text
stringlengths
542
18.7k
label
int64
0
1
label_text
stringclasses
2 values
===================== Product Identification ===================== Product ID:FBX TANK CAR INSULATION CAGE:FO322 CAGE:7X148 CAGE:FO322 ============= Composition/Information on Ingredients ============= Ingred Name:VITREOUS MINERAL FIBER ACGIH TLV:10 MG/CUM (DUST) Ingred Name:CURED RESIN Other REC Limits:10 MG/CUM (DUST) ACGIH TLV:10 MG/CUM (DUST) ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: MAY CAUSE TRANSITORY IRRITATION OR RASH TO SKIN, EYES, OR RESPIRATORY TRACT. NON-TOXIC, NON-CORROSIVE. Explanation of Carcinogenicity:NONE Effects of Overexposure:MAY CAUSE TRANSITORY IRRITATION OR RASH TO SKIN, EYES, OR RESPIRATORY TRACT. Medical Cond Aggravated by Exposure:RASH TO SKIN ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER. DON'T RUB. IF IRRITATION CONTINUES, CONSULT A PHYSICIAN. SKIN: WASH WITH SOAP AND WATER. DON'T RUB. IF IRRITATION PERSISTS, CONSULT A PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:NON-FLAMMABLE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:IF FIBERS OR PARTICLES ARE RELEASED, USE VACUUM OR WET CLEANUP PROCEDURES TO MINIMIZE AIRBORNE DUST. ======================Handling and Storage ====================== Handling and Storage Precautions:WASH AFTER HANDLING. DON'T GET IN EYES OR ON SKIN. DON'T BREATHE DUST. LAUNDER WORK CLOTHES SEPARATELY AND CLEAN WASHER AFTER USE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH-APPROVED DUST RESPIRATOR IF TLV IS EXCEEDED. Ventilation:WORK AREAS SHOULD BE WELL VENTILATED TO MINIMIZE THE POSSIBILITY OF EXCEEDING TLV LEVELS. Other Protective Equipment:LOOSE FITTING CLOTHING Work Hygienic Practices:LAUNDER WORK CLOTHES SEPARATELY AND CLEAN WASHER AFTER USE. Supplemental Safety and Health FIBREX PRODUCTS MAY INCLUDE FACING PRODUCTS, SUCH AS STAINLESS STEEL MESH OR FOIL-SKRIM-KRAFT. ================== Physical/Chemical Properties ================== Solubility in Water:NEGLIGIBLE Appearance and Odor:YELLOW TO TAN ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, STRONG ALKALIS Hazardous Decomposition Products:CO & CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE TO SOLID WASTE LANDFILL.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:SODIUM SILICOFLUORIDE TECHNICAL CAGE:MO428 CAGE:81684 CAGE:MO428 ============= Composition/Information on Ingredients ============= Ingred Name:DISODIUM SILICO FLUORIDE CAS:16893-85-9 RTECS #:VV8410000 Fraction by Wt: 100% OSHA PEL:2.5 MG/M3 (F) ACGIH TLV:2.5 MG/M3 (F); 8990 ===================== Hazards Identification ===================== Effects of Overexposure:GASTRO-INTESTINAL SYMPTOMS.IRRITATION OF EYES,SKIN,& MUCONS MEMBRANES. ======================= First Aid Measures ======================= First Aid:SKIN & EYES:FLUSH WITH WATER FOR 15 MIN.CALL DOC.INGESTION-INDUCE VOMITING.GIVE SUBSTANCE WITH HIGH CALCIUM CONTENT,E,G,MILK,EGG WHITES PN H*2O,LIME WATER,WEAK CALCIUM CHLORIDE,CALL A MD.INHALATION RE MOVE TO FRESH AIR.CALL A MD. ===================== Fire Fighting Measures ===================== Extinguishing Media:NONE Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE IGNITION SOURCES. STOP LEAK. EVACUATE AREA.DO NOT TOUCH SPILLAGE. SM SPILL:ABSORB W. INERT ABSORBENT. PLACE IN CLOSED CONTAINER. FLUSH AREA W. WATER. LG. SPILL:DIKE AHEAD FOR LATER DISPOSAL. NOTIFY AUTHORITIES. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENT,LOW FIRE RISK AREA. PROTECT FROM PHYSICAL DAMAGE.AVOID ANY PHYSICAL CONTACT. KEEP CONTAINERS TIGHTLY CLOSED. Other Precautions:WASH ALL CONTAMINATED CLOTHING BEFORE REUSE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED DUST RESPIRATOR. Ventilation:LOCAL EXHAUST TO ELIMINATE MISTS/FUMES/GASES. Other Protective Equipment:FULL FACE SHLD;FULL PROT. CLTHG/BOOTS; COVERALLS; PROT.APRON Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:T3 Boiling Pt:B.P. Text:DECOMPOSES Spec Gravity:2.679. Solubility in Water:0.75 % Appearance and Odor:WHITE,CRYSTALLINE,ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STR MNL ACIDS, ORG ACIDS, OXID AGTS, RED. AGTS, STR ALK. Stability Condition to Avoid:NONE Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:KEEP IN COVERED DRUMS,PENDING DISPOSAL. HANDLE & DISPOSE IN FULL COMPLIANCE WITH ALL APPLICABLE INTERNATIONAL,FEDERAL,STATE, & LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:R-1075 CAGE:5U206 CAGE:5U206 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III) CAS:71-55-6 RTECS #:KJ2975000 Fraction by Wt: 40%. OSHA PEL:350 PPM/450 STEL ACGIH TLV:350 PPM/450STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ozone Depleting Chemical:1 Ingred Name:METHYL ETHYL KETOXIME,CAS#96-29-7.(MFR STATES GIVEN OFF DURING CURE) CAS:96-29-7 RTECS #:EL9275000 Ingred Name:SILICON CAS:7440-21-3 RTECS #:VW0400000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 ===================== Hazards Identification ===================== Effects of Overexposure:IRRITATING TO EYES,MUCOUS MEMBRANES,AND IN HIGH CONC.,NARCOTIC. ======================= First Aid Measures ======================= First Aid:WASH AREAS EXPOSED W/SOAP AND WATER. REMOVE TO FRESH AIR. FLUSH EYES WITH FRESH WATER. FOR SEVERE EXPOSURE GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:CO*2, FOAM, DRY CHEM. Fire Fighting Procedures:NONE SPECIFIED Unusual Fire/Explosion Hazard:NONE SPECIFIED ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN SPILL;SMALL SPILLS:SOAK UP W/ABSORBENT;LG SPILLS:REMOVE BY VACUUMING.-STORE IN APPROPRIATE DISPOSAL CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT. Other Precautions:THE CONTAINERS SHOULD BE KEPT CLOSED WHEN NOT IN USE TO PREVENT CURE AND SOLVENT EVAPORATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:APPVD ORG.VAP.RESP.WHEN TLV IS EXCEEDED Ventilation:PROVIDE MECHAN(GEN/LOCAL EXHAUST)VENT TO MAINTN <TLV Other Protective Equipment:NONE SPECIFIED Supplemental Safety and Health UNDATED MSDS. ================== Physical/Chemical Properties ================== HCC:T4 Boiling Pt:B.P. Text:165F,74C Spec Gravity:1.19 Evaporation Rate & Reference:1.39 (CCL*4=1) Appearance and Odor:TRANSLUCENT THICK LIQUID,SWEET SMELL. Percent Volatiles by Volume:36. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED Stability Condition to Avoid:NONE SPECIFIED Hazardous Decomposition Products:SIO*2,CO*2,CO,CHLORINATED BYPRODUCTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW LOCAL,STATE,FEDERAL REGS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:CITRIKLEEN HD CAGE:56883 CAGE:56883 ============= Composition/Information on Ingredients ============= Ingred Name:2-(2-BUTOXYETHYOXY)-ETHANOL, DIETHYLENE GLYCOL MONOBUTYL ETHER (BUTYL CARBITOL) CAS:112-34-5 RTECS #:KJ9100000 Ingred Name:2-AMINOETHANOL, ETHANOLAMINE, MONOETHANOLAMINE CAS:141-43-5 RTECS #:KJ5775000 Other REC Limits:3 PPM OSHA PEL:3 PPM ACGIH TLV:7.5 MG/CUM Ingred Name:DIETHANOLAMINE CAS:111-42-2 RTECS #:KL2975000 Other REC Limits:3 PPM ACGIH TLV:13 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Ingred Name:D-LIMONENE Ingred Name:FATTY ACID SOAPS Ingred Name:NON-IONIC SURFACTANT Ingred Name:DIPROPYLENE GLYCOL CAS:25265-71-8 RTECS #:UB8765000 Ingred Name:PINE OIL SOAP *94-2* CAS:8002-09-3 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION W/SLIGHT BURNS UPON CONTACT. SKIN: PROLONGED CONTACT MAY CAUSE IRRITATION, POSSIBLE BURNS. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, BURNS, DRYNESS, HEADACHE, NAUSEA, REDNESS, DIZZINESS Medical Cond Aggravated by Exposure:CUTS, ABRASIONS, DERMATITIS ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: FLUSH W/WATER FOR SEVERAL MINS. INHALATION: REMOVE TO FRESH AIR. PERFORM CPR IF NEEDED. INGESTION: GIVE LARGE AMOUNTS OF MILK/WATER. DON'T INDUCE VOMITING. OBTIA N MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:125F Extinguishing Media:CO2, DRY POWDER, FOAM TYPE Fire Fighting Procedures:TREAT AS CLASS B (OIL TYPE) FIRE. COOL CONTAINERS W/WATER. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE MATERIAL. REMOVE IGNITION SOURCES. RECOVER FREE LIQUID. USE ABSORBENTS AS NEEDED. RINSE AREA W/WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE & AWAY FROM HEAT & OPEN FLAME. DON'T REUSE CONTAINERS. KEEP OUT OF REACH OF CHILDREN. Other Precautions:AVOID PROLONGED/REPEATED BREATHING OF CONCENTRATED VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED UNDER NORMAL CONDITIONS. Ventilation:ADEQUATE VENTILATION & AIR MOVEMENTS INCLUDING OPEN DOORS, WINDOWS/EXHAUST FANS RECOMMENDED. Other Protective Equipment:RUBBER APRON & QUANTLETS, EYE BATH & SAFETY SHOWER. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F7 Boiling Pt:B.P. Text: 212F Vapor Pres:AS WATER Vapor Density:AS WATER Spec Gravity:0.950 pH:11.2 Evaporation Rate & Reference:(ACETONE=1): <0.1 Solubility in Water:EMULSIFIES Appearance and Odor:CLEAR AMBER LIQUID W/CITRUS WINTERGREEN ODOR. Percent Volatiles by Volume: 75 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS & OXIDIZERS Stability Condition to Avoid:HEAT, OPEN FLAME Hazardous Decomposition Products:CO & CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. NA 1760.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:KLEEN KING 125 WHITEWALL CLEANER CAGE:EO722 CAGE:EO722 CAGE:24653 ============= Composition/Information on Ingredients ============= Ingred Name:OCTYL PHENOXY POLYETHOXY ETHANOL Fraction by Wt: 2% Ingred Name:2-BUTOXYETHANOL CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: 5% OSHA PEL:S, 50 PPM ACGIH TLV:S, 25 PPM; 9293 Ingred Name:SODIUM SILICATE CAS:6834-92-0 RTECS #:VV9275000 Fraction by Wt: 6% ===================== Hazards Identification ===================== Effects of Overexposure:EYE, SKIN AND RESPIRATORY IRRITATION ======================= First Aid Measures ======================= First Aid:INGESTION: CONTACT A PHYSICIAN, DON'T INDUCE VOMITING. EYE: FLUSH W/WATER FOR 15 MINUTES, SEEK MEDICAL ATTENTION. SKIN: FLUSH W/WATER, IF IRRITATION PERSISTS, SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NON-COMBUSTIBLE Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN SPILL, MOP UP OR RINSE TO DRAIN ======================Handling and Storage ====================== Handling and Storage Precautions:CORROSIVE TO EYES. AVOID CONTACT WITH EYES AND SKIN AND BREATHING OF VAPOR. USE WITH ADEQUATE NTILATION. KEEP OUT OF THE REACH OF CHILDREN. Other Precautions:STORE IN A COOL AREA, PROTECT FROM FREEZING. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED FOR NORMAL USE Ventilation:LOCAL EXHAUST. MECHANICAL: ACCEPTABLE Other Protective Equipment:NOT REQUIRED FOR NORMAL USE Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:1.12 Solubility in Water:COMPLETE Appearance and Odor:CLEAR LIQUID WITH GLYCOL ETHER ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, STRONG OXIDIZING AND REDUCING AGENTS ==================== Disposal Considerations ==================== Waste Disposal Methods:IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:EPICARE LOTION SOAP CAGE:89044 CAGE:89044 ============= Composition/Information on Ingredients ============= Ingred Name:NON HAZARDOUS INGREDIENTS Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: MAY CAUSE MILD IRRITATION OF EYES ON CONTACT. CHRONIC: NONE SPECIFIED BY MANUFACTURER. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES: REDNESS, TEARING, DISCOMFORT. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH LOTS OF WATER FOR 15 MINUTES. SEE DOCTOR. SWALLOWED: RINSE MOUTH, THEN , IF CONSCIOUS, DRINK 1-2 GLASSES OF WATER. DO NOT INDUCE VOMITING. SEE DOCTOR. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN SPILL. ABSORB WITH INERT MATERIAL AND PLACE IN A CONTAINER FOR DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN DRY AREA. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. Ventilation:NONE NORMALLY REQUIRED. Other Protective Equipment:NONE NORMALLY REQUIRED. Work Hygienic Practices:FOLLOW STANDARD PERSONAL HYGENE PRACTICES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:>212F,>100C Spec Gravity:1.03-1.04 pH:9-10 Solubility in Water:COMPLETE Appearance and Odor:BLUE, PEARLESCENT; PLEASANT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:DO NOT MIX WITH ANYTHING EXCEPT WATER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
0
gloves_not_mandatory
===================== Product Identification ===================== Product ID:3-BROMOPROPIONITRILE, 99%, 10923-1 CAGE:60928 CAGE:60928 ============= Composition/Information on Ingredients ============= Ingred Name:PROPIONITRILE, 3-BROMO-;(BROMOPROPIONITRILE) CAS:2417-90-5 RTECS #:UG1050000 ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:(IPR, MUS):50 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:HARMFUL BY INHALATION, INGESTION OR SKIN ABSORPTION. VAPOR OR MIST IS IRRITATING TO EYES, MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. CAUSES SKIN IRRITATION. THE CHEMICAL, PHYSICAL AND TOXICOL OGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SKIN:FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING & SHOES. DISCARD CONTAMINATED CLO THING AND SHOES. INHAL:MOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT GIVE OXYGEN. INGEST:WASH OUT MOUTH W/WATER PROVIDED PERSON IS CONSCIOUS. CALL MD. ===================== Fire Fighting Measures ===================== Flash Point:207F,97C Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL POWDER, OR APPROPRIATE FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR NIOSH/MSHA APPROVED SCBA, RUBBER BOOTS KEEP IN A CLOSED CONTAINER AND HOLD FOR WASTE DISPOSAL. VENTILATE AREA AND WASH SPILL SIT E AFTER MATERIAL PICKUP IS COMPLETE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL DRY PLACE. KEEP CONTAINER CLOSED. HARMFUL LIQUID AND FUMES. Other Precautions:DO NOT BREATHE VAPOR. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. IRRITANT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:MECHANICAL EXHAUST REQUIRED. Other Protective Equipment:SAFETY SHOWER AND EYE BATH. OTHER PROTECTIVE CLOTHING. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:169F,76C Spec Gravity:1.615 Appearance and Odor:COLORLESS LIQUID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, STRONG BASES, STRONG OXIDIZING AGENTS, STRONG REDUCING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE, AND NITROGEN OXIDES. HYDROGEN BROMIDE GAS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISSOLVE OR MIX MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER. DISPOSAL MUST BE I/A/W FEDERAL, STATE AND LOCAL REGULATIONS .
1
gloves_mandatory
===================== Product Identification ===================== Product ID:2103 HARVEST RED, INDUSTRIAL MAINTENANCE (SUPDAT) CAGE:IO479 CAGE:IO479 CAGE:09800 ============= Composition/Information on Ingredients ============= Ingred Name:PROPANE (PROPELLANT) VP: 780.0 CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 13% OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT; 9495 Ingred Name:BUTANE; (PROPELLANT) VP: 700.0 CAS:106-97-8 RTECS #:EJ4200000 Fraction by Wt: 7% OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT; 9495 Ingred Name:BENZENE, ETHYL-; (ETHYL BENZENE) (SARA 313) CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 2% OSHA PEL:100 PPM ACGIH TLV:100 PPM/125STEL;9495 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENE (SARA 313) (CERCLA) VP: 5.9 CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 10% OSHA PEL:100 PPM ACGIH TLV:100 PPM/150STEL;9495 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BUTYL ALCOHOL; (N-BUTANOL) (SARA 313) (CERCLA) CAS:71-36-3 RTECS #:EO1400000 Fraction by Wt: 1% OSHA PEL:100 PPM ACGIH TLV:S, C 50 PPM; 9495 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ACETONE (SARA 313) (CERCLA) VP: 180.0 CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 35% OSHA PEL:1000 PPM ACGIH TLV:750PPM/1000STEL;9495 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:2-BUTANONE; (METHYL ETHYL KETONE) (MEK) (SARA 313) (CERCLA) VP: 70.0 CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 8% OSHA PEL:200 PPM ACGIH TLV:200 PPM/300STEL;9495 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:2-PENTANONE, 4-METHYL-; (METHYL ISOBUTYL KETONE) (HEXONE) (SARA 313) (CERCLA) VP: 10.0 CAS:108-10-1 RTECS #:SA9275000 Fraction by Wt: 3% OSHA PEL:100 PPM ACGIH TLV:50 PPM/75 STEL; 9495 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ACETIC ACID,2-METHOXY-1-METHYLETHYL ESTER; (1-METHOXY-2-PROPANOL ACETATE) VP: 1.8 CAS:108-65-6 RTECS #:AI8925000 Fraction by Wt: 7% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT:REPORTS HAVE ASSOCIATED REPEATED & PROLONGED OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYS DMG. RTECS #:9999999ZZ Ingred Name:WASTE DISP METH:DO NOT INCINERATE. DEPRESSURIZE CNTNR. DISPOSE OF I/A/W/FED, STATE, & LOCAL REGS REGARDING POLLUTION. RTECS #:9999999ZZ Ingred Name:OTHER PREC:DO NOT PUNCTURE, INCINERATE/EXPOSE TO TEMP ABOVE 120F. HEAT FROM SUNLIGHT, RADIATORS, STOVES, HOT (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:H*2O, & OTHER HEAT SOURCES COULD CAUSE CNTNR TO BURST. DO NOT TAKE INTERNALLY. KEEP OUT OF THE REACH OF (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:CHILDREN. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING THE CONTENTS CAN BE HARMFUL/FATAL. (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15:USE ONLY WITH ADEQUATE VENTILATION. AVOID BREATHING VAPOR AND SPRAY MIST. AVOID CONTACT WITH SKIN AND EYES. RTECS #:9999999ZZ Ingred Name:VENT:LIMITS. REFER TO OSHA STANDARDS 1910.56, 1910.107, 1910.108 RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:HDCH, DIZZ, NAUSEA, & LOSS OF COORDINATION ARE INDICATIONS OF EXCESSIVE EXPOS TO VAPS/SPRAY MISTS. REDNESS & ITCHING/BURNING SENSATION MAY INDICATE EYE/EXCESSIVE SKIN EXPOS. ACUTE:IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERVOUS SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCONSCIOUSNESS & POSS DEATH. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:CHRONIC:PRLNG OVEREXP TO SOLV INGREDS IN INGRED SECTION MAY CAUSE ADVERSE EFFECTS TO THE LIVER, URINARY, BLOOD-FORMING, CVS, & REPROD SYS. METHYL ETHYL KETONE MAY INCR THE NERVOUS SYS EFFECTS OF OTHER SOLVS. RATE EXPOSED TO TITANIUM DIOXIDE DUST AT 250 MG/M3 DEVELOPED LUNG CANCER, HOWEVER, SUCH EXPOS (SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE. EYES: FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGEST: GET MEDICAL ATTENTIONS. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:<0F,<-18C Lower Limits:0.9% Upper Limits:13.1% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . IF H*2O IS USED, FOG NOZZLES ARE PREF. H*2O MAY BE USED TO COOL CLSD CNTNRS TO PVNT PRESS BUILD-UP & (SUPDAT) Unusual Fire/Explosion Hazard:ISOLATE FROM HEAT, ELEC EQUIP, SPARKS, & OPEN FLAMES. CLSD CNTNRS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. APPLICATN TO HOT SURFS REQUIRES SPECIAL (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FRON HEAT, SPARKS, AND OPEN FLAME. VAPORS WILL ACCUMULATE READILY AND MAY IGNITE EXPLOSIVELY. DURING USE AND UNTIL ALL VAPORS ARE GONE. Other Precautions:KEEP AREA VENT-DO NOT SMOKE-EXTING ALL FLAMES, PILOT LIGHTS, & HEATERS-TURN OFF STOVES, ELECTRIC TOOLS & APPLICANCES, & ANY OTHER SOURCES OF IGNIT. CONSULT NFPA CODE. USE APPRVD BONDING & GROUNDING PR OC. CONTENTS UNDER PRESS. (ING 13) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW APPLICABLE LIMITS BY VENTILATION, WEAR A PROPERLY FITTED ORGANIC VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH FOR PROTECTION AGAINST MATERIALS IN INGR EDIENT SECTION. Ventilation:LOC EXHST PREF. GEN EXHST ACCAPTABLE IF THE EXPOS TO MATLS IN INGRED SECTION IS MAINTAINED BELOW APPLIC EXPOS (ING 17) Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH HANDS AFTER USING. Supplemental Safety and Health MFR'S TRADE NAME/PART #:TOUCH UP SPRAY COLORS. FIRE FIGHT PORC:POSS AUTOIGNITION/EXPLOSION WHEN EXPOSED TO EXTREME HEAT. EXPLO HAZ:PREC. DURING EMER CNDTNS OVEREXP TO DECOMP PROD MAY CAUSE HLTH HAZ. S YMPS MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN. EFTS OF OVEREXP:LEVELS ARE NOT ATTAINABLE IN THE WORKPLACE. (ING 11) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:<302F,<150C Vapor Pres:SEE INGRED Vapor Density:HVR/AIR Volatile Org Content %:88 Evaporation Rate & Reference:FASTER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF METALS IN INGREDIENT SECTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM THIS PROD MAY BE HAZS AS DEFINED UNDER THE RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERM THE APPLIC EPA HAZ WASTE NUMBER. WASTE FROM PROD CNTNG METHYL ETHYL KETONE/COPPPE R MAY REQ TESTING FOR EXTRACTABILITY. (ING 12) ======================= Other Information =======================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:74-6630, PHOSPHORUS ENRICHMENT SOLUTION (KIT COMPONENT) Kit Part:Y CAGE:59896 Contract Num:MDA414-00-P-1314 CAGE:59896 Contract Num:MDA414-01-P-0841 CAGE:59896 Contract Num:MDA414-98-A-O-118-0127 CAGE:59896 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM DIHYDROGEN PHOSPHATE MONOHYDRATE OR SODIUM PHOSPHATE, MONOBASIC CAS:10049-21-5 = Wt:.03 OSHA PEL:NONE ACGIH TLV:NONE ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): 8290MG/KG Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:POTENTIAL HEALTH EFFECTS: EYES: MAY BE IRRITATING TO THE EYES. SKIN: NOT EXPECTED TO BE HAZARDOUS BY CONTACT. INGESTION: MAY CAUSE GASTROINTESTINAL DISTURBANCES IF INGESTED IN LARGE QUANTITIES. INHAL ATION: NOT EXPECTED TO BE A HAZARD BY INHALATION. TARGET ORGANS: NO INFORMATION AVAILABLE. Explanation of Carcinogenicity:NO INGREDIENT LISTED AS CAUSING CANCER BY IARC, NTP OR OSHA. Effects of Overexposure:POTENTIAL HEALTH EFFECTS: EYES: MAY BE IRRITATING TO THE EYES. SKIN: NOT EXPECTED TO BE HAZARDOUS BY CONTACT. INGESTION: MAY CAUSE GASTROINTESTINAL DISTURBANCES IF INGESTED IN LARGE QUANTITIES. INHAL ATION: NOT EXPECTED TO BE A HAZARD BY INHALATION. TARGET ORGANS: NO INFORMATION AVAILABLE. Medical Cond Aggravated by Exposure:NO INFORMATION AVAILABLE. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES, RAISING AND LOWERING EYELIDS OCCASIONALLY. GET MEDICAL ATTENTION. SKIN: THOROUGHLY WASH EXPOSED AREA WITH SOAP AND WATER FOR AT LEAST 15 MINUTES. REMOVE CONTAMINATED CLOTHING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE. IF IRRITATION DEVELOPS OR PERSISTS, GET MEDICAL ATTENTION. INGESTION: NOT A HAZARD UNDER NORMAL CONDITIONS OF USE. INHALATION: NOT A HAZARD UNDER NORMAL CONDITIONS OF USE. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE MEDIA SUITABLE TO EXTINGUISH SURROUNDING FIRE. Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR FULL PROTECTIVE EQUIPMENT AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACE-PIECE OPERATED IN THE PRESSURE DEMAND OR OTHER POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF SPILL. CLEANUP PERSONNEL SHOULD WEAR PROPER PROTECTIVE CLOTHING AND EQUIPMENT. ABSORB ON VERMICULITE OR OTHER SUITABLE ABSORBENT MATERIAL. WHEN SATURATED, SHOVEL OR SCOOP UP AND CONT AINERIZE FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP IN TIGHTLY CLOSED CONTAINER. STORE AT CONTROLLED ROOM TEMPERATURE. Other Precautions:NONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NEEDED UNDER NORMAL CONDITIONS OF USE WITH ADEQUATE VENTILATION. Ventilation:NONE NEEDED. Other Protective Equipment:LAB COAT, EYE WASH, SAFETY SHOWER. Work Hygienic Practices:NEVER WEAR CONTACTS IF WORKING WITH CHEMICALS. Supplemental Safety and Health ITEM IS A TWO PART KIT CONSISTING OF PHOSPHORUS ENRICHMENT SOLUTION AND NITROGEN ENRICHMENT SOLUTION. SEE MSDS SERIAL # CKVHZ.. CONTRACTOR'S PART NUMBER/TRADE NAME: DISSOLVED OXYGEN & AQUATIC/ITEM 74- 6630. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:=100.C, 212.F B.P. Text:APPROXIMATELY Melt/Freeze Pt:=0.C, 32.F M.P/F.P Text:APPROXIMATELY Vapor Pres:17.5 MM HG Vapor Density:0.7 Spec Gravity:NO INFO Evaporation Rate & Reference:~1 (WATER=1) Solubility in Water:COMPLETE Appearance and Odor:CLEAR, ODORLESS SOLUTION. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER REACTIVE MATERIALS. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:NONE INDICATED. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information=================== Toxicological Information:TOXICITY DATA: TO THE BEST OF OUR KNOWLEDGE THE TOXICOLOGICAL PROPERTIES OF THIS MIXTURE HAVE BEEN THOROUGHLY EVALUATED. DATA IS LISTED FOR INDIVIDUAL COMPONENTS. ALL DATA RTECS, 1986.SODIUM PHOSPHATE , MONOBASIC - LD50(ORAL-RAT) - 8290. EFFECTS OF OVEREXPOSURE: CHRONIC: SODIUM PHOSPHATE, MONOBASIC: NO TOXICITY DATA FOUND (RTECS, 1986). NOT LISTED AS CAUSING CANCER BY IARC, NTP OR OSHA. ===================== Ecological Information ===================== Ecological:EPA WASTE NUMBER: NONE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APLICABLE FEDERAL, STATE AND LOCAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:NON-REGULATED MATERIAL. ===================== Regulatory Information ===================== SARA Title III Information:HAZARD CATEGORY FOR SARA SECTION 311/312 REPORTING: ACUTE. SARA EHS SECT. 302: SODIUM PHOSPHATE, MONOBASIC-NO. SARA SECT. 313 CHEMICALS: SODIUM PHOSPHATE, MONOBASIC-NO. Federal Regulatory Information:EPA TSCA STATUS: THE INGREDIENTS OF THIS PRODUCT ARE ALL ON THE TSCA INVENTORY LIST. CERCLA SECT. 103: SODIUM PHOSPHATE, MONOBASIC-NO. RCRA: SODIUM PHOSPHATE, MONOBASIC-NO ======================= Other Information =======================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:741036 BROWN 3279 CAGE:61196 CAGE:61196 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL SPIRITS CAS:64475-85-0 RTECS #:PY8240000 Fraction by Wt: 35% ACGIH TLV:500 PPM Ingred Name:TRIETHYLAMINE (SARA III) CAS:121-44-8 RTECS #:YE0175000 Fraction by Wt: <0.5% OSHA PEL:25 PPM/15 STEL ACGIH TLV:10 PPM/15 STEL; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Effects of Overexposure:INHALATION-ANESTHETIC,IRRITATION OF RESPIRATORY TRACT OR ACUTE NERVOUS SYSTEM DEPRESSION. ======================= First Aid Measures ======================= First Aid:CONTACT-FLUSH SKIN AND EYES WITH WATER WHILE REMOVING CONTAMINATED CLOTHING. INHALATION-REMOVE TO FRESH AIR. CALL PHYSICIAN IF SYMPTOMS PERSIST. ===================== Fire Fighting Measures ===================== Flash Point:104F, 40C TCC Lower Limits:1.10 Extinguishing Media:NFPA CLASS B EXTINGUISHER; POLYMER FOAM FOR LARGE FIRES Fire Fighting Procedures:SELF CONTAINED BREATHING APPARATUS SHOULD BE AVAILABLE Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. AVOID BREATHING VAPORS. VENTILATE AREA. REMOVE WITH INERT ABSORBENT AND NON-SPARKING TOOLS. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE ABOVE 120F STORE LARGE QUANTITIES IN BUILDING DESIGNED TO COMPLY WITH OSHA 1910.106 Other Precautions:GROUND CONTAINERS WHEN POURING.AVOID FREE FALL OF LIQUID IN XS OF FEW INCHES DO NOT FLAME CUT, BRAZE OR WELD COATED MATERIAL WITHOUT BUR OF MINES APPROVED RESPIRATOR OR APPROPRIATE VENTILATION ============= Exposure Controls/Personal Protection ============= Respiratory Protection:OPEN AREA:BUR MINES MECH RESPIRATOR;CLOSED:BUR MINES CHEM/MECH FILTE Ventilation:GENERAL DILUTION OR LOCAL EXHAUST TO KEEP TLV BELOW LIMIT Other Protective Equipment:PREVENT PROLONGED SKIN CONTACT TO CONTAMINATED CLOTHING Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:311-373F Vapor Density:>AIR Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:59 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS-INCINERATE IN APPROVED FACILITY-DO NOT INCINERATE CLOSED CONTAINERS.
