*2O
FOR 15 MINS, SEE MD.
===================== Fire Fighting Measures =====================
Flash Point:>35F;1.67C (CC)
Extinguishing Media:DRY CHEM, CO*2
Fire Fighting Procedures:FIGHT AS EXPLOSIVE SOLVENT
================== Accidental Release Measures ==================
Spill Release Procedures:CLEAN UP W/ TOLUENE OR KETONES. WHEN USING
THESE SOLVENTS OBSERVE ALL NECESSARY PRECAUTIONS.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL PLACE <80F.
Other Precautions:WASH THOROUGHLY AFTER HANDLING. STORE <80F.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT REQUIRED FOR REGULAR OPEN AREA USE (MFR)
Ventilation:LOCAL EXHAUST & MECHANICAL VENTILATION.
Other Protective Equipment:CHEMICAL RESISTANT APRON
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR AMBER
Percent Volatiles by Volume:85
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:TEMP >80F
Conditions to Avoid Polymerization:TEMP >80F.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IAW FEDERAL, STATE & LOCAL CODES.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:02394 CLOSE CELL PVC FOAM WEATHERSTRIPS/SEAL TAPE/INSULATION
CAGE:82464
CAGE:82464
============= Composition/Information on Ingredients =============
Ingred Name:CHLOROETHYLENE POLYMER, POLYVINYLCHLORIDE, POLYVINYL
CHLORIDE
CAS:9002-86-2
RTECS #:KV0350000
Fraction by Wt: 45%
Ingred Name:PHTHALATE PLASTICIZER
Fraction by Wt: 45%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN: IRRITATION. INHALATION:
RESPIRATORY TRACT IRRITATION, DIZZINESS, & NAUSEA. INGESTION:
IRRITATION, DIZZINESS, & NAUSEA.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:SKIN: IRRITATION. INHALATION: RESPIRATORY TRACT
IRRITATION. INGESTION: IRRITATION, DIZZINESS, & NAUSEA.
Medical Cond Aggravated by Exposure:RESPIRATORY CONDITIONS
======================= First Aid Measures =======================
First Aid:SKIN: WASH W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR.
INGESTION: DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL
CASES.
===================== Fire Fighting Measures =====================
Flash Point:440F
Extinguishing Media:CO2, FOAM, DRY CHEMICAL, WATER
Fire Fighting Procedures:SELF-CONTAINED BREATHING APPARATUS IN POSITIVE
PRESSURE MODE & FULL PROTECTIVE GEAR SHOULD BE WORN.
Unusual Fire/Explosion Hazard:IRRITATING OR TOXIC GASES & AEROSOLS MAY
BE PRODUCED DURING BURNING.
======================Handling and Storage ======================
Handling and Storage Precautions:DON'T STORE NEAR HEAT SOURCES, SPARKS
OR FLAME. STORE <150F. DON'T INGEST. KEEP AWAY FROM CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:AS REQUIRED
Ventilation:LOCAL EXHAUST: RECOMMENDED MECHANICAL: ADEQUATE
Work Hygienic Practices:WASH SKIN & HANDS AFTER USE.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:485.6F
Vapor Pres:0.4
Vapor Density:>1
Solubility in Water:INSOLUBLE
Appearance and Odor:POROUS, SOFT, SPONGYSOLID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AMINES.
Stability Condition to Avoid:FLAMES, SPARKS.
Hazardous Decomposition Products:CO2, CO, HYDROGEN CHLORIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:SANITARY LANDFILL IN ACCORDANCE W/LOCAL, STATE,
& FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:AMERCOAT, 5105
Preparer's Name:H. KLINE
CAGE:0Y2E4
CAGE:55849
CAGE:0Y2E4
============= Composition/Information on Ingredients =============
Ingred Name:(TALC (POWDER),CONTAINING NO ASBESTOS FIBERS; (TALC
(ASBESTOS FREE).
CAS:14807-96-6
RTECS #:WW2710000
Fraction by Wt: <45%
OSHA PEL:0.2 FIBERS/CC
ACGIH TLV:0.2 FIBERS/CC
Ingred Name:ALKYD RESIN. VP: 2.54 @ 68F.
CAS:68333-62-0
Fraction by Wt: <15%
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE). LD50: (ORAL,RAT) 24
G/KG.
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: <15%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
Ingred Name:STODDARD SOLVENT. VP: 2 @ 68F. LD50: (ORAL,RAT) 5 G/KG.
CAS:8052-41-3
RTECS #:WJ8925000
Fraction by Wt: 10.72%
OSHA PEL:500 PPM
ACGIH TLV:100 PPM
Ingred Name:NAPHTHA PETROLEUM, HEAVY ALKYLATE (C9-C12); (ODORLESS
MINERAL SPIRITS). VP: 1.2 @ 68F.
CAS:64741-65-7
Fraction by Wt: 10.72%
OSHA PEL:100 PPM (MFR)
ACGIH TLV:100 PPM (MFR)
Ingred Name:IRON OXIDE; (YELLOW IRON OXIDE). LD50:(ORAL,RAT) >10 G/KG.
CAS:51274-00-1
Fraction by Wt: <10%
OSHA PEL:5 PPM (MFR)
ACGIH TLV:5 PPM (MFR)
Ingred Name:SOLVENT NAPHTHA; (HEAVY AROMATIC NAPHTHA). VP: 4.8 @ 68F.
LD50:(ORAL,RAT)0.5 G/KG.
CAS:64742-94-5
RTECS #:WF3100000
Fraction by Wt: 3.54%
OSHA PEL:500 PPM (MFR)
ACGIH TLV:N/K
Ingred Name:SOLVENT NAPHTHA (PETROLEUM), LIGHT AROMATIC; (HIGH FLASH
NAPTHA). VP: 2.7 @ 68F. LD50: 4.7 G/KG.
CAS:64742-95-6
RTECS #:WF3400000
Fraction by Wt: 2.55%
OSHA PEL:N/K
ACGIH TLV:100 PPM
Ingred Name:CARBON BLACK. (PNA'S <0.1%)
CAS:1333-86-4
RTECS #:FF5800000
Fraction by Wt: <5%
OSHA PEL:3.5 MG/M3
ACGIH TLV:3.5 MG/M3
Ingred Name:BENZENE,1,2,4-TRIMETHYL-; (1,2,4-TRIMETHYLBENZENE)(SARA
III). VP: 1 @ 68F.
CAS:95-63-6
RTECS #:DC3325000
Fraction by Wt: 1.7%
OSHA PEL:25 PPM
ACGIH TLV:25 PPM
Ingred Name:SILICA,CRYSTALLINE-QUARTZ; (SILICA(QUARTZ)). LD50:
(ORAL,RAT) 5 G/KG.
CAS:14808-60-7
RTECS #:VV7330000
Fraction by Wt: <5%
OSHA PEL:10 MG/M3 RDUST
ACGIH TLV:0.1 MG/M3 RDUST
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:VAP/SPRAY MIST CAN BE HARMFUL. IRRIT
TO EYES,SKIN,NOSE & THROAT. EXCESS INHAL CAN CAUSE HDCH, NAUS/DIZZ.
RPTD/PRLNG OCCUP OVEREXP TO SOLVS IS ASSOC W/PERM BRAIN & CNS DMG.
CAN BE HARMFUL IF INHALED/AB SORB THRU SKIN. OVEREXP CAN DMG LUNGS,
CNS. OVEREXP CAN CAUSE DELAYED LUNG INJURY, CHEM PNEUM. ASPIRATION
HAZARD.
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ: IARC
MONGRAPHS,SUPPLEMENT. VOL 7, PG 341, 1987: GROUP 21. NTP 7TH ANNUAL
REPORT (SUPP DATA)
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:RESPIRATORY, SKIN. EYES.
======================= First Aid Measures =======================
First Aid:INHAL: PROVIDE FRESH AIR; IF BREATHING IS LABORED, GIVE
OXYGEN/ARTF RESP. SKIN: WASH THOROUGHLY W/SOAP & WATER. EYES: FLUSH
IMMEDIATELY W/PLENTY OF WATER FOR AT LEAST 15 MINS & GET MED ATTN.
INGEST: D RINK 1 OR 2 GLASSES OF WATER TO DILUTE.DO NOT INDUCE
VOMITING. CONSULT PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY.
TREAT SYMPTOMATICALLY.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:105F,41C
Lower Limits:0.50%
Upper Limits:7.00%
Extinguishing Media:FOAM, CO*2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:CLSD CNTNRS MAY EXPLO WHEN EXPOS TO
EXTREME HEAT. ISOLATE FROM HEAT, ELECT EQUIP, SPARKS & OPEN FLAME.
KEEP AWAY FROM HEAT & OPEN FLAME. PVNT STATIC(SUPP DATA)
================== Accidental Release Measures ==================
Spill Release Procedures:AVOID BREATHING OF VAPORS. USE ABSORBENT
CLEANUP MATERIALS. PLACE IN SEPARATE CNTNR. KEEP OUT OF SEWERS &
WATERWAYS. IF ENTRY IS THREATENED OR OCCURS, NOTIFY LOCAL
AUTHORITIES. ELIMINATE ALL SOURCES O F IGNITION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED, UPRIGHT WHEN
NOT IN USE. STORE IN COOL, DRY, WELL-VENTILATED AREA. AVOID STORAGE
TEMPERATURES ABOVE 100F.
Other Precautions:DO NOT TAKE INTERNALLY. AVOID PRLNG BRTHG OF
VAPORS/SPRAY MIST/CONT WITH SKIN & EYES. DESTROY CONTAMD LEATHER &
ABSORB SHOES WHICH CANNOT BE DECONTAMD. DO NOT WELD OR FLAME CUT AN
EMPTY CONTAINER. GRO UND CONTAINERS WHEN POURING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA CERTIFIED RESP. FOR SPEC CNDTNS,
REFER TO CURRENT HIOSH POCKET GUIDE TO CHEMICAL HAZARDS. USE
NIOSH/MSHA APPRVD AIR-LINE RESPS IN CONFINED/RESTRICTED VENT AREAS.
REFER TO 29 CFR,OSHA PARTS1910 & 1915, FOR COATING OPERATIONS.
Ventilation:SUFF VENT, IN VOL & PATTERN SHOULD BE PROVIDED TO KEEP AIR
CONTAM CONC BELOW TLV LIMIT. REMOVE WELDING/FLAME (SUPP DATA)
Other Protective Equipment:FULL PROTECTIVE CLOTHING. SPARK-PROOF
EQUIPMENT.
Work Hygienic Practices:WASH THORO BEFORE EATING, SMOKING/USING
WASHROOM. LAUNDER CONTAMD CLOTHING BEFORE REUSE.
Supplemental Safety and Health
EVAP RATE: LOW:0.10,HIGH: 0.17(BUAC=1). EXPLO HAZ: DISCHARGE. AN ING
MAY PRDCE A FLOATING FIRE HAZ. CARCINS: ON CARCINOGENS, 1994:
ANTICIPATED TO BE CARCINOGEN. VENT: CUTTING DECOMPOSITION PRODUCTS.
R EFER TO 29 CFR, OSHA PARTS 1910 & 1915,FOR COATING OPERATIONS.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>300F,>149C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Evaporation Rate & Reference:(SUPP DATA)
Appearance and Odor:LIQUID WITH SOLVENT ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, ACIDS, ALKALINE.
Stability Condition to Avoid:HEAT, OPEN FLAME, ARC OR SPARKS.
Hazardous Decomposition Products:CO & CO*2, IRON OXIDE FUMES.
==================== Disposal Considerations ====================
Waste Disposal Methods:IN SEPARATE, CLOSED METAL CONTAINER IN
ACCORDANCE WITH LOCAL, STATE & FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:FP003, PREP TONE
CAGE:0K209
CAGE:0K209
============= Composition/Information on Ingredients =============
Ingred Name:ETHANOL, 2-BUTOXY-; (GLYCOL ETHER EB)
CAS:111-76-2
RTECS #:KJ8575000
Fraction by Wt: 6%
OSHA PEL:S, 50 PPM
ACGIH TLV:S, 25 PPM; 9293
Ingred Name:SILICIC ACID (H*2SIO*3), DISODIUM SALT; (SODIUM
METASILICATE)
CAS:6834-92-0
RTECS #:VV9275000
OSHA PEL:2 MG/M3
Ingred Name:SUPP DATA: OR CLAY ETC. AND SHOVELED INTO CONTAINERS.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:(ACUTE)EYES: OVEREXP CAN CAUSE SEV
IRRIT, REDNESS, TEARING, & BLURRED VISION. SODIUM METASILICATE IS
CORR TO EYES. SKIN: PRLNGD/RPTD CONT CAN CAUSE IRRIT, DEFAT & DERM.
CAN BE ABSORBED IN TOX AMTS, ES PEC FROM PRLNGD/RPTD EXPOS. INHAL:
EXCESSIVE INHAL OF VAPS CAN CAUSE NASAL & RESP IRRIT, CNS EFTS INCL
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: DIZZ,WEAK, FATIGUE, NAUS, HDCH & POSS
UNCON, & EVEN DEATH. INGEST: CAN CAUSE GI IRRIT, NAUS, VOMIT &
DIARR. (CHRONIC) OVEREXP TO EB GLYCOL ETHER HAS APPARENTLY BEEN
FOUND TO CAUSE THESE EFTS IN LAB ANIMALS: LIVER ABNORM, ANEMIA,
KIDNEY DMG, LUNG DMG, & BLOOD ABNORMALITIES. ANIMAL STUDIES CLEARLY
(SUPP DATA)
Medical Cond Aggravated by Exposure:HEADACHES, SKIN & EYE IRRITATION.
======================= First Aid Measures =======================
First Aid:SKIN: THORO WASH EXPOSED AREA WITH SOAP AND WATER. REMOVE
CONTAM CLOTHING AND LAUNDER BEFORE RE-USE. EYES: FLUSH WITH LARGE
AMOUNTS OF WATER FOR AT LEAST 15 MIN, LIFTING UPPER AND LOWER LIDS
OCCASIONA LLY, GET MEDICAL ATTENTION. INGESTION: IMMEDIATELY DRINK
TWO GLASSES OF WATER AND CALL PHYS. INHALATION: REMOVE INDIVIDUAL
TO FRESH AIR, IF BREATHING BECOMES DIFFICULT GIVE ARTF RESP. SEEK
MED ATTN.
===================== Fire Fighting Measures =====================
Extinguishing Media:CO2, FOAM, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.
================== Accidental Release Measures ==================
Spill Release Procedures:SML: ABSORB LIQ ON PAPER, VERMICULITE, FLOOR
ABSORB/OTHER ABSORB & TRANSFER TO HOOD. LRG: ELIMINATE ALL IGNIT
SOURCES, PERSONS NOT WEARING PROT EQUIP SHD BE EXCLUDED FROM SPILL
AREA, OR UNTIL CLEAN-UP HAS BEEN COMPLETED. STOP SPILL AT (SUPP
DATA)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED AND AVOID
FREEZING.
Other Precautions:KEEP OUT OF REACH OF CHILDREN. READ ALL LABELS AND
CAUTIONS BEFORE USE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV'S.
Other Protective Equipment:WEAR PROT CLTHG-NON ABSORBENTS. READ ALL
CAUTIONS AND LABELS BEFORE USE. EMERGENCY EYE WASH AND DELUGE
SHOWER .
Work Hygienic Practices:WEAR CLEAN PROTECTIVE EQUIPMENT.
Supplemental Safety and Health
EFTS OF OVEREXP: DEMONSTRATED DOSE-RELATED ADVERSE EFTS ON CNS,
HEMATOPOIETIC TISS, BLOOD, KIDNEYS & LIVER, ASSOC W/ ADMIN OF EGBE.
(EXTRACTED FROM DHHS (NIOSH) PUBLICATION NO. 90-118) . SPILL P ROC:
SOURCE, DIKE AREA OF SPILL TO PVNTSPREADING, PUMP LIQ TO SALVAGE
TANK. REMAINING LIQ MAY BE TAKEN UP W/SAND (ING 3
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:212F,100C
Vapor Pres:25
Spec Gravity:1.02 (H2O=1)
Evaporation Rate & Reference:1 (WATER=1)
Solubility in Water:100%
Appearance and Odor:RED WITH CELLOSOLVE ODOR.
Percent Volatiles by Volume:90
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CONCENTRATE MINERAL ACIDS AND STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HEATING OR FREEZING.
Hazardous Decomposition Products:NOT APPLICABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTACT FEDERAL, STATE, COUNTY OR LOCAL
ENVIRONMENTAL REGULATIONS FOR GUIDANCE.
| 0 | gloves_not_mandatory |
===================== Product Identification =====================
Product ID:ELFTEX
CAGE:0VZP9
CAGE:0VZ09
CAGE:0VZP9
============= Composition/Information on Ingredients =============
Ingred Name:CARBON BLACK
CAS:1333-86-4
RTECS #:FF5800000
Fraction by Wt: 100%
OSHA PEL:3.5 MG/M3
ACGIH TLV:3.5 MG/M3
Ingred Name:SUPDAT:VOLATILE MATTER". CARBON BLACK DUSTS CONTAINING <8%
TOTAL VOLATILE MATTER ARE NOT CONSIDERED TO PRESENT (ING 3)
RTECS #:9999999ZZ
Ingred Name:ING 2:EXPLO HAZARDS. MFR CARBON BLACKS ARE WELL BELOW 8%
TOTAL VOLATILE MATTER.
RTECS #:9999999ZZ
Ingred Name:EFTS OF OVEREXP:STUDIES IN USSR & E. EUROPE RPT RESP
DISEASES, INCLDG:BRONCH, PNEUMOCONIOSIS, EMPHYSEMA & (ING 5)
RTECS #:9999999ZZ
Ingred Name:ING 4:RHINITIS AMONG SOME WORKERS. SUCH STUDIES ARE OF
QUESTIONABLE VALIDITY DUE TO INADEQ STUDY DESIGN & (ING 6)
RTECS #:9999999ZZ
Ingred Name:ING 5:METHODOLOGY, LACK OF APPROP CONTROLS FOR CIGARETTE
SMKNG & OTHER CONFOUNDING FACTORS, SUCH AS CO, COAL (ING 7)
RTECS #:9999999ZZ
Ingred Name:ING 6:OIL & PETRO VAPS. MOREOVER, REVIEW OF THESE STUDIES
INDICATES THAT CONC OF CARBON BLACK WAS SUBSTANTIALLY (ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7:GREATER THAN OSHA REC LEVS. CHRONIC INFLAMM, LUNG
FIBROSIS, & LUNG TUMORS HAVE BEEN FOUND IN PRELIMINARY (ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8:STUDIES IN RATS EXPERIMENTALLY EXPOSED, FOR LONG
PERIODS OF TIME, TO EXCESS CONCS OF CARBON BLACK & OTHER (ING 10)
RTECS #:9999999ZZ
Ingred Name:ING 9:INSOLUBLE DUST PARTICLES WHICH OVERWHELM LUNG
CLEARANCE MECHANISMS. RESEARCHERS WHO CONDUCTED THESE TESTS (ING
11)
RTECS #:9999999ZZ
Ingred Name:ING 10:BELIEVE THESE CNDTNS MOST LIKELY RSLT FROM MASSIVE
ACCUM OF SM DUST PARTICLES IN LUNG, "DUST OVERLOAD (ING 12)
RTECS #:9999999ZZ
Ingred Name:ING 11:PHENOMENON", RATHER THAN FROM SPECIFIC CHEM EFT OF
DUST PARTICLES. SUCH EFTS OCCUR ONLY WHEN LUNGS ARE (ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12:OVERLOADED W/EXCESS OF SM PARTICLES. THEY ARE
UNLIKELY TO RSLT FROM WORKPLACE EXPOS TO CARBON BLACK AT (ING 14)
RTECS #:9999999ZZ
Ingred Name:ING 13:OR BELOW TLV. HUMAN STUDIES HAVE NOT FOUND WORKPLACE
EXPOSURES TO CARBON BLACK AT/BELOW TLV CAUSE THESE EFFECTS.
RTECS #:9999999ZZ
Ingred Name:HYGIENE PRACT:A MILD UNSCENTED SOAP SHOULD BE USED.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:NONE EXPECTED. TEMPORARY
DISCOMFORT TO UPPER RESP TRACT MAY OCCUR DUE TO INHAL OF DUST CONCS
ABOVE TLV. CHRONIC:CARBON BLACK CNTNS <0.2% OF ABSORBED POLYNUCLEAR
AROMATIC CMPDS (PNA). IN NON-ADSO RBED FORM, SOME PNA'S HAVE BEEN
FOUND TO BE CARCINS IN CERTAIN STUDIES. NO CARCIN EFT, HOWEVER, HAS
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:BEEN FOUND IN HUMANS DUE TO EXPOS TO
CARBON BLACK. CARBON BLACK IS NOT CONSIDERED CARCIN BY IARC, THE
OCCUP SFTY & HLTH ADMIN, OR NTP. EPIDEMIOLOGIC STUDIES OF WORKERS
IN CARBON BLACK PRODUCI NG INDUSTRY IN U.S. & W. EUROPE SHOW
NOSIGNIFICANT ADVERSE HLTH EFTS DUE TO OCCUP EXPOS TO CARBON BLACK.
SOME (ING 4)
Medical Cond Aggravated by Exposure:NONE EXPECTED. CARBON BLACK, LIKE
ANY NUISANCE DUST, MAY AGGRAVATE CERTAIN PRE-EXISTING UPPER
RESPIRATORY DISORDERS, SUCH AS BRONCHITIS OR ASTHAM.
======================= First Aid Measures =======================
First Aid:INGEST:CALL MD IMMEDIATELY . EYES:IMMEDIATELY FLUSH W/POTABLE
WATER FOR MINIMUM OF 15 MINUTES, SEEK ASSISTANCE FROM MD .
SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . INHAL:MOVE V ICTIM
TO FRESH AIR.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:>932F,>500C
Extinguishing Media:COPIOUS WATER.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . NORMAL FOG OR NOZZLE JET APPLICATION AND/OR EXCLUSION
OF AIR.
Unusual Fire/Explosion Hazard:CARBON MONOXIDE & CARBON DIOXIDE ARE
PRODS OF COMBUST. USE APPROP NIOSH/MSHA APPRVD RESP FOR PROT
AGAINST POSS EXPOS TO CO/CO*2. IT MAY NOT BE OBVIOUS (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:CARBON BLACK IS NOT HAZ WASTE UNDER U.S.
FEDERAL RCRA REG. WEAR NIOSH/MSHA APPRVD DUST PROT RESP, IF NEEDED.
SPILLS SHOULD BE REMOVED BY VACUUMING, OR SPRAYING WITH WATER &
SWEEPING MIXTURE INTO A SUI TABLE CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:BEFORE ENTERING CLOSED VESSELS AND
CONFINED SPACES, TEST FOR POSSIBLE ELEVATED LEVELS OF CO.
Other Precautions:WEAR APPROP NIOSH/MSHA APPRVD RESP TO GUARD AGAINST
POSSIBLE EXPOSURE TO CO, CO*2, OR LACK OF ADEQUATE OXYGEN SUPPLY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE IN NORMAL HANDLING. WEAR NIOSH/MSHA
APPROVED RESPIRATOR FOR NUISANCE DUST WHEN DUST LEVELS EXCEED TLV.
Ventilation:SUFFICIENT VENTILATION, IN VOLUME AND PATTERN, TO MAINTAIN
EXPOSURE BELOW TLV.
Other Protective Equipment:ANSI APPRVD EMERGENCY EYE WASH & DELUGE
SHOWER .
Work Hygienic Practices:WASH EXPOSED SKIN. MOST SKIN IRRIT ATTRIBUTED
TO CARBON BLACK HAS BEEN FOUND TO BE DUE TO SOAP USED FOR WASHUP.
(ING 15)
Supplemental Safety and Health
EXPLO HAZ:THAT CARBON BLACK IS BURNING UNLESS MATL IS STIRRED & SPARKS
ARE APPARENT. THE NATIONAL ELECTRICAL CODE (NEC) IS DERIVED FROM
NFPA STD 70, & IS REFERENCED IN OSHA REGS. UNDER NEC, CHAPTER 5,
ARTICLE 500-3, CARBON BLACK DUSTS ARE INCLUDED UNDER FPN NO. 14,
GROUP F DUSTS IF THEY CNTN "MORE THAN 8% TOTAL (ING 2)
================== Physical/Chemical Properties ==================
Spec Gravity:1.7-1.9(H*2O=1)
Solubility in Water:INSOLUBLE
Appearance and Odor:AMORPHOUS BLACK SOLID, NO ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
MAY REACT UPON CONTACT WITH STRONG OXIDIZERS SUCH AS CHLORATES,
BROMATES & NITRATES.
Stability Condition to Avoid:EXCESSIVE HEAT OR FLAME.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE &
SMALL AMOUNTS OF SULFUR CONTAINING GASES WHEN BURNING.
==================== Disposal Considerations ====================
Waste Disposal Methods:BURN OR BURY IN ACCORDANCE WITH FEDERAL, STATE
AND LOCAL LAWS AND REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:MT COLOR TONER II SEPIA
CAGE:GO339
CAGE:GO339
CAGE:23736
============= Composition/Information on Ingredients =============
Ingred Name:STYRENE ACRYLATE COPOLYMER
CAS:25153-46-2
Fraction by Wt: >85%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ORGANIC PIGMENT
CAS:32517-36-5
Fraction by Wt: 5-10%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:PROPENE POLYMERS; (POLYPROPYLENE)
CAS:9003-07-0
RTECS #:TR5000000
Fraction by Wt: 1-5%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ALKYLAMMONIUM SALT
Fraction by Wt: 1-3%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:OCTADECAMIDE; (STEARAMIDE)
CAS:124-26-5
RTECS #:RG0182000
Fraction by Wt: <1%
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORAL,RAT) >5 G/KG.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:MIN RESP TRACT IRRIT MAY OCCUR
AS W/EXPOS TO LG AMTS OF ANY NONTOX DUST. MAY CAUSE COUGH & RAISE
PHLEGM. CHRONIC:NONE. TONER PRESENTS LOW HAZ FOR USUAL OCCUP
SETTINGS. THE RSLTS OF ONE ANIMAL ST UDY WHERE RATS INHALED TONER
THAT WAS 10 TIMES MORE RESPIRABLE THAN COMMERCIALLY AVAIL TONER
WERE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:OBSERVED TO HAVE NO LUNG CHANGES AT
LOW EXPOS (THE MOST RELEVANT TO POTNTL HUMAN EXPOS). AT HIGHER
LEVELS A SLIGHT DEGREE OF LUNG FIBROSIS WAS OBSERVED DUE TO
EXCESSIVE AMTS OF DUST RETAINED IN THE LUNGS FOR A PROLONGED
INTERVAL. TONER, AS A MIXTURE, IS CONSIDERED A NUISANCE DUST.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHAL:WASH NOSTRILS, RINSE MOUTH. INGEST:DILUTE STOMACH
CONTENTS W/SEVERAL GLASSES OF WATER. EYES:FLUSH W/WATER FOR AT
LEAST 15 MINUTES. SKIN:WASH W/SOAP & WATER.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER, FOAM, DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . AVOID INHALATION OF SMOKE.
Unusual Fire/Explosion Hazard:IF DISPERSED IN AIR, TONER, LIKE MOST
FINELY DIVIDED ORGANIC POWDERS, MAY FORM AN EXPLOSIVE MIXTURE.
================== Accidental Release Measures ==================
Spill Release Procedures:IF SPILLED, SWEEP UP OR VACUUM.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:NONE.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN . NONE REQUIRED WHEN USED AS INTENDED IN
MINOLTA EQUIPMENT.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:N1
Spec Gravity:1.2 (H*2O=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:SEPIA POWDER; FAINT ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:PRODUCTS OF COMBUSTION ARE TOXIC.
AVOID BREATHING OF SMOKE.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE MAY BE DISPOSED OR INCINERATED UNDER
CONDITIONS WHICH MEET ALL FEDERAL, STATE & LOCAL ENVIRONMENTAL
REGULATIONS.
| 0 | gloves_not_mandatory |
===================== Product Identification =====================
Product ID:SODIUM ACETATE, I-118
CAGE:84898
CAGE:84898
CAGE:8Y898
============= Composition/Information on Ingredients =============
Ingred Name:ACETIC ACID, SODIUM SALT, TRIHYDRATE; (SODIUM ACETATE)
CAS:6131-90-4
RTECS #:AJ4580000
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SUPDAT:HAS ARRIVED. INGEST:DO NOT ADMIN LIQS/INDUCE VOMIT
TO AN UNCON/CONVULSING PERSON. IF SWALLOWED DRINK 1-2 (ING 3)
RTECS #:9999999ZZ
Ingred Name:ING 2:GLASSES OF WATER. CONT POIS CTL CTR IMMED IF NEC. GET
MED ATTN IF NEC. IF PATIENT IS VOMIT-WATCH CLOSELY (ING 4)
RTECS #:9999999ZZ
Ingred Name:ING 3:TO MAKE SURE AIRWAY DOES NOT BECOME OBSTRUCTED BY
VOMIT.
RTECS #:9999999ZZ
Ingred Name:EYE PROT:AND FULL LENGTH FACE SHIELD .
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50(RAT):3530 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:CONT LENSES SHOULD NOT BE WORN IN LAB.
ALL CHEMS SHOULD BE CONSIDERED HAZ-AVOID DIRECT PHYSICAL CONT! CAN
CAUSE EYE AND SKIN IRRITATION. REPEATED EXPOSURE TO VAPORS AND/OR
DUST CAN CAUSE EYE INJURY. D UST AND/OR VAPORS CAN CAUSE IRRITATION
TO RESPIRATORY TRACT. CAN BE IRRITATING TO MUCOUS MEMBRANES.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:AN ANTIDOTE IS SUBSTANCE INTENDED TO COUNTERACT EFT OF POIS.
IT SHOULD BE ADMIN ONLY BY MD/TRAINED EMER PERS. MED ADVICE CAN BE
OBTAINED FROM POIS CTL CTR. EYES:FLUSH CONTINUOUSLY W/WATER FOR @
LST 15 MIN. SKIN:FLUSH W/WATER FOR 15-20 MIN.IF NO BURNS HAVE
OCCURRED-USE SOAP & WATER TO CLEANSE. REMOVE & WASH CONTAM CLTHG.
DO NOT WEAR SHOES/CLTHG UNTIL ABSOLUTELY FREE OF ALL CHEM ODORS.
(SUPDAT)
===================== Fire Fighting Measures =====================
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. WEAR APPROPRIATE OSHA-REGULATED
EQUIPMENT. VENTILATE AREA. SWEEP UP AND PLACE IN AN APPROPRIATE
CONTAINER. HOLD FOR DISPOSAL. WASH CONTAMINATED SURFACES TO REMOVE
ANY RESIDUES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:USE APPROP OSHA/MSMA APPRVD SFTY
EQUIP. AVOID CONT W/SKIN, EYES & CLTHG. KEEP TIGHTLY CLSD & STORE
IN COOL, DRY PLACE. STORE ONLY W/COMPATIBLE CHEMS.
Other Precautions:PERSONS NOT SPECIFICALLY & PROPERLY TRAINED SHOULD
NOT HNDL CHEM/ITS CNTNR. FURNISHED FOR LAB USE ONLY! MAY NOT BE
USED AS DRUGS, COSMETICS, AGRICULTURAL/PESTICIDAL PRODS, FOOD
ADDITIVES/AS HOUSEHOLD CHEMS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:THIS CHEMICAL SHOULD BE HANDLED ONLY IN A HOOD.
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRST AID PROC:INHAL:REMOVE TO FRESH AIR. ADMIN OXYG IF PATIENT IS
HAVING DFCLTY BRTHG. IF PATIENT HAS STOPPED BRTHG ADMIN ARTF RESP.
IF PATIENT IS EXHIBITING SIGNS OF SHOCK-KEEP WARM & QUIET. GET MED
ATTN IF NEC. IF PATIENT IS IN CARDIAC ARREST ADMIN CPR. CONTINUE
LIFE SUPPORTING MEASURES UNTIL MED ASSISTANCE (ING 2)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:253F,123C
Melt/Freeze Pt:M.P/F.P Text:136F,58C
Vapor Density:1.45
Solubility in Water:SOLUBLE
Appearance and Odor:COLORLESS CRYSTALLINE SOLID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
REACTS WITH ACID HALIDES, ANHYDRIDES, PHOSPHORUS HALIDES AND THIONYL
CHLORIDE.
Stability Condition to Avoid:DO NOT USE MAGNESIUM/ALUMINUM OR THEIR
ALLOYS AS CONTAINERS.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS . FLUSH TO SEWER WITH COPIOUS AMOUNTS OF WATER.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:H3095-0 ALLOYS, HASTELLOY X ALLOY N06002
Preparer's Name:SAFETY DEPT
CAGE:80357
CAGE:80357
============= Composition/Information on Ingredients =============
Ingred Name:BORON (% IS MAX AMT)
CAS:7440-42-8
RTECS #:ED7350000
Fraction by Wt: 0.008%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:10 MG B203/M3
ACGIH TLV:10 MG B2O3/M3
Ingred Name:COBALT (SARA 313)
CAS:7440-48-4
RTECS #:GF8750000
Fraction by Wt: 1.5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.1 MG/M3
ACGIH TLV:0.02 MG/M3; A3; 9596
Ingred Name:CHROMIUM (SARA 313) (CERCLA)
CAS:7440-47-3
RTECS #:GB4200000
Fraction by Wt: 22%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3; 9596
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:IRON
CAS:7439-89-6
RTECS #:NO4565500
Fraction by Wt: 18%
Other REC Limits:NONE RECOMMENDED
Ingred Name:MANGANESE (SARA 313)
CAS:7439-96-5
RTECS #:OO9275000
Fraction by Wt: 1% MAX
Other REC Limits:NONE RECOMMENDED
OSHA PEL:C, 5 MG/M3 (FUME)
ACGIH TLV:0.2 MG/M3; 9596
Ingred Name:MOLYBDENUM
CAS:7439-98-7
RTECS #:QA4680000
Fraction by Wt: 9%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:10 PPM.
ACGIH TLV:10 PPM.
Ingred Name:NICKEL (SARA 313) (CERCLA)
CAS:7440-02-0
RTECS #:QR5950000
Fraction by Wt: 47%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3; 9596
Ingred Name:SILICON
CAS:7440-21-3
RTECS #:VW0400000
Fraction by Wt: 1% MAX
Other REC Limits:NONE RECOMMENDED
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9596
Ingred Name:TUNGSTEN,AS W,SOLUBLE COMPOUNDS.
CAS:7440-33-7
RTECS #:YO7175000
Fraction by Wt: 0.6%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:NOE ESTABLISHED
ACGIH TLV:1 MG/M3/3 STEL; 9596
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:INHAL:METAL DUST/FUME/POWDER MAY
RESULT FROM MELT/DROSS HNDLG/CAST/WELD/THERM
CUT/FRINK/CRUSH/SIMILAR OPERATIONS WHICH GENERATE AIRBORNE METAL
PARTICULATE DURING MATLS USE.INGEST:HAND/CLOTH/FOOD/DRINK CONTACT
W/METAL DUST/FUME/POWDER CAN CAUSE PARTICULATE INGEST DURING HAND
TO MOUTH ACTIVITIES(DRINK/SMOKE/(SUPPLEMENTA)
Explanation of Carcinogenicity:PER MSDS:CR(VI)/NI CMPDS CARC BY
OSHA/IARC/NTP.WELD FUME/CO CARC BY OSHA/IARC.CHEMS KNOWN TO STATE
OF CALIFORNIA CARC.
Effects of Overexposure:INGREDS METAL DUST/FUME IRRIT SKIN/EYE/MUC
MEMB.CR/CO/CU/NI CONTACT CAUSE ALLERGIC SKIN RX.IRRIT
SKIN/DERM,INJURY TO EYE FRM IRRIT/MECHAN INJURY TO CORNEA/CONJ BY
DUST/PARTIC.EXCESS AL,CO,CU,MN,NI RES P
IRRIT,COUGH,BRON,CHILLS,FUME FEVER,ASTHMA-LIKE SYMPT.RESP
DISEASE,CNS DEPRESS,GI DISORDER,LUNG CHANGES.
Medical Cond Aggravated by Exposure:ALLERGIC RX/SENS TO METALS
ENCOUNTER SKIN RASH/DERM.IMPAIRED PULM FUNCTION/AIRWAY
DISEASE/CONDITIONS LIKE ASTHMA,EMPHY,CHRONIC BRON,ETC FURTHER
DISABILITY.NERV,CIRC,BLOOD,KID DMG/DISEASE NEED SCREENIG
======================= First Aid Measures =======================
First Aid:INHAL:BREATH DIFFI MOVE TO FRESH AIR.STOP BREATH PERFORM ART
RESP.GET MED ATTN IMMED.INGGEST:SWALLOW LG QUANT OF WATER,ATTEMPT
TO INDUCE VOMIT IF CONSC.GET MED ATTN IMMED.SKIN:CUT/ABRASION TREAT
BY ST D 1STAID:CONTAM REMOVE BY WASHING W/SOAP/WATER.IRRIT PERSIST
GET MED ATTN.EYE:FLUSH W/COPIOUS AMTS OF CLEAN WATER.IRRIT PERSIST
GET MED ATTN.CONTACT LENSES SHOULDNT BE WORN WHEN WORK W/METAL
DUST/POWD
===================== Fire Fighting Measures =====================
Flash Point:NONE
Autoignition Temp:Autoignition Temp Text:NP
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:THESE ALLOYS ARE NON-COMBUSTIBLE.USE EXTINGUISHING
MEDIA APPROPRIATE TO SURROUNDING FIRE.
Fire Fighting Procedures:IF THESE MATLS REDUCED TO POWDER FORM CAUT
MUST BE USED TO PREVENT FIRE/EXPLO.TO EXT METAL POWDER FIRE USE DRY
SAND,DRY GRAPHITE,OTHER CLASS D FIRE EXT POWDER.
Unusual Fire/Explosion Hazard:NO USUSUAL FIRE OR EXPLO HAZARDS ARE
ASSOCIATED WITH THESE MATLS.
================== Accidental Release Measures ==================
Spill Release Procedures:SOLID FORM MATL POSE NO SPEC CLEANUP
PROBLEMS.MATL POWDER/DUST FORM CLEANUP SHOULD BE CONDUCTED W/VACUUM
SYS UTILIZING HEPA FILT SYS.CAUT SHOULD BE TAKEN TO MIN AIRBORNE
GENERATION OF POWDER/DUST,AVOI D CONTAM OF AIR/WATER.PROPERLY LABEL
COLLECT MATL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:HNDL ACCORDING TO
SIZE/SHAPE/QUANT.SOLID-USE HOIST,CRANE,ETC.POWDER-SPILL/RELEASE
POT.SOLID NO SPEC STORAGE PROBLEM.STORE METAL/POWDER IN DRY AREA.
Other Precautions:DONT STORE ADJ TO MINERAL ACIDS.KEEP FINE METAL
POWDER AWAY FLAME/IGN.EXPO TO ELEMENTS BEST DETERMINE BY AIR SMPLS
FRM WORKER BREATH ZONE/WORK AREA/DEPT.LUNG FUNCT TEST/CHEST
X-RAY/ROUTINE PHYS EXAM U SEFUL-DETERMINE EFFEFT OF DUST/FUME EXPO
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPROV RESP AS SPEC BY INDUSTR HYG/QUAL
SAF PROF.LUNG FUNCTION TESTS RECOMMENDED FOR USERS OF NEG PRESSURE
DEVICES.USE FUME RESP OR AIR SUPPL RESP WHERE LOC EXHAU/VENTI
DOESNT KEEP EXPO BEL OSHA LIMITS FOR AIR CONTAMINANTS.
Ventilation:LOC EXHAU VENTI SHOULD BE USED TO CONTROL EXPO TO AIRBORNE
DUST & FUME WHENEVER POSSIBLE.
Other Protective Equipment:POT CLOTH(UNIFORMS,DISPO COVERALLS,SAF
SHOES,ETC)MAY BE REQURIED DURING METAL HDNLG OPERATIONS AS APPROP
TO EXPO CIRCUM.
Work Hygienic Practices:CONTAINS SEC 313 EPCRA CHEMS.HEALTH HAZ INFO
GIVEN IN MSDS H-1072 FOR WELDING PRODUCTS ALSO APPLY.
Supplemental Safety and Health
HEALTH:NAIL BITE,ETC).SKIN:CONTACT MAY CAUSE IN SOME SENS PEOPLE
ALLERGIC RESPONSE IF ELEMENTS LIKE CR,CO,CU,NI PRESENT.METAL
DUST/POWDER CONTACT/ABRASION CAUSE IRRIT,DERM.EYE:PARTICU METAL
DANGEROUS TO EYE/SURROUNDING TISSUE.AIRBORNE PARTIC POT PROBLEM AS
WELL AS INSERTING FINGER INTO EYE IF HAND/CLOTH CONTAM W/PARTIC
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:NA
Melt/Freeze Pt:M.P/F.P Text:-2300F,-129
Decomp Temp:Decomp Text:NP
Vapor Pres:NA
Vapor Density:NA
Spec Gravity:0.297=DENSITY
pH:NP
Viscosity:NP
Evaporation Rate & Reference:NA
Solubility in Water:NONE
Appearance and Odor:SOLID-SILVER GRAY COLOR, NO ODOR
Percent Volatiles by Volume:NONE
Corrosion Rate:NP
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID COTNACT W/MINERAL ACIDS & OXIDIZING AGENTS WHICH MAY GENERATE
HYDROGEN GAS;EVOLUTION OF HYDROGEN MAY BE EXPLO HAZ.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:VAR ELEMENTAL METALS/METAL OXIDES MAY
BE GENERATED FRM WELD/CUT/GRINK/MELT/DROSS HNDLG OPERATIONS.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE MATL DISPO IAW STATE/FED REGS.SPEC
LABEL/PKG/STORAGE/TRANSPO/DISPO PROCEDURES CALL ENVIRO
ENGINEER/CONSULTANT FAMILIAR W/WASTE DISPO REGS.SOLID NO SPEC
ENVIRO PROBLEMS;POWDER/DUST SIGN IMPACT ONAIR/H2O QUAL.CONTROL
EMISS/SPILL/RELEASE.
======================================================================
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:HIGH TEMPERATURE INSULATION ADHESIVE, 760 NG
CAGE:14947
CAGE:14947
============= Composition/Information on Ingredients =============
Ingred Name:SODIUM SILICATE (AQUEOUS SOLUTION OF ALKALINE). VP: NOT
AVAILABLE. LD50:(ORAL,RAT) 2000-3000 MG/KG.
CAS:1344-09-8
Minumum % Wt:80.
Maxumum % Wt:90.
OSHA PEL:2 MG/M3, C
ACGIH TLV:2 MG/M3
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENT.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN: ON CONTINUED CONTACT, WILL CAUSE
SEVERE IRRITATION. CHRONIC LOCAL EFFECT MAY CONSIST OF SUPERFICIAL
DESTRUCTION. EYES: CAN CAUSE SEVERE IRRITATION IF NOT TREATED.
INHALATION: EXPOSURE TO MISTS M AY CAUSE COUGHING, SNEEZING; SEVERE
EXPOSURE MAY RESULT IN LUNG TISSUE DAMAGE. INGESTION: IRRITATION TO
MUCOUS MEMBRANES.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE KNOWN.
======================= First Aid Measures =======================
First Aid:SKIN: WASH WITH SOAP AND WATER. EYES: FLUSH WITH CLEAN WATER
FOR AT LEAST 15 MINUTES. IF IRRITATION PERSISTS, CONSULT MD.
INHALATION: REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT,
ADMINISTER OXYGEN.IF IRRITATION PERSISTS, CONSULT MD. INGESTION:
DO NOT INDUCE VOMITING. GIVE SEVERAL GLASSES OF MILK OR WATER; SEEK
MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:=100.C, 212.F
NO FLASH TO BOIL
Lower Limits:NOT AVAIL
Extinguishing Media:FOAM, CO*2, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE KNOWN. FLAMMABILITY CLASSIFICATION:
OSHA - IIIB; DOT - NOT REGULATED.
================== Accidental Release Measures ==================
Spill Release Procedures:SPILLS WILL BE VERY SLIPPERY. FOR LARGE
SPILLS, CONTAIN LIQUID AND SHOVEL UP MATERIAL FOR REMOVAL BY VACUUM
TRUCK. NEUTRALIZE RESIDUE WITH DILUTE ACID, FLUSH AREA WITH WATER,
FOLLOWED BY LIBERAL COVER ING OF SODIUM BICARBONATE. SMALL SPILLS
ARE READILY WASHED AWAY WITH WATER.
Neutralizing Agent:NEUTRALIZE RESIDUE WITH DILUTE ACID, FLUSH AREA WITH
WATER, FOLLOWED BY LIBERAL COVERING OF SODIUM BICARBONATE.
======================Handling and Storage ======================
Handling and Storage Precautions:FOR INDUSTRIAL USE ONLY. STORE INDOORS
AT TEMPERATURES OF 40F TO 90F. NOT FOR SPRAY TYPE APPLICATIONS.
PROTECT FROM FREEZING.
Other Precautions:FOR INDUSTRY/PROFESSIONAL USE ONLY. NOT INTENDED FOR
RETAIL SALE OR USE BY INDIVIDUAL CONSUMERS. DO NOT REUSE CONTAINER
FOR POTABLES OR EDIBLES. DRIED MATERIAL CAN PRODUCE VERY HARD,
SHARP EDGES. DO N OT SAND OR GRIND DRIED MATERIAL, AS RESPIRABLE
SILICA DUST CAN BE GENERATED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IN RESTRICTED VENTILATION AREAS, USE NIOSH
APPROVED CHEMICAL VAPOR RESPIRATOR. IN APPLICATIONS WHERE MISTS OR
SPRAY MAY BE GENERATED, AVOID INHALATION OF AIRBORNE PARTICULATES
BY USING A NIOSH APPROVE D RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE
WITH PREFILTER FOR MIST OR DUST.
Ventilation:GENERAL (MECHANICAL) ROOM VENTILATION IS EXPECTED TO BE
SATISFACTORY.
WATER.
FACESHIELD .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:THOROUGHLY CLEANSE HANDS AFTER HANDLING, AS
EXPOSURE CAN CAUSE BURNS WHICH ARE NOT IMMEDIATELY PAINFUL OR
VISIBLE. LAUNDER & DRY CLOTHING BEFORE REUSE. DISCARD FOOTWEAR THAT
CANNOT BE CLEANED.
Supplemental Safety and Health
PHYSICAL DATA: WT/GAL: 10.4 LBS.
================== Physical/Chemical Properties ==================
Boiling Pt:>100.C, 212.F
B.P. Text:212F - 216F
Melt/Freeze Pt:=0.C, 32.F
Decomp Temp:=426.7C, 800.F
Decomp Text:APPROX
Vapor Pres:SEE INGREDIENT
Vapor Density:LTR/AIR
Spec Gravity:1.25
pH:11
Viscosity:APPROX 80,000 CENTIPOISE
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:APPRECIABLE
Percent Volatiles by Volume:56
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
THIS MATERIAL IS ALKALINE - AVOID CONTACT WITH ACIDIC MATERIALS.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:NONE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS . DISPOSE OF I/A/W ALL APPLICABLE REGULATIONS. REVIEW
HAZARD SECTION OF THIS MSDS BEFORE ATTEMPTING CLEANUP. EMPTY
CONTAINERS ARE NON HA ZARDOUS UNDER RCRA AS INDUSTRIAL WASTE.
=================== MSDS Transport Information ===================
Transport Information:SHIPPING CLASS 55, PAINT (NO SPECIAL LABELS
REQUIRED).
===================== Regulatory Information =====================
SARA Title III Information:THIS MIXTURE CONTAINS THE FOLLOWING
MATERIALS REGULATED UNDER SECTION 313: NONE.
State Regulatory Information:
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:ALUMINUM, READY MIX TT-P-38E
Preparer's Name:C. M. K.
CAGE:0GB20
CAGE:0GB20
============= Composition/Information on Ingredients =============
Ingred Name:HYDROCARBON MIXTURE
CAS:64741-41-9
Fraction by Wt: 35.0%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM
ACGIH TLV:100 PPM
Ingred Name:ALUMINUM PASTE PIGMENT (SARA 313)
CAS:7429-90-5
RTECS #:BD0330000
Fraction by Wt: 15.0%
Other REC Limits:NONE RECOMMENDED
ACGIH TLV:5 MG/M3 DUST
Ingred Name:XYLENES (O-,M-,P- ISOMERS) (SARA 313) (CERCLA)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 10.0%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM/STEL 200 PPM
ACGIH TLV:100 PPM/150STEL PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:AROMATIC HYDROCARBON MIXTURE (SARA 313)
CAS:64742-95-6
Fraction by Wt: 5.0%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:50 PPM
ACGIH TLV:50 PPM
Ingred Name:TURPENTINE (SARA 313)
CAS:8006-64-2
RTECS #:YO8400000
Fraction by Wt: 5.0%
Other REC Limits:NONE RECOMMENDED
ACGIH TLV:100 PPM/STEL 150 PPM
Ingred Name:STEARIC ACID
CAS:57-11-4
RTECS #:WI2800000
Fraction by Wt: 5.0%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE: IRRIT (PAIN, TEAR, RED, SWELL,
STINGING SENSATION). SKIN: DEFATTING, DRYING, IRRIT, DERMATITIS.
INHAL: HEADACHE, DIZZY, NAUSEA, DECREASED BLOOD PRESSURE,
ARRHYTHMIA, CYANOSIS. INGEST: HARMFUL/FAT AL. CHRONIC: MAY CAUSE
NS/BRAIN DAMAGE.
======================= First Aid Measures =======================
First Aid:EYE: IMMED FLUSH W/PLENTY WATER >15 MIN, GET MED AID. SKIN:
WASH W/SOAP/WATER, GET MED AID, REMOVE CONTAM CLOTHES/SHOES, WASH
BEFORE REUSE. INHAL: GET FRESH AIR, IF NO BREATH, GIVE ARTIF RESP,
IF BREA TH DIF, GIVE OXY, GET IMMED MED AID. INGEST: INDUCE VOMIT
IMMED AS DIRECTED BY DOCTOR, NEVER GIVE ANYTHING BY MOUTH TO
UNCONSCIOUS PERSON, GET MED AID IMMED.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:102F,39C
Lower Limits:0.5
Upper Limits:7.0
Extinguishing Media:ALCOHOL FOAM, CO2, DRY CHEMICAL FOAM.
Fire Fighting Procedures:WEAR PRESSURE DEMAND SCBA, FULL PROTECTIVE
GEAR. DIKE/COLLECT WATER USED TO FIGHT FIRE.
Unusual Fire/Explosion Hazard:CAN RELEASE EXPLOSIVE VAPORS, CONTAINER
RETAINS RESIDUE.
================== Accidental Release Measures ==================
Spill Release Procedures:VENT AREA, ABSORB, PLACE IN CHEMICAL WASTE
CONTAINER, IF LARGE SPILL DIKE AREA, CALLL SPILL RESPONSE TEAM,
NOTIFY APPROPRIATE STATE/LOCAL AGENCIES.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM IGNITS, KEEP CONTAINER
CLOSED WHEN NOT IN USE, STORE IN COOL, DRY PLACE W/APPROPRIATE
VENT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED AIR PURIFYING RESPIRATOR
W/ORGANIC VAPOR CARTRIDGE OR CANISTER. IF LEVELS EXCEEDED, USE
POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR.
Ventilation:LOCAL EXHAUST VENT, USE EXPLOSION PROOF EQUIPMENT.
Other Protective Equipment:CHEMICAL SUIT, RUBBER BOOTS.
Work Hygienic Practices:WASH BEFORE EAT/DRINK/SMOKE, AVOID CONTACT
W/EYES/SKIN/CLOTHING.
Supplemental Safety and Health
(MORE INFORMATION ON FILE).
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:154 TO 395F
Vapor Density:>AIR
Spec Gravity:0.9612
Evaporation Rate & Reference:<BUAC
Percent Volatiles by Volume:52.9
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALKALIES, AQUEOUS ACIDS, AMINES & ACIDIC ALCOHOLS & STRONG OXIDIZING
AGENTS.
