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BASF 18

===================== Product Identification ===================== Product ID:SILVER NITRATE SOLUTION HT101-2, COMPONENT OF HT101A CAGE:21076 CAGE:21076 ============= Composition/Information on Ingredients ============= Ingred Name:SILVER NITRATE. (EC NO: 231-853-9) CAS:7761-88-8 RTECS #:VW4725000 OSHA PEL:0.01 MG/M3 ACGIH TLV:0.01 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:LABEL PRECAUTIONARY STATEMENT: HARMFUL. HARMFUL IF SWALLOWED. IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN. POSSIBLE RISK OF IRREVERSIBLE EFFECTS. ACUTE EFFECTS: SKIN: CAUSES SKIN IRRITATION. MAYBE HARMFUL IF ABSORBED THROUGH SKIN. EYES: VAPOR OR MIST IRRITATING TO EYES. INHALATION: VAPOR OR MIST IS IRRITATING TO THE MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT. MAY BE HARMFUL IF INHALED. INGE STION: HARMFUL IF SWALLOWED. INGESTION CAN CAUSE SEVERE GASTROENTERITIS THAT MAY BE FATAL. MAY CAUSE ARGYRIA (SLATE-GRAY OR BLUISH DISCOLORATION OF SKIN AND DEEP TISSUES DUE TO THE DEPOSIT OF INSOLUBL E ALBUMINATE OF SILVER). (OVEREXPOSURE) Effects of Overexposure:HEALTH HAZARDS ACUTE/CHRONIC (CONT'D): ABSORPTION INTO BODY LEADS TO THE FORMATION OF METHEMOGLOBIN WHICH IN SUFFICIENT CONCENTRATION CAUSES CYANOSIS. ONSET MAY BE DELAYED 2 TO 4 HOURS OR LONGER. CHRO NIC EFFECTS: TARGET ORGAN(S): EYES, NERVES, BLOOD, LUNGS. LABORATORY EXPERIMENTS HAVE SHOWN MUTAGENIC EFFECTS. ======================= First Aid Measures ======================= First Aid:INGESTION: IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL A PHYSICIAN. INHALATION: REMOVE TO FRESH AIR. IF BREATHING BECOMES DIFFICULT, CALL A PHYSICIAN. SKIN: IN CASE OF C ONTACT, IMMEDIATELY WASH SKIN WITH SOAP AND COPIOUS AMOUNTS OF WATER. EYES: IN CASE OF CONTACT, FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. ASSURE ADEQUATE FLUSHING BY SEPARATING THE EYELIDS WITH FINGERS. CALL A PHYSICIAN. ===================== Fire Fighting Measures ===================== Extinguishing Media:CARBON DIOXIDE, WATER SPRAY, DRY CHEMICAL POWDER OR APPROPRIATE FOAM. Fire Fighting Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES. Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR NIOSH-APPROVED SELF-CONTAINED BREATHING VERMICULITE AND PLACE IN CLOSED CONTAINERS FOR DISPOSAL. VENTILATE AREA AND WASH SPILL S ITE AFTER MATERIAL PICKUP IS COMPLETE. EVACUATE AREA. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP TIGHTLY CLOSED. STORE IN A COOL, DRY PLACE. Other Precautions:DO NOT BREATHE VAPOR. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A NIOSH-APPROVED RESPIRATOR APPROPRIATE FOR THE EXPOSURE OF CONCERN . Ventilation:MECHANICAL EXHAUST REQUIRED. FACESHIELD . Other Protective Equipment:SAFETY SHOWER AND EYE BATH MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Vapor Density:5.8 G/L Spec Gravity:1.015 Appearance and Odor:LIQUID; NO ODOR SPECIFIED BY MANUFACTURER . ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES PROTECT FROM LIGHT. ALCOHOLS, AMMONIA, MAGNESIUM, STRONG BASES, STRONG REDUCING AGENTS. INCOMPATIBLE WITH: CHLORIDES, CARBONATES, THIOCYANATES, FERROUS SALTS, CHLOROSULFONIC ACID, ARSENIC POWDER, CHLORIDE TRIFLUORIDE OR PHO Stability Condition to Avoid:MAY DECOMPOSE ON EXPOSURE TO LIGHT. Hazardous Decomposition Products:SILVER/SILVER OXIDES. NITROGEN OXIDES. Conditions to Avoid Polymerization:WILL NOT OCCUR. ===================== Ecological Information ===================== Ecological:DATA NOT YET AVAILABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTACT A LICENSED PROFESSIONAL WASTE DISPOSAL SERVICE TO DISPOSE OF THIS MATERIAL. OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION. ===================== Regulatory Information ===================== Federal Regulatory Information:EUROPEAN INFORMATION: CATALOG # HT101-2. NAME: SILVER NITRATE SOLUTION. EC INDEX NO: 047-001-00-2. HARMFUL. R22 HARMFUL IF SWALLOWED. R/36/78/38. IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN. R40 P OSSIBLE RISK OF IRREVERSIBLE EFFECTS. S26 IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND SEEK MEDICAL ADVICE. S36 WEAR SUITABLE PROTECTIVE CLOTHING. State Regulatory Information:N/P. MATERIALS TO AVOID (CONT'D):IODIDE. SOLUTIONS OF SILVER NITRATE WITH AMMONIA, AMMONIA SODIUM CARBONATE, OR AMMONIA/SODIUM HYDROXIDE HAVE HAD SEVERAL INSTANCES OF EXPLOSIONS REPORTED. REACTION W ITH ACEALDEHYDE, ACETYLENE OR OTHER TERMINAL ALKYNES MAY PRODUCE EXPLOSIVE COMPOUNDS. A DRY MIXTURE OF POWDERED MAGNESIUM AND SILVER NITRATE HAS BEEN REPORTED TO IGNITE EXPLOSIVELY ON CONTACT WITH A D ROP OF WATER. A MIXTURE WITH CHARCOAL IGNITES WHEN STRUCK WITH A HAMMER WHILE MIXTURES WITH PHOSPHOR US OR SULFUR EXPLODE WHEN STRUCK. PASSAGE OF PHOSPHINE GAS INTO A SOLUTION OF SILVER NITRATE RESULTED IN AN EXPLOSION. (OTHER INFORMATION) ======================= Other Information =======================

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