1
gloves_mandatory
======================================================= NIIN: 00-004-4333 Product ID: DURO 80249 WHITE PLASTIC RUBB; WPR-1 DURO WHITE PLASTIC RUB. Cage: 08028 ======================================================= Preparer Co. when other than Responsible Party Co. ======================================================= Cage: 08028 ======================================================= Contractor Summary ======================================================= Cage: 08028 Cage: 05972 ======================================================= Item Description Information ======================================================= Item Name: SEALING COMPOUND Specification Number: UNKNOWN Type/Grade/Class: NONE Type of Container: TUBE ======================================================= Ingredients ======================================================= Cas: 78-93-3 RTECS #: EL6475000 % Wt: 25-30 Other REC Limits: NONE RECOMMENDED OSHA PEL: 200 PPM ACGIH TLV: 200 PPM/300STEL;9394 EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 64742-89-8 % Wt: 30-35 Other REC Limits: NONE RECOMMENDED OSHA PEL:: 400 PPM ------------------------------ Cas: 110-82-7 RTECS #: GU6300000 % Wt: <5 Other REC Limits: NONE RECOMMENDED OSHA PEL: 300 PPM ACGIH TLV: 300 PPM, 9394 EPA Rpt Qty: 1000 LBS DOT Rpt Qty: 1000 LBS ------------------------------ % Wt: 40-50 Other REC Limits: NONE RECOMMENDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED ----------------------------- % Wt: TRACE Other REC Limits: NONE RECOMMENDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: UNKNOWN Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: EYE IRRITANT. TOXIC BY INGEST/INHAL. CAN IRRITATE NOSE, THROAT, SKIN & EYES. Explanation Of Carcinogenicity: PER MSDS:CARCINOGEN:NTP/IARC/ OSHA:NO. Signs And Symptions Of Overexposure: EXCESSIVE INHALATION CAUSES HEADACHE,DIZZINESS,NAUSEA,LEADING TO ANESTHESIS IN VERY HIGH CONCENTRATIONS. Medical Cond Aggravated By Exposure: NONE KNOWN. TARGET ORGANS:LIVER/NERVOUS SYTEM/RESPIRATORY SYSTEM/GASTROINTESTINAL TRACT. First Aid: INGEST:DO NOT INDUCE VOMITING. CALL PHYSICIAN IMMED. INHAL:REMOVE TO FRESH AIR. CALL PHYSICIAN. SKIN:WASH W/LARGE AMTS OF WATER. EYE:FLUSH W/WATER FOR @LEAST 15MINS. SEEK MED HELP. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: REMOVE SOURCES OF IGNITION, SPARKS. USE ADEQUATE VENTILATION. AVOID BREATHING VAPORS. CLEAN UP WITH NON-SPARKING TOOLS. Waste Disposal Methods: LANDFILL OR INCINERATE FOLLOWING EPA & LOCAL REGULATIONS. Handling And Storage Precautions: DO NOT SMOKE. TURN OFF ALL SOURCES OF IGNITION. VAPORS MAY FLASH & EXPLODE. AVOID PROLONG BREATHING OF VAPORS & CONTACT WITH SKIN. KEEP AWAY FROM EYES Other Precautions: NONE SPECIFIED BY MANUFACTURER. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: TCC Flash Point Text: 0F/-18C Extinguishing Media: DRY POWDER, FOAM, CO2. Fire Fighting Procedures: NONE SPECIFIED BY MANUFACTURER. HOWEVER USE APPROPRIATE PROT CLOTHING/EQPMT AS CONDITIONS WARRANT. Unusual Fire/Explosion Hazard: VAPORS MAY CAUSE FLASH FIRE. VAPORS MAY IGNITE EXPLOSIVELY. ======================================================= Control Measures ======================================================= Respiratory Protection: NONE SPECIFIED BY MANUFACTURER. Ventilation: SUFFICIENT TO MAINTAIN VAPOR CONCENTRATION BELOW TLV. Other Protective Equipment: NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices: WASH HANDS AFTER HANDLING. USE GOOD CHEMICAL HYGIENE PRACTICE. ======================================================= Physical/Chemical Properties ======================================================= HCC: F2 B.P. Text: 150F,66C Vapor Pres: 50 MM Vapor Density: >1 Spec Gravity: 1.0 Solubility in Water: NEGLIGIBLE Appearance and Odor: WHITE LIQUID,KETONE ODOR ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER. HOWEVER AVOID ALL SOURCES OF IGNITION. Materials To Avoid: STRONG OXIDIZING AGENTS. Hazardous Decomposition Products: NON-THERMAL:NONE KNOWN. FIRE/THERMAL:OXIDES OF CARBON. Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Trans ID NO: 43318 Product ID: DURO 80249 WHITE PLASTIC RUBB; WPR-1 DURO WHITE PLASTIC RUB. Review Date: 03/01/1995 Net Unit Weight: 4 OZ Multiple KIT Number: 0 Review IND: Y Type Of Container: TUBE Additional Data: PER MSDS:DOT PROPER SHIPPING NAME:FLAMM LIQUIDS, CLASS 3, IATA:FLAMM LIQ, CLASS 3, UN1133. ======================================================= Detail DOT Information ======================================================= DOT PSN Code: AFR DOT Proper Shipping Name: ADHESIVES, DOT PSN Modifier: CONTAINING A FLAMMABLE LIQUID Hazard Class: 3 UN ID Num: UN1133 DOT Packaging Group: II Label: FLAMMABLE LIQUID Special Provision: B52,T,T30 Packaging Exception: 150 Non Bulk Pack: 173 Bulk Pack: 242 Max Qty Pass: 5 L Max Qty Cargo: 60 L Vessel Stow Req: B ======================================================= Detail IMO Information ======================================================= IMO PSN Code: AIH IMO Proper Shipping Name: ADHESIVES, IMO PSN Modifier: CONTAINING A FLAMMABLE LIQUID o IMDG Page Number: 3174 UN Number: 1133 UN Hazard Class: 3.2 IMO Packaging Group: I/II* Subsidiary Risk Label: - EMS Number: 3-05 MED First Aid Guide NUM: 330 ======================================================= Detail IATA Information ======================================================= IATA PSN Code: AKY IATA UN ID Num: 1133 IATA Proper Shipping Name: ADHESIVES IATA PSN Modifier: ,CONTAINING FLAMMABLE LIQUID IATA UN Class: 3 IATA Label: FLAMMABLE LIQUID UN Packing Group: II Packing Note Passenger: 305 Max Quant Pass: 5L Max Quant Cargo: 60L Packaging Note Cargo: 307 Exceptions: A7 ======================================================= Detail AFI Information ======================================================= AFI PSN Code: AKY AFI Proper Shipping Name: ADHESIVES AFI PSN Modifier: ,CONTAINING FLAMMABLE LIQUID AFI Hazard Class: 3 AFI UN ID NUM: UN1133 AFI Packing Group: II Special Provisions: P5 Back Pack Reference: A7.3 ======================================================= HAZCOM Label ======================================================= Product ID: DURO 80249 WHITE PLASTIC RUBB; WPR-1 DURO WHITE PLASTIC RUB. Cage: 08028 Company Name: LOCTITE CORP AUTOMOTIVE AND CONSUMER GROUP Street: 4450 CRANWOOD COURT Zipcode: 44128-4004 Label Required IND: Y Date Of Label Review: 03/01/1995 Status Code: C Label Date: 03/01/1995 Origination Code: F Skin Protection IND: YES Signal Word: DANGER Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: Severe Reactivity Hazard: None Hazard And Precautions: EYE IRRITANT. TOXIC BY INGEST/INHAL. CAN IRRITATE NOSE, THROAT, SKIN & EYES. DO NOT SMOKE. TURN OFF ALL SOURCES OF IGNITION. VAPORS MAY FLASH & EXPLODE. AVOID PROLONG BREATHING OF VAPORS & CONTACT WIT H SKIN. KEEP AWAY FROM EYES. TARGET ORGANS:GASTROINTESTINAL TRACT/LIVER/RESPIRATORY SYS/NERVOUS SYSTEM. FIRST AID: INGEST:DO NOT INDUCE VOMITING. CALL PHYSICIAN IMMED. INHAL:REMOVE TO FRESH AIR. CALL PHYSICIAN. SKIN:WASH W/LARGE AMTS OF WATER. EYE:FLUSH W/WATER FOR @LEAST 15MINS. SEEK MED HELP. =======================================================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:MULTIGRADE II RP ACTIVATOR CAGE:64145 CAGE:64145 ============= Composition/Information on Ingredients ============= Ingred Name:POTASSIUM HYDROXIDE (SARA III) CAS:1310-58-3 RTECS #:TT2100000 Fraction by Wt: 9-12% OSHA PEL:C, 2 MG/M3 ACGIH TLV:C 2 MG/M3; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:POTASSIUM SULFITE CAS:10117-38-1 Fraction by Wt: 1-3% Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 80-85% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PRODUCT CAUSES SEVERE EYE, SKIN & G/I TRACT IRRITATION AND CAUSES BURNS WITH PROLONGED/REPEATED CONTACT. RESPIRATORY EXPOSURE IS UNUSUAL WITH NORMAL INDUSTRIAL HANDLING, BUT BREATHING A MIST WILL CAU SE RESPIRATORY IRRITATION. Explanation of Carcinogenicity:PRODUCT HAS NO CARCINOGENS LISTED BY IARC, NTP, OR OSHA. Effects of Overexposure:EYE:SEVERE IRRITATION, BURNS SKIN:IRRITATION, AND MAY CAUSE ALLERGIC DERMATITIS INHALED:UNLIKELY EXPOSURE,MAY CAUSE IRRITATION. INGESTED:MAY BE HARMFUL IF SWALLOWED. HMIS:MAY CAUSE G/I IRRITATION,N AUSEA,VOMITING, G/I BURNS Medical Cond Aggravated by Exposure:MAY CAUSE IRRITANT DERMATITIS ======================= First Aid Measures ======================= First Aid:EYE:FLUSH WITH WATER 15 MIN.SKIN:REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. WASH SKIN WITH SOAP AND WATER. INHALED: REMOVE TO FRESH AIR. INGESTED:IF CONSCIOUS,GIVE 1-2 GLASSES OF WATE R DO NOT INDUCE VOMITING. (NOTHING BY MOUTH IF UNCONSCIOUS.) GET IMMEDIATE MEDICAL CARE. IF ANY IRRITATION PERSISTS OR IS SEVERE, SEE A DOCTOR. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:USE MEDIA APPROPRIATE FOR SOURCE OF FIRE. Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:RECOVER AS LIQUID OR MOP UP WITH CLOTH,PAPER,ETC. OR NEUTRALIZE AND FLUSH TO DRAIN. Neutralizing Agent:ACETIC ACID ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,DRY,WELL VENTILATED AREA. KEEP AWAY FROM ACIDS. Other Precautions:READ LABEL AND FOLLOW DIRECTIONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. USE NIOSH/MSHA APPROVED RESPIRATOR IF PEL/TLV IS EXCEEDED DURING MIXING OPERATIONS. Ventilation:NORMAL ROOM VENTILATION IS SUFFICIENT. SUPPLEMENT WITH LOCAL EXHAUST WHEN MIXING. Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER. USE APRON AND FACE SHIELD WHEN POURING LIQUIDS OR IF SPLASHING IS LIKELY. Work Hygienic Practices:USE GOOD CHEMICAL HYGIENE PRACTICE. AVOID UNNECESSARY CONTACT. Supplemental Safety and Health ILFORD STOCK NUMBER MG9112310 (MSDS DATE 07NOV88) 5 GALLON ACTIVATOR. MSDS ALSO COVERS THE ACTIVATOR CONTAINED IN KIT NO MG9112300. NO COD IS GIVEN BY MFR. ALSO SEE ADD.DATA. ================== Physical/Chemical Properties ================== HCC:B1 Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:18 MM Vapor Density:0.6 Spec Gravity:1.106 pH:>13 Evaporation Rate & Reference:AS WATER Solubility in Water:COMPLETE Appearance and Odor:CLEAR COLORLESS LIQUID, NO ODOR Percent Volatiles by Volume:90 WT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS. Stability Condition to Avoid:NO INFORMATION GIVEN BY MANUFACTURER Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE I/A/W FEDERAL,STATE,LOCAL REGULATIONS. MFR SUGGESTS NEUTRALIZE THEN FLUSH TO SEWER IF PERMITTED.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:BATTERY SEALED NON-SPILLABLE CAGE:04055 CAGE:04055 ============= Composition/Information on Ingredients ============= Ingred Name:LEAD (SARA 313) (CERCLA) CAS:7439-92-1 RTECS #:OF7525000 Fraction by Wt: 43-70% OSHA PEL:SEE 1910.1025 ACGIH TLV:0.15 MG/M3 DUST EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:SULFURIC ACID (SARA 302/313) (CERCLA) CAS:7664-93-9 RTECS #:WS5600000 Fraction by Wt: 6-12% OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3/3 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ANTIMONY (SARA 313) (CERCLA) CAS:7440-36-0 RTECS #:CC4025000 Fraction by Wt: 0-4% OSHA PEL:0.5 MG/M3 ACGIH TLV:0.5 MG (SB)/M3 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ARSENIC (SARA 313) (CERCLA) CAS:7440-38-2 RTECS #:CG0525000 Fraction by Wt: <0.01% OSHA PEL:SEE 1910.1018 ACGIH TLV:0.01 MG/M3, A1 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:POLYPROPYLENE CAS:9003-07-0 RTECS #:TR5000000 Fraction by Wt: 5-10% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SILICA, AMORPHOUS (FUMED); (SILICON DIOXIDE) CAS:112945-52-5 RTECS #:VV7310000 Fraction by Wt: 5-15% OSHA PEL:6 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:CALCIUM CAS:7440-70-2 RTECS #:EV8040000 Fraction by Wt: <1% OSHA PEL:1.0 MG/M3 (MFR) ACGIH TLV:1.0 MG/M3 (MFR) ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: AVOID CONT. GELLED MATL MAY CAUSE IRRIT OF EYES, NOSE & THROAT. CONT W/EYES & SKIN CAUSES IRRIT & SKIN BURNS. GELLED MATL IS CORR. DO NOT OPEN BATTERY, AVOID CONT W/INTERNAL COMPONENTS. INTERNA L COMPONENTS INCL LEAD & GELLED ELECTROLYTE. ELECTROLYTE IS CORR & CONT MAY CAUSE SKIN IRRIT & CHEM (EFTS OF OVEREXP) Explanation of Carcinogenicity:ANTIMONY OXIDE: IARC MONOGRAPHS, VOLUME 47, PAGE 291, 1989: GROUP 2B. ANIMAL: NEOPLASTIGENIC, CVS & LUNG EFTS. SULFURIC ACID: IARC MONOGRAPHS, VOLUME 54, PAGE 41, 1992: GROUP 1. ANIMAL: PULMONARY IRRI TATION. Effects of Overexposure:HLTH HAZ: BURNS. CHRONIC: LEAD APPEARS ON THE NAVY OCCUP CHEM REPRO HAZ LIST. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS INFO . Medical Cond Aggravated by Exposure:NOT APPLICABLE. ======================= First Aid Measures ======================= First Aid:SKIN: FLUSH W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. REMOVE CONTAM CLOTHING & OBTAIN MEDICAL ATTENTION IF NECESSARY. EYES: WASH (FOR AT LEAST 15 MINUTES) &/OR EMERGENCY SHOWER SHOULD BE READI LY AVAILABLE. INGESTION: GIVE LARGE VOLUMES OF WATER. DO NOT INDUCE VOMITING. OBTAIN MEDICAL TREATMENT. INHALATION: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE OXYGEN/ARTIFICIAL RESPIRATION) . ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Lower Limits:4% Upper Limits:74% Extinguishing Media:CLASS ABC EXTINGUISHER, CARBON DIOXIDE. Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP . COOL EXTERIOR OF BATTERY IF EXPOSED TO FIRE TO PVNT RUPTURE. ACID MIST & VAPS IN FIRE SITUATION ARE CORROSIVE. Unusual Fire/Explosion Hazard:HYDROGEN GAS, WHICH MAY EXPLODE IF IGNITED, IS PRDCED BY BATTERY, WHEN CHARGING. USE ADEQ VENT, AVOID OPEN FLAMES, SPKS/OTHER SOURCES OF IGNITION NEAR BATTERY. ================== Accidental Release Measures ================== Spill Release Procedures:GELLED MATERIAL IS CORROSIVE. CONTAINS SULFURIC ACID. NEUTRALIZE ANY SPILLED MATERIAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM REACTIVE MATERIAL AS DEFINED IN REACTIVITY DATA SECTION. Other Precautions:IF BATTERY CASE IF BROKEN, AVOID DIRECT CONTACT WITH INTERNAL COMPONENTS. KEEP AWAY FROM IGNITION SOURCES DURING CHARGING. DOT EMERGENCY RESPONSE GUIDE #154. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT APPLICABLE. USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:MUST BE PROVIDED WHEN CHARGING IN AN ENCLOSED AREA. FACESHIELD . Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:GOOD PERSONAL HYGIENE AND WORK PRACTICES ARE RECOMMENDED. Supplemental Safety and Health HAZ DECOMP PROD: NASCENTHYDROGEN MAY GENERATE HIGHLY TOX ARSINE GAS. ================== Physical/Chemical Properties ================== Evaporation Rate & Reference:<1.0 (BUTYL ACETATE=1) Appearance and Odor:CELLED ELECTROLYTE. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES SULFURIC ACID: CONT W/COMBUSTS & ORG MATLS MAY CAUSE FIRE & EXPLO. ALSO REACTS VIOLENTLY W/STRONG REDUCING AGENTS, METALS, STRONG OXIDIZERS & WATER. CONT W/METALS MAY PRDCE TOX SULFUR DIOXIDE FUMES & MAY RELEASE FLAM HYDROG Stability Condition to Avoid:PROLONGED OVERCHARGING, SOURCES OF IGNITION. Hazardous Decomposition Products:SULFURIC ACID: EXCESS OVERCHARGING/FIRE MAY CREATE SULFUR TRIOXIDE, CARBON MONOXIDE, SULFURIC ACID MIST, SULFUR DIOXIDE, & HYDROGEN. LEAD CMPDS:CONT W/STRONG ACIDS/BASES/PRESENCE OF (SUP DAT) ==================== Disposal Considerations ==================== Waste Disposal Methods:LEAD-ACID BATTERIES ARE COMPLETELY RECYCLABLE. FOR INFORMATION ON RETURNING BATTERIES TO MANUFACTURER FOR RECYCLING, CONTACT YOUR MANUFACTURER REPRESENTATIVE. DISPOSE OF ANY COLLECTED MATERIAL I/A/W L OCAL, STATE OR APPLICABLE FEDERAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:VINYL PATCH LF, 106-7796 Z1-250-1 CAGE:55138 CAGE:55138 ============= Composition/Information on Ingredients ============= Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:METHYL ETHYL KETONE;(2-BUTANONE). VP:70 @ 20C. CAS:78-93-3 RTECS #:EL6475000 OSHA PEL:200 PPM;300 STEL ACGIH TLV:200 PPM;300 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TOLUENE. VP:22 @ 20C CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 40% OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:OTHER PREC:VESSEL. NOTE:TOLUENE CAS#108-88-3 APPEARS ON THE NAVY LISTING OF OCCUP REPROD HAZ. SEEK CONSULTATION (ING 5) RTECS #:9999999ZZ Other REC Limits:NONE SPECIFIED Ingred Name:ING 4:FROM APPROP HEALTH PROFESSIONALS CONCERN LATEST HAZ LIST INFO AND SAFE HANDLING & EXPOS RECOMMENDATIONS . RTECS #:9999999ZZ Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INGEST:CAN CAUSE GI IRRITATION, NAUSEA & VOMITING. ASPIR OF MATL INTO LUNG MAY CAUSE CHEM PNEUM WHICH CAN BE FATAL. INHAL:MAY CAUSE NOSE/THROAT IRRIT. HIGH CONC MAY CAUSE ACUTE CNS DEPRESS CHARACTERIZ ED BY HDCH, DIZZ, NAUS & CONFUSION. EYE:MAY CAUSE IRRITATION. SKIN:MAY CAUSE DEFATTING & IRRITATION OF SKIN. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:REPEATED OVEREXPOSURE TO TOLUENE MAY CAUSE LIVER DMG. RPTS HAVE ASSOC PRLNGD/RPTD OCCUP OVEREXP TO SOLVS W/PERM BRAIN/ NERV SYS DMG. INTENTIONAL MISUSE BY DELIBERATELY CONC & INHALING CONTENTS MAY BEHARMFUL/FATAL. TOLUENE HAS BEEN FOUND TO CAUSE KIDNEY, LUNG AND SPLEEN DAMAGE IN LABORATORY ANIMALS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST:DO NOT INDUCE VOMIT. CALL POIS CTL CTR, HOSP EMER ROOM OR MD IMMED. INHAL:REMOVE TO FRESH AIR IMMED. IF BRTHG HAS STOPPED, GIVE ARTF RESP. KEEP WARM & QUIET. GET MD IMMED. EYE:FLUSH W/ LGE AMTS OF WATER FOR AT LEAST 15 MINS, LIFTINGUPPER & LOWER LIDS OCCASIONALLY. GET MD. SKIN:REMOVE CONTAM CLTHG. WASH AFFECTED AREA W/SOAP & WATER. GET MD IF IRRIT PERSISTS. NOTE TO MD:ANY TREATMENT (SUPDAT ===================== Fire Fighting Measures ===================== Flash Point:24.0F,-4.4C Extinguishing Media:USE NFPA CLASS B FIRE EXTINGUISHERS (CO2, ALL PURP DRY CHEM, ALCOHOL FOAM) DESIGNED TO EXTING FLAMM LIQ (SUPP DATA) Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . WATER MAY BE INEFTIVE, BUT MAY BE USED TO COOL CLSD CNTNRS TO PVNT PRESS BUILD-UP & POSS AUTOIGNIT(SUPDAT) Unusual Fire/Explosion Hazard:DURING EMERGENCY CONDITIONS, OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT. GET MD. ================== Accidental Release Measures ================== Spill Release Procedures:KEEP SPECTATORS AWAY. ELIMINATE ALL IGNIT SOURCES (FLAMES/HOT SURFS/SOURCES OF ELEC, STATIC, FRICTIONAL SPARKS). DIKE/CNTN SPILL W/INERT MATL (E.G., SAND, EARTH). TRANSFER LIQ TO COVERED METAL CNTNRS FOR DISP. PVNT CONTAM OF SEWERS, STREAMS,(SUPDAT) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE ABOVE 95F. STORE LARGE QUANTITIES IN COMPLIANCE WITH OSHA 29 CFR 1910.106. Other Precautions:DO NOT TAKE INTERNALLY.CLOSE CNTNR AFTER EACH USE. EMPTY CNTNRS MUST NOT BE WASHED/REUSED FOR ANY PURP.CNTNRS SHOULD BE GROUNDED/BONDED TO RECEIVING CNTNR.DO NOT WELD/BRAZE/CUT EMPTY CNTNR. NEVER USE PRESS TO EMPTY.DRUM IS NOT PRESS (ING 4) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:REFER TO ORIGINAL MSDS . Ventilation:PROVIDE GEN DILUTION/LOC EXHST VENT IN VOLUME & PATTERN TO MAINTAIN CONC OF HAZ SUBS BELOW LOWEST EXPOS LIMITS STATED. Other Protective Equipment:NOT LIKELY TO BE NEEDED. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EXTING MEDIA:FIRES. POLYMER FOAM IS PREF FOR LGE FIRES. FIRE FIGHT PROC:OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. FIRST AID PROC:THAT MIGHT BE REQ FOR OV EREXP SHOULD BE DIRECTED AT CNTRL OF SYMPS & CLINICAL CNDTNS. SPILL PROC:& GROUNDWATER W/SPILLED MATL OR USED ABSORBENT. ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:B.P. Text:162F,72C Vapor Pres:SEE ING Vapor Density:HVR/AIR Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:73 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS OR ALKALINE MATERIALS. Stability Condition to Avoid:AVOID EXCESSIVE HEAT AND SOURCES OF IGNITION. Hazardous Decomposition Products:BURNING, INCLUDING WHEN HEATED BY WELDING OR CUTTING, WILL PRODUCE SMOKE, CO, CO2. Conditions to Avoid Polymerization:KEEP AWAY FROM HEAT, SPARKS AND FLAME. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISP I/A/W FED, STATE & LOC LAWS. INCIN ONLY IN EPA PERMITTED FACILITY. DO NOT INCIN CLSD CNTNRS. OBSERVE PRECS FOR DISP OF FLAMM MATLS. CONTAM ABSORB MAY BE DISP OF IN HAZ WASTE LANDFILL. DISP ONLY I /A/W FED, STATE AND LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:MS-2000; HARDENER COMPONENT Kit Part:Y CAGE:AMSAT CAGE:88444 CAGE:AMSAT ============= Composition/Information on Ingredients ============= Ingred Name:1,2-ETHANEDIAMINE, N-(2-AMINOETHYL)-N-'-(2-((2-AMINOETHYL)AMINO)ETHYL); (TETRAETHYLENEPENTAMINE) CAS:112-57-2 RTECS #:KH8585000 Fraction by Wt: 4% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:POLYAMIDE RESIN CAS:68410-23-1 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:BUTYL ALCOHOL; (N-BUTYL ALCOHOL) CAS:71-36-3 RTECS #:EO1400000 Fraction by Wt: 20% OSHA PEL:100 PPM ACGIH TLV:S, C 50 PPM; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYES: CAUSES SEVERE IRRIT/BURNS. MAY CAUSE PERMANENT VISUAL IMPAIRMENT. SKIN: CAUSES SEVERE IRRIT/BURNS. MAY BE ABSORBED THRU SKIN IN HARMFUL AMOUNTS. INHAL: MAY CAUSE UPPER RESPIRATORY TRACT I RRITATION. INGEST: MAY CAUSE BURNS OF MOUTH & THROAT. CONTAINS MATERIAL THAT MAY BE SLIGHTLY TOXIC. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: OVEREXPOSURE EFTS: IRRITATION, SENSITIZATION AND DERMATITIS. Medical Cond Aggravated by Exposure:ALLERGY, ECZEMA AND OTHER SKIN CONDITIONS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. WASH CONTACT AREA WITH MILD SOAP AND WATER. INHAL: REMOVE TO FRESH AIR. IF S YMPTOMS PERSIST CONSULT A PHYSICIAN. INGEST: DO NOT INDUCE VOMITING. IF CONSCIOUS, GIVE LARGE QY OF WATER TO DILUTE. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:>100F,>38C Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, CHEMICAL FOAM/WATER. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . ELIMINATE ALL IGNITION SOURCES. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY RUPTURE (DUE TO BUILD UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT. DECOMP & COMBUSTION PRODUCTS MAY BE TOXIC. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. DIKE SPILL. ABSORB W/INERT MATERIAL AND COLLECT FOR DISPOSAL. FLUSH CONTAMINATED AREA WITH WATER; PREVENT WASHINGS FROM ENTERING WATERWAYS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID ALL PERSONAL CONTACT. DO NOT EXCEED 110F/43C IN STORAGE AREA. GROUND AND BOND METAL CONTAINERS FOR LIQUID TRANSFER TO AVOID STATIC SPARKS. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE IF REQUIRED. Ventilation:EXPLO-PROOF MECH VENT & LOC EXHAUST RECOM. MECH EXHAUST IS NOT RECOM AS SOLE MEANS OF CONTROLLING EMPLOYEE EXPOSURE. Other Protective Equipment:IN OPERATIONS WHERE CONT MAY OCCUR COVERALLS, APRON & IMPERVIOUS FOOT COVERING ARE RECOM. SFTY SHOWER & EYE (SUPP DATA) Work Hygienic Practices:IMMEDIATELY REMOVE AND THOROUGHLY LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health OTHER PROT EQUIP: WASH FACILITY SHOULD BE AVAILABLE TO EMPLOYEES. ================== Physical/Chemical Properties ================== Spec Gravity:0.96 Solubility in Water:PARTIALLY SOLUBLE Appearance and Odor:AMBER LIQUID, SOLVENT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:EXCESSIVE HEAT. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND OXIDES OF NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:IPA-ANHYDROUS Resp. Party Other MSDS Num.:MSDS NUMBER: 90275000 Preparer's Name:NOT PROVIDED CAGE:TO317 Contract Num:SP0411-02-M-E614 CAGE:4N760 Contract Num:SP0450-00-M-SF75 CAGE:4N760 CAGE:TO317 ============= Composition/Information on Ingredients ============= Ingred Name:THIS PRODUCT IS HAZARDOUS AS DEFINED IN29 CFR1910.1200. ===================== Hazards Identification ===================== Health Hazards Acute and Chronic:POTENTIAL HEALTH EFFECTS: EYE CONTACT: IRRITATING, AND MAY INJURE EYE TISSUE IF NOT REMOVED PROMPTLY. SKIN CONTACT: FREQUENT OR PROLONGED CONTACT MAY IRRITATE AND CAUSE DERMATITIS. LOW ORDER OF TOXICI TY. INHALATION: VAPOR CONCENTRATIONS ABOVE EXPOSURE LEVELS ARE IRRITATING TO THE EYES AND RESPIRATORY TRACT, MAY CAUSE HEADACHES AND DIZZINESS, ARE ANESTHETIC AND MAY HAVE OTHER CENTRAL NERVOUS SYSTEM EFFECTS. NEGLIGIBLE HAZARD AT AMBIENT TEMPERATURE. INGESTION: MINIMAL TOXICITY. SMALL AMOUNTS OF THE LIQUID ASPIRATED INTO THE RESPIRATORY SYSTEM DURING INGESTION, OR FROM VOMITING, MAY CAUSE BRONCHI OPNEUMONIA OR PULMONARY EDEMA. Effects of Overexposure:EYE CONTACT: IRRITATING. SKIN CONTACT: FREQUENT OR PROLONGED CONTACT MAY IRRITATE AND CAUSE DERMATITIS. INHALATION: VAPOR CONCENTRATIONS ABOVE EXPOSURE LEVELS ARE IRRITATING TO THE EYES AND RESPIRATOR Y TRACT, MAY CAUSE HEADACHES AND DIZZINESS, ARE ANESTHETIC. ======================= First Aid Measures ======================= First Aid:EYE CONTACT: IMMEDIATELY FLUSH EYES WITH LARGE AMOUNT OF WATER FOR AT LEAST 15 MINUTES. GET PROMPT MEDICAL ATTENTION. SKIN CONTACT: IMMEDIATELY FLUSHWITH LARGE AMOUNT OF WATER; USE SOAP IF AVAILABLE . REMOVE CONTAMINATED CLOTHING, INCLUDING SHOES, AFTER FLUSHING HAS BEGUN. INHALATION: USING PROPER RESPIRATORY PROTECTION, IMMEDIATELY REMOVE THE AFFECTED VICTIM FROM EXPOSURE. ADMINISTER ARTIFICIAL RESPIRATION IF BREATHING IS STOPPED. KEEP AT REST. CALL FOR PROMPT MEDICAL ATTENTION. INGESTION: IF SWALLOWED, DO NOT INDUCE VOMITING. KEEP AT REST. GET PROMPT MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:=11.7C, 53.F Autoignition Temp:>350.C, 662.F Lower Limits:2.0 Upper Limits:12.7 Extinguishing Media:EITHER ALLOW FIRE TO BURN OUT UNDER CONTROLLED CONDITIONS OR EXTINGUISH WITH FOAM, OR DRY CHEMICAL. TRY TO COVER LIQUID SPILLS WITH FOAM. Fire Fighting Procedures:USE WATER SPRAY TO COOL FIRE EXPOSED SURFACES AND TO PROTECT PERSONNEL. SHUT OFF "FUEL" TO FIRE. IF A LEAK OR SPILL HAS NOT IGNITED, USE WATER SPRAY TO DISPERSE THE VAPORS. Unusual Fire/Explosion Hazard:FLAMMABLE LIQUID, CAN RELEASE VAPORS THAT FORM FLAMMABLE MIXTURES AT TEMPERATURES AT OR ABOVE THE FLASHPOINT. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE IGNITION SOURCES. PREVENT ADDITIONAL DISCHARGES, IF POSSIBLE. SMALL SPILLS: IMPLEMENT CLEANUP PROCEDURES; LARGE SPILLS: IMPLEMENT CLEANUP PROCEDURES AND KEEP PUBLIC AWAY AND ADVISE AUTHORITI ES. PREVENT LIQUID FROM ENTERING SEWERS, WATERCOURSES, LOW AREAS. CONTAIN WITH SAND OR EARTH. DO NOT USE COMBUSTIBLE MATERIAL SUCH AS SAWDUST. RECOVER WITH EXPLOSION-PROOF PUMP OR SUITABLE ABSORBENT. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. HANDLE AND OPEN CONTAINERS WITH CARE. STORE IN A COOL, WELL VENTILATED PLACE AWAY FROM INCOMPATIBLE MATERIALS. DO NOT HANDLE OR STORE NEAR AN OPEN FLAME, HEAT OR OTHER SOURCES O F IGNITION. PROTECT MATERIAL FROM DIRECT SUNLIGHT. Other Precautions:THIS MATERIAL IS NOT A STATIC ACCUMULATOR, BUT USE PROPER BONDING AND/OR GROUNDING PROCEUDRES. DO NOT PRESSURIZE, CUT, HEAT, OR WELD CONTAINERS. EMPTY PRODUCT CONTAINERS MAY RETAIN PRODUCT RESIDUE. DO NOT REUSE EMPTY CONTAINERS WITHOUT COMMERCIAL CLEANING OR RECONDITIONING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE CONCENTRATIONS IN AIR MAY EXCEED THE LIMITS GIVEN AND ENGINEERING, WORK PRACTICE OR OTHER MEANS OF EXPOSURE REDUCTION ARE NOT ADAQUATE, NIOSH/MSHA APPROVED RESPIRATORS MAY BE NECESSARY TO PREVEN T OVEREXPOSURE BY INHALATION. Ventilation:THE USE OF MECHANICAL DILUTION VENTILATION IS RECOMMENDED WHENEVER PRODUCT IS USED IN CONFINED SPACES, IS HEATED/AGITATED. EXPLOSION-PROOF VENTILATION EQUIPMENT Other Protective Equipment:WEAR LONG SLEEVES. Supplemental Safety and Health "EMPTY" CONTAINERS RETAIN PRODUCT RESIDUE (LIQUID AND/OR VAPOR) AND CAN BE DANGEROUS. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS OR OTHE R IGNITION SOURCES: THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:180-181F Melt/Freeze Pt:=-88.7C, -128.F Vapor Pres:36 @ 212F Vapor Density:>1 Spec Gravity:0.79 Viscosity:2.2 CST @ 68F Evaporation Rate & Reference:2.3 (N-BUTYL ACETATE=1) Solubility in Water:100% @ 68F Appearance and Odor:CLEAR COLORLESS LIQUID Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CAUSTICS, AMINES, ALKANOLAMINES, ALDEHYDES, AMMONIA, STRONG OXIDIZING AGENTS, AND CHLORINATED COMPOUNDS. Stability Condition to Avoid:MODERATE RISK OF PEROXIDE FORMATION. MODERATE PEROXIDE HAZARD ON STORAGE AND CONCENTRATION. INHIBITOR NOT BEEN ADDED TO MITIGATE PEROXIDE HAZARD. Hazardous Decomposition Products:NONE =================== Toxicological Information=================== Toxicological Information:POTENTIAL HEALTH EFFECTS: EYE CONTACT: IRRITATING, AND MAY INJURE EYE TISSUE IF NOT REMOVED PROMPTLY. SKIN CONTACT: FREQUENT OR PROLONGED CONTACT MAY IRRITATE AND CAUSE DERMATITIS. LOW ORDER OF TOXICI TY. INHALATION: VAPOR CONCENTRATIONS ABOVE EXPOSURE LEVELS ARE IRRITATING TO THE EYES AND RESPIRATORY TRACT, MAY CAUSE HEADACHES AND DIZZINESS, ARE ANESTHETIC AND MAY HAVE OTHER CENTRAL NERVOUS SYSTEM EFFECTS. NEGLIGIBLE HAZARD AT AMBIENT TEMPERATURE. INGESTION: MINIMAL TOXICITY. SMALL AMOUNTS OF THE LIQUID ASPIRATED INTO THE RESPIRATORY SYSTEM DURING INGESTION, OR FROM VOMITING, MAY CAUSE BRONCHI OPNEUMONIA OR PULMONARY EDEMA. ===================== Ecological Information ===================== Ecological:NO SPECIFIC ECOLOGICAL DATA ARE AVAILABLE FOR THIS PRODUCT. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT AN EXPERT ON DISPOSAL OF RECOVERED MATERIAL AND ENSURE CONFORMITY TO LOCAL DISPOSAL REGUALTIONS. =================== MSDS Transport Information =================== Transport Information:DEPARTMENT OF TRASNPORTATION (DOT): DOT SHIPPING DESCRIPTION: ISOPROPANOL, 3, UN 1219, I I. ===================== Regulatory Information ===================== SARA Title III Information:UNDER THE PROVISIONS OF TITLE III, SECTIONS 311/312 OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT, THIS PRODUCT IS CLASSIFIED INTO THE FOLLOWING HAZARD CATEGORIES: IMMEDIATE HEALTH, DELAYED HEAL TH, FIRE. THIS INFORMATION MAY BE SUBJECT TO THE PROVISIONS OF THE COMMUNITY RIGHT-TO-KNOW REPORTING REQUIREMENTS (40 CFR 370) IF THRESHOLD QUANTITY CRITERIA ARE MET. Federal Regulatory Information:THIS PRODUCT IS LISTED ON THE TSCA INVENTORY AT CAS REGISTRY NUMBER 67-63-0. CERCLA: IF THIS PRODUCT IS ACCIDENTALLY SPILLED, IT IS NOT SUBJECT TO ANY SPECIAL REPORTING UNDER THE REQUIREMENT OF THE CO MPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT (CERCLA). WE RECOMMEND YOU CONTACT LOCAL AUTHORITIES TO DETERMINE IF THERE MAY BE OTHER LOCAL REPORTING REQUIREMENTS. ======================= Other Information =======================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:METAPHOSPHORIC ACID, PX1004 CAGE:0SK29 CAGE:0SK29 CAGE:63612 ============= Composition/Information on Ingredients ============= Ingred Name:METAPHOSPHORIC ACID CAS:37267-86-0 Ingred Name:METAPHOSPHORIC ACID, SODIUM SALT; (CONTAINS APPROX 65% SODIUM METAPHOSPHATE AS STABILIZER) CAS:10361-03-2 RTECS #:OY3750000 Fraction by Wt: 65% ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CAUSES BURNS (POSSIBLY SEVERE) ON CONTACT WITH SKIN OR EYES. DUST INHALATION IRRITATING TO UPPER RESPIRATORY TRACT AND MAY CAUSE LUNG DAMAGE. INGESTION CAUSES BURNS TO DIGESTIVE TRACT. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:DATA NOT AVAILABLE. ======================= First Aid Measures ======================= First Aid:GET MED ASSISTANCE FOR ALL CASES OF OVEREXPOSURE! SKIN: IMMED FLUSH THORO WITH LARGE AMOUNTS OF WATER. EYES: IMMED FLUSH THORO WITH WATER FOR AT LEAST 15 MIN. INHAL: REMOVE TO FRESH AIR; GIVE ARTF RES P IF BREATHING HAS STOPPED. INGEST: DO NOT INDUCE VOMIT; IF CONSCIOUS, GIVE WATER FREELY AND GET MED ATTN. ===================== Fire Fighting Measures ===================== Flash Point:NOT COMBUSTIBLE Extinguishing Media:WATER SPRAY TO COOL CONTAINERS. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCES TOXIC FUMES. ================== Accidental Release Measures ================== Spill Release Procedures:TAKE UP AND CONTAINERIZE FOR PROPER DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTR TIGHTLY CLSD. STORE @ CONTROLLED ROOM TEMP AWAY FROM METALS. DO NOT BRTH DUST. DO NOT GET IN EYES, ON SKIN/CLTHG. DO NOT TAKE INTERNALLY. Other Precautions:RETAINED RESIDUES MAY MAKE EMPTY CONTAINERS HAZARDOUS: USE CAUTION! ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:MATERIAL SHOULD BE HANDLED OR TRANSFERRED IN AN APPROVED FUME HOOD OR WITH ADEQUATE VENTILATION. Other Protective Equipment:PROTECTIVE CLOTHING. EYEWASH & SAFETY EQUIPMENT. DELUGE SHOWER . Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health BP: SUBLIMES AT RED HEAT. ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:B.P. Text:SUPP DATA Spec Gravity:2.2-2.5 Evaporation Rate & Reference:NEG Solubility in Water:88 Appearance and Odor:CLEAR, COLORLESS SOLID, ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES BASES, METALS, CARBONATES,SULFIDES, CYANIDES. Stability Condition to Avoid:REACTS WITH COMMON MTALS, IF HEATED OR ON SOLN, TO PRODUCE HYDROGEN GAS WHICH FORMS FLAMMABLE MIXTURE WITH AIR. Hazardous Decomposition Products:PO*X, NA2O. ==================== Disposal Considerations ==================== Waste Disposal Methods:TO BE PERFORMED IN COMPLIANCE WITH ALL CURRENT LOCAL, STATE AND FEDERAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:EXTERIOR ALKYD HOUSE PAINT PRIMER, 06434/6-434 CAGE:0EKH6 CAGE:0EKH6 ============= Composition/Information on Ingredients ============= Ingred Name:CONTAINS INGREDIENTS 2-7 RTECS #:9999999ZZ Fraction by Wt: 10.0% Ingred Name:MAGNESIUM SILICATE HYDRATE; (TALC) (HYDRATED MAGNESIUM SILICATE) CAS:1343-90-4 RTECS #:OM4360000 Fraction by Wt: 20-40% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TALC (POWDER), CONTAINING NO ASBESTOS FIBERS; (TALC (FIBROUS, CONTAINS NO ASBESTOS) CAS:14807-96-6 RTECS #:WW2710000 Fraction by Wt: 1-5% OSHA PEL:20 MPPCF Z-3 ACGIH TLV:2 MG/M3 RDUST Ingred Name:TREMOLITE; (TREMOLITE NONASBESTIFORM) CAS:14567-73-8 RTECS #:CI6560000 Fraction by Wt: 30-50% OSHA PEL:2 FIBERS/CC ACGIH TLV:2 FIBERS/CC,A1 Ingred Name:ANTHOPHYLLITE NONASBESTIFORM Fraction by Wt: 5-10% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SERPENTINE (ANTIGORITE) Fraction by Wt: 20-30% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (QUARTZ) CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: 0-2% OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 RDUST Ingred Name:DIATOMACEOUS EARTH (CONTAINING INGREDIENT 9) Fraction by Wt: 5.0% OSHA PEL:N/K ACGIH TLV:20 MPPCF (MFR) Ingred Name:SILICA, CRYSTALLINE - CRISTOBALITE; (CRYSTALLINE SILICA-CRISTOBALITE) CAS:14464-46-1 RTECS #:VV7325000 Fraction by Wt: 35% OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.05 MG/M3 RDUST Ingred Name:HYDROCARBON SOLVENT VP:2 @ 68F Fraction by Wt: 24.0% OSHA PEL:N/K ACGIH TLV:118 PPM (MFR) ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE:HEADACHE, DIZZINESS, NAUSEA, EYE IRRITATION. CHRONIC:LOSS OF APPETITE, NOSE BLEEDS. REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. Explanation of Carcinogenicity:SILICA, CRYSALLINE-CRISTOBALITE:IARC MONOGRAPHS, SUPP, VOL 7, PG 341, 1987:GROUP 2A. NTP 7TH ANNUAL RPT ON (SUPP DATA) Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:SKIN CONTACT:PROLONGED OR REPEATED LIQUID CONTACT WILL DRY AND DEFAT SKIN LEADING TO IRRITATION AND DERMATITIS. EYE CONTACT:DIRECT EYE CONTACT WILL CAUSE EYE IRRITATION. ======================= First Aid Measures ======================= First Aid:SKIN:WASH WITH SOAP AND WATER. EYE:IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES; CALL A PHYSICIAN. INGESTION:DO NOT INDUCE VOMITING; CALL A PHYSICIAN; DRINK 1 OR 2 GLASSES OF WA TER. INHALATION:REMOVE TO FRESH AIR, RESTORE BREATHING, CALL A PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:108F,42C Lower Limits:1.0% Extinguishing Media:FOAM, DRY CHEMICAL, WATER FOG, CO*2. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . WATER MAY BE HELPFUL APPLIED AS A SPRAY OR MIST TO COOL CLOSED CONTAINERS. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAMES. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL IGNITION SOURCES. KEEP PEOPLE AWAY. REMOVE WITH INERT ABSORBENT. PROVIDE ADEQUATE VENTILATION. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CNTNRS CLSD WHEN NOT IN USE. AVOID CONT W/SKIN & EYES. PROVIDE ADEQ VENT. KEEP OUT OF REACH OF CHILDREN. DO NOT TAKE INTERNALLY. Other Precautions:AVOID OPEN FLAMES, SPK SOURCES & HIGH TEMP AREAS. THIS COATING CNTNS MATLS CLASSIFIED AS NUISANCE PARTICULATES, FOR EXAMPLE TITANIUM DIOXIDE, CALCIUM CARBONATE, ETC. (SEE ACGIH TLV LIST, PREFACE & APP ENDIX D), WHICH MAY BE PRESENT (SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED CANNISTER OR AIR HOSE MASK IF TLV IS EXCEEDED. IF MATERIAL IS SPRAYED AND TLV IS NOT EXCEEDED USE DUST MASK (NIOSH/MSHA APPROVED). Ventilation:VENTILATE WORKING SPACES TO BELOW TLV. Other Protective Equipment:ANSI APPRVD EMER EYEWASH & DELUGE SHOWER . USE CHEM-RESIST APRON/OTHER CLTHG IF NEEDED TO AVOID RPTD OR (SUPDAT) Work Hygienic Practices:WASH HANDS BEFORE EATING OR USING BATHROOM. Supplemental Safety and Health EXPLAN OF CARCIN:CARCINOGENS. 1994:ANTICIPATED TO BE CARCINOGEN. OTHER PRECS:AT HAZARDOUS LEVELS ONLY DURING THE SPRAYING OF THIS COATING, OR SANDING OR ABRADING OF THE DRIED FILM. OTHER PROT EQUIP:PR OLONGED CONTACT. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>318F,>159C Vapor Pres:SEE ING 10 Vapor Density:HVR/AIR Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:43 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HEAT, OPEN FLAMES, SPARKS. Hazardous Decomposition Products:CARBON MONOXIDE, CO*2 AND SMOKE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:METHANOL CAGE:3D253 CAGE:3D253 CAGE:86511 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ALCOHOL (METHANOL) (SARA III) CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: 100% OSHA PEL:S,200PPM/250STEL ACGIH TLV:S,200PPM/250STEL; 93 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Effects of Overexposure:HDACHE,DIZZY,WEAK,BLURRD VISION,LIGHTHEADEDNESS,"DRUNKENNESS",IRRIT OF EYES,SKN,RESP TRACT. ======================= First Aid Measures ======================= First Aid:INHAL:RMV TO FRESH AIR. IF NOT BRTHNG GIVE CPR; IF BRTHNG DIFF GIVE OXYGEN, EYE:IMMED FLUSH W/PLENTY OF WATER. SKIN:WASH W/SOAP&WATER. RMV CONTAM CLTHG&SHOES. INGEST:INDUCE VOMIT. RPT UNTIL VOMIT IS C LEAR. NOTHG BY MOUTH IF UNCONSC. GET MEDICAL ATTN. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:=11.1C, 52.F Autoignition Temp:=385.C, 725.F Lower Limits:6.0 Upper Limits:36.5 Extinguishing Media:DRY CHEMICAL,ACOHOL TYPE FOAM,CO*2. Fire Fighting Procedures:WEAR SCBA. USE H*2O ONLY AS FOG/MIST TO COOL CONTRS. Unusual Fire/Explosion Hazard:GIVE FLAMM VAP BELOW ROOM TEMP;IF EXPOSD TO IGN SOURCE IN ARI,MAY BURN IN OPEN OR EXPLODE IF CONFIND ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE UNPROTECTED PERSONS. ELIM IGNITION SOURCES. STOP LEAK. H*2O SPRAY COOL CONT/DIVERT SPILL FROM FIRE/HEAT. PROVIDE VENTILATION. ABSORB W COMMERCIAL ABSORBENT,SHOVEL INTO METAL DRUMS:LG SPILL:DI KE W COMMERCIAL ABSORBENT,PUMP INTO COVERED DRUMS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN TIGHTLY CLOSED/PROPERLY VENTED CONTNRS AWAY FM IGN SOURCE/HEAT IN COOL/VENTILATD AREAR.HANDLE EMPTY DRUMS W/CARE;WILL ABSORB ATMOSPHRC MOISTR Other Precautions:DO NOT USE SOLID H*2O STREAM BUT H*2O SPRAY/FOG ARE USEFUL TO COOL CONTNRS.AVOID CONTACT W/SKIN & EYES.GROUND CONTNRS PROPERLY BEFORE TRNSFR LIQUID.DO NOT STORE IN ALUMINUM/ZINC CONTAINERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AIR-SUPPLIED EQUIPMENT OR GAS MASK WITH APPROVED CANISTER FOR METHAN Ventilation:GENL DILUTION,LOCAL EXHAUST Other Protective Equipment:RUBBER APRON Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.DISCARD CONTAMINATED LEATHER SHOES. Supplemental Safety and Health LYONDELL TOOK OVER PRODUCTION OF METHANOL FROM ARCO CHEMICAL IN HOUSTON,TEXAS. ================== Physical/Chemical Properties ================== HCC:F5 NRC/State Lic Num:NOT RELEVANT Boiling Pt:=64.4C, 148.F Vapor Pres:92 Vapor Density:1.11 Spec Gravity:0.79 Evaporation Rate & Reference:6.3,ETHER Solubility in Water:COMPLETE Appearance and Odor:CLEAR LIQUID WITH FAINT ALCOHOL ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDANTS,CHLOROFORM,EXPLOSV MATLS,BASES,ACTIVE METALS Stability Condition to Avoid:WATER,IGN SOURCES,HEAT Hazardous Decomposition Products:INCOMPLETE COMBUSTION PRODUCES CO & MAY GIVE FORMALDEHYDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE IN APPROVED INCINERATOR OR DISPOSE OF IN APPROVED CHEMICAL DUMP IN ACCORDANCE WITH LOCAL,STATE & FEDERAL REGULATIONS.