Stability Condition to Avoid:HEAT/SPARKS/OPEN FLAME.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:IN FACILITY PERMITTED FOR DISPOSAL OF HAZARDOUS
WASTE.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:162-168 MINERAL OIL
Preparer's Name:DICK KARBO
CAGE:KMADD
CAGE:KMADD
============= Composition/Information on Ingredients =============
Ingred Name:BARIUM COMPOUNDS
Fraction by Wt: 14%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:PROLONGED CONTACT W/SKIN/EYES CAN
CAUSE IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION
======================= First Aid Measures =======================
First Aid:EYES: FLUSH IMMEDIATELY W/WATER. SKIN: WASH AFFECTED AREA
W/SOAP & WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:>200F
Extinguishing Media:FOAM, CO2, DRY CHEMICAL
================== Accidental Release Measures ==================
Spill Release Procedures:SMALL: WIPE UP & STORE WIPERS IN UNDERWRITERS
APPROVED CONTAINERS. LARGE: SCOOP MATERIAL INTO SEALABLE
CONTAINERS. WIPE UP REMAINDER & STORE WIPERS IN UNDERWRITERS
APPROVED CONTAINERS.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN CLOSED CONTAINERS.
Other Precautions:AVOID CONTACT W/SKIN, EYES & CLOTHING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:AS REQUIRED
Ventilation:LOCAL EXHAUST
Work Hygienic Practices:WASH AFTER USE. REMOVE/LAUNDER CONTAMINATED
CLOTHING BEFORE REUSE. DON'T CONSUME FOOD/BEVERAGE WHERE PRODUCT IS
USED.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:470-610F
Evaporation Rate & Reference:SLOWER THAN WATER
Solubility in Water:INSOLUBLE
Appearance and Odor:OILY
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE &
LOCAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:PAINT AND VARNISH REMOVER, TAKE IT OFF
CAGE:DESTA
CAGE:DESTA
============= Composition/Information on Ingredients =============
Ingred Name:NO INGREDIENT FOR THIS FORMULATION_INGREDIENT
===================== Hazards Identification =====================
LD50 LC50 Mixture:N/K
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYES: SEVERE IRRIT, REDNESS, TEARING,
BLURRED VISION. SKIN: PRLG/RPTD CONTACT CAN CAUSE MODERATE IRRIT,
DEFATTING, DERM. MEASURES SHOULD BE TAKEN SO THAT THE TLV IS NOT
INVALIDATED. ESSENTIALLY NON-IR RIT. INHAL: EXCESS INHAL CAN CAUSE
NASAL & RESP IRRIT, DIZZ, HDACH. PRACTICALLY NON-TOXIC TO ANIMALS.
INGEST: CAN (SUPP)
Explanation of Carcinogenicity:IARC 2A
Effects of Overexposure:(SEE HEALTH HAZARDS)
Medical Cond Aggravated by Exposure:N/K
======================= First Aid Measures =======================
First Aid:EYES: IMMED FLUSH W/WATER FOR 15 MIN. SEEK MEDICAL ATTENTION
IF PAIN OR REDNESS PERSIST. SKIN: FLUSH W/WATER. REMOVE CONTAM
CLOTHING & WASH BEFORE RE-USE. WASH SKIN W/SOAP & WATER. INHAL:
MOVE TO FRES H AIR. IF BRTH HAS STOPPED/DIFFICULT GIVE ARTF
RESP/OXYGEN IF INDICATED. CALL MD. INGEST: DO NOT INDUCE VOMITING.
DRINK ONE GLASS OF WATER. CONTACT MD OR POISON CONTROL CENTER
IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point:67.0F,19.4C
Lower Limits:.5
Upper Limits:12.0
Extinguishing Media:CO*2, ALCOHOL, DRY CHEMICAL, OR OTHER NATIONAL FIRE
PROTECTION ASSOCIATION APPROVED METHOD.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . CLEAR FIRE AREA OF UNPROTECTED PERSONNEL.
COOL CONTAINERS WITH WATER.
Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE
FROM HEAT AND FLAME. NEVER USE WELDING OR CUTTING TORCH ON OR NEAR
THE CONTAINER.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. SOAK UP SPILLS
WITH ABSORBENT. PLACE IN NON-LEAKING CONTR. STORE LARGE QUANTITIES
IN BUILDING THAT COMPLY WITH OSHA 1910.106, OR IN A FENCED,
PROTECTED AREA OUTSIDE.
Neutralizing Agent:N/K
======================Handling and Storage ======================
Handling and Storage Precautions:COMPLY WITH FEDERAL, STATE, AND
FEDERAL REGULATIONS. DO NOT STORE ABOVE 120F, AVOID OPEN FLAMES AND
DIRECT SUNLIGHT.
Other Precautions:KEEP COVERED WHEN NOT IN USE. DO NOT TRANSFER
CONTENTS TO BOTTLES OR CONTAINERS THAT ARE NOT LABELED. KEEP OUT OF
REACH OF CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR FOR EXPOSURE OF
CONCERN .
Ventilation:VENTILATION APPROPRIATE FOR CONDITIONS OF USE.CONSULT
INDUSTRIAL HYGIENIST/SAFETY SPECIALIST FOR SPECIFIC GUIDANCE
Other Protective Equipment:LONG-SLEEVE SHIRT, TROUSERS, SAFETY SHOES,
SHOWER .
Work Hygienic Practices:NORMAL CARE. NO EATING, DRINKING, OR SMOKING
DURING USE.
Supplemental Safety and Health
HLTH HAZ: CAUSE NAUSEA, VOMITING, DIARRHEA, BLINDNESS, AND DEATH.
PULMONARY ASPIRATION HAZARD IF VOMITING OCCURS. CAN NOT BE MADE
================== Physical/Chemical Properties ==================
HCC:F3
Boiling Pt:B.P. Text:182F,83C
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Pres:20 AT 825F
Vapor Density:1.6
Spec Gravity:< WATER
pH:N/E
Evaporation Rate & Reference:LESS THAN ETHER.
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR LIQUID SOLVENT SWEET ODOR.
Percent Volatiles by Volume:90
Corrosion Rate:
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT, SPARKS, AND FLAMES.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN HAZARDOUS WASTE LANDFILL OR
RECLAIM/REPROCESS. DISPOSE OF NON-RETURNABLE CONTAINERS IN
HAZARDOUS WASTE LANDFILL.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:ACRYLIC LACQUER THINNER, CA 3098
CAGE:MART3
CAGE:MART3
CAGE:16772
============= Composition/Information on Ingredients =============
Ingred Name:RESP PROT: MASK OR PARTICULATE RESPIRATOR.
RTECS #:9999999ZZ
Ingred Name:EFTS OF OVEREXP:ANIMAL STUDIES HAVE CLEARLY DEMONSTRATED
DOSE-RELATED ADVERSE EFTS ON CNS, HEMATOPOIETIC TISSUE,(ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12: BLOOD, KIDNEYS, LIVER ASSOCIATED W/ADMINISTRATION
OF ETHYLENE GYCOL MONOBUTYL ETHER (EGBE) & ETHYLENE (ING 14)
RTECS #:9999999ZZ
Ingred Name:ING 13: GLYCOL MONOBUTYL ETHER ACETATE (EGBEA). (EXTRACTED
FROM DHHS (NIOSH) PUBLICATION NO. 90-118) .
RTECS #:9999999ZZ
Ingred Name:ING 9: MISUSE BY DELIBERATELY CONCENTRATING AND INHALING
CONTENTS CAN BE HARMFUL OR FATAL.
RTECS #:9999999ZZ
Ingred Name:VM & P NAPHTHA; (LIGHT ALIPHATIC HYDROCARBON SOLVENT). VP:
53
CAS:64742-89-8
Fraction by Wt: 15-25%
OSHA PEL:300 PPM;400 PPM STEL
ACGIH TLV:300 PPM
Ingred Name:TOLUENE (SARA III)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 15-40%
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:XYLENE. VP: 5.9
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 5%
OSHA PEL:100 PPM;150 PPM STEL
ACGIH TLV:100 PPM;150 PPM STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:METHANOL. VP: 92
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: <5%
OSHA PEL:S,200PPM/250STEL
ACGIH TLV:S,200PPM/250STEL; 93
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ISOPROPYL ALCOHOL; (2-PROPANOL). VP: 33
CAS:67-63-0
RTECS #:NT8050000
Fraction by Wt: 10%
OSHA PEL:400 PPM;500 PPM STEL
ACGIH TLV:400 PPM;500 PPM STEL
Ingred Name:ACETONE. VP: 180
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 20-30%
OSHA PEL:1000PPM
ACGIH TLV:750PPM/1000STEL;9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ACETIC ACID, BUTYL ESTER; (N-BUTYL ACETATE). VP: 10
CAS:123-86-4
RTECS #:AF7350000
Fraction by Wt: 5-10%
OSHA PEL:150 PPM;200 PPM STEL
ACGIH TLV:150 PPM;200 PPM STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ETHANOL, 2-BUTOXY-,ACETATE; (2-BUTOXYETHYL ACETATE) VP: 1
CAS:112-07-2
RTECS #:KJ8925000
Fraction by Wt: <5%
Ingred Name:SUPP DATA: CNTNRS W/COMPLETE & APPROP LBLG. DO NOT TAKE
INTERNALLY. KEEP OUT OF REACH OF CHILDREN. INTENTIONAL (ING 10)
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: IRRIT OF EYES, SKIN AND RESP
SYS. MAY CAUSE NERVOUS SYS DEPRESSION. EXTREME OVEREXPOS MAY RESULT
IN UNCON & POSSIBLY DEATH. HEADACHE, DIZZINESS, NAUSEA, AND LOSS OF
COORDINATION ARE INDICATIONS OF EXCESSIVE EXPOSURE TO VAPORS OR
SPRAY MISTS. REDNESS AND ITCHING/BURNING SENSATION MAY (SEE EFTS OF
OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: INDICATE EYE/EXCESSIVE SKIN EXPOS.
CHRONIC: PRLNGD OVEREXPOS TO SOLV INGREDS IN INGREDS SECTION MAY
CAUSE ADVERSE EFTS TO LIVER, URINARY, BLOOD FORMING,
CARDIO-VASCULAR, AND REPRODUCTIVE SYS . REPORTS HAVE ASSOCIATED
REPEATED AND PROLONGED OVEREXP TO SOLVENTS WITH PERM BRAIN &
NERVOUS SYS DAMAGE. (SEE ING 12)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP
WARM AND QUIET. SKIN: WASH AFFECTED AREA THORO WITH SOAP AND WATER.
REMOVE CONTAM CLOTHING AND LAUNDER BEFORE RE-USE. EYES: FLUSH EYES
WITH LA RGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL
ATTENTION. INGESTION: NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. DO NOT INDUCE VOMIT. GIVE SEVERAL GLASSES OF
H*2O. SEEK MED ATTN.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:1F,-17C
Lower Limits:0.5%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT
EQIUP.H*2O SPRAY MAY BE INEFFECTIVE.IF H*2O IS USED,FOG NOZ ARE
PREFERABLE. H*2O MAY BE USED TO COOL CLSD(SUP DATA)
Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM
HEAT/ELEC EQUIP/SPARKS & OPEN FLAME. CLSD CNTNRS MAY EXPLO WHEN
EXPOS TO EXTREME HEAT. APPLIC TO HOT SURFS REQS(SUP DATA)
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:CONTENTS ARE EXTREMELY FLAMMABLE. KEEP
AWAY FROM HEAT, SPARKS, & OPEN FLAME. VAPORS WILL ACCUMULATE
READILY & MAY IGNITE EXPLOSIVELY.
Other Precautions:DURING USE & UNTIL ALL VAPS ARE GONE: KEEP AREA
VENT.DO NOT SMOKE.EXTING ALL FLAMES, PILOT LIGHTS,& HEATERS-TURN
OFF STOVES, ELEC TOOLS & APPLIANCES, & ANY OTHER SOURCES OF IGNIT.
CONSULT NFPA CODE. U SE APPRVD BONDING & GROUNDING (SUP DATA)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CNTRLD BELOW APPLIC
LIMITS BY VENT,WEAR NIOSH/MSHA APPRVD PROPERLY FITTED ORG
VAP/PARTICULATE RESP FOR PROT AGAINST MATLS IN INGREDS SECTION.
WHEN SANDING/ABRADING DRIED FI LM, WEAR NIOSH/MSHA APPRVD DUST(ING
11)
Ventilation:SUFFICIENT TO MAINTAIN CONCENTRATIONS BELOW PEL/TLV.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC: CNTNRS TO PVNT PRESS BUILD-UP & POS AUTOIGNIT/EXPLO
WHEN EXPOS TO EXTREME HEAT. EXPLO HAZ: SPECIAL PREC. DURING EMER
CNDTNS OVEREXPOS TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMP MAY NOT
BE IMMED APPARENT. OBTAIN MED ATTN. OTHER PREC: PROC. KEEP CNTNR
CLSD WHEN NOT IN USE. TRANSFER ONLY TO APPRVD (ING 9)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:132F,56C
Vapor Pres:SEE INGRED
Vapor Density:HVR/AIR
Spec Gravity:0.8
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE FROM PROD MAY BE HAZ AS DEFINED UNDER RCRA
40 CFR 261.WASTE MUST BE TESTED FOR IGNITABILITY TO DETERM APPLIC
EPA HAZ WASTE NUMBERS.INCINERATE IN APPRVD FACILITY.DO NOT
INCINERATE CLSD CNTNR.DISPI/A/W FED, ST,& LOCAL REGS REGARDING
POLLUTION.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:LITHIUM HYDROXIDE MONOHYDRATE
CAGE:5D132
CAGE:5D132
============= Composition/Information on Ingredients =============
Ingred Name:LITHIUM HYDROXIDE; (LITHIUM HYDROXIDE MONOHYDRATE). MFR CAS
#1310-66-3.
CAS:1310-65-2
RTECS #:OJ6307070
Fraction by Wt: 99%
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:CORROSIVE. ACUTE:CHEMICAL BURNS TO
SKIN, EYES, NOSE AND THROAT. CHRONIC:CONTINUOUS INHALATION MAY
CAUSE LUNG DAMAGE.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYE: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINUTES. OBTAIN
MEDICAL ATTENTION. SKIN: IMMEDIATELY WASH AFFECTED SKIN W/PLENTY OF
WATER. REMOVE CONTAMINATED CLOTHING. GET IMMEDIATE MEDICAL
ATTENTION, I F NECESSARY. INHAL: REMOVE TO FRESH AIR. GET IMMEDIATE
MEDICAL ATTENTION IF NECESSARY. INGEST: DO NOT INDUCE VOMITING. IF
CONSCIOUS, GIVE LARGE AMOUNTS OF COLD WATER. GET IMMEDIATE MEDICAL
ATTENTION.
===================== Fire Fighting Measures =====================
Extinguishing Media:ANY SUITED FOR FIRE IN SURROUNDING AREA.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . NONE.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:COLLECT IN SUITABLE CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE AWAY FROM ACIDS AND WATER. KEEP
CONTAINER CLOSED. WASH THOROUGHLY AFTER HANDLING.
Other Precautions:HEALTH: CORROSIVE TO EYES, SKIN, NOSE AND THROAT.
CONTINUOUS INHALATION OF DUST MAY CAUSE LUNG DAMAGE. PHYSICAL:
REACTS WITH ACIDS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR WHEN
ADEQUATE VENTILATION IS NOT AVAILABLE.
Ventilation:USE WITH ADEQUATE VENTILATION.
Other Protective Equipment:EMERG EYE WASH AND DELUGE SHOWER WHICH MEETS
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EYE PROT:& FULL LENGTH FACESHIELD .
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:471C (880F)
Spec Gravity:1.5
Solubility in Water:22.3 AT 10C (50F)
Appearance and Odor:WHITE CRYSTALS, ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS, ALUMINUM, ZINC.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF WASTE ACCORDING TO FEDERAL EPA, STATE
AND LOCAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:SPARVAR PRODUCTS-2, S-161 BABY BLUE
CAGE:DO642
CAGE:87187
CAGE:DO642
============= Composition/Information on Ingredients =============
Ingred Name:PROPANE; (PROPANE (PROPELLANT)). VP: 760.0
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: 20%
OSHA PEL:1000 PPM
ACGIH TLV:ASPHYXIANT; 9495
Ingred Name:HEXANE (N-HEXANE) (CERCLA). VP: 127.0
CAS:110-54-3
RTECS #:MN9275000
Fraction by Wt: 18%
OSHA PEL:500 PPM
ACGIH TLV:50 PPM; 9495
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:XYLENE (SARA 313) (CERCLA). VP: 5.9
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 2%
OSHA PEL:100 PPM
ACGIH TLV:100 PPM/150STEL;9495
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:ACETONE (SARA 313) (CERCLA). VP: 180.0
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 15%
OSHA PEL:1000 PPM
ACGIH TLV:750PPM/1000STEL;9495
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:VM & P NAPHTHA. VP: 12.0
CAS:64742-89-8
Fraction by Wt: 18%
OSHA PEL:N/K
ACGIH TLV:300 PPM (MFR)
Ingred Name:ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER; (1-METHOXY
2-PROPANOL ACETATE)
CAS:108-65-6
RTECS #:AI8925000
Fraction by Wt: 5%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 9%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9495
Ingred Name:VOLATILE ORGANIC CONTENT AS A PERCENT BY WEIGHT PER BAAQMD
RULE 49: 85
RTECS #:9999999VO
Ingred Name:SUPDAT:TO THE LIVER, URINARY, BLOOD-FORMING,
CARDIOVASCULAR, AND REPROD SYS. RATS EXPOSED TO TITANIUM DIOXIDE
(ING 10)
RTECS #:9999999ZZ
Ingred Name:ING 9:DUST AT 250 MG/M3 DEVELOPED LUNG CANCER, HOWEVER,
SUCH EXPOS LEVELS ARE NOT ATTAINABLE IN THE WORKPLACE. (ING 11)
RTECS #:9999999ZZ
Ingred Name:ING 10:REPORTS HAVE ASSOCIATED REPEATED & PROLONGED
OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN & NERVOUS SYS DAMAGE.
RTECS #:9999999ZZ
Ingred Name:WASTE DISP METH:EXTRACTABILITY. DO NOT INCINERATE.
DEPRESSURIZE CONTAINER. DISPOSE OF IN ACCORDANCE WITH (ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12:FEDERAL, STATE, AND LOCAL REGULATIONS REGARDING
POLLUTION.
RTECS #:9999999ZZ
Ingred Name:OTHER PREC:DO NOT PUNCTURE, INCINERATE, OR EXPOSE TO TEMP
ABOVE 120F. HEAT FROM SUNLIGHT, RADIATORS, STOVES, (ING 15)
RTECS #:9999999ZZ
Ingred Name:ING 14:HOT WATER, AND OTHER HEAT SOURCES COULD CAUSE
CONTAINER TO BURST. DO NOT TAKE INTERNALLY. KEEP OUT OF (ING 16)
RTECS #:9999999ZZ
Ingred Name:ING 15:REACH OF CHILDREN. INTENTIONAL MISUSE BY
DELIBERATELY CONCENTRATING & INHALING CONTENTS CAN BE HARMFUL OR
FATAL.
RTECS #:9999999ZZ
Ingred Name:RESP PROT:BY NIOSH FOR DUST WHICH MAY BE GENERATED FROM
THIS PRODUCT, UNDERLYING PAINT, OR THE ABRASIVE.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: IRRIT OF EYES, SKIN & RESP SYS.
MAY CAUSE NERVOUS SYS DEPRESS. EXTREME OVEREXP MAY RESULT IN
UNCONSCIOUSNESS & POSSIBLY DEATH. SIGNS & SYMPS OF OVEREXP: HDCH,
DIZZ, NAUSEA, & LOSS OF COORDINATI ON ARE INDICATIONS OF EXCESSIVE
EXPOS TO VAPS/SPRAY MISTS. REDNESS & ITCHING/BURNING SENSATION MAY
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:INDICATE EYE/EXCESSIVE SKIN EXPOS.
CHRONIC: PRLNG & RPTD EXPOS TO HEXANE MAY CAUSE DMG TO NERVE TISS
OF ARMS & LEGS (PERIPHERAL NEUROPATHY), RSLTG IN MUSCULAR WEAK &
LOSS OF SENSATION. THIS E FT MAY BE INCR BY PRESENCE OF METHYL
ETHYL KETONE. METHYL ETHYL KETONE MAY INCREASE THE NERVOUS SYSTEM
(SUPDAT)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
======================= First Aid Measures =======================
First Aid:INHAL: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING.
KEEP WARM AND QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP
AND WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE.
EYES: FLUSH EYES WITH LARGE AMOUNTS OF WATERFOR AT LEAST 15
MINUTES. GET MEDICAL ATTENTION. INGEST: GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:<0F,<-18C
Lower Limits:0.9%
Upper Limits:13.1%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . IF
H*2O IS USED, FOG NOZZLES ARE PREF. H*2O MAY BE USED TO COOL CLSD
CNTNRS TO PVNT PRESSURE BUILD-UP (SUPDAT)
Unusual Fire/Explosion Hazard:ISOLATE FROM HEAT, ELEC EQUIP, SPARKS, &
OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT.
APPLICATIONS TO HOT SURFACES REQS SPECIAL (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, & OPEN
FLAME. VAPS WILL ACCUM READITLY & MAY IGNITE EXPLOSIVELY. DURING
USE & UNTIL ALL VAPS ARE GONE. KEEP AREA VENT.
Other Precautions:DO NOT SMOKE. EXTINGUISH ALL FLAMES, PILOT LIGHTS, &
HEATERS-TURN OFF STOVES, ELECTRIC TOOLS & APPLIANCES, & ANY OTHER
SOURCES OF IGNITION. CONSULT NFPA CODE. USE APPROVED BONDING &
GROUNDING PROCEDUR ES. CONTENTS UNDER PRESSURE. (ING 14)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
APPLIC LIM BY VENT, WEAR A PROPERLY FITTED ORG VAP/PARTICULATE RESP
APPRVD BY NIOSH FOR RESP ASSIST MATLS IN SECTION 2. WHEN
SANDING/ABRADING DRIED FILM, W EAR A DUST/MIST RESP APPROVED (ING
17)
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS TO MATLS IN
SECTION 2 IS MAINTAINED BELOW APPLICABLE EXPOS LIMITS.
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC:& POSS AUTOIGNITION/EXPLOSION WHEN EXPOSED TO EXTREME
HEAT. EXPLO HAZ:PRECS. DURING EMER CNDTNS OVEREXP TO DECOMP PRODS
MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE IMMED APPARENT. OBTAIN MED
ATTN. EFTS OF OVEREXP:EFTS OF OTHER SOLVS. PRLNG OVEREXP TO SOLV
INGS IN SECTION 2 MAY CAUSE ADVERSE EFTS (ING 9)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:<0F,<-18C
Vapor Pres:SEE ING
Vapor Density:HVR/AIR
Evaporation Rate & Reference:FASTER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE, OXIDES OF METALS IN SECTION 2.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE FROM THIS PROD MAY BE HAZS AS DEFINED
UNDER THE RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO
DETERM THE APPLCABLE EPA HAZ WASTE NUMBERS. WASTE FROM PRODS
CONTAINING METHYL ETHYL KET ONE OR COPPER MAY REQUIRE TESTING FOR
(ING 12)
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:102 2490,PROSTAR PLUS DEVLPR(AFTER AUG/83
CAGE:19139
CAGE:19139
============= Composition/Information on Ingredients =============
Ingred Name:HYDROQUINONE (SARA III)
CAS:123-31-9
RTECS #:MX3500000
Fraction by Wt: 3.0%
OSHA PEL:2 MG/M3
ACGIH TLV:2 MG/M3; 9192
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:MIXTURE OF SODIUM/POTASSIUM SULFATE; WT % RANGE:5-10%
Fraction by Wt: 7.5%
Ingred Name:WATER; CAS #7732-18-5; WT % RANGE:85-90
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 89.5%
===================== Hazards Identification =====================
Effects of Overexposure:EYES:LIQ MAY CAUSE IRRIT;
SKIN:PROLONGED/REPEATED CONTACT MAY CAUSE SKIN IRRIT &/OR ALLERGIC
ACTION.
======================= First Aid Measures =======================
First Aid:EYES:IMMED FLUSH EYES W PLENTY OF WATER & GET MED ATTN IF ANY
SYMPTOMS APPEAR AFTER WASHING;SKIN:FLUSH W/PLENTY OF WATER.IF SKIN
IRRITATION/AN ALLERGIC SKIN REACTION DEVELOPS,GET MED
ATTN;INGESTION:IM MEDIATELY GET MED ATTN.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:EXTINQUISH W. AGENT SUITABLE FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR SELF-CNTND BRTHG APP
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE
HAZARDOUS DECOMPOSITION OF THE PRODUCT OR RUPTURE CONTAINER.
================== Accidental Release Measures ==================
Spill Release Procedures:DO NOT TOUCH SPILL MATL. SM SPILL:ABSORB W
SAND,OTHER NON COMBUSTIBLES ABSORB; FLUSH W/H*2O LG SPILL:DIKE FAR
AHEAD OF SPILL FOR LATER DISPOSAL.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED
AREA. PROTECT FROM PHYSICAL DAMAGE.AVOID ANY PHYSICAL CONTACT. KEEP
CONTAINERS TIGHTLY CLOSED;AVOID CONTACT W/MINERA
Other Precautions:AVOID CONTACT WITH SKIN;THE ROUTINE USE OF A
NON-ALKALINE(ACID)TYPE OF HAND CLEANER WILL HELP MINIMIZE THE
POSSIBILITY OF ALLERGIC SKIN REACTION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED
Ventilation:GOOD GENERAL VENTILATION SHOULD BE SUFFICIEN(10 RM
VOL/HOUR)
Other Protective Equipment:FULL WORK CLOTHING TO PREVENT REPEATED OR
PROLONGED CONTACT.
Supplemental Safety and Health
MSDS FM MFR DATED:1-13-84;APPROX PH:10.6;MFR ADVISED(AUG/83) THE OLD
CAT #197 3114 IS DISCONTND AND ITEM UNDER THIS NE CAT #102 2490 IS
IMPROVED PRODUCT;SEE P/N IND A,THIS NSN,FOR OLD PRODUCT.
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:212F(100C)
Vapor Pres:18
Vapor Density:0.6
Spec Gravity:1.10
Evaporation Rate & Reference:0.36(BU-ACTATE=1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR,LIGHT YELLOW SOLUTION;ODORLESS
Percent Volatiles by Volume:85%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
MINERAL ACIDS PER MFR.
Hazardous Decomposition Products:SULFUR DIOXIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:KEEP IN COVERED DRUMS,PENDING DISPOSAL. HANDLE &
DISPOSE IN FULL COMPLIANCE WITH ALL APPLICABLE
INTERNATIONAL,FEDERAL,STATE, & LOCAL REGULATIONS;MFR SPECIFIED FLUS
WASTE TO ACID-FREE SEWER W/LG AMT H* 2O IAW REGS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:CHARCOAL, ACTIVATED (SEE SUPPL)
Kit Part:Y
Resp. Party Other MSDS Num.:CC 250
Preparer's Name:MICHAEL RASZEJA
CAGE:63759
Contract Num:MDA414-99-P-3705
CAGE:63759
============= Composition/Information on Ingredients =============
Ingred Name:ACTIVATED CARBON
CAS:7440-44-0
RTECS #:FF5250000
= Wt:100.
===================== Hazards Identification =====================
LD50 LC50 Mixture:NO DATA PROVIDED BY MANUFACTURER
Health Hazards Acute and Chronic:MAY BE HARMFUL IF INHALED. CAUSES EYE
AND SKIN IRRITATION. MATERIAL IS IRRITATING TO MUCOUS MEMBRANES AND
UPPER RESPIRATORY TRACT.
Explanation of Carcinogenicity:NO DATA PROVIDED BY MANUFACTURER
Effects of Overexposure:MAY BE HARMFUL IF INHALED. CAUSES EYE AND SKIN
IRRITATION. MATERIAL IS IRRITATING TO MUCOUS MEMBRANES AND UPPER
RESPIRATORY TRACT.
Medical Cond Aggravated by Exposure:NO DATA PROVIDED BY MANUFACTURER
======================= First Aid Measures =======================
First Aid:EYE: FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES,
LIFTING UPPER AND LOWER EYELIDS OCCASIONALLY; GET IMMEDIATE MEDICAL
ATTENTION. INHALATION: REMOVE TO FRESH AIR. IF ILL EFFECTS DEVELOP,
GET ME DICAL ATTENTION. SKIN: FLUSH THOROUGHLY WITH WATER.
INGESTION: IF SWALLOWED, IF CONSCIOUS, GIVE ONE OR TWO GLASSES OF
WATER TO DRINK. IF GASTROINTESTINAL SYMPTOMS DEVELOP, CALL
PHYSICIAN. NEVER GIVE A NYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point:COMBUSTIBLE
Extinguishing Media:WATER FOG, CARBON DIOXIDE, DRY CHEMICAL (ABC),
AVOID METHODS WHICH MAY STIR UP DUST CLOUDS.
Fire Fighting Procedures:IN FIRE CONDITIONS, WEAR A NIOSH/MSHA
APPROVED, SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE
CLOTHING.
Unusual Fire/Explosion Hazard:AIRBORNE DUST. WEAK EXPLOSION HAZARD. ALL
CARBONACEOUS MATERIALS WILL BURN UNDER CERTAIN CONDITIONS AND
ACTIVATED CARBON IS NO EXCEPTION. ACTIVATED CARBONS HOWEVER ARE NOT
HIGHLY FLAMMABLE AND BURN SL OWLY WITHOUT PRODUCING SMOKE OR FLAME.
================== Accidental Release Measures ==================
Spill Release Procedures:RECOVER FOR USE IF NOT CONTAMINATED. SWEEP UP
AND PLACE IN A SUITABLE CONTAINER. AVOID RAISING DUST. WASH SPILL
AREA WITH SOAP AND WATER.
Neutralizing Agent:NO DATA PROVIDED BY MANUFACTURER
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY PLACE AWAY FROM
FIRE HAZARDS. WASH THOROUGHLY AFTER HANDLING. KEEP CONTAINER
TIGHTLY CLOSED WHEN NOT IN USE.
Other Precautions:READ LABEL ON CONTAINER BEFORE USING. DO NOT WEAR
CONTACT LENSES WHEN WORKING WITH CHEMICALS. AVOID CONTACT WITH
SKIN, EYE AND CLOTHING. DO NOT BREATHE DUST. USE WITH ADEQUATE
VENTILATION. REMOVE AND WASH CONTAMINATED CLOTHING. KEEP OUT OF
REACH OF CHILDREN. FOR LABORATORY USE ONLY. NOT FOR FOOD, DR UG OR
HOUSEHOLD USE
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED IN NORMAL LABORATORY
HANDLING. IF DUSTY CONDITIONS PREVAIL, WORK IN A FUME HOOD OR WEAR
A NIOSH APPROVED DUST MASK OR RESPIRATOR.
Ventilation:LOCAL/MECHANICAL: RECOMMENDED. SPECIAL/OTHER: NO
Other Protective Equipment:SAFETY GLASSES, SMOCK, APRON, FIRE
EXTINGUISHER, AND EYE WASH STATION.
Work Hygienic Practices:REMOVE AND WASH CONTAMINATED CLOTHING.
Supplemental Safety and Health
PART OF AIR POLLUTION KIT P/N: 36W2045. HCC IS FOR BOTH THE KIT & THIS
PART. OTHER KIT RELATED MSDS': CLJPM, CLJPP,
================== Physical/Chemical Properties ==================
HCC:F8
Boiling Pt:B.P. Text:DECOMPOSES
Melt/Freeze Pt:M.P/F.P Text:3652-3697C
Vapor Pres:NEGLIGIBLE AS SOLID
Vapor Density:NO DATA
Spec Gravity:1.8-2.1
Evaporation Rate & Reference:NON-VOLITILE(NA)
Solubility in Water:INSOLUBLE
Appearance and Odor:BLACK POWDER; ODORLESS
Percent Volatiles by Volume:NON-VOLITILE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS
Stability Condition to Avoid:STABLE UNDER NORMAL AND FIRE CONDITIONS.
Hazardous Decomposition Products:CARBON MONOXIDE AND/OR CARBON DIOXIDE
=================== Toxicological Information===================
Toxicological Information:NO DATA PROVIDED BY MANUFACTURER
===================== Ecological Information =====================
Ecological:NO DATA PROVIDED BY MANUFACTURER
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN AN APPROVED INCINERATOR OR
UNCONTAMINATED MATERIAL MAY BE DISPOSED OF IN A SANITARY LANDFILL.
=================== MSDS Transport Information ===================
Transport Information:DOT: CARBON, ACTIVATED, 4.2, UN1362, PGIII.
===================== Regulatory Information =====================
SARA Title III Information:NO DATA PROVIDED BY MANUFACTURER
Federal Regulatory Information:NO DATA PROVIDED BY MANUFACTURER
State Regulatory Information:NO DATA PROVIDED BY MANUFACTURER
======================= Other Information =======================
| 0 | gloves_not_mandatory |
===================== Product Identification =====================
Product ID:MD 993 COVE BASE ADHESIVE
Preparer's Name:J BENNETT
CAGE:MACKL
CAGE:MACKD
CAGE:MACKL
============= Composition/Information on Ingredients =============
Ingred Name:MEDIUM ALIPHATIC NAPHTHA (AROMATIC 100), PARAFFIN-NAPTHANES
MINERAL SPIRITS *97-2*
CAS:64742-88-7
Fraction by Wt: <5%
Other REC Limits:100 PPM
OSHA PEL:500 PPM
ACGIH TLV:100 PPM
Ingred Name:ETHYLENE GLYCOL *97-2*
CAS:107-21-1
RTECS #:KW2975000
Fraction by Wt: 3%
Other REC Limits:10 MG/CUM
OSHA PEL:50 PPM
ACGIH TLV:C 127 MG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:VOLATILE ORGANIC CONTENT: 110 GM/L
RTECS #:9999999VO
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY CAUSE SLIGHT IRRITATION OF THE
SKIN.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/WATER FOR 10-15 MINS. SKIN: WASH W/SOAP &
WATER. INGESTION: DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION
IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:CO2, CHEMICAL FOAM, WATER FOG
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING GEAR WHEN IN
CONFINED AREA.
================== Accidental Release Measures ==================
Spill Release Procedures:SCOOP INTO CONTAINER & ALLOW TO DRY.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE INSIDE AT TEMPERATURES OF 60F TO
100F. DON'T ALLOW PRODUCT TO FREEZE.
Other Precautions:KEEP OUT OF EYES. AVOID INHALING HIGH CONCENTRATIONS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT REQUIRED.
Ventilation:LOCAL VENTILATION
Other Protective Equipment:NONE
Work Hygienic Practices:WASH W/SOAP & WATER AFTER EXPOSURE.
Supplemental Safety and Health
OEM CORP. SOLD OUT TO MACKLANBURG AROUND 5 YEARS AGO. OEM PRODUCT WAS
CALLED: NON FLAMMABLE WATER BASE COVE BASE ADHESIVE.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:212F
Vapor Pres:AS WATER
Vapor Density:>1
Spec Gravity:1.45
Evaporation Rate & Reference:(N-BUTYL ACETATE=1): 1
Solubility in Water:COMPLETE
Appearance and Odor:LIGHT CREAM LATEX
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:EXCESSIVE HEAT/COLD. FREEZING
Hazardous Decomposition Products:WHEN DRY: CO, WATER, CO2, NITROGEN
OXIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:WKG SOL,KODAK ECP-2B KIT COLOR DEVELOPER REPLENISHER
Preparer's Name:NOT PROVIDED
CAGE:19139
CAGE:19139
============= Composition/Information on Ingredients =============
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:95.
Maxumum % Wt:99.
Other REC Limits:NOT PROVIDED
Code:F
Code:F
Ingred Name:SODIUM CARBONATE
CAS:497-19-8
RTECS #:VZ4050000
Minumum % Wt:1.
Maxumum % Wt:5.
Other REC Limits:NOT PROVIDED
OSHA PEL:NOT PROVIDED
ACGIH TLV:NOT PROVIDED
Ingred Name:N,N-DIETHYL-2-METHYL-P-PHENYLENEDIAMINE, MONOHYDROCHLORIDE
CAS:2051-79-8
RTECS #:SS9560000
< Wt:1.
Other REC Limits:0.1 MG/M3 (MFR)
OSHA PEL:NOT PROVIDED
ACGIH TLV:NOT PROVIDED
Ingred Name:SODIUM SULFITE
CAS:7757-83-7
RTECS #:WE2150000
< Wt:1.
Other REC Limits:NOT PROVIDED
OSHA PEL:NOT PROVIDED
ACGIH TLV:NOT PROVIDED
Ingred Name:SODIUM SULFATE
CAS:7757-82-6
RTECS #:WE1650000
< Wt:1.
Other REC Limits:NOT PROVIDED
OSHA PEL:NOT PROVIDED
ACGIH TLV:NOT PROVIDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD-50 (FEMALE RAT): 107 MG/KG
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EFFECTS OF EXPOSURE: INHALATION:
EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED HANDLING. EYES: NO
SPECIFIC HAZARD KNOWN. MAY CAUSE TRANSIENT IRRITATION. SKIN: MAY
CAUSE ALLERGIC SKIN REACTION. INGESTIO N: MAY BE HARMFUL IF
SWALLOWED.
Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION
(COMPONENTS PRESENT AT 0.1% OR MORE): INTERNATIONAL AGENCY FOR
RESEARCH ON CANCER (IARC): NONE - AMERICAN CONFERENCE OF
GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH) (SODIU M BISULFITE): NOT
CLASSIFIABLE AS A HUMAN CARCINOGEN (A4) - NATIONAL TOXICOLOGY
PROGRAM (NTP): NONE - OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
(OSHA): NONE
Effects of Overexposure:EYES: MAY CAUSE TRANSIENT IRRITATION. SKIN: MAY
CAUSE ALLERGIC SKIN REACTION.
Medical Cond Aggravated by Exposure:NOT PROVIDED
======================= First Aid Measures =======================
First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT
SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES:
ANY MATERIAL THAT CONTACTS THE EYE SHOULD BE WASHED OUT IMMEDIATELY
WITH WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.SKIN:
IMMEDIATELY REMOVE CONTAMINATED CLOTHING AND SHOES AND WASH WITH
SOAP AND PLENTY OF WATER. GET MEDICAL ATTENTION. WASH CONTAMINATED
CLOTHING BEFORE REUSE . DESTROY OR THOROUGHLY CLEAN CONTAMINATED
SHOES. INGESTION: DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL
ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:ABSORB SPILL WITH VERMICULITE OR OTHER INERT
MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN
SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
Neutralizing Agent:NOT PROVIDED
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED.
Other Precautions:AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. AVOID
PROLONGED OR REPEATED BREATHING OF MIST OR VAPOR. USE WITH ADEQUATE
VENTILATION. WASH THOROUGHLY AFTER HANDLING. ROUTINE USE OF
NONALKALINE (ACID) TY PE OF HAND CLEANER AND REGULAR CLEANING OF
REACTION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
RISK OF EXPOSURE.
Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER
Work Hygienic Practices:NOT PROVIDED
Supplemental Safety and Health
SUPPLEMENTARY LOCAL EXHAUST VENTILATION, CLOSED SYSTEMS, OR RESPIRATORY
PROTECTION MAY BE NEEDED IN SPECIAL CIRCUMSTANCES SUCH AS POORLY
VENTILATED SPACES, EVAPORATION FROM LARGE SURFACES, SPRAYING, H
EATING, ETC.
================== Physical/Chemical Properties ==================
HCC:B3
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:>100.C, 212.F
Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:(68F): 24 MBAR (18 MM HG)
Vapor Density:0.6
Spec Gravity:NOT AVAILABLE
pH:10.5
Viscosity:NOT PROVIDED
Evaporation Rate & Reference:NOT PROVIDED
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS, ODORLESS, LIQUID.
Percent Volatiles by Volume:95-99 WT
Corrosion Rate:NOT PROVIDED
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE WITH COMMON MATERIALS AND CONTAMINANTS WITH WHICH THE MATERIAL MAY
REASONABLY COME INTO CONTACT.
Stability Condition to Avoid:NOT PROVIDED
Hazardous Decomposition Products:NONE (NONCOMBUSTIBLE)
=================== Toxicological Information===================
Toxicological Information:ACUTE TOXICITY DATA FOR
N,N-DIETHYL-2-METHYL-P-PHENYLENEDIAMINE,MONOHYDROCHLORIDE:ORAL
LD-50 (FEMALE RAT): 107 MG/KG. ORAL LD-50(MALE RAT):132 MG/KG.
DERMAL LD-50:>2000 MG/KG. SKIN IRRITATION: NONE. R EPEATED SKIN
APPLICATION:MODERATE IRRITATION. SKIN SENSITIZATION: MODERATE. SKIN
SENSITIZATION (HUMAN): POSITIVE. EYE IRRITATION (UNWASHED
EYES):MODERATE. EYE IRRITATION(WASHED EYES): SLIGHT. SUBCHRON IC
TOXICITY DATA FOR
N,N-DIETHYL-2-METHYL-P-PHENYLENEDIAMINE,MONOHYDROCHLORIDE:ORAL
STUDY(4 WEEKS, RAT): NOEL=20 MG/KG/DAY LOEL=60 MG/KG/DAY(TARGET
ORGAN EFFECTS:LIVER). LOEL=LOWEST-OBSERVED-EFFECT LE VEL. NOEL =
NO-OBSERVED-EFFECT LEVEL.
===================== Ecological Information =====================
Ecological:NOT PROVIDED
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. CONTRACT WITH A LICENSED
CHEMICAL DISPOSAL AGENCY. SINCE EMPTIED CONTAINERS RETAIN PRODUCT
RESIDUE, FOLLOW LABEL WAR NINGS EVEN AFTER CONTAINER IS EMPTIED.
=================== MSDS Transport Information ===================
Transport Information:NOT REGULATED.
===================== Regulatory Information =====================
SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR
PART 372: NONE
Federal Regulatory Information:NOT PROVIDED
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: NONE - MATERIAL(S) KNOWN TO THE STATE
OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE
======================= Other Information =======================
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===================== Product Identification =====================
Product ID:BUFFER PE,QUIAPREP SPIN MINIPREP KIT,27106
CAGE:01QT0
CAGE:01QT0
============= Composition/Information on Ingredients =============
Ingred Name:TRIS(HYDROXYMETHYL)AMINOMETHANE
CAS:77-86-1
RTECS #:TY2900000
Ingred Name:HYDROCHLORIC ACID
CAS:7647-01-0
RTECS #:MW4025000
OSHA PEL:C7 MG/M3;C5 PPM
ACGIH STEL:C7.5 MG/M3;C5 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:ACUTE: INHALATION: MAY BE HARMFUL BY
INHALATION. EYE CONTACT: MAY CAUSE IRRITATION. SKIN CONTACT: MAY
CAUSE IRRITATION. INGESTION: MAY BE HARMFUL IF SWALLOWED. CHRONIC:
NOT APPLICABLE.
Effects of Overexposure:SEE HEALTH HAZARDS.
======================= First Aid Measures =======================
First Aid:EYES: IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT
LEAST 15 MINUTES. ASSURE ADEQUATE FLUSHING OF EYES BY SEPARATING
EYELIDS WITH FINGERS. SKIN: IMMEDIATELY WASH WITH SOAP AND COPIOUS
AMOUNTS OF WATER. REMOVE AND WASH CONTAMINATED CLOTHING PROMPTLY.
INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. INGESTION:
WASH OUT MO UTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL MD.
===================== Fire Fighting Measures =====================
Extinguishing Media:NONCOMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE
TO SURROUNDING FIRE CONDITIONS.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
CONTAINERS FOR DISPOSAL. VENTIL ATE AREA AND WASH SPILL SITE AFTER
MATERIAL PICKUP IS COMPLETE.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE TIGHTLY CLOSED AT 20-25C. KEEP
TIGHTLY CLOSED. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. DO NOT
BREATHE VAPOR. STORE IN A DRY PLACE.
Other Precautions:SEVERE EYE IRRITANT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Vapor Pres:NOT APPLICABLE (20C)
Spec Gravity:0.985 G/CM3 @ 20C
pH:7.7 @ 20C
Viscosity:NOT APPLICABLE (20C)
Solubility in Water:SOLUBLE @ 20C
Appearance and Odor:COLORLESS LIQUID; NO ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NOT APPLICABLE.
Hazardous Decomposition Products:NOT APPLICABLE.
=================== Toxicological Information===================
Toxicological Information:TOXICITY DATA: NOT APPLICABLE. ADDITIONAL
INFORMATION: THE PRODUCT SHOULD BE HANDLED WITH THE NORMAL CAUTION
ACCORDED CHEMICALS. ADDITIONAL HARMFUL PROPERTIES CANNOT BE RULED
OUT.
===================== Ecological Information =====================
Ecological:NOT APPLICABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:FOR SMALL QUANTITIES FLUSH DOWN SINK WITH WATER.
OBSERVE ALL FEDERAL, STATE AND LOCAL LAWS.
=================== MSDS Transport Information ===================
Transport Information:NOT APPLICABLE.
===================== Regulatory Information =====================
SARA Title III Information:NOT APPLICABLE.
Federal Regulatory Information:NOT APPLICABLE.
State Regulatory Information:NOT APPLICABLE.
======================= Other Information =======================
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===================== Product Identification =====================
Product ID:FORMULA 1477N
CAGE:DO828
CAGE:DO828
CAGE:94058
============= Composition/Information on Ingredients =============
Ingred Name:150F FLASH POINT AROMATIC SOLVENT.(MFR STATES DOES NOT
CONTAIN BENZENE)
Fraction by Wt: 60%
ACGIH TLV:50PPM (MFR)
Ingred Name:2-BUTOXYETHANOL
CAS:111-76-2
RTECS #:KJ8575000
Fraction by Wt: 15%
OSHA PEL:S, 50 PPM
ACGIH TLV:S, 25 PPM; 9293
Ingred Name:DETERGENTS. WHEN COMBINED W/ WETTING AGENTS FORMS 25% OF
THE PRODUCT.
Ingred Name:WETTING AGENT
===================== Hazards Identification =====================
Effects of Overexposure:DIZZINESS, DEFATS SKIN.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/ WATER FOR 15 MINUTES. SKIN: WASH W/ SOAP &
WATER. INHAL: REMOVE TO FRESH AIR. IF ANY SYMPTOMS PERSIST, CALL
MD.
===================== Fire Fighting Measures =====================
Flash Point:150F; 66C
Lower Limits:2
Upper Limits:6
Extinguishing Media:CO*2, WATER
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH WITH WATER OR USE DRY ABSORBENT.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE NEAR HEATED AREAS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:MFR RECOMMENDS NIOSH/MSHA APPRVD RESPIRATOR FOR
ORGANIC CHEM IF NEC.
Ventilation:MECHANICAL(GENERAL) SUFFICIENT TO KEEP BELOW TLV.
Supplemental Safety and Health
SPEC: CLASS I. VAPOR PRESSURE: <0.5. CONTAINER SIZE: 5 GAL CAN.
================== Physical/Chemical Properties ==================
HCC:V4
Boiling Pt:B.P. Text:270F; 132C
Vapor Density:3.1
Spec Gravity:0.912
Evaporation Rate & Reference:<0.1 (H*2O = 1)
Solubility in Water:DISPERSES
Appearance and Odor:CLEAR,STRAW COLOR, AROMATIC ODOR.
Percent Volatiles by Volume:15
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
==================== Disposal Considerations ====================
Waste Disposal Methods:MFR RECOMMENDS DISPOSING AS COMBUSTIBLE WASTE.
DISPOSAL METHOD MUST BE IAW FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:POLYURETHANE NO. 81
CAGE:01PD6
CAGE:72818
CAGE:01PD6
============= Composition/Information on Ingredients =============
Ingred Name:MEDIUM ALIPHATIC NAPHTHA (AROMATIC 100)
CAS:64742-88-7
Fraction by Wt: 20-25%
Other REC Limits:100 PPM
OSHA PEL:500 PPM
ACGIH TLV:100 PPM
Ingred Name:POLYURETHANE ALKYD
CAS:67989-28-0
Fraction by Wt: 20-25%
Ingred Name:ALKYD RESIN
CAS:68459-17-6
Fraction by Wt: 20-25%
Ingred Name:HYDROTREATED LIGHT DISTILLATE, PETROLEUM
CAS:64742-47-8
Fraction by Wt: 26-31%
Other REC Limits:300 PPM (MFR)
OSHA PEL:500 PPM
ACGIH TLV:100 PPM
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: RESP TRACT/MUCOUS MEMBRANE
IRRITATION/FATIGUE/DROWSINESS/DIZZINESS/HEADACHE/UNCOORDINATION/NAU
SEA/VOMITING/CNS DEPRESSION/ANESTHETIC/NARCOSIS. SKIN:
IRRITATION/DERMATITIS/DEFATTING. EYE: I RRITATION/BLURRED
VISION/TEARING/REDNESS/CORNEAL INJURY. INGESTION: LUNG INFLAMMATION
& DAMAGE DUE TO ASPIRATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:CAUSES PERMANENT BRAIN/NERVOUS SYSTEM DAMAGE.
INGESTION: POSSIBLE LIVER/KIDNEY DAMAGE. INHALATION: MAY LEAD TO
UNCONSCIOUSNESS, RESPIRATORY FAILURE, ASPHYXIATION & EVEN DEATH.
INTENTIONAL MISUSE BY DE LIBERATELY CONCENTRATING & INHALING
THECONTENTS MAY BE HARMFUL OR FATAL.
Medical Cond Aggravated by Exposure:PREEXISTING RESPIRATORY/LUNG
DISORDERS & ASTHMA.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE/SUPPORT BREATHING.
HAVE TRAINED PERSON GIVE OXYGEN IF NECESSARY. GET MEDICAL HELP FOR
ANY BREATHING DIFFICULTY. SKIN: WASH OFF QUICKLY W/PLENTY OF WATER.
THEN SOAP/WATER. REMOVE CONTAMINATED CLOTHING/WASH BEFORE REUSE.
EYES: FLUSH W/LARGE AMTS OF WATER FOR 15 MINS. OBTAIN MEDICAL
TREATMENT. INGESTION: OBTAIN MEDICAL TREATMENT IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point:104F
Lower Limits:0.7%
Extinguishing Media:DRY CHEMICAL, FOAM
Fire Fighting Procedures:WATER MAY BE USED TO COOL & PROTECT EXPOSED
CONTAINERS.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT/FLAME. VAPORS CAN FORM EXPLOSIVE MIXTURES
IN AIR AT ELEVATED TEMPERATURES.
================== Accidental Release Measures ==================
Spill Release Procedures:COMPLY W/ALL APPLICABLE HEALTH & ENVIRONMENTAL
REGULATIONS. VENTILATE AREA. SPILLS MAY BE COLLECTED
W/NON-COMBUSTIBLE ABSORBENT MATERIALS.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE <100F. KEEP AWAY FROM HEAT,
SPARKS & OPEN FLAME. USE ONLY W/ADEQUATE VENTILATION. DON'T TAKE
INTERNALLY. KEEP OUT OF REACH OF CHILDREN.
Other Precautions:AVOID CONTACT W/SKIN, EYES & BREATHING OF VAPORS.
WASH HANDS THOROUGHLY AFTER HANDLING, BEFORE EATING, SMOKING. KEEP
CONTAINERS TIGHTLY CLOSED/UPRIGHT WHEN NOT IN USE. EMPTY CONTAINERS
MAY CONTAIN HAZ ARDOUS RESIDUES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF SANDING IS DONE, WEAR A DUST MASK TO AVOID
BREATHING OF SANDING DUST. WHERE RESPIRATORY PROTECTION IS
REQUIRED. USE ONLY NIOSH/MSHA APPROVED RESPIRATORS.
Ventilation:PROVIDE MECHANICAL/LOCAL EXHAUST VENTILATION TO KEEP <TLV.
Other Protective Equipment:EYE WASH, SAFETY SHOWER
Work Hygienic Practices:REMOVE/WASH CONTAMINATED CLOTHING BEFORE REUSE.
WASH HANDS THOROUGHLY AFTER HANDLING, BEFORE EATING & SMOKING.
Supplemental Safety and Health
WT PER GAL: 7.4 LBS.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:308-374F
Percent Volatiles by Volume:60.1%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZERS, ACIDS, BASES, AMINES
Stability Condition to Avoid:KEEP AWAY FROM HEAT, SPARKS & OPEN FLAME
Hazardous Decomposition Products:CO, CO2. MAY DECOMPOSE UNDER FIRE
CONDITIONS EMITTING IRRITANT/TOXIC GASES.
Conditions to Avoid Polymerization:ELEVATED TEMPS. CONTACT W/OXIDIZING
AGENT.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND
FEDERAL REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:PLATINUM POTASSIUM CHLORIDE, P1581
CAGE:1B464
CAGE:1B464
============= Composition/Information on Ingredients =============
Ingred Name:ING 5:WORKERS. SKIN:PRLNG/RPTD EXPOS TO SOL PLATINUM CMPDS
MAY RESULT IN SENSIT. CHRONIC PLATINOSIS MAY RESULT IN(ING 7)
RTECS #:9999999ZZ
Ingred Name:ING 6:ECZEMATOUS PATCHES W/DRY SKIN, REDNESS, CRACKING &
SCALING OF LAYERS OF SKIN. EYE:PRLNG/RPTD EXPOS MAY CAUSE CONJ.
RTECS #:9999999ZZ
Ingred Name:FIRST AID PROC:UPPER & LOWER LIDS, UNTIL NO EVID OF CHEM
REMAINS (APPROX 15-20 MINS). GET MD IMMED. INGEST:TREAT (ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8:SYMPTOMATICALLY & SUPPORTIVELY. GET MD IMMED. IF
VOMIT OCCURS, KEEP HEAD LOWER THAN HIPS TO PVNT ASPIRATION.
RTECS #:9999999ZZ
Ingred Name:OTHER PROT EQUIP:SUBSTANCE, EMPLOYER SHOULD PROVIDE EYE
WASH FOUNTAIN & QUICK DRENCH SHOWER W/IN IMMED WORK AREA(ING 11)
RTECS #:9999999ZZ
Ingred Name:ING 10:FOR EMERGENCY USE.
RTECS #:9999999ZZ
Ingred Name:PLATINATE (2-), HEXACHLORO-, DIPOTASSIUM; (PLATINUM
POTASSIUM CHLORIDE)
CAS:16921-30-5
RTECS #:TP1650000
Fraction by Wt: 100%
OSHA PEL:0.002 MG/M3 (PT)
ACGIH TLV:0.002 MG/M3 (PT)
Ingred Name:SUPDAT:WHICH MAY BE DELAYED 2-6 MTHS MAY INCL SNEEZING,
RUNNING OF EYES & COUGH. LATER ASTHMATIC SYMPS OF COUGH, (ING 3)
RTECS #:9999999ZZ
Ingred Name:ING 2:TIGHTNESS OF CHEST, WHEEZING, DYSPNEA & CYANOSIS MAY
APPEAR ALL OF WHICH BECOME PROGRESSIVELY MORE SEV W/ (ING 4)
RTECS #:9999999ZZ
Ingred Name:ING 3:FURTHER EXPOS. AFT RECOVERY MOST INDIVIDUALS DEVEL
ALLERGIC SYMPS & EXPER FURTHER ASTHMA ATTACKS WHEN EXPOS(ING 5)
RTECS #:9999999ZZ
Ingred Name:ING 4:TO EVEN MINIMAL AMTS OF PLATINUM DUSTS/MISTS. NASAL
ULCERATION & BRONCH ASTHMA HAS BEEN REPORTED IN SOME (ING 6)
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:MAY CAUSE MUC MEMB IRRIT.
ALLERGIC RHINITIS & ASTHMATIC ATTACKS MAY OCCUR IN PREVIOUSLY
EXPOSED INDIVIDUALS. ASTHMATIC SYMPS OF COUGH, CHEST TIGHTNESS,
WHEEZING & SHORTNES OF BREATH MAY AP PEAR LATER. SKIN:CONT W/SOL
PLATINUM SALTS MAY CAUSE "PLATINOSIS" WHICH IS CHARACT BY ITCH,
REDNESS, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:PRURITIS & URTICARIAL RASH. IN SEV
CASES, RASH MAY DEVEL ON FACE & NECK. DERM WILL GENERALLY DISAPPEAR
W/IN SEVERAL DAYS AFT REMOVAL FROM EXPOS. EYE:DUSTS OF SOL PLATINUM
CMPDS MAY CAUSE BURN ING SENSATION, LACRIM & CONJ HYPEREMIA,WHICH
IS SOMETIMES ASSOC W/PHOTOPHOBIA. CHRONIC:INHAL:WORKERS RPTDLY
(SUPDAT)
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF ASTHMA OR
ALLERGIES MAY BE AT AN INCREASED RISK FROM EXPOSURE.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE FROM EXPOS AREA TO FRESH AIR IMMED. IF BRTHG HAS
STOPPED, PERFORM ARTF RESP. KEEP PERS WARM & @ REST. TREAT
SYMPTOMATICALLY & SUPPORTIVELY. GET MD IMMED. SKIN:REMOVE CONTAM
CLTHG & SHOES IMMED. WASH AFFECTED AREA W/SOAP/MILD DETERGENT & LG
AMTS OF H*2O UNTIL NO EVID OF CHEM REMAINS (APPROX 15-20 MINS). GET
MD IMMED. EYE:WASH IMMED W/LG AMTS OF H*2O/NORM SALINE, OCCAS
LIFTING (ING 8)
===================== Fire Fighting Measures =====================
Extinguishing Media:DRY CHEMICAL, CO*2, WATER SPRAY/ALCOHOL-RESISTANT
FOAM. FOR LARGER FIRES, USE WATER SPRAY, FOG/ALCOHOL-RESISTANT
FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD PRESS DEMAND/POS-PRESS
SCBA & FULL PROT EQUIP . MOVE CNTNR FROM FIRE AREA IF YOU CAN DO IT
W/OUT RISK. DO NOT SCATTER (SUPP DATA)
Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO
HEAT OR FLAME.
================== Accidental Release Measures ==================
Spill Release Procedures:OCCUPATIONAL SPILL:NO SPECIAL PRECAUTIONS
INDICATED.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:OBSERVE ALL FEDERAL, STATE & LOCAL
REGULATIONS WHEN STORING THIS SUBSTANCE, CONTACT THE DISTRICT
DIRECTOR OF THE ENVIRONMENTAL PROTECTION AGENCY.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR BASED ON
CONTAMINATION LEVELS FOUND IN WORKPLACE & ON SPECIFIC OPERATION.
REFER TO ORIGINAL MSDS FOR SPECIFIC SELECTIONS .
Ventilation:PROVIDE LOCAL EXHAUST OR PROCESS ENCLOSURE VENTILATION TO
MEET PEL.
Other Protective Equipment:APPROP PROT (IMPERVIOUS) CLTHG & EQUIP.
WHERE THERE IS ANY POSS THAT EMPLOYEE'S EYES &/OR SKIN MAY BE
EXPOSED TO(ING 10)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC:SPILLED MATL W/HIGH-PRESS H*2O STREAMS. DIKE FIRE-CTL
H*2O FOR LATER DISP. USE AGENTS SUITABLE FOR TYPE OF SURROUND FIRE.
AVOID BRTHG HAZ VAPS, KEEP UPWIND. EFTS OF OVEREXP:EXPOSED TO SOL
PLATINUM SALTS MAY DEVEL PLATINOSISWHICH IS CHARACT BY PRONOUNCED
IRRIT OF NOSE & UPPER RESP PASSAGES. SYMPS(ING 2)
================== Physical/Chemical Properties ==================
HCC:N1
Melt/Freeze Pt:M.P/F.P Text:482F,250C
Vapor Pres:0 @ 20C
Spec Gravity:3.499
Solubility in Water:5.22% @ 100C
Appearance and Odor:SMALL ORANGE-YELLOW CUBIC CRYSTALS OR POWDER.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NO DATA AVAILABLE.
Stability Condition to Avoid:NONE REPORTED.
Hazardous Decomposition Products:THERMAL DECOMPOSITION EMITS TOXIC
FUMES OF HYDRGEN CHLORIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE & LOCAL REGULATIONS
WHEN DISPOSING OF THIS SUBSTANCE, CONTACT THE DISTRICT DIRECTOR OF
THE ENVIRONMENTAL PROTECTION AGENCY.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:D.O. ELECTROLYTE, 096-0026
CAGE:IO924
CAGE:IO924
CAGE:62766
============= Composition/Information on Ingredients =============
Ingred Name:POTASSIUM HYDROXIDE (CERCLA). LD50:(ORAL,RAT) 365 MG/KG.
CAS:1310-58-3
RTECS #:TT2100000
Fraction by Wt: 5.8%
OSHA PEL:2 MG/M3, C
ACGIH TLV:2 MG/M3, C
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 94.2%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SUPDAT:FOG IN FLOODING AMTS. USE WATER SPRAY TO ABSORB CORR
MISTS. COOL CNTNRS W/FLOODING AMTS OF WATER FROM AS (ING 4)
RTECS #:9999999ZZ
Ingred Name:ING 3:FAR A DISTANCE AS POSSIBLE. AVOID BREATHING CORROSIVE
MISTS; KEEP UPWIND.
RTECS #:9999999ZZ
Ingred Name:EFTS OF OVEREXP:OCCUR IN FIRST 24 HRS, GASTRIC/ESOPHAGEAL
PERFORATION MAY CAUSE SEV ABDOM PAIN, RIGIDITY & SUDDEN(ING 6)
RTECS #:9999999ZZ
Ingred Name:ING 5:HYPOTENSION AFTER 2-4 DAYS. ESOPHAGEAL STRICTURE MAY
OCCUR LATER, EVEN AFTER SEVERAL YRS. CHRONIC:INHAL: (ING 7)
RTECS #:9999999ZZ
Ingred Name:ING 6:SAME AS ACUTE INHAL. SKIN CONT:RPTD/PRLNG EXPOS MAY
CAUSE DERM. EYE CONT:RPTD/PRLNG EXPOS TO MISTS CAUSES (ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7:CONJUNCTIVITIS & CORNEAL BURNS.
RTECS #:9999999ZZ
Ingred Name:FIRST AID PROC:(APPROX 15-20 MINS). IN CASE OF CHEM BURNS,
COVER AREA W/STERILE, DRY DRESSING. BANDAGE SECURELY,(ING 10)
RTECS #:9999999ZZ
Ingred Name:ING 9:BUT NOT TOO TIGHTLY. GET MED ATTN. EYES:WASH IMMED
W/LG AMTS OF WATER, OCCAS LIFTING UPPER & LOWER LIDS, (ING 11)
RTECS #:9999999ZZ
Ingred Name:ING 10:UNTIL NO CHEM REMAINS (FOR AT LST 15-20 MINS). IN
PRESENCE OF BURNS, APPLY STERILE BANDAGES LOOSELY W/OUT(ING 12)
RTECS #:9999999ZZ
Ingred Name:ING 11:MEDICATION. GET MED ATTN. INGEST:IF VICTIM IS
CONSCIOUS & NOT CONVULSIVE, GIVE HIM LG QTYS OF WATER TO (ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12:DILUTE. DO NOT INDUCE VOMITING. GET MEDICAL
ATTENTION IMMEDIATELY.
RTECS #:9999999ZZ
Ingred Name:MATLS TO AVOID:NITROSOUREA & METHYLENE CHLORIDE;
N-NITROSOMETHYLENE; MALEIC ANHYDRIDE:EXPLO RXN. NITROBENZENE: (ING
15)
RTECS #:9999999ZZ
Ingred Name:ING 14:EXPLO RXN ON HEATING. TETRAHYDROFURAN; CHLORINE
DIOXIDE:POSS EXPLO RXN. ACROLEIN; ACRYLONITRILE:VIOLENT (ING 16)
RTECS #:9999999ZZ
Ingred Name:ING 15:POLYMERIZATION. CHLOROFORM & METHANOL:INTENSE
EXOTHERMIC RXN. BENZOYL CHLORIDE & SODIUM AZIDE:VIOLENT (ING 17)
RTECS #:9999999ZZ
Ingred Name:ING 16:EXOTHERMIC RXN. O-NITROPHENOL (MOLTEN):VIOLENT RXN.
POTASSIUM PEROXODISULFATE; POTASSIUM PERSULFATE & (ING 18)
RTECS #:9999999ZZ
Ingred Name:ING 17:WATER; 2,2,3,3-TETRAFLUOROPROPANOL; HYPONITROUS
ACID:IGNIT RXN. TETRACHLOROETHANE:IGNIT ON HEATING. (ING 19)
RTECS #:9999999ZZ
Ingred Name:ING 18:THORIUM CARBIDE:INCANDESCENT RXN ON HEATING.
AMMONIUM HEXACHLOROPLATINATE; 1,2-DICHLOROETHYLENE; (ING 20)
RTECS #:9999999ZZ
Ingred Name:ING 19:NITROPARAFFINS (NITROETHANE; NITROMETHANE);
NITROALKANES; CALCIUM CARBIDE & CHLORINE; 2,4,6- (ING 21)
RTECS #:9999999ZZ
Ingred Name:ING 20:TRINITROTOLUENE & METHANOL:FORM OF EXPLO PROD.
TRICHLOROETHYLENE:FORM OF EXPLO PROD ON HEATING. (ING 22)
RTECS #:9999999ZZ
Ingred Name:ING 21:TETRACHLOROETHANE:FORM OF FLAMM PROD. ACIDS:REACTS
VIOLENTLY. METALS:CORR RXN W/FORM OF FLAMM HYDROGEN (ING 23)
RTECS #:9999999ZZ
Ingred Name:ING 22:GAS. GERMANIUM:INCANDESCENT REACTION.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENT 1.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:POTASSIUM HYDROXIDE SOLN IS SEV EYE,
SKIN & MUC MEMB IRRIT & CORR. ACUTE:INHAL:CORR. SINCE NO MIST WOULD
BE FORMED IN PROPOSED APPLICATION OF PROD NO PROB IS ANTIC. SKIN
CONT:CORR. RAPIDLY CAUSES IRRI T & SOFT NECROTIC DEEPLY PENETRATING
BURNS ON CONT. PENETRATION MAY CONTINUE FOR SEVERAL DAYS. EYE (EFTS
OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:CONT:IRRIT. CONT W/MISTS CAUSES IRRIT,
REDNESS, PAIN, BLURRED VISION, CONJ & BURNS. DIRECT CONT CAUSES
CONJ EDEMA & DMG & CORNEAL & EPISCLERAL DMG/DESTRUCTION.
INGEST:CORR. SEV PAIN IN MOUTH, THROAT & ABDOMEN, VOMIT,
HEMATOMESIS, DIARR, ANOREXIA, DIZZ, COLLAPSE, COMA & DEATH ARE
POSS. IF DEATH DOES NOT (ING 5)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE FROM EXPOS AREA TO FRESH AIR IMMED. IF BRTHG HAS
STOPPED, GIVE ARTF RESP. MAINTAIN AIRWAY & ADMIN OXYG IF AVAIL.
KEEP AFFECTED PERS WARM & AT REST. ADMIN OF OXYG SHOULD BE
PERFORMED BY QU ALIFIED PERS. GET MED ATTN IMMED. SKIN:REMOVE
CONTAM CLTHG WHILE RUNNING STREAMS OF WATER UNDER CLTHG. WASH
AFFECTED AREA W/SOAP OR MILD DETERGENT & LG AMTS OF WATER UNTIL NO
CHEM REMAINS (ING 9)
===================== Fire Fighting Measures =====================
Flash Point:WILL NOT BURN
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER OR FOAM. FOR
LARGER FIRES, USE WATER SPRAY, FOG OR ALCOHOL FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . MOVE
CNTNRS FROM FIRE AREA IF POSS. COOL CNTNRS EXPOS TO FLAMES W/WATER
FROM SIDE UNTIL WELL AFTER FIRE (SUPDAT)
Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE & EXPLOSION HAZARD WHEN
EXPOSED TO HEAT OR FLAME. HOWEVER, CONTACT W/MANY METALS CAUSES
EMISSION OF FLAMMABLE HYDROGEN GAS.
================== Accidental Release Measures ==================
Spill Release Procedures:OCCUP SPILL:DO NOT TOUCH SPILLED MATL. PROVIDE
VENT. WEAR PPE. FOR SM SPILLS, TAKE UP W/SAND OR OTHER ABSORB MATL
& PLACE INTO CNTNRS FOR LATER DISP. DO NOT USE METAL CNTNRS. CLOSE
TIGHTLY & LBL CORR. MOVE CNTNRS FROM SPILL AREA. KEEP UNNEC
(SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID HEATING TO BOILING POINT,
APPOXIMATELY 100C, WHERE CORROSIVE MIST IS EVOLVED. AVOID OTHER
ACTIONS WHICH WOULD CAUSE SOLUTION TO SPRAY.
Other Precautions:AVOID CONTACT WITH OR STORAGE W/INCOMPATIBLE
MATERIALS, INCLUDING THOSE LISTED IN REACTIVITY SECTION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:HIGH LEVELS - NIOSH APPROVED SUPPLIED-AIR
RESPIRATOR W/FULL FACEPIECE, HELMET OR HOOD. NIOSH APPROVED
SELF-CONTAINED BREATHING APPARATUS W/FULL FACEPIECE.
Ventilation:PROVIDE LOCAL EXHAUST VENTILATION &/OR GENERAL DILUTION
VENTILATION TO MEET PELS.
Other Protective Equipment:ANSI APPRVD EYE WASH FOUNTAIN & DELUGE
SHOWER . EMPLOYEE MUST WEAR APPROP PROT CLTHG & EQUIP TO PVNT
RPTD/(SUPDAT)
Work Hygienic Practices:DO NOT WEAR CONTACT LENSES WHEN WORKING
W/CHEMICALS.
Supplemental Safety and Health
SKIN CONT W/THIS SOLN. FIRE FIGHT PROC:IS OUT. EXTING USIN G AGENTS
INDICATED; DO NOT USE WATER DIRECTLY ON MATL. IF LG AMTS OF COMBUST
MATLS ARE INVOLVED, USE WATER SPRAY/(ING 3)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:212F,100C
Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C
Spec Gravity:1
pH:13.5
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS LIQUID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WATER-REACTIVE & OTHER SUBSTANCES:OLEUM, SODIUM. NITRIC TRICHLORIDE;
PHOSPHORUS; CHLORINE; N-METHYL-N- (ING 14)
Stability Condition to Avoid:STABLE UNDER NORMAL PRESSURES UP TO THE
BOILING POINT, APPROXIMATELY 100C.
Hazardous Decomposition Products:EMITS CORROSIVE MIST AT THE BOILING
POINT OR WHEN OTHERWISE CAUSED TO SPRAY.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS .
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:857 7611 COLOREDGE 1560/1565 CYAN DEVELOPER,500 GMS
Preparer's Name:NONE
CAGE:S5612
CAGE:EO274
CAGE:S5612
CAGE:19139
CAGE:5K871
============= Composition/Information on Ingredients =============
Ingred Name:COPPER OXIDE (1:1) (CUPRIC OXIDE)
CAS:1317-38-0
RTECS #:GL7900000
Fraction by Wt: <15%
Other REC Limits:NONE RECOMMENDED
Ingred Name:ZINC OXIDE
CAS:1314-13-2
RTECS #:ZH4810000
Fraction by Wt: <15%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:10 MG/M3 TDUST
ACGIH TLV:10MG/M3 TDUST; 9394
Ingred Name:IRON OXIDE
CAS:1309-37-1
RTECS #:NO7400000
Fraction by Wt: 90-95%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:10 MG/M3 (FE)
ACGIH TLV:5 MG/M3(FE),B2; 939
Ingred Name:POLYESTER RESIN
CAS:39382-25-7
Fraction by Wt: 3-10%
Other REC Limits:NONE RECOMMENDED
Ingred Name:PIGMENT (TRADE SECRET, REGISTRATION NO. 80100185-5013P)
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT) IS UNKNOWN.
Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION EXPECTED TO BE A LOW HAZARD
FOR RECOMMENDED HANDLING. EYE CONTACT MAY CAUSE TRANSIENT
IRRITATION. EXPECTED TO BE A LOW SKIN CONTACT HAZARD FOR
RECOMMENDED HANDLING. EXPECTED TO BE A LOW ING ESTION HAZARD.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:EYES: IRRITATION.
Medical Cond Aggravated by Exposure:PERSONS WITH A SKIN DISORDER MAY BE
AT INCREASED RISK FROM CONTACT WITH THIS PRODUCT.
======================= First Aid Measures =======================
First Aid:EYES: ANY MATERIAL THAT CONTACTS THE EYES SHOULD BE WASHED
OUT IMMEDIATELY WITH WATER. GET MEDICAL ATTENTION IF SYMPTOMS
OCCUR. SKIN: WASH AREA WITH SOAP AND WATER. GET MEDICAL ATTENTION
IF SYMPTOMS O CCUR. INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR.
GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. INGESTION: DRINK 1-2
GLASSES OF WATER. GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:COMBUSTIBLESOLID
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:COMBUSTIBLE SOLID. USE WATER SPRAY, CARBON DIOXIDE,
DRY CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. FIRE OR EXCESSIVE
HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS
Unusual Fire/Explosion Hazard:POWDERED MATERIAL MAY FORM EXPLOSIVE
DUST- AIR MIXTURES.
================== Accidental Release Measures ==================
Spill Release Procedures:DO NOT USE A VACUUM CLEANER TO CLEAN UP SPILLS
OF POWDERED DEVELOPERS AND TONERS. THE VERY FINE PARTICLES CAN
CAUSE A FIRE OR EXPLOSION. SWEEP MATERIAL ONTO PAPER AND PLACE IN A
FIBER CARTON. AVOID GE NERATION OF DUST.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINERS CLOSED. AVOID
BREATHING DUST. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY
AFTER HANDLING.
Other Precautions:LOW HAZARD FOR RECOMMENDED HANDLING. MINIMIZE DUST
GENERATION AND ACCUMULATION. REFER TO NFPA PAMPHLET NO.
654,"PREVENTION OF FIRE AND DUST EXPLOSIONS IN THE CHEMICAL, DYE,
PHARMACEUTICAL, AND PLASTIC S INDUSTRIES".
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NORMALLY REQUIRED.
Ventilation:GOOD VENTILATION (4-6 ROOM VOLUMES/HR) SHOULD BE USED.
VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS.
Other Protective Equipment:PROVIDE WASHING FACILITIES.
Work Hygienic Practices:WASH AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:NOT GIVEN
Melt/Freeze Pt:M.P/F.P Text:212 TO 302F
Vapor Pres:NEGLIGIBLE
Vapor Density:NOT GIVEN
Spec Gravity:4.0-5.0
Evaporation Rate & Reference:NEGLIGIBLE
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BLUE SOLID POWDER. SLIGHT ODOR.
Percent Volatiles by Volume:NIL
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
OXIDES OF IRON.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL, STATE
AND FEDERAL REGULATIONS. INCINERATE OR LANDFILL IF PERMITTED.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:7566/3
CAGE:53021
CAGE:00853
CAGE:53021
============= Composition/Information on Ingredients =============
Ingred Name:POLYCHLORINATED BIPHENYLS (PCBS) (SARA III)
CAS:1336-36-3
RTECS #:TQ1350000
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
Effects of Overexposure:ABSORBED THRU SKIN,LUNGS,INTESTINE.CAUSES
CANCER,LIVER,KIDNEY,STOMACH,EYE,HEARING DISORDER(SUP DATA)
======================= First Aid Measures =======================
First Aid:EYES:FLUSH W/WATER IMMEDIATELY.SKIN:WASH W/SOAP
IMMEDIATELY.INHAL:REMOVE TO FRESH AIR,GIVE ART.RESPIR.AS
NEEDED.INGEST:GET MEDICAL ATTN.GIVE LARGE QTY OF SALT WATER,INDUCE
VOMITING,BUT DO NOT MAKE UNC ONSCIOUS PERSON VOMIT.
================== Accidental Release Measures ==================
Spill Release Procedures:USE ABSORBENT & DIKES TO PREVENT
RUNOFF.ISOLATE & NOTIFY PROPER AUTHORITIES.
======================Handling and Storage ======================
Handling and Storage Precautions:STORAGE MUST FOLLOW RCRA REQUIREMENTS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SUPPLIED AIR W/FULL FACEPIECE,HELMET OR HOOD
Ventilation:LOCAL EXHAUST
Other Protective Equipment:FULL CLOTHING TO PREVENT SKIN CONTACT
Supplemental Safety and Health
OVEREXPOS:CAN CAUSE FORMATION OF CYSTS,CAUSES STILLBIRTHS.IRRITATES
EYES,NOSE THROAT.
================== Physical/Chemical Properties ==================
HCC:T6
Appearance and Odor:LIGHT STRAW-COLORED LIQUID,AROMATIC ODOR
================= Stability and Reactivity Data =================
STRONG OXIDIZERS
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-GENERALLY HIGH
TEMPERATURE INCINERATION.ONLY APPROVED DISPOSAL OPERATOR PERMITTED.
| 1 | gloves_mandatory |
=======================================================
Product ID: VF0151 CEFAZOLIN SODIUM
Cage: GO399
=======================================================
Preparer Co. when other than Responsible Party Co.
=======================================================
Cage: GO399
Assigned Ind: Y
=======================================================
Contractor Summary
=======================================================
Cage: GO399
Cage: 75602
=======================================================
Ingredients
=======================================================
Cas: 27164-46-1
RTECS #: XI0390000
=======================================================
Health Hazards Data
=======================================================
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ALLERGIC REACTIONS HAVE BEEN REPORTED, WHICH MAY INCLUDE
EYE IRRITATION.
Explanation Of Carcinogenicity: NONE
Signs And Symptions Of Overexposure: RASH, NASAL CONGESTION, COUGH, DRY THROAT,
GASTROINTESTINAL UPSET, IRRITATION, ANAPHYLACTIC SHOCK.
Medical Cond Aggravated By Exposure: PENICILLIN/CEPHALOSPORIN HYPERSENSITIVITY.
First Aid: EYES: FLUSH W/PLENTY OF WATER. SKIN: WASH W/PLENTY OF SOAP &
WATER. INHALATION: MOVE TO FRESH AIR. IF NOT BREATHING, PROIDE CPR IF
NECESSARY. INGESTION: DON'T INDUCE VOMITING. ADMINISTER ACTIVATED CHA RCOAL
(6-8 HEAPING TEASPOONFULS) W/TWO TO THREE GLASSES OF WATER. DON'T GIVE
ANYTHING BY MOUTH IF UNCONSCIOUS. OBTAIN MEDICAL ATTENTION IN ALL CASES.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: CONTAIN DRY MATERIAL BY SWEEPING UP/VACUUMING USING A
DUST COLLECTION FILTER. BE AWARE OF DUST EXPLOSION WHEN USING ELECTRICAL
EXPOSURE.
Waste Disposal Methods: DISPOSE OF ANY CLEANUP MATERIALS & WASTE RESIDUE IN
ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
Handling And Storage Precautions: UNDER NORMAL USE & HANDLING CONDITIONS,
NO PROTECTIVE EQUIPMENT IS REQUIRED.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: WATER, CO2, DRY CHEMICAL, FOAM/HALON
Unusual Fire/Explosion Hazard: AS A FINELY DIVIDED MATERIAL, MAY FORM EXPLOSIVE
DUST MIXTURES IN AIR WHICH COULD EXPLODE IF SUBJECTED TO A SOURCE OF
IGNITION.
=======================================================
Control Measures
=======================================================
Respiratory Protection: USE AN APPROVED RESPIRATOR. IN PRODUCTION,
AIRLINE-SUPPLIED, HOOD-TYPE RESPIRATORS ARE PREFERRED.
Ventilation: LABORATORY FUME HOOD/LOCAL EXHAUST
Other Protective Equipment: CHEMICAL RESISTANT CLOTHING, SAFETY GLASSES
Work Hygienic Practices: REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health: PH (10% SOLUTION): 4.5-6.
=======================================================
Physical/Chemical Properties
=======================================================
PH: (SUPP)
Solubility in Water: COMPLETE
Appearance and Odor: WHITE TO OFF-WHITE CRYSTALLINE POWDER W/NO ODOR
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: HEAT
Materials To Avoid: STRONG OXIDIZING AGENTS
Hazardous Decomposition Products: TOXIC FUMES WHEN HEATED
Hazardous Polymerization Indicator: NO
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: VF0151 CEFAZOLIN SODIUM
Cage: GO399
Assigned IND: Y
Company Name: LILLY ELI & CO PHARMACEUTICAL DIV
Street: LILLY CORPORATE CENTER
Zipcode: 46285
Label Required IND: Y
Date Of Label Review: 12/16/1998
Status Code: C
Label Date: 12/16/1998
Origination Code: G
Hazard And Precautions: ALLERGIC REACTIONS HAVE BEEN REPORTED, WHICH MAY
INCLUDE EYE IRRITATION.
RASH, NASAL CONGESTION, COUGH, DRY THROAT, GASTR
OINTESTINAL UPSET, IRRITATION, ANAPHYLACTIC SHOCK.
=======================================================
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:DUBL-CHEK PENETRANT, HM3A
CAGE:21405
CAGE:21405
============= Composition/Information on Ingredients =============
Ingred Name:POLYETHYLENE GLYCOL ETHER;(SECONDARY ETHOXLYATED FATTY
ALCOHOLS MIXTURE)
CAS:68131-40-8
Ingred Name:HYDROTREATED MIDDLE PETROLEUM DISTILLATE
CAS:64742-46-7
RTECS #:JN9379645
OSHA PEL:5 MG/M3 (OIL MIST)
ACGIH TLV:5 MG/M3 (OIL MIST)
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:NOT KNOWN.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:EYE:SEVERE IRRITATION. SKIN:IRRITATION.
INHAL:LIGHT HEADEDNESS.
Medical Cond Aggravated by Exposure:UNKNOWN.
======================= First Aid Measures =======================
First Aid:EYE:FLUSH WITH WATER FOR AT LEAST 15 MINUTES. GET MD.
SKIN:WASH, REMOVE CONTAMINATED CLOTHING. INHAL:FRESH AIR. INGEST:DO
NOT INDUCE VOMITING. GET MD.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:200F,93C
Extinguishing Media:CO*2, FOAM, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIP . DO NOT USE A DIRECT STREAM OF WATER, IT SPREADS
FIRE. PROD MAY FLOAT & REIGNITE ON SURF OF WATER.
Unusual Fire/Explosion Hazard:ON BURNING, THIS PRODUCT CAN RELEASE
TOXIC FUMES AND VAPORS.
================== Accidental Release Measures ==================
Spill Release Procedures:EXTINGUISH ALL FLAMES. MAKE DIKE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:HANDLING:DO NOT SPLASH OR CREATE MISTS
OR VAPORS. STORAGE:STORE AWAY FROM HIGH TEMPERATURES AND OPEN
FLAMES. KEEP CONTAINERS CLOSED.
Other Precautions:EMPTIED CONTAINER RETAINS VAPOR AND PRODUCT RESIDUES.
DO NOT CUT OR WELD ON OR NEAR THIS CONTAINER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR IF VAPORS OR
MISTS ARE GENERATED.
Ventilation:LOCAL EXHAUST IS ADVISABLE. MECHANIAL (GENERAL) EXHAUST IS
USUALLY NOT NECESSARY.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH BEFORE EATING. DO NOT SMOKE.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:440F,227C
Spec Gravity:0.90 (H*2O=1)
Solubility in Water:EMULSIFIABLE
Appearance and Odor:YELLOW, GREEN LIQUID. PETROLEUM ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING MATERIALS.
Stability Condition to Avoid:OPEN FLAMES AND HAZARDS NORMALLY
INCOMPATIBLE WITH PETROLEUM OILS.
Hazardous Decomposition Products:CARBON MONOXIDE AND OTHER UNIDENTIFIED
ORGANIC COMPOUNDS MAY BE FORMED UPON COMBUSTION.
==================== Disposal Considerations ====================
Waste Disposal Methods:TAKE UP WITH AN ABSORBENT MATERIAL AND DISPOSE
OF IN COMPLIANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:METHYL ALCOHOL 14280, A412RS115
CAGE:1B464
CAGE:1B464
============= Composition/Information on Ingredients =============
Ingred Name:METHYL ALCOHOL; (METHANOL) (SARA 313) (CERCLA)
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: >99%
OSHA PEL:S, 200 PPM
ACGIH TLV:S, 200 PPM/250 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:SUPDAT: ALUMINUM SALTS, BERYLLIUM, DIHYDRIDE, CARBON
TETRACHLORIDE & METALS, CHLOROFORM & HEAT, CHLOROFORM & (ING 3)
RTECS #:9999999ZZ
Ingred Name:ING 2: SODIUM HYDROXIDE, CYANURIC CHLORIDE, DIETHYL ZINC,
NITRIC ACID, & POTASSIUM TERTBUTOXIDE. PLEASE REFER (ING 4)
RTECS #:9999999ZZ
Ingred Name:ING 3: TO NFPA FIRE PROTECTION GUIDE FOR ALL SPECIFICS.
RTECS #:9999999ZZ
Ingred Name:EFTS OF OVEREXP: DESCRIBED FOR INGESTION. CHRONIC:
PROLONGED OR REPEATED SKIN CONT MAY CAUSE DERMATITIS. (ING 6)
RTECS #:9999999ZZ
Ingred Name:ING 5: CHRONIC INHALATION AND INGESTION MAY CAUSE EFFECTS
SIMILAR TO THOSE OF ACUTE INHALATION AND INGESTION. (ING 7)
RTECS #:9999999ZZ
Ingred Name:ING 6: TARGET ORGANS: KIDNEYS, CENTRAL NERVOUS SYSTEM,
LIVER, EYES.
RTECS #:9999999ZZ
Ingred Name:FIRST AID PROC: TEASPOON OF SYRUP OF IPECAC. INHAL: GET MED
AID IMMED. REMOVE FROM EXPOSURE TO FRESH AIR IMMED. (ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8: IF NOT BRTHG, GIVE ARTIFICIAL RESPIRATION. IF BRTHG
IS DIFFICULT, GIVE OXYGEN. NOTES TO PHYS: EFFECTS (ING 10)
RTECS #:9999999ZZ
Ingred Name:ING 9: MAY BE DELAYED. ETHANOL MAY INHIBIT METABOLISM. NO
SPECIFIC ANTIDOTE EXISTS.
RTECS #:9999999ZZ
Ingred Name:SPILL PROC: OR VERMICULITE.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50: (ORAL,RAT) 5628 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE: CAUSES MOD IRRIT. VAPS CAN
CAUSE EYE IRRIT. MAY CAUSE PAINFUL SENSITIZ TO LIGHT. SKIN: MAY
CAUSE IRRIT. MAY BE ABSORBED THRU SKIN IN HARMFUL AMTS. INGEST: MAY
CAUSE IRRIT OF DIGESTIVE TRAC T. MAY CAUSE CNS DEPRESS, CHARACT BY
EXCITEMENT, FOLLOWED BY HDCH, DIZZ, DROW, & NAUS. ADVANCED STAGES
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: MAY CAUSE COLLAPSE, UNCON, COMA &
POSS DEATH DUE TO RESP FAILURE. MAY CAUSE KIDNEY FAILURE. INHAL:
MAY CAUSE RESP TRACT IRRIT. MAY CAUSE LIVER & KIDNEY DMG. MAY CAUSE
ADVERSE CNS EFTS INCL H DCH, CONVLS, & POSS DEATH. MAY CAUSE VISUAL
IMPAIRMENT & POSS PERM BLNDNESS. MAY CAUSE EFTS SIMILAR TO THOSE
(ING 5)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/PLENTY OF WATER FOR @ LST 15 MINS, OCCASNLY
LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. DO NOT ALLOW VICTIM
TO RUB/KEEP EYES CLSD. SKIN: FLUSH W/PLENTY OF SOAP & WATER FOR @
LST 15 MI NS WHILE REMOVING CONTAMD CLTHG & SHOES. GET MED AID IF
IRRIT DEVELOPS/PERSISTS. INGEST: IF CONSCIOUS & ALERT, GIVE 2-4
CUPFULS OF MILK/WATER. GET MED AID IMMED. INDUCE VOMIT BY GIVING
ONE (ING 8)
===================== Fire Fighting Measures =====================
Flash Point:53F,12C
Lower Limits:6.0%
Upper Limits:31.0%
Extinguishing Media:SM FIRES, USE DRY CHEM, CO*2, WATER
SPRAY/ALCOHOL-RESIST FOAM. USE WATER SPRAY TO COOL FIRE-EXPOS
CNTNRS. WATER (SUPDAT)
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:CNTNRS CAN BUILD UP PRESS IF EXPOS TO
HEAT &/OR FIRE. VAPS CAN TRAVEL TO SOURCE OF IGNIT & FLASH BACK.
DURING FIRE, IRRITATING & HIGHLY TOX GASES MAY BE(SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:USE PROPER PERSONAL PROT EQUIP AS INDICATED.
SCOOP UP W/NONSPK TOOL, THEN PLACE INTO SUITABLE CNTNR FOR DISP.
USE WATER SPRAY TO DISPERSE GAS/VAP. REMOVE ALL SOURCES OF IGNIT.
ABSORB SPILL USING ABSOR B, NON-COMBUST MATL SUCH AS EARTH, SAND,
(ING 11)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM SOURCES OF IGNIT. STORE
IN COOL, DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE
SUBSTANCES. FLAMMABLE-AREA. USE W/ADEQUATE VENT.
Other Precautions:EMPTY CNTNRS RETAIN PROD RESIDUE, (LIQUID AND/OR
VAPOR), AND CAN BE DANGEROUS. DO NOT GET ON SKIN/IN EYES. DO NOT
INGEST/INHALE. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL,
GRIND/EXPOSE EMPTYCNTNRS TO HEAT, SPARKS/OPEN FLAMES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
29CFR 1910.134. ALWAYS USE A NIOSH-APPROVED RESPIRATOR WHEN
NECESSARY.
Ventilation:USE ADEQ GEN/LOC EXHAUST VENT TO KEEP AIRBORNE CONCS BELOW
PERMISSIBLE EXPOSURE LIMITS.
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . WEAR
APPROP PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE
CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
Supplemental Safety and Health
EXTING MEDIA: MAY BE INEFTIVE. EXPLO HAZ: GENERATED BY THERM
DECOMP/COMBUST. FLAMM LIQ. CAN RELEASE VAPS THAT FORM EXPLO MIX @
TEMPS ABOVE FLASHPOINT. MATLS TO AVOID: SODIUM HYPOCHLORITE).
ACTIVE META LS (SUCH AS POTASSIUM & MAGNESIUM). SUBSTANCE IS ALSO
INCOMPAT W/SPECIFIC CHEMS INCL: ACETYL BROMIDE, ALKYL (ING 2)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:148F,65C
Melt/Freeze Pt:M.P/F.P Text:-144F,-98C
Vapor Pres:96
Vapor Density:1.1
Spec Gravity:0.7910
Evaporation Rate & Reference:5.2 (ETHER = 1)
Solubility in Water:MISCIBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID. SLIGHT ALCOHOL-LIKE ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDANTS (SUCH AS BARIUM PERCHLORATE, BROMINE, CHLORINE, HYDROGEN
PEROXIDE, LEAD PERCHLORATE, PERCHLORIC ACID, (SUPDAT)
Stability Condition to Avoid:STABLE AT ROOM TEMP IN CLSD CNTNRS UNDER
NORM STOR & HNDLG CNDTNS. HIGH TEMPS, INCOMPATIBLE MATLS, IGNITION
SOURCES.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
FORMALDEHYDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE, AND LOCAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:SODIUM SULFIDE, 9-HYDRATE
CAGE:DO870
CAGE:DO870
CAGE:70829
============= Composition/Information on Ingredients =============
Ingred Name:SODIUM SULFIDE, 9-HYDRATE
CAS:1313-84-4
RTECS #:WE1925000
Fraction by Wt: 90-100%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SEVERE IRRITATION AND BURNS.
Explanation of Carcinogenicity:NONE OF THE CHEMICALS IN THIS PRODUCT IS
LISTED BY IARC, NTP OR OSHA AS A CARCINOGEN.
Effects of Overexposure:CONTACT WITH SKIN OR EYES MAY CAUSE SEVERE
IRRITATION OR BURNS.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF SKIN
DISORDERS MAY BE AT INCREASED RISK FROM EXPOSURE.
======================= First Aid Measures =======================
First Aid:IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING. IN
CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES. FLUSH SKIN WITH WATER.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER SPRAY
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:CAN BE AN EXPLOSION HAZARD,ESPECIALLY
WHEN HEATED.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & FULL
PROTECTIVE CLOTHING.SHUT OFF IGNITION SOURCES.NO FLARES,SMOKING OR
FLAMES IN AREA.WITH CLEAN SHOVEL,CAREFULLY PLACE MATERIAL INTO
CLEAN,DRY CONTAINER & C OVER.REMOVE FROM AREA.FLUSH SPILL AREA WITH
WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:PROTECT AGAINST PHYSICAL DAMAGE; STORE
IN COOL PLACE AWAY FROM ACIDS, OXIDIZING AGENTS & SOURCES OF
IGNITION, KEEPING CONTAINERS CLOSED.
Other Precautions:PRODUCT MUST BE REFRIGERATED AT 36-46F (2-8C).
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED WHERE ADEQUATE VENTILATIONS EXIST.
IF AIRBORNE CONCENTRATION IS HIGH,USE AN APPROPRIATE RESPIRATOR OR
DUST MASK.
Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP
FUME OR DUST LEVELS AS LOW AS POSSIBLE.
Other Protective Equipment:SAFETY SHOWER AND EYE BATH. OTHER EQUIPMENT
AS REQUIRED TO MINIMIZE EXPOSURE FROM PROLONGED OR REPEATED
CONTACT.
Work Hygienic Practices:WASH THROUGHLY AFTER HANDLING AND BEFORE
EATING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:B1
NRC/State Lic Num:NOT RELEVANT
Melt/Freeze Pt:=50.C, 122.F
Spec Gravity:1.43
Solubility in Water:APPRECIABLE
Appearance and Odor:YELLOW CRYSTALS WITH ODOR OF HYDROGEN SULFIDE.
Percent Volatiles by Volume:0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS, MOST COMMON METALS.
Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, AND OPEN FLAMES
Hazardous Decomposition Products:HYDROGEN SULFIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL,STATE & LOCAL ENVIRONMENTAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:AEROSOL SPRAY PAINT (GREEN) #14097
CAGE:07708
CAGE:07708
============= Composition/Information on Ingredients =============
Ingred Name:ACETONE (SARA 313) (CERCLA)
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 10-30%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1000 PPM
ACGIH TLV:750PPM/1000STEL;9596
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:METHYLENE CHLORIDE (SARA 313) (CERCLA)
CAS:75-09-2
RTECS #:PA8050000
Fraction by Wt: 10-40%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:500 PPM; Z-2
ACGIH TLV:50 PPM, A2; 9596
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:TOLUENE (SARA 313) (CERCLA)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 10-15%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:200 PPM; Z-2
ACGIH TLV:S, 50 PPM; 9596
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE
CAS:108-65-6
RTECS #:AI8295000
Fraction by Wt: 0-5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:NOT ESTABLISHED.
ACGIH TLV:NOT ESTABLISHED.
Ingred Name:DIACETONE ALCOHOL (4-HYDROXY-4-METHYL-2-PENTANONE)
CAS:123-42-2
RTECS #:SA9100000
Fraction by Wt: 5-10%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:50 PPM
ACGIH TLV:50 PPM; 9596
Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA 313) (CERCLA)
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: 0-5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:200 PPM
ACGIH TLV:200 PPM/300STEL;9596
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:PROPANE
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: <20%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1000 PPM
ACGIH TLV:ASPHYXIANT; 9596
Ingred Name:ISOBUTANE
CAS:75-28-5
RTECS #:TZ4300000
Fraction by Wt: <20%
Other REC Limits:NONE RECOMMENDED
Ingred Name:BUTANE
CAS:106-97-8
RTECS #:EJ4200000
Fraction by Wt: <20%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:800 PPM
ACGIH TLV:800 PPM; 9596
Ingred Name:NON-HAZARDOUS INGREDIENTS
RTECS #:9999999ZZ
Fraction by Wt: 15-20%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYES- CAN CAUSE SEVERE IRRITATION.
SKIN- IRRITATION. INHALATION- CAN CAUSE NASAL AND RESPIRATORY
IRRITATION, CENTRAL NERVOUS SYSTEM DEPRESSION. INGESTION- CAN
CAUSE GASTROINTESTINAL IRRITATION.NO KNOWN CHRONIC EFFECTS.
Explanation of Carcinogenicity:THIS PRODUCT CONTAINS METHYLENE
CHLORIDE.
Effects of Overexposure:EYES- REDNESS, TEARING, BLURRED VISION. SKIN-
DIZZINESS,WEAKNESS, FATIGUE, NAUSEA, HEADACHES, POSSIBLE
UNCONSCIOUSNESS AND ENVEN ASPH YXIATION. INGESTION- CAN CAUSE
NAUSEA,VOMITING, DIARRHEA.
Medical Cond Aggravated by Exposure:ALLERGIC RESPIRATORY AND/OR SKIN
REACTIONS.
======================= First Aid Measures =======================
First Aid:EYES- FLUSH WITH WATER FOR 15 MIN. WHILE OCCASIONALLY HOLDING
EYELIDS OPEN. SKIN- WASH WITH SOAP AND WATER OR VARIOUS HAND
CLEANERS. WASH CLOTHING BEFORE RE-USE. INHALATION- REMOVE
INDIVIDUAL TO FRE SH AIR. IF BREATHING IS DIFFICULT, ADMINISTER
OXYGEN. GIVE CPR IF NEEDED. INGESTION- DO NOT INDUCE VOMITING
(ASPIRATION INTO LUNGS CAN CAUSE CHEMICAL PNEUMONITIS). GET
IMMEDIATE MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:0F,-18C
Lower Limits:1.0
Extinguishing Media:ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WATER MAY BE INEFFECTIVE. WATER MAY BE USED TO
COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD-UP. USE
SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL
ALONG THE GROUND AND IGNITED BY PILOT LIGHTS, ETC.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES, EVACUATE AREA.
VENTILATE AND AVOID BREATHING VAPORS. TURN OFF HEATING AND/OR AIR
CONDITIONING SOURCES. ABSORB LIQUID ON PAPER, VERMICULITE, FLOOR
ABSORBENT, OR OTHER MA TERIAL AND TRANSFER TO CLOSED CONTAINERS.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE IN AREAS ABOVE 120F, OR
IN DIRECT SUNLIGHT, OR NEAR HEAT OR OPEN FLAMES.
Other Precautions:NONE
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHERE VAPOR CONCENTRATION IS GREATER THAN 100
PPM, AN ORGANIC VAPOR TYPE RESPIRATOR IS ADVISED.
Ventilation:DO NOT USE IN CONFINED AREAS. PROVIDE SUFFICIENT MECHANICAL
(GENERAL) AND/OR LOCAL EXHAUST VENTILATION.
Other Protective Equipment:SOLVENT RESISTANT BOOTS, APRON, HEADGEAR
AND/OR FACESHIELD.
Work Hygienic Practices:WASH HANDS BEFORE EATING OR USING WASHROOM. AS
WITH ALL CHEMICALS, MINIMIZE PERSONAL CONTACT AND/OR BREATHING
VAPORS.
Supplemental Safety and Health
NONE
================== Physical/Chemical Properties ==================
HCC:V3
Boiling Pt:B.P. Text:104-331F
Vapor Density:>AIR
Evaporation Rate & Reference:SOLVENT < THAN ETHER
Solubility in Water:SLIGHT TO MODERATE
Appearance and Odor:TYPICAL SOLVENT PAINT.
Percent Volatiles by Volume:85-90
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, HEAT, ALKALIES, HOT SURFACES AND REACTIVE
METALS.
Stability Condition to Avoid:HEAT, SPARKS, AND OPEN FLAMES.
Hazardous Decomposition Products:MAY FORM TOXIC MATERIALS, NITROGEN
COMPOUNDS, ETC. CARBON DIOXIDE AND CARBON MONOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:MATERIAL COLLECTED ON ABSORBENT MATERIAL MAY BE
DEPOSITED IN A POSTED TOXIC SUBSTANCE LANDFILL IN ACCORDANCE WITH
LOCAL, STATE, AND FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:WB-B (GUIDE SHOE)
Preparer's Name:TERRY MEILER
CAGE:58436
CAGE:58436
============= Composition/Information on Ingredients =============
Ingred Name:IRON
CAS:7439-89-6
RTECS #:NO4565500
OSHA PEL:10MG/CUM(OXIDE FUME)
ACGIH TLV:5 MG/CUM(OXIDE FUME)
Ingred Name:COPPER (SARA III)
CAS:7440-50-8
RTECS #:GL5325000
OSHA PEL:0.1MG/M3 FUME/1 DUST
ACGIH TLV:0.2MG/M3 FUME; 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:COBALT (SARA III)
CAS:7440-48-4
RTECS #:GF8750000
OSHA PEL:0.1 MG/M3;AS CO
ACGIH TLV:0.05 MG/M3;DUST 9293
Ingred Name:TIN
CAS:7440-31-5
RTECS #:XP7320000
OSHA PEL:2 MG/M3
ACGIH TLV:2 MG/M3; 9192
Ingred Name:GRAPHITE, SYNTHETIC
CAS:7440-44-0
RTECS #:FF5250100
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:2 MG/M3 TDUST; 9293
Ingred Name:MANGANESE (SARA III)
CAS:7439-96-5
RTECS #:OO9275000
OSHA PEL:(C) 5 MG/M3 DUST
ACGIH TLV:5 MG/M3 DUST 9293
Ingred Name:ALUMINUM (SARA III)
CAS:7429-90-5
RTECS #:BD0330000
OSHA PEL:15MG/M3 DUST/5 FUME
ACGIH TLV:10MG/M3 DUST; 9192
Ingred Name:CHROMIUM (SARA III)
CAS:7440-47-3
RTECS #:GB4200000
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3; 9192
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:MOLYBDENUM
CAS:7439-98-7
RTECS #:QA4680000
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3; 9293
Ingred Name:NICKEL (SARA III)
CAS:7440-02-0
RTECS #:QR5950000
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3; 9192
Ingred Name:SILICON
CAS:7440-21-3
RTECS #:VW0400000
Other REC Limits:5MG/CUM(RESP.DUST)
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:LEAD (SARA III)
CAS:7439-92-1
RTECS #:OF7525000
OSHA PEL:0.05 MG/M3;1910.1025
ACGIH TLV:0.15 MG/M3;DUST 9192
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:ZINC (SARA III)
CAS:7440-66-6
RTECS #:ZG8600000
OSHA PEL:10 MG ZNO/M3
ACGIH TLV:10 MG ZNO/M3; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:OPERATIONS SUCH AS
ABRADING,MELTING,WELDING,CUTTING OR PROCESSING IN ANY OTHER FASHION
MAY PRODUCE POTENTIALLY HAZARDOUS DUST OR FUMES WHICH CAN BE
INHALED,SWALLOWED,OR COME IN CONTACT WITH THE SKIN O R EYES. DUST
OR FUME MAY CAUSE IRRITATION TO THE EYES,NOSE OR THROAT; -CONTINUES
IN SUPPLEMENTAL SAFETY & HEALTH DATA-
Explanation of Carcinogenicity:NICKEL IS A CARCINOGEN AND CERTAIN
COMPOUNDS OF CHROMIUM AND COBALT HAVE BEEN IDENTIFIED AS SUSPECT
HUMAN CARCINOGENS.
Effects of Overexposure:SEE HEALTH HAZARDS AND MEDICAL CONDITIONS
AGGRAVATED BY EXPOSURE.
Medical Cond Aggravated by Exposure:OVEREXPOSURE SYMPTOMS MAY BE
AGGRAVATED FOR SENSITIVE INDIVIDUALS WITH RESP.CONDITION (SUCH AS
EMPHYSEMA). PERSON WITH LT SKIN,SENSITIVE SKIN OR LG AMTS OF BODY
HAIR MAY EXPERIENCE SKIN DISORDERS.
======================= First Aid Measures =======================
First Aid:EYES:FLUSH WITH WATER.SEEK MEDICAL ATTENTION;SKIN:WASH WITH
SOAP & WATER;INHALATION:REMOVE TO FRESH AIR.IF NOT BREATHING GIVE
CPR.SEEK MEDICAL ATTENTION;INGESTION:SEEK MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING
FIRE.
Unusual Fire/Explosion Hazard:DUST HAZARDS EXIST UNDER FAVORING
CONDITIONS OF SMALL PARTICLE SIZE. DISPERSION IN AIR AND STRONG
IGNITION SOURCE MAY RESULT IN AN EXPLOSION.
================== Accidental Release Measures ==================
Spill Release Procedures:PICK UP AND PLACE IN APPROPRIATE DISPOSAL
CONTAINER.
======================Handling and Storage ======================
Handling and Storage Precautions:NO SPECIAL PROCEDURE REQUIRED.
Other Precautions:REMOVE TRACES OF MATERIAL DUST IF
SOLDERING,WELDING,BRAZING,CUTTING OR OTHER PROCESS INVOLVING
IGNITION SOURCES TO PREVENT A FIRE HAZARD.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IN CASE OF DUST CONDITIONS,USE NIOSH APPROVED
RESPIRATOR FOR METAL DUST.
Ventilation:LOCAL EXHAUST
Work Hygienic Practices:STANDARD PRACTICE
Supplemental Safety and Health
HEALTH HAZARDS,CONT'D:LEAVES A METALLIC TASTE IN THE MOUTH;RESULTS IN
METAL FUME FEVER (FLU-LIKE SYMPTOMS).