1
gloves_mandatory
======================================================= Product ID: ENVIRO-TAC, A1015 Cage: 09UK5 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 09UK5 ======================================================= Item Description Information ======================================================= ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE: EYES: MAY CAUSE SLIGHT IRRITATION BUT DOES NOT INJURE EYE TISSUE. SKIN: FREQUENT OR PROLONGED CONTACT MAY CAUSE IRRITATION. INHAL: INHALATION OF MIST CAN CAUSE IRRITATION OF NASAL AND RESPIRATO RY PASSAGES. ABUSIVE OR EXCESSIVE INHALATION MAY CAUSE IRRITATION TO THE UPPER RESPIRATORY TRACT, DIZZINESS, NAUSEA AND OTHER CENTRAL NERVOUS SYSTEM EFFECTS. INGESTION: CAN CAUSE GASTROINTESTINAL IRRI TATION, NAUSEA, VOMITING AND DIARRHEA. ASPIRATION OF MATERIAL INTO THE LUNGS CAN CAUSE CHEMICAL PNEUMONITIS. Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. First Aid: EYES: FLUSH WITH LARGE AMOUNTS OF COOL RUNNING WATER FOR AT LEAST 15 MINUTES WHILE HOLDING UPPER AND LOWER LIDS OPEN. IF IRRITATION PERSISTS GET MEDICAL ATTENTION IMMEDIATELY. SKIN: WASH WITH SOAP AND WATER. IF IRRITATION PERSISTS SEEK MEDICAL ATTENTION. INHALATION: REMOVE TO FRESH AIR. SEEK MEDICAL ATTENTION IMMEDIATELY. IF BREATHING STOPS GIVE ARTIFICIAL RESPIRATION. INGESTION: DO NOT INDUCE VOM ITING. SEEK MEDICAL ATTENTION IMMEDIATELY. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: ALLOW PROPELLANT & SOLVENT TO EVAPORATE. MAINTAIN LOCAL EXHAUST AND ADEQUATE VENTILATION. NO SMOKING. KEEP SPARKS, HEAT SOURCES AND OPEN FLAME FAR AWAY FROM SPILL OR LEAK. NO ADDITIONAL CLEANING SHOUL D BE REQUIRED. Waste Disposal Methods: AEROSOL CANS, WHEN EMPTIED AND DEPRESSURIZED THROUGH NORMAL USE, POSE NO DISPOSAL HAZARD AND SHOULD BE RECYCLED. CONSULT FEDERAL, STATE AND LOCAL AUTHORITIES FOR APPROVED PROCEDURES. Handling And Storage Precautions: STORE IN A COOL, DRY AREA AWAY FROM HEAT OR OPEN FLAME. DO NOT STORE AT TEMPERATURES ABOVE 120F. Other Precautions: FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY. NFPA CODE 30B RATING: LEVEL 1 AEROSOL. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: NONE TO BOILING Extinguishing Media: FLAMMABILITY (AS PER USA FLAME PROJECTION TEST): NON-FLAMMABLE SPRAY. FOAM, CO*2, DRY MEDIA. Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). COOL FIRE EXPOSED CONTAINERS TO PREVENT RUPTURING. Unusual Fire/Explosion Hazard: EXPOSURE TO TEMPERATURE ABOVE 120F MAY CAUSE BURSTING. ======================================================= Control Measures ======================================================= Respiratory Protection: NONE NEEDED FOR PROPER USE IN ACCORDANCE WITH LABEL DIRECTIONS. NIOSH APPROVED RESPIRATOR APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N). Ventilation: PROVIDE LOCAL EXHAUST TO KEEP TLV OF INGRED SECTION BELOW ACCEPTABLE LIMITS. Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N). Supplemental Safety and Health: PHYSICAL DATA: TOTAL VOC%: -3%. PHYSICAL DATA BASED ON AEROSOL CONCENTRATE ONLY. ======================================================= Physical/Chemical Properties ======================================================= Boiling Point: =32.2C, 90.F Vapor Pres: 80 (PSIG @ 70F Vapor Density: >1 (AIR=1) Spec Gravity: 1.250(H*2O =1) Solubility in Water: SLIGHT Appearance and Odor: CLEAR COLORLESS LIQUID, ETHER-LIKE ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Materials To Avoid: AVOID CONTACT WITH STRONG OXIDIZING AGENTS. Hazardous Decomposition Products: CARBON DIOXIDE, CARBON MONOXIDE, HYDROGEN CHLORIDE, HYDROGEN FLUORIDE AND CHLORINE. Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= Sara Title III Information: 313 CHEM: 1,1-DICHLORO-1-FLUOROETHANE: YES. ======================================================= Other Information ======================================================= Other Information: RATING (BASED ON AEROSOL CONC): 0-MINIMAL, 1-SLIGHT, 2-MODERATE, 3-SERIOUS, 4-EXTREME. HEALTH: 2, FIRE: 0, REACTIVITY:0, PERSONAL PROTECTION: B. ======================================================= HAZCOM Label ======================================================= Product ID: ENVIRO-TAC, A1015 Cage: 09UK5 Company Name: OMEGA INDUSTRIAL SUPPLY INC Street: 2479 INDUSTRIAL PARKWAY WEST, SUITE L Zipcode: 94545 Label Required IND: Y Date Of Label Review: 09/01/1999 Status Code: A Origination Code: F Skin Protection IND: YES Signal Word: NONE Respiratory Protection IND: YES Health Hazard: None Contact Hazard: None Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE: EYES: MAY CAUSE SLIGHT IRRITATION BUT DOES NOT INJURE EYE TISSUE. SKIN: FREQUENT OR PROLONGED CONTACT MAY CAUSE IRRITATION. INHAL: INHALATION OF MIST CAN CAUSE IRRITATION OF NASAL AND RESPIRATO RY PASSAGES. ABUSIVE OR EXCESSIVE INHALATION MAY CAUSE IRRITATION TO THE UPPER RESPIRATORY TRACT, DIZZINESS, NAUSEA AND OTHER CENTRAL NERVOUS SYSTEM EFFECTS. INGESTION: CAN CAUSE GASTROINTESTINAL IRRI TATION, NAUSEA, VOMITING AND DIARRHEA. ASPIRATION OF MATERIAL INTO THE LUNGS CANCAUSE CHEMICAL PNEUMONITIS. CHRONIC: NONE SPECIFIED BY MANUFACTURER (FP N). =======================================================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:INSTALOID CAGE:20750 CAGE:20750 ============= Composition/Information on Ingredients ============= Ingred Name:1,2-PROPANEDIOL; (PROPYLENE GLYCOL U.S.P.) VP:0.08, VAP DENS:2.62 CAS:57-55-6 RTECS #:TY2000000 Fraction by Wt: 45-50% OSHA PEL:N/K ACGIH TLV:10 MG/M3 (MFR) Ingred Name:SILICA, AMORPHOUS, DIATOMACEOUS EARTH; (SILICA) CAS:61790-53-2 RTECS #:HL8600000 Fraction by Wt: <5% OSHA PEL:20 MPPCF ACGIH TLV:10 MG/M3 TDUST ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NO PARTICULAR HAZARD, BUT NORMAL GOOD CLEANING SHOULD BE USED. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:REPEATED EXCESSIVE INGESTION MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS. ======================= First Aid Measures ======================= First Aid:INGESTION:CALL MD IMMEDIATELY . INHALATION:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:IRRIGATE IMMEDIATELY WITH WATER FOR AT LEAST 15 MINUTES. SKIN:WASH OFF IN FLOW ING WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS. ===================== Fire Fighting Measures ===================== Extinguishing Media:NON-FLAMMABLE. USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING FIRE. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NOT APPLICABLE. ================== Accidental Release Measures ================== Spill Release Procedures:IF MOLTEN, ALLOW TO COOL. SCRAPE UP AND DISCARD. USE SOAP AND WATER TO REMOVE RESIDUE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE GEL IN A AIR TIGHT CONTAINER. EXERCISE REASONABLE CARE AND CAUTION. Other Precautions:FOR MOLTEN MATERIAL, AVOID SPILLING HOT LIQUID. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . NOT APPLICABLE. Ventilation:GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT. Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE SHOWER . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:220F,104C Vapor Pres:SEE ING 1 Vapor Density:SEE ING 1 Spec Gravity:1.4 (H*2O=1) pH:7.0 Solubility in Water:SLIGHTLY Appearance and Odor:PINK ODORLESS THERMOSET GEL. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING MATERIAL. Stability Condition to Avoid:STABLE UNDER NORMAL CONDITION. Hazardous Decomposition Products:PROPION ALDEHYDE, CARBON MONOXIDE IN THE PRESENCE OF LIMITED OXYGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:AMERICAN ACCENTS, 7934 CAGE:08882 CAGE:08882 ============= Composition/Information on Ingredients ============= Ingred Name:XYLENE; (XYLOL) (SARA 313) (CERCLA). VP:9.5 @ 20C. LEL:1%. CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 10-35% OSHA PEL:100 PPM ACGIH TLV:100 PPM;150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SOLVENT NAPHTHA (PETROLEUM), LIGHT AROMATIC; (AROMATIC HYDROCARBON). VP:4 @ 20C. LEL:1%. CAS:64742-95-6 RTECS #:WF3400000 Fraction by Wt: 0-25% OSHA PEL:100 PPM (MFR) ACGIH TLV:N/K Ingred Name:HYDROCARBON PROPELLANT; (PROPANE, BUTANE, ISOBUTANE). VP:52 PSIA @ 20C. LEL:1.8%. CAS:68476-86-8 Fraction by Wt: 25% OSHA PEL:1000 PPM (MFR) ACGIH TLV:1000 PPM (MFR) ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:INHAL:HARMFUL IF INHALED. MAY AFFECT BRAIN/NERV SYS, CAUSING DIZZ, HDCH/NAUS. RPTD OVEREXPS MAY PROGRESSIVELY LEAD TO STAG GAIT, CONFUSN, UNCON/COMA. CAUSES NOSE & THROAT IRRIT. SKIN/EYE CONT:CA USES IRRIT WHICH CAN LEAD TO DERM W/RPTD OVEREXPS. INGEST:MAY CAUSE GI IRRIT, NAUS, VOMIT & DIARR. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:CHRONIC:RPTS HAVE ASSOC RPTD & PRLNG OCCUP OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS DMG. OVEREXP TO XYLOL IN LAB ANIMALS HAS ALSO BEEN ASSOC W/LIVER ABNORMS, KIDNEY, LUNG, SPLEEN & EYE DMG AS WELL AS ANEMIA. EFTS IN HUMANS HAVE INCL LIVER & CARDIAC ABNORMS. INTENTIONAL MISUSE BY DELIB CONCENTRATING & (SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE FROM EXPOSURE, RESTORE BREATHING & NOTIFY MD. EYES:FLUSH IMMEDIATELY W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. NOTIFY MD. SKIN:WASH AFFECTED AREA W/SOAP & WATER, REMOVE CONTAMINAT ED CLOTHING & WASH BEFORE REUSE. INGEST:DO NOT INDUCE VOMITING. KEEP PERSON WARM, QUIET & GET MEDICAL ATTENTION. ASPIRATION OF THIS MATL INTO LUNGS CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:<0F,<-18C Lower Limits:SEE INGS Extinguishing Media:NFPA CLASS B EXTINGUISHERS (CARBON DIOXIDE, DRY CHEMICAL OR FOAM). Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER SPRAY MAY BE INEFT. WATER MAY BE USED TO COOL CLSD CNTNRS TO PVNT PRESS BUILD-UP & POSS AUTO-IGNIT(SUPDAT) Unusual Fire/Explosion Hazard:EXTREMELY FLAMM. KEEP CNTNRS TIGHTLY CLSD. KEEP AWAY FROM HEAT, ELEC EQUIP, SPKS & OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME HEAT. DO(SUPP DATA) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION, VENTILATE AREA & REMOVE W/INERT ABSORBENT & NON-SPARKING TOOLS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE ABOVE 120F. DO NOT PUNCTURE CONTAINERS. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED CHEMICAL CARTRIDGE RESPIRATOR (TC23C) TO REMOVE AIRBORNE OVERSPRAY PARTICLES & ORGANIC VAPORS DURING SPRAY APPLICATION. IN CONFINED AREAS:USE NIOSH APPROVED SUPPLIED-AIR RESPIRATORS OR HOODS (TC19C). Ventilation:PROVIDE GENERAL DILUTION OR LOCAL EXHAUST VENT IN VOLUME & PATTERN TO KEEP TLV OF HAZ INGS BELOW ACCEPTABLE LIMITS. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . USE IMPERVIOUS CLTHG TO PVNT PRLNG SKIN CONT. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRE FIGHT PROC:NOT APPLY TO HOT SURFACES. EXPLO HAZ:OR EXPLOSION. IF WATER IS USED, FOG NOZZLES ARE PREFERRED. EFTS OF OVEREXP:INHALATION CONTENTS CAN BE HARMFUL OR FATAL. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:<0F,<-18C Vapor Pres:SEE INGS Vapor Density:LTR/AIR Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES INCOMPATIBLE W/STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:BY OPEN FLAME - CARBON MONOXIDE & CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF ACCORDING TO LOCAL, STATE & FEDERAL REGULATIONS. DO NOT INCINERATE CONTAINERS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:CLEANING COMPOUND, SEPTIC TANK A-A-11 CAGE:WINST CAGE:WINST ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS INGREDIENTS Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CHRONIC EXPOSURE MAY LEAD TO ALLERGIC SENSITIZATION, BASED ON EXPOSURE LEVEL DURATION AND SUSCEPTIBILITY. SUBSEQUENT CHRONIC OR ACUTE EXPOSURE IN SENSITIZED INDIVIDUALS CAN CAUSE A RESPIRATORY ALLERGI C REACTION WITHIN MINUTES OR DELAYED UPTO 24 HOURS, OR A MIXTURE OF BOTH. Explanation of Carcinogenicity:NOT CLASSIFIED AS A CARCINOGEN. Effects of Overexposure:INHALATION:RESPIRATORY IRRITATION, BREATHLESSNESS, COUGHING, CHEST TIGHTNESS AND DIFFICULTY BREATHING. SKIN CONTACT:MAY CAUSE IRRITATION. EYE CONTACT:MAY CAUSE IRRITATION. INGESTION:MAY CAUSE SYMPTOMS OF GASTROINTESTINAL IRRITATION. ======================= First Aid Measures ======================= First Aid:INHALATION:IMMEDIATELY REMOVE INDIVIDUAL TO FRESH AIR.SKIN CONTACT:WASH EXPOSED SKIN THOROUGHLY WITH SOAP AND WATER. REMOVE AFFECTED CLOTHES AND WASH.EYE CONTACT:FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES.INGESTION:DRINK WATER,THEN INDUCE VOMITING BY HAVING PERSON STICK FINGER DOWN THROAT.KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION INTO LUNGS.GET MED ATTN. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY OR WATER FLOODING. Fire Fighting Procedures:TOXIC FUMES OF AMMONIA & SULFUR OXIDES MAY BE RELEASED VIOLENTLY AT HIGH TEMPS,FULL PROTECT CLOTHING/SCBA SHOULD BE WORN.USE H2O TO COOL FIRE EXPOSED CONTAINERS Unusual Fire/Explosion Hazard:MAY EXPLODE IF MIXED WITH OXIDIZERS, SUCH AS POTASSIUM NITRATE, POTASSIUM NITRITE OR POTASSIUM CHLORATE. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP SPILLED MATERIAL AND DISPOSE OF IN A MANNER APPROVED BY CITY, STATE AND FEDERAL REGULATIONS. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE. STORE IN COOL DRY AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED UNDER NORMAL CONDITIONS OF USE. IF RISK OF INHALATION MAY OCCUR, RESPIRATORY PROTECTIVE EQUIPMENT MUST BE SELECTED AND USED IN ACCORDANCE WITH OSHA/NIOSH GUIDELINES. Ventilation:RECOMMEND WELL VENTILATED WORK ENVIRONMENT. LOCAL EXHAUST AS NEEDED TO PREVENT DUST OR AEROSOL GENERATION. Other Protective Equipment:WEAR LONG-SLEEVED SHIRT AND TROUSERS TO AVOID CONTACT. SAFETY SHOWER, EYE BATH AND WASHING FACILITIES AVAILABLE. Work Hygienic Practices:FOLLOW GOOD INDUSTRIAL HYGIENE PRACTICES. Supplemental Safety and Health *AMMONIA IS RELEASED UPON REACTION WITH SULFUR DYES. CORROSIVE TO CARBON STEEL. ================== Physical/Chemical Properties ================== Solubility in Water:APPRECIABLE Appearance and Odor:TAN POWDER WITH SLIGHT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXYGEN,PEROXIDE,STRONG BASES,OXIDIZERS,E.G.POTASSIUM SALTS-NITRITE,NITRATE,CHLORATE,ZINC CLAD,COPPER/COPPER BEAR MAT'L. Stability Condition to Avoid:AVOID HEATING ABOVE 212 F TO AVOID DECOMPOSITION. Hazardous Decomposition Products:AMMONIA, SULFUR TRIOXIDE AND SULFUR DIOXIDE GASES BY DECOMPOSITION ABOVE 536 DEGREES F. ==================== Disposal Considerations ==================== Waste Disposal Methods:SWEEP UP MATERIAL AND DISPOSE OF IN A MANNER APPROVED BY CITY, STATE AND FEDERAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:192 7698, PT C, KODAK FLEXICOLOR DEVELOPER Kit Part:Y Preparer's Name:NOT PROVIDED CAGE:19139 CAGE:19139 Contract Num:SP0500-96-D-9413M387 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Minumum % Wt:70. Maxumum % Wt:75. Other REC Limits:NOT PROVIDED Code:F Code:F Ingred Name:4-(N-ETHYL-N-2-HYDROXYETHYL)-2-METHYLPHENYLENEDIAMINE SULFATE CAS:25646-77-9 RTECS #:KJ6477000 Minumum % Wt:25. Maxumum % Wt:30. Other REC Limits:0.1 MG/M3 (MFR) OSHA PEL:NOT PROVIDED ACGIH TLV:NOT PROVIDED Ingred Name:SODIUM BISULFITE CAS:7631-90-5 RTECS #:VZ2000000 Minumum % Wt:1. Maxumum % Wt:5. Other REC Limits:NOT PROVIDED OSHA PEL:NOT PROVIDED ACGIH TLV:5 MG/M3 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD-50 (MALE RAT): 25-50 MG/KG Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EFFECTS OF EXPOSURE: CONTAINS 4-(N-ETHYL-N-2-HYDROXYETHYL)-2-METHYLPHENYLENEDIAMINE SULFATE. MAY CAUSE KIDNEY DAMAGE BASED ON ANIMAL DATA. INHALATION: MAY BE HARMFUL IF INHALED. LIBERATES SULFUR DIOXI DE GAS WHICH CAN CAUSE IRRITATION TO THE RESPIRATORY TRACT. SOME ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING. EYES: CAUSES IRRITATION. VAPOR IRRITATING. SKIN: CAUSES IR RITATION. MAY CAUSE ALLERGIC SKIN REACTION BASED ON HUMAN EXPERIENCE. INGESTION: HARMFUL IF SWALLOWED. MAY CAUSE KIDNEY DAMAGE BASED ON ANIMAL DATA. MAY CAUSE IRRITATION OF THE GASTROINTESTINAL TRACT. Explanation of Carcinogenicity:INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC): NONE - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): SODIUM BISULFITE, A4, NOT CLASSIFIABLE AS A HUMAN CARCINOGEN; SULFUR DIOXI DE, A4, NOT CLASSIFIABLE AS A HUMAN CARCINOGEN. - NATIONAL TOXICOLOGY PROGRAM (NTP): NONE - OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA): NONE Effects of Overexposure:INHALATION: LIBERATES SULFUR DIOXIDE GAS WHICH CAN CAUSE IRRITATION TO THE RESPIRATORY TRACT. EYES: CAUSES IRRITATION. VAPOR IRRITATING. SKIN: CAUSES IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION BASED ON HUMAN EXPERIENCE. MAY CAUSE IRRITATION OF THE GASTROINTESTINAL TRACT. Medical Cond Aggravated by Exposure:SOME ASTHMATICS, HYPERSENSITIVE OR SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING, WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS, WEAKNESS AND DIARRHEA. ======================= First Aid Measures ======================= First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTEN TION. SKIN: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, REMOVING CONTAMINATED CLOTHING AND SHOES. WASH CONTAMINATED CLOTHING BEFORE REUSE. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. DESTROY OR THOROUGHLY CLEAN CONTAMINATED SHOES. INGESTION: INDUCE VOMITING AS DIRECTED BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CALL A PHYSICIAN OR POISON CONTROL C ENTER IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Extinguishing Media:WATER SPRAY, CARBON DIOXIDE (CO2), DRY CHEMICAL, ALCOHOL FOAM. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. USE WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL. Unusual Fire/Explosion Hazard:ELEVATED TEMPERATURE CAN CAUSE DECOMPOSITION. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNT OF WATER. OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL C ONTAMINATION. Neutralizing Agent:NOT PROVIDED ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. STORE IN A COOL PLACE. KEEP FROM CONTACT WITH OXIDIZING MATERIALS. KEEP AWAY FROM HEAT. Other Precautions:DO NOT GET IN EYES, ON SKIN, ON CLOTHING. AVOID BREATHING MIST OR VAPOR AT CONCENTRATIONS GREATER THAN THE EXPOSURE LIMITS. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE CONCENTRATIONS BELOW RECOMMENDED EXPOSURE LIMITS, AN APPROVED RESPIRATOR MUST BE WORN. RESPIRATOR TYPE: ACID GAS. IF RESPIRATORS ARE USED, A PROGRAM S HOULD BE INSTITUTED TO ASSURE COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134. Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. APPROPRIATE FOR RISK OF EXPOSURE Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER Work Hygienic Practices:NOT PROVIDED Supplemental Safety and Health SUPPLEMENTARY LOCAL EXHAUST VENTILATION, CLOSED SYSTEMS, OR RESPIRATORY PROTECTION MAY BE NEEDED IN SPECIAL CIRCUMSTANCES SUCH AS POORLY VENTILATED SPACES, EVAPORATION FROM LARGE SURFACES, SPRAYING, H EATING, ETC. ================== Physical/Chemical Properties ================== HCC:C2 NRC/State Lic Num:NOT RELEVANT Boiling Pt:>100.C, 212.F Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED Decomp Temp:Decomp Text:NOT PROVIDED Vapor Pres:68F: 24 MBAR(18 MM HG) Vapor Density:0.6 Spec Gravity:1.10 pH:2.1 Viscosity:NOT PROVIDED Evaporation Rate & Reference:NOT PROVIDED Solubility in Water:COMPLETE Appearance and Odor:REDDISH-BROWN LIQUID, SULFUR DIOXIDE ODOR. Percent Volatiles by Volume:70-75 WT Corrosion Rate:NOT PROVIDED ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:STABLE; MATERIALS CONTAINING SIMILAR STRUCTURAL GROUPS CAN DECOMPOSE IF HEATED ABOVE 172C (342F). Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF NITROGEN, OXIDES OF SULFUR. =================== Toxicological Information=================== Toxicological Information:DATA FOR 4-(N-ETHYL-N-2-HYDROXYETHYL)-2-METHYLPHENYLENEDIAMINE SULFATE. ORAL LD-50 (MALE RAT): 25-50 MG/KG (TARGET ORGAN EFFECTS: KIDNEY) ORAL LD-50 (FEMALE RAT): 30 MG/KG (TARGET ORGAN EFFECTS: KIDN EY) ORAL LD-50 (MOUSE): 141 MG/KG (TARGET ORGAN EFFECTS: KIDNEY) DERMAL LD-50: >2000 MG/KG SKIN IRRITATION: MODERATE REPEATED SKIN APPLICATION: MODERATE IRRITATION SKIN SENSITIZATION: MODERATE TO ST RONG SKIN SENSITIZATION (HUMAN): POSITIVE EYE IRRITATION (UNWASHED EYES): MODERATE. INTRAPERITONEAL INJECTION STUDY LD-50 (RAT) 10-25 MG/KG INTRAPERITONEAL INJECTION STUDY LD-50 (MOUSE) 10-25 MG/KG ===================== Ecological Information ===================== Ecological:THE FOLLOWING PROPERTIES ARE ESTIMATED FROM THE COMPONENTS OF THE PREPARATIONS. POTENTIAL TOXICITY: FISH LC50 MG/L: < 1. DAPHNID EC50 MG/L: 1-10.ALGAL IC50 MG/L: 10-100. ORGANICS READILY DEGRA DABLE (>70%): YES (7 DAYS). POTENTIAL BIOACCUMULATION: LOG POW <1. COD (APPROXIMATE G/L): 365. BOD5 (APPROXIMATE G/L): 40. POTENTIAL TOXICITY: WASTE TREATMENT MICROORGANISMS EC50 (MG/L): >100. A FTER DILUTION WITH A LARGE AMOUNT OF WATER, FOLLOWED BY SECONDARY WASTE TREATMENT, THIS MATERIAL IS NOT EXPECTED TO CAUSE ADVERSE ENVIRONMENTAL EFFECTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE AMOUNT OF WATER. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS EV EN AFTER CONTAINER IS EMPTIED. =================== MSDS Transport Information =================== Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE: (716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD TIME), MONDAY THROUGH FRIDAY . ===================== Regulatory Information ===================== SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART 372: NONE Federal Regulatory Information:NOT PROVIDED State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER: NONE - MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE ======================= Other Information =======================