================== Physical/Chemical Properties ==================
HCC:N1
Melt/Freeze Pt:M.P/F.P Text:1100-2500F
Spec Gravity:7.8
Solubility in Water:NOT SOLUBLE
Appearance and Odor:SOLID METAL OBJECT. ANTI-RUST COATING HAS ODOR OF
KEROSENE.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS,BASES OR STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products:METAL FUMES IF HEATED. ANTI-RUST
COATING IS COMBUSTIBLE AND WILL PRODUCE OXIDES OF CARBON.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IAW FEDERAL,STATE AND LOCAL
REGULATIONS.
| 1 | gloves_mandatory |
=======================================================
Product ID: 62-4437-4933-8 00-21200-85846-8, SUPER 77 (SUPDAT)
Cage: 1BY21
Proprietary Ind: Y
=======================================================
Contractor Summary
=======================================================
Cage: 76381
Cage: 1BY21
=======================================================
Ingredients
=======================================================
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYES: MOD IRRIT: SIGNS/SYMPS CAN INCL REDNESS, SWELL,
PAIN, TEARING & HAZY VISION. SKIN: MILD IRRIT (AFTER PRLNGD/RPTD
CNONTACT): SIGNS/SYMPS CAN INCL REDNESS, SWELL & ITCHING. MAY BE ABSORBED
THRU SK IN IN HARMFUL AMTS. INHAL: INTENTIONAL CONC & INHAL MAY BE
HARMFUL OR FATAL. CNS DEPRESS: SIGNS/SYMPS (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ: CAN INCL HDCH, DIZZ, DROW,
INCOORD, SLOWED RXN TIME, SLURRED SPEECH, GIDD & UNCON. IRRIT (UPPER
RESP): SIGNS/SYMPS CAN INCL SORENESS OF NOSE OF NOSE & THROAT, COUGH
& SNEEZING. INGEST: NOT L IKELY ROUTE OF EXPOS TO THIS PROD. WHILE
FOLLOWING EFTS ARE ASSOC W/ONE OR MORE OF INDIVIDUAL INGREDIENTS IN (SUPDAT)
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYES: IMMEDIATELY FLUSH EYES W/LARGE AMTS OF WATER FOR AT LST 15
MIN. GET IMMEDIATE MEDICAL ATTENTION. SKIN: FLUSH SKIN W/LARGE AMTS OF WATER.
IF IRRITATION PERSISTS, GET MEDICAL ATTENTION. INHAL: REM OVE PERSON TO FRESH
AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS
DIFFICULT, GET IMMEDIATE MEDICAL ATTENTION. INGEST: DO NOT INDUCE VOMITING.
DRINK TWO GLASSES OF WATER. CALL MD.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: REFER TO OTHER SECTIONS OF MSDS FOR INFO REGARDING
PHYSICAL & HEALTH HAZS, RESP PROT, VENT & PERSONAL PROT EQUIP. IN USA
CALL 612-733-1110 OR 612-733-6100 FOR 24-HR SPILL ASSISTANCE. VENT AREA.
EXTING ALL IGNIT SOURCES. COVER W/ABSORB MATL.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: INCINERATE IN PERMITTED HAZ WASTE INCINERATOR IN
PRESENCE OF COMBUST MATL. FACILITY MUST BE CAPABLE OF HNDLG AEROSOL CANS.
DISPOSE OF EMPTY CANS IN SANITARY LANDFILL. DISPOSE OF WASTE PROD IN FACILITY
PERMITTED TO ACCEPT CHEM WASTE. SINCE
Handling And Storage Precautions: STORE AT TEMPERATURES BELOW 120F (49C). KEEP
OUT OF THE REACH OF CHILDREN.
Other Precautions: AEROSOL CONTAINER CONTAINS FLAMMABLE GAS UNDER PRESSURE.
KEEP AWAY FROM HEAT, SPARKS, OPEN FLAME & OTHER SOURCES OF IGNITION.
EXTREMELY FLAMMABLE LIQUID & VAPOR. DO NOT PIERCE OR BURN CONTAINER, EVEN
AFTER USE. AVOID STATIC DISCHARGE.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point Text: -42F,-41C
Upper Limits: FLAM GAS
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures: USE NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N)
INCL BUNKER COAT & PANTS, BANDS AROUND ARMS, WAIST & LEGS, FACEMASK
& PROT COVERING FOR EXPOSED AREAS OF HEAD.
Unusual Fire/Explosion Hazard: CLSD CNTNRS EXPOSED TO HEAT FROM FIRE MAY BUILD
PRESS & EXPLODE. VAPS MAY TRAVEL LONG DISTANCES ALONG THE GROUND OR FLOOR
TO IGNITION SOURCE & FLASH BACK.
=======================================================
Control Measures
=======================================================
Respiratory Protection: AVOID BREATHING VAPORS, MISTS OR SPRAY. SELECT ONE OF
FOLLOWING NIOSH APPROVED RESPIRATORS BASED ON AIRBORNE CONCENTRATION OF
CONTAMINANTS AND IN ACCORDANCE WITH OSHA REGSULATIONS: HALF-MASK ORGANIC V
APOR RESPIRATOR.
Ventilation: USE IN WELL-VENTILATED AREA. PROVIDE SUFFICIENT VENTILATION TO
MAINTAIN EMISSIONS BELOW RECOMMENDED EXPOSURE
Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N).
Work Hygienic Practices: AVOID EYE CONTACT W/VAPOR, SPRAY OR MIST. AVOID SKIN
CONTACT. DO NOT INGEST.
Supplemental Safety and Health: USERS OF "L" VERSION SHOULD CONSULT "LR"
VERSION FOR ADDNL INFO (FP N). MFR'S TRADE NAME/PART NO: SPRAY ADHESIVE. BP:
COMPRESSED GAS. VP: COMPRESSED GAS. EFTS OF OVEREXP: THIS PROD & ARE REQD
TO BE IN CLUDED ON MSDS BY OSHA STDS, THEY ARE NOT EXPECTED EFTS DURING
FORESEEABLE USE OF PROD: INHAL: PERIPHERAL
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: SUPDAT
Vapor Pres: SUPDAT
Vapor Density: 2.97
Spec Gravity: 0.697 (H*2O=1)
Evaporation Rate & Reference: 1.90 ETHER=1
Solubility in Water: NIL
Appearance and Odor: LIQUID IN AEROSOL, LIGHT CREAM COLORED, SWEET/FRUITY ODOR.
Percent Volatiles by Volume: 75 WT
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: HEAT.
Materials To Avoid: NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products: CARBON MONOXIDE AND CARBON DIOXIDE, TOXIC
VAPORS, GASES OR PARTICULATES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: 62-4437-4933-8 00-21200-85846-8, SUPER 77 (SUPDAT)
Cage: 1BY21
Company Name: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV
Street: 3M CTR
Zipcode: 55144-1000
Label Required IND: Y
Date Of Label Review: 03/28/1997
Status Code: C
Label Date: 03/28/1997
Origination Code: G
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: Slight
Hazard And Precautions: FLAMMABLE. DECOMPOSITION VAPORS MAY BE TOXIC. ACUTE:
EYES: REDNESS, SWELLING, PAIN, TEARING AND HAZY VISION. SKIN: REDNESS,
SWELLING AND ITCHING, MAY BE ABSORBED THROUGH THE SKIN IN HARMFUL AMOUNTS. I
NHALATION: CENTRAL NERVOUS SYSTEM DEPRESSION; HEADACHE, DIZZINESS,
DROWSINESS, INCOORDINATION, SLOWED RACTION TIME, SLURRED SPEECH, GIDDINESS
AND UNCONSCIOUSNESS. UPPER RESPIRATORY IRRITATION; SORENES S OF THE NOSE AND
THROAT, COUGHING AND SNEEZING. INTENTIONAL CONCENTRATION AND INHALATION MAY
BE HARMFUL OR FATAL. CHRONIC: NONE LISTED BY MANUFACTURER.
=======================================================
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:RED TOP HYDRATED MASONS LIME
CAGE:GO213
CAGE:0GRK9
CAGE:GO213
============= Composition/Information on Ingredients =============
Ingred Name:HYDRATED DOLOMITIC LIME *92-4*
CAS:58398-71-3
Fraction by Wt: 100%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: IRRITATION & CORROSION DAMAGE.
SKIN: IRRITATION & BURNS. INHALATION: UPPER RESPIRATORY TRACT
IRRITATION, & MUCOUS MEMBRANE DAMAGE. INGESTION: DIGESTIVE TRACT
CORROSION.
Explanation of Carcinogenicity:NONE
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/WATER FOR 15 MINS, INCLUDING UNDER LIDS. SKIN:
WASH W/PLENTY OF WATER. INHALATION: REMOVE TO FRESH AIR. INGESTION:
DILUTE BY GIVING 2 GLASSES OF MILK OR WATER TO DRINK, FOLLOWED BY
FRUIT JUICES OR DILUTED VINEGAR TO NEUTRALIZE THE ALKALI. OBTAIN
MEDIAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:NOT COMBUSTIBLE
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS NIOSH
APPROVED.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PERSONAL PROTECTION. KEEP SPILLED
MATERIAL AWAY FROM ACIDS. CAREFULLY PICK UP SOLID W/A MINIMUM OF
DUSTING & COLLECT IN METAL CONTAINERS W/COVERS FOR DISPOSAL. TRACE
AMOUNTS OF RESIDUE IN SPILL A REA CAN BE FLUSHED TO DRAIN USING
PLENTY WATER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE MATERIAL IN SEALED CONTAINERS IN
DRY PLACE, AWAY FROM ACIDS. PROTECT CONTAINERS AGAINST PHYSICAL
DAMAGE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE APPROVED DUST RESPIRATOR WHEN DUSTY
CONDITION EXISTS
Ventilation:GENERAL & LOCAL EXHAUST TO MEET TLV REQUIREMENTS FOR LIME
DUST. MECHANICAL EXHAUST: SUFFICIENT IN ABSENCE OF DUST/MIST.
Other Protective Equipment:DRY RUBBER BODY-COVERING PROTECTIVE
CLOTHING, EYE WASH STATION & SAFETY SHOWER
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:2850C
Spec Gravity:2.2-2.6
pH:11.7
Solubility in Water:0.1 G/100G
Appearance and Odor:WHITE POWDER W/LOW ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
BORIC OXIDE, ACIDS, FLUORINE, ORGANIC MATERIALS
==================== Disposal Considerations ====================
Waste Disposal Methods:ADD TO WATER, DILUTE & FLUSH TO SEWER (LARGE
AMOUNTS MAY REQUIRE NEUTRALIZATION BY ACID) IN ACCORDANCE
W/FEDERAL, STATE, & LOCAL REGULATIONS. ALTERNATELY, WASTE LIME CAN
BE USED FOR NEUTRALIZING PLANT ACID WASTE.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:685 INTERIOR-EXTERIOR CLEAR STAIN
Preparer's Name:NORMA HABEE
CAGE:6F266
CAGE:6F266
============= Composition/Information on Ingredients =============
Ingred Name:LIGROINE; (MINERAL SPIRITS)
CAS:8032-32-4
RTECS #:OI6180000
Fraction by Wt: 71.40%
OSHA PEL:300 PPM
ACGIH TLV:300 PPM
Ingred Name:VOLATILE ORGANIC COMPOUND:611 GRAMS/LITER (LESS WATER)
RTECS #:9999999VO
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN:MATERIAL MAY CAUSE IRRITATION,
SENSITIZATION, OR DEFATTING UPON PROLONGED OR REPEATED CONTACT.
INHALATION:EXCESSIVE EXPOSURE TO VAPORS OR SPRAY MISTS CAN RESULT
IN HEADACHE, DIZZINESS, NAUSEA, AN D LOSS OF CONSCIOUSNESS. SOME
REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL
OVEREXPOSURE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZS:TO SOLVENTS WITH PERMANENT BRAIN AND
NERVOUS SYSTEM DAMAGE. EYES:MATERIAL MAY BE AN IRRITANT.
Medical Cond Aggravated by Exposure:NONE, WHEN USED IN ACCORDANCE WITH
SAFE HANDLING INSTRUCTIONS (SEE HANDLING AND STORAGE PREC DATA AND
CONTROL MEASURES).
======================= First Aid Measures =======================
First Aid:SKIN:PROMPTLY WASH W/SOAP & WATER. REMOVE & WASH ANY CONTAM
CLTHG BEFORE REUSE. EYES:FLUSH W/LG QTYS OF WATER FOR @ LST 15 MIN
& SEEK MED ATTN. INGEST:DO NOT INDUCE VOMIT. KEEP PERSON WARM,
QUIET & GE T MED ATTN. ASPIR OF MATL INTO LUNGS CAN CAUSE CHEM
PNEUM WHICH CAN BE FATAL. INHAL:REMOVE TO FRESH AIR IMMED. IF RESP
SYMPS DEVELOP, SEEK MED ATTN AT ONCE.
===================== Fire Fighting Measures =====================
Flash Point Method:TOC
Flash Point:>107F,>42C
Lower Limits:0.7%
Upper Limits:6.0%
Extinguishing Media:FOAM, DRY CHEM, WATER FOG, CO*2. USE THESE/ANY
CLASS B EXTING AGENT. WATER MAY BE UNSUITABLE EXTING MEDIUM, BUT
(SUPDAT)
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . EVACUATE AREA OF UNPROTECTED PERSONNEL.
Unusual Fire/Explosion Hazard:VAPORS MAY FORM AN EXPLOSIVE MIXTURE IN
AIR AND MAY BE IGNITED BY SPARKS, PILOT LIGHTS, ETC. CLOSED
CONTAINERS MAY RUPTURE WHEN EXPOSED TO EXTREME HEAT.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT. VENT AREA. ABSORB
SPILL W/ABSORB MATL SUCH AS SAWDUST, VERMICULITE/SAND & PLACE MATL
INTO CLSD CNTNR. IF LG SPILL, DIKE AREA TO PVNT MATL FROM ENTERING
WATER SYS/SEWERS. W EAR PROT EQUIP DURING CLEANUP.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOD PRLNGD/RPTD INHAL OF HEATED
VAPS/SPRAY MISTS. KEEP AWAY FROM HEAT/OPEN FLAME. MATL MAY CAUSE
SENSIT. DO NOT GET IN EYES, ON SKIN/CLTHG.
Other Precautions:DO NOT ALLOW CONTAMINATED CLOTHING TO CONTACT SKIN.
DO NOT WELD ON FULL OR EMPTY CONTAINERS. KEEP CONTAINERS CLOSED,
WHEN NOT IN USE, AND PROPERLY LABELED. KEEP OUT OF THE REACH OF
CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED CANISTER-TYPE RESPIRATOR
MUST BE WORN TO PREVENT INHALATION OF VAPORS OR SPRAY MISTS WHEN
TLV OR PEL IS EXCEEDED.
Ventilation:GEN VENT IS REQ DURING NORMAL USE. LOC VENT MAY BE REQ
DURING CERTAIN OPERATIONS TO KEEP EXPOS LEVEL BELOW LIMS IN INGS.
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER . WEAR PROTECTIVE CLOTHING TO PREVENT SKIN CONTACT.
Work Hygienic Practices:WASH HANDS BEFORE EATING OR SMOKING.
Supplemental Safety and Health
EXTING MEDIA:HELPFUL IN KEEPING ADJACENT CONTAINERS COOL. WASTE DISP
METH:WITH LOCAL, STATE AND FEDERAL AGENCIES. GROUND HANDLING
EQUIPMENT TO PREVENT SPARKS. FOR FURTHER INFORMATION: CONTACT YOUR
STA TE OR LOCAL WASTE AGENCY OR THE UNITED STATES ENVIRONMENTAL
PROT AGENCY'S RCRA HOTLINE (1-800-424-9346/1-202-382-3000).
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>307F,>153C
Vapor Pres:2.6 @ 20C
Vapor Density:HVR/AIR
Spec Gravity:0.86
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:NIL
Appearance and Odor:CLEAR LIQUID, MILD ODOR.
Percent Volatiles by Volume:76.55
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDANTS, ACIDS, BASES AND EPOXY HARDENERS
UNDER UNCONTROLLED CONDITIONS.
Stability Condition to Avoid:HEAT, SPARKS AND OPEN FLAMES. IF PRODUCT
CONTAINS ALUMINUM, MOISTURE IN CLOSED CONTAINERS WILL GENERATE
HYDROGEN GAS.
Hazardous Decomposition Products:INCOMPLETE COMBUSTION CAN YIELD CARBON
MONOXIDE AND TOXIC VAPORS.
==================== Disposal Considerations ====================
Waste Disposal Methods:IF DISCARDED, MATL & CNTNRS SHOULD BE TREATED AS
HAZ WASTES BASED ON CHARACT OF IGNITABILITY AS DEFINED UNDER FED
RCRA REGS (40 CFR 261). DISP OF MATL/ITS CNTNRS REQS COMPLIANCE
W/APPLIC LBLING, PACKA GING & RECORDKEEPING STDS. DISP IN ACCORD
(SUPDAT)
| 1 | gloves_mandatory |
=======================================================
Product ID: CPD 9107 PART A
Kit Part: Y
Cage: GO735
Box: 58
Proprietary Ind: Y
=======================================================
Contractor Summary
=======================================================
Cage: CMPPL
Box: UNKNOW
Cage: GO735
Box: 58
=======================================================
Ingredients
=======================================================
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: WILL MODERATELY IRRITATE SKIN AND EYES. ISOCYANATE
VAPOR CAN IRRITATE THE RESPIRATORY TRACT CAUSING RUNNY NOSE, SORE THROAT,
COUGHING AND REDUCED LUNG FUNCTION. CHRONIC: MAY CAUSE LUNG SENSITIZ ATION.
REPEATED VAPOR OVEREXPOSURE OR ASINGLE LARGE DOSE MAY CAUSE CHEMICAL ASTHMA
OR OTHER ALLERGIC (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ: RESPONSE, WHICH WILL CAUSE A
LATER REACTION TO AN ISOCYANATE AT LEVELS BELOW THE TLV. MAY CAUSE SKIN
SENSITIZATION WITH ACCOMPANYING RASH.
Medical Cond Aggravated By Exposure: ALLERGY, ECZEMA OR SKIN CONDITIONS.
First Aid: SKIN: FLUSH W/LARGE AMTS OF WATER FOR AT LEAST 15 MIN. CONTACT MD
IMMED. SKIN: WASH W/SOAP & WATER. WASH CONTAM CLOTHES & DESTROY
CONTAM SHOES. SEEK MED ATTN IF THERE IS A SEV EXPOS. INHAL: NOT LIKELY
EXCEPT UNDER CONDITIONS OF SPRAY &/OR HEAT. REMOVE TO FRESH AIR. CONTACT
MD IMMED. INGEST: DILUTE BY GIVING WATER OR MILK TO DRINK IF VICTIM IS
CONSCIOUS. CONTACT MD OR REGIONAL POIS CTL CTR IMMED.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: ONLY PROPERLY PROTECTED PERSONNEL SHOULD REMAIN IN
AREA AND TRANSFER MATERIALS. USE ABSORBENT MATERIAL OR SCRAPE UP DRIED
MATERIAL AND PLACE INTO CONTAINERS. COVER LOOSELY FOR 24 HOURS BEFORE
SEALING.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE OF ACCORDING TO FEDERAL, STATE AND LOCAL
STANDARDS. DO NOT REUSE EMPTY CONTAINERS.
Handling And Storage Precautions: STORE AWAY FROM WATER, STRONG BASES,
ALCOHOLS. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. KEEP CONTAINERS
FROM EXCESSIVE HEAT AND FREEZING.
Other Precautions: PROVIDE VENTILATION IN STORAGE AREA. KEEP OUT OF REACH OF
CHILDREN. DO NOT STORE AT TEMPERATURES ABOVE 85F.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: CC
Flash Point Text: >395F,>202C
Extinguishing Media: FOAM, ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER
FOG.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT
(FP N). SPRAY CONTAINERS EXPOSED TO HEAT WITH WATER TO KEEP COOL AND TO
MINIMIZE POSSIBILITY OF RUPTURE.
Unusual Fire/Explosion Hazard: CONTAINERS MAY RUPTURE IF EXPOSED TO EXTREME
HEAT OR MOISTURE CONTAMINATION.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NORMALLY NOT NEEDED IN OPEN, WELL-VENTILATED AREAS. IN
CONFINED, UN-VENTILATED AREAS USE NIOSH APPRVD ORGANIC VAPOR RESPIRATOR IF
TLV IS NOT EXCEEDED. FOR EXPOS IN EXCESS OF THE TLV, NIOSH APPRVD AIR
SUPPLIED RESPIRATOR WOULD BE REQUIRED.
Ventilation: PROVIDE SUFFICIENT MECH VENT (LOC/GEN EXHST) TO MAINTAIN EXPOS
BELOW TLV. VAPS ARE HVR/AIR & WILL COLLECT IN LOW(SUPDAT)
Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N).
PROVIDE IMPERVIOUS APRON IF BODY CONTACT WITH PRODUCT MAY OCCUR.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: USERS OF "L" VERSION SHOULD CONSULT "LR"
VERSION FOR ADDNL INFO (FP N). CNDTNS TO AVOID: & RSLTG IN PRESS BUILDUP.
VENT: AREAS. MATL SHOULD BE CONFINED AS FAR AS POSS W/IN SEALED OR COVERED
EQUIP IN W HICH CASE NORM ROOM VENT SHOULD BE ADEQ. SPEC (LOC) VENT WILL BE
NEEDED IN AREAS WHERE VAPS ARE EXPECTED TO BE VENTED.
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: DECOMPOSES
Vapor Pres: 0.001 @25C
Spec Gravity: 1.03 (H*2O=1)
Solubility in Water: NOT SOLUBLE
Appearance and Odor: CLEAR LIQUID.
Percent Volatiles by Volume: NEGLIG
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: MOISTURE & HIGH HEAT. HAZ CNDTNS MAY DEVELOP UPON
LONG TERM CNTCT W/MOISTURE IN CLSD CNTNR DUE TO CO*2 EVOLUTION(SUPDAT)
Materials To Avoid: WATER, AMINES, STRONG BASES, ALCOHOLS, METAL COMPOUNDS AND
SURFACE ACTIVE MATERIALS.
Hazardous Decomposition Products: BY HIGH HEAT AND FIRE, CO*X, NO*X AND TRACES
OF HCN.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
Other Information: VOLATILE ORGANIC COMPOUND: 0 G/L.
=======================================================
HAZCOM Label
=======================================================
Product ID: CPD 9107 PART A
Cage: GO735
Assigned IND: Y
Company Name: COMPOSITE POLYMER DESIGN
Street: 949 S CONCORD
PO Box: 58
Zipcode: 55075
Label Required IND: Y
Date Of Label Review: 04/03/1998
Status Code: C
Label Date: 04/03/1998
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: ACUTE: WILL MODERATELY IRRITATE SKIN AND EYES.
ISOCYANATE VAPOR CAN IRRITATE THE RESPIRATORY TRACT CAUSING RUNNY NOSE, SORE
THROAT, COUGHING AND REDUCED LUNG FUNCTION. CHRONIC: MAY CAUSE LUNG SENSITIZ
ATION. REPEATED VAPOR OVEREXPOSURE OR ASINGLE LARGE DOSE MAY CAUSE CHEMICAL
ASTHMA OR OTHER ALLERGIC RESPONSE WHICH WILL CAUSE A LATER REACTION TO AN
ISOCYANATE AT LEVELS BELOW THE TLV. MAY CAUSE SKIN SENSITIZATION WITH
ACCOMPANYING RASH.
=======================================================
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:DESK TOP CLEANER
CAGE:0BBAI
CAGE:0BBAI
============= Composition/Information on Ingredients =============
Ingred Name:NO HAZARDOUS INGREDIENTS LISTED
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
Effects of Overexposure:VAPORS MAY BE IRRITATING TO EYES & RESPIRATORY
PASSAGES. TLV= 100 PPM.
======================= First Aid Measures =======================
First Aid:EYES:FLUSH WITH WATER AT LEAST 15 MINUTES. GET MEDICAL
ATTENTION. SKIN:FLUSH WITH WATER. REMOVE CONTAMINATED CLOTHING.
INHALATION:REMOVE FROM EXPOSURE TO FRESH AIR. GET MEDICAL
ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:86 F/30 C
Extinguishing Media:ALCOHOL FOAM, CO2, DRY CHEMICAL
Fire Fighting Procedures:SELF CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING SHOULD BE WORN IN FIGHTING FIRES INVOLVING
CHEMICALS
Unusual Fire/Explosion Hazard:TREAT AS FLAMMABLE LIQUID
================== Accidental Release Measures ==================
Spill Release Procedures:SMALL SPILLS MAY BE COLLECTED WITH ABSORBENT
MATERIAL.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS & OPEN
FLAME
Other Precautions:DO NOT REUSE "EMPTY" CONTAINERS WITHOUT COMMERCIAL
CLEANING & RECONDITIONING
============= Exposure Controls/Personal Protection =============
Respiratory Protection:A NIOSH APPROVED RESPIRATOR FOR ORGANIC VAPOR IF
TLV IS EXCEEDED
Ventilation:LOCAL EXHAUST: RECOMMENDED & MECHANICAL(GENERAL):
RECOMMENDED.
Other Protective Equipment:EYE FOUNTAIN IN WORK AREA
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:F3
Boiling Pt:B.P. Text:253F,123C
Vapor Pres:3.2
Vapor Density:2.6
Spec Gravity:0.9124
Evaporation Rate & Reference:235.7 (ETHER=1)
Solubility in Water:APPRECIABLE
Appearance and Odor:CLEAR, WATER WHITE; ESTER ODOR
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS
Stability Condition to Avoid:ISOLATE FROM HEAT, SPARKS & OPEN FLAMES
Hazardous Decomposition Products:CARBON MONOXIDE FROM BURNING
==================== Disposal Considerations ====================
Waste Disposal Methods:LIQUID INCINERATION OR IF ABSORBED, IN A POSTED
TOXIC SUBSTANCE LANDFILL
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:146 6788,PT A,KODAK MEDICAL X-RAY LIQUID FIXER,MX 1764-3
Kit Part:Y
CAGE:19139
CAGE:19139
============= Composition/Information on Ingredients =============
Ingred Name:AMMONIUM THIOSULFATE
CAS:7783-18-8
RTECS #:XN6465000
= Wt:45.
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:35.
Maxumum % Wt:40.
Ingred Name:SODIUM THIOSULFATE
CAS:7772-98-7
RTECS #:XN6476000
Minumum % Wt:5.
Maxumum % Wt:10.
Ingred Name:AMMONIUM SULFITE
CAS:10196-04-0
= Wt:3.
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:SODIUM ACETATE
CAS:127-09-3
RTECS #:AJ4300010
Minumum % Wt:1.
Maxumum % Wt:5.
Ingred Name:ACETIC ACID
CAS:64-19-7
RTECS #:AF1225000
Minumum % Wt:1.
Maxumum % Wt:5.
OSHA PEL:25 MG/M3;10 PPM
ACGIH TLV:25 MG/M3;10 PPM
ACGIH STEL:37 MG/M3;15 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:SODIUM BISULFITE
CAS:7631-90-5
RTECS #:VZ2000000
Minumum % Wt:1.
Maxumum % Wt:5.
ACGIH TLV:5 MG/M3
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EFFECTS OF EXPOSURE: INHALATION:
EXPECTED LOW HAZARD FOR USUAL INDUSTRIAL OR COMMERCIAL HANDLING BY
TRAINED PERSONNEL. IN CONTACT WITH STRONG ACIDS OR IF HEATED,
SULFITES LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE GAS IS
IRRITATING TO RESPIRATORY TRACT. SOME ASTHMATICS OR HYPERSENSITIVE
INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING. EYES: MAY CAUSE
TRANSIENT IRRITATION. HOWEVER, IMMEDIATE FLUSHI NG OF THE EYES WITH
WATER WILL MINIMIZE ANY IRRITATIVE EFFECT. SKIN: MATERIAL HAS LOW
POTENTIAL TO CAUSE ALLERGIC SKIN REACTIONS; HOWEVER, CASES OF HUMAN
SKIN SENSITIZATION HAVE BEEN REPORTED. INGESTI ON: MAY BE HARMFUL
IF SWALLOWED.
Effects of Overexposure:EFFECTS OF EXPOSURE: INHALATION: EXPECTED LOW
HAZARD FOR USUAL INDUSTRIAL OR COMMERCIAL HANDLING BY TRAINED
PERSONNEL. IN CONTACT WITH STRONG ACIDS OR IF HEATED, SULFITES
LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE GAS IS IRRITATING TO
RESPIRATORY TRACT. SOME ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS
MAY EXPERIENCE DIFFICULT BREATHING. EYES: MAY CAUSE TRANSIENT
IRRITATION. HOWEVER, IMMEDIATE FLUSHI NG OF THE EYES WITH WATER
WILL MINIMIZE ANY IRRITATIVE EFFECT. SKIN: MATERIAL HAS LOW
POTENTIAL TO CAUSE ALLERGIC SKIN REACTIONS; HOWEVER, CASES OF HUMAN
SKIN SENSITIZATION HAVE BEEN REPORTED. INGESTI ON: MAY BE HARMFUL
IF SWALLOWED.
Medical Cond Aggravated by Exposure:SOME ASTHMATICS OR
SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE WHEEZING, CHEST
TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS, WEAKNESS AND DIARRHEA.
======================= First Aid Measures =======================
First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT
SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES:
MATERIAL THAT CONTACTS THE EYE SHOULD BE WASHED OUT IMMEDIATELY
WITH WATER. GET M EDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN: WASH
WITH SOAP AND WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
INGESTION: DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION.
NEVER GIVE ANYTHING BY MOUT H TO AN UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:FLOOD WITH WATER.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:SOLUTION CONTAINS A STRONG REDUCING
AGENT. DRIED PRODUCT RESIDUE CAN ACT AS A REDUCING AGENT.
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. COLLECT
IN A NONCOMBUSTIBLE CONTAINER FOR PROMPT DISPOSAL.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED TO
PREVENT LOSS OF WATER. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES. DO
NOT STORE OR SHIP TOGETHER WITH COMBUSTIBLE MATERIALS. STORE IN
ORIGINAL CONTAINER. WASH THOROUGHLY A FTER HANDLING. REMOVE AND
WASH CONTAMINATED CLOTHING PROMPTLY.
Other Precautions:KEEP FROM CONTACT WITH OXIDIZING MATLS, HIGHLY
OXYGENATED OR HALOGENATED SOLVENTS, ORGANIC COMPDS CONTAINING
REDUCIBLE FUNCTIONAL GROUPS, OR AQUEOUS AMMONIA. AVOID BREATHING
VAPOR AT CONCENTRATIONS GR EATER THAN EXPOSURE LIMITS. AVOID
CONTACT WITH EYES AND REPEATED/PROLONGED CONTACT WITH SKIN. USE AD
EQUATE VENTILATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED. A RESPIRATOR SHOULD BE
WORN IF HAZARDOUS DECOMPOSITION PRODUCTS ARE LIKELY TO BE OR HAVE
BEEN RELEASED. RESPIRATOR TYPE: ACID GAS. SEE STABILITY AND
REACTIVITY SECTION. IF RESPI RATORS ARE USED, A PROGRAM SHOULD BE
INSTITUTED TO ASSURE COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER.
Work Hygienic Practices:IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO
MINIMIZE EYE CONTACT.IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO
MINIMIZE SKIN CONTACT.
Supplemental Safety and Health
SUPPLEMENTARY LOCAL EXHAUST VENTILATION, CLOSED SYSTEMS, OR RESPIRATORY
PROTECTION MAY BE NEEDED IN SPECIAL CIRCUMSTANCES SUCH AS POORLY
VENTILATED SPACES, EVAPORATION FROM LARGE SURFACES, SPRAYING, H
EATING, ETC.
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:>100.C, 212.F
Vapor Pres:68F: 24MBAR (18 MM HG)
Spec Gravity:1.36
pH:5.4
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, LIGHT YELLOW LIQUID. ODOR: ACETIC ACID.
Percent Volatiles by Volume:40-45 WT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
COMBUSTIBLE MATERIAL, HALOGENATED MATERIALS, STRONG ACIDS, BASES,
SODIUM HYPOCHLORITE (BLEACH), STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:STABLE.
Hazardous Decomposition Products:AMMONIA, CHLORAMINE, SULFUR DIOXIDE.
CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF NITROGEN, OXIDES OF
SULFUR.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information===================
Toxicological Information:WARNING! MAY BE HARMFUL IF SWALLOWED. CAUSES
EYE IRRITATION. DRIED PRODUCT RESIDUE CAN ACT AS A REDUCING AGENT.
DRYING ON CLOTHING OR OTHER MATERIALS MAY CAUSE FIRE.
===================== Ecological Information =====================
Ecological:THE FOLLOWING PROPERTIES ARE ESTIMATED FROM THE COMPONENTS
OF THE PREPARATIONS. POTENTIAL TOXICITY- FISH LC50 MG/L: >100,
DAPHNID EC50 MG/L: >100, ALGAL IC50 MG/L: >100. ORGANICS READILY
DEGRADABLE(>70%): YES (7 DAYS). POTENTIAL BIOACCUMULATION: LOG
POW <1. COD (APPROXIMATE G/L): 360. BOD5 (APPROXIMATE G/L): 290.
POTENTIAL TOXICITY WASTE TREATMENT MICROORGANISMS EC50 (MG/L):
>100.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS.FLUSH TO SEWER WITH LARGE
AMOUNTS OF WATER. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED.
=================== MSDS Transport Information ===================
Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS
PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE:
(716) 722-2400 BETWEEN 8 AM AND 5 PM (EASTERN STANDARD TIME),
MONDAY THROUGH FRIDAY.
===================== Regulatory Information =====================
SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART
372: AMMONIUM THIOSULFATE, AMMONIUM SUL FITE, AS A SOURCE OF
AQUEOUS AMMONIA.
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: NONE. MATERIAL(S) KNOWN TO THE STATE
OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:MOTHERS MAG & ALUMINIUM POLISH
CAGE:MOTHE
CAGE:MOTHE
============= Composition/Information on Ingredients =============
Ingred Name:KEROSENE
CAS:8008-20-6
RTECS #:OA5500000
OSHA PEL:200 P/M A
Ingred Name:SODIUM HYDROXIDE
CAS:1310-73-2
RTECS #:WB4900000
OSHA PEL:2 MG/M3 B
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
======================= First Aid Measures =======================
First Aid:INGESTION: DO NOT INDUCE VOMITING CONTACT PHYSICIAN
IMMEDIATELY. EYE CONTACT: WASH EYES THROUGHLY FOR 15 MINITUES
CONTACT PHYSICIAN IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point Method:TOC
Flash Point:=90.C, 194.F
194 F
Extinguishing Media:FOAM, CO2 DRY CHEMICAL
Fire Fighting Procedures:TREAT AS SOLVENT FIRE.
================== Accidental Release Measures ==================
Spill Release Procedures:WASH DOWN WITH WATER THROUGHLY.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID PROLONGED SKIN CONTACT.
============= Exposure Controls/Personal Protection =============
Ventilation:MECHANICAL
Work Hygienic Practices:WASH HANDS THROUGHLY AFTER USE.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:=48.9C, 120.F
M.P/F.P Text:120F
Spec Gravity:0.833
Solubility in Water:DISPERSABLE
Appearance and Odor:WHITE PASTE WITH PINE SCENT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
==================== Disposal Considerations ====================
Waste Disposal Methods:TREAT AS PETROLEUM PRODUCT
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:MAGNESIUM CHLORIDE HEXAHYDRATE, M35212
CAGE:1B464
CAGE:1B464
============= Composition/Information on Ingredients =============
Ingred Name:MAGNESIUM CHLORIDE, HEXAHYDRATE
CAS:7791-18-6
RTECS #:OM2975000
Fraction by Wt: 100%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SUPDAT: GLUCONATE TO PRECIPITATE THE OXALATE SHOULD BE
DETERMINED BY ONLY QUALIFIED MEDICAL PERSONNEL.
RTECS #:9999999ZZ
Ingred Name:FIRE FIGHT PROC: HEAT TO IGNITE NEARBY COMBUSTIBLE
MATERIALS.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL, RAT): 8100 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE: MAY CAUSE MILD EYE
IRRITATION. SKIN: MAY CAUSE SKIN IRRITATION. INGESTION: CAUSES
GASTROINTESTINAL IRRITATION WITH NAUSEA, VOMITING AND DIARRHEA.
INHALATION: MAY CAUSE RESPIRATORY TRACT IR RITATION. INHALATION OF
FUMES MAY CAUSEMETAL FUME FEVER, WHICH IS CHARACTERIZED BY FLU-LIKE
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: SYMPTOMS WITH METALLIC TASTE, FEVER,
CHILLS, COUGH, WEAKNESS, CHEST PAIN, MUSCLE PAIN AND INCREASED
WHITE BLOOD CELL COUNT. CHRONIC: NO INFORMATION FOUND. TARGET
ORGANS: KIDNEYS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES: IMMED FLUSH W/PLENTY OF H*2O FOR AT LEAST 15 MIN,
OCCASIONALLY LIFTING UPPER & LOWER LIDS. GET MED AID. SKIN: IMMED
FLUSH SKIN W/PLENTY OF SOAP & H*2O FOR AT LEAST 15 MIN WHILE
REMOVING CONTAMD CLTHG & SHOES. GET MED AID IF IRRIT
DEVELOPS/PERSISTS. INGEST: IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4
CUPFULS OF MILK/WATER. GET MED AID. INHAL: GET MED AID IMMED.
REMOVE FROM EXPOS TO (SUPDAT)
===================== Fire Fighting Measures =====================
Extinguishing Media:USE EXTINGUISHING MEDIA MOST APPROPRIATE FOR THE
SURROUNDING FIRE.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . MATL
WILL NOT BURN. USE H*2O W/CAUTION & IN FLOODING AMTS. CNTCT
W/MOISTURE/H*2O MAY GENERATE SUFFICIENT (ING 3)
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP UP OR ABSORB MATERIAL, THEN PLACE INTO A
SUITABLE CLEAN, DRY, CLOSED CONTAINER FOR DISPOSAL. AVOID
GENERATING DUSTY CONDITIONS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED
AREA AWAY FROM INCOMPATIBLE SUBSTANCES. KEEP AWAY FROM WATER. USE
WITH ADEQUATE VENTILATION.
Other Precautions:MINIMIZE DUST GENERATION AND ACCUMULATION. AVOID
CONTACT WITH EYES, SKIN, AND CLOTHING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
29CFR 1910.134. ALWAYS USE A NIOSH-APPROVED RESPIRATOR WHEN
NECESSARY.
Ventilation:GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT TO CONTROL
AIRBORNE LEVELS.
Other Protective Equipment:ANSI APPRVD EMER EYE WASH & DELUGE SHOWER .
WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE.
Work Hygienic Practices:WASH HANDS BEFORE EATING.
Supplemental Safety and Health
PH: 7.0 (SOLUTION). SOL IN H*2O: SOLUBLE IN H*2O & ALCOHOL. MATLS TO
AVOID: CONSIDERABLE AMTS OF HEAT; INCOMPATIBLE W/STRONG OXIDIZERS.
FIRST AID PROC: FRESH AIR IMMED. IF NOT BRTHG GIVE ARTF RESP. IF
BRTHG IS DFCLT, GIVE OXYGEN. NOTES TO MD: TREAT SYMPTOMATICALLY &
SUPPORTIVELY. ANTIDOTE: THE USE OF CALCIUM (ING 2)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:2574F,1412C
Melt/Freeze Pt:M.P/F.P Text:244F,118C
Spec Gravity:1.569
pH:SUPDAT
Solubility in Water:SUPDAT
Appearance and Odor:WHITE TO GRAY WHITE SOLID; NONE ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
EXPLOSIVE WHEN COMBINED W/2-FURAN PERCARBOXYLIC ACID. MAGNESIUM
CHLORIDE DISSOLVES IN AQUEOUS SOLNS GIVING OFF (SUPDAT)
Stability Condition to Avoid:CONTACT WITH WATER, HEATING TO
DECOMPOSITION.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, CHLORINE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE, AND LOCAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:NITROGEN, MGI 16625
CAGE:08772
CAGE:08772
Contract Num:SP0450-99-M-JC23
CAGE:8K810
============= Composition/Information on Ingredients =============
Ingred Name:NITROGEN GAS
CAS:7727-37-9
RTECS #:QW9700000
= Wt:100.
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Health Hazards Acute and Chronic:TARGET EFFECTS: SIMPLE ASPHYXIANT.
INHALATION-SIMPLE ASPHYXIANT. IN SUDDEN ACUTE ASPHYXIA,
UNCONSCIOUSNESS MAY BE IMMEDIATE. SKIN-THE LIQUID MAY CAUSE
FROSTBITE. IN MORE SEVERE CASES THE SKIN MAY BECO ME HARD & WHITE &
DEVELOP BLISTERS. EYE-MAY CAUSE IRRITATION IF SPRAYED INTO EYES.
THE LIQUID MAY CAUSE FROSTBITE. INGESTION-IF LIQUID IS SWALLOWED,
FROSTBITE DAMAGE OF THE LIPS, MOUTH & MUCOUS MEMBRA NES MAY OCCUR.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION-RAPID RESPIRATION & PULSE, AIR,
HUNGER, DIZZINESS, REDUCED AWARENESS,TIGHTNESS IN THE HEAD,
TINGLING SENSATIONS, INCOORDINATION, FAULTY JUDGEMENT, EMOTIONAL
INSTABILITY, & RAPID FATIGUE. NA USEA, VOMITING, COLLAPSE,
UNCONSCIOUSNESS, CONVULSION, DEEP COMMA & DEATH ARE POSSIBLE.
SKIN-REDNESS, TINGLING, AND PAIN OR NUMBNESS. EYE-REDNESS, PAIN &
BLURRED VISION.
======================= First Aid Measures =======================
First Aid:INHALATION-REMOVE FROM EXPOSURE TO FRESH AIR, IMMEDIATELY.
PERFORM ARTIFICIAL RESPIRATION IF NEEDED. MAINTAIN AIRWAY, BLOOD
PRESSURE & RESPIRATION. KEEP WARM/AT REST. GET MEDICAL AID
IMMEDIATELY. SKIN -GET MEDICAL AID. IF FROSTBITE, FREEZING,
CRYOGENIC BURNS OCCUR. WARM AFFECTED AREA IN WARM WATER (107F).
GENTLY WRAP PARTS IN BLANKETS. ENCOURAGE EXERCISING AFFECTED PART
WHILE BEING WARMED. GET MED ICAL AID. EYE-WASH EYES IMMEDIATELY
WITH WATER, LIFTING EYE LIDS, UNTIL NO CHEMICAL REMAINS. GET
MEDICAL AID. INGESTION-INGESTION OF GAS IS UNLIKELY THAT EMERGENCY
TREATMENT IS REQUIRED. TREAT SYMPTOM ATICALLY/SUPPORTIVELY. GET
MEDICAL AID.
===================== Fire Fighting Measures =====================
Extinguishing Media:DRY CHEMICAL OR CARBON DIOXIDE.
Fire Fighting Procedures:MOVE CONTAINER FM FIRE IF WITHOUT RISK, APPLY
COOLING WATER TO SIDES OF CONTAINERS EXPOSED TO FLAMES UNTIL
WELLAFTER FIRE IS OUT. STAY AWAY FROM ENDS OF TANKS. WITHDRAW
IMMEDIATELY IF RISING SOUND FRO M VENTING SAFETY DEVICE OR
DISCOLORATION OF TANK DUE TO FIRE. MATLS IF SPILLED, MAY EVAPORATE
LEAVING FLAMMABLE RESIDUE.
Unusual Fire/Explosion Hazard:ISOLATE FOR 1/2 MILE IN ALL DIRECTIONS IF
TANK, FAIL CAR OR TANK TRUCK IS INVOLVED IN FIRE (1993 EMERGENCY
RESPONSE GUIDEBOOK, RSPA P 5800.6. GUIDE PAGE 12). NEGLIGIBLE FIRE
HAZARD WHEN EXPOSED TO HEA T OR FLAME. CONTAINER MAY EXPLODE IN
HEAT OF FIRE.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN ACCORDANCE WITH 29 CFR
1910.101. STORE AWAY FROM INCOMPATIBLE SUBSTANCES.
Other Precautions:STORE IN ACCORDANCE WITH 29 CFR 1910.101. STORE AWAY
FROM INCOMPATIBLE SUBSTANCES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:ANY SUPPLIED-AIR RESPIRATOR OPERATED IN
PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE. ANY SELF-CONTAINED
BREATHING APPARATUS. SPECIFIC RESPIRATOR SELECTED MUST BE BASED ON
CONTAMINATION LEVELS FOUN D IN WORK PLACE, BASED ON SPECIFIC
OPERATION , NOT EXCEED WORKING LIMITS OF RESPIRATOR & BE JOINTLY
APPROVED BY (NIOSH-MSHA).
Ventilation:PROVIDE LOCAL EXHAUST VENTILATION SYSTEM.
RECOMMENDED.
Other Protective Equipment:WHERE THERE IS ANY POSSIBILITY OF CONTACT
A FACESHIELD TO PREVENT CONTACT W/SUBSTANCE. CONTACT LENSES SHOULD
NOT BE WORN.
Work Hygienic Practices:EMERGENCY WASH FACILITIES; WHERE POSSIBILITY AN
EMPLOYEE'S EYES &/OR SKIN MAY BE EXPOSED TO LIQUID FORM OF
SUBSTANCE, THE EMPLOYER SHOULD PROVIDE EYE WASH FOUNTAIN & QUICK
DRENCH SHOWER WITHIN WORK AREA
Supplemental Safety and Health
IF CONTACT WITH LIQUID FORM IS POSSIBLE, EMPLOYEE MUST WEAR APPROPRIATE
PROTECTIVE CLOTHING & EQUIPMENT TO PREVENT SKIN FROM FREEZING.
================== Physical/Chemical Properties ==================
HCC:G3
Boiling Pt:=-196.1C, -321.F
Melt/Freeze Pt:=-210.C, -346.F
Vapor Pres:760 MMHG@-196C
Vapor Density:0.967
Spec Gravity:1.2506
Viscosity:0.01787 CP@27C
Solubility in Water:1.6%@2
Appearance and Odor:ODORLESS, TASTELESS, COLORLESS, INERT GAS.
Percent Volatiles by Volume:100%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
LITHIUM: MAY IGNITE IN THE GAS. MAGNESIUM: VIOLENT REACITON W/LIQUID ON
IGNITION. NEODYMIUM: VIGOROUS REACTION. OZONE: MIXTURES OF GASES
MAY BE EXPLOSIVE. TITANIUM: WILL BURN IN NITROGEN ATMOSPHERE.
Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES &
PRESSURES.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE TOXIC OXIDES OF NITROGEN.
Conditions to Avoid Polymerization:HAZARDOUS POLYMERIZATION HAS NOT
BEEN REPORTED TO OCCUR UNDER NORMAL TEMPERATURES & PRESSURES.
=================== Toxicological Information===================
Toxicological Information:NO OCCUPATIONAL EXPOSURE LIMITS ESTABLISHED
BY OSHA, ACGIH OR NIOSH.
==================== Disposal Considerations ====================
Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS
WHEN STORING OR DISPOSING OF THIS SUBSTANCE.
=================== MSDS Transport Information ===================
Transport Information:NONFLAMMABLE GAS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:TRICHLOROETHANE
Preparer's Name:HMIS TECHNICIAN
CAGE:97984
CAGE:97984
============= Composition/Information on Ingredients =============
Ingred Name:METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III)
CAS:71-55-6
RTECS #:KJ2975000
Fraction by Wt: 100%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:350 PPM/450 STEL
ACGIH TLV:350 PPM/450STEL;9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ozone Depleting Chemical:1
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT) = 10300 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY CAUSE EYE & SKIN
IRRITATION. MAY CAUSE RESPIRATORY TRACT IRRITATION. CENTRAL NERVOUS
SYSTEM DEPRESSANT. LOSS OF CONSCIOUSNESS AND EVEN DEATH CAN OCCUR
AT HIGH LEVELS OF EXPOSURE. CHRONIC: U NKNOWN
Explanation of Carcinogenicity:NOT LISTED AS A CARCINOGEN BY NTP, IARC
OR OSHA
Effects of Overexposure:INCOORDINATION AND IMPAIRED JUDGMENT MAY OCCUR
AT VAPOR EXPOSURES FROM 500-1000 PPM. DIZZINESS, DROWSINESS, AND
GENERAL ANESTETHIC EFFECTS MAY OCCUR IN RANGES OF 1000 PPM AND
HIGHER.
Medical Cond Aggravated by Exposure:INCREASED SENSITIVITY TO ADRENALINE
MAY BE CAUSED BY OVER EXPOSURE.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE CPR.
IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL A PHYSICIAN. EYE:
FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES. GET
MEDICAL AT TENTION. SKIN: REMOVE CONTAMINATED CLOTHING. WASH WITH
SOAP AND WATER PROMPTLY. INGESTION: DO NOT INDUCE VOMITING. GIVE
MILK OR USP MINERAL OIL. GET IMMEDIATE MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Autoignition Temp:Autoignition Temp Text:932F
Lower Limits:7
Upper Limits:16
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED
CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS.
================== Accidental Release Measures ==================
Spill Release Procedures:SMALL SPILL: WIPE UP WITH RAGS OR TOWELS.
LARGE SPILLS: WEAR NIOSH APPROVED RESPIRATOR. VENTILATE AREA. DIKE
TO RETAIN FLUID. PUMP UP FREE LIQUID. RESIDUE WILL EVAPORATE
QUICKLY. DO NOT FLUSH TO SEWER OR WATERWAY.
Neutralizing Agent:NONE
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED
LOCATION, AWAY FROM ANY AREA WHERE THE FIRE HAZARD MAY BE ACUTE.
KEEP CONTAINERS CLOSED WHEN NOT IN USE.
Other Precautions:DO NOT USE WITH ALUMINUM. READ AND FOLLOW DIRECTIONS
ON LABEL. DO NOT REUSE CONTAINERS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IN HIGH VAPOR AREA, USE NIOSH/MSHA APPROVED
RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE. USE SELF-CONTAINED
BREATHING APPARATUS IF VAPOR LEVELS EXCEED 1000 PPM.
Ventilation:LOCAL EXHAUST RECOMMENDED TO CONTROL VAPORS BELOW 50% OF
TLV.
Other Protective Equipment:APRON AND WORK CLOTHING TO MINIMIZE
EXPOSURE. EYE WASH STATION & SAFETY SHOWER RECOMMENDED.
Work Hygienic Practices:WASH THOROUGHLY AFTER USE AND BEFORE EATING,
SMOKING OR USING TOILET FACILITIES. DO NOT BREATH VAPORS OR MIST.
Supplemental Safety and Health
TARGET ORGANS ARE SKIN, CNS, CVS, AND EYES
================== Physical/Chemical Properties ==================
HCC:T4
Boiling Pt:B.P. Text:165F,74C
Melt/Freeze Pt:M.P/F.P Text:-22F,-30C
Vapor Pres:100 MM HG
Spec Gravity:1.34 (WATER=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID; MILD ODOR LIKE CHLOROFORM
Corrosion Rate:UNKNOWNU
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:WHEN INVOLVED IN FIRE,
1,1,1-TRICHLOROETHANE EMITS HIGHLY TOXIC AND IRRITATING HYDROGEN
CHLORIDE AND PHOSGENE FUMES.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF I/A/W FEDERAL, STATE & LOCAL
REGULATIONS
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===================== Product Identification =====================
Product ID:ODEX SUPER READYPAC
CAGE:53883
CAGE:56883
CAGE:53883
============= Composition/Information on Ingredients =============
Ingred Name:PARAFORMALDEHYDE (SARA III)
CAS:30525-89-4
RTECS #:RV0540000
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:DYE
Ingred Name:AROMATIC OILS
===================== Hazards Identification =====================
Effects of Overexposure:SKIN:CAUSES IRRIT; EYES:CAUSES SEV IRRITATION
ON CONTACT;INHAL:VAP MAY HAVE UNPLEASANT EFFECT.
======================= First Aid Measures =======================
First Aid:SKIN:WASH W.SOAP & H*2O EYES:FLUSH W. H*2O. INGESTED:GIVE 2
GLASSES H*2O; INDUCE VOMITING.CALL A PHYSICIAN. INHALE:REMOVE TO
FRESH AIR. GIVE CPR/OXYGEN IF NEED. KEEP WARM & QUIET. REMOVE
CONTAMINATED CLOTHING. IF UNCONS DO NOT TAKE ANYTHING BY MOUTH.
===================== Fire Fighting Measures =====================
Flash Point:168F/76C (TCC)
Extinguishing Media:WATER SPRAY, CO*2
Fire Fighting Procedures:WEAR SELF-CNTD BRTHG,APP H*20 SPRAY TO COOL
CONTR.