1
gloves_mandatory
===================== Product Identification ===================== Preparer's Name:DOD HMIS/DGSC-SSH CAGE:JO772 CAGE:14153 CAGE:JO772 ============= Composition/Information on Ingredients ============= Ingred Name:ASBESTOS, CHRYSOTILE CAS:12001-29-5 RTECS #:CI6478500 OSHA PEL:0.2 FIBERS/CC ACGIH TLV:2 FIBERS/CC; A1;9192 Ingred Name:ASBESTOS & STEEL OVERALL COMPOSITION RTECS #:9999999ZZ Ingred Name:GENERIC "MSDS". SPECIFIC ASBESTOS TYPE NOT KNOWN. ONE CITED IS ASSUMED. INFORMATION BASED ON SEGMENT "M" OF "DLSC TIR" RTECS #:9999999ZZ ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE: NO ACUTE EFFECTS ARE KNOWN; CHRONIC: DUST FROM ABRASIVE ACTIONS(EG. CUTTING, MACHINING, FILING, ETC.) MAYCONTAIN ASBESTOS FIBERS. CHRONIC OVEREXPOSURE TO AIRBORNE FIBERS MAY LEAD TO ASBESTOSIS & MESOTHELIOMA. SMOKINGCOMBINED W/FIBER INHALATION GREATLY INCREASES LUNG CANCER RISK! Explanation of Carcinogenicity:OVEREXPOSURE TO AIRBORNE CONCENTRATIONS OF ASBESTOS MAY LEAD TO ASBESTOSIS AND MESOTHELIOMA. Effects of Overexposure:INHAL: INHALATION OF AIRBORNE DUST CONTAINING ASBESTOS FIBERS ON REPEATED EXPOSURE MAY CAUSE OR CAN LEAD TO ASBESTOSIS/ MESOTHELIOMA; SKIN: N/K; EYE: POTENTIAL IRRITATION FROM AIRBORNE DUST; INGEST: N/K. Medical Cond Aggravated by Exposure:RESPIRATORY DEFICIENCIES DUE TO REPEATED INHALATION OF AIRBORNE FIBERS. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. OBTAIN MEDICAL ADVICE; SKIN: WASH EXPOSED AREA WITH SOAP & WATER; EYE: FLOOD W/ WATER. IF IRRITATION OCCURS, GET MEDICAL ATTN; INGEST: CONSULT A PHYSICIAN; OTHER: CHANGE CLOTHING AS REQUIRED TO AVOIDCARRYING DUST PARTICLES INTO OTHER AREAS ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:MATERIAL IS NOT FLAMMABLE ; USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:COMBUSTION PRODUCTS OF THIS MATERIAL MAY BE TOXIC. USE A SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRES INVOLVING CHEMICAL PRODUCTS. Unusual Fire/Explosion Hazard:NONE KNOWN ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTION. VACUUM OR WET CLEAN IF DUST IS INVOLVED. ANY VACUUM SYSTEM SHOULD BE EQUIPPED W/ AN OUTLET "HEPA" FILTER TO PREVENT REINTRODUCING ASBESTOS FIBERS TO THE ATMOSPHERE. ======================Handling and Storage ====================== Handling and Storage Precautions:HANDLE IN A MATTER TO MINIMIZE FORMATION OR RETENTION OF AIRBORNE DUST. USE PROPER PERSONAL PROTECTION FOR TASK AT HAND. CHECK W/YOUR SAFETY OFFICE!!! Other Precautions:AS MANUFACTURED, LOCKED-IN ASBESTOS DOES NOT PRESENT A HAZARD. ONLY WHEN THE ITEM IS SUBJECTED TO ABRASIVE ACTIONS & DUST IS GENERATED, THEN ASBESTOS FIBERS MAY BE RELEASED & BECOME AIRBORNE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURES EXCEED ESTABLISHED LIMITS, A NIOSH/MSHA APPROVED RESPIRATOR FOR ASBESTOS SHOULD BE USED. CONSULT YOUR SAFETY OFFICE/IH PERSONNEL FOR GUIDANCE FOR THE TASK AT HAND. Ventilation:LOCAL EXHAUST IS RECOMMENDED IN SITUATIONS WHERE DUST IS GENERATED BY ABRASIVE ACTIONS, ABRASION OR OTHER MEANS. Other Protective Equipment:AS REQUIRED FOR TASK AT HAND, AND THE GUIDANCE SET FORTH BY YOUR SAFETY OFFICE OR IH PERSONNEL Work Hygienic Practices:DONOT INHALE DUST CREATED BY ABRADING ACTIONS. USE FULL PROTECTION AGAINST AIRBORNE FIBERS. AVOID AIRBORNE DUST CREATION Supplemental Safety and Health GENERIC "MSDS" CREATED FOR "NSN" IDENTIFIED BY "DISC" AS CONTAINING ASBESTOS.WHEN A MANUFACTURER'S SPECIFIC "MSDS" IS PROVIDED FOR MATERIAL PROCURED UNDER THIS NSN, THIS GENERIC "MSDS" WILL BE REMOVED. ================== Physical/Chemical Properties ================== HCC:T6 Evaporation Rate & Reference:NONE Solubility in Water:NOT SOLUBLE Appearance and Odor:MANUFACTURED COMMODITY DESCRIBED BY LOGISTICS: "ITEM-NAME" Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN Stability Condition to Avoid:NONE KNOWN ==================== Disposal Considerations ==================== Waste Disposal Methods:DUST SHOULD BE HANDLED AS A HAZARDOUS AIR POLLUTANT I/A/W 40CFR61 SUBPART "M" PERTAINING TO ASBESTOS. USE LANDFILLS APPROVED FOR ASBESTOS DISPOSAL. NOTE IF ITEM UNDER CONSIDERATION FOR DISPOSAL IS "FRIABLE OR NON-FRIABLE".
1
gloves_mandatory
===================== Product Identification ===================== Product ID:PREMIUM TICONIUM WIRE (61622) CAGE:65024 CAGE:65024 ============= Composition/Information on Ingredients ============= Ingred Name:NICKEL (SARA III) CAS:7440-02-0 RTECS #:QR5950000 Fraction by Wt: 10% % Other REC Limits:NONE RECOMMENDED OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3; 9394 Ingred Name:COBALT (SARA III) CAS:7440-48-4 RTECS #:GF8750000 Fraction by Wt: 51% % Other REC Limits:NONE RECOMMENDED OSHA PEL:0.05 MG/M3 ACGIH TLV:0.05 MG/M3;DUST 9394 Ingred Name:CHROMIUM (SARA III) CAS:7440-47-3 RTECS #:GB4200000 Fraction by Wt: 20% % Other REC Limits:NONE RECOMMENDED OSHA PEL:1 MG/M3 ACGIH TLV:0.5 MG/M3; 9394 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:TUNGSTEN CAS:7440-33-7 RTECS #:YO7175000 Fraction by Wt: 15% % Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3/10 STEL ACGIH TLV:5 MG/M3/10 STEL;8990 Ingred Name:MANGANESE (SARA III) CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: 1.5% % Other REC Limits:NONE RECOMMENDED OSHA PEL:C 5 MG/M3 ACGIH TLV:5 MG/M3, DUST; 9394 ===================== Hazards Identification ===================== LD50 LC50 Mixture:TLV 0.05 MG/M3 (COBALT) Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:SKIN CONTACT MAY CAUSE DERMATITIS OR ALLERGIES. SHORT-TERM OVEREXPOSURE TO WELDING FUMES MAY RESULT IN DISCOMFORT SUCH AS NAUSEA, OR DRYNESS OR IRRITATION OF THE NOSE, THROAT OR EYES. Explanation of Carcinogenicity:CONTAINS NICKEL AND CHROMIUM WHICH ARE LISTED BY NTP AND IARC AND COBALT LISTED AS POSSIBLE BY IARC. Effects of Overexposure:NAUSEA, IRRITATION OF NOSE/THROAT, EYE IRRITATION, SKIN IRRITATION. Medical Cond Aggravated by Exposure:AGGRAVATION OF RESPIRATORY ALLERGIC CONDITIONS MAY OCCUR IN SOME WORKERS. SKIN CONTACT MAY BE THE CAUSE OF DERMATITIS OR ALLERGIES. ======================= First Aid Measures ======================= First Aid:IN THE EVENT OF OVEREXPOSURE, REMOVE THE VICTIM FROM WELDING AREA, ADMINISTER FIRST AID. OBTAIN PROMPT MEDICAL ATTENTION. IF UNCONSCIOUS, ADMINISTER OXYGEN. IF NOT BREATHING, BEGIN RESUSCITATION IMMED IATELY. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Lower Limits:NOT GIVEN Upper Limits:NOT GIVEN Extinguishing Media:NONFLAMMABLE. USE MEDIA SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures:NONFLAMMABLE. USE PROCEDURES SUITABLE FOR SURROUNDING FIRE. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:IN SOLID FORM THIS MATERIAL POSES NO SPECIAL CLEAN-UP PROBLEMS. REMOVE DUST BY VACUUMING OR WET SWEEPING TO AVOID AIR CONTAMINATION. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FUME OR AIR SUPPLIED RESPIRATOR WHEN WELDING Ventilation:LOCAL Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT AND BEFORE EATING DRINKING OR SMOKING. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:T7 Boiling Pt:B.P. Text:NOT GIVEN Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN Vapor Pres:NOT GIVEN Vapor Density:NOT GIVEN Spec Gravity:7-9 Evaporation Rate & Reference:NIL Solubility in Water:INSOLUBLE Appearance and Odor:18 GAUGE DIAMETER WIRE (0.050 INCH NOMINAL) Percent Volatiles by Volume:NIL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MINERAL ACIDS AND STRONG OXIDIZING AGENTS Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:VARIOUS ELEMENTAL OXIDES MAY BE GENERATED FROM WELDING. ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:GALLIC ACID, R-7046 Preparer's Name:STEPHEN BACON CAGE:EO526 CAGE:EO526 CAGE:89975 ============= Composition/Information on Ingredients ============= Ingred Name:GALLIC ACID CAS:149-91-7 RTECS #:LW7525000 Fraction by Wt: 100% ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: DUST IRRITATING TO SKIN, EYES, AND RESPIRATORY TRACT. CONTACT W/SKIN CAN CAUSE IRRITATION. CONTACT W/EYES CAUSES MODERATE TO SEVERE IRRITATION. INGESTION CAN CAUSE GI IRRITATION WITH NAUSEA. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. IF BREATHING DIFFICULT, CONTACT PHYS & GIVE OXYGEN AS NEEDED. SKIN: WASH THORO W/SOAP & WATER. IF IRRIT PERSISTS, SEEK MED ATTN. EYES: FLUSH WELL FOR @ LST 15 MIN W/WATER. IF IRRIT PERSISTS, GET MED ATTN. INGEST: CONTACT PHYS & GIVE LG AMTS OF WATER. INDUCE VOMITING UNDER DIRECTION OF PHYS. ===================== Fire Fighting Measures ===================== Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:MAY EMIT ACRID SMOKE AND FUMES UNDER FIRE CONDITIONS. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP & CONTAINERIZE FOR LATER DISPOSAL. AVOID RAISING DUST. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID BREATHING DUST & UNNECESSARY CONTACT W/POWDER. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED DUST MASK SHOULD BE WORN WHEN HANDLING LARGE QTY. Ventilation:NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment:LAB COAT. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health HMIS(LEVIEN) NOTES THAT THE ORAL LD50 (RBT) IS 5G/KG. MATL TO AVOID: CARBONATES, AND SILVER SALTS. ================== Physical/Chemical Properties ================== HCC:T6 Solubility in Water:SLIGHTLY Appearance and Odor:WHITE, ODORLESS POWDER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONT W/FERRIC SALTS, OXIDIZERS, CHLORATES, PERMANGANATE, AMMONIA, LEAD ACETATE, ALKALI HYDROXIDES & (SUPP DATA) Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF BY INCINERATION OR OTHER METHOD APPROVED OF BY LOCAL, STATE, OR FEDERAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:*2232 TOLUENE >99% SPECTROPHOTOMETRIC GRADE CAGE:55371 CAGE:55371 ============= Composition/Information on Ingredients ============= Ingred Name:TOLUENE CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: >99% Other REC Limits:375 MG/CUM OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL (RAT) LD50: 5000 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN: HARMFUL ABSORPTION/IRRITATION. EYE: IRRITATION. INHALATION: HARMFUL/IRRITATION TO MUCOUS MEMBRANE & UPPER RESPIRATORY TRACT/BURNS/COUGHING/WHEEZING/LARYNGITIS/BREATH SHORTNESS/HEADACHE/NAUSEA/VO MITING/LUNG IRRITATION/CHEST PAIN/EDEMAWHICH MAY BE FATAL. INGESTION: HARMFUL & TOXIC. Explanation of Carcinogenicity:NONE Effects of Overexposure:INGESTION: LIVER & KIDNEY DAMAGE/SOMNOLENCE/HALLUCINATION/DISTORTED PERCEPTIONS/CHANGE IN MOTOR ACTIVITY, PSYCHOPHYSIOLOGICAL TESTS. BONE MARROW/ANESTHESIA/BLOOD, BRAIN, CNS, PATERNAL, FERTILITY, NEWB ORN, MUSCULOSKELETAL, UROGENITAL SYSTEM& ANTIPSYCHOTIC EFFECTS. INHALATION/EYES/SKIN: HARMFUL, IRRITATION, & TOXIC. ======================= First Aid Measures ======================= First Aid:EYES/SKIN: FLUSH W/COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINS. INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:40F Lower Limits:1% Upper Limits:7% Extinguishing Media:CO2, DRY CHEMICAL POWDER, ALCOHOL, OR POLYMER FOAM. Fire Fighting Procedures:WATER MAY BE EFFECTIVE FOR COOLING, BUT MAY NOT EFFECT EXTINGUISHMENT. WEAR SCBA/PROTECTIVE CLOTHING. USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:AUTOIGNITION TEMP: 997F. EXTREMELY FLAMMABLE. VAPOR MAY TRAVEL TO CONSIDERABLE DISTANCE TO IGNITION SOURCE/FLASHBACK. CONTAINER EXPLOSION MAY OCCUR IN A FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA. SHUT OFF ALL SOURCES OF IGNITION. WEAR PROTECTIVE EQUIPMENT. COVER W/ACTIVATED CARBON ABSORBENT. TAKE UP & PLACE IN CLOSED CONTAINERS. TRANSPORT OUTDOORS. VENTILATE AREA & WASH SPILL SI TE AFTER MATERIAL PICKUP IS COMPLETE. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID INHALATION OF VAPOR. AVOID CONTACT W/SKIN/EYES/CLOTHING. KEEP TIGHTLY CLOSED. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAME. STORE UNDER NITROGEN. Other Precautions:STORE IN A COOL, DRY PLACE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:MECHANICAL EXHAUST: REQUIRED. Other Protective Equipment:OTHER PROTECTIVE CLOTHING, SAFETY SHOWER, EYE BATH, HEAVY RUBBER BOOTS Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE/LAUNDER CONTAMINATED CLOTHING/SHOES BEFORE REUSE. Supplemental Safety and Health USE OF ALCOHOL CAN INCREASE THE NARCOTIC EFFECT & THE BLOOD EFFECTS OF TOLUENE. IRON OR FERRIC CHLORIDE CATALYZES A VIGOROUS EXOTHERMIC REACTION BETWEEN TOLUENE & SULFUR DICHLORIDE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:231.8F Melt/Freeze Pt:M.P/F.P Text:-135.4F Vapor Pres:22 Vapor Density:3.2 Spec Gravity:0.867 Appearance and Odor:COLORLESS LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS Stability Condition to Avoid:SOURCES OF IGNITION, HEAT, SPARKS, & OPEN FLAMES Hazardous Decomposition Products:CO, CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AN AFTERBURNER & SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS MATERIAL IS HIGHLY FLAMMABLE. DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATION S.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:848 4396 STABILIZER AND REPLENISHER, MX 144 CAGE:19139 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 90-95% Other REC Limits:NONE SPECIFIED Ingred Name:TRIETHANOLAMINE CAS:102-71-6 RTECS #:KL9275000 Fraction by Wt: 1-5% Other REC Limits:NONE SPECIFIED Ingred Name:SILICONE CAS:63148-52-7 Fraction by Wt: 1-5% Other REC Limits:NONE SPECIFIED Ingred Name:FORMALDEHYDE (SARA III) CAS:50-00-0 RTECS #:LP8925000 Fraction by Wt: 0.9% Other REC Limits:NONE SPECIFIED OSHA PEL:SEE 1910.1048 ACGIH TLV:C 0.3 PPM; A2; 9293 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:POLYMALEIC ACID CAS:26099-09-2 Fraction by Wt: <1% Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS 800 MG/KG (HCHO) Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:FORMALDEHYDE IS DETECTABLE AT LEVELS BELOW 1 PPM. IT PRODUCES MILD SENSORY IRRITATION OF THE EYES, NOSE AND THROAT AT 2-5 PPM, BECOMES UNPLEASANT AT 5-10 PPM, AND IS INTOLERABLE AT HIGHER CONCENTRATIO NS. EXPOSURE MAY CAUSE RESPIRATORY SENSITIZATION OR AGGRAVATE ASTHMATIC CONDITIONS. CAN CAUSE EYE AND SKIN IRRITATION. Explanation of Carcinogenicity:FORMALDEHYDE, A MINOR COMPONENT OF THIS PRODUCT, HAS BEEN IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN. Effects of Overexposure:CAN CAUSE EYE, SKIN & RESPIRATORY TRACT IRRITATION. PRODUCT IS EXPECTED TO BE A LOW INGESTION HAZARD. Medical Cond Aggravated by Exposure:EXPOSURE TO FORMALDEHYDE MAY CAUSE RESPIRATORY SENSITIZATION IN SOME INDIVIDUALS OR AGGRAVATE PRE-EXISTING ASTHMATIC CONDITIONS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. IF SYMPTOMS PERSIST, GET MEDICAL ATTENTION. EYES: IMMEDIATELY FLUSH WITH RUNNING WATER FOR 15 MINUTES. GET MEDICAL ATTENTION. SKIN: IMMEDIATELY FLUSH WITH WATER WHILE REMOVING CONTAMINATED CLOTHING. IF IRRITATION DEVELOPS, GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITTING. IF CONSCIOUS, DRINK A GLASS OF WATER. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Autoignition Temp:Autoignition Temp Text:NONE Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB IN VERMICULITE OR OTHER SUITABLE ABSORBENT AND PLACE IN IMPERVIOUS CONTAINER. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:NONE Other Precautions:29CFR 1910.1048 SHOULD BE CONSULTED FOR SPECIFIC FORMALDEHYDE, ESTABLISHING REGULATED AREAS, ESTABLISHING RESPIRATORY PROTECTION PROGRAMS , HOUSEKEEPING, RECORD KEEPING, ETC. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF FORMALDEHYDE IS EMITTED AT LEVELS REQUIRING RESPIRATORY PROTECTION, A FULL FACEPIECE WITH CARTRIDGES OR CANISTERS SPECIFICALLY APPROVED BY NIOSH FOR PROTECTION AGAINST FORMALDEHYDE OR A TYPE C SUPP LIED AIR RESPIRATOR SHOULD BE WORN. Ventilation:GOOD GENERAL ROOM VENTILATION SHOULD BE USED. LOCAL EXHAUST VENTILATION OR AN ENCLOSED HANDLING SYSTEM MAY BE REQUIRED. Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER. USE APRON AND FACE SHIELD WHEN MIXING LIQUIDS OR IF SPLASHING IS LIKELY. Work Hygienic Practices:USE GOOD CHEMICAL HYGIENE PRACTICE. AVOID UNNECESSARY CONTACT. Supplemental Safety and Health IRAC CONCLUDED THERE IS SUFFICIENT EVIDENCE THAT FORMALDEHYDE IS CARCINOGENIC TO RATS. FORMALDEHYDE WAS TESTED FOR CARCINOGENICITY BY INHALATION EXPOSURE AT HIGH CONCENTRATIONS IN RATS, HAMSTERS AND M ICE. A SIGNIFICANT INCIDENCE OF SQUAMOUS CELL CARCINOMAS OF THE NASAL CAVITY WERE INDUCED ONLY IN RATS. ================== Physical/Chemical Properties ================== HCC:T7 Boiling Pt:B.P. Text:212F,100C Vapor Pres:18 Vapor Density:0.6 Spec Gravity:1.01 pH:9.47 Evaporation Rate & Reference:0.4 (N-BUTYL ACETATE=1) Solubility in Water:COMPLETE Appearance and Odor:CLEAR, PALE YELLOW SOLUTION. SLIGHT FORMALDEHYDE ODOR. Percent Volatiles by Volume:95 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE OF THE COMMON MATERIALS AND CONTAMINANTS WITH WHICH THE MATERIAL MAY REASONABLY COME INTO CONTACT. Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE BY INCINERATION OR CONTACT WITH A LICENSED CHEMICAL WASTE DISPOSAL AGENCY. DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO LOCAL, STATE AND FEDERAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:P7002-14062 GREEN PLASTISOL Preparer's Name:ROY WHEELDON CAGE:8L872 CAGE:8L872 ============= Composition/Information on Ingredients ============= Ingred Name:VINYL CHLORIDE MONOMER (SARA III) CAS:75-01-4 RTECS #:KU9625000 Fraction by Wt: <0.003% Other REC Limits:NONE RECOMMENDED OSHA PEL:1 PPM ACGIH TLV:5 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:PHTHALATE PLASTICIZER (NOT HAZARDOUS) Other REC Limits:NONE RECOMMENDED Ingred Name:EPOXIDIZED SOYBEAN OIL (NOT HAZARDOUS) Other REC Limits:NONE RECOMMENDED Ingred Name:PVC RESIN (NOT HAZARDOUS) Other REC Limits:NONE RECOMMENDED Ingred Name:BARIUM CARBOXYLATE STABILIZER Fraction by Wt: 0.5% Other REC Limits:NONE RECOMMENDED ACGIH TLV:0.05 MG/M3 (CADMIUM) Ingred Name:CADMIUM CARBOXYLATE STABILIZER Fraction by Wt: 0.1% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.2 MG/M3 (CADMIUM) Ingred Name:ORGANIC PIGMENT (NOT HAZARDOUS) Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:UNKNOWN IARC:YES Health Hazards Acute and Chronic:EYE: MAY CAUSE IRRITATION. SKIN CONTACT: CAN CAUSE SLIGHT IRRITATION. INHALATION: SHOULD BE VENTILATED IF HEAT PROCESSED. INGESTION: CAN CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING, AND DIARRH EA. Explanation of Carcinogenicity:CADMIUM COMPOUND LISTED IARC SUSPECTED CARCINOGEN;NO SPECIFIC INFO ON CADMIUM STABILIZER THAT WOULD PUT THEM IN CATAGORY ======================= First Aid Measures ======================= First Aid:EYE CONTACT: FLUSH WITH WATER FOR 15 MINUTES. SKIN CONTACT: WASH WITH SOAP AND WATER. INHALATION: IF EXCESSIVE INHALATION, REMOVE TO FRESH AIR. INGESTION: CONSULT A PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:>350F,>177C Extinguishing Media:DRY CHEMICAL, REGULAR FOAM, OR WATER FOG. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS IF IGNITED. Unusual Fire/Explosion Hazard:TOXIC GASES CAN FORM - CARBON DIOXIDE, CARBON MONOXIDE, AND VARIOUS HYDROCARBONS. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL SPILLS: ABSORB ON VERMICULITE OR FLOOR DRY. LARGE SPILLS: PUMP TO SALVAGE TANK. ======================Handling and Storage ====================== Handling and Storage Precautions:CONTAINERS MAY BE HAZARDOUS WHEN EMPTIED DUE TO VAPOR BUILD-UP. STORE BETWEEN 50 F AND 90 F, AWAY FROM HEAT OR FLAME. Other Precautions:ALL HAZARD PRECAUTIONS IN THE DATA SHEET MUST BE OBSERVED. THIS PRODUCT CONTAINS A SECTION 313 CHEMICAL SUBJECT TO THE REPORTING REQUIREMENTS OF TITLE III OR SARA AND 40 CFR PART 372. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RECOMMENDED IF LOCAL EXHAUST. NIOSH APPROVED. Ventilation:LOCAL EXHAUST: RECOMMENDED FOR HEAT PROCESSING. MECHANICAL (GENERAL) RECOMMENDED. Other Protective Equipment:WASH WITH SOAP AND WATER IF CONTACT WITH SKIN. WASH CONTAMINATED CLOTHING BEFORE REUSE. Work Hygienic Practices:GOOD INDUSTRIAL HYGIENE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:1:1 (WATER=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:GREEN COLORED LIQUID - VISCOUS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH TEMPERATURES Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, VARIOUS HYDROCARBONS, HYDROGEN CHLORIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE ACCORDING TO LOCAL AND FEDERAL STANDARDS. LIQUID FORM IS HAZARDOUS, SOLID IS NOT. LIQUID HAZARD WASTE CODES: D005, D006.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:822 3554 KODAK RA 2001 DEVELOPER 2 1/5 GALLONS READY-TO-USE CAGE:19139 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 85-90% Ingred Name:POTASSIUM SULFITE CAS:10117-38-1 RTECS #:WT3530000 Fraction by Wt: 1-5% Ingred Name:SODIUM SULFITE CAS:7757-83-7 RTECS #:WE2150000 Fraction by Wt: 1-5% Other REC Limits:5 MG/CUM (DUST) Ingred Name:HYDROQUINONE; 1,4-DIHYDROXYBENZENE; 1,4-BENZENEDIOL CAS:123-31-9 RTECS #:MX3500000 Fraction by Wt: 1-5% OSHA PEL:2 MG/CUM ACGIH TLV:2 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:POTASSIUM CARBONATE, POTASH, PEARL ASH CAS:584-08-7 RTECS #:TS7750000 Fraction by Wt: 1-5% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE: IRRITATION. SKIN: IRRITATION & ALLERGIC REACTION. INGESTION/INHALATION: LOW HAZARD. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. SKIN: FLUSH W/PLENTY OF WATER & WASH W/A NON-ALKALINE (ACID) TYPE OF SKINCLEANER. INGESTION: DRINK 1 TO 2 GLASSES OF WATER. INHALATION: REMOVE TO FR ESH AIR. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NON-COMBUSTIBLE Extinguishing Media:USE APPROPRIATE AGENT FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR A SELF-CONTAINED BREATHING APPARATUS & PROTECTIVE CLOTHING. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO AN ACID-FREE SEWER W/PLENTY OF WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED & AWAY FROM STRONG ACIDS. ============= Exposure Controls/Personal Protection ============= Ventilation:GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT. Other Protective Equipment:NON-ALKALINE (ACID) TYPE OF SKIN CLEANER. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING/SHOES BEFORE REUSE/DESTROY SHOES. KEEP WORK SURFACE CLEAN. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:<212F Vapor Pres:18 Vapor Density:0.6 Spec Gravity:1.091 pH:10.35 Evaporation Rate & Reference:(N-BU AC =1): 0.4 Solubility in Water:COMPLETE Appearance and Odor:CLEAR, NEARLY COLORLESS LIQUID W/FAINT ODOR. Percent Volatiles by Volume:88/WT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS Stability Condition to Avoid:EXCESSIVE HEAT Hazardous Decomposition Products:OXIDES OF SULFUR ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREAT/DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:EA6 EPOXY Kit Part:Y CAGE:1JB33 CAGE:1JB33 CAGE:33564 ============= Composition/Information on Ingredients ============= Ingred Name:MODIFIED RESINS,EPOXY Ingred Name:ASBESTOS (AMIANTHUS, OBSOLETE AMOSITE), (FOR OSHA PEL, SEE 29CFR 1910.1101) CAS:1332-21-4 RTECS #:CI6475000 Fraction by Wt: 23%. OSHA PEL:0.2 FIBERS/CC ACGIH TLV:0.5 FIBERS/CC; A1;89 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Effects of Overexposure:MAY CAUSE EYE IRRITATION, SKIN SENSITIZATION OR OTHER ALLERGIC RESPONSES. ======================= First Aid Measures ======================= First Aid:SKIN CONTACT:WASH IMMEDIATELY WITH SOAP AND WATER. EYE CONTACT:FLUSH IMMEDIATELY WITH PLENTY OF WATER. ===================== Fire Fighting Measures ===================== Flash Point:>200F TCC Extinguishing Media:CO*2, FOAM, DRY CHEMICALS ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE EXCESS & WIPE CLEAN WITH SOLVENTS AS NECESSARY. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AT 90F. Other Precautions:READ CONTAINER LABELS. IF IT IS NEC.TO SAND THE CURED ADHSV"WET SANDING"ISREC.TO ELIM.AIRBORNE ASBESTOS.FOR"DRY SANDING"FOLLOW REC. IN"RESPIRATORY PROTECTION." ============= Exposure Controls/Personal Protection ============= Respiratory Protection:APPRVD NIOSH RESPIRATOR AND FILTER FOR ASBESTOS.SEE"OTHER PRECAUTNS" Ventilation:LOCAL AND GENERAL RECOMMENDED. Supplemental Safety and Health KEY1:N1. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:DECOMPOSES Spec Gravity:1.28 Solubility in Water:NEGLIGIBLE Appearance and Odor:RED VISCOUS PASTE WITH PUNGENT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:LANDFILL OR CONTROLLED BURNING AS REGULATED BY ALL GOVERNMENTAL AGENCIES.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:R320-113 *R320-02 PRIMER COATING ALKYD CAGE:PRATT CAGE:PRATT CAGE:61196 ============= Composition/Information on Ingredients ============= Ingred Name:ZINC CHROMATE CAS:13530-65-9 RTECS #:GB3290000 Fraction by Wt: < OSHA PEL:0.1 MG/M3 (CRO3) ACGIH TLV:0.01MG/M3(CR)A1;9192 Ingred Name:TRIETHYLAMINE (SARA III) CAS:121-44-8 RTECS #:YE0175000 Fraction by Wt: <0.5% OSHA PEL:25 PPM/15 STEL ACGIH TLV:10 PPM/15 STEL; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:MINERAL SPIRITS CAS:64475-85-0 RTECS #:PY8240000 Fraction by Wt: 35% ACGIH TLV:500 PPM Ingred Name:LEAD NAPHTHENATE 365 RTECS #:OG1945000 Fraction by Wt: <0.5% Ingred Name:METHYL EHTYL KETOXIME RTECS #:PM7783000 Fraction by Wt: ,0.5% ===================== Hazards Identification ===================== Effects of Overexposure:IRRIT OF NOSE,THROAT,EYES & POSS DIZZ & NAUSEA. SPRAY MIST CONTAIN LEAD.LEAD POISON IS CHARACTE(SUPP ======================= First Aid Measures ======================= First Aid:INHAL:REMOV FR EXPOS & PROVID FRESH AIR.SPLASH EYES,FLUSH IMMED.W/LG AMTS OF WATR F/15 MIN.SPLASH SKN,REMOV CONTAMIN CLOTHING & WASH AFFECTED AREA W/WATR.INGEST:DO NOT INDUC VOMITING.CONSULT A PHYSICI AN IMMED IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:104F TCC 40C Extinguishing Media:CO*2,DRY CHEM,ALCOH FOAM,POLYMER FOAM PREF F/LARGE FIRES. Fire Fighting Procedures:SELF-CONTAINED BREATH APPARAT F/FIREMN.WATER MAY BE INEFFECT Unusual Fire/Explosion Hazard:KP CONTNRS TIGHT CLOS.ISOLAT FR HEAT,ELECT EQPMT,SPARKS,OPN FLAM.DO NOT APPLY TO VERY HOT SURFACES. ================== Accidental Release Measures ================== Spill Release Procedures:REMOV ALL SOURC OF IGNIT (FLAMS,HOT SURFAC,ELECTRICAL,STATIC OR FRICTIONAL SPARKS.VENTILAT AREA & AVOID BREATHING VAPORS.REVOV W/INERT ABSORBENT & NON-SPARKING TOOLS.STEPS MUST BE TAKEN TO PREVENT CON TAMINATION OF GROND WATER OR STREAMS. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE ABOVE 120F.STORE LG QUANTITIES IN COMPLIANCE W/OSHA 1910.106.CONTAINERS SHOULD BE GROUNDED & BONDED TO THE RECEIVING CONTAINER. Other Precautions:DO NOT CUT OR WELD ON EMPTY CONTAINER.DO NOT USE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ & FULLY UNDERSTOOD BY THE USER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:MECH RESPIRAT TO REMOV OVERSPRA IN OUTDOOR OR OPEN AREA. Ventilation:PRVID GEN DILUT/LOC EXHAUST VENTILAT IN VOL TO KP BELOW TLV Other Protective Equipment:USE PROTECTIV EQPMT TO PREVNT SKIN CONTACT. Supplemental Safety and Health EFFECTS OF OVEREXPOS:BY THE FOLLOWING:HDACHES,DIZZ, STAGGERING GAIT, CONFUSION, UNCONSCIOUSNESS,OR COMA. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:311-375F Vapor Density:HEAV Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:58 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVD CONTCT W/STRONG ACIDS OR ALKALINE MATERIALS. Stability Condition to Avoid:FIRES,HEAT & HOT SURFACES. Hazardous Decomposition Products:BRUNING WILL PRODUC SMOK & OXIDES OF CARBON & LEAD. Conditions to Avoid Polymerization:DO NOT DRIERS OR REACTV CHEM W/O TECHNICAL SUPERVISION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORD W/LOC,STATE & FED REGULATIONS.INCINERATE IN EPA APPRVD FACILITY. DO NOT INCINERATE CLOSED CONTAINERS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:MIL-C-22750E EPOXY CLEAR M0-086, PART A Kit Part:Y Preparer's Name:DAVID SCHMETTERER CAGE:DO165 CAGE:DO165 CAGE:5V430 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ETHYL KETONE (SARA III) (VAPOR PRESSURE 71.2 MM HG) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 20% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM ACGIH TLV:200 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:BISPHENOL A-EPICHLOROHYDRIN RESIN CAS:25085-99-8 Fraction by Wt: 30% Other REC Limits:NONE SPECIFIED Ingred Name:TOLUENE (SARA III) (CONTAINS A TRACE OF BENZENE) (VAPOR PRESSURE 38 MM HG) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 15% Other REC Limits:NONE SPECIFIED OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:VOC: 331 GPL RTECS #:9999999VO Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:OVEREXPOSURE: ACUTE TOXICITY RESULTING IN HEADACHE, DIZZINESS, NAUSEA AND LOSS OF CONSCIOUSNESS. SEVERE EYE IRRITATION POSSIBLY RESULTING IN PERMANENT DAMAGE. IRRITATED MUCOUS MEMBRANES. VOMITING DUE TO INGESTION. DEFATTING & DRYING OF SKIN. SENSITIZATION AFTER REPEATED CONTACT. UNLIKELY THAT NORMAL WORK OPERATIONS * Explanation of Carcinogenicity:YOU SHOULD BE AWARE THAT THIS RESIN HAS BEEN REPORTED TO CAUSE CANCER IN LABORATORY ANIMALS. Effects of Overexposure:* WITH THIS RESIN COULD PRODUCE ATMOSPHERIC CONCENTRATIONS APPROACHING OSHA LIMIT. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH W/LUKEWARM LOW PRESSURE WATER 15 MIN, LIFT EYELIDS. GET MED AID. INHAL: REMOVE TO FRESH AIR. GIVE OXYGEN IF BREATHING DIFFICULT. GIVE ARTIF RESP IF NOT BREATHING. GET MED AID. KEEP WARM & C OMFORTABLE. NEVER GIVE UNCONSCIOUS PERSON LIQS. INGEST: CALL DR IMMED. ONLY INDUCE VOMIT ON DR'S INSTRUCTS. IF VOMIT OCCURS, KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION OF LIQ INTO LUNGS. NEVER GIVE ** ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:22.0F,-5.6C Lower Limits:1.2 Extinguishing Media:FOAM, CO2, OR DRY CHEMICAL. Fire Fighting Procedures:USE WATER TO KEEP EXPOSED CNTNRS COOL, & TO KEEP FLAMMABLE STRUCTURE WET. DON'T ENTER FIRE AREA W/O PROPER PROTECTION BECAUSE HAZARD DECOMP PROD MAY BE PRESENT. Unusual Fire/Explosion Hazard:WATER PRESSURE MAY SPREAD A FLAMMABLE LIQUID FIRE. SEALED CONTAINERS MAY EXPLODE IF OVERHEATED. ================== Accidental Release Measures ================== Spill Release Procedures:WARNING - FLAMMABLE. ELIMINATE ALL IGNITION SOURCES. HANDLING EQUIPMENT MUST BE GROUNDED TO PREVENT SPARKING. SOAK UP WITH AN ABSORBENT AND PLACE IN NON-LEAKING CONTAINERS. SEAL TIGHTLY FOR PROPER DIS POSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:HAZARD-FLAMM. KNOW DOT REGS BEFORE TRANSPORTING MAT'L. WARNING: HOT ORGANIC CHEMICAL VAPORS/MIST SUCEPTIBLE TO SPONTANEOUS COMBUST WHEN MIXED W/AIR. Other Precautions:IGNIT MAY OCCUR AT TEMPS BELOW THOSE PUBLISHED IN LITERATURE (AUTOIGNIT/IGNIT TEMPS). IGNIT TEMPS DECREASE W/INCREASING VAPOR VOL & VAPOR/AIR CONTACT TIME INFLUENCED BY PRESSURE CHANGES. IGNIT MAY OCC UR AT TYPICAL ELEVATED TEMP PROCESS # ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IMPORTANT-MUST PROVIDE ADEQUATE VENTILATION TO MAINTAIN VAPOR CONCENTRATION BELOW ESTABLISHED TLV LIMIT AS GIVEN BY OSHA. IN MORE CONFINED AREAS NIOSH/MSHA APPROVED RESPIRATOR EQUIPPED W/ORGANIC VAPOR CARTRIDGE SHOULD BE WORN. Ventilation:MUST PROVIDE ADEQUATE VENTILATION, SEE RESPIRATORY PROTECTION. Other Protective Equipment:HAVE EYE BATH AND SAFETY SHOWER AVAILABLE. Work Hygienic Practices:N/K *** CLOTHING & SHOES. WASH W/SOAP & WATER. DON'T REUSE CONTAM CLOTHING/SHOES. IF IRRITATION PERSISTS, GET MED AID. Supplemental Safety and Health # CONDITIONS, ESPECIALLY IN PROCESS OPERATING UNDER VACUUM IF SUBJECTED TO SUDDEN INGRESS OF AIR/OUTSIDE PROCESS EQUIP OPERATING UNDER ELEVATED PRESSURE IF SUDDEN ESCAPE OF VAPOR/MIST TO ATMOSPHERE OC CURS. EVALUATE ANY PROPOSED USE IN ELEVATED TEMP PROCESS TO ASSURE SAFE OPERATING CONDITIONS ESTABLISHED/MAINTAINED. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:174 TO 232F Vapor Density:> AIR. Spec Gravity:1.03 Viscosity:>200 CENT Evaporation Rate & Reference:3.42 X N-BUTYL ACETATE Solubility in Water:SLIGHT Appearance and Odor:CLEAR LIQUID; SOLVENT ODOR. Percent Volatiles by Volume:40.0 Corrosion Rate:NOT CORR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MAY BE INCOMPATIBLE WITH OXIDIZING AGENTS AND STRONG ALKALIES. Stability Condition to Avoid:AVOID HEAT, SPARKS, OPEN FLAMES AND INCOMPATIBILITIES. Hazardous Decomposition Products:INCOMPLETE COMBUSTION FOR PRODUCTS LIKE THIS MAY GENERATE HIGHLY POISONOUS CARBON MONOXIDE AND OTHER TOXIC GASES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH CURRENT LOCAL, STATE, AND FEDERAL REGULATION. CONTACT AN APPROVED DISPOSAL FACILITY. EPA HZD#: D001, IGNITABLE. ** ANYTHING BY MOUTH TO UNCONSCIOUS PER SON. SKIN: FLUSH W/WATER WHILE REMOVINGCONTAM ***
1
gloves_mandatory
===================== Product Identification ===================== Product ID:SODIUM SULFITE ANHYDROUS, 3922 CAGE:DO811 CAGE:DO811 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM SULFITE (2:1), ANHYDROUS CAS:7757-83-7 RTECS #:WE2150000 Fraction by Wt: 98-100% ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL:IRRITATION OF MUCOUS MEMBRANES, IRRITATION OF UPPER RESPIRATORY TRACT. SKIN/EYE:IRRITATION. INGEST:GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING, UNCONSCIOUSNESS, CENTRAL NERVOUS SYSTEM DEPRESSI ON, ALLERGIC REACTION MAY DEVELOP, ACHING MUSCLES, MAY BE FATAL. CHRONIC:NONE IDENTIFIED. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:ASTHMA. ======================= First Aid Measures ======================= First Aid:INGEST:IF CONSCIOUS, IMMEDIATELY GIVE LARGE AMOUNTS OF WATER. GET MD. INHAL:MOVE TO FRESH AIR. SKIN:IMMEDIATELY WASH WITH PLENTY OF SOAP & WATER FOR AT LEAST 15 MINUTES. EYE:IMMEDIATELY FLUSH WITH PLE NTY OF WATER FOR AT LEAST 15 MINUTES. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED POSITIVE PRESSURE SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE IDENTIFIED. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR SUITABLE PROTECTIVE CLOTHING. CAREFULLY SWEEP UP AND REMOVE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE AREA. Other Precautions:DURING USE AVOID CONTACT WITH EYES, SKIN, CLOTHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED WHERE ADEQUATE VENTILATION CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS HIGH, USE AN APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR OR DUST MASK. Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE. Other Protective Equipment:LAB COAT. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:2.63 Solubility in Water:APPRECIABLE (>10%) Appearance and Odor:SOLID WHITE CRYSTALS OR POWDER. ODORLESS. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG ACIDS. Stability Condition to Avoid:HEAT, MOISTURE. Hazardous Decomposition Products:SO*X, OXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:ASPHALT EMULSION EZ STIR FILLER SEALER, 063 CAGE:0VZ30 CAGE:0VZ30 ============= Composition/Information on Ingredients ============= Ingred Name:ASPHALT (PETROLEUM); (PETROLEUM ASPHALT) CAS:8052-42-4 RTECS #:CI9900000 Fraction by Wt: <45% OSHA PEL:N/K ACGIH TLV:5 MG/M3 (FUME) Ingred Name:INORGANIC FILLERS Fraction by Wt: <10% OSHA PEL:N/K ACGIH TLV:0.39 MG/M3 (MFR) Ingred Name:LATEX Fraction by Wt: <2% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: >50% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT:ANSI Z49.1 & OTHER GOVERNMENTAL & INDUSTRIAL REFERENCES PERTAINING TO CLEANING, REPAIRING, WELDING OR (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:OTHER CONTEMPLATED OPERATIONS. RTECS #:9999999ZZ Ingred Name:OTHER PROT EQUIP:SHOULD WEAR CLOTHING THAT IS IMPERVIOUS TO ASPHALT. RTECS #:9999999ZZ Ingred Name:HYGIENE PRACT:THORO BEFORE EATING/SMOKING. REMOVE CONTAM CLTHG, LAUNDER/DRY CLEAN BEFORE REUSE. REMOVE CONTAM (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:SHOES & THOROUGHLY CLEAN & DRY BEFORE REUSE. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:HEALTH STUDIES HAVE SHOWN THAT INDIVIDUAL SENSITIVITIES VARY FROM PERSON TO PERSON. AS A PRECAUTION, EXPOSURE TO VAPORS, LIQUIDS, MISTS OR FUMES SHOULD BE MINIMIZED. BREATHING ASPHALT AEROSOL OR ASPHA LT SMOKE FOR PROTRACTED PERIODS OF TIMEHAS PRODUCED DAMAGE TO LUNGS OF MICE. AMONG CHANGES OBSERVED (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:WERE: BRONCHITIS, PNEUMONITIS & ABSCESS FORMATION. IARC HAS DETERMINED THERE IS LIMITED EVID OF CARCIN FOR UNDILUTED STEAM-REFINED ASPHALTS IN ANIMALS & ADEQ EVID OF CARCIN FOR UNDILUTED STEA M-REFINED ASPHALTS IN HUMANS. Medical Cond Aggravated by Exposure:PERSONS W/HISTORY OF DISEASES IN LIVER, SKIN, EYE, RESP SYS, BLOOD FORMING ORGS OR W/BLEEDING ABNORMS/EXPOS TO MATL HARMFUL TO THESE SYS ARE AT GREATER RISK THAN NORMAL RISK OF DEVELOPING (SUPP DATA) ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/LG AMTS OF WATER FOR AT LST 15 MINS & SEEK MED ATTN. SKIN:WASH AFFECTED AREA W/MILD SOAP & WATER. REMOVE CONTAM CLTHG/SHOES & WIPE EXCESS FROM SKIN. IF IRRIT PERSISTS SEEK MED ATTN. DO NO T REUSE CLTHG UNTIL THORO LAUNDERED. INHAL:REMOVE FROM EXPOS. IF BRTHG HAS STOPPED ADMIN ARTF RESP/OXYG AS NEEDED. SEEK MED ATTN. INGEST:DO NOT INDUCE VOMIT-TRANSPORT TO HOSPITAL IMMED. GET MED ATTN. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:>325F,>163C Extinguishing Media:USE DRY CHEMICAL OR WATER FOG AS AN EXTINGUISHING MEDIA. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . WATER MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:LG SPILLS:EVACUATE ALL UNNEC PERS FROM AFFECTED AREA. DO NOT RE-ENTER AFFECTED AREA W/OUT PROPER PROT EQUIP. VENTILATE AREA OF SPILL. COLLECT IN MOST SAFE MANNER FOR DISP/RECLAMATION IN SEALED CNTNRS.FOR FURTHER INFO RELATIVE TO SPILLS (SUPP DATA) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CNTNRS CLSD WHEN NOT IN USE. DO NOT STORE NEAR HEAT, SPKS, FLAME/STRONG OXIDANTS. KEEP CNTNRS TIGHTLY CLSD & IN PROPERLY VENTILATED AREA. Other Precautions:MIN BRTHG VAPS/MIST. "EMPTY" CNTNRS RETAIN RESIDUE(LIQ &/OR VAPS) & CAN BE DANGEROUS. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND/EXPOSE SUCH CNTNRS TO HEAT, FLAME, SPKS/OTHER SOURCES OF IGNIT. THEY MAY EXPLODE & CAUSE(SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR WHEN TLV IS EXCEEDED. Ventilation:VENT SHOULD BE ADEQUATE. MAINTAIN VAPOR &/OR PARTICULATE LEVELS BELOW APPLICABLE EXPOSURE LIMITS FOR ASPHALT FUMES. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . EMPLOYEES WHO HAVE PRLNG/RPTD EXPOS (ING 7) Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING W/THIS MATL. EMPLOYEES WHO HANDLE THIS MATL SHOULD CLEANSE HANDS (ING 8) Supplemental Safety and Health PH:6.5-7.5. MED CNDTNS:ADVERSE HLTH EFTS WHEN WORKING W/THIS PROD. SPILL PROC:RESULTING FROM TRANSPORTATION INCIDENTS, REFER TO LATEST DOT GUIDEBOOK FOR HAZ MATLS INCIDENTS, DOT P 5800.3. OTHER PREC:I NJURY/DEATH. DO NOT ATTEMPT TO CLEAN SINCE RESIDUE IS DFCLT TO REMOVE. FOR WORK ON TANKS, REFER TO OSHA REG (ING 5) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>212F,>100C Melt/Freeze Pt:M.P/F.P Text:>10F,>-12C Vapor Pres:<1 @ 25C Vapor Density:HVR/AIR Spec Gravity:1-1.4 pH:SUPDAT Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:PARTIALLY MISCIBLE Appearance and Odor:MODERATELY THICK, DARK BROWN TO BLACK COLORED LIQUID W/PETROLEUM LIKE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID STRONG OXIDIZERS. Stability Condition to Avoid:AVOID HEAT OR OPEN FLAMES. Hazardous Decomposition Products:PYROLYSIS PRODUCTS OF AROMATIC HYDROCARBONS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . DISPOSE OF IN AN ENVIRONMENTALLY SAFE MANNER & I/A/W GOVERNMENTAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:QKA-1660 CAGE:JO981 CAGE:49956 CAGE:JO981 ============= Composition/Information on Ingredients ============= Ingred Name:BERYLLIUM OXIDE (AS BERYLLIUM) CAS:1304-56-9 RTECS #:DS4025000 OSHA PEL:0.002 MG/M3; C,0.005 ACGIH TLV:0.002 MG/M3; A2;8990 ===================== Hazards Identification ===================== Effects of Overexposure:ACUTE: PNEUMONITIS. ACUTE LOCAL:IRRITANT. CHRONIC: BERYLLIOSIS. POSSIBLE CARCINOGEN. ======================= First Aid Measures ======================= First Aid:CUT OR PUNCTURE WOUND: IMMED ATTENTION BY FLUSH EXTENSIVELY. BEO CAUSES ULCERS WHICH ARE EXTREMELY LONG IN HEALING. INHALE: IMMED CHEST X-RAY. EYES: FLUSH IMMEDIATELY AND EXTENSIVELY FOR AT LEAST 15 M INS. FOR ALL SITUATION SEE MD IMMEDIATELY. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAINMENT.HIGHLY TOXIC BY INHALATION. REQUIRES SUITABLE RESPIRATORY PROTECTION. DO NOT DRY SWEEP OR IN ANY WAY CAUSE POWDER TO BECOME AIRBORNE. ======================Handling and Storage ====================== Handling and Storage Precautions:POWERED MATERIAL SHOULD BE STORED IN A SEALED CONTAINER. TRANSFER SHOULD BE DONE WITHIN VENTILATED HOOD. Other Precautions:STRICT HYGIENE: PREVENT DUST DISPERSION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORMALLY REQUIRED IF MATERIAL NOT AIRBORNE. Ventilation:LOCAL EXHAUST HOME. Supplemental Safety and Health BRUSH WELLMAN, ELMORE OHIO SUPPLIES B O. RAYTHEON FOUNDRY AVE WALTHAM MA. 02254 MFG OF TUBE. ================== Physical/Chemical Properties ================== HCC:T3 Boiling Pt:B.P. Text:7160F,3960C Spec Gravity:3.016 Solubility in Water:NEGLIGIBLE Appearance and Odor:WHITE POWDER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:SKIN CONTACT OR INHALATION. ==================== Disposal Considerations ==================== Waste Disposal Methods:IN ACCORDANCE WITH ALL LOCAL, STATE, FEDERAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:162 0509 RP X-OMAT DEVELOPER REPLENISHER,PART B Kit Part:Y CAGE:19139 CAGE:19139 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:ACETIC ACID (CERCLA) CAS:64-19-7 RTECS #:AF1225000 Fraction by Wt: 75 - 80% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 PPM ACGIH TLV:10 PPM/15 STEL; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:1-PHENYL-3-PYRAZOLIDONE/PYRAZOLIDINONE CAS:92-43-3 RTECS #:UQ8750000 Fraction by Wt: 10 - 15% Other REC Limits:NONE RECOMMENDED Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 5 - 10% Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS UNKNOWN. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, RESPIRATORY & GI TRACTS. ACUTE- CORROSIVE. INHALE:EXTREMELY IRRITATING. MAY CAUSE DELAYED LUNG INJURY. EYES:CAUSES SEVERE BURNS. VAPORS EXTREMELY IRRITATING. SKIN:CAUSES SEVE RE BURNS, ALLERGIC REACTIONS. ORAL:MAY BE FATAL. MAY CAUSE GI TRACT BURNS. CHRONIC- MAY CAUSE BLOOD EFFECTS IN ANIMALS. Explanation of Carcinogenicity:NONE Effects of Overexposure:SEVERE IRRITATION, SEVERE BURNS, PAIN, TEARING, COUGHING Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS, EYE PROBLEMS OR IMPAIRED RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES:IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES. HOLD EYELIDS OPEN. CALL PHYSICIAN. SKIN:FLUS H WITH WATER FOR 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING. ORAL:DO NOT INDUCE VOMITING. IF CONSCIOUS, DRINK 1-2 GLASSES OF WATER. CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:134F,57C Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, ALCOHOL FOAM, WATER SPRAY. USE WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. HAZARDOUS DECOMPOSITION PRODUCTS MAY BE FORMED. Unusual Fire/Explosion Hazard:FLAMMABLE AND CORROSIVE. CONTAINER MAY RUPTURE. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENTS. VENTILATE AREA. REMOVE IGNITION SOURCES. NEUTRALIZE WITH BAKING SODA. ABSORB WITH VERMICULITE. PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE THOROUGHLY. PREVENT RU NOFF FROM ENTERING DRAINS, SEWERS OR STREAMS. Neutralizing Agent:SODIUM BICARBONATE ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE IN COOL, VENTILATED AREA, AWAY FROM INCOMPATIBLE MATERIALS AND SOUCES OF IGNITION. Other Precautions:KEEP THIS AND ALL CHEMICALS OUT OF REACH OF CHILDREN. THIS PRODUCT FOR INDUSTRIAL USE ONLY. AVOID BREATHING VAPORS OR MISTS. DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. WASH THOROUGHLY AFTER HANDLING. LAUNDER CONTAMINATED CLOTHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE CONCENTRATIONS BELOW TLV/PEL, A NIOSH-APPROVED ORGANIC VAPOR, ACID GAS RESPIRATOR MUST BE WORN. A PROGRAM SHOULD BE INSTITUTED TO ASSURE COMPLIANCE WIT H OSHA STANDARD 29 CFR 1910.134. Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES/HR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS Other Protective Equipment:SAFETY SHOWER AND EYE WASH FOUNTAIN SHOULD BE LOCATED NEARBY. WEAR APPROPRIATE PROTECTIVE CLOTHING FOR RISK OF EXPOSURE. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health KEY1:F6. CATALOG FOR PARTS: B AND C. SEE W (WORK SOLUTION). ECOLOGICAL INFORMATION:A HIGH BIOCHEMICAL OXYGEN DEMAND, A HIGH POTENTIAL TO AFFECT SOME AQUATIC ORGANISMS. AFTER DILUTION WITH LARGE AMOUNT OF WATER, FOLLOWED BY SECONDARY WASTE TREATMENT, THIS MATERIAL IS NOT EXPECTED TO CAUSE ADVERSE ENVIRONMENTAL EFFECTS. ================== Physical/Chemical Properties ================== HCC:F6 NRC/State Lic Num:NOT RELEVANT Vapor Pres:18 @ 68F Vapor Density:1.7 Spec Gravity:1.081 pH:<1.0 Solubility in Water:COMPLETE Appearance and Odor:ORANGE LIQUID - PUNGENT ODOR Percent Volatiles by Volume:85- 90 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG BASES Stability Condition to Avoid:FLAMES AND OTHER SOURCES OF IGNITION Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, OXIDES OF NITROGEN ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT TO FEDERAL, STATE OR LOCAL REGULATIONS. FLUSH TO SEWER WITH LARGE AMOUNT OF WATER, IF ALLOWED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE, FOLLOW L ABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:EASY PAKS VANISH BOWL CLEANER CAGE:85234 CAGE:85234 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM CARBONATE CONCENTRATE (DILUTED [BOWL]: <0.2%) CAS:497-19-8 RTECS #:VZ4050000 Fraction by Wt: <20% Other REC Limits:NONE RECOMMENDED Ingred Name:CITRIC ACID CONCENTRATE (DILUTED [BOWL]: <0.2%) CAS:77-92-9 RTECS #:GE7350000 Fraction by Wt: <20% Other REC Limits:NONE RECOMMENDED Ingred Name:PROTEASE ENZYME CONCENTRATE (DILUTED [BOWL]:<0.01%) CAS:9001-92-7 RTECS #:UK9540000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.00006 MG/M3 ACGIH TLV:0.00006 MG/M3 Ingred Name:SODIUM CHLORIDE CONCENTRATE (DILUTED [BOWL]:<0.5%) CAS:7647-14-5 RTECS #:VZ4725000 Fraction by Wt: <50% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:POWDER: INHALATION, ABSORPTION, & INGESTION: SYSTEMIC POISONING IS NOT EXPECTED BY THIS ROUTE. HEALTH HAZARD (POWDER): IRRITANT TO EYES. ENZYME MAY CAUSE ALLERGIC REACTION TO SENSITIVE INDIVIDUALS. (D ILUTION): MAY CAUSE SENSATION OF IRRITATION TO THE EYES. ALLERGIC REACTION CAN OCCUR IN SENSITIVE INDIVIDUALS. Effects of Overexposure:POWDER: EYES: IRRITATION, REDNESS, SWELLING. SKIN: REDNESS AND SENSATION OF IRRITATION. INGESTION: SPONTANEOUS VOMITING AND DIARRHEA MAY OCCUR. ALLERGIC REACTION: INDIVIDUALS SENSITIVE TO ENZYMES MAY DEVELOP ALLERGIC SYMPTOMS. DILUTION: EYES: SENSATION OF IRRITATION. SKIN: NONE KNOWN. INGESTION: NONE KNOWN. Medical Cond Aggravated by Exposure:PRE-EXISTING SENSITIZATION TO ENZYMES. ======================= First Aid Measures ======================= First Aid:POWDER: EYES: RINSE IMMEDIATLEY WITH WATER. REMOVE CONTACT LENSES & THEN FLUSH EYES WITH WATER 15 MINUTES. IF IRRITATION PERSISTS, CONTACT PHYSICIAN. SKIN: FLUSH WITH WATER 15 MINUTES. IF IRRITATION P ERSISTS, CONTACT PHYSICIAN. SKIN: FLUSHWITH WATER 15 MINUTES. IF IRRITATION PERSISTS, CONTACT PHYSICIAN. INGESTED: DRINK GLASSFUL OF WATER OR MILK. THEN CONTACT POISON CTR OR DR IMMEDIATELY. * ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:NONE Upper Limits:NONE Extinguishing Media:WATER FOG, DRY ALCOHOL TYPE OR ALL PURPOSE FOAM, DRY CHEMICAL, CARBON DIOXIDE OR OTHER CLASS B EXTINGUISHING AGENTS. Fire Fighting Procedures:THOSE EXPOSED TO COMBUSTION BY-PRODUCTS SHOULD WEAR FULL PROTECTIVE EQUIPMENT, INCLUDING PRESSURE DEMAND SELF CONTAINED BREATHING APPARATUS & TURNOUT EQUIPMENT. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:AVOID EYE,SKIN,MOUTH,CLOTH CONTACT.AVOID WHEN CLEANING UP LRG SPILL.CONSULT RESP MFR FOR SELECTION.MIST W/WATER TO REDUCE DUST.SWEEP U P & REMOVE TO DISPOSAL SITE. MOP/FLH ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT REMOVE PACKETS FROM DISPENSER BEFORE USE. DO NOT HANDLE PACKETS W/WET HANDS. RESEAL CONTAINER AFTER REMOVING PACKET.STORE IN COOL,DRY PLACE. Other Precautions:KEEP FROM FREEZING.AVOID CONTACT W/EYES.WASH HANDS THOROUGHLY AFTER HANDLING POWDER.DON'T USE IF ALLERGIC TO ENZYMES.NEVER USE W/CHLORINE PRODUCTS.CAN REACT TO GIVE CHLORINE GAS.IF OCCURS,LEAVE AREA I MMED. DON'T RETURN FOR 1/2 HR.VENT AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN USED ACCORDING TO LABEL DIRECTIONS, PRODUCT EXPOSURE EXCEEDS THAT CONTEMPLATED BY LABEL DIRECTIONS (MFR & LRG SPILL) USE PROTECT IVE MEASURES.CONSULT PROTECTIVE MFRS. Ventilation:SEE RESPIRATORY PROTECTION Other Protective Equipment:SEE RESPIRATORY PROTECTION Work Hygienic Practices:ALWAYS USE THE PRODUCT IN THE VICINITY OF A WATER SOURCE IN CASE OF ACCIDENT. Supplemental Safety and Health * FIRST AID CONT'D: DILUTION: EYES: RINSE IMMEDIATELY WITH WATER. REMOVE CONTACT LENSES AND THEN FLUSH EYES WITH WATER FOR 15 MINUTES. IF IRRITATION PERSISTS, CONTACT PHYSICIAN. ALLERGIC REACTION: CON TACT PHYSICIAN IF ALLERGIC SYMPTOMS DEVELOP. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:NONE Melt/Freeze Pt:M.P/F.P Text:NONE Vapor Pres:NONE Vapor Density:NONE Spec Gravity:0.95 (WATER=1) pH:APPRX6 Evaporation Rate & Reference:NONE Solubility in Water:100% Appearance and Odor:BLUE POWDER WITH LAVENDER FRAGRANCE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CHLORINE PRODUCTS Stability Condition to Avoid:DO NOT MIX WITH ANYTHING BUT WATER. Hazardous Decomposition Products:WHEN BURNED OXIDES OF CARBON FORM ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE ONLY IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE, AND LOCAL LAWS AND REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:ISOPROPYL ALCOHOL, ISOPROPANOL Kit Part:Y Preparer's Name:DGSC-SSH CAGE:86257 CAGE:86257 ============= Composition/Information on Ingredients ============= Ingred Name:ISOPROPYL ALCOHOL (SARA III) CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 100% OSHA PEL:400 PPM/500 STEL ACGIH TLV:400 PPM/500STEL;9192 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE- MAY CAUSE IRRITATION OF EYES, SKIN & G.I. TRACT. CNS EFFECTS LIKE HEADACHE, DIZZINESS, NAUSEA AND VOMITING POSSIBLE. REDNESS AND/OR BURNS OF EYES/SKIN MAY OCCUR. CHRONIC: DRYING OF SKIN AND DEF ATTING. Effects of Overexposure:MAY CAUSE IRRITATION OF EYES, SKIN & G.I. TRACT. CNS EFFECTS LIKE HEADACHE, DIZZINESS, NAUSEA AND VOMITING POSSIBLE. REDNESS AND/OR BURNS OF EYES/SKIN MAY OCCUR. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS MAY BE MORE SUSCEPTIBLE TO THIS MATERIAL. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. SKIN:WASH WITH SOAP & WATER. REMOVE CONTAMINATED CLOTHING. EYE:FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. INHALED:REMOVE TO FRESH AIR & PROVIDE O XYGEN/CPR IF NEEDED. ORAL:IF CONSCIOUS,INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MEDICAL PERSONNEL. CALL A PHYSICIAN/POISON CONTROL CENTER IMMEDIATELY. NEVER GIVE ANYTHING TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:70.0F,21.1C Lower Limits:2.5 Upper Limits:5.2 Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, ALCOHOL FOAM. WATER MAY BE INEFFECTIVE, BUT SHOULD BE USED TO COOL FIRE-EXPOSED CONTAINERS Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:VAPOR IS HEAVIER THAN AIR AND CAN TRAVEL CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. CONTAINERS MAY RUPTURE DUE TO VAPOR PRESSURE BUILDUP. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. ELIMINATE SOURCES OF IGNITION. VENTILATE THE AREA. CONTAIN THE SPILL. PICK UP LARGE SPILL WITH NON-SPARKING TOOLS; SMALL SPILLS/RESIDUE WITH INERT ABSORBENT MATERIAL. PLACE IN CONTAINERS. PREVENT ENTERING WATERWAYS/SEWERS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE- STORE IN COOL, VENTILATED AREA, IN TIGHTLY CLOSED CONTAINERS, AWAY FROM HEAT, FLAMES & OXIDIZERS. Other Precautions:AVOID BREATHING VAPORS OR MISTS. DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR DRINKING. REMOVE CONTAMINATED CLOTHING PROMPTLY. KEEP OUT OF REACH OF C HILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NON REQUIRED UNDER NORMAL CONDITIONS. IF HIGH VAPOR OR MIST CONCENTRATIONS EXPECTED, USE NIOSH-APPROVED RESPIRATOR FOR ORGANIC VAPORS AND MISTS. WEAR SUPPLIED-AIR RESPIRATOR PROTECTION IN CONFINED OR ENCLOSED SPACES, IF NEEDED. Ventilation:MECHANICAL (GENERAL AND/OR LOCAL EXHAUST, EXPLOSION-PROOF) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S). Other Protective Equipment:EYE WASH STATION, QUICK DRENCH SHOWER AND IMPERVIOUS CLOTHING Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health NO MSDS WAS AVAILABLE FROM MANUFACTURER. THIS MSDS WAS PREPARED BY THE PROFESSIONALS OF DGSC-SSH WITHOUT ANY WARRANTY. IT IS THE USER'S RESPONSIBILITY TO GATHER INFORMATION AND USE THE MATERIAL PROPER LY TO PROTECT EMPLOYEES AND ENVIRONMENT.KIT CONSISTS OF TWO PARTS. FOR PART TWO, SEE PIN B SAME NSN. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:181F,83C Vapor Density:>1 Spec Gravity:0.7854 Solubility in Water:COMPLETE Appearance and Odor:COLORLESS LIQUID, PLEASANT ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HEAT, SPARKS, FLAME, FIRE, AND OTHER SOURCES OF IGNITION Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:HILTI .27 CAL SHORT POWERLOADS CAGE:9H236 CAGE:9H236 CAGE:MARKN ============= Composition/Information on Ingredients ============= Ingred Name:BASE METAL; (BASE METAL-BRASS CASE.) % (WT):77.2-84.2 Fraction by Wt: SEE ING OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:PROPELLANT; (HERCULES PROPELLANT-DOUBLE BASE FOR COLOR CODE-GREEN, YELLOW, RED, PURPLE). % (WT):13.3-20.5 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:CCI PRIMING MIXTURE - R7 (FOR COLOR CODE - GREEN, YELLOW, RED, PURPLE) Fraction by Wt: 2.3-2.5% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE AND CHRONIC:NONE LISTED BY MANUFACTURER. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:IMMEDIATELY FLUSH W/POTABLE WATER FOR MINIMUM OF 15 MINUTES, SEEK ASSISTANCE FROM MD ( ). SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . ===================== Fire Fighting Measures ===================== Flash Point:392F,200C Extinguishing Media:WATER. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . PRODUCT WILL EXPLODE WHEN HEATED ABOVE 200C. Unusual Fire/Explosion Hazard:PRODUCT WILL EXPLODE WHEN HEATED ABOVE 200C. ================== Accidental Release Measures ================== Spill Release Procedures:NONE SPECIFIED BY MANUFACTURER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY PLACE. STORE IN ORIGINAL CONTAINER. DO NOT CRUSH. Other Precautions:USE ONLY IN POWDER ACTUATED TOOLS DESIGNED TO HANDLE THESE LOADS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE. NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment:RECOMMEND WEARING EYE, FOOT & HEARING PROT WHEN USING LOADS. ANSI APPRVD EMER EYE WASH & DELUGE SHOWER . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Evaporation Rate & Reference:NOT KNOWN Appearance and Odor:BRASS CASE - COLOR CODED ON STAR CRIMP. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, STRONG OXIDIZERS. Stability Condition to Avoid:ACIDS, HEAT, CRUSHING, ELECTRICAL SHORT CIRCUITS. Hazardous Decomposition Products:LEAD FUMES IN CONFINED AREAS OVER PROLONGED USE. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTROLLED BURNING ON APPROVED SITE. DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS .
1
gloves_mandatory
===================== Product Identification ===================== Product ID:ARDROX 985 P-13;DYE PENETRANT-FLUORESCENT Preparer's Name:ABAYOMI I.OWEI CAGE:23373 CAGE:23373 ============= Composition/Information on Ingredients ============= Ingred Name:DITRIDECYLPHTHALATE(PHTHALATE) Fraction by Wt: >30.0% Other REC Limits:NONE SPECIFIED Ingred Name:SURFACTANTS Other REC Limits:NONE SPECIFIED Ingred Name:FLUORESCENT DYE Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:IRRITATION OF EYES,SKIN,RESPIRATORY OR G.I.TRACTS;INGESTION MAY CAUSE STOMACH UPSET. Explanation of Carcinogenicity:DATA PER MSDS Effects of Overexposure:MAY CAUSE IRRITATION OF EYES,SKIN,RESPIRATORY OR G.I.TRACTS; INGESTION MAY CAUSE STOMACH UPSET. Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS OR WITH A PRE-EXISTING DISEASE INVOLVING THE EYES, SKIN, OR RESPIRATORY TRACT MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING. GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN:REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. IF IRRITATION PERSISTS, GET MEDICAL ADVICE. INGESTION:DO NOT INDUCE VOMITING. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:200F,93C Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:NONE NOTED BY THE MFR ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTION;CONTAIN FREE MATERIAL IF POSSIBLE;USE SUITABLE INERT ABSORBENT MATERIAL AND RECOVER FOR PROPER DISPOSAL IN AN APPROVED CONTAINER. Neutralizing Agent:NOT APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED AREA. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. PROTECT CONTAINERS FROM PHYSICAL DAMAGE. Other Precautions:DO NOT TAKE INTERNALLY. DO NOT BREATHE MIST. AVOID PROLONGED OR REPEATED BREATHING OF VAPOR. AVOID CONTACT WITH EYES. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NEEDED WITH ADEQUATE VENTILATION . Ventilation:LOCAL/GENERAL TO MAINTAIN PEL/TLV. Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER,WORK CLOTHING AND APRON AS REQUIRED. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO NOT BREATHE VAPORS OR MISTS. ================== Physical/Chemical Properties ================== HCC:V4 Boiling Pt:B.P. Text:266F,130C Vapor Density:>1.0 Spec Gravity:0.89 Evaporation Rate & Reference:<1.0(N-BUTYL ACETATE=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR YELLOW GREEN,FLUORESCENT MOBILE LIQUID WITH MILD SOLVENT TYPE ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS AND STRONG ACIDS(NITRIC ACID) Stability Condition to Avoid:HIGH TEMPERATURES AND OPEN FLAMES Hazardous Decomposition Products:NONE NOTED . ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT LOCAL AUTHORITIES.DISPOSAL MUST BE MADE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:SC-1-1B INSTAROK CABLE,SEALING CEMENT CAGE:MCRET CAGE:MCRET ============= Composition/Information on Ingredients ============= Ingred Name:PLASTER OF PARIS; CALCIUM SULFATE HEMIHYDRATE CAS:10034-76-1 RTECS #:EW4150000 Fraction by Wt: 55% ACGIH TLV:10 MG/CUM Ingred Name:SILICA ACID, CALCIUM SALT *95-4* CAS:1344-95-2 RTECS #:VV9150000 Fraction by Wt: 44% OSHA PEL:0.05 MG/CUM (CD) ACGIH TLV:10 MG/CUM Ingred Name:FLOW CONTROL AGENTS Fraction by Wt: 1% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES/SKIN: MAY CAUSE IRRITATION. INHALATION: DUST IS CONSIDERED A NUISANCE DUST. THIS PRODUCT HARDENS WHEN WETTED & IF INGESTED MAY RESULT IN OBSTRUCTION. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLOOD W/WATER FOR 15 MINS. SKIN: REMOVE BY WASHING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NONCOMBUSTIBLE Extinguishing Media:USE MEDIA APPROPRIATE TO THE SURROUNDING AREA. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP & PLACE IN SUITABLE CONTAINERS. AVOID CREATING EXCESSIVE DUST. DON'T WASH SLURRY DOWN DRAINS SINCE THIS MAY CAUSE PLUGGING. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN DRY LOCATION AWAY FROM WATER/HIGH HUMIDITY CONDTIONS TO AVOID PREMATURE HARDENING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED NUISANCE DUST RESPIRATOR IF >TLV. Ventilation:GENERAL MECHANICAL EXHAUST Other Protective Equipment:NONE Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:2.7 pH:9 Solubility in Water:2% Appearance and Odor:GRAY, ODORLESS POWDER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF AS SOLID WASTE IN LANDFILL IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:STAY-SILV 30 CAGE:27911 CAGE:27911 ============= Composition/Information on Ingredients ============= Ingred Name:SILVER (SARA III) CAS:7440-22-4 RTECS #:VW3500000 Fraction by Wt: 30% Other REC Limits:10 UG/CUM OSHA PEL:0.01 MG/M3 ACGIH TLV:0.1 MG/M3; 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:COPPER (SARA III) CAS:7440-50-8 RTECS #:GL5325000 Fraction by Wt: 27% Other REC Limits:0.2 MG/CUM FUMES OSHA PEL:0.1MG/M3 FUME/1 DUST ACGIH TLV:0.2MG/M3 FUME; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ZINC OXIDE CAS:1314-13-2 RTECS #:ZH4810000 Fraction by Wt: 23% OSHA PEL:15MG/M3 TDUST/5 FUME ACGIH TLV:10MG/M3 TDUST; 9293 Ingred Name:CADMIUM OXIDE (FUME) CAS:1306-19-0 RTECS #:EV1930000 Fraction by Wt: 20% OSHA PEL:0.05 MG/CUM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: METAL FUME FEVER, METALLIC TASTE IN THE MOUTH, DRYNESS OR IRRITATION OF THE THROAT, NOSE & CHEST PAIN, COUGHING, SHORTNESS OF BREATH, NAUSEA, BODY ACHE, & CHILLS. Explanation of Carcinogenicity:NICKEL CONSIDERED A POSSIBLE CARCINOGEN. CADMIUM SUSPECTED CARCINOGENS BASED ON ANIMAL TESTS. Effects of Overexposure:INHALATION: LONG TERM CAUSE PULMONARY IRRITATION, PNEUMOCONIOSIS, LUNG & KIDNEY DAMAGE, PULMONARY EDEMA, WHICH MAY BE FATAL. Medical Cond Aggravated by Exposure:INDIVIDUALS WITH IMPAIRED PULMONARY FUNCTIONS OR ILLNESS MAY HAVE SYMPTOMS EXACERBATED BY FUME IRRITANTS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE FROM DUST/FUME EXPOSURE. IF BREATHING HAS STOPPED, PERFORM ARTIFICIAL RESPIRATION. SUMMON MEDICAL AID IMMEDIATELY. ===================== Fire Fighting Measures ===================== Unusual Fire/Explosion Hazard:NON FLAMMABLE. OPEN FLAME & SPARKS CAN IGNITE COMBUSTIBLES. ======================Handling and Storage ====================== Handling and Storage Precautions:BRAZING ROD OR WIRE IS A NONHAZARDOUS SOLID AT AMBIENT TEMPERATURE. HAZARDS MAY RESULT FROM FUME GENERATED DURING BRAZING. Other Precautions:BRAZING ALLOYS ARE FREQUENTLY USED WITH A FLUORIDE TYPE FLUX. IF APPLICABLE, FLUX FUME SHOULD BE CONSIDERED IN EVALUATION OF HAZARDS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE RESPIRABLE FUME RESPIRATOR OR AIR SUPPLIED RESPIRATOR WHEN BRAZING IN CONFINED SPACE. Ventilation:PROVIDE LOCAL EXHAUST VENTILATION TO KEEP <TLV. Other Protective Equipment:ARM PROTECTORS, APRONS, HATS, SHOULDER Work Hygienic Practices:DETERMINE THE COMPOSITION & QTY OF FUMES & GASES IS TO TAKE AN AIR SAMPLE IN THE WORKER'S BREATHING ZONE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Appearance and Odor:SOLID WIRE OR ROD. RODS MAY BE COATED W/CHEMICAL FLUX. FLUX COATING MAY BE RED. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:BRAZING FUMES, GASES, SILVER, COPPER, ZINC (OXIDE), CADIUM (OXIDE), TIN (OXIDE), BORIC ACID (BORON OXIDE), FLUORIDES (F)
1
gloves_mandatory
===================== Product Identification ===================== Product ID:DEGREASE-IT CW2295 AEROSOL DEGREASER SPRAY Preparer's Name:KEN HEARREAN CAGE:67292 CAGE:67292 ============= Composition/Information on Ingredients ============= Ingred Name:FORMAL Fraction by Wt: <25% Ingred Name:HEPTANE *98-1* CAS:142-82-5 RTECS #:MI7700000 Fraction by Wt: <60% Other REC Limits:400 PPM OSHA PEL:2000 MG/CUM ACGIH TLV:1640 MG/CUM Ingred Name:PROPANE (DIMETHYLMETHANE)*98-1* CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: <25% Other REC Limits:1800 MG/CUM OSHA PEL:1000 PPM ACGIH TLV:SIMPLE ASPHYXIANT ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SHORT TERM EXPOSURE: MAY CAUSE DIZZINESS, HEADACHE, IRRITATION OF EYES & SKIN & DEFATTING OF SKIN. LONG TERM EXPOSURE: MAY CAUSE DERMATITIS. LIQUID ASPIRATED INTO LUNGS MAY CAUSE CHEMICAL PNEUMONITIS. MAY CAUSE DEATH W/LONGER EXPOSURE. INGESTION MAY BE FATAL. MAY CAUSE DAMAGE TO LUNGS/LIVER/KIDNEY & AFFECT CNS. Explanation of Carcinogenicity:NONE Effects of Overexposure:SHORT TERM EXPOSURE: MAY CAUSE DIZZINESS, HEADACHE, IRRITATION OF EYES & SKIN & DEFATTING OF SKIN. LONG TERM EXPOSURE: MAY CAUSE DERMATITIS. Medical Cond Aggravated by Exposure:PRE-EXISTING RESPIRATORY/ALLERGIC CONDITIONS & DERMATITIS/SKIN DISORDERS MAY OCCUR IN SOME WORKERS & MAY AGGRAVATE LUNG, KIDNEY/LIVER AILMENTS. DERMATOLOGICAL DISORDERS. ======================= First Aid Measures ======================= First Aid:EMPLOY FIRST AID TECHNIQUES RECOMMENDED BY THE AMERICAN RED CROSS. INHALATION: REMOVE TO FRESH AIR. GIVE OXYGEN IF NECESSARY. SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/WATER FOR 15 MINS. INGESTION: GIV E LARGE QUANTITIES OF WATER/MILK TO DILUTE. DON'T INDUCE VOMITING. GASTRIC LAVAGE. NEVER GIVE ANYTHING BY MOUTH IF UNCONSCIOUS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:<0F Lower Limits:1 Upper Limits:9.5 Extinguishing Media:DRY CHEMICAL, WATER FOG, CO2 Fire Fighting Procedures:USE PROTECTIVE EQUIPMENT W/SCBA. WATERFOG MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILDUP/AUTOIGNITION/EXPLOSION WHEN EXPOSED TO EXTREME HEAT. Unusual Fire/Explosion Hazard:AEROSOL PRODUCTS UNDER PRESSURE. EXPOSURE TO TEMPS >120F MAY CAUSE BURSTING. SPATTER GUARD CW1093 MAY DEVELOP FLAMMABLE ATMOSPHERE IN CONFINED AREAS. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE SOURCES OF HEAT/IGNITION. WIPE UP PRODUCTS W/RAG/USE ABSORBENT SWEEPING COMPOUND & WASH AREA DOWN W/SOAP & WATER. DISPOSE OF RESIDUE IN SEALED CONTAINERS. KEEP AIRBORNE DUST AT A MINIMUM WHEN C LEANING UP. AVOID INHALATION OF DUST. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE, AVOIDING CONTACT W/EXTREME HEAT/COLD TO MAINTAIN PRODUCT QUALITY. KEEP OUT OF REACH OF CHILDREN. FOR INDUSTRIAL USE ONLY. Other Precautions:AVOID CONTACT W/EYES, SKIN/CLOTHING WHEN USING PRODUCTS. PREVENT ACCUMULATIONS OF DUST/FUMES. VAPORS MAY COLLECT IN LOW LYING AREAS ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRABLE VAPOR RESPIRATOR/AIR SUPPLIED RESPIRATOR WHEN USING PRODUCTS/FUME/DUST RESPIRATOR WHEN WELDING, BRAZING/SOLDERING IN CONFINED SPACE/WHERE LOCAL EXHAUST/VENTILATION DOESN' T KEEP EXPOSURE BELOW TLV. Ventilation:LOCAL EXHAUST: TO KEEP THE FUMES & GASES BELOW THE TLV'S IN THE WORKER'S BREATHING ZONE & THE GENERAL AREA. Other Protective Equipment:SAFETY EYEWASH STATION Work Hygienic Practices:USE GOOD HOUSEKEEPING PRACTICES. WASH HANDS AFTER HANDLING. DON'T SMOKE/EAT/DRINK IN WORK AREA. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:-44 T0 210F Vapor Pres:>100 Vapor Density:>1 Spec Gravity:0.5667 Evaporation Rate & Reference:(BUTYL ACETATE=1): >1 Solubility in Water:NONE Appearance and Odor:CLEAR SPRAY W/SOLVENT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG BASES & OXIDIZERS, OXYGEN, SODIUM HYDROXIDE Stability Condition to Avoid:EXTREME HEAT/COLD, HIGH TEMPS/TEMPS >120F, FLAMES Hazardous Decomposition Products:OXIDES OF CARBON ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER/LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER IAW/LOCAL, STATE & FEDERAL REGULATIONS. DON'TPUNCTURE/INCINERATE AEROSOL CONTAINERS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:TABULAR ALUMINA CAGE:ALUMI CAGE:01634 CAGE:ALUMI ============= Composition/Information on Ingredients ============= Ingred Name:ALPHA-ALUMINA (ALUMINUM OXIDE) (EPA LISTS ONLY FIBROUS FORMS) (SARA III) CAS:1344-28-1 RTECS #:BD1200000 Fraction by Wt: 99.5% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:LOW HEALTH RISK BY INHALATION. TREAT AS A NUISANCE DUST AS SPECIFIED BY THE AMERICAN CONFERENCE OF GOVERNMENT INDUSTRIAL HYGIENISTS. Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:NONE SPECIFIED BY MANUFACTURER. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:EXTINGUISH WITH AGENT SUITABLE FOR SURROUNDING FIRE Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:PER MFR,NOT AN EXPLOSION HAZARD ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP SPILLS WITH VACUUM, BROOMS, OR SHOVELS SO THAT DUSTING IS MINIMIZED. COLLECT SPILLS AND WASTE IN CONTAINERS, BAGS, OR COVERED DUMPSTER BOXES. IF REUSE OR RECYCLING IS NOT POSSIBLE, MATERIAL M AY BE DISPOSED OF AT A SANITARY LANDFILL. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED AREA. PROTECT FROM PHYSICAL DAMAGE.AVOID ANY PHYSICAL CONTACT. KEEP CONTAINERS TIGHTLY CLOSED Other Precautions:USE W/ADEQUATE VENTILATION. WHEN EXPOSURE LIMIT IS EXCEEDED, USE NIOSH APPROVED RESP. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED Ventilation:NO SPECIAL REQUIREMENTS W ADEQUATE VENT. Other Protective Equipment:SEE OTHER PRECAUTIONS Supplemental Safety and Health MSDS FROM ALCOA DATED:7/30/86; IMPURITIES IN ALUMINA ARE AS FOLLOWS:SILICA DIOXIDE,0.04-0.06%; FERRIC OXIDE,0.06%; SODIUM OXIDE,0.10-0.30%; CALCIUM OXIDE,0.03%. ================== Physical/Chemical Properties ================== HCC:N1 Melt/Freeze Pt:M.P/F.P Text:3727F,2053C Spec Gravity:3.9 Solubility in Water:INSOLUBLE Appearance and Odor:CRYSTALLINE POWDER, GRANULES, OR BALLS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS/BASES Stability Condition to Avoid:NONE Hazardous Decomposition Products:NO HAZARDOUS PRODUCTS FORMED WHEN EXPOSED TO HEAT OR FIRE ==================== Disposal Considerations ==================== Waste Disposal Methods:MATERIAL MAY BE DISPOSED OF IN A SANITARY LANDFILL. FOLLOW ALL APPLICABLE LOCAL, STATE, AND FEDERAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:202 YELLOW 17A MARKING PAINT Preparer's Name:MIKE A TRAQUINA CAGE:0UPL1 CAGE:0UPL1 ============= Composition/Information on Ingredients ============= Ingred Name:XYLENE, DIMETHYLBENZENE, XYLOL (IARC - GROUP 3) *96-4* CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 14% Other REC Limits:100 PPM OSHA PEL:100 PPM ACGIH TLV:100 PPM, SKIN EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:LIGHT ALIPHATIC NAPHTHA, VM & P NAPHTHA, LACOLENE *96-4* CAS:64742-89-8 Fraction by Wt: 20% OSHA PEL:300 PPM ACGIH TLV:300 PPM Ingred Name:STODDARD SOLVENT (PETROLEUM DISTILLATE), MINERAL SPIRITS *96-4* CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: <5% Other REC Limits:525 MG/CUM OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:PROPANE (DIMETHYLMETHANE)*96-4* CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 15% Other REC Limits:1800 MG/CUM OSHA PEL:1000 PPM ACGIH TLV:SIMPLE ASPHYXIANT Ingred Name:ISOBUTANE, 2-METHYLPROPANE CAS:75-28-5 RTECS #:TZ4300000 Fraction by Wt: <5% Other REC Limits:1000 PPM OSHA PEL:1800 MG/CUM ACGIH TLV:1000 PPM Ingred Name:BUTANE, N-BUTANE *96-4* CAS:106-97-8 RTECS #:EJ4200000 Fraction by Wt: 5% Other REC Limits:800 PPM OSHA PEL:800 PPM ACGIH TLV:1900 MG/CUM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN: IRRITATION, BURNING SENSATION, DERMATITIS. EYES: IRRITATION. INHALATION: IRRITATION OF RESPIRATORY TRACT/NERVOUS SYSTEM DEPRESSION, DERMATITIS. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, DIZZINESS, NAUSEA, HEADACHE ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE FROM AREA & RESTORE BREATHING. SKIN: WASH. EYES: FLUSH IMMEDIATELY W/WATER FOR 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:89.6F Lower Limits:0.7 Upper Limits:9.5 Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG Fire Fighting Procedures:WATER SPRAY MAY BE INNEFFECTIVE, BUT WATER MAY BE USED TO COOL FIRE/HEAT EXPOSED CONTAINERS TO PREVENT PRESSURE BUILDUP. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE DUE TO PRESSURE BUILDUP FROM EXTREME HEAT/FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AREA & SOAK UP W/INERT ABSROBENT USING NON-SPARKING TYPE TOOLS. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T STORE >120F. DON'T STORE/USE NEAR HEAT, SPARKS/OPEN FLAME. DON'T GET IN EYES. DON'T BREATHE VPORS. AVOID SKIN CONTACT. DON'T TAKE INTERNALLY. Other Precautions:SMOKING WHILE USING THIS PRODUCT IS STRICTLY PROHIBITED. DUST FROM SANDING THE DRY PAINT FILMS SHOULD BE TREATED AS NUISANCE DUST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:OUTDOORS: AN APPROVED PARTICULATE FILTER TO REMOVE ANY AIRBORNE OVERSPRAY IS RECOMMENDED. IN RESTRICTED AREAS W/POOR VENTILATION & CLOSE TO TLV A NIOSH APPROVED RESPIRATOR W/ORAGIC VAPOR CARTRIDGE IS RECOMMENDED Ventilation:ALL APPLICATION AREAS SHOULD BE ADEQUATELY VENTILATED IN ORDER TO KEEP INGREDIENTS BELOW EXPOSURE LIMITS Other Protective Equipment:EYEWASH FOUNTAIN W/SIDESHIELDS Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:10F Vapor Density:>1 Spec Gravity:0.8 VOC Grams/Liter:4.7 Evaporation Rate & Reference:FASTER THAN BU AC Solubility in Water:NEGLIGIBLE Appearance and Odor:OPAQUE LIQUID W/SOLVENT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH TEMPS Hazardous Decomposition Products:CO, CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. UN1950
1
gloves_mandatory
===================== Product Identification ===================== Product ID:BENZOIC ACID CAGE:DO806 CAGE:DO806 CAGE:86491 ============= Composition/Information on Ingredients ============= Ingred Name:BENZOIC ACID (SARA III) CAS:65-85-0 RTECS #:DG0875000 Fraction by Wt: 100% EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: ORAL(RAT) 2,565MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CHRONIC: EFFECTS OF CHRONIC AND SUB-ACUTE EXPOSURE ARE UNKNOWN. BENZOIC ACID OCCURS NATURALLY IN FOODS. THE FDA HAS AFFIRMED BENZOID ACID AS GENERALLY RECOGNIZED AS SAFE (GRAS) WHEN USED AT LEVELS NOT HIGHER THAN 0.1%. INGEST: NOT CONSIDERED A NORMAL ROUTE OF EXPOSURE. EYE: CONSIDERED SEVERE IRRIT (SEE EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: IN RABBITS, NO HUMAN DATA AVAILABLE. DIRECT CONTACT MAY CAUSE IRRIT. SKIN: CONSIDERED A MODERATE SKIN IRRITANT. INHALATION: HIGHLY TOXIC BY INHALATION OF VAPORS TO MUCOUS MEMBRANE. ALSO GAST RIC IRRITATION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST: NOT APPLICABLE IF CONSUMED IN SMALL CHANCE AMOUNTS. IF LARGER INGESTION IS INVOLVED, PURGE THE STOMACH. EYE: FLUSH EYE CONTACT IMMEDIATELY WITH PLENTY OF WATER FOR A MINIMUM OF 15 MINUTES. GET MEDICAL ATTENTION. SKIN: FLUSH SKIN WITH WATER. LAUNDER CLOTHING BEFORE REUSE. INHAL: REMOVE PATIENT TO FRESH AIR-SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:250F,121C Lower Limits:3% Upper Limits:35% Extinguishing Media:WATER, CO2, DRY CHEMICAL, SPRAY OR MIST. Fire Fighting Procedures:NONE NORMALLY. USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE-WEAK B OF M RELATIVE EXPLOSION HAZARD RATING. ================== Accidental Release Measures ================== Spill Release Procedures:FLAKE/POWDER FORMS ARE COLLECTED BY VACUUM/ BROOM & SHOVEL. LIQ FORM ARE ALLOWED TO COOL THEN COLLECTED BY BROOM & SHOVEL. MAJOR LIQ SPILLS MUST BE DIKED TO CONTAIN MATL. NIOSH/MSHA APPRVD SELF CONTAI NED BRTHG EQUIP SHOULD BE USED IN HNDLGLIQ SPILLS Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE REQD FOR POWDER/FLAKE, IN HNDLG SHIELD & ACID PROOF SUIT AS PROT FROM FUMES. Other Precautions:STORE IN TIGHTLY CLOSED CONTAINERS WITH ADEQUATE VAPOR BARRIERS. KEEP AWAY FROM STRONG OXIDIZING AGENT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AS FLAKE-NONE; AS POWDER-NIOSH/MSHA APPROVED NUISANCE DUST MASK. Ventilation:LOCAL EXHAUST TO CONTAIN DUSTING. WHEN HANDLING MOLTEN MATERIAL (122 C). Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health % VOLAT: SUBLIMES ABOVE 205 F. ================== Physical/Chemical Properties ================== HCC:N1 Vapor Pres:6.5 Vapor Density:4.21 Spec Gravity:-1.316 pH:2.8 Evaporation Rate & Reference:NOT APPLICABLE. Solubility in Water:SLIGHT. Appearance and Odor:WHITE FLAKES/POWDER,CHARACT ODOR OF BENZALDEHYDE/ BENZOIN.MOLTEN MATL ALSO AVAI Percent Volatiles by Volume:SUPDAT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES USUAL INCOMPATIBILITIES OF ORGANIC ACIDS/STRONG OXIDIZERS, AGENTS. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:FROM SEVERE HEAT OF FIRE: BENZINE, CO2 AND CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:COMPLY WITH APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS. CONSIDER LANDFILL OR INCINERATION.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:ACRYLIC ENAMEL NON-LEAD COLORS MID TONE (SU CAGE:54636 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:VENT:1910.94, 1910.107, 1910.108. RTECS #:9999999ZZ Ingred Name:OTHER PREC:PROC. TRANSFER ONLY TO APPRVD CNTNRS W/COMPLETE APPROP LABELING. DO NOT TAKE INTERNALLY. KEEP OUT OF(ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:REACH OF CHILDREN. INTENTIONAL MISUSE BY DELIB CONC & INHALING CONTENTS CAN BE HARMFUL/FATAL. AVOID BRTHG(ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:VAP OR SPRAY MIST. AVOID SKIN/EYE CNTCT. THIS COATING MAY CNTN MATLS CLASSIFIED AS NUISANCE PARTICULATES (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:SUCH AS TITANIUM DIOXIDE OR CALCIUM CARBONATE, WHICH MAY BE PRESENT AT HAZARDOUS LEVELS ONLY (ING 15)] RTECS #:9999999ZZ Ingred Name:ING 14:ONLY DURING SANDING OR ABRADING OF DRIED FILM. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP:OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS DMG. NOTE:TOLUENE (CAS #108-88-3) APPEARS ON THE NAVY (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16:LISTING OF OCCUPATIONAL CHEM REPROD HAZARDS. SEEK CONSULTATION FROM APPROPRIATE HEALTH PROFESSIONALS (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17:CONCERNING THE LATEST HAZARD LIST INFORMATION AND SAFE HANDLING AND USE RECOMMENDATIONS . ANIMAL (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18:STUDIES CLEARLY DEMONSTRATED DOSE RELATED ADVERSE EFTS ON CNS, HEMATOPOIETIC TISS, BLOOD, KIDNEYS & LIVER(ING 20) RTECS #:9999999ZZ Ingred Name:ING 19:ASSOCIATED WITH THE ADMINISTRATION OF ETHYLENE GLYCOL MONOBUTYL ETHER (EGBE) (EXTRACTED FROM DHHS (NIOSH)(ING 21) RTECS #:9999999ZZ Ingred Name:ING 20:PUBLICATION NO. 90-118) . RTECS #:9999999ZZ Ingred Name:MINERAL SPIRITS. VP:2. CAS:64742-47-8 Fraction by Wt: <5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TOLUENE (SARA III). VP:22. CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 10% OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BENZENE, ETHYL-;(ETHYL BENZENE) (SARA III). VP:7.1 CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: <5% OSHA PEL:100 PPM;125 PPM STEL ACGIH TLV:100 PPM;125 PPM STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENE. VP:5.9. CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 30-35% OSHA PEL:100 PPM;150 PPM STEL ACGIH TLV:100 PPM;150 PPM STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:AROMATIC NAPHTHA;(LIGHT AROMATIC NAPHTHA). VP:3.8. CAS:64742-95-6 Fraction by Wt: <5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ETHANOL, 2-BUTOXY-;(2-BUTOXYETHANOL). VP:0.6 CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: <5% OSHA PEL:S, 50 PPM ACGIH TLV:S, 25 PPM; 9293 Ingred Name:ETHANOL, 2-BUTOXY-, ACETATE; (2-BUTOXYETHYL ACETATE) CAS:112-07-2 RTECS #:KJ8925000 Fraction by Wt: <5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER; (1-METHOXY-2-PROPANOL ACETATE). VP:1.8 CAS:108-65-6 RTECS #:AI8295000 Fraction by Wt: <5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TITANIUM OXIDE;(TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 0-15% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:IRRITATION OF EYES, SKIN AND RESPIRATORY SYSTEM. MAY CAUSE NERVOUS SYSTEM DEPRESSION. EXTREME OVEREXPOSURE MAY RESULT IN UNCON & POSS DEATH. SIGNS/SYMPS:HDCH, DIZZ, NAUS & LOSS OF COORDINATION A RE INDICATIONS OF EXCESS EXPOS TO VAPORS OR MISTS. REDNESS & ITCHING OR BURNING SENSATION MAY INDICATE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:EYE/EXCESS SKIN EXPOS. CHRONIC:PRLNGD OVEREXP TO SOLV INGREDS MAY CAUSE ADVERSE EFTS TO LIVER, URINARY, BLOOD FORMING, CVS & REPROD SYS. RATS EXPOSED TO TITANIUM DIOXIDE DUST AT 250 MG/M3 DEV ELOPED LUNG CANCER, HOWEVER, SUCH EXOPSLEVELS ARE NOT ATTAINABLE IN WORKPLACE. REPORTS HAVE ASSOC RPTD/PRLNGD (ING 16) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM & QUIET. SKIN:WASH AFFECTED AREAS THOROUGHLY WITH SOAP & WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. EYE:FLUSH WITH LARGE AMO UNTS OF WATER FOR AT LEAST 15 MINUTES. INGEST:CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:40.0F,4.4C Lower Limits:0.5% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROT EQUIP . WATER SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZ ARE PREF. WATER MAY BE USED TO COOL (SUPP DATA) Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM HEAT, ELEC EQUIP, SPARKS, & OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. APPLIC TO HOT SURFS(SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:CONTENTS ARE FLAMMABLE. KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME. KEEP CONTAINER CLOSED WHEN NOT IN USE. USE WITH ADEQUATE VENTILATION. Other Precautions:DURING USE & UNTIL ALL VAPS ARE GONE:KEEP AREA VENT-DO NOT SMOKE-EXTING ALL FLAMES, PILOT LIGHTS, & HEATERS-TURN OFF STOVES, ELEC TOOLS & APPLIANCES, & ANY OTHER SOURCES OF IGNITION. CONSULT NFPA CODE . USE APPROVED BONDING/GROUNDING(ING 10) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ALL RESPS MUST BE NIOSH/MSHA APPROVED. IF PERS EXPOS CANNOT BE CNTRLD BELOW APPLIC LIMITS BY VENT, WEAR A PROPERLY FITTED ORG VAP/PARTICULATE RESP. Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS IS MAINTAINED BELOW APPLIC EXPOS LIMITS. REFER TO OSHA STANDARDS (ING 10) Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:WASH HANDS AFTER USING. Supplemental Safety and Health MFR PT#/TRADE NAME:WHITE, F79 W 102.FIRE FIGHT:CLSD CNTNRS TO PVNT PRESS BUILDUP/POSS AUTOIGNIT/EXPLO WHEN EXPOSED TO EXTREME HEAT. EXPLO HAZ:REQS SPECIAL PRECS. DURING EMERG CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS MAY NOTBE IMMED APPARENT. GET MD. MATLS TO AVOID:DANGEROUSLY INCR PRESS IN CLSD CNTNRS. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:222F,106C Vapor Pres:SEE ING Spec Gravity:0.95-1.05 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:61-64 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES METALLICS CONTAIN ALUMINUM. CONTAM W/WATER, ACIDS/ALKALIES CAN CAUSE EVOLUTION OF HYDROGEN, WHICH MAY RSLT IN (SUPDAT) Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:BY FIRE:CARBON DIOXIDE, CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM PROD MAY BE HAZ AS DEFINED UNDER RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNIT TO DETERMINE APPLIC EPA HAZ WASTE NUMBERS. INCIN IN APPRVD FACILITY. DO NOT INCIN CLSD CNTNR. DISPOSE OF I/A /W FEDERAL, STATE AND LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:40654 DEPO-PROVERA STERILE AQUEOUS SUSPENSION 10 ML CAGE:GO374 CAGE:93703 CAGE:GO374 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: <58% Ingred Name:MEDROXYPROGESTERONE