Unusual Fire/Explosion Hazard:ON HEATING,FORMALDEHYDE SOLUTIONS MAY
RELEASE METHANOL VAP & FORMALDEHYDE VAP.
================== Accidental Release Measures ==================
PROTECTION.SWEEP UP & COLLECT IN A CLOSED CONTAINER.KEEP SPILL IN
CONTAINER PENDING DISPOSAL INSTRUCTIONS.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED
AREA. PROTECT FROM PHYSICAL DAMAGE.AVOID ANY PHYSICAL CONTACT. KEEP
CONTAINERS TIGHTLY CLOSED
Other Precautions:DO NOT STORE NEAR HEAT/IGNITION SOURCES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED
Ventilation:NO SPECIAL REQUIREMENTS W ADEQUATE VENT.
Other Protective Equipment:NORMAL WORK CLOTHING COVERING ARMS & LEGS.
Supplemental Safety and Health
MSDS EFFECTIVE:3/4/85; SPEC REF:MIL-D-83790A,TYPE I, SIZE A.
================== Physical/Chemical Properties ==================
HCC:V4
Solubility in Water:COMPLETE
Appearance and Odor:FREE FLOWING POWDER;PERFUMED
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS & BASES,ACTIV METAL, OXIDANTS,ACYLATING AGENTS
Stability Condition to Avoid:HEAT, IGNITION SOURCES
Hazardous Decomposition Products:INCOMPLETELY BURNED CARBON PRODUCTS,
CO*2, CO.
==================== Disposal Considerations ====================
Waste Disposal Methods:KEEP IN COVERED DRUMS,PENDING DISPOSAL. HANDLE &
DISPOSE IN FULL COMPLIANCE WITH ALL APPLICABLE
INTERNATIONAL,FEDERAL,STATE, & LOCAL REGULATIONS.
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===================== Product Identification =====================
Product ID:COARSE STAUROLITE
Kit Part:Y
CAGE:0ERJ7
CAGE:0ERJ7
CAGE:18873
============= Composition/Information on Ingredients =============
Ingred Name:ING 5:SILICOSIS. SILICOSIS IS A CHRONIC FIBROTIC LUNG
DISEASE CHARACTERIZED BY FORMATION OF SILICA-CONTAINING (ING 7)
RTECS #:9999999ZZ
Ingred Name:ING 6:SCAR TISSUE IN LUNGS W/SYMPS OF COUGHING, DYSPNEA,
WHEEZING & NONSPECIFIC RESP ALIMENTS. GROSS ACUTE (ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7:OVEREXP TO QUARTZ BY INHAL MAY CAUSE FATALITY.
EPIDEMIOLOGICAL STUDIES SHOW THAT IN ADDITION TO SILICOSIS (ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8:THERE IS LTD EVID OF EXCESS LUNG CANCER IN OCCUP
INVOLVING EXPOS MAINLY TO RESPIRABLE QUARTZ, SUCH AS (ING 10)
RTECS #:9999999ZZ
Ingred Name:ING 9:STONE CUTTERS & GRANITE INDUSTRY WORKERS. STAUROLITE
PRODUCTS CONTAIN TRACES QTIES (2-3 PCI/G) (ING 11)
RTECS #:9999999ZZ
Ingred Name:ING 10:OF NATURALLY OCCURRING RADIOACTIVE URANIUM & THORIOM
(LESS THAN OR EQUAL TO NORMAL BACKGROUND LEVELS) & (ING 12)
RTECS #:9999999ZZ
Ingred Name:ING 11:(2-6 PCI/G) RADIUM.
RTECS #:9999999ZZ
Ingred Name:RESP PROT:PRESSURE AIR SUPPLIED RESPIRATOR IF THERE IS ANY
POTENTIAL FOR AN UNCONTROLLED RELEASE, EXPOSURE (ING 14)
RTECS #:9999999ZZ
Ingred Name:ING 13:LEVELS ARE NOT KNOWN, OR ANY OTHER CIRCUMSTANCES
WHERE AIR PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE PROT.
RTECS #:9999999ZZ
Ingred Name:VENT:IN CONFINED AREAS, AIRBORNE DUST LEVELS SHOULD BE
CONTROLLED BY PHYSICAL ENCLOSURE OF THE ABRASIVE (ING 16)
RTECS #:9999999ZZ
Ingred Name:ING 15:BLASTING OPERATION. THE ENCLOSURE SHOULD BE EXHAUST
VENTILATED I/A/W/29 CFR 1910.94 VENT (A) ABRASIVE BLASTING.
RTECS #:9999999ZZ
Ingred Name:ING 16: SHOULDERS TO PROVIDE PROTECTION FROM REBOUND
ABRASIVE PER 29 CFR 1910.94 (A) (5).
RTECS #:9999999ZZ
Ingred Name:VENT: CONFINED AREAS, AIRBORNE DUST LEVELS SHOULD BE
CONTROLLED BY PHYSICAL ENCLOSURE OF ABRASIVE BLASTING (ING 19)
RTECS #:9999999ZZ
Ingred Name:ING 18: OPERATION. ENCLOSURE SHOULD BE EXHAUST VENTILATED
I/A/W 29 CFR 1910.94 VENTILATION (A) ABRASIVE BLASTING.
RTECS #:9999999ZZ
Ingred Name:STAUROLITE (MFR CAS # 12182-56-8)
CAS:12181-56-8
Fraction by Wt: 86%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:TITANIUM COMPOUND; (TITANIUM MINERALS)
Fraction by Wt: 6%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SILICA, CRYSTALLINE - QUARTZ
CAS:14808-60-7
RTECS #:VV7330000
Fraction by Wt: <5%
OSHA PEL:SEE TABLE Z-3
ACGIH TLV:0.1 MG/M3 RDUST;9495
Ingred Name:SUPDAT:CELL CULTURE ASSAYS FOR GENE MUTATION IN BACTERIA &
DNA DMG IN MAMMALIAN CELLS & IN A WHOLE ANIMAL ASSAY (ING 5)
RTECS #:9999999ZZ
Ingred Name:ING 4:FOR CHROMOSOMAL EFTS. THE PREDOMINATE EFTS OF OVEREXP
TO AIRBORNE RESPIRABLE QUARTZ IN HUMANS IS (ING 6)
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:THE PROD, AS SHIPPED, DOES NOT POSE
ANY INHAL HLTH HAZ BECAUSE IN CNTNS ESSENTIALLY NO PARTICLES IN
RESPIRABLE SIZE RANGE. HOWEVER, IF DURING HNDLG/USE, PARTICLES ARE
BROKEN DOWN TO A SIZE THAT CAN BE INHALED, DUSTS MAY BE HARMFUL TO
RESP SYS. EYE CNTCT W/MINERAL SANDS MAY CAUSE IRRIT W/DISCOMFORT,
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ:IARC
MONOGRAPHS, VOL 68, 1997:GROUP 1A. NTP 7TH ANNUAL RPT ON CARCIN,
1994: (SUPDAT)
Effects of Overexposure:HLTH HAZ:TEARING, & BLURRING OF VISION.
STAUROLITE PRODS MAY CONTAIN UP TO 5% QUARTZ. EFTS NOTED IN ANIMALS
EXPOSED TO RESPIRABLE QUARTZ BY INHAL ON INTRATRACHEAL INSTILLATION
INCLUDE PULM FIBROSIS, I NFLAMM, EDEMA, & EMPHYSEMA. LUNG
TUMORSOCCURED IN RATS EXPOSED BY INHAL FOR UP TO TWO YEARS TO
LEVELS (SUPDAT)
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PREEXISTING
CONDITIONS OF LUNGS MAY HAVE INCREASED SUSCEPTIBILITY TO THE
TOXICITY OF EXCESSIVE EXPOSURES.
======================= First Aid Measures =======================
First Aid:INHAL:IMMED REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF
RESP. IF BRTHG IS DFCLTY, GIVE OXYGEN. CALL MD. SKIN:CMPD IS NOT
HAZ BY SKIN CNTCT, BUT REMOVAL OF PARTICLES & CLEANSING SKIN AFTER
USE IS ADVI SABLE. EYE CNTCT:IMMED FLUSH EYES W/PLENTY OF H*2O FOR
AT LEAST 15 MIN. CALL MD. INGEST:NO SPECIFIC INTERVENTION IS
INDICATED AS CMPD IS NOT HAZ BY INGEST. HOWEVER, IF SYMPS OCCUR,
CONSULT MD.
===================== Fire Fighting Measures =====================
Extinguishing Media:AS APPROPRIATE FOR COMBUSTIBLES IN AREA.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:SAFEGUARDS (PERSONNEL) NOTE:REVIEW FIRE
FIGHTING MEASURES AND HANDLING (PERSONNEL) SECTIONS BEFORE
PROCEEDING WITH CLEAN-UP. USE APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT DURING CLEAN-UP. ACCIDENTIAL RELEASE MEASURES: SWEEP UP
SPILLAGE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID BREATHING DUST.
WASHING BEFORE EATING, DRINKING, APPLYING COSMETICS OR SMOKING IS
ADVISABLE TO MINIMIZE DUST INHALATION FROM HANDS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:A NIOSH APPRVD AIR PURIFYING RESP W/DUST/MIST
CARTRIDGE/CANISTER MAY BE PERMISSIBLE UNDER CERTAIN CIRCUMSTANCES
WHERE AIRBORNE CONCS ARE EXPECTED TO EXCEED EXPOS LIM. PROT
PROVIDED BY AIR PURIFYING RE SP IS LIM. USE A POSITIVE (ING 13)
Ventilation:USE SUFFICIENT VENT TO KEEP EMPLOYEE EXPOS BELOW REC
LIMITS. IF USING THIS PRODUCT AS A ABRASIVE BLAST AGENT (ING 15)
Other Protective Equipment:ANSI APPRVD EMER EYE WASH & DELUGE SHOWER .
WEAR IMPERVIOUS CLOTHING, APRON, BOOTS OR WHOLE BODYSUIT AS APPROP.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EXPLAN OF CARCIN:CARCIN, 1994: ANTICIPATED TO BE CARCIN. EFTS OF
OVEREXP:OF 12.4 OR 51.6 MG/M3 OF RESPIRABLE QUARTZ. ALSO LUNG
TUMORS WERE SEEN IN STUDIES IN WHICH QUARTZ WAS INSTILLED IN
TRACHEA OF R ATS. QUARTZ WAS POS IN MAMALIAN CELL CULTURES OF CELL
TRANSFORMATION & CHROMOSOMAL EFTS & WAS NEGATIVE IN (ING 4)
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:2498F,1370C
Vapor Pres:NOT VOLAT
Vapor Density:NOT VOLAT
Spec Gravity:3.7
Evaporation Rate & Reference:NOT VOLAT (BU AC = 1)
Solubility in Water:INSOLUBLE
Appearance and Odor:REDDISH BROWN; ODORLESS; SOLID, FREE-FLOWING SAND.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE REASONABLY FORESEEABLE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:DECOMPOSITION WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:TREATMENT, STORAGE, TRANSPORTATION, AND DISPOSAL
MUST BE IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE/PROVINCIAL,
AND LOCAL REGULATIONS. IF APPROVED, MAY BE TRANSFERRED TO A LAND
DISPOSAL SITE.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:TERRAZZO WESTPAC TM-35 PART A
Kit Part:Y
CAGE:88444
CAGE:88444
============= Composition/Information on Ingredients =============
Ingred Name:ARALDITE GY 250(DGBA EPOXY RESINS) LD50:>5G/KG.
CAS:25068-38-6
RTECS #:CE6880000
Fraction by Wt: 69%
Ingred Name:C12-C14 ALKYL GLYCIDYL ETHERS LD50:>5G/KG
CAS:686909-97-2
Fraction by Wt: 69%
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHAL: BREATHING DIFFICULTIES,
IRRITATION. SKIN: IRRITATION, SENSITIZATION, DERMATITIS. EYE:
IRRITATION.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:SKIN CONDITIONS, KIDNEY OR LIVER
DISEASE.
======================= First Aid Measures =======================
First Aid:SKIN: WASH WITH SOAP AND WATER. INHAL: REMOVE TO FRESH AIR.
GIVE OXYGEN IF NEEDED. INGEST: GIVE LARGE QUANTITIES OF WATER,
INDUCE VOMITING. CALL PHYSICIAN. EYES: WASH WITH LARGE QUANTITIES
OF WATER FO R AT LEAST 15 MINUTES. GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:>200F,>93C
Extinguishing Media:CARBON DIOXIDE, FOAM, DRY CHEMICAL, WATER SPRAY
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:DECOMPOSITION AND COMBUSTION PRODUCTS MAY
BE TOXIC. THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE HCL AND
PHOSGENE .
================== Accidental Release Measures ==================
Spill Release Procedures:AVOID ALL PERSONAL CONTACT. TAKE UP WITH
ABSORBENT MATERIAL. SHOVEL INTO CLOSABLE CONTAINERS. FLUSH
CONTAMINATED AREA WITH WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:WARNING! CAUSES IRRIT. MAY CAUSE
ALLERGIC SKIN REACTION. AVOID CONTACT WITH EYES, SKIN OR CLOTHING.
AVOID BREATHING VAPOR, MIST OR (SEE OTHER PREC)
Other Precautions:HNDLG/STOR PREC:SPRAY.USE W/GOOD VENT.WASH AFTER
HNDLG.STORE IN COOL,DRY AREA IN CLOSED CNTNR.MAY CRYSTALLIZE IF
STORED BELOW 20 C (68 F).NO SMOKING IN AREA OF USE.DO NOT USE IN
GEN VICINITY OF ARC WE LDING,OPEN FLAMES/HOT (SEE SUPP DATA)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED ORGANIC CHEMICAL CARTRIDGE
RESPIRATOR IF NEEDED.
Ventilation:GOOD LOCAL EXHAUST. GOOD MECHANICAL VENTILATION.
Other Protective Equipment:WEAR PROTECTIVE CLOTHING.
Work Hygienic Practices:DO NOT SMOKE OR EAT WHILE HANDLING MATERIAL.
Supplemental Safety and Health
HNDLG/STOR PREC: SURFACES. HEAT AND/OR UV RADIATION MAY CAUSE THE
FORMATION OF HCL AND/OR PHOSGENE .
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:300F,149C
Vapor Pres:<.1MM
Spec Gravity:1.1
Evaporation Rate & Reference:<1
Solubility in Water:NIL
Appearance and Odor:OPAQUE, WHITISH LIQUID, MILD ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:ELEVATED TEMPERATURES
Hazardous Decomposition Products:CO*2, CO, HYDROGEN CHLORIDE & OTHER
TOXIC FUMES. PHOSGENE .
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:L-DEICER,SAFEWAY SF SUPERSAK,SF SOLID DEICER
CAGE:0U3B1
CAGE:NO813
CAGE:0WT77
CAGE:024Z2
Contract Num:SP0450-98-M-D790
CAGE:0U3B1
Contract Num:SP0450-99-M-C486
CAGE:0U3B1
============= Composition/Information on Ingredients =============
Ingred Name:SODIUM FORMATE (FORMIC ACID,SODIUM SALT)
CAS:141-53-7
RTECS #:LR0350000
= Wt:98.
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL, RAT) >2000 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:HUMAN HEALTH EFFECTS OF OVEREXPOSURE
MAY CAUSE SKIN OR EYE IRRITATION OR SKIN RASH, TEARING, OR BLURRING
OF VISION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, TEARS, REDNESS, BLURRED VISION.
======================= First Aid Measures =======================
First Aid:EYES:IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES. HOLD
EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER. WASH CONTAMINATED
CLOTHING BEFORE REUSE. INHALED:MOVE TO FRESH AIR. IF NOT BREATHING,
GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT,GIVE
OXYGEN. INGEST: NO SPECIFIC INTERVENTION IS INDICATED AS COMPOUND
IS NOT LIKELY TO BE HAZARDOUS BY INGESTION. CONSULT A PHYSICIAN IF
NECESSARY.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Lower Limits:NOT RELEVANT
Upper Limits:NOT RELEVANT
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL
FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED
CONTAINERS.
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. SPILL MAY BE
REMOVED IN DRY FORM WITH SUITABLE EQUIPMENT OR FLUSHED AWAY WITH
LARGE AMOUNT OF WATER.
Neutralizing Agent:NOT RELEVANT
======================Handling and Storage ======================
Handling and Storage Precautions:STORE AWAY FROM ACIDS. KEEP CONTAINER
CLOSED. KEEP OUT OF REACH OF CHILDREN.
Other Precautions:DO NOT GET IN EYES, ON SKIN/ON CLOTHING. AVOID
INHALATION OF DUST. FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY. READ
AND FOLLOW ALL LABEL DIRECTIONS AND PRECAUTIONS. WASH AFTER
HANDLING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NEEDED. IF DUSTY SITUATIONS PREVAIL, WEAR
NIOSH-APPROVED DUST RESPIRATOR OR MASK.
Ventilation:USE VENTILATION THAT IS ADEQUATE TO KEEP EMPLOYEE EXPOSURE
TO AIRBORNE DUST LIMITED.
Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. WASH THOROUGHLY BEFORE EATING,
DRINKING/SMOKING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:B3
NRC/State Lic Num:NOT RELEVANT
Melt/Freeze Pt:M.P/F.P Text:DECOMPOSES
Decomp Temp:>250.C, 482.F
Spec Gravity:0.950
pH:11.5
Viscosity:NOT RELEVANT
Evaporation Rate & Reference:NOT RELEVANT
Solubility in Water:45%
Appearance and Odor:WHITE GRANULES, SLIGHT SPECIFIC ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE
=================== Toxicological Information===================
Toxicological Information:ACUTE INHALATION TOXICITY LC50: > 670 MG/M3
(DUST, RAT, 4 HRS)
===================== Ecological Information =====================
Ecological:FISH TOXICITY LC50: > 1000 MG/L (96 H, ZEBRA FISH, OECD
203). BIOLOGICAL ELIMENATION: >90% (STATIC TEST, 7 DAYS) DIN
38412-L25.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT
TO FEDERAL, STATE OR LOCAL REGULATIONS. INCINERATION OR RECYCLING
IS RECOMMENDED.
=================== MSDS Transport Information ===================
Transport Information:NOT REGULATED.
===================== Regulatory Information =====================
SARA Title III Information:SARA INVENTORY STATUS: NOT DETERMINED.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:158 2352 KODAK EXTACOLOR RA BLEACH FIXER / RA-4; P/N = B
CAGE:19139
CAGE:19139
CAGE:5K871
============= Composition/Information on Ingredients =============
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 75-80%
Other REC Limits:NONE RECOMMENDED
Ingred Name:FERRIC AMMONIUM ETHYLENEDIAMINETETRAACETIC ACID
CAS:21265-50-9
Fraction by Wt: 15-20%
Other REC Limits:NONE RECOMMENDED
Ingred Name:ACETIC ACID (SARA III)
CAS:64-19-7
RTECS #:AF1225000
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:10 PPM
ACGIH TLV:10 PPM/15 STEL; 9394
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION- LOW HAZARD FOR RECOMMENDED
HANDLING. EYES- MAY CAUSE TRANSIENT IRRITATION. SKIN- LOW HAZARD
FOR RECOMMENDED HANDLING. INGESTION- EXPECTED TO BE A LOW INGESTION
HAZARD.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:EYE IRRITATION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHALATION- IF SYMPTOMATIC, MOVE TO FRESH AIR. EYES- WASH OUT
IMMEDIATELY WITH WATER FOR AT LEAST 15 MINUTES. GET MEDICAL
ATTENTION. SKIN- WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF
SYMPTOMS O CCUR. INGESTION- DRINK 1-2 GLASSES OF WATER. CALL A
PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL
FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE
SUBJECT TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH
LARGE AMOUNTS OF WATER. OTHERWISE, ABSORB SPILL WITH VERMICULITE OR
OTHER INERT MATERIAL, THEN P LACE IN A CONTAINER FOR CHEMICAL
WASTE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP
AWAY FORM INCOMPATIBLE SUBSTANCES.
Other Precautions:USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER
HANDLING THIS MATERIAL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NORMALLY REQUIRED.
Ventilation:GOOD GENERAL VENTILATION SHOULD BE USED (TYPICALLY 10 AIR
CHANGES PER HOUR). MATCH RATE TO CONDITIONS.
Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER.
Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER
BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES.
Supplemental Safety and Health
KEY1:N1.
================== Physical/Chemical Properties ==================
HCC:C3
Boiling Pt:B.P. Text:>212F,>100C
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Decomp Temp:Decomp Text:NOT GIVEN
Vapor Pres:18
Vapor Density:0.6
Spec Gravity:1.12
pH:6.2
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:COMPLETE
Appearance and Odor:BROWN LIQUID WITH A SLIGHT AMMONIA ODOR.
Percent Volatiles by Volume:75-80
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
BASES, STRONG OXIDIZING AGENTS, SODIUM HYPOCHLORITE (BLEACH).
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:AMMONIA, CHLORAMINE
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:3629 SPRED HOUSE DURA-FLAT FINISH
CAGE:01PD6
CAGE:72818
CAGE:01PD6
============= Composition/Information on Ingredients =============
Ingred Name:CALCIUM CARBONATE, DOMOLITE, LIMESTONE, WHITING
CAS:1317-65-3
RTECS #:EV9580000
Fraction by Wt: 5-10%
OSHA PEL:15 MG/CUM (DUST)
ACGIH TLV:10 MG/CUM (DUST)
Ingred Name:ETHYLENE GLYCOL, GLYCOL
CAS:107-21-1
RTECS #:KW2975000
Fraction by Wt: 1-5%
Other REC Limits:10 MG/CUM
ACGIH TLV:C 127 MG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:TITANIUM DIOXIDE, TIO2
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 10-20%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:ZINC OXIDE
CAS:1314-13-2
RTECS #:ZH4810000
Fraction by Wt: 5-10%
OSHA PEL:15MG/M3 TDUST/5 FUME
ACGIH TLV:10MG/M3 TDUST; 9293
Ingred Name:ACRYLIC COPOLYMER
Fraction by Wt: 10-20%
Ingred Name:TALL OIL FATTY ACIDS, PENTAERYTHRITOL, ISOPHTHALIC ACID
POLYMER*92-3*
CAS:67746-05-8
Fraction by Wt: 1-5%
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 40-50%
Ingred Name:FORMALDEHYDE, FORMALIN (2A CARCINOGEN BY NTP, IARC, OSHA)
INTENDED CHANGE
CAS:50-00-0
RTECS #:LP8925000
Fraction by Wt: <0.1%
OSHA PEL:SEE 1910.1048
ACGIH TLV:C 0.3 PPM; A2; 9293
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:WEIGHT PER GALLON IN POUNDS: 10.9
RTECS #:9999999WG
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:INHALATION: RESPIRATORY TRACT
IRRITATION. SKIN/EYES: IRRITATION. INGESTION: LARGE AMOUNTS COULD
CAUSE SERIOUS INJURY.
Explanation of Carcinogenicity:SEE INGREDIENTS
Effects of Overexposure:INHALATION: MUCOUS MEMBRANE IRRITATION,
DROWSINESS, DIZZINESS, &/OR LIGHTHEADEDNESS, HEADACHE, NAUSEA,
ALLERGIC SENSITIZATION. SKIN: DERMATITIS, DIZZINESS, &/OR
LIGHTHEADEDNESS, HEADACHE, NAUSEA. MAY BE ABSORBED. INGESTION:
KIDNEY DAMAGE &/OR FAILURE.
Medical Cond Aggravated by Exposure:EYES, SKIN, RESPIRATORY, LUNG,
KIDNEY, LIVER & NERVOUS SYSTEM DISORDERS.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED
BREATHING. HAVE TRAINED PERSON GIVE OXYGEN IF NECESSARY. SKIN: WASH
OFF QUICKLY W/PLENTY OF WATER, THEN SOAP & WATER. EYES: FLUSH
W/PLENTY OF WATER FOR AT LEAST 15 MINS. INGESTION: OBTAIN MEDICAL
ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:>200F
Extinguishing Media:DRY CHEMICAL OR FOAM
Fire Fighting Procedures:CLOSED CONTAINERS MAY BURST IF EXPOSED TO
EXTREME HEAT OR FIRE.
Unusual Fire/Explosion Hazard:WATER MAY BE USED TO COOL & PROTECT
EXPOSED CONTAINERS.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA. COLLECT SPILLS W/ABSORBENT
MATERIAL.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE <100F. KEEP FROM FREEZING. USE
ONLY W/ADEQUATE VENTILATION. KEEP CONTAINERS TIGHTLY CLOSED &
UPRIGHT WHEN NOT IN USE. DON'T TAKE INTERNALLY.
Other Precautions:KEEP OUT OF REACH OF CHILDREN. AVOID CONTACT W/SKIN,
EYES & BREATHING OF VAPORS. AVOID CONDITIONS WHICH RESULT IN
FORMATION OF INHALABLE PARTICLES SUCH AS SPRAYING OR ABRADING
(SANDING) PAINTED SURFAC ES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE ONLY NIOSH/MSHA APPROVED RESPIRATORS
Ventilation:DILUTION VENTILATION OR LOCAL EXHAUST TO PREVENT BUILD-UP
OF VAPORS.
Other Protective Equipment:EYE WASH, SAFETY SHOWER
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH HANDS THOROUGHLY AFTER HANDLING, BEFORE EATING OR
SMOKING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text: 212F
Percent Volatiles by Volume:64.6%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZERS, HYDROFLUORIC ACID
Stability Condition to Avoid:ELEVATED TEMPERATURES
Hazardous Decomposition Products:CO, CO2
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE W/ALL APPLICABLE
REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:7448 RUST-OLEUM PROFESSIONAL COATING
CAGE:08882
CAGE:08882
============= Composition/Information on Ingredients =============
Ingred Name:STODDARD SOLVENT (PETROLEUM DISTILLATE), MINERAL SPIRITS
*98-1*
CAS:8052-41-3
RTECS #:WJ8925000
Fraction by Wt: 40-55%
Other REC Limits:525 MG/CUM
OSHA PEL:500 PPM
ACGIH TLV:100 PPM
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: HARMFUL, MAY AFFECT THE
BRAIN/NERVOUS SYSTEM, NOSE & THROAT IRRITATION. SKIN:
IRRITATION/DERMATITIS. EYES: IRRITATION. INGESTION: GI IRRITATION.
REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS MAY CAUSE PERMANENT
BRAIN & NERVOUS SYSTEM DAMAGE. EFFECTS IN HUMANS HAVE INCLUDED
LIVER & CARDIAC ABNORMALITIES. (SUPP
Explanation of Carcinogenicity:NONE
Effects of Overexposure:DIZZINESS, HEADACHE, NAUSEA, STAGGERING GAIT,
CONFUSION, UNCONSCIUOSNESS, COMA, IRRITATION, VOMITING, DIARRHEA.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. EYES:
FLUSH W/LARGE AMOUNTS OF WATER FOR 15 MINS. SKIN: WASH W/SOAP &
WATER. INGESTION: DON'T INDUCE VOMITING. KEEP WARM & QUIET. OBTAIN
MEDICAL ATT ENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:102-105F
Extinguishing Media:CO2, DRY CHEMICAL/FOAM.
Fire Fighting Procedures:USE FULL PROTECTIVE EQUIPMENT & SCBA. WATER
SPRAY MAY BE INEFFECTIVE. WATER MAY BE USED TO COOL CLOSED
CONTAINERS. IF WATER IS USED, FOG NOZZLES ARE PREFERRED.
Unusual Fire/Explosion Hazard:COMBUSTIBLE LIQUID. CLOSED CONTAINERS MAY
EXPLODE WHEN EXPOSED TO EXTREME HEAT. DON'T APPLY TO HOT SURFACES.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE SOURCES OF IGNITION, VENTILATE AREA &
REMOVE W/INERT ABSORBENT & NON-SPARKING TOOLS.
======================Handling and Storage ======================
Handling and Storage Precautions:DON'T STORE >120F.
Other Precautions:DON'T PUNCTURE CONTAINERS. INTENTIONAL MISUSE BY
DELIBERATELY CONCENTRATING & INHALING THE CONTENTS CAN BE
HARMFUL/FATAL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED CHEMICAL CARTRIDGE
RESPIRATOR(TC23C)TO REMOVE SOLID AIRBORNE PARTICLES OF OVERSPRAY &
ORGANIC VAPORS DURING SPRAYING APPLICATION. IN CONFINED AREAS, USE
NIOSH APPROVED SUPPLIED AIR RESPIRATORS/HOODS (TC19C).
Ventilation:GENERAL DILUTION/LOCAL EXHAUST IN VOLUME & PATTERN TO KEEP
TLV BELOW ACCEPTABLE LIMITS.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
HLTH HZRDS CONT'D: ASPIRATION OF THIS MATERIAL INTO THE LUNGS CAN CAUSE
CHEMICAL PNEUMONITIS WHICH CAN BE FATAL.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:307-389F
Vapor Density:>1
Evaporation Rate & Reference:SLOWER THAN ETHER
Percent Volatiles by Volume:59-78
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
INCOMPATIBLE W/STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:OPEN FLAME, HOT SURFACES.
Hazardous Decomposition Products:CO & CO2.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS. DON'T INCINERATE CONTAINERS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:MIL-P-23377E EPOXY POLYAMIDE PRIMER (COMP A & B)
Kit Part:Y
Preparer's Name:NONE
CAGE:KOPPE
CAGE:KOPPE
CAGE:85663
============= Composition/Information on Ingredients =============
Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)
CAS:78-93-3
RTECS #:EL6475000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:200 PPM
ACGIH TLV:200 PPM/300STEL 9394
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:TOLUENE (SARA III)
CAS:108-88-3
RTECS #:XS5250000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:200 PPM; Z-2
ACGIH TLV:S, 50 PPM; 9394
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:ISOPROPANOL (ISOPROPYL ALCOHOL) (SARA III)
CAS:67-63-0
RTECS #:NT8050000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:400 PPM
ACGIH TLV:400 PPM/500STEL;9394
Ingred Name:STRONTIUM CHROMATE(SARA III)
CAS:7789-06-2
RTECS #:GB3240000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:C 0.1 MG (CRO3)/M3
ACGIH TLV:0.0005MG(CR)/M3;A294
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Ingred Name:PROPYLENE GLYCOL MONOMETHYL ETHER
CAS:107-98-2
RTECS #:UB7700000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM
ACGIH TLV:100 PPM/150STEL;9394
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT) IS UNKNOWN.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: IRRITATING TO EYES, NOSE AND
THROAT FROM VAPORS. HIGHER CONCENTRATIONS CAUSE RESPIRATORY TRACT
IRRITATION, HEADACHE, DROWSINESS, DIZZINESS, FATIGUE, NAUSEA,
COLLAPSE. CHRONIC: NONE SPECIFIED BY MANUFACTURER.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES: IRRITATION. SKIN: IRRITATION. INHALATION:
RESPIRATORY TRACT IRRITATION, HEADACHE, DROWSINESS, DIZZINESS,
FATIGUE, NAUSEA, COLLAPSE. INGESTION: GASTROINTESTINAL IRRITATION,
ABDOMINAL PAIN, NAUSEA , VOMITING, DIARRHEA, EFFECTS SIMILAR
TOINHALATION.
Medical Cond Aggravated by Exposure:PERSON WITH PRE-EXISTING DISEASE
INVOLVING EYES, SKIN, RESPIRATORY TRACT, KIDNEY, LIVER, BONE
MARROW, BLOOD CELLS, CNS ARE AT GREATER THAN NORMAL RISK OF ADVERSE
EFFECTS WHEN EXPOSED TO THIS PRODUCT.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH WITH LARGE AMOUNTS OF WATER. GET MEDICAL
ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. WASH AREA WITH SOAP
AND WATER. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION.
INHALATION: MOVE TO FR ESH AIR. IF NOT BREATHING, GIVE CPR.
IFBREATHING DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
INGESTION: DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:23.0F,-5.0C
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, FOAM, WATER SPRAY.
WATER MAY BE INEFFECTIVE.
Fire Fighting Procedures:WEAR COMPLETE FIRE SERVICE PROTECTIVE
EQUIPMENT, FULL-FACE MSHA/NIOSH APPROVED SCBA. USE WATER TO COOL
FIRE-EXPOSED CONTAINER, STRUCTURE, PROTECT PERSONNEL.
Unusual Fire/Explosion Hazard:VAPORS FORM EXPLOSIVE MIXTURE IN AIR.
VAPORS HEAVIER THAN AIR, MAY TRAVEL TO DISTANT IGNITION SOURCE AND
FLASHBACK. CLOSED CONTAINER MAY RUPTURE IN HIGH HEAT.
================== Accidental Release Measures ==================
Spill Release Procedures:AVOID BREATHING VAORS. REMOVE ALL SOURCES OF
IGNITION. VENTILATE AREA. CONTAIN AND SCOOP UP SPILL WITH
NON-SPARKING TOOLS OR RAGS. USE INERT ABSORBENT ON SMALL SPILLS OR
ON RESIDUALS OF LARGE SPILLS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, WELL VENTILATED AREA
AWAY FROM FLAMES, WELDING, SMOKING, SPARKS, OPEN LIGHTS. KEEP
CONTAINERS CLOSED AND UPRIGHT TO PREVENT LEAKAGE.
Other Precautions:AVOID BREATHING VAPORS OR SPRAY MIST. AVOID EYE AND
SKIN CONTACT. DO NOT USE PRESS TO EMPTY DRUMS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN EXPOSURE BELOW
PEL(TLV), USE MSHA/NIOSH APPROVED UNITS PER CURRENT 29CFR1910.134.
Ventilation:PROVIDE ADEQUATE MECHANICAL (GENERAL)/LOCAL EXHAUST
VENTILATION IN VOLUME AND PATTERN TO CONTROL EXPOSURE BELOW
PEL/TLV.
Other Protective Equipment:WEAR INDUSTRIAL TYPE WORK CLOTHING AND
SAFETY FOOTWEAR.
Work Hygienic Practices:WASH AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
THIS PRODUCT IS A TWO COMPONENT COATING. ANY MIXTURE OF COMPONENT A & B
WILL HAVE HAZARDS OF BOTH COMPONENTS. DATA SUPPLIED IS BASED ON
MIXTURE OF THE TWO CONPONENTS.
================== Physical/Chemical Properties ==================
HCC:F2
Vapor Density:>1
Spec Gravity:8.6-9.4 LBS/GAL
Evaporation Rate & Reference:>1 (BUTYL ACETATE=1)
Solubility in Water:MODERATELY
Appearance and Odor:YELLOW COLORED LIQUID. STRONG SOLVENT ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID OXIDIZING AGENTS, HYDROFLUORIC ACID, ALKALI, REDUCING AGENTS,
STRONG ACIDS.
Stability Condition to Avoid:EXCESSIVE TEMPERATURES, OPEN FLAMES,
SPARKS, OTHER SOURCES OF IGNITION.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
OXIDES OF NITROGEN.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:US EPA DEFINED IGNITABLE HAZARDOUS WASTE.
DISPOSE OF AS AN IGNITABLE WASTE IN ACCORDANCE WITH LOCAL, STATE
AND FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:AMERCOAT 3147 CURE, 3212200
CAGE:0Y2E4
CAGE:55849
CAGE:0Y2E4
============= Composition/Information on Ingredients =============
Ingred Name:NONYLPHENOL. VP:<1. LD50:1.6 G/KG
CAS:25154-52-3
RTECS #:SM5600000
Fraction by Wt: <10%
Ingred Name:AMINE. VP:@68F <1. LD50:0.75 G/KG
CAS:9046-10-0
Fraction by Wt: <10%
Ingred Name:EPOXY HARDNER
Fraction by Wt: <5%
Ingred Name:FURFURYL ALCOHOL
CAS:98-00-0
RTECS #:LU9100000
Fraction by Wt: <5%
OSHA PEL:S, 50 PPM/15 STEL
ACGIH TLV:S,10 PPM/15STEL;9293
Ingred Name:ETHYL BENZENE (SARA III)
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: <5%
OSHA PEL:100 PPM/125 STEL
ACGIH TLV:100 PPM/125STEL 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:PHENOL,2,4,6-TRIS(DIMETHYLAMINOMETHYL) PHENOL. VP:<1;
LD50:1.7 G/KG.
CAS:90-72-2
RTECS #:SN3500000
Fraction by Wt: <5%
Ingred Name:OIL OF ORANGE (DEODORIZING OIL). VP:2.
CAS:8008-57-9
RTECS #:RI8600000
Fraction by Wt: <5%
Ingred Name:TALC (CONTAINING NO ASBESTOS)
CAS:14807-96-6
RTECS #:WW2710000
Fraction by Wt: <25%
OSHA PEL:2 MG/M3 RDUST
ACGIH TLV:2 MG/M3 RDUST; 9192
Ingred Name:BARIUM SULFATE
CAS:7727-43-7
RTECS #:CR0600000
Fraction by Wt: <20%
Other REC Limits:0.5 MG/M3(AS BA)-MFR
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: <20%
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:POLYAMIDE RESIN. (TETA <5%) LD50:2.5 G/KG
CAS:68410-23-1
Fraction by Wt: <10%
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENT.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:VAPOR, SPRAY MIST AND/OR DUST CAN BE
HARMFUL. IRRITATING TO SKIN, MUCOUS MEMBRANES, EYES AND RESP
SYSTEM. EXCESSIVE INHAL CAN CAUSE HDCH, NAUSEA, DIZZINESS OR
ASPHYXIATION. RPTD/PRLNGD OCCUPATIONAL OV EREXP TO SOLVS IS
ASSOCIATED WITH PERM BRAIN & NERV SYS DMG. CAN BE HARMFUL OR FATAL
IF SWALLOWED. (SEE EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:CAN BE HARMFUL IF INHALED OR ABSORBED
THROUGH THE SKIN. OVEREXPOSURE OR INGESTION CAN CAUSE LUNG, KIDNEY,
AND/OR LIVER DAMAGE. CAN CAUSE IRREVERSIBLE EYE BURNS AND DAMAGE.
SKIN AND RESPIRATOR Y SENSITIZATION AND ALLERGIC REACTION CAN
OCCUR. CAN CAUSE SEVERE EYE INJURY.
Medical Cond Aggravated by Exposure:RESPIRATORY, ALLERGIES, KIDNEY AND
LIVER DISORDERS.
======================= First Aid Measures =======================
First Aid:INHAL:OVEREXPOSURE TO VAPOR, SPRAY MIST OR DUST-PROVIDE FRESH
AIR; IF BREATHING LABORED, GIVE O*2/ART RESP. SKIN:WASH THOROUGHLY
W/SOAP & WATER. EYE:FLUSH IMMEDIATELY W/PLENTY OF WATER FOR AT
LEAST 15 MINUTES AND GET MD. INGEST:DRINK 1 OR 2 GLASSES OF WATER
TO DILUTE. DO NOT INDUCE VOMITING. GET MD OR CONSULT POIS CTL CTR
IMMED. TREAT SYMPTOMATICALLY.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:87.0F,30.6C
Lower Limits:0.30
Extinguishing Media:FOAM, CO*2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT,
SPARKS & OPEN FLAME. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO
EXTREME HEAT.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. AVOID
BREATHING OF VAPS OR DUST. USE ABSORBENT CLEANUP MATERIALS OR SWEEP
UP. PLACE IN SEPARATE CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED, UPRIGHT WHEN
NOT IN USE. STOR IN COOL, DRY, WELL VENTILATED AREA. AVOID STORAGE
TEMPERATURES ABOVE 100F.
Other Precautions:DO NOT TAKE INTERNALLY. AVOID PRLNGD BRTHG OF DUST,
VAPS OR SPRAY MIST OR CONTACT W/SKIN & EYES. GROUND CNTNRS WHEN
POURING. DO NOT WELD OR FLAME CUT AN EMPTY CONTAINER. DESTROY
CONTAM LEATHER & ABSOR BENT SHOES WHICH CANNOT BE DECONTAM.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR. USE AIR LINE
RESPS IN CONFINED/RESTRICTED VENT AREAS OR W/POLYURETHANE OR
ISOCYANTES.
Ventilation:SUFFICIENT VENT, IN VOLUME & PATTERN SHOULD BE PROVIDED TO
KEEP AIR CONTAM CONC BELOW TLV LIMIT. REMOVE (SEE SUPP DATA)
Other Protective Equipment:FULL PROTECTIVE CLOTHING AND SPARK PROOF
EQUIPMENT.
Work Hygienic Practices:WASH THOROUGHLY BEFORE EATING, SMOKING OR USING
WASHROOM. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
VENT:WELDING OR FLAME CUTTING DECOMPOSITION PRODUCTS.
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:277F,136C
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:LIQUID WITH SOLVENT ODOR.
Percent Volatiles by Volume:29
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, ACIDS, ALKALIES. EPOXIES UNDER UNCONTROLLED
CONDITIONS.
Stability Condition to Avoid:HEAT, OPEN FLAME, ARC OR SPARKS.
Hazardous Decomposition Products:CO AND CO*2, NO*X, AMMONIA, SO*X.
==================== Disposal Considerations ====================
Waste Disposal Methods:IN SEPARATE, CLOSED METAL CONTAINER IN
ACCORDANCE WITH ALL APPLICABLE, LOCAL, STATE, AND FEDERAL
REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:CONTOUR PUTTY FOR PLASTIC MODELS, 3511
CAGE:FO415
CAGE:87890
CAGE:FO415
============= Composition/Information on Ingredients =============
Ingred Name:CELLULOSE ACETATE BUTYRATE
CAS:9004-36-8
Fraction by Wt: 5%
OSHA PEL:5 MG/M3 (RDUST), MFR
Ingred Name:ISOPROPYL ACETATE
CAS:108-21-4
RTECS #:AI4930000
Fraction by Wt: 1-5%
OSHA PEL:250 PPM/310 STEL
ACGIH TLV:250 PPM/310STEL;9192
Ingred Name:ISOPROPYL ALCOHOL (SARA III)
CAS:67-63-0
RTECS #:NT8050000
Fraction by Wt: 10-15%
OSHA PEL:400 PPM/500 STEL
ACGIH TLV:400 PPM/500STEL;9192
Ingred Name:ACETONE (SARA III)
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 1-5%
OSHA PEL:1000PPM
ACGIH TLV:750PPM/1000STEL;9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:MAGNESIUM ALUMINUM SILICATE
CAS:8031-18-3
Fraction by Wt: F1-5%
OSHA PEL:5 MG/M3 (RDUST), MFR
Ingred Name:ZINC STEARATE
CAS:557-05-1
RTECS #:ZH5200000
Fraction by Wt: 1-5%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:WOLLASTONITE; (CALCIUM SILICATE)
CAS:13983-17-0
Fraction by Wt: 60-65%
OSHA PEL:15 MG/M3 (TDUST)
ACGIH TLV:10 MG/M3 (TDUST)
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE: LIQ SPLASHES & HIGH VAP CONC
CAUSE IRRIT. LIQ MAY RESULT IN CORNEAL INJURY WHICH HEALS SLOWLY.
SKIN: PROLONGED & REPEATED LIQ CONTACT CAN CAUSE DEFATTING & DRYING
OF THE SKIN WHICH MAY RESULT IN SKIN IRRIT AND DERMATITIS. INHAL:
CONC ABOVE THE TLV MAY BE IRRITATIVE A CAUSE DIZZ, HDCH, (SEE EFTS
OF OVEREXPO)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: VOMITING & POSSIBLY NARCOSIS. INGEST:
SLIGHTLY TOXIC. INGEST OF A LG QUANITY MAY CAUSE DROWSINESS & LOSS
OF CONSCIOUSNESS. STOMACH CRAMPS, NAUSEA, VOMITING & DIARRHEA MAY
ALSO OCCUR. CHRONIC OVEREXPOSURE: MAY RESULT IN DIZZINESSS,
HEADACHE, NAUSEA, VOMITING & POSSIBLY NARCOSIS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYE: WASH IMMED W/PLENTY OF H2O FOR AT LEAST 15 MIN WHILE
HOLDING LIDS OPEN. CALL MD. SKIN: WASH IMMED W/MILD SOAP & H2O.
INHAL: REMOVE TO FRESH AIR. USE ARTF RESP IF NEEDED. INGEST: GIVE
NO MORE THAN 2 GLASSES OF H2O & 2 TBLSP OF SYRUP OFIPECAC TO
INDUCE VOMITING. IF VICTIM IS A CHILD, GIVE NO MORE THAN 1 GLASS OF
H2O & 1 TBLSP OF SYRUP OF IPECAC. KEEP HEAD BELOW HIPS WHILE
VOMITING.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:43.0F,6.1C
Lower Limits:1.7
Upper Limits:12.8
Extinguishing Media:ALCOHOL RESISTANT FOAM, CO2 OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . A STREAM OF H2O COULD SPREAD FIRE. AVOID
BREATHING VAPORS.
Unusual Fire/Explosion Hazard:COOL FIRE EXPOSED CONTAINERS WITH H2O.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE ALL POSSIBLE IGNITION SOURCES.
PROVIDE ADEQUATE VENTILATION. TAKE UP WITH AN ABSORBENT MATERIAL
AND PLACE IN NON-LEAKING CONTAINER. SEAL FOR PROPER DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:READ ALL LABEL CAUTIONS. STORE AWAY
FROM IGNITION SOURCES IN A COOL WELL VENTILATED AREA. HANDLE AS
FLAMMBLE LIQUID. DO NOT DROP CONTAINER.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF TLV OF PROD OR ANY COMPONENT IS EXCEEDED, A
NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED IN ABSENCE
OF PROPER ENVIRONMENTAL CONTROL. OSHA REGS ALSO PERMIT OTHER
NIOSH/MSHA RESPIRATORS UND ER SPECIFIC CONDITIONS.
Ventilation:IF THE PROD IS USED IN A CONFINED AREA, PROVIDE SUFFICIENT
MECH (GEN &/LOCAL EXHAUST) VENTILATION TO (SEE SUPP DATA)
Other Protective Equipment:AS REQUIRED TO AVOID SKIN CONTACT OR
BREATHING VAPORS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
VENT: MAINTAIN EXPOSURE BELOW TLV(S). EXPLOSION PROOF EQUIPMENT IS
ADVISED.
================== Physical/Chemical Properties ==================
HCC:F3
Boiling Pt:B.P. Text:177F,81C
Vapor Pres:58
Vapor Density:2.27
Spec Gravity:1.609
Evaporation Rate & Reference:3.32 (N-BUTYL ACETATE=1)
Solubility in Water:15.9%
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:38
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS & STRONG ALKALIES.
Stability Condition to Avoid:AVOID HEAT, SPARKS, FLAME & OTHER IGNITION
SOURCES.
Hazardous Decomposition Products:CO IF BURNED WITH INSUFFICIENT AIR.
==================== Disposal Considerations ====================
Waste Disposal Methods:DO NOT INCINERATE CLOSED CONTAINERS. DISPOSE OF
I/ A/W LOCAL, STATE, AND FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:FORMULA 102 ZINC DUST PAINT,MIL-P-15145
CAGE:85319
CAGE:85319
============= Composition/Information on Ingredients =============
Ingred Name:NAPHTHA (PETROLEUM SPIRITS OR BENZIN)
CAS:8030-30-6
RTECS #:SE7555000
Fraction by Wt: 43.5%
OSHA PEL:100 PPM
Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 4.1%
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:ISOPROPYL ALCOHOL (SARA III)
CAS:67-63-0
RTECS #:NT8050000
Fraction by Wt: 0.5%
OSHA PEL:400 PPM/500 STEL
ACGIH TLV:400 PPM/500STEL;9192
======================= First Aid Measures =======================
First Aid:REMOVE TO VENTILATED AREA-FLUSH EYES WITH WATER-WIPE AFFECTED
SKIN AREAS WITH CLEAN CLOTH-WASH WITH SOAP & WATER-GET MEDICAL
ATTENTION
===================== Fire Fighting Measures =====================
Flash Point:83F (TCC)
Lower Limits:0.8
Upper Limits:7.0
Extinguishing Media:CO*2,FOAM,DRY CHEMICAL
Fire Fighting Procedures:WATER MAY BE INEFFECTIVE
Unusual Fire/Explosion Hazard:NONE (MFR)
================== Accidental Release Measures ==================
Spill Release Procedures:AVOID BREATHING VAPORS.REMOVE SOURCES OF
IGNITION
======================Handling and Storage ======================
Handling and Storage Precautions:STORE BELOW 120F.KEEP CONTAINERS
TIGHTLY CLOSED & AWAY FROM SOURCES OF IGNITION
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPRVD RESP PROTCTN FOR PARTICULAR
EXPOSURE OF CONC.
Ventilation:MFR RECM MECHANICAL VENTILATION
Supplemental Safety and Health
SOLUBILITY IN WATER: TRACE
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:170-400F
Vapor Density:3.8
Spec Gravity:0.9
Evaporation Rate & Reference:<1 (BUT ACET=1)
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE (MFR)
==================== Disposal Considerations ====================
Waste Disposal Methods:SWEEP WITH SAWDUST.BURN SWEEPINGS IN SAFE
AREA.MUST BE IAW LOCAL,STATE & FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
=======================================================
NIIN: 01-024-6991
Product ID: ITEM 31231, SPEEDBONDER 312 STRUCTURAL ADESIVE
Cage: 05972
=======================================================
Contractor Summary
=======================================================
Cage: 05972
=======================================================
Item Description Information
=======================================================
Item Manager: GSA
Item Name: ADHESIVE
Specification Number: NONE
Type/Grade/Class: NONE
Unit of Issue: BT
Quantitative Expression: 00000000050ML
UI Container Qty: 0
Type of Container: BOTTLE
=======================================================
Ingredients
=======================================================
% Wt: 50-55
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
-----------------------------
Cas: 27813-02-1
% Wt: 35-40
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
------------------------------
Cas: 79-10-7
RTECS #: AS4375000
% Wt: 5-10
OSHA PEL: S, 10 PPM
ACGIH TLV: S, 2 PPM; 9192
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Cas: 80-15-9
RTECS #: MX2450000
% Wt: 1-3
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
------------------------------
Cas: 102-82-9
RTECS #: YA0350000
% Wt: 0.1-1
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: LD50 (ORAL) IS >10,000 MG/KG
Route Of Entry Inds - Inhalation: NO
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: LIQUID IS AN EYE IRRITANT. VAPORS MAY IRRITATE EYE, NOSE,
THROAT.
Explanation Of Carcinogenicity: MANUFACTURER GAVE NO COMMENTS OTHER THAN THE
ABOVE REFERENCES TO THE THREE LISTINGS FOR EACH INGREDIENT.
Signs And Symptions Of Overexposure: IRRITATION OF EYES, SKIN, NOSE OR THROAT.
MAY CAUSE DERMATITS ON, PROLONGED CONTACT IN SENSITIVE INDIVIDUALS.
Medical Cond Aggravated By Exposure: UPPER RESPIRATORY AND LUNG DISEASES,
DERMATITIS.
First Aid: INGESTED:DO NOT INDUCE VOMITING. KEEP INDIVIDUAL CALM. OBTAIN
MEDICAL ATTENTION. INHALED:REMOVE TO FRESH AIR. IOF SYMPTOMS PERSIST, OBTAIN
MEDICAL ATTENTION. SKIN:WASH WITH SOAP & WATER. EYE:FLUSH WI TH WATER AT
LEAST 15 MINUTES. OBTAIN MEDICAL ATTENTION.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: SOAK RP IN AN INERT ABSORBENT. STORE IN A PARTLY
FILLED CLOSED CONTAINER UNTIL DISPOSAL.
Neutralizing Agent: NO INFORMATION GIVEN BY MFR ON MSDS.
Waste Disposal Methods: INCINERATE FOLLOWING IPA AND LOCAL REGULATIONS.
Handling And Storage Precautions: STORE BELOW 110F. AVOID PROLONGED SKIN
CONTACT. KEEP AWAY FROM EYES. AVOID PROLONGED BREATHING OF VAPORS.
Other Precautions: NONE
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point Text: >200F,>93C
Lower Limits: 0.8 OR 2
Upper Limits: 6.4 OR 8
Extinguishing Media: CARBON DIOXIDE, FOAM, DRY CHEM.
Fire Fighting Procedures: NONE
Unusual Fire/Explosion Hazard: NONE
=======================================================
Control Measures
=======================================================
Respiratory Protection: NO INFORMATION GIVEN BY MFR ON MSDS.
Ventilation: SUFFICIENT TO MAINTAIN VAPOR CONCENTRATION BELOW TLV.
Other Protective Equipment: NO INFORMATION GIVEN BY MFR ON MSDS.
Work Hygienic Practices: MFR: ? :USE GOOD INDUSTRIAL HYGIENE PRACTICE. AVOID
UNNECESSARY EXPOSURE. WASH THOROUGHLY BEFORE EATING OR DRINKING
Supplemental Safety and Health: NONE
=======================================================
Physical/Chemical Properties
=======================================================
HCC: N1
NRC/State LIC No: NONE
B.P. Text: >300F,>149C
M.P/F.P Text: UNKNOWN
Decomp Text: UNKNOWN
Vapor Pres: <10 MM
Vapor Density: UNKNOWN
Spec Gravity: 1.08
Evaporation Rate & Reference: UNKNOWN
Solubility in Water: SLIGHT
Appearance and Odor: YELLOWISH LIQUID, SHARP IRRITATING ODOR
Corrosion Rate: UNKNOWN
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE
Materials To Avoid: NONE
Hazardous Decomposition Products: NONE. FROM FIRE:IRRITATING ORGANIC VAPORS
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
Transportation Information
=======================================================
Trans ID NO: 99804
Product ID: ITEM 31231, SPEEDBONDER 312 STRUCTURAL ADESIVE
Review Date: 12/22/1994
Net Unit Weight: >200F,>93C,
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: BT
Container QTY: 0
Type Of Container: BOTTLE
=======================================================
Detail DOT Information
=======================================================
DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
=======================================================
Detail IATA Information
=======================================================
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail AFI Information
=======================================================
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
HAZCOM Label
=======================================================
Product ID: ITEM 31231, SPEEDBONDER 312 STRUCTURAL ADESIVE
Cage: 05972
Company Name: LOCTITE CORPORATION
Street: 1001 TROUT BROOK CROSSING
Zipcode: 06067-3910
Label Required IND: Y
Date Of Label Review: 12/22/1994
Status Code: C
MFG Label NO: NONE
Label Date: 12/22/1994
Origination Code: F
Skin Protection IND: YES
Signal Word: CAUTION
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: **TARGET ORGANS:EYES, RESPIRATORY SYSTEM** LIQUID IS
AN EYE IRRITANT. VAPORS MAY IRRITATE EYE, NOSE, THROAT. STORE BELOW 110F.
AVOID PROLONGED SKIN CONTACT. KEEP AWAY FROM EYES. AVOID PROLONGED BREA THING
OF VAPORS. IN CASE OF SPILL: SOAKUP IN AN INERT ABSORBENT. STORE IN A PARTLY
FILLED CLOSED CONTAINER UNTIL DISPOSAL.
=======================================================
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:FRICTION MATERIAL
CAGE:8H856
CAGE:8H856
============= Composition/Information on Ingredients =============
Ingred Name:BARIUM SULFATE/BARIMITE
CAS:7727-43-7
RTECS #:CR0600000
Fraction by Wt: <= 39%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:BRASS
Fraction by Wt: <= 10%
Other REC Limits:1 MG/M3 RDUST
Ingred Name:ALPHA-ALUMINA (ALUMINUM OXIDE) (EPA LISTS ONLY FIBROUS
FORMS) (SARA III)
CAS:1344-28-1
RTECS #:BD1200000
Fraction by Wt: <= 8%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:FIBROUS GLASS
CAS:65997-17-3
Fraction by Wt: <= 31%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5 MG/M3 (MFR)
ACGIH TLV:10 MG/M3 (MFR)
Ingred Name:PHENOL FORMALDEHYDE RESIN
CAS:9003-35-4
Fraction by Wt: <= 33%
Other REC Limits:5 MG/M3
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE & CHRONIC- SOME PERSONS MAY BE
SENSITIVE TO PHENOLIC RESINS & DEVELOP DERMATITIS. DUSTS MAY CAUSE
PULMONARY PROBLEMS. METAL DUSTS CAN IRRITATE EYES & UPPER
RESPIRATORY TRACTS. GI DISTURBANCES IF INGESTED. CHRONIC POISONING
FROM ALUMINUM & BRASS POSSIBLE. FIBERGLASS MAY CAUSE LUNG DISEASE
(FIBROSIS).
Explanation of Carcinogenicity:DOES NOT CONTAIN ASBESTOS.
Effects of Overexposure:SOME PERSONS MAY BE SENSITIVE TO PHENOLIC
RESINS & DEVELOP DERMATITIS. DUSTS MAY CAUSE PULMONARY PROBLEMS.
METAL DUSTS CAN IRRITATE EYES & UPPER RESPIRATORY TRACTS. GI
DISTURBANCES IF INGESTED. CHRONI C POISONING FROM ALUMINUM & BRASS
POSSIBLE. FIBERGLASS MAY CAUSE LUNG DISEASE (FIBROSIS).
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS SUCH AS DERMATITIS, RESPIRATORY PROBLEMS, LUNG DISEASE OR
ANY CONDITION THAT MAY BE AGGRAVATED BY NUISANCE DUST OR FIBERS.
======================= First Aid Measures =======================
First Aid:SHOULD NOT BE NECESSARY FROM A PROPER HANDLING OF THIS
FRICTION MATERIAL PRODUCT. SEEK MEDICAL ATTENTION IF SYMPTOMS
DEVELOP. IN CASE OF EYE IRRITATION GENTLY RINSE WITH WATER FOR 15
MINUTES WHILE KEE PING EYELIDS OPEN. SKIN: WASH FREQUENTLY WITH
SOAP AND WATER. INHALATION: REMOVE TO FRESH AIR. INGESTION:
UNLIKELY.
===================== Fire Fighting Measures =====================
Flash Point:NON FLAMMABLE
Extinguishing Media:WATER, (CLASS A, B OR C), FOG OR FOAM. USE WATER
SPRAY TO COOL FIRE EXPOSED CONTAINERS.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND
NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS OPERATED IN THE
POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:FLAMMABLE ONLY IN OXYGEN-RICH ATMOSPHERE.
================== Accidental Release Measures ==================
Spill Release Procedures:DO NOT DRY SWEEP OR USE COMPRESSED AIR. WET
METHOD SHOULD BE USED FOR EXTRACTION OF DUST AND DEBRIS. HIGH
EFFICIENCY PARTICULATE APPARATUS (HEPA) VACUUMS SHOULD BE USED.
Neutralizing Agent:NOT APPLICABLE.
======================Handling and Storage ======================
Handling and Storage Precautions:STORAGE- AVOID CREATING DUST BY
SANDING OR GRINDING THE PRODUCT.
Other Precautions:MONITORING TO DETERMINE DUST AND FIBER LIMITS SHOULD
BE DONE IN ACCORDANCE WITH OSHA RECOMMENDED GUIDELINES. WORK AREAS
SHOULD BE KEPT CLEAN AND FREE FROM AIRBORNE DUST THROUGH ADEQUATE
DUST COLLECTIO N AND PROPER VENTILATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED HIGH EFFICIENCY FIBERS/FUMES
RESPIRATOR WHEN AIRBORNE FIBER CONCENTRATIONS EXCEED THE PEL OR
WHEN MACHINING IS NECESSARY.
Ventilation:LOCAL/GENERAL TO MAINTAIN PEL/TLV. CHECK LOCAL REGULATIONS
FOR EMISSION STANDARDS.
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER, WORK
CLOTHING AND APRON AS REQUIRED. DO NOT WEAR CONTACT LENSES. APPLY
SKIN CREAM.
Work Hygienic Practices:DON'T TAKE PROTECTIVE GEAR/CLOTHING HOME IF
EXPOSED TO DUST. DON'T SHAKE. DON'T EAT IN AREA WHERE DUST PRESENT.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:N1
Spec Gravity:1.8 - 3.5
Solubility in Water:INSOLUBLE
Appearance and Odor:LIGHT TAN TO DARK GREY SOLID - SLIGHT ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:NONE KNOWN
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE
AND FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:ZYTEL NYLON RESINS, 159L NC010
Preparer's Name:D.L. LICZWEK
CAGE:0ERJ7
CAGE:0ERJ7
CAGE:18873
============= Composition/Information on Ingredients =============
Ingred Name:POLYHEXAMETHYLENE DODECANDIAMIDE
CAS:26098-55-5
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:LUBRICANTS
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:STABILIZERS
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SOME GRADES MAY CONTAIN INGS 5, 6, 7, OR 8 PIGMENTS
ENCAPSULATED IN THE POLYMER. NO HAZ ING LISTED @ 0.1% OR MORE
(MFR).
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:BARIUM (SARA III)
CAS:7440-39-3
RTECS #:CQ8370000
Fraction by Wt: <2%
OSHA PEL:0.5 MG/M3
ACGIH TLV:N/K
Ingred Name:COBALT (SARA III)
CAS:7440-48-4
RTECS #:GF8750000
Fraction by Wt: <2%
OSHA PEL:0.05 MG/M3
ACGIH TLV:0.05 MG/M3, DUST
Ingred Name:NICKEL (SARA III)
CAS:7440-02-0
RTECS #:QR5950000
Fraction by Wt: <2%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
Ingred Name:ZINC (SARA III)
CAS:7440-66-6
RTECS #:ZG8600000
Fraction by Wt: <2%
OSHA PEL:N/K
ACGIH TLV:N/K
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INGESTION: NOT A PROBABLE ROUTE
OF EXPOSURE. SKIN: MOLTEN POLYMER CAUSES THERMAL BURNS. EYES:
MECHANICAL IRRITATION ONLY. INHALATION: GRANULES NOT RESPIRABLE.
FUMES FROM OVERHEATING MAY CAUSE S YMPTOMS . CHRONIC EFFECTS: NONE
KNOWN.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE KNOWN.
======================= First Aid Measures =======================
First Aid:INHAL: IF EXPOSED TO FUMES FROM OVERHEATING, MOVE TO FRESH
AIR. CONSULT MD IF SYMPTOMS PERSIST. SKIN: WASH WITH SOAP & PLENTY
OF WATER. EYES: FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES.
CONSULT MDIF SYMPTOMS PERSIST. SKIN: IF MOLTEN POLYMER CONTACTS
SKIN, COOL RAPIDLY WITH COLD WATER. DO NOT ATTEMPT TO PEEL POLYMER
FROM SKIN. OBTAIN MEDICAL ATTENTION FOR THERMAL BURN.
===================== Fire Fighting Measures =====================
Flash Point:752F,400C
Extinguishing Media:WATER, CARBON DIOXIDE, FOAM, DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:LARGE MOLTEN MASSES MAY IGNITE
SPONTANEOUSLY IN AIR. WATER QUENCHING OF SUCH MASSES IS GOOD
PRACTICE.
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP UP TO PREVENT A SLIPPING HAZARD.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:COOL, DRY PLACE. KEEP CONTAINERS
TIGHTLY CLOSED TO PREVENT MOISTURE ABSORPTION AND CONTAMINATION.
Other Precautions:READ SECTION 12, SAFETY, IN "ZYTEL MOLDING GUIDE"
BULLETIN E-97221, BEFORE USING PRODUCT. FACE MASK & PROTECTIVE
CLOTHES RECOMMENDED FOR ABNORMAL PROCESSING PROBLEMS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN . NONE UNDER NORMAL PROCESSING IF
VENTILATION IS ADEQUATE.
Ventilation:LOCAL EXHAUST AT PROCESSING EQUIPMENT TO KEEP PARTICULATE
BELOW 15 MG/M3 (OSHA LIMIT FOR NUISANCE DUSTS).
Other Protective Equipment:LONG SLEEVE COTTON SHIRT & LONG PANTS IF
HANDLING MOLTEN POLYMER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:>406F,>208C
Solubility in Water:INSOLUBLE
Appearance and Odor:GRANULES; NO ODOR.
Percent Volatiles by Volume:1
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS AND OXIDIZING AGENTS.
Stability Condition to Avoid:HEATING ABOVE 340C.
Hazardous Decomposition Products:COMBUSTION PRODS PRIMARILY AMMONIA,
CARBON MONOXIDE, SMALL AMOUNT OF HYDROGEN CYANIDE, ALDEHYDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:LANDFILL OR INCINERATION IN COMPLIANCE WITH
FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:AC-275 ACCELERATOR
Preparer's Name:HENRY SIMMONS
CAGE:1DWR5
CAGE:1DWR5
============= Composition/Information on Ingredients =============
Ingred Name:MANGANESE OXIDE
CAS:1313-13-9
RTECS #:OP0350000
Minumum % Wt:60.
Maxumum % Wt:70.
OSHA PEL:C5 MG/M3
ACGIH TLV:5 MG/M3
Ingred Name:TERPHENYL, HYDROGENATED
CAS:61788-32-7
RTECS #:WZ6535000
Minumum % Wt:20.
Maxumum % Wt:30.
ACGIH TLV:4.9 MG/M3;0.5 PPM
Ingred Name:1,3-DIPHENYLGUANIDINE
CAS:102-06-7
RTECS #:MF0875000
Minumum % Wt:1.
Maxumum % Wt:5.
Ingred Name:TERPHENYL
CAS:26140-60-3
RTECS #:WZ6450000
Minumum % Wt:1.
Maxumum % Wt:5.
OSHA PEL:C9 MG/M3;C1 PPM
ACGIH STEL:C5 MG/M3;C0.53 PPM
Ingred Name:ETHOXYLATED NONYLPHENOL PHOSPHATE
CAS:51811-79-1
Minumum % Wt:1.
Maxumum % Wt:5.
Ingred Name:SODIUM HYDROXIDE
CAS:1310-73-2
RTECS #:WB4900000
Minumum % Wt:1.
Maxumum % Wt:5.
OSHA PEL:2 MG/M3
ACGIH STEL:C2 MG/M3
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:LIVER, KIDNEYS, NERVOUS SYSTEM. BLOOD
AND/OR BLOOD-FORMING ORGANS. LUNGS AND RESPIRATORY SYSTEM.
REPRODUCTIVE SYSTEM (AND REPRODUCTIVE EFFECTS). EYES. SKIN. IMMUNE
SYSTEM, (E.G., ALLERGIC REACTIONS).
Effects of Overexposure:EYE CONTACT: MAY CAUSE MODERATE IRRITATION.
SKIN CONTACT: MAY CAUSE SLIGHT TO MILD IRRITATION,MAY CAUSE
ALLERGIC SKIN REACTIONS AND SENSITIZATION. INHALATION: IRRITATING
TO THE EYES, NOSE, AND RESPI RATORY TRACT. CAN CAUSE DIZZINESS,
HEADACHES, AND INCOORDINATION. INGESTION: IRRITATING TO THE MOUTH,
THROAT, AND STOMACH. MAY CAUSE NAUSEA, VOMITING, PAIN, AND STOMACH
UPSET (E.G., DIARRHEA).
Medical Cond Aggravated by Exposure:LIVER, KIDNEYS, LUNGS AND
RESPIRATORY SYSTEM. SKIN. IMMUNE SYSTEM AND/OR SPECIFIC CHEMICAL
ALLERGIES.
======================= First Aid Measures =======================
First Aid:EYE CONTACT: IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR
AT LEAST 15 MINUTES. GET MEDICAL ATTENTION IF IRRITATION PERSISTS.
SKIN CONTACT: IMMEDIATELY FLUSH WITH WATER. REMOVE CONTAMINATED
CLOTHIN G AND SHOES. GET MEDICAL ATTENTION IF IRRITATION PERSISTS.
PROFESSIONALLY WASH CLOTHING AND SHOES BEFORE RE-USE. INHALATION
(BREATHING): REMOVE TO FRESH AIR. IF SYMPTOMS DEVELOP, SEEK
IMMEDIATE MEDIC AL ATTENTION. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION. INGESTION (SWALLOWING): SEEK MEDICAL ATTENTION:
IMMEDIATELY INDUCE VOMITING, AS DIRECTED BY MEDICAL PERSONNEL.
NEVER GIVE ANYTHING BY MOUT H TO AN UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:=93.3C, 200.F
Extinguishing Media:SMALL FIRES: DRY CHEMICAL, CARBON DIOXIDE, HALON,
WATER SPRAY, OR FOAM. LARGE FIRES: WATER SPRAY, FOG, OR ALCOHOL
FOAM.
Fire Fighting Procedures:FIRE FIGHTERS AND OTHERS WHO MAY BE EXPOSED TO
THE PRODUCTS OF COMBUSTION SHOULD BE EQUIPPED WITH NIOSH-APPROVED
POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA) AND
FULL PROTECTIVE CLOTHIN G.
Unusual Fire/Explosion Hazard:DURING A FIRE, IRRITATING AND HIGHLY
TOXIC GASES MAY BE GENERATED DURING COMBUSTION OR DECOMPOSITION.
================== Accidental Release Measures ==================
Spill Release Procedures:ISOLATE HAZARD AREA. KEEP UNNECESSARY AND
UNPROTECTED PERSONNEL FROM ENTERING. SAFETY STOP DISCHARGE.
CONTAIN MATERIAL, AS NECESSARY, WITH A DIKE OR BARRIER. STOP
MATERIAL FROM CONTAMINATING SOIL, OR FROM ENTERING SEWERS OF
BODIES OF WATER. STOP DISCHARGE, IF SAFE TO DO SO. USE PROPER
PROTECTIVE EQUIPMENT. COVER SPILLS WITH ABSORBENT CLAY OR SAWDUST
AND PLACE IN CLOSED CHEMICAL WASTE CONTAINERS.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, DRY, WELL VENTILATED
AREA, IGNITION SOURCES, AND DIRECT SUNLIGHT. KEEP CONTAINERS
TIGHTLY CLOSED.
Other Precautions:THIS CONTAINER CAN BE HAZARDOUS WHEN EMPTY. FOLLOW
LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED SINCE EMPTY
CONTAINERS MAY RETAIN PRODUCT RESIDUES. DO NOT REUSE EMPTY
CONTAINER WITHOUT PROFESSIONAL CLEANING FOR FOOD, CLOTHING, OR
PRODUCTS FOR HUMAN OR ANIMAL CONSUMPTION OR WHERE SKIN CONTACT CAN
O CCUR.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:AVOID BREATHING VAPOR OR MIST. WEAR
NIOSH/MSHA-APPROVED EQUIPMENT. DETERMINE THE APPROPRIATE TYPE BY
CONSULTING THE RESPIRATOR MANUFACTURER. HIGH AIRBORNE CONCENTRATION
MAY NECESSITATE THE USE OF SELF CONTAINED BREATHING APPARATUS
(SCBA) OR A SUPPLIED AIR RESPIRATOR. RESPIRATORY PROTECTION
PROGRAMS MUST BE IN COMPLIANCE WITH 29 CFR 1910.134
Ventilation:LOCAL EXHAUST VENTILATION WHEN VAPORS, MISTS, OR DUSTS CAN
BE RELEASED IN EXCESS OF ESTABLISHED AIRBORNE EXPOSURE LIMITS
(TLV?S OR PEL?S)
SHIELDS
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING, ESPECIALLY
BEFORE EATING, DRINKING, SMOKING, AND USING RESTROOM FACILITIES.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Vapor Pres:0.1 MMHG
Vapor Density:> AIR
Spec Gravity:2.1
Evaporation Rate & Reference:<1 (BUTYL ACETATE)
Solubility in Water:INSOLUBLE
Appearance and Odor:BLACK PASTE AND DISTANT ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZERS, ACIDS
Stability Condition to Avoid:HIGH CONDITIONS
Hazardous Decomposition Products:SMOKE, SOOT, AND TOXIC/IRRITATING
FUMES (I.E., CARBON DIOXIDE, CARBON MONOXIDE, ETC). FORMALDEHYDE
AND/OR OTHER ALDEHYDES. OXIDES OF SULFUR. HYDROGEN SULFIDE.
=================== Toxicological Information===================
Toxicological Information:MANGANESE OXIDE: EYE, SKIN, AND RESPIRATORY
TRACT. CAN CAUSE LIVER AND KIDNEY INJURY. TERPHENYL, HYDROGENATED:
ORAL LD50 RAT 17,500 MG/KG MOUSE 12,500 MG/KG DERMAL LD50 RABBIT
>2,000 MG/KG 1,3-DIPHENYLQUANIDINE: ORAL RAT 507 MG/KG MOUSE
290 MG/KG TERPHENYL ORAL LD50 RAT 13,200 MG/KG ETHOXYLATED
NONYLPHENOL PHOSPHATE ORAL LD50 RAT 3,630 MG/KG SODIUM HYDROXIDE:
CORROSIVE! CAUSE EYE AND S KIN BURNS. DERMAL LD50 RABBIT 1000
MG/KG.
==================== Disposal Considerations ====================
Waste Disposal Methods:OF THE METHODS OF DISPOSAL CURRENTLY AVAILABLE,
IT IS RECOMMENDED THAT AN ALTERNATIVE BE ACCORDING OR THE FOLLOWING
ORDER OF PREFERENCE. BASED UPON ENVIRONMENTAL ACCEPTABILITY. (1)
RECYCLE OR REWORK,IF FEASIBLE; (2) INCINERATE AT AN AUTHORIZED
FACILITY; OR (3) TREAT AT AN ACCEPTABLE WASTE TREATMENT FACILITY.
===================== Regulatory Information =====================
SARA Title III Information:SECTION 311/312-HAZARD CATEGORIES: IMMEDIATE
AND DELAYED HEALTH HAZARD. SARA SECTION 302 EXTREMELY HAZARDOUS
MAT-NO REGULATED INGREDIENTS SARA SECTION 313 TOXIC CHEMICALS
MANGANESE OXIDE
Federal Regulatory Information:CHEMICAL COMPONENTS THIS PRODUCT ARE ON
THE SECTION 8(B) CHEMICAL SUBSTANCE INVENTORY LIST (40 CFR 710)
State Regulatory Information:STATE RIGHT TO KNOW PENNSYLVANIA-NEW
JERSEY R-T-K MANGANESE OXIDE 1313-13-9 60-70% TERPHENYL,
HYDROGENATED 61788-32-7 20-30% 1,3 ? DIPHENYLQUANIDINE 102-06 1-5%
TERPHENYL 26140-60-3 1-5%ETHOXYL ATED NONYLPHENOL PHOSPHATE
51811-79-1 1-5% SODIUM HYDROXIDE 1310-73-2 1-5% WATER 7732-18-5
1-5% CALIFORNIA ? CALIFORNIA PROPOSITION 65-NO REGULATED
INGREDIENTS
| 1 | gloves_mandatory |
=======================================================
Product ID: DERUSTO RPE SPRAY GRADE, 884 G. ALMOND
Cage: 90300
Box: 277
Proprietary Ind: Y
=======================================================
Contractor Summary
=======================================================
Cage: 90300
Box: 277
=======================================================
Ingredients
=======================================================
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: MAY IRRITATE EYES, SKIN, NOSE & RESP TRACT.
HARMFUL IF INHALED. HARMFUL/FATAL IF SWALLOWED. IF INGESTED, THIS PROD MAY
CAUSE VOMIT, DIARR & DEPRESSED RESPIRATION. ASPIR OF MATL INTO LUNGS DUE
T O VOMIT MAY CAUSE CHEM PNEUM WHICH CAN BE FATAL. INHAL MAY AFFECT BRAIN OR
NERVOUS SYS CAUSING HDCH, (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ: DIZZ OR NAUS. CHRONIC: CNTNS
MATL WHICH APPEARS ON THE NAVY LIST OF OCCUP CHEM REPRO HAZS. SEEK
CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO
& SAFE HNDLG & EXP OS INFO (FP N). RPTS HAVE ASSOC PERM BRAIN &
NERVOUS SYS DMG W/PRLNGD & RPTD OCCUP OVEREXP TO SOLVS. PRLNGD/RPTD
CNTCT W/SKIN CAN CAUSE DEFAT OF SKIN WHICH MAY LEAD TO DERM. OVEREXP OR
MISUSE OF TOLU ENE CAN CAUSE LIVER, KIDNEY & BRAIN DMG AS WELL AS CARDIAC
ABNORMALITIES.
Medical Cond Aggravated By Exposure: NONE KNOWN.
First Aid: EYES: FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
CONTACT MD IMMEDIATELY. SKIN: WASH WITH SOAP AND WATER. INHALATION: REMOVE TO
FRESH AIR. CONTACT MD IMMEDIATELY. INGESTION: DO NOT INDU CE VOMITING.
IMMEDIATELY CONTACT MD OR REGIONAL POISON CONTROL CENTER.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: DIKE SPILL AREA. USE ABSORBENT MATERIAL OR SCRAPE UP
DRIED MATERIAL AND PLACE INTO CONTAINERS.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE OF ACCORDING TO FEDERAL, STATE AND LOCAL
STANDARDS. USE ALL MATERIAL BEFORE DISPOSAL. IF UNABLE TO USE ENTIRE CONTENTS
OF CAN, RELIEVE PRESSURE IN CONTAINER UNTIL IT EQUALS EXTERNAL PRESSURE.
Handling And Storage Precautions: KEEP OUT OF REACH OF CHILDREN. KEEP CNTNRS
TIGHTLY CLSD WHEN NOT IN USE. KEEP CNTNRS FROM EXCESS HEAT & FREEZING. DO
NOT STORE AT TEMPS ABOVE 120F.
Other Precautions: STORE AWAY FROM CAUSTICS AND OXIDIZERS. INTENTIONAL MISUSE
BY DELIBERATELY CONCENTRATING AND INHALING VAPORS MAY BE HARMFUL OR FATAL.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: EXTREM. FLAMM.
Extinguishing Media: FOAM, WATER FOG, CARBON DIOXIDE, DRY CHEMICALS.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT
(FP N). COOL EXPOSED CONTAINERS WITH WATER.
Unusual Fire/Explosion Hazard: CNTNRS MAY EXPLODE IF EXPOSED TO EXTREME HEAT.
ELIM SOURCE OF IGNIT: HEAT, ELEC EQUIP, SPARKS & OPEN FLAMES. DO NOT PUT
IN CNTCT W/OXIDIZING OR CAUSTIC MATLS.
=======================================================
Control Measures
=======================================================
Respiratory Protection: IF 8-HOUR EXPOSURE LIMIT OR VALUE IS EXCEEDED FOR ANY
COMPONENT, USE A NIOSH APPROVED RESPIRATOR. CONSULT YOUR SAFETY EQUIPMENT
SUPPLIER AND THE OSHA REGULATION, 29 CFR 1910.134 FOR RESPIRATOR REQUIRE
MENTS.
Ventilation: PROVIDE SUFFICIENT MECH VENT (LOCAL OR GEN EXHST) TO MAINTAIN
EXPOS BELOW PEL & TLV. VAPS ARE HVR/AIR & WILL COLLECT IN LOW AREAS.
CHECK ALL LOW AREAS (SUPDAT)
Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N).
BARRIER CREAMS MAY BE USED.
Work Hygienic Practices: WASH CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health: USERS OF "L" VERSION SHOULD CONSULT "LR"
VERSION FOR ADDITIONAL INFORMATION (FP N). VENTILATION: (BASEMENTS, SUMPS,
ETC) FOR VAPOR BEFORE ENTERING.
=======================================================
Physical/Chemical Properties
=======================================================
Vapor Density: >1
Spec Gravity: 0.60-0.80 (H*2O=1).
Evaporation Rate & Reference: >1 (N-BUTYL ACETATE=1)
Solubility in Water: NEGLIGIBLE
Appearance and Odor: OPAQUE LIQUID, VARIOUS COLORS; GASOLINE-LIKE ODOR.
Percent Volatiles by Volume: 85-92
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: EXCESSIVE HEAT AND FREEZING.
Materials To Avoid: STRONG OXIDIZERS AND CAUSTICS.
Hazardous Decomposition Products: NORMAL COMBUSTION PRODUCTS, IE CO*X, NO*X.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
Other Information: VOLATILE ORGANIC COMPOUND: 540-623 G/L (80-90%); VOC LESS
EXEMPT SOLVENT: 540-623 G/L (80-90%)
=======================================================
HAZCOM Label
=======================================================
Product ID: DERUSTO RPE SPRAY GRADE, 884 G. ALMOND
Cage: 90300
Company Name: DAP INC.
PO Box: 277
Zipcode: 45401-0277
Label Required IND: Y
Date Of Label Review: 05/07/1997
Status Code: C
Label Date: 05/07/1997
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMMABLE AEROSOL. DO NOT INHALE OR INGEST. ACUTE: MAY
IRRITATE EYES, SKIN, NOSE & RESPIRATORY TRACT. HARMFUL IF INHALED.
HARMFUL OR FATAL IF SWALLOWED. INGESTION MAY CAUSE VOMITING, DIARRHEA &
DEPRES SED RESPIRATION. ASPIRATION INTO LUNGS MAY CAUSE CHEMICAL PNEUMONITIS
WHICH MAY BE FATAL. INHALATION MAY AFFECT BRAIN OR NERVOUS SYSTEM WITH
HEADACHE, DIZZINESS OR NAUSEA. CHRONIC: CONTAINS MATERIAL W HICH APPEARS ON
THE NAVY OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS LIST (FP N). OVEREXPOSURE
TO SOLVENTS HAS BEEN ASSOCIATED WITH PERMANENT BRAIN & NERVOUS SYSTEM
DAMAGE. DEFATTING & DERMATITIS. LIVE R, KIDNEY & BRAIN DAMAGE &
CARDIAC ABNORMALITIES.
=======================================================
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:DRY CLEANING SOLVENT
Preparer's Name:C. A. EISENHARD
CAGE:DO652
CAGE:60777
CAGE:DO652
============= Composition/Information on Ingredients =============
Ingred Name:HYDROTREATED LIGHT PETROLEUM DISTILLATE
CAS:64742-47-8
Fraction by Wt: 93%
Other REC Limits:NONE SPECIFIED
OSHA PEL:NONE ESTABLISHED
ACGIH TLV:NONE ESTABLISHED
Ingred Name:ALKYLBENZENES C10-12
CAS:68515-25-3
Fraction by Wt: 7%
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES/SKIN: IRRITATION. INHALATION:
WILL CAUSE CENTRAL NERVOUS SYSTEM EFFECTS.INGESTION:LOW DEGREE OF
TOXICITY; HOWEVER IT IS AN ASPIRATION HAZARD. DO NOT INDUCE
VOMITING.
Explanation of Carcinogenicity:NONE OF THE COMPOUNDS IN THIS PRODUCT IS
LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN.
Effects of Overexposure:HEADACHE, DIZZINESS, LOSS OF APPETITE, WEAKNESS
AND LOSS OF COORDINATION.
Medical Cond Aggravated by Exposure:NONE REPORTED
======================= First Aid Measures =======================
First Aid:EYES: FLUSH WITH RUNNING WATER FOR 15 MINUTES. SEEK MEDICAL
ATTN. SKIN:WASH WITH SOAP & WATER. REMOVE CONTAMINATED CLOTHING &
LAUNDER BEFORE REUSE. INHALATION: REMOVE TO FRESH AIR. GIVE
ARTIFICIAL RES PIRATION IF NEEDED. INGESTION: PREVENT ASPIRATION.
DO NOT INDUCE VOMITING. GIVE WATER OR MILK TO DRINK. NOTHING BY
MOUTH IF UNCONSCIOUS. GET MEDICAL ATTENTION IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:140F,60C
Lower Limits:1.0
Upper Limits:6.0
Extinguishing Media:USE CARBON DIOXIDE, FOAM, DRY CHEMICAL, OR WATER
FOG.
Fire Fighting Procedures:DO NOT ENTER ANY ENCLOSED SPACE W/O PROTECTIVE
EQUIPMENT. THIS MAY INCLUCDE SCBA TO PROTECT AGAINST NORMAL
PRODUCTS OF COMBUSTION AND/OR OXYGEN DEFICIENCY.
Unusual Fire/Explosion Hazard:LIQUID EVAPORATES & FUMES CAN BURN WITH
EXPLOSIVE FORCE. VAPOR IS HEAVIER THAN AIR & CAN SPREAD & BE
IGNITED BY PILOT LIGHTS, ELECTRICAL EQUIP, THEN FLASH BACK.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. STOP SOURCES
OF LEAKS. CONTAIN LIQUID TO PREVENT CONTAMINATION OF GROUND WATER,
SURFACE WATERS, AND SOIL.
Neutralizing Agent:NO INFORMATION GIVEN ON MSDS BY SUPPLIER
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE OR USE NEAR FLAME, SPARKS
OR HOT SURFACES. USE ONLY IN A WELL VENTILATED AREA. KEEP TIGHTLY
CLOSED. REPLACE CAP OR BUNG.
Other Precautions:'EMPTY' CONTAINERS MAY CONTAIN RESIDUE OR VAPOR.
TREAT THEM WITH THE RESPECT DUE FULL ONES. DO NOT CUT,WELD,ETC. ON
THEM. DO NOT USE PRESSURE TO EMPTY CONTAINER OR EXPLOSION MAY
RESULT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SUPPLIED AIR RESPIRATOR IN POSITIVE PRESSURE
MODE IF VENTILATION IS INADEQUATE.
Ventilation:USE LOCAL OR MECHANICAL VENTILATION.
Other Protective Equipment:IMPERVIOUS CLOTHING
Work Hygienic Practices:EYE WASH STATION AND QUICK DRENCH SHOWER,
Supplemental Safety and Health
MSDS RECEIVED FROM NAVY (FOCAL POINT N). NAVY IDENTIFIED NSN.
================== Physical/Chemical Properties ==================
HCC:F4
NRC/State Lic Num:NONE
Boiling Pt:B.P. Text:365F,185C
Vapor Pres:1 MM
Vapor Density:5.3 AIR=1
Spec Gravity:0.79
Solubility in Water:INSOLUBILE
Appearance and Odor:COLORLESS LIQUID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING MATERIALS.
Stability Condition to Avoid:SUPPLIER LEFT THIS FIELD BLANK.
Hazardous Decomposition Products:NORMAL COMBUSTION FORMS CARBON DIOXIDE
AND WATER VAPOR. INCOMBLETE COMBUSTION CAN PRODUCE CARBON MONOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:PLACE CONTAMINATED MATERIALS IN DISPOSABLE
CONTAINER AND DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS. CONTACT LOCAL ENVIRONMENTAL OR HEALTH
AUTHORITIES FOR APPROVED DISPOSAL OF THIS MATERIAL.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:DO-IT BEST LATEX INTERIOR FINISH VELVET, W56A708 NEUTRAL BAS
Resp. Party Other MSDS Num.:LI/HW1
CAGE:54636
CAGE:54636
============= Composition/Information on Ingredients =============
Ingred Name:2-(2-BUTOXYETHOXY)ETHANOL. VP: 0.1
CAS:112-34-5
RTECS #:KJ9100000
= Wt:1.
Ingred Name:ETHYLENE GLYCOL. VP: 0.1 (<5% WHEN TINTED)
CAS:107-21-1
RTECS #:KW2975000
< Wt:5.
OSHA PEL:50 PPM
ACGIH STEL:C127 MG/M3;C50 PPM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:SILICA, CRYSTALLINE-QUARTZ
CAS:14808-60-7
RTECS #:VV7330000
Minumum % Wt:12.
Maxumum % Wt:13.
OSHA PEL:0.1 MG/MG
ACGIH TLV:0.1 MG/M3
Ingred Name:CALCIUM CARBONATE
CAS:471-34-1
RTECS #:FF9335000
Minumum % Wt:8.
Maxumum % Wt:11.
OSHA PEL:10 MG/M3
ACGIH TLV:15 MG/M3
Ingred Name:TITANIUM DIOXIDE
CAS:13463-67-7
RTECS #:XR2275000
Minumum % Wt:0.
Maxumum % Wt:9.
OSHA PEL:15 MG/M3
ACGIH TLV:10 MG/M3
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:46.4
Maxumum % Wt:55.3
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EXPOSURE MAY BE BY INHAL AND/OR
SKIN/EYE CONT, DEPENDING ON CNDTNS OF USE. TO MINIMIZE EXPOS,
FOLLOW RECS FOR PROPER USE, VENT, & PERSONAL PROT EQUIP. ACUTE:
IRRITATION OF EYES, SKIN & UPPER RESPIRATO RY SYSTEM. IN CONFINED
AREA VAPORS IN HIGH CONCENTRATION MAY CAUSE HEADACHE, NAUSEA OR
DIZZINESS. CHRONIC: CRYSTALLINE SILICA (QUARTZ, CRISTOBALITE) IS
LISTED BY IARC & NTP. LONG TERM EXPOSURE TO HIGH LEVELS OF SILICA
DUST, WHICH CAN OCCUR ONLY WHEN SANDING OR ABRADING DRY FILM, MAY
CAUSE LUNG DAMAGE (SILICOSIS) AND POSSIBLY CANCER. ETHYLENE GLYCOL
IS CONSIDERED ANIMAL TERATOGEN. IT HAS BEEN (EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ: IARC
MONOGRAPHS, VOL 68, 1997: GROUP 1. NTP 7TH ANNUAL REPORT ON
CARCINOGENS. 1994: ANTICIPATED TO BE CARCINOGEN.
Effects of Overexposure:HLTH HAZS: SHOWN TO CAUSE BIRTH DEFECTS IN RATS
& MICE AT HIGH DOSES WHEN GIVEN IN DRINKING WATER/BY GAVAGE. THERE
IS NO EVIDENCE TO INDICATE IT CAUSES BIRTH DEFECTS IN HUMANS.
PROLONGED OVEREXPOSURE TO SOLVENT INGREDS IN SECTION II MAY CAUSE
ADVERSE EFFECTS TO LIVER & URINARY SYSTEMS. RATS EXPOSED TO
TITANIUM DIOXIDE DUST AT 250 MG/M3 DEVELOPED LUNG CANCER. HOWEVER,
SUCH EXPOSURE LEVELS ARE NOT A TTAINABLE IN THE WORKPLACE.
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
======================= First Aid Measures =======================
First Aid:INHAL: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING.
KEEP WARM & QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP
AND WATER. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE.
EYES: FLUS H WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
GET MEDICAL ATTENTION. INGEST: GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG
NOZZLES ARE PREFERABLE. WATER MAY BE USED TO COOL CLSD CNTNRS TO
PVNT PRESSURE BUILD -UP & POSSIBLE AUTOIGNITION OR EXPLOSION WHEN
EXPOSED TO EXTREME HEAT.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO THE
BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT. HMIS (NFPA)
RATING(HEALTH-FLAMMABILITY-REACTIVITY): 2-0-0.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
======================Handling and Storage ======================
Handling and Storage Precautions:USE ONLY W/ADEQ VENT. AVOID BRTHG VAP
& SPRAY MIST. AVOID CONT W/SKIN & EYES. WASH HANDS AFTER USING.
THESE COATINGS MAY CNTN MATLS CLASSIFIED AS NUISANCE PARTICULATES
(LISTED "AS DUST" IN SECTION II) WHICH MAY BE PRESENT ! HAZ LEVELS
ONLY DURING SANDING/ABRADING OF DRIED FILM.
Other Precautions:IF NO SPECIFIC DUSTS ARE LISTED IN SECTION II,
APPLICABLE LIMITS FOR NUISANCE DUSTS ARE ACGIH TLV 10 MG/M3 (TOTAL
DUST), OSHA PEL 15 MG/M3 (TOTAL DUST), 5 MG/M3 (RESPIRABLE
FRACTION. KEEP CNTNR CLSD W HEN NOT IN USE. TRANSFER ONLY TO APPRVD
CNTNRS W/COMPLETE & APPROP LBLG. DO NOT TAKE INTERNALLY. (SU PDAT)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW
APPLICABLE LIMITS BY VENT, WEAR PROPERLY FITTED ORGANIC
VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH FOR PROTECTION
AGAINST MATLS IN SECTION II. WHEN SANDING OR ABRADING DRIED FILM.
WEAR DUST/MIST RESPIRATOR APPROVED BY NIOSH FOR DUST WHICH MAY BE
GENERATED FROM THIS PRODUCT, (SUPDAT)
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOSURE TO MATLS
IN SECTION II IS MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS.
(SUPDAT)
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER
MEETING ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
VOC - TOTAL (LBS/GAL.): 0.14-0.26. VOC - LESS WATER (LBS/GAL):
0.39-0.64. OTHER PREC: KEEP OUT OF REACH OF CHILDREN. RESP PROT:
UNDERLYING PAINT, OR THE ABRASIVE. VENT: REFER TO OSHA STANDARDS
1910.94 , 1919.107, 1910.108.
================== Physical/Chemical Properties ==================
Boiling Pt:>100.C, 212.F
B.P. Text:212-488F
Vapor Pres:SEE INGREDIENTS
Vapor Density:HVR/AIR
Spec Gravity:1.12-1.55
pH:8.2-9.0
Evaporation Rate & Reference:SLOWER THAN ETHER
Percent Volatiles by Volume:57-81
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE FROM THESE PRODS IS NOT HAZ AS DEFINED
UNDER RCRA 40 CFR 261. INCINERATE IN APPRVD FACILITY. DO NOT
INCINERATE CLOSED CONTAINER. DISPOSE OF IN ACCORDANCE WITH FEDERAL,
STATE, AND LOCAL REGULATIO NS REGARDING POLLUTION.
===================== Regulatory Information =====================
SARA Title III Information:22-(2-BUTOXYETHOXY)-ETHANOL AND ETHYLENE
GLYCOL ARE SUBJECT TO REPORTING REQUIREMENTS OF THE SUPERFUND
AMENDMENT AND REAUTHORIZATION ACT (SARA) SECTION 313, 40 CFR
372.85C.
State Regulatory Information:CALIFORNIA PROPOSITION 65: THESE PRODUCTS
CONTAIN A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:ABCOV-L
CAGE:DSIIN
CAGE:DSIIN
============= Composition/Information on Ingredients =============
Ingred Name:FORMIC ACID
CAS:64-18-6
RTECS #:LQ4900000
Other REC Limits:5 PPM IN AIR
OSHA PEL:5 PPM (AIR)
ACGIH TLV:9.4 MG/CUM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:AMMONIUM BIFLUORIDE
CAS:1341-49-7
RTECS #:BQ9200000
OSHA PEL:2.5 MG/CUM
ACGIH TLV:2.5 MG/CUM
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:NONE CURRENTLY KNOWN EXCEPT FOR
REDDENING OF SKIN.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:SKIN: REDDENING ON EXTENSIVE CONTACT.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH WITH WATER FOR 15 MINS, LIFTING UPPER & LOWER
EYELIDS OCCASIONALLY. SEEK MEDICAL ATTENTION. SKIN: IMMEDIATELY
FLUSH WITH WATER. SEEK MEDICAL ATTENTION. INHALATION: REMOVE TO
FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. SEEK
MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. GIVE LOTS OF
WATER, MILK OR MAGNESIA TO DRINK. SEEK MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:NON-FLAMMABLE
Extinguishing Media:USE METHODS APPROPRIATE FOR SURROUNDINGS.
Fire Fighting Procedures:WEAR SELF-CONTAINED RESPIRATORS & PROTECTIVE
COTHING.
Unusual Fire/Explosion Hazard:TOXIC FUMES UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:SMALL SPILLS/DRIPS: MOP OR WIPE UP WITH WET
RAG. DISPOSE IN DOT-APPROVED WASTE CONTAINER. LARGE SPILL: CONTAIN
BY DIKING WITH WITH SOIL OR OTHER NON-COMBUSTIBLE ABSORBENT
MATERIAL. PUMP INTO DOT-APPR OVED CONTAINER.
Neutralizing Agent:LIME
======================Handling and Storage ======================
Handling and Storage Precautions:NORMAL CARE. STORE AT ROOM
TEMPERATURE, DO NOT EXCEED 120F. AVOID EXTENSIVE SKIN CONTACT.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF AIRBORNE CONCENTRATION IS HIGH, USE AN
APPROPRIATE RESPIRATOR.
Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST TO KEEP FUME LEVELS
AS LOW AS POSSIBLE.
Other Protective Equipment:STANDARD WORKING APPAREL IS RECOMMENDED.
Work Hygienic Practices:WASH HANDS BEFORE EATING.
Supplemental Safety and Health
NONE
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:100C/212F
Vapor Density:1.6
Spec Gravity:1.05
Solubility in Water:COMPLETE
Appearance and Odor:LIGHT BLUE CLEAR LIQUID; SLIGHT VINEGAR SMELL.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALKALINE OR BASIC COMPOUNDS.
Stability Condition to Avoid:TEMPERATURES ABOVE 120F
Hazardous Decomposition Products:AMMONIA, HYDROGEN FLUORIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, &
FEDERAL REGULATIONS.
| 0 | gloves_not_mandatory |
===================== Product Identification =====================
Product ID:BLUE SHOWER CLEANER/DEGREASER 1657 AEROSOL
Preparer's Name:B. RIFFEL
CAGE:DO989
CAGE:DO989
CAGE:54700
============= Composition/Information on Ingredients =============
Ingred Name:ETHANE, 1,1,2-TRICHLORO-1,2,2-TRIFLUORO-;
(1,1,2-TRICHLOROTRIFLUOROETHANE) (FREON TF)) (SARA 313)
CAS:76-13-1
RTECS #:KJ4000000
Fraction by Wt: 30-40%
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM; 1250 STEL
Ozone Depleting Chemical:1
Ingred Name:METHANE, TRICHLOROFLUORO-; (TRICHLOROFLUOROMETHANE)
(CFC-11) (SARA 313) (CERCLA)
CAS:75-69-4
RTECS #:PB6125000
Fraction by Wt: 40-50%
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM, C
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ozone Depleting Chemical:1
Ingred Name:CARBON DIOXIDE
CAS:124-38-9
RTECS #:FF6400000
Fraction by Wt: <2%
OSHA PEL:5000 PPM
ACGIH TLV:5000 PPM; 30000 STEL
Ingred Name:ISOPROPYL ALCOHOL; (ISOPROPANOL) (SARA 313)
CAS:67-63-0
RTECS #:NT8050000
Fraction by Wt: 2-5%
OSHA PEL:400 PPM
ACGIH TLV:400 PPM; 500 STEL
Ingred Name:METHANE, CHLORODIFLUORO-; (CHLORODIFLUOROMETHANE) (SARA
313) (CERCLA)
CAS:75-45-6
RTECS #:PA6390000
Fraction by Wt: 15-20%
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM
Ozone Depleting Chemical:2
Ingred Name:VOLATILE ORGANIC COMPOUND: 26.27 G/L OF NONEXEMPT VOC
RTECS #:9999999VO
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:CHLOROFLUOROCARBON (CFC) MATLS HAVE
PRDCED SENSIT OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD
HAVE SIMILAR EFT IN HUMANS. ADRENOMIMETICS (IE, EPINEPHRINE) MAY BE
CONTRA-INDICATED EXCEPT FOR LI FE-SUSTAINING USES IN HUMANS
ACUTELY/CHRONICALLY EXPOS TO CFCS . INHAL: MAJOR ROUTE OF EXPOS.
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: VAP IS HVR/AIR & CAN CAUSE
SUFFOCATION BY REDUCING AVAIL OXYGEN FOR BRTHG. BRTHG HIGH CONCS OF
VAP MAY CAUSE LT HEAD, GIDD, SHORTNESS OF BREATH, CONFUSN, UNCON OR
EVEN DEATH. EYES: LIQ CAN C AUSE SLIGHT, TEMPORARY IRRIT W/SLIGHT
TEMPORARY CORNEAL INJURY. VAPS CAN IRRIT. SKIN: NOT CORR/IRRIT;
HOWEVER, (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE TO FRESH AIR. IF BRTHG HAS STOPPED, ADMINISTER
ARTF RESP. SEEK MED ATTN. EYES; FLUSH EYES FOR AT LEAST 15 MINUTES
W/CLEAR WATER. IF IRRITATION PERSISTS, SEEK MED ATTN. SKIN: WASH
W/SOAP & WATER. INGEST: DO NOT INDUCE VOMITING! GIVE 2 GLASSES OF
WATER & IMMEDIATELY SEEK MED ATTN. NOTE: ADRENALIN & OTHER SIMILAR
CARD STIMULANTS SHOULD NOT BE USED TO TREAT EFTS OF OVEREXPOSURE TO
PROD.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:NONE
Extinguishing Media:WATER, FOAM, DRY CHEMICAL, CARBON DIOXIDE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE FLUORIDES, CHLORIDES AND PHOSGENE . AEROSOL CANS MAY ERUPT
WITH FORCE AT TEMPERATURES ABOVE 120F.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. VENTILATE AREA WELL AND AVOID
BREATHNG VAPORS. VAPOR CONCENTRATION WILL BE HIGHEST ALONG FLOOR
AND IN LOW LYING AREAS. PICK UP LIQUID ON SUITABLE ABSORBENT AND
STORE IN SEALED CONTAINER S.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP AEROSOL CANS IN COOL PLACE OUT OF
DIRECT SUNLIGHT. KEEP THIS & ALL CHEMICALS OUT OF REACH OF
CHILDREN. THIS PRODUCT FOR INDUSTRIAL USE ONLY.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR
UV RADIATION MAY CAUSE THE FORMATION OF CHLORIDES, FLUORIDES OR
PHOSGENE .
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF LEVELS EXCEED TLVS, INCREASED VENTILATION OR
NIOSH/MSHA APPROVED ORGANIC VAPOR MASK REQUIRED.
Ventilation:DO NOT USE IN CLOSED SPACE. VENTILATION REQUIRED.
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EFTS OF OVEREXP: RPTD/PRLNG EXPOS CAN CAUSE DEFAT OF SKIN. INGEST:
SINGLE DOSE TOX IS LOW TO MOD. IF VOMIT OCCURS LIQ CAN BE ASPIR
INTO LUNGS WHICH CAN CAUSE CHEM PNEUM & SYSTEMIC EFTS. HUMAN
PSYCHOTR OPIC, GI & CNS EFTS POSS.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:117F,47C
Vapor Density:>1
Solubility in Water:0
Appearance and Odor:CLEAR, WATER-WHITE MOBILE LIQUID WITH SLIGHT
ETHEREAL ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
REACTIVE ALKALI METALS, STRONG ACIDS AND BASES.
Stability Condition to Avoid:CONTACT WITH OPEN FLAME, HEAT.
Hazardous Decomposition Products:FLUORIDES . HYDROGEN CHLORIDE,
PHOSGENE, CHLORINE, CARBON DIOXIDE AND CARBON MONOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:MATERIAL MAY BE DISPOSED OF BY A LICENSED
RECLAIMER OR INCINERATION FACILITY. CONSULT LOCAL, STATE AND
FEDERAL DISPOSAL AUTHORITIES FOR APPROVED PROCEDURES. DO NOT
INCINERATE OR DESTROY AEROSOL CANS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:ERIBATE
CAGE:0DT34
CAGE:0DT34
============= Composition/Information on Ingredients =============
Ingred Name:SODIUM ERYTHORBATE; (SODIUM ISO-ASCORBATE)
CAS:6381-77-7
Other REC Limits:15 MG/M3 RESP (MFR)
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: LONG-TERM INHALATION OF
EXCESSIVE DUST MAY CAUSE DELAYED LUNG INJURY. MAY CAUSE RESPIRATORY
IRRITATION IN SUSCEPTIBLE INDIVIDUALS. SKIN: MAY CAUSE IRRITATION
FOR SUSCEPTIBLE INDIVIDUALS. E YES: MAY CAUSE IRRITATION.
INGESTION: MAY CAUSE TOXIC EFFECTS IF LARGE AMOUNTS ARE SWALLOWED.
NO EFTS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HEALTH HAZARDS: KNOWN FOR RARE ACCIDENTAL
SWALLOWING. OTHER: IS AN APPROVED FOOD ADDITIVE.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHALATION: GET MEDICAL ATTENTION IF ADVERSE EFFECTS OCCUR.
SKIN: WASH THOROUGHLY WITH SOAP AND WATER. EYES: FLUSH WITH WATER
FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION IF EFFECTS PERSIST.
INGESTI ON: GET MEDICAL ATTENTION IF ADVERSE EFFECTS OCCUR.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER, CARBON DIOXIDE, FOAM, HALOGEN.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:DUST IN AIR CAN BE AN EXPLOSION HAZARD.
================== Accidental Release Measures ==================
Spill Release Procedures:COLLECT AS MUCH AS POSSIBLE FOR USE OR
DISPOSAL. FLUSH REMAINDER INTO NORMAL DRAINAGE OR INTO GROUND WITH
COPIOUS AMOUNTS OF WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP AT COOL TEMPERATURES. AVOID HIGH
HUMIDITY. KEEP CONTAINERS TIGHTLY CLOSED. PREVENT CONTAMINATION OF
THIS FOOD ADDITIVE PRODUCT.
Other Precautions:AVOID GENERATING DUST. IF SUBSTANTIAL DUST IN AIR,
TAKE MEASURES TO REMOVE SOURCES OF IGNITION TO PREVENT POSSIBLE
DUST COMBUSTION OR EXPLOSION. PROMPTLY VENTILATE AREA. ADOPT
PROCEDURES TO MINIMIZE D UST GENERATION. AVOID SWALLOWING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR NIOSH/MSHA APPROVED DUST RESPIRATOR WHEN
VISIBLE DUST IS PRESENT, AND/OR IF IRRITATION OCCURS.
Ventilation:GENERAL VENTILATION SUFFICIENT TO KEEP AIRBORNE
CONCENTRATION BELOW CURRENT EXPOSURE LIMITS .
Other Protective Equipment:WEAR PROTECTIVE CLOTHING AS NEEDED.
Work Hygienic Practices:NONE LISTED BY MANUFACTURER.
Supplemental Safety and Health
NONE LISTED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
HCC:N1
Spec Gravity:1.2 (H2O=1)
Solubility in Water:1 GR/7ML
Appearance and Odor:WHITE GRANULAR POWDER, NO ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
==================== Disposal Considerations ====================
Waste Disposal Methods:IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE AND
LOCAL REGULATIONS. NORMALLY CAN BE FLUSHED DOWN SEWERS. NOT
HAZARDOUS WASTE UNDER RCRA CRITERIA.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:101 3176;LIQUID DEVELOPER SYSTEM CLEANER;CONC;KAN 427808
CAGE:19139
CAGE:19139
CAGE:5K871
============= Composition/Information on Ingredients =============
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 65-70%
Other REC Limits:NONE RECOMMENDED
Ingred Name:SODIUM BICHROMATE (SARA III)
CAS:10588-01-9
RTECS #:HX7700000
Fraction by Wt: 15-20%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:C 0.1 MG (CRO3)/M3
ACGIH TLV:0.05 MG(CR)/M3; 9394
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Ingred Name:SULFURIC ACID (SARA III)
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: 17%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3; 9394
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:TLV SODIUM DICHROMATE IS 0.05MG/KG TWA
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYES:MAY CAUSE IRRITATION AND SEVERE
BURNS.SKIN:MAY CAUSE IRRITATION AND SEVERE BURNS.INGEST:MAY CAUSE
GI TRACT IRRITATION AND CAUSE KIDNEY DAMAGE.INHAL:MAY CAUSE
RESPIRATORY IRRITATION.CHRONIC:HEXAVA LENT CHROMIUM COMOUNDS ARE
SUSPECT CARCINOGENS.
Explanation of Carcinogenicity:HEXAVALENT CHROMIUM COMPOUNDS ARE
SUSPECT CARCINOGENS.
Effects of Overexposure:SKIN:ALLERGIC SKIN REACTIONS.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING KIDNEY
AILMENTS MAY BE AT INCREASED RISK FROM EXPOSURE.
======================= First Aid Measures =======================
First Aid:SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH WATER.EYES:FLUSH
WITH WATER FOR 15 MINUTES.INHAL:REMOVE TO FRESH AIR.GIVE OXYGEN OR
ARTIFICIAL RESPIRATION IF NEEDED.INGEST:DO NOT INDUCE VOMITING.GET
PROMP T QUALIFIED MEDICAL ATTENTION.IF CONSCIOUS,GIVE A GLASS OF
WATER.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:FIRE CONDITIONS MAY EVOLVE TOXIC
FUMES.DRIED PRODUCT CAN ACT AS A STRONG OXIDIZER.
================== Accidental Release Measures ==================
Spill Release Procedures:SOAK UP WITH NON-COMBUSTIBLE INERT
ADSORBANT(EG.CLAY);PLACE COLLECTED MATERIEL IN AN APPROPRIATE
CONTAINER FOR DISPOSAL;CLEAN SPILL AREA TO REMOVE
SLIPPERINESS.CLEAN SPILL AREA THOROUGHLY.
Neutralizing Agent:NOT REPORTED.
======================Handling and Storage ======================
Handling and Storage Precautions:USE WITH ADEQUATE VENTILATION.KEEP
CONTAINERS CLOSED.KEEP AWAY FROM BASES AND COMBUSTIBLE MATERIALS.
Other Precautions:FOLLOW LABEL DIRECTIONS.AVOID BREATHING VAPORS.AVOID
SKIN AND EYE CONTACT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHERE ENVIRONMENTAL CONTROLS ARE LACKING OR IN
ENCLOSED SPACES USE EITHER A SELF-CONTAINED BREATHING APPARATUS OR
A NIOSH/MSHA APPROVED RESPIRATOR FOR ACID GAS,DEPENDING ON THE
AIRBORN CONCENTRATION.
Ventilation:LOCAL VENTILATION AT THE WORKSITE;MECHANICAL(GENERAL)
VENTILATION TO MAINTAIN TLV/PEL.
Other Protective Equipment:PROTECTIVE CLOTHING,AS NEEDED.PROVIDE A
LOCAL EYE WASH STATION AND SAFETY SHOWER.
Work Hygienic Practices:WASH HANDS.SEPERATE WORK CLOTHES FROM STREET
CLOTHES.LAUNDER WORK CLOTHES BEFORE REUSE.KEEP FOOD OUT OF THE WORK
AREA.
Supplemental Safety and Health
KEY1;C1.
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:>212F,>100C
Vapor Pres:18
Vapor Density:0.6
Spec Gravity:1.262
pH:1.0
Solubility in Water:COMPLETE
Appearance and Odor:LIQUID;ORANGE;SLIGHT ACRID
Percent Volatiles by Volume:65
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
REDUCING AGENTS,BASES,COMBUSTIBLE MATERIALS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:SULFUR DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND
LOCAL REGULATIONS.HMIS SUGGESTS TO EVALUATE TCLP AND CONSIDER RCRA
CODE D007(CHROMIUM).
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:TIRE SHINE,765-2584
CAGE:DO833
CAGE:70842
CAGE:DO833
CAGE:0NBN5
============= Composition/Information on Ingredients =============
Ingred Name:XYLENES (O-,M-,P- ISOMERS) (SARA 313) (CERCLA)
CAS:1330-20-7
RTECS #:ZE2100000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM
ACGIH TLV:100 PPM/150STEL;9596
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:ACETONE (SARA 313) (CERCLA)
CAS:67-64-1
RTECS #:AL3150000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1000 PPM
ACGIH TLV:750PPM/1000STEL;9596
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:PERCHLOROETHYLENE (TETRACHLOROETHYLENE) (SARA 313) (CERCLA)
CAS:127-18-4
RTECS #:KX3850000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM, Z-2
ACGIH TLV:25PPM/100STEL,A3; 96
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:PROPANE
CAS:74-98-6
RTECS #:TX2275000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1000 PPM
ACGIH TLV:ASPHYXIANT; 9596
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, CNS, LUNGS.
ACUTE- EXCESSIVE INHALATION IS HARMFUL. VAPORS IN HIGH
CONCENTRATIONS ARE ANESTHETIC. MAY CAUSE IRRITATION OF EYES, SKIN &
UPPER RESPIRATORY TRACT. INGESTION UNLI KELY. CHRONIC- MAY CAUSE
SKIN DEFATTING.
Explanation of Carcinogenicity:CONTAINS PERCHLOROETHYLENE.
Effects of Overexposure:IRRITATION, HEADACHE, DIFFICULTY IN BREATHING,
NAUSEA, DIZZINESS, LOSS OF CONSCIOUSNESS, SKIN DEFATTING, BLURRED
VISION
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS, EYE PROBLEMS OR IMPAIRED CNS OR RESPIRATORY FUNCTION MAY
BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT.
======================= First Aid Measures =======================
First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:REMOVE TO FRESH
AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES:FLUSH WITH WATER FOR 15
MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER.
INGESTION:DO N OT INDUCE VOMITING. GET MEDICAL ATTENTION
IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:FLAMMABL AEROSOL
Extinguishing Media:CARBON DIOXIDE, FOAM, SAND/DRY CHEMICAL. AVOID
SPREADING ANY BURNING LIQUID WITH WATER SPRAY. WATER MAY BE
INEFFECTIVE.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND
NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. COOL
FIRE-EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:SPRAY CANS UNDER PRESSURE. EXTREMELY
FLAMMABLE. EXPLOSION HAZARD EXISTS WHEN SPRAY CANS HEATED. DO NOT
ENTER SPRAY CAN STORAGE AREA IF FIRE PRESENT.
================== Accidental Release Measures ==================
Spill Release Procedures:LEAKING CONTAINERS SHOULD BE PLACED OUTDOORS,
IN AN OPEN CONTAINER, AWAY FROM SOURCES OF IGNITION. ALLOW PRESSURE
TO DISSIPATE. VENTILATE AREA. ABSORB LIQUID WITH NON-FLAMMABLE
ABSORBENT MATERIALS AND PLACE IN CONTAINER FOR DISPOSAL.
Neutralizing Agent:NOT RELEVANT
======================Handling and Storage ======================
Handling and Storage Precautions:STORE SPRAY CANS IN COOL, WELL
VENTILATED AREAS AWAY FROM SOURCES OF IGNITION AND SUNLIGHT. DO NOT
STORE ABOVE 120F.
Other Precautions:EXTREMELY FLAMMABLE. "EMPTY" CONTAINERS RETAIN
RESIDUE AND CAN BE DANGEROUS. FOLLOW ALL LABEL INSTRUCTIONS. AVOID
REPEATED/PROLONGED SKIN CONTACT. KEEP OUT OF REACH OF CHILDREN. DO
NOT BREATHE VAPORS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF TLV IS EXCEEDED, WEAR NIOSH-APPROVED ORGANIC
VAPOR RESPIRATOR OR AIR-PURIFYING RESPIRATOR. IN EMERGENCY, WEAR A
NIOSH-APPROVED POSITIVE-PRESSURE SELF-CONTAINED BREATHING
APPARATUS.
Ventilation:MECHANICAL (GENERAL AND/OR LOCAL EXHAUST, EXPLOSION-PROOF)
VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Other Protective Equipment:EYE WASH STATION & SAFETY SHOWERS SHOULD BE
AVAILABLE IN THE IMMEDIATE VICINITY OF ANY POTENTIAL EXPOSURE.
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. WASH AFTER HANDLING AND BEFORE EATING OR
DRINKING.
Supplemental Safety and Health
EXTREMELY FLAMMABLE. CONTENTS UNDER PRESSURE. CONTAINS GAS SIMILAR TO
PROPANE AND FLAMMABLE LIQUID. DO NOT USE IN CONFINED AREA OR AREA
WITH LITTLE AIR MOVEMENT. EMPLOY MEANS TO PREVENT VAPOR BUILDUP.
================== Physical/Chemical Properties ==================
HCC:V3
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:<0F PROPELL
Vapor Pres:3604
Vapor Density:>1
Solubility in Water:NONE
Appearance and Odor:AEROSOL SPRAY - CHLORINATED SOLVENT ODOR
Percent Volatiles by Volume:95
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES, DIRECT SUNLIGHT,
TEMPERATURES ABOVE 120F
Hazardous Decomposition Products:HYDROGEN CHLORIDE, CARBON MONOXIDE,
CARBON DIOXIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS. DO NOT PUNCTURE, INCINERATE SPRAY CANS.
DISPOSE OF EMPTY CANS IN TRASH PICK-UP. DO NOT PLACE IN HOME TRASH
COMPACTOR.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:0523 PASSAGE II
Preparer's Name:R REEVES
CAGE:GO368
CAGE:GO368
CAGE:64796
============= Composition/Information on Ingredients =============
Ingred Name:ISOPROPANOL (ISOPROPYL ALCOHOL), 2-PROPANOL, DIMETHYL
CARBINOL(IARC CANCER REVIEW GROUP 3) *96-3*
CAS:67-63-0
RTECS #:NT8050000
Other REC Limits:400 PPM
OSHA PEL:400 PPM
ACGIH TLV:400 PPM
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:DIRECT CONTACT W/EYES MAY CAUSE
IRRITATION. DIRECT CONTACT W/EYES FOR PROLONGED PERIOD OF TIME MAY
CAUSE MARKED IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR & TREAT SYMPTOMATICALLY.
SKIN: WASH OFF W/PLENTY OF SOAP & WATER. EYES: IMMEDIATELY FLUSH
W/PLENTY OF WATER FOR 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL
CASES.
===================== Fire Fighting Measures =====================
Flash Point:NONFLAMMABLE
Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED RESPIRATOR WHEN
FIGHTING FIRES IN CONFINED AREAS.
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH DOWN DRAIN.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE BETWEEN 32-120F. STORE AT
MODERATE TEMPS.
Other Precautions:KEEP OUT OF REACH OF CHILDREN. READ ENTIRE LABEL
BEFORE USING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT REQUIRED.
Ventilation:GENERAL: ADEQUATE.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:210F
Vapor Pres:20
Vapor Density:0.6
Spec Gravity:1.06
pH:7
Evaporation Rate & Reference:(BU AC =1): 0.1
Solubility in Water:COMPLETE
Appearance and Odor:BROWN TO AMBER, TURBID, SEMI-VISCOUS W/LEMON ODOR.
Percent Volatiles by Volume:98
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, BLEACH, DISINFECTANTS, OTHER HARSH DRAIN CHEMICALS.
Stability Condition to Avoid:TEMPS <32F/>120F.
Hazardous Decomposition Products:OXIDES OF CARBON.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:NYE SYNTHETIC OIL 192A
CAGE:DO759
CAGE:98354
CAGE:DO759
============= Composition/Information on Ingredients =============
Ingred Name:NON-HAZARDOUS FOR INGREDIENTS
Fraction by Wt: 100%
===================== Hazards Identification =====================
Effects of Overexposure:SKIN, EYES, RESPIRATORY IRRITAITON.
======================= First Aid Measures =======================
First Aid:SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/WATER & REFER TO
PHYSICIAN FOR TREATMENT. INHALATION: MOVE TO FRESH AIR & REFER TO
PHYSICIAN FOR TREATMENT.
===================== Fire Fighting Measures =====================
Flash Point:445F
Extinguishing Media:CO2, FOAM, DRY CHEMICAL, WATER SPRAY
Fire Fighting Procedures:AVOID SMOKE INHALATION. WATER SPRAY MAY CAUSE
FROTHING.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE FREE LIQUID (SAND, EARTH, SAWDUST) TO
SPILL AREA. AFTER REMOVING ABSORBENT, WH WALKING SURFACES WITH SOAP
AND WATER TO REDUCE SLIPPING HAZARD.
======================Handling and Storage ======================
Handling and Storage Precautions:ORDINARY CARE IN HANDLING CHEMICALS.
AVOID CONTAMINATION OF CIGARETTES/TOBACCO PRODUCTS. WASH NDS BEFORE
SMOKING.
Other Precautions:USERS SHOULD BE ALERT TO THE POSSIBILITY THAT VERY
SMALL PERCENTAGES OF THE POPULATION MAY DISPLAY UNEXPECTED SKIN
REACTIONSO OTHERWISE INNOCUOUS INDUSTRIAL CHEMICALS & RAW
MATERIALS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED UNLESS MISTS, SMOKE/VAPORS ARE
PRODUCED AT HIGH TEMPS.
Ventilation:NONE REQUIRED
Other Protective Equipment:IF REQUIRED TO AVOID PROLONGED OR REPEATED
SKIN CONTACT.
Supplemental Safety and Health
MSDS DATE: 1/23/81. WT/GAL: 7 LBS.
================== Physical/Chemical Properties ==================
Vapor Density:>AIR
Evaporation Rate & Reference:SLOWR THAN ETHER
Percent Volatiles by Volume:NONE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING MATERIALS, HEAT, FLAME
Stability Condition to Avoid:PYROLYSIS
Hazardous Decomposition Products:BURNING MAY PRODUCE CO & SMALL AMTS OF
OTHER TOXIC FUMES.
Conditions to Avoid Polymerization:CONTAMINATION OF CIGARETTES OR OTHER
TOBACCO PRODUCTS.
==================== Disposal Considerations ====================
Waste Disposal Methods:MANY STATES CLASSIFY WASTE LUBES AS 'HAZARDOUS',
WHICH MEANS DISPOSAL ONLY BY A LICENSED FIRM. CONSULT LOCAL, STATE
& FEDERAL REGULATIONS APPLICABLE FOR YOUR AREA.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:KRYLON TEN 4 SPRAY (AEROSOL)
CAGE:9P972
CAGE:86142
CAGE:9P972
============= Composition/Information on Ingredients =============
Ingred Name:OTHER PREC: UV RADIATION MAY CAUSE FORMATION OF HCL AND/OR
PHOSGENE .
RTECS #:9999999ZZ
Ingred Name:VENT: TO KEEP AIR CONTAM CONC LEVELS BELOW ACCEPTABLE
CRITERIA. THE FOLLOWING MAY BE USED: LOC EXHST, ENCLSD (ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7: SYS, PROCESS ISOLATION, REMOTE CTL IN COMBINATION
W/PROT EQUIP & PRUDENT WORK PRACTICES. MFR RECOM YOU (ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8: CONSULT W/EXPERTS.
RTECS #:9999999ZZ
Ingred Name:ETHANE, 1,1,1-TRICHLORO-; (1,1,1-TRICHLOROETHANE)
CAS:71-55-6
RTECS #:KJ2975000
Fraction by Wt: 33%
OSHA PEL:350 PPM;450 PPM STEL
ACGIH TLV:350 PPM;450 PPM STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ozone Depleting Chemical:1
Ingred Name:PROPANE
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: 18%
OSHA PEL:1000 PPM
ACGIH TLV:SIMPLE ASPHYXIANT
Ingred Name:KEROSENE (PETROLEUM), HYDROTREATED; (HYDROTREATED LIGHT
DISTILLATE (PETROLEUM))
CAS:64742-47-8
RTECS #:OA5504000
Fraction by Wt: 5%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SUPP DATA: EPINEPHRINE) MAY BE CONTRAINDICATED EXCEPT FOR
LIFE-SUSTAINING USES IN HUMANS ACUTELY OR CHRONICALLY (ING 5)
RTECS #:9999999ZZ
Ingred Name:ING 4: EXPOSED TO CHLOROCARBONS .
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: SKIN ABSORP/INGEST: NOT
EXPECTED TO BE HARMFUL UNDER NORM CNDTNS OF USE. INHAL: MAY BE
HARMFUL. LIQ/VAPS CAN CAUSE IRRIT OF NOSE, THROAT & LUNGS.
SKIN/EYES: CAUSES IRRIT. ING 1: OVEREXP MAY CAU SE LIVER & KIDNEY
DAM BASED ON TEST W/LAB ANIMALS. CAN CAUSE CNS DEPRESS. SIGNS &
SYMPS MAY INCL HDCH, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:DIZZ, NAUS, VOMIT, UNCON & EVEN DEATH.
ING 2 MATL IS A SIMPLE ASPHYXIANT. SIGNS & SYMPS OF OVEREXP INCL
CYANOSIS, RESP DISTRESS, HDCH, DIZZ, DROW, UNCON & EVEN ASPHY. CAN
CAUSE CNS DEPRESS. I NG 3: OVEREXP MAY CAUSE KIDNEY DAM BASED ON
TEST W/LAB ANIMALS. CAN CAUSE CNS DEPRESS. SIGNS & SYMPS MAY
INCL(SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST: DO NOT INDUCE VOMIT. CALL A PHYS IMMED. INHAL: REMOVE
TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP, PREF MOUTH-TO-MOUTH. IF
BRTHG IS DFCLT, GIVE OXYGEN. CALL A PHYS. SKIN: FLUSH W/ WATER. IF
IRR IT PERSISTS, CALL A PHYS. EYE: IMMED FLUSH W/PLENTY OF WATER
FOR @ LST 15 MIN. EYELIDS SHOULD BE HELD APART DURING IRRIGATION TO
ENSURE WATER CONT W/ENTIRE SURF OF EYES & LIDS. CALL A PHYS.
===================== Fire Fighting Measures =====================
Extinguishing Media:IN CASE OF FIRE, USE DRY CHEM, FOAM/CARBON DIOXIDE.
Fire Fighting Procedures:NIOSH/MSHA APPROVED PRESS DEMAND SCBA AND FULL
PROTECTIVE EQUIPMENT . WATER MAY BE INEFFECTIVE, BUT SHOULD BE USED
TO KEEP FIRE-EXPOSED CONTAINERS COOL.
Unusual Fire/Explosion Hazard:EXTREMELY FLAMM. CONTENTS UNDER PRESS.
EXPOS TO HIGH TEMP MAY CAUSE BURST. AVOID RADIA, STOVES, DIRECT
SUNLIGHT/OTHER HEAT SOURCE. DO NOT PUNCTURE/ (SUPP DATA)
================== Accidental Release Measures ==================
Spill Release Procedures:ELIM ALL IGNITION SOURCES. SOAK UP WITH
ABSORBENT MATERIAL AND REMOVE TO A CHEMICAL DISPOSAL AREA. PREVENT
ENTRY INTO NATURAL BODIES OF WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE AT TEMPS OVER 120F. AVOID
PRLNGD/RPTD CONT W/EYES/SKIN/CLTHG. AVOID BRTHG VAP/MIST. USE
ADEQUATE VENTILATION.
Other Precautions:HANDLE I/A/W GOOD INDUST HYGIENE & SFTY PRACTICES.
THESE PRACTICES INCL AVOIDING UNNEC EXPOS & REMOVAL OF MATL FROM
EYES, SKIN & CLTHG. NO SMOKING IN AREA OF USE. DO NOT USE IN GEN
VICIN OF ARC WELD,OPEN FLAMES/HOT SURF. HEAT &/OR (ING 6)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHERE AIR CONTAM CAN EXCEED ACCEPTABLE CRITERIA,
USE NIOSH/MSHA APPRVD RESP PROT EQUIP. RESP SHOULD BE SELECTED
BASED ON FORM & CONC OF CONTAM IN AIR I/A/W OSHA 29 CFR
1910.134/OTHER APPLIC STD/ GUIDE LINES.
Ventilation:IF AIRBORNE CONTAM ARE GENERATED WHEN MATL IS HEATED/HNDLD,
SUFFICIENT VENT IN VOL & PATTERN SHOULD BE PROVIDED(ING 7)
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EXPLO HAZ: INCIN CONTR. DO NOT SPRAY NEAR OPEN FLAME. THERMAL DECOMP
PROD MAY INCL HCL & PHOSGENE . EFTS OF OVEREXP: HDCH, DIZZ, NAUS,
VOMIT, UNCON & EVEN ASPHY. CHLOROCARBON MATLS HAVE PRDCD SE NSIT OF
MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIMILAR EFT
IN HUMANS. ADRENOMIMETICS (E.G., (ING 4)
================== Physical/Chemical Properties ==================
Vapor Pres:50PSIG
Vapor Density:HVR/AIR
Spec Gravity:LTR/WATER
Evaporation Rate & Reference:FASTER THAN BUTYL ACETATE
Solubility in Water:SLIGHT
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:88
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE. HCL,
PHOSGENE .
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF ACCORDING TO LOCAL, STATE, AND
FEDERAL REQUIREMENTS. EMPTY CONTR: MAY CNTN EXPLOS VAPS. DO NOT
CUT, PUNCT/WED ON/ NEARBY. INCINERATE WILL CAUSE CONTAINER TO BURST
VIOLENTLY.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:PR-1432-G, PART B
Kit Part:Y
Preparer's Name:JESLINE SAMSON
CAGE:DO563
CAGE:83574
CAGE:DO563
============= Composition/Information on Ingredients =============
Ingred Name:MAGNESIUM CHROMATE
CAS:13423-62-5
Fraction by Wt: <5%
Other REC Limits:NONE SPECIFIED
OSHA PEL:0.5 MG/M3
ACGIH TLV:0.05 MG/M3
Ingred Name:PHENOL POLYMER WITH FORMALDEHYDE (PHENOLIC RESIN)
CAS:9003-35-4
Fraction by Wt: <5%
Other REC Limits:NONE SPECIFIED
Ingred Name:4,4-ISOPROPYLIDENDIPHENOL EPICHLOROHYDRIN RESIN (EPOXY
RESIN)
CAS:25068-38-6
Fraction by Wt: <5%
Other REC Limits:NONE SPECIFIED
Ingred Name:TOLUENE (SARA III)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 20%
Other REC Limits:NONE SPECIFIED
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: 10%
Other REC Limits:NONE SPECIFIED
OSHA PEL:200 PPM/300 STEL
ACGIH TLV:200 PPM/300STEL 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:VOC. G/L (MIXED): 385
RTECS #:9999999VO
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:SKIN: ALLERGIC SKIN RASH IN SENSITIZED
PERSONS. PROLONGED EXPOSURE TO HEXAVALENT CHROMIUM COMPOUNDS OVER
THE PEL MAY CAUSE PAINLESS PENETRATING ULCERS OF THE SKIN. INHALE:
POSSIBLE LIVER & KIDNEY DAMA GE. MAY CAUSE PENETRATING ULCERS OF
MUCOUS MEMBRANES OF THE NOSE & PERFORATION OF CARTILAGINOUS NASAL
SEPTUM.
Explanation of Carcinogenicity:PROPOSITION 65 INCLUDES ALL HEXAVALENT
CHROMIUM COMPOUNDS
Effects of Overexposure:EYES: IRRITATION. SKIN: LOCAL IRRITATION. SKIN
LOCAL IRRITATION. INHALATION: IRRITATION TO NOSE & THROAT,
HEADACHE, FATIGUE, CONFUSION, DIZZINESS, DROWSINESS, NUMBNESS &
UNCONSCIOUSNESS. INGESTION:MAY CAUSE NAUSEA, VOMITING, LIVER &
KIDNEYDAMAGE.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH WITH LUKE WARM WATER FOR 15 MINUTES, CONSULT
PHYSICIAN. SKIN: WASH WITH SOAP & WATER. IF SYMPTOMS PERSIST,
CONSULT A PHYSICIAN. INHALATION: REMOVE TO FRESH AIR. IF SYMPTOMS
ARE PRESENT CON SULT MEDICAL ATTENTION. & INGESTION: CONSULT A
PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:23 F/-5 C
Lower Limits:1.8
Upper Limits:10.0
Extinguishing Media:CO2, DRY CHEMCIAL, FOAM, WATER FOG
Fire Fighting Procedures:USE AIR SUPPLIED RESPIRATOR. USE WATER TO COOL
HEAT EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:HIGH TEMPERATURES MAY CAUSE PRESSURE
BUILD-UP IN CLOSED CONTAINER
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL IGNITION SOURCES. WEAR AIR-SUPPLIED
RESPIRATOR FOR MAJOR UNVENTILATED SPILL. COVER WITH ABSORBANT.
SCOOP INTO CONTAINERS. CLEAN-UP RESIDUE WITH 1,1,1-TRICHLOROETHANE.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID INGESTION.
Other Precautions:THIS PRODUCT CONTAINS A TOXIC CHEMICAL OR CHEMICALS
SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III
OF THE SUPERFUND AMENDMENTS & REAUTHORIZATION ACT OF 1986 & 40 CFR
PART 372.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHEN SPRAYING, APPLYING IN CONFINED AREA OR
OTHER CIRCUMSTANCES LIKELY TO PRODUCE AIRBORNE LEVELS OF SOLVENT IN
EXCESS OF PEL, USE AN ORGANIC VAPOR CARTRIDGE RESPIRATOR OR
AIR-SUPPLIED RESPIRATOR.
Ventilation:GENERAL VENTILATION TO MAINTAIN VAPORS BELOW PEL.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING & BEFORE SMOKING
OR EATING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Spec Gravity:1.29
Solubility in Water:MODERATE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products:OXIDES OF CARBON, SO2, TRACES OF H2S,
CHROMIUM COMPOUNDS
==================== Disposal Considerations ====================
Waste Disposal Methods:EPA WASTE NO. D-001 & D-007. DISPOSE OF SPILLAGE
IN COMPLIANCE WITH FEDERAL & STATE REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:SILVER GEL
CAGE:9Z634
CAGE:9Z634
============= Composition/Information on Ingredients =============
Ingred Name:SILVER(I) NITRATE(1:1) (4% BY WT SILVER)
CAS:7761-88-8
RTECS #:VW4725000
Fraction by Wt: 6.5%
OSHA PEL:0.15 MG/M3
ACGIH TLV:0.15 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:SILICA GEL
CAS:63231-67-4
RTECS #:VV7340000
Fraction by Wt: 93.5%
OSHA PEL:6 MG/M3
ACGIH TLV:10 MG/M3
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHAL: DUSTS, MISTS &AEROSOLS ARE
IRRITATING TO MUC MEMB. CAN PRDCE PIGMENTATION OF MUC MEMB
(ARGYRIA). SKIN:PRDCES LOC PIGMENTATION. EYES:CORR. CAN PRDCE BURNS
TO CORNEA & PIGMENTATION OF CONJ. CND TN NOT REVERSIBLE AFTER 7
DAYS. INGEST:CORR. PRDCES PIGMENTATION OF MUC MEMB.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH WITH WATER, SEEK MED ADVICE. SKIN: WASH WITH SOAP
AND WATER. INGEST: DO NOT ATTEMPT TO MAKE VICTIM VOMIT. SEEK
MEDICAL ATTENTION IMMED. INHAL: REMOVE FROM AREA.
===================== Fire Fighting Measures =====================
Extinguishing Media:NONFLAMMABLE. MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:SILVER NITRATE IS AN OXIDIZER.
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP/VACUUM UP SPILL. PLACE SPILLED MATERIAL
IN METAL SAFETY CAN.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINERS TIGHTLY CLOSED AND
STORE IN DRY AREA TO PROTECT QUALITY. PRODUCT CONTAINS SILVER
CORROSIVE MATERIAL.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR IN
POORLY VENTILATED AREAS AND WHERE DUSTY CONDITIONS PREVAIL.
Ventilation:LOCAL EXHAUST VENTILATION SYSTEM.
Other Protective Equipment:EMERGENCY EYE BATH AND DELUGE SHOWER .
Work Hygienic Practices:WASH HANDS AND FACE AFTER PROLONGED USE.
Supplemental Safety and Health
EYE PROT: FULL LENGTH FACESHIELD .
================== Physical/Chemical Properties ==================
HCC:D1
Vapor Density:4.4
Spec Gravity:<2.5(WATER=1)
Evaporation Rate & Reference:0(BUTYL ACETATE=1)
Appearance and Odor:DRY WHITE GRANULES, NO ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
RECOMMEND AVOID PYROPHORIC MATERIAL.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:NOT DETERMINED.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF ACCORDING TO FEDERAL, STATE AND LOCAL
REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:GRAM SAFRANIN
Resp. Party Other MSDS Num.:3332
CAGE:04487
CAGE:04487
============= Composition/Information on Ingredients =============
Ingred Name:METHYL ALCOHOL (METHANOL) (SARA 313) (CERCLA)
CAS:67-56-1
RTECS #:PC1400000
= Wt:1.
Other REC Limits:NONE RECOMMENDED
OSHA PEL:S, 200 PPM
ACGIH TLV:S,200PPM/250STEL; 96
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ETHYL ALCOHOL (ETHANOL)
CAS:64-17-5
RTECS #:KQ6300000
= Wt:19.
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM; 9596
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:CONTACT MAY CAUSE EYE IRRITATION.
PROLONGED OR REPEATED CONTACT CAUSES SKIN IRRITATION. INHALATION
CAUSE IRRITATION & MAY BE HARMFUL. INGESTION MAY BE HARMFUL.
CHRONIC: EXPOSURE TO ETHANOL HAS BEEN LI NKED TO REPRODUCTIVE
DISORDERS & TUMOR FORMATION. METHANOL TARGET ORGANS: EYES AND
KIDNEYS. REPRODUCTIVE EFFECTS: MAY CAUSE BIRTH DEFECTS. TARGET
ORGANS: REDUCED WEIGHT GAIN. CENTRAL NERVOUS SYSTEM, M
USCULOSKELETAL SYSTEM, DEVELOPMENTAL ABNORMALITIES.
Explanation of Carcinogenicity:TUMORIGENIC BY RTEC STANDARDS; IARC
INADEQUATE EVIDENCE. TARGET ORGANS: LIVER, GASTROINTESTINAL TUMORS,
BLOOD, LYMPHOMAS.
Effects of Overexposure:EYES-IRRITATION. SKIN-IRRITATION.
INHALED-IRRITATION; MAY BE HARMFUL. INGESTED-HARMFUL.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES-RINSE WITH WATER & SEEK MEDICAL ADVICE. SKIN-WASH
IMMEDIATELY WITH PLENTY OF WATER. REMOVE TO FRESH AIR. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING DIFFICULT,
GIVE OXYGEN. SEEK M EDICAL ADVICE. INGESTED-SEEK MEDICAL ADVICE
IMMEDIATELY AND SHOW CONTAINER.
===================== Fire Fighting Measures =====================
Flash Point:=38.9C, 102.F
Lower Limits:6.5
Upper Limits:22
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, ALCOHOL FOAM, OR
WATER FOG.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND
FULL FACE-PIECE SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:NO UNUSUAL HAZARDS UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
WITH DAMP SPONGE OR MOP, RINSE DOWN DRAIN WITH PLENTY OF WATER.
LARGE SPILL: ELIMINATE ALL SOURCES OF IGNITION. WHILE WEARING
SUITABLE PROTECTIVE EQUIPME NT, SOAK UP & PLACE IN A CONTAINER FOR
DISPOSAL.
Neutralizing Agent:NO DATA PROVIDED BY RESPONSIBLE PARTY.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY PLACE.
Other Precautions:NO DATA PROVIDED BY RESPONSIBLE PARTY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE A CHEMICAL FUME HOOD TO CONTROL MIST.
Other Protective Equipment:BODY-COVERING CLOTHING TO PREVENT CONTACT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING, DRINKING OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
NO DATA PROVIDED BY RESPONSIBLE PARTY.
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:174F,79C
Spec Gravity:0.975
Evaporation Rate & Reference:NOT AVAILABLE
Solubility in Water:COMPLETE
Appearance and Odor:RED SOLUTION.
Percent Volatiles by Volume:20
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:KEEP AWAY FROM IGNITION SOURCES.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
HYDROGEN CHLORIDE, OXIDES OF NITROGEN.
Conditions to Avoid Polymerization:THIS PRODUCT IS STABLE AND HAZARDOUS
POLYMERIZATION WILL NOT OCCUR.
=================== Toxicological Information===================
Toxicological Information:THE TOXICILOGICAL & ECOLOGICAL EFFECTS HAVE
NOT BEEN THOROUGHLY INVESTIGATED.
===================== Ecological Information =====================
Ecological:THE TOXICILOGICAL & ECOLOGICAL EFFECTS HAVE NOT BEEN
THOROUGHLY INVESTIGATED.
==================== Disposal Considerations ====================
Waste Disposal Methods:THIS PRODUCT IS NOT CONSIDERED A RCRA HAZARDOUS
WASTE (PER MFR MSDS). FOLLOW LOCAL, STATE AND FEDERAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:THIS IS NOT A HAZARDOUS MATERIAL FOR ANY
TRANSPORTATION PURPOSE (NOTE: DLA-HMIS STAFF DISAGREES WITH THIS
ASSESSEMENT SINCE FLASH POINT IS LESS THAN 141F).
===================== Regulatory Information =====================
SARA Title III Information:SARA 311/312: THIS PRODUCT MAY BE SUBJECT TO
REPORTING. SARA 313: METHANOL IS SUBJECT TO REPORTING.
Federal Regulatory Information:TSCA: THIS PRODUCT IS EXEMPT UNDER TSCA.
CERCLA: THIS PRODUCT CONTAINS METHANOL WHICH HAS A REPORTING
QUANTITY (RQ) OF 5000 LBS.
State Regulatory Information:NO DATA PROVIDED BY RESPONSIBLE PARTY.
======================= Other Information =======================
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:30142 502.2 CALIBRATION MIX #1
CAGE:0JL17
CAGE:0JL17
============= Composition/Information on Ingredients =============
Ingred Name:METHANOL (METHYL ALCOHOL), COLUMBIAN SPIRITS *96-2*
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: 98.8%
Other REC Limits:200 PPM
OSHA PEL:200 PPM
ACGIH TLV:200 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:DICHLORODIFLUOROMETHANE, FREON 12
CAS:75-71-8
RTECS #:PA8200000
Fraction by Wt: 0.2%
Other REC Limits:1000 PPM
OSHA PEL:1000 PPM
ACGIH TLV:4950 MG/CUM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ozone Depleting Chemical:1
Ingred Name:VINYL CHLORIDE (CHLOROETHYLENE) (HUMAN CARCINOGEN BY NTP &
IARC GROUP 1, ACGIH CONFIRMED CARCINOGEN, HUMAN) *96-2*
CAS:75-01-4
RTECS #:KU9625000
Fraction by Wt: 0.2%
OSHA PEL:1 PPM
ACGIH TLV:13 MG/CUM (A1)
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:ETHYL CHLORIDE, CHLOROETHANE
CAS:75-00-3
RTECS #:KH7525000
Fraction by Wt: 0.2%
Other REC Limits:2600 MG/CUM
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:METHYL CHLORIDE (IARC CARCINOGEN - GROUP 3) *96-2*
CAS:74-87-3
RTECS #:PA6300000
Fraction by Wt: 0.2%
Other REC Limits:50 PPM
OSHA PEL:50 PPM
ACGIH TLV:103 MG/CUM
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:METHYL BROMIDE (SUPSPECTED ANIMAL CARCINOGEN BY
IARC, GROUP 3)*96-2*
CAS:74-83-9
RTECS #:PA4900000
Fraction by Wt: 0.2%
Other REC Limits:5 PPM (SKIN)
OSHA PEL:5 PPM
ACGIH TLV:19 MG/CUM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:FLUOROTRICHLOROMETHANE, FREON 11, TRICHLOROFLUOROMETHANE,
TRICHLOROMONOFLUOROMETHANE
CAS:75-69-4
RTECS #:PB6125000
Fraction by Wt: 0.2%
Other REC Limits:1000 PPM MSHA
OSHA PEL:1000 PPM
ACGIH TLV:C 5600 MG/CUM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ozone Depleting Chemical:1
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION: EXPOSURE CAN CAUSE DEATH
AT HIGH CONCENTRATIONS. EYES: CAN CAUSE MODERATE BURNING. SKIN:
EXTENSIVE, REPEATED/PROLONGED CONTACT CAN CAUSE BURNING. INGESTION:
CAUSES BURNING OF THE GI TRACT & TOXIC EFFECTS.
METHANOL-INGESTION: CAN CAUSE DEATH.
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:DROWSINESS, INTOXICATION, HEADACHE, VISUAL
DISTURBANCE, BLINDNESS, COUGHING, SHORTNESS OF BREATH, COLLAPSE,
BURNING, WATERING, SWELLING, REDNESS, ITCHING, BLISTERS, FATIGUE,
NAUSEA, DELAYED VISUAL BLU RRING, SHALLOW RESPIRATION, CYANOSIS,
COMA, HYPOTENSION, DILATED PUPILS.
Medical Cond Aggravated by Exposure:DERMATITIS, DISEASES OF EYES,
LIVER, KIDNEYS, LUNGS & CARDIOVASCULAR SYSTEM.
======================= First Aid Measures =======================
First Aid:EYES: WASH W/LARGE VOLUME OF WATER FOR 15 MINS. SKIN:
IMMEDIATELY WASH W/SOAP & WATER. CONTINUE RINSING W/LARGE VOLUME OF
WATER FOR 15 MINS. INHALATION: REMOVE TO FRESH AIR. HAVE TRAINED
PERSON GIVE O XYGEN/CPR IF NEEDED. INGESTION: NEVER GIVE ANYTHING
BY MOUTH TO A UNCONSCIOUS VICTIM/HAVING CONVULSIONS. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:60.8F
Lower Limits:6
Upper Limits:36.5
Extinguishing Media:DRY CHEMICAL, CO2, ALCOHOL FOAM, WATER MIST/FOG.
Fire Fighting Procedures:WEAR SCBA & PROTECTIVE CLOTHING. KEEP
CONTAINERS COOL W/WATER SPRAY. MAY BURN W/AN INVISIBLE FLAME.
Unusual Fire/Explosion Hazard:HEAT MAY BUILD PRESSURE & RUPTURE CLOSED
STORAGE CONTAINERS. MIXTURES W/WATER AS LOW AS 21% ARE FLAMMABLE,
CAN CORRODE CERTAIN METALS & GENERATE HYDROGEN GAS.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PERSONAL PROTECTIVE EQUIPMENT. PROTECT
FROM IGNITION. ABSORB ON PAPER, VERMICULITE/OTHER ABSORBENT.
COLLECT & STORE IN CLOSED CONTAINER FOR DISPOSAL.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED CONTAINER.
PROTECT FROM EXTREME TEMPS & DIRECT SUNLIGHT. HANDLE W/THE UTMOST
CARE. STORE AT -30.4F IN EXPLOSION PROOF FREEZER
Other Precautions:AVOID ALL INHALATION & CONTACT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOLLOW NIOSH & EQUIPMENT MANUFACTURERS
RECOMMENDATIONS TO DETERMINE APPROPRIATE RESPIRATOR.
Ventilation:GENERAL & LOCAL EXHAUST MEETING OSHA REQUIREMENTS.
Other Protective Equipment:PROTECTIVE CLOTHING MEETING LABORATORY
SAFETY REQUIREMENTS.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. REMOVE CONTACT LENSES IF PRESENT.
Supplemental Safety and Health
WARNING: CONTAINS TRICHLOROFLUOROMETHANE, DICHLORODIFLUORMETHANE &
BROMOMETHANE, SUBSTANCES WHICH HARM HUMAN HEALTH & ENVIRONMENT BY
DESTROYING OZONE IN THE UPPER ATMOSPHERE.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:149F
Vapor Pres:97
Solubility in Water:MISCIBLE
Appearance and Odor:COLORLESS/ALCOHOL ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS & REACTIVE METALS, INCOMPLETE COMBUSTION.
Stability Condition to Avoid:HEAT, SPARKS, IGNITION SOURCES, EXTREME
TEMPS, DIRECT SUNLIGHT.
Hazardous Decomposition Products:COMBUSTION: CO & OTHER TOXIC VAPORS,
FORMALDEHYDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE AT AN APPROVED FACILITY IAW/FEDERAL,
STATE & LOCAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:R-12
Preparer's Name:DGSC-VBA/HMIS
CAGE:02LX8
CAGE:02LX8
============= Composition/Information on Ingredients =============
Ingred Name:DICHLORODIFLUOROMETHANE (SARA 313) (CERCLA)
CAS:75-71-8
RTECS #:PA8200000
Fraction by Wt: 100%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM; 9495
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ozone Depleting Chemical:1
===================== Hazards Identification =====================
LD50 LC50 Mixture:TLV 1000 PPM
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:CARDIOVASCULAR &
PERIPHERAL NERVOUS SYSTEMS. ACUTE- IF INHALED IN CONCENTRATIONS
ABOVE 1000 PPM MAY CAUSE IRRITATION, NARCOSIS & ASPHYXIATION. MAY
CAUSE FROSTBITE IF EYES OR SKIN WAS EXP OSED TO LIQUID OR SPRAY.
INGESTION IS UNLIKELY DUE TO EXISTANCE AS A GAS AT ROOM
TEMPERATURES. CHRONIC- UNKNOWN.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYE AND/OR SKIN FROSTBITE, NARCOSIS,
ASPHYXIATION, RESPIRATORY TRACT IRRITATION, DIZZINESS, TREMORS,
UNCONSCIOUSNESS, CARDIAC ARREST
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH CARDIAC ARRHYTHMIA
OR RESPIRATORY DISORDERS MAY BE AT INCREASED RISK IN SEVERE
EXPOSURES.
======================= First Aid Measures =======================
First Aid:GET MEDICAL ATTENTION IN ALL CASES. EYE/SKIN:FLUSH WITH WATER
FOR 15 MINUTES. HOLD EYELIDS OPEN. TREAT FOR FROSTBITE, IF NEEDED.
INHALED:REMOVE TO FRESH AIR & PROVIDE OXYGEN/CPR IF NEEDED.
ORAL:NOT APOTENTIAL ROUTE OF EXPOSURE; GET MEDICAL ATTENTION IF
NECESSARY.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL
FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED
CYLINDERS.
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS. SEE 1990 EMERGENCY RESPONSE
GUIDEBOOK, DOT P 5800.5, GUIDE NO 12.
Unusual Fire/Explosion Hazard:MAY FORM CORROSIVE AND TOXIC HYDROGEN
FLUORIDE, HYDROGEN CHLORIDE AND/OR PHOSGENE ABOVE 600C (1112F).
CYLINDERS MAY RUPTURE.
================== Accidental Release Measures ==================
Spill Release Procedures:KEEP UPWIND. VENTILATE ENCLOSED SPACES UNTIL
GAS IS DISPERSSED. DO NOT SMOKE OR OPERATE INTERNAL COMBUSTION
ENGINES IN IMMEDIATE VICINITY. IF 5000 LBS (RQ) OR MORE IS
RELEASED, NOTIFY THE NATIONAL RES PONSE CENTER AT 800-424-8802.
Neutralizing Agent:NOT RELEVANT
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN WELL-VENTILATED, DRY, COOL
(BELOW 125F) PLACE AWAY FROM OPEN FLAMES AND INCOMPATIBLE
MATERIALS. KEEP OUT OF REACH OF CHILDREN.
Other Precautions:AVOID BREATHING VAPORS. AVOID EYE OR SKIN CONTACT.
WASH WITH SOAP AND WATER AFTER HANDLING AND BEFORE EATING OR
DRINKING. USE WITH ADEQUATE VENTILATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NORMALLY REQUIRED. IF TLV EXCEEDED, WEAR
NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS OR SUPPLIED-AIR
RESPIRATOR, OPERATED IN POSITIVE PRESSURE MODE.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV
REQUIREMENTS.
Other Protective Equipment:EYEBATH, SAFETY SHOWER, PROTECTIVE CLOTHING
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
Supplemental Safety and Health
THIS MSDS WAS PREPARED BY THE PROFESSIONALS OF DGSC-VBA/HMIS WITHOUT
ANY WARRANTY. IT IS THE USER'S RESPONSIBILITY TO GATHER INFORMATION
AND USE THE MATERIAL PROPERLY TO PROTECT EMPLOYEES AND ENVIRONM
ENT. OTHER TRADE NAMES: HALON 122, PROPELLANT 12, FREON 12,
REFRIGERANT 12. CONVERSION FACTOR: 1 PPM = 5.03 MG/M3.
================== Physical/Chemical Properties ==================
HCC:G3
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:-22F,-30C
Melt/Freeze Pt:M.P/F.P Text:-252F,-158C
Decomp Temp:Decomp Text:>1112F,>600
Vapor Density:4.2
Spec Gravity:1.29
Viscosity:NOT RELEVANT
Evaporation Rate & Reference:GAS
Solubility in Water:INSOLUBLE
Appearance and Odor:COLORLESS LIQUEFIED GAS - FAINT ETHEREAL ODOR
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CHEMICALLY ACTIVE METALS SUCH AS SODIUM, POTASSIUM, CALCIUM, POWDERED
ALUMINUM, ZINC AND MAGNESIUM
Stability Condition to Avoid:OPEN FLAME, EXTREMELY HOT/GLOWING METAL
SURFACES, HIGH TEMPERATURES
Hazardous Decomposition Products:MAY FORM HYDROGEN FLUORIDE, HYDROGEN
CHLORIDE AND/OR PHOSGENE ABOVE 600C (1112F).
==================== Disposal Considerations ====================
Waste Disposal Methods:FOR DISCHARGE OR DISPOSING OF MATERIAL, CONSULT
LOCAL, STATE AND FEDERAL AUTHORITIES. DO NOT WENT TO ATMOSPHERE.
RECYLCE PRODUCT.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:WEEDAR BRAND 64 BROADLEAF HERBICIDE
CAGE:9Z675
CAGE:9Z675
============= Composition/Information on Ingredients =============
Ingred Name:ACETIC ACID (2, 4-DICHLOROPHENOXY) COMPOUND WITH
N-METHYLMETHANAMINE (1:1) 2, -4 D, DIMEHYLAMINE SALT
CAS:2008-39-1
RTECS #:AG8400000
Fraction by Wt: 46.8%
Other REC Limits:* 2, 4-FREE ACID
OSHA PEL:10 MG/M3 *
ACGIH TLV:10 MG/M3 *
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 RATS: 1150 MG/KG *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:UNKNOWN IARC:YES
Health Hazards Acute and Chronic:INGEST: HARMFUL. MAY BE FATAL IF
ABSORBED THRU SKIN. INHALATION: MAY BE HARMFUL, CAUSE IRRIT TO RESP
TRACT. EYE: IRREVERSIBLE EYE DAMAGE, SEEN AS CORNEAL OPACITY.
REPEATED OVEREXPOS MAY CAUSE LIVER, K IDNEY, GASTROINTESTINAL &
MUSCULAR EFFECTS. RARE CASES OF PERIPHERAL NERVE DAMAGE HAVE BEEN
REPORTED.
Explanation of Carcinogenicity:PHENOXYACETIC ACID HERBICIDES ARE LISTED
AS CLASS 2B CARCINOGEN.
Effects of Overexposure:SWALLOWING, SKIN ABSORPTION & INHALATION:
NAUSEA, MYTONIA, MUSCLE WEAKNESS AND FALL IN BLOOD PRESSURE.
SWALLOWING: VOMITING, ABDOMINAL PAIN. EYE: VAPORS OR SPRAYS (MISTS)
ARE IRRITATING TO EYES. *D ERMAL RABBITS: 1530 MG/KG. SKIN
EFFECTSRABBITS: MINIMAL IRRITATION. EYE EFFECTS RABBITS: SEVERE
IRRIT.
Medical Cond Aggravated by Exposure:SKIN IRRITATION MAY BE AGGRAVATED
IN PERSON WITH EXISTING SKIN LESIONS. BREATHING OF VAPOR, DUST OR
SPRAYS (MISTS) MAY AGGRAVATE ASTHMA AND INFLAMMATORY OR FIBROTIC
PULMONARY DISEASE.
======================= First Aid Measures =======================
First Aid:REMOVE FROM EXPOS. INGEST: IF CONSCIOUS/ALERT GIVE 2-3 GLASS
WATER/MILK. INDUCE VOMITING (FINGER BACK OF THROAT/IPECAC--1
TBLSPOON. IF NO VOMIT IN 20 MIN, 1 TBLSPOON MORE).
UNCONSCIOUS--DON'T INDUCE V OMIT. CALL DR. SKIN: WASH SKIN W/SOAP
&WTR, REMOVING CONTAM CLOTH & SHOES. INHAL: REMOVE TO FRESH AIR.
NOT BREATHING--ARTIF RESP. ADMIN OXYGEN IF NEEDED. CALL DR. EYES:
FLUSH W/WATER 15 MIN. CALL DR.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Autoignition Temp:Autoignition Temp Text:NONE
Extinguishing Media:NOT COMBUSTIBLE. USE APPROPRIATE EXTINGUISHING
MEDIA FOR MATERIAL THAT IS SUPPLYING FUEL.
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND USE
SELF-CONTAINED BREATHING APPARATUS. DIKE AREA TO PREVENT RUNOFF AND
CONTAMINATION OF WATER SOURCES.
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY BE
HAZARDOUS. THESE MAY INCLUDE HYDROGEN CHLORIDE AND NITROGEN OXIDES.
================== Accidental Release Measures ==================
Spill Release Procedures:DIKE LRG SPILLS W/ABSORB OR IMPERVIOUS MAT'L.
RECOVER & CONTAIN FREE LIQ. RECOVER REMAINING MAT'L AS APPROPRIATE
(VACUUM, FLUSHING TO INDUST SEWER, ETC). COLLECT & CONTAIN
CONTAMINATED ABSORBENT & DIK E MATERIAL FOR DISPOSAL. ABSORB SMALL
SPILL ON **
Neutralizing Agent:N/K **SAND/VERMIC. PLACE CONTAM MAT'L IN CNTNR
FOR DISPOSAL. IF SPILLED***
======================Handling and Storage ======================
Handling and Storage Precautions:DON'T GET IN EYES, ON SKIN, OR ON
CLOTHING. DON'T INGEST. AVOID EXPOSURE BY INHAL. DO NOT CONTAMINATE
WATER, FOOD OR FEED BY STORAGE OR DISPOSAL.
Other Precautions:***ON GROUND, AFFECTED AREA SHOULD BE REMOVED TO
DEPTH OF 1 OR 2 INCHES & PLACED IN AN APPROPRIATE CNTNR FOR
DISPOSAL. DON'T FLUSH MAT'L TO PUBLIC SEWER SYSTEMS/ANY WATERWAYS.
WEAR APPROPRIATE PROTECT IVE CLOTHING & EQUIPMENT DURING****
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR FOR PESTICIDE
MIST. USE POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS FOR
EMERGENCY CONDITIONS.
Ventilation:LOCAL EXHAUST VENTILATION.
Other Protective Equipment:FULL-BODY PROTECTIVE CLOTHING, SAFETY
SHOWER.
Work Hygienic Practices:WASH CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
NOTE TO PHYSICIAN: SEE ORIGINAL MSDS.
****CLEANUP ACTIVITIES. ENSURE ADEQ UATE
DECONTAMINATION OF TOOLS AND EQUIPMENT FOLLOWING CLEANUP.
================== Physical/Chemical Properties ==================
HCC:T5
Melt/Freeze Pt:M.P/F.P Text:21.2F,-6.0C
Spec Gravity:1.16 @ 20/20C
pH:7.5-10
Solubility in Water:100% @ 25 C
Appearance and Odor:CLEAR, BROWN TO BLACK LIQUID. CHARACTERISTIC
PHENOXY ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS AND ACIDS.
Stability Condition to Avoid:AVOID EXCESSIVE HEAT.
Hazardous Decomposition Products:HYDROGEN CHLORIDE AND NITROGEN OXIDES
MAY BE PRODUCED UPON DECOMPOSITION.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN AN APPROVED LANDFILL OR
INCINERATOR FOLLOWING ALL APPLICABLE FEDERAL, STATE & LOCAL
REGULATIONS. NOTE: 2,4-D SALTS ARE A RCRA HAZARDOUS WASTE (U240)
WHEN DISPOSED. SPILLS ARE SUBJECT TO CERLCA REPORTING
REQUIREMENTS: REPORT QTY 100 LBS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:874 1563 VNF/I/RVNP COLOR DEVELOPER, PART A
CAGE:19139
CAGE:19139
CAGE:5K871
============= Composition/Information on Ingredients =============
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 25 - 30%
Other REC Limits:NONE RECOMMENDED
Ingred Name:BENZYL ALCOHOL
CAS:100-51-6
RTECS #:DN3150000
Fraction by Wt: 20 - 25%
Other REC Limits:NONE RECOMMENDED
Ingred Name:ETHYLENE GLYCOL (SARA 313) (CERCLA)
CAS:107-21-1
RTECS #:KW2975000
Fraction by Wt: 17%
Other REC Limits:NONE RECOMMENDED
ACGIH TLV:C STEL39PPM,A4,VAP96
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:SODIUM HYDROXIDE (CERCLA)
CAS:1310-73-2
RTECS #:WB4900000
Fraction by Wt: 10 - 15%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:2 MG/M3
ACGIH TLV:C 2 MG/M3; 9596
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:ETHYLENEDIAMINE (SARA 302) (CERCLA)
CAS:107-15-3
RTECS #:KH8575000
Fraction by Wt: 10 - 15%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:10 PPM
ACGIH TLV:S, 10 PPM; 9596
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT): NOT GIVEN
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:VAPOR IRRITATING. MAY CAUSE ALLERGIC
RESPIRATORY REACTION. SOME ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS
MAY EXPERIENCE DIFFICULT BREATHING. CAUSES SEVERE EYE BURNS. CAUSES
SEVERE SKIN BURNS. MAY CAUS E ALLERGIC SKIN REACTION. MAY BE FATAL
IF SWALLOWED. CAN CAUSE KIDNEY DAMAGE. MAY CAUSE GI TRACT BURNS.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:EYE IRRITATION, ALLERGIC RESPIRATORY REACTION,
DIFFICULTY BREATHING, EYE BURNS, SKIN BURNS, ALLERGIC SKIN
REACTIONS, DEATH, KIDNEY DAMAGE, GI TRACT BURNS.
Medical Cond Aggravated by Exposure:MAY CAUSE ALLERGIC RESPIRATORY
REACTION IN SMOE ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS.
======================= First Aid Measures =======================
First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL
ATTENTION IF SYMPTOMS PERSIST. EYES: WASH OUT IMEEDIATELY WITH
WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN: WASH WITH
SOAP AND WATER . GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
INGESTION: DO NOT INDUCE VOMITING. GIVE A GLASS OF WATER IF
CONSCIOUS. CALL A PHYSICIAN OR POSION CONTROL CENTER IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point:>200F,>93C
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL
FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY PRODUCE
HAZARDOUS DECOMPOSTION PRODUCTS. DRIED PRODUCT RESIDUE CAN ACT AS A
REDUCING AGENT.
================== Accidental Release Measures ==================
Spill Release Procedures:MAY REQUIRE NEUTRALIZATION. FLUSH TO SEWER IF
ALLOWABLE WITH LARGE AMOUNTS OF WATER. OTHERWISE, ABSORB SPILL WITH
VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN A CONTAINER FOR
CHEMICAL WASTE. CLE AN SURFACE TO REMOVE RESIDUAL CONTAMINATION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP
AWAY FROM INCOMPATIBLE SUBSTANCES. DO NOT GET IN EYES, ON SKIN OR
ON CLOTHING. AVOID BREATHING VAPOR.
Other Precautions:THE ROUTINE USE OF A NONALKALINE (ACID) TYPE OF HAND
CLEANER AND REGULAR CLEANING OF WORKING SURFACES WILL HELP MINIMIZE
THE POSSIBILITY OF A SKIN REACTION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOSURE MAY OR DOES EXCEED OCCUPATION
EXPOSURE LIMITS USE A NIOSH-APPROVED RESPIRATOR TO PREVENT
OVEREXPOSURE. IN ACCORD WITH 29 CFR 1910.134 USE EITHER AN
ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AI R-PURIFYING RESPIRATOR.
Ventilation:GOOD GENERAL VENTILATION, TYPICALLY 10 AIR CHANGES PER
HOUR, SHOULD BE USED. RATES SHOULD MATCH CONDITIONS.
Other Protective Equipment:CHEMICAL RESISTANT CLOTHING AS NECESSARY TO
PREVENT SKIN CONTACT. AN EMERGENCY EYEWASH AND SHOWER SHOULD BE
AVAILABLE.
Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER
BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES.
Supplemental Safety and Health
REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE. KEY1:C2.
================== Physical/Chemical Properties ==================
HCC:F8
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:>212F,>100C
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Decomp Temp:Decomp Text:NOT GIVEN
Vapor Pres:18
Vapor Density:0.6
Spec Gravity:1.28
pH:13.0
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:COMPLETE
Appearance and Odor:SLIGHT YELLOW LIQUID, SLIGHT ODOR
Percent Volatiles by Volume:60-65%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, ACIDS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
OXIDES OF NITROGEN.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE OR LOCAL LAWS. MAY REQUIRE NEUTRALIZATION IF PH
< 2.0 OR PH > 12.5. DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE AND L OCAL REGULATIONS.
| 1 | gloves_mandatory |
=======================================================
Product ID: S-5 SUPER CLEAN
Cage: JO038
Box: 45
Proprietary Ind: Y
=======================================================
Contractor Summary
=======================================================
Cage: 8U352
Cage: JO038
Box: 45
=======================================================
Ingredients
=======================================================
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: SEE INGREDIENTS.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE:INGEST:ASPIR HAZ. MAY CAUSE SEV BURNS TO MOUTH,
LIPS, ESOPHAGUS, STOM. HARMFUL/FATAL IF SWALLOWED. MAY CAUSE POSS PERFORATION
OF ESOPHAGUS/STOM. MAY CAUSE STRONG SALIVATION, VOMIT, NAUS, DROW &
FATG. SKIN:CORROSIVE. INHAL:BRTHG PROD DUST/MIST MAY IRRIT RESP TRACT. PRLNG
EXPOS TO VAPS GENERATED AT(EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ:ELEVATED TEMPS MAY CAUSE RESP
IRRIT & NARCOS. EYE CONT:MAY CAUSE INFLAMM OF CONJ. LIQ & MIST ARE
IRRIT & MAY CAUSE SEV BURNS. MAY CAUSE POSS SEV BURNS. CHRONIC:ANIMAL
STUDIES CLEARLY DEMONSTR ATED DOSE-RELATED ADVERSE EFTS ON CNS, HEMATOPOIETIC
TISSUES, BLOOD, KIDNEYS & LIVER, ASSOC W/ADMIN OF ETHYLENE (SUPDAT)
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INGEST:IF VOMIT OCCURS SPONT, HOLD HEAD LOWER THAN HIPS TO PVNT
ASPIR. RINSE MOUTH OUT & SPIT. DO NOT SWALLOW! DO NOT INDUCE VOMIT. DRINK
WATER/MILK. CONTINUE SIPPING FLUIDS UNTIL MED HELP IS OBTAINED . ASSIST IN
FIRST AID. NEVER ATTEMPT TOGIVE ANYTHING BY MOUTH TO UNCON PERS. SKIN:REMOVE
CONTAM CLTHG AT ONCE. BLOT OFF WET CHEM W/COMPAT WIPE/BRUSH OFF DRY CHEM.
FLUSH W/COLD WATER FOR 15 (SUPDAT)
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: CONSULT SPECIAL PROT INFO SECTION FOR PROPER SAFETY
EQUIP. DIKE SPILL & PROT SEWER & WATER INTAKE. VENTILATE AREA,
MONITOR AIR FOR ACCUM OF HAZ VAPS. NOTIFY ALL PROPER AUTHS IF REQD IN CASE OF
SPILL. FOLLOW ENVIRON REGS. ABSORB W/COMPAT
Neutralizing Agent: WEAK ACIDIC SOLUTION.
Waste Disposal Methods: FOLLOW LOCAL, STATE & FEDERAL DISPOSAL REGULATIONS.
CONSULT MFR FOR FURTHER INFO. DISPOSE OF WASTE I/A/W FEDERAL, STATE &
LOCAL LAW. INCINERATE AT A FEDERALLY APPROVED FACILITY. LANDFILL AT SECURED
AP PROVED LANDFILL.
Handling And Storage Precautions: DO NOT TRANSFER TO CONTAINERS NOT PROPERLY
LABELED FOR THIS PRODUCT. DO NOT CONTAMINATE W/DIRTY EQUIPMENT. KEEP FROM
FREEZING!
Other Precautions: CORROSIVE LIQUID. KEEP OUT OF REACH OF CHILDREN. FOR
INDUSTRIAL & COMMERCIAL USE ONLY.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: NONFLAMMABLE
Extinguishing Media: MATL IS NOT COMBUSTIBLE. IF INVOLVED IN A FIRE, CHOOSE
EXTINGUISHING AGENT MOST SUITABLE FOR TYPE OF SURROUNDING FIRE.
Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). RUN-OFF MAY CONTAIN HAZ MATLS & SHOULD BE CONTROLLED IF
NEC. EVACUATE DOWN WIND.
Unusual Fire/Explosion Hazard: TOXIC SMOKE & FUMES MAY BE PRODUCED.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE
OF CONCERN (FP N).
Ventilation: ADEQUATE FOR WORK AREA. MAINTAIN LEVELS BELOW TLV.
Other Protective Equipment: EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI
DESIGN CRITERIA (FP N). PROT LEVELS SHOULD BE INCR ACCORDING
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: NOTE:USERS OF "L" VERSION SHOULD CONSULT "LR"
VERSION FOR ADDNL INFO (FP N). EFTS OF OVEREXP:GLYCOL MONOBUTYL ETHER (EGBE).
(EXTRACTED FROM DHHS (NIOSH) PUBLICATION NO.90-118) (FP N). FIRST AID PROC:M
INS. MONITOR VICTIM FOR RECURRING SYMPS. CLEAN CONTAM CLTHG BEFORE REUSE.
DISCARD SHOES BY APPRVD METHS. DO NOT
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: 210F,99C
M.P/F.P Text: 28.0F,-2.2C
Spec Gravity: 1.016 (H*2O=1)
PH: 13.1
Solubility in Water: COMPLETE
Appearance and Odor: DARK BLUE LIQUID; BUTYL ODOR.
Percent Volatiles by Volume: 8.6
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: CONTAMINATION FROM ANY OUTSIDE SOURCE. KEEP AWAY
FROM FIRE, OPEN FLAME OR ANY HEAT SOURCE.
Materials To Avoid: DO NOT MIX W/ACIDS, STRONG OXIDIZERS, CHLORINES, NITRITES
OR PEROXIDES.
Hazardous Decomposition Products: CARBON DIOXIDE OR CARBON MONOXIDE MAY BE
FORMED.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: S-5 SUPER CLEAN
Cage: JO038
Assigned IND: Y
Company Name: S & S COMPANY OF GA INC
Street: 827 PINE AVE
PO Box: 45
Zipcode: 31702-0045
Label Required IND: Y
Date Of Label Review: 05/16/1995
Status Code: C
Label Date: 05/16/1995
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Severe
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE:INGEST:ASPIRATION HAZARD. MAY CAUSE SEVERE BURNS
TO MOUTH, LIPS, ESOPHAGUS, STOMACH. HARMFUL OR FATAL IF SWALLOWED. MAY CAUSE
POSSIBLE PERFORATION OF ESOPHAGUS OR STOMACH. MAY CAUSE STRONG SALIV ATION,
VOMITING, NAUSEA, DROWSINESS & FATIGUE. EYE/SKIN:CORROSIVE.
INHAL:BREATHING PRODUCT VAPORS, DUST OR MIST MAY IRRITATE RESPIRATORY TRACT.
CHRONIC:ANIMAL STUDIES CLEARLY DEMONSTRATED DOSE-RELATED ADVERSE EFFECTS ON
CENTRAL NERVOUS SYSTEM, BLOOD-FORMING TISSUES, BLOOD, KIDNEYS & LIVER,
ASSOCIATED W/ADMINISTRATION OF 2-BUTOXYETHANOL (FP N).
=======================================================
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:ISOPROPYL ALCOHOL, ANHYDROUS
CAGE:4H542
CAGE:4H542
CAGE:72190
CAGE:1DZ38
============= Composition/Information on Ingredients =============
Ingred Name:ISOPROPYL ALCOHOL (SARA III)
CAS:67-63-0
RTECS #:NT8050000
Fraction by Wt: 100%
Other REC Limits:NONE SPECIFIED
OSHA PEL:400 PPM/500 STEL
ACGIH TLV:400 PPM/500STEL;9192
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 ORAL RAT=5840MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE-EYE:IRRITATION AND EYE INJURY IF
REMOVED PROMPTLY. SKIN:IRRITATION/DEFATTING. INHALATION:HEADACHE,
DIZZINESS, ANESTHETIC, IRRITATING TO RESPIRATORY TRACT.
INGESTION:MINIMAL TOXICITY. SMALL AMOUN TS ASPIRATED INTO LUNGS MAY
CAUSE BRONCHIOPNEUMONIA AND PULMONARY EDEMA. CHRONIC:DERMATITIS.
Effects of Overexposure:EYES:SEVERE IRRITATION. SKIN:IRRITATION.
INHALATION:COUGHING, HEADACHE, DIZZINESS.
INGESTION:GASTROINTESTINAL PAIN, CRAMPS, NAUSEA, VOMITING.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS,EYE
PROBLEMS, IMPAIRED RESPIRATORY FUNCTIONS.
======================= First Aid Measures =======================
First Aid:EYES:FLUSH WITH PLENTY OF WATER FOR 15 MINUTES. SEE DOCTOR
IMMEDIATELY. SKIN:REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP &
WATER. IF IRRITATION PERSISTS,SEE DOCTOR. INHALATION:REMOVE TO
FRESH AIR. GI VE CPR/ OXYGEN IF NEEDED. GET MEDICAL HELP.
INGESTION:DRINK WATER. DO NOT INDUCE VOMITING. SEE DOCTOR
IMMEDIATELY. GIVE NOTHING BY MOUTH IF UNCONSCIOUS.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:54.0F,12.2C
Lower Limits:2.0
Upper Limits:12.0
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. EVACUATE AREA. COOL
FIRE EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE THE AREA. REMOVE IGNITION SOURCES.
VENTILATE. WEAR RESPIRATORY PROTECTION & PROTECTIVE CLOTHING.
SPILLS MAY BE ABSORBED IN INERT MATERIAL OR RECOVERED BY PUMPING.
Neutralizing Agent:NONE
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED
PLACE,AWAY FROM STRONG OXIDIZERS & IGNITION SOURCES.PROTECT FROM
PHYSICAL DAMAGE. STORE IN NON-SMOKING AREA.
Other Precautions:CONTAINERS SHOULD BE BONDED & GROUNDED FOR TRANSFERS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:A FULL FACE RESPIRATOR WITH ORGANIC VAPORS
FILTER, OR A SELF CONTAINED RESPIRATOR IS RECOMMENDED.
Ventilation:LOCAL EXHAUST AND/OR MECHANICAL (GENERAL) VENTILATION
RECOMMENDED. LOCAL EXHAUST,PREFERRED.
Other Protective Equipment:BOOTS,LAB COAT,APRON OR COVERALLS. EYEWASH
STATION & SAFETY SHOWER.
Work Hygienic Practices:AVOID BREATHING VAPORS.AVOID CONTACT WITH EYES,
SKIN & CLOTHING. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:F3
Boiling Pt:B.P. Text:181F,83C
Melt/Freeze Pt:M.P/F.P Text:-128F,-89C
Vapor Pres:33M
Vapor Density:2.1
Spec Gravity:0.79
Evaporation Rate & Reference:2.83 (BU AC=1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR COLORLESS LIQUID
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:CARBON MONOIXED AND CARBON DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF I/A/W FEDERAL, STATE & LOCAL
REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:EPOXY COATING,B 58 T 104 ULTRADEEP BASE
CAGE:54636
CAGE:54636
============= Composition/Information on Ingredients =============
Ingred Name:VOLATILE ORGANIC COMPOUNDS (1.17 LBS/GAL)
RTECS #:9999999VO
Other REC Limits:NONE RECOMMENDED
OSHA PEL:NOT RELEVANT
ACGIH TLV:NOT RELEVANT
Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM
ACGIH TLV:100 PPM/150STEL;9394
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:NAPHTHA, LIGHT AROMATIC
CAS:64742-95-6
Fraction by Wt: 6%
Other REC Limits:NONE RECOMMENDED
Ingred Name:ISOBUTYL ALCOHOL (SARA III)/2-METHYL-1-PROPANOL
CAS:78-83-1
RTECS #:NP9625000
Fraction by Wt: 1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:50 PPM.
ACGIH TLV:50 PPM; 9394
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:FORMALDEHYDE (SARA III)
CAS:50-00-0
RTECS #:LP8925000
Fraction by Wt: 0.1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:SEE 1910.1048
ACGIH TLV:C 0.3 PPM; A2; 9394
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:POLYAMINE
Fraction by Wt: 21%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:TLV FOR FORMALDEHYDE IS 1 PPM.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, CNS,
RESPIRATORY TRACT. ACUTE- IRRITATION OF EYES, SKIN & RESPIRATORY
SYSTEM. MAY CAUSE NERVOUS SYSTEM DEPRESSION. EXTREME OVEREXPOSURE
MAY CAUSE UNCONSCIOUSNESS & POSSIBLY D EATH. MAY CAUSE ALLERGIC
SKIN REACTION.HARMFUL IF INGESTED. CHRONIC- MAY CAUSE LIVER,
KIDNEY, BLOOD & BRAIN DAMAGE.
Explanation of Carcinogenicity:CONTAINS F [50-00-0] WHICH IS
LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN.
Effects of Overexposure:HEADACHE, DIZZINESS, NAUSEA, LOSS OF
COORDINATION, IRRITATION OF EYES, SKIN AND RESPIRATORY TRACT,
REDNESS AND ITCHING OR BURNING SENSATION OF EYES OR SKIN
Medical Cond Aggravated by Exposure:MAY CAUSE ALLERGIC SKIN REACTION IN
SUSCEPTIBLE PERSONS.
======================= First Aid Measures =======================
First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. INHALED: REMOVE TO
FRESH AIR. PROVIDE OXYGEN IF NEEDED. EYES: FLUSH WITH WATER FOR 15
MINUTES. KEEP EYELIDS OPEN. SKIN: WASH WITH SOAP & WATER.
INGESTION: DO NOT INDUCE VOMITING IF VOMITING OCCURS, KEEP HEAD
BELOW HIPS. CALL PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point:105F,41C
Lower Limits:0.7
Upper Limits:6.0
Extinguishing Media:USE CARBON DIOXIDE, FOAM, OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED
CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:VAPOR IS HEAVIER THAN AIR AND CAN TRAVEL
CONSIDERABLE DISTANCE OR BE MOVED BY VENTILATION TO A SOURCE OF
IGNITION AND FLASH BACK. CONTAINER MAY EXPLODE.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR APPROPRIATE RESPIRATORY PROTECTION AND
PROTECTIVE CLOTHING. CONTAIN SPILLED MATERIAL. TRANSFER TO SECURE
CONTAINERS. WHERE NECESSARY, COLLECT USING ABSORBENT MEDIA SUCH AS
SAND/VERMICULITE. ELIMI NATE ANY SOURCE OF IGNITION. VENTILATE
AREA.
Neutralizing Agent:NOT RELEVANT
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, VENTILATED AREA, AWAY
FROM HEAT, FLAMES & SPARKS. USE APPROVED BONDING AND GROUNDING
PROCEDURES.
Other Precautions:USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER
HANDLING AND BEFORE EATING OR DRINKING. DO NOT GET IN EYES, ON SKIN
OR ON CLOTHING. DO NOT BREATHE VAPOR AND SPRAY MIST. KEEP OUT OF
REACH OF CHILD REN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION
EXPOSURES BELOW PEL(TLV), USE NIOSH APPROVED RESPIRATORS.
RESPIRATORS SHOULD BE SELECTED BASED ON THE FORM AND CONCENTRATION
OF CONTAMINANT IN AIR & IN ACCO RDANCE WITH OSHA (29 CFR 1910.134).
Ventilation:MECHANICAL (GENERAL) ROOM VENTILATION IS NORMALLY ADEQUATE.
LOCAL EXHAUST MAY BE REQUIRED IF WORK AREA NOT VENTED.
Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER,
INDUSTRIAL-TYPE WORK CLOTHING, APRON AND BARRIER CREAM FOR EXPOSED
SKIN
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
FORMULA CHANGED. FOR PREVIOUS FORMULATION, SEE PNI A, UNDER THE SAME
NSN.
================== Physical/Chemical Properties ==================
HCC:F4
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:222F - 395F
Vapor Density:>1
Spec Gravity:1.642
Evaporation Rate & Reference:<1 (ETHER=1)
Appearance and Odor:LIQUID WITH SOLVENT ODOR
Percent Volatiles by Volume:<= 25
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:HIGH HEAT, SPARKS, OPEN FLAMES AND OTHER
SOURCES OF IGNITION
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, AND
OXIDES OF NITROGEN
==================== Disposal Considerations ====================
Waste Disposal Methods:ALL RECOVERED MATERIAL SHOULD BE PACKAGED,
LABELED, TRANSPORTED, AND DISPOSED OR RECLAIMED IN ACCORDANCE WITH
ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.
INCINERATE IN APPROVED FACIL ITY. DO NOT INCINERATE CLOSED
CONTAINER.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:3-AMINOPHENOL, 98% 10024-2
CAGE:60928
CAGE:60928
============= Composition/Information on Ingredients =============
Ingred Name:PHENOL, M-AMINO- (3-AMINOPHENOL, 98%)
CAS:591-27-5
RTECS #:SJ4900000
Fraction by Wt: 98%
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE SUPP DATA
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:HARMFUL IF INGESTED, INHALED OR
ABOSRBED THROUGH SKIN. CAUSES EYE/SKIN IRRIT. MATL IS IRRIT TO MUC
MEMB/ UPPER RESP TRACT. DEPENDING ON INTENSITY/DURATION OF EXPOS,
EFTS MAY VARY FROM MILD IRRIT TO SEVERE DESTRUCTION OF TISS.
CHRONIC:DAMAGE TO EYES. SEVERE IRRITATION OR BURNS.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES:IMMEDIATELY FLUSH W/COPIOUS AMTS OF WATER FOR AT LEAST
15 MINUTES. SKIN:IMMEDIATELY FLUSH W/COPIOUS AMTS OF WATER WHILE
REMOVING CONTAMINATED CLOTHING AND SHOES. WASH CONTAMINATED
CLOTHING BEFORE REUSE. INHAL:REMOVE TO FRESH AIR. SUPPORT
BREATHING (GIVE O2/ARTIFICIAL RESPIRATION). CALL MD. INGEST:CALL MD
IMMEDIATELY .
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER,
ALCOHOL OR POLYMER FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT TO PREVENT CONTACT WITH SKIN AND EYES.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. WEAR NIOSH/MSHA APPROVED SCBA,
FOR WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE AREA & WASH SPILL
SITE AFTER MATERIAL PICKUP IS COMPLETE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT BREATHE DUST. STORE IN A COOL,
DRY PLACE.
Other Precautions:TOXIC. IRRITANT. AVOID CONTACT WITH EYES, SKIN AND
CLOTHING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Other Protective Equipment:PROTECTIVE CLOTHING. SAFETY SHOWER AND EYE
BATH.
Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER USE AND BEFORE
EATING, DRINKING, SMOKING OR USING SANITARY FACILITIES .
Supplemental Safety and Health
LD50-LC50 MIX:LD50:(ORAL,RAT)1 GM/KG. LD50: (UNR,RAT)1125 MG/KG.
LD50:(ORAL,MOUSE)420 MG/KG. LD50:(IPR,MOUSE)150 MG/KG.
LD50:(UNR,MOUSE)225 MG/KG. LD50:(ORAL,QAL)750 MG/KG.
LD50:(UNR,MAM)1245 MG/ KG.LD50:(ORAL,BWD)237 MG/KG.
================== Physical/Chemical Properties ==================
HCC:T4
Boiling Pt:B.P. Text:327F,164C
Melt/Freeze Pt:M.P/F.P Text:255F,124C
Appearance and Odor:OFF-WHITE FLAKES
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS, ACID CHLORIDES, ACID ANHYDRIDES, CHLOROFORMATES, STRONG
OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:TOXIC FUMES OF CARBON MONOXIDE, CARBON
DIOXIDE, NOX.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISSOLVE OR MIX MATERIAL W/COMBUSTIBLE SOLVENT &
BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AFTERBURNER & SCRUBBER.
DISPOSE I/A/W FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:OFF-WHITE HIGH SOLIDS PRIMER, PART A, ID 4488WEP-3
Kit Part:Y
Preparer's Name:JANE FREEMAN
CAGE:09225
CAGE:09225
============= Composition/Information on Ingredients =============
Ingred Name:METHYL ISOAMYL KETONE
CAS:110-12-3
RTECS #:MP3850000
Fraction by Wt: 14.738%
Other REC Limits:NONE RECOMME
OSHA PEL:50 PPM
ACGIH TLV:50 PPM
Ingred Name:TITANIUM DIOXIDE PIGMENT
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 20-30%
Other REC Limits:NONE RECOMME
OSHA PEL:10 MG/M3
ACGIH TLV:10 MG/M3
Ingred Name:SILICA PIGMENT
CAS:14808-60-7
RTECS #:VV7330000
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMME
OSHA PEL:0.1 MG/M3
ACGIH TLV:0.1 MG/M3
Ingred Name:EPOXY RESIN
Fraction by Wt: 15-20%
Other REC Limits:NONE RECOMME
Ingred Name:METHYL ISOBUTYL KETONE (SARA III)
CAS:108-10-1
RTECS #:SA9275000
Fraction by Wt: 7.016%
Other REC Limits:NONE RECOMME
OSHA PEL:50 PPM; STEL 75 PPM
ACGIH TLV:50 PPM; STEL 75 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:EPOXY RESIN
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMME
Ingred Name:BUTYL ALCOHOL SOLVENT (SARA III)
CAS:71-36-3
RTECS #:EO1400000
Fraction by Wt: 1.044%
Other REC Limits:SKIN NOTATIO
OSHA PEL:50 PPM (CEILING)
ACGIH TLV:50 PPM (CEILING)
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ZINC METAL (SARA III)
CAS:7440-66-6
RTECS #:ZG8600000
Fraction by Wt: 1.616%
Other REC Limits:NUISANCE DUS
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:UNREGULATED CORROSION INHIBITIVE PIGMENT
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMME
Ingred Name:VOC: 3.033 LBS/GAL; 363.444 GRAMS/LITER
RTECS #:9999999VO
Other REC Limits:NONE RECOMME
===================== Hazards Identification =====================
Reports of Carcinogenicity:NTP:UNKNOWN IARC:YES
Health Hazards Acute and Chronic:INHAL: ANESTHETIC. RESP TRACT IRRIT,
ACUTE NERVOUS SYSTEM DEPRESSION (HEADACHE, DIZZINESS, STAGGERING,
CONFUSION, COMA). SKIN OR EYE: IRRIT. CHRONIC:REPEATED & PROLONGED
OVEREXPOSURE TO SOLVENTS W/PER MANENT BRAIN & NERVOUS SYSTEM
DAMAGE, LIVER, KIDNEY DAMAGE. MAY CAUSE LUNG INJURY IF RESPIRATORY
PRECAUTION NOT USED.
Explanation of Carcinogenicity:BASED UPON ANIMAL DATA, IARC HAS LISTED
SILICA AS PROBABLE HUMAN CARCINOGEN.
Medical Cond Aggravated by Exposure:ASTHMA AND OTHER RESPIRATORY
AILMENTS; CHEMICAL SENSITIZATION.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP
WARM & QUIET. NOTIFY PHYSICIAN. EYES: FLUSH IMMEDIATELY WITH LARGE
AMOUNTS OF RUNNING WATER AT LEAST 15 MINUTES. TAKE TO PHYSICIAN FOR
MEDICAL TREATMENT. SKIN: WASH AFFECTED AREAS WITH SOAP & WATER.
REMOVE CONTAMINATED CLOTHING. CONSULT PHYSICIAN. INGESTION: CALL
PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:60.0F,15.6C
Lower Limits:1.0
Upper Limits:11.2
Extinguishing Media:FOAM, DRY CHEMICAL, CO2
Fire Fighting Procedures:WEAR FULL PROTECTIVE EQUIP INCLUDING SCBA.
WATER MAY BE INEFFECTIVE,USE TO COOL (FOG NOZZLE PREFERRED) CLOSED
CONTAINER (PREVENT PRESSR BLDUP,AUTOIGNIT,EXPLOSN)
Unusual Fire/Explosion Hazard:KEEP CONTAINER TIGHTLY CLSD. KEEP FROM
HEAT/IGNIT SOURCE. CLOSED CONTAINER MAY EXPLODE W/HEAT. DON'T APPLY
TO HOT SURFACE. NEVER USE WELD/CUT TORCH ON/NEAR DRUM
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION (FLAMES, HOT
SURFACES, ELECTRICAL, STATIC OR FRICTIONAL SPARKS). AVOID BREATHING
VAPORS. VENTILATE AREA. CONTAIN & REMOVE WITH INERT ABSORBENT AND
NONSPARKING TOOLS.
======================Handling and Storage ======================
Handling and Storage Precautions:DON'T STORE ABOVE 120F.STORE LRG QTY
IN BLDGS IN COMPLY W/OSHA1910.106.KEEP AWAY FROM
SPARKS/FLAME.EMPTIED CNTNR RETAIN HZD RESIDUE & EXPLOSIVE VAPOR.
Other Precautions:DON'T INGEST.GROUND CNTNR WHEN POURING. AVOID LIQ
FREE FALL >FEW INCHES. USE W/VENT & RSPRTRY EQUIP. AVOID PROLONGED
VAPOR BREATHING/SPRAY MIST. AVOID PROLONGED/REPEATED SKIN CONTACT.
FOLLOW PRECAUTIO NS IN MSDS TILL CNTNR CLEANED/DESTROYED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHEN SPRAY IN OUTDOOR OR DURING SAND/GRINDING:
NIOSH MECHAN FILTER RSPRTR (REMOVE SOLID PARTICLES). RESTRICTED
AREA: NIOSH CHEM/MECHAN FILTER (SOLID & GAS). CONFINED AREA: NIOSH
AIR SUPPLD RSPRTR/HOOD .USE NIOSH RSPRTR WHEN WELD,CUT,HAZING.
Ventilation:GENRL DILUTN/LOCAL EXHAUST TO KEEP BELOW PEL IN
MIXING,APPLICATION & CURING AREAS & REMOVE DECOMP FROM WELD & FLAME
CUT.
Other Protective Equipment:PROTECTIVE SKIN CREAM IF CONTACT
LIKELY.PREVENT PROLONGED SKIN CONTACT W/CONTAM CLOTHES.WASH CONTAM
CLOTHES BEFORE REUSE
Work Hygienic Practices:WASH HANDS BEFORE EATING OR SMOKING. SMOKE IN
DESIGNATED AREA ONLY.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:232 TO 298F
Decomp Temp:Decomp Text:400F,204C
Vapor Pres:15.00 @68F
Vapor Density:> AIR
Spec Gravity:1.55
Viscosity:65-80 KU
Evaporation Rate & Reference:FASTER THAN BUTYL ACETATE
Solubility in Water:NEGLIGIBLE
Appearance and Odor:OPAQUE LIQUID, SOLVENT ODOR
Percent Volatiles by Volume:44.96
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS
Hazardous Decomposition Products:MAY PRODUCE HAZARDOUS FUMES WHEN
HEATED TO DECOMPOSITION AS IN WELDING. MAY CONTAIN CARBON MONOXIDE,
CARBON DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND
FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS.
INCINERATE IN AN APPROVED FACILITY. EPA HAZARDOUS WASTE NUMBER
CODE: D001, IGNITABLE. DISPOSAL METHODS: INCINERATION.
======================================================================
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:ARDROX 9D6F
Preparer's Name:N.P.WHITEHORN
CAGE:23373
CAGE:23373
============= Composition/Information on Ingredients =============
Ingred Name:METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III)
CAS:71-55-6
RTECS #:KJ2975000
Fraction by Wt: 90.0%
Other REC Limits:NONE SPECIFIED
OSHA PEL:350 PPM/450 STEL
ACGIH TLV:350 PPM/450STEL;9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ozone Depleting Chemical:1
Ingred Name:OTHER COMPONENTS
Fraction by Wt: BALANCE
Other REC Limits:NONE SPECIFIED
OSHA PEL:400 PPM/500 STEL
ACGIH TLV:400 PPM/500STEL;9091
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:IRRITATION OF
EYES,SKIN,RESPIRATORY OR G.I.TRACTS;CNS EFFECTS LIKE
HEADACHE,DIZZINESS,NAUSEA AND VOMITING. REDNESS/TEAR OR BURNS OF
EYES/SKIN POSSIBLE.CHRONIC:DRYING OF SKIN,DEFATTING OR DERMATI TIS.
Explanation of Carcinogenicity:DATA PER MSDS
Effects of Overexposure:MAY CAUSE IRRITATION OF EYES,SKIN,RESPIRATORY
OR G.I.TRACTS;MAY CAUSE HEADACHE,DIZZINESS,NAUSEA,VOMITING OR GI
TRACT DISTURBANCES POSSIBLE.BURNS OR REDNESS OF EYES/CRACKING OR
DRYNESS OF SKIN.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS
OR WITH A PRE-EXISTING DISEASE INVOLVING THE EYES, SKIN, OR
RESPIRATORY TRACT MAY BE AT INCREASED RISK FROM EXPOSURE.
======================= First Aid Measures =======================
First Aid:INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING.
GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER
FOR 15 MINUTES HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION.
SKIN:REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. IF
IRRITATION PERSISTS, GET MEDICAL ADVICE. INGESTION:DO NOT INDUCE
VOMITING. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE
MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Lower Limits:6.0
Extinguishing Media:WATER SPRAY
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:NEVER USE OPEN FLAMES NEAR
DRUMS;CONTAINERS MAY RUPTURE DUE TO EXTREME HEAT.
================== Accidental Release Measures ==================
Spill Release Procedures:USE PROPER PERSONAL PROTECTION;REMOVE ALL
IGNITION SOURCES. CONTAIN FREE MATERIAL IF POSSIBLE;USE SUITABLE
INERT ABSORBENT MATERIAL AND RECOVER FOR PROPER DISPOSAL IN AN
APPROVED CONTAINER.
Neutralizing Agent:NOT APPLICABLE.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED
AREA. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. KEEP AWAY
FROM NAKED FLAMES.
Other Precautions:DO NOT TAKE INTERNALLY. DO NOT BREATHE MIST. AVOID
PROLONGED OR REPEATED BREATHING OF VAPOR. AVOID CONTACT WITH EYES.
USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR AS REQUIRED
IF ABOVE PEL/TLV OR SCBA IN AN ENCLOSED AREA.
Ventilation:LOCAL/GENERAL TO MAINTAIN PEL/TLV.
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER,WORK
CLOTHING AND APRON AS REQUIRED.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO
NOT BREATHE VAPORS OR MISTS.
================== Physical/Chemical Properties ==================
HCC:T4
Boiling Pt:B.P. Text:165F,74C
Vapor Pres:100
Vapor Density:4.5
Spec Gravity:1.29
Solubility in Water:NEGLIGIBLE
Appearance and Odor:WHITE POWDER DISPERSED IN A VOLATILE SOLVENT.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WATER AND CATIONIC MATERIALS
Stability Condition to Avoid:HIGH TEMPERATURES ,SPARKS AND NAKED
FLAMES.
Hazardous Decomposition Products:HYDROGEN CHLORIDE ;VERY SMALL AMOUNT
OF PHOSGENE AND CHLORINE.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONSULT LOCAL AUTHORITIES.DISPOSAL MUST BE MADE
IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND
REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:INK, STAMP-PAD
CAGE:82956
CAGE:82956
============= Composition/Information on Ingredients =============
Ingred Name:LT GREEN S F (DYE)
Fraction by Wt: 1%
Ingred Name:ETHYLENE GLYCOL (SARA III)
CAS:107-21-1
RTECS #:KW2975000
Fraction by Wt: 33%
OSHA PEL:C 50 PPM
ACGIH TLV:C 50 PPM,VAPOR; 9192
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
Effects of Overexposure:EYE/SKIN: IRRITATION. INGESTION: MAY CAUSE
DEATH/NAUSEA/VOMITING/DIARRHEA/CYANOSIS/UREMIA/ANURIA.
======================= First Aid Measures =======================
First Aid:SKIN: FLUSH WITH SOAP/WATER. REMOVE CONTAMINATED CLOTHING.
INGESTION: DRINK WATER. INDUCE VOMITING. CALL PHYSICIAN. EYES:
FLUSH W/WATER.
===================== Fire Fighting Measures =====================
Flash Point:360F (TCC)
Extinguishing Media:CO2, DRY CHEMICAL OR WATER FOG
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:CONTAIN SPILL. PREVENT ENVIRONMENTAL
CONTAMINATION OF GROUND/SURFACE WATERS. RECOVERPILLED INK ON
ADSORBENTS SUCH AS SAWDUST/VERMICULITE/SWEEP INTO CONTAINEFOR
DISPOSAL. AFTER ALL TRACES HAVE BEEN REM OVED, THOROUGHLY WET CLEAN
T AREA.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE.
DON'T STORE IN UNLABLED OR MISLABLED CONTAINERS. KEEP AY FROM HEAT,
SPARK OR FLAME.
Other Precautions:KEEP OUT OF REACH OF CHILDREN. DON'T TAKE INTERNALLY.
AVOID CONTACT WITH EYES, SKIN OR CLOTHING. WASH THOROUGHLY AFTER
HANDLG.
============= Exposure Controls/Personal Protection =============
Ventilation:FRESH AIR
Other Protective Equipment:BOOTS, APRONS, CHEMICAL & EYE BATH.
Supplemental Safety and Health
MSDS DATE: 12 MAY 1986.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:299F
Vapor Pres:.01
Vapor Density:3.66
Spec Gravity:1.2
Evaporation Rate & Reference:NEGLIGIBLE
Solubility in Water:COMPLETE
Appearance and Odor:COLOR OF REPRESENTED INK. ODORLESS
Percent Volatiles by Volume:0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Hazardous Decomposition Products:NONE
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTAMINATED SAWDUST, VERMICULITE OR OTHER
CLEANUP DEBRIS CAN BE DISPOSED OF IN A PERMITTED HAZARDOUS WASTE
MANAGEMENT FACILITY.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:COMMERCIAL COATINGS - 629 CHEVROLET ORANGE
CAGE:MART2
CAGE:MART2
============= Composition/Information on Ingredients =============
Ingred Name:PROPANE
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: 14%
Other REC Limits:1800 MG/CUM
OSHA PEL:1000 PPM
ACGIH TLV:SIMPLE ASPHYXIANT
Ingred Name:ISOBUTANE, 2-METHYLPROPANE
CAS:75-28-5
RTECS #:TZ4300000
Fraction by Wt: 14%
Other REC Limits:1000 PPM
OSHA PEL:1800 MG/CUM
ACGIH TLV:1000 PPM
Ingred Name:TOLUENE
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 16%
Other REC Limits:375 MG/CUM
OSHA PEL:100 PPM
ACGIH TLV:100 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:XYLENE, DIMETHYLBENZENE, XYLOL
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 7%
Other REC Limits:100 PPM
OSHA PEL:100 PPM
ACGIH TLV:100 PPM, SKIN
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:ACETONE; DIMETHYL KETONE; 2-PROPANONE
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 37%
OSHA PEL:2400 MG/CUM
ACGIH TLV:750 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ETHYL 3-ETHOXYPROPIONATE
CAS:763-69-9
RTECS #:UF3325000
Fraction by Wt: 3%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:IRRITATION OF EYES/SKIN/RESPIRATORY
SYSTEM. CNS DEPRESSION. PROLONGED SOLVENT MAY CAUSE ADVERSE EFFECTS
TO LIVER/URINARY/BLOOD FORMING/REPRODUCTIVE/CARDIOVASCULAR
SYSTEMS/PERMANENT BRAIN/CNS DAMAGE. E XTREME OVEREXPOSURE MAY CAUSE
UNCONSCIOUSNESS & POSSIBLY DEATH.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION:
HEADACHE/DIZZINESS/NAUSEA/COORDINATION LOSS/UNCONSCIOUSNESS/DEATH.
SKIN/EYES: REDNESS/ITCH/BURNING SENSATION. SYMPTOMS MAY NOT BE
IMMEDIATELY APPARENT.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. KEEP WARM
& QUIET. SKIN: WASH THOROUGHLY W/SOAP & WATER, REMOVE CONTAMINATED
CLOTHING. EYES: FLUSH W/PLENTY OF WATER FOR 15 MINUTES. INGESTION:
NEVE R GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. DO NOT
INDUCE VOMITING. GIVE SEVERAL GLASSES OF WATER. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:<0F
Lower Limits:0.7%
Upper Limits:6%
Extinguishing Media:CO2, DRY CHEMICAL, FOAM
Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT INCLUDING SCBA.
WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE
PREFERABLE.
Unusual Fire/Explosion Hazard:WATER MAY BE USED TO COOL CLOSED
CONTAINERS TO PREVENT PRESSURE BUILD-UP, POSSIBLE AUTOIGNITION, OR
EXPLOSION WHEN EXPOSED TO EXTREME HEAT. FLAMMABLE.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE IGNITION SOURCES. VENTILATE AREA,REMOVE
W/INERT ABSORBENT.
======================Handling and Storage ======================
Handling and Storage Precautions:USE ONLY IN ADEQUATE VENTILATION. KEEP
AWAY FROM HEAT, SPARKS, OPEN FLAME. DURING USE & UNTIL ALL VAPORS
ARE GONE; KEEP ARE VENTILATED. DON'T SMOKE.
Other Precautions:EXTINGUISH ALL FLAMES, PILOT LIGHTS & HEATERS. TURN
OFF STOVES/ELECTRIC TOOLS/APPLIANCES & OTHER IGNITION SOURCES.
CONSULT NFPA CODE. USE APPROVED BONDING/GROUNDING PROCEDURES. KEEP
CONTAINER CLOSED W HEN NOT IN USE. DON'T TAKE INTERNALLY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW
TLV BY VENTILATION, USE A FITTED ORGANIC VAPOR/PARTICULATE
RESPIRATOR APPROVED BY NIOSH/MSHA. WHEN SANDING/ABRADING DRIED
FILM, USE A NIOSH/MSHA DUST/MI ST RESPIRATOR.
Ventilation:LOCAL EXHAUST: PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF
EXPOSURE TO MATERIALS IS MAINTAINED BELOW APPLICABLE LIMITS.
Work Hygienic Practices:WASH HANDS AFTER USING. REMOVE/LAUNDER
CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
COATING MAY CONTAIN MATERIALS CLASSIFIED AS NUISANCE PARTICULATES WHICH
MAY BE PRESENT AT HAZARDOUS LEVELS ONLY DURING SANDING/ABRADING OF
DRIED FILM. KEEP OUT OF REACH OF CHILDREN. OMPLETE LABELING. KEEP
OUT OF REACH OF CHILDREN. INTENTIONAL MISUSE BY DELIBERATELY
CONCENTRATING/INHALING CONTENTS CAN BE HARMFUL/FATAL.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:<0-360F
Vapor Density:>1
Evaporation Rate & Reference:FASTER THAN ETHER
Percent Volatiles by Volume:>75
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:HEAT/SPARKS/OPEN FLAMES/PILOT LIGHTS &
OTHER SOURCES OF IGNITION.
Hazardous Decomposition Products:CO2, CO
==================== Disposal Considerations ====================
Waste Disposal Methods:PRODUCT WASTE MAY BE HAZARDOUS AS DEFINED UNDER
THE RCRA. TEST WASTE FOR IGNITABILITY TO DETERMINE THE APPLICABLE
EPA HAZARDOUS WASTE NUMBERS. DON'T INCINERATE. DEPRESSURIZE
CONTAINER. DISPOSE OF IN A CCORDANCE W/FEDERAL, STATE & LOCAL
REGULATIONS.
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===================== Product Identification =====================
Product ID:SODIUM HEXAMETAPHOSPHATE
CAGE:1V771
CAGE:1V771
============= Composition/Information on Ingredients =============
Ingred Name:SODIUM PHOSPHATE, TRIBASIC(SARA III)
CAS:10124-56-8
RTECS #:OY3675000
Fraction by Wt: 90-100%
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT) IS 7250 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: IRRITATION OF UPPER
RESPIRATORY TRACT. SKIN: IRRITATION. EYE: IRRITATION.
Explanation of Carcinogenicity:NONE IDENTIFIED.
Effects of Overexposure:INGESTION: HEADACHE, NAUSEA, VOMITING,
DIZZINESS, GASTROINTESTINAL IRRITATION.
Medical Cond Aggravated by Exposure:NONE IDENTIFIED.
======================= First Aid Measures =======================
First Aid:INGESTION-IF SWALLOWED & PERSON IS CONSCIOUS, IMMEDIATELY
GIVE LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION. INHALATION-MOVE
THE EXPOSED PERSON TO FRESH AIR. SKIN-IMMEDIATELY WASH SKIN WITH
PLENTY OF SOAP AND WATER FOR AT LEAST 15 MINUTES. EYE-IMMEDIATELY
FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
===================== Fire Fighting Measures =====================
Extinguishing Media:USE EXTINGUISHING MEDIA APPROPIATE FOR SURROUNDING
FIRE.
Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE
EQUIPMENT & SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE
OPERATED IN POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:NONE IDENTIFIED.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR SUITABLE PROTECTIVE CLOTHING. CAREFULLY
SWEEP UP AND REMOVE.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED.
SUITABLE FOR ANY GENERAL CHEMICAL STORAGE AREA. STORE IN DRY AREA.
Other Precautions:NONE
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED WHERE ADEQUATE VENTILATION
CONDITIONS EXIST. IF AIRBORNE CONCENTRATIONS IS HIGH, USE AN
APPROPAITE RESPIRATOR OR DUST MASK.
Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP
FUME OR DUST LEVELS AS LOW AS POSSIBLE.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH AFTER HANDLING.
Supplemental Safety and Health
NONE
================== Physical/Chemical Properties ==================
HCC:N1
Melt/Freeze Pt:M.P/F.P Text:1022F,550C
Spec Gravity:1.20
Solubility in Water:COMPLETE
Appearance and Odor:WHITE GRANULAES. ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE IDENTIFIED.
Stability Condition to Avoid:MOISTURE, AIR.
Hazardous Decomposition Products:OXIDES OF PHOSPHORUS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH APPLICABLE LOCAL,
STATE AND FEDERAL ENVIRONMENTAL REGULATIONS.
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===================== Product Identification =====================
Product ID:SODIUM BISULFITE,7444,7448,S 85
CAGE:EO303
CAGE:0X801
CAGE:70829
CAGE:EO303
============= Composition/Information on Ingredients =============
Ingred Name:SODIUM BISULFITE (SASA III) (CERCLA)
CAS:7631-90-5
RTECS #:VZ2000000
Fraction by Wt: <0.001%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3; 9596
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:SODIUM METABISULFITE
CAS:7681-57-4
RTECS #:UX8225000
Fraction by Wt: 100%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3; 9596
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50(ORAL,RAT) 2000 MG/KG (NA BISULFITE)
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS: EYES, SKIN, RESPIRATORY
AND GASTROINTESTINAL TRACTS. ACUTE- INHALE: CAUSES IRRITATION TO
RESPIRATORY TRACT. EYE: CAUSES IRRITATION. MAY CAUSE EYE DAMAGE.
SKIN: CAUSES IRRITATION. ORAL: MAY CAUSE GASTRIC IRRITATION. LARGE
DOSES MAY CAUSE CNS DEPRESSION. ESTIMATED FATAL DOSE IS 10 GRAMS.
CHRONIC- UNKNOWN.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, TEARING, COUGHING, SHORTNESS OF
BREATH, NAUSEA, VOMITING, DIARRHEA, ABDOMINAL PAIN, CIRCULATORY
DISTURBANCES, HEADACHE, DIZZINESS, ITCHING, BLINDNESS
Medical Cond Aggravated by Exposure:SOME ASTHMATICS OR
SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE WHEEZING, CHEST
TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS, WEAKNESS AND DIARRHEA.
======================= First Aid Measures =======================
First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYE/SKIN:
IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN.
INHALED: MOVE TO FRESH AIR. PROVIDE OXYGEN/CPR IF NEEDED. ORAL: IF
CONSCIOUS, INDUC E VOMITING IMMEDIATELY AS DIRECTED BY MEDICAL
PERSONNEL. CALL A PHYSICIAN/POISON CONTROL CENTER IMMEDIATELY.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Lower Limits:NOT RELEVANT
Upper Limits:NOT RELEVANT
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL
FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED
CONTAINERS.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND
NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL
FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. VENTILATE AREA TO
REMOVE SULFUR DIOXIDE. WITH CLEAN, DRY SHOVEL, CAREFULLY PLACE
MATERIAL INTO CLEAN, DRY CONTAINER AND COVER; REMOVE FROM AREA.
AVOID GENERATING DUST. FLUSH SPILL AREA WITH WATER. AVOID ENTERING
SEWER/SOIL.
Neutralizing Agent:NOT RELEVANT
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY, VENTILATED AREA
AWAY FROM INCOMPATIBLES. RELEASES TOXIC SULFUR DIOXIDE GAS WHEN IN
CONTACT WITH WATER OR ICE.
Other Precautions:DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. AVOID
BREATHING DUST. PROTECT CONTAINER AGAINST PHYSICAL DAMAGE. WASH
THOROUGHLY AFTER HANDLING. DO NOT INGEST. KEEP OUT OF REACH OF
CHILDREN. EMPTY CONTAI NER RETAINS RESIDUE; SEE LABEL/MSDS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF ENGINEERING CONTROLS ARE INADEQUATE TO
CONTROL DUST/GAS LEVELS LOW, A NIOSH-APPROVED DUST
RESPIRATOR/RESPIRATOR WITH AN ACID GAS CARTRIDGE SHOULD BE WORN. IN
EMERGENCY, USE FULL-FACEPIECE POSITIVE PRESSURE AIR-SUPPLIED
RESPIRATOR.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP DUST/GAS
LEVELS AS LOW AS POSSIBLE.
Other Protective Equipment:EYE WASH STATION, QUICK DRENCH SHOWER AND
IMPERVIOUS CLOTHING
Work Hygienic Practices:GOOD PERSONAL HYGIENE PRACTICES REQUIRE THAT
GROSS AMOUNT OF ANY CHEMICAL BE REMOVED FROM THE SKIN AS SOON AS
PRACTICAL.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:N1
NRC/State Lic Num:NOT RELEVANT
Melt/Freeze Pt:=150.C, 302.F
Spec Gravity:1.48
Viscosity:NOT RELEVANT
Evaporation Rate & Reference:NOT RELEVANT
Solubility in Water:VERY
Appearance and Odor:COARSE WHITE GRANULES - SLIGHT ODOR OF SULFUR
DIOXIDE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS, WATER, ALKALIS, SODIUM NITRITE, OXIDIZERS, ALUMINUM POWDER
Stability Condition to Avoid:MOISTURE, HEAT, FLAMES
Hazardous Decomposition Products:OXIDES OF SULFUR
==================== Disposal Considerations ====================
Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECLAMATION MAY BE
DISPOSED OF IN AN APPROVED WASTE DISPOSAL FACILITY. ENSURE
COMPLIANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. DO NOT
CONTAMINATE ENVIRONMENT.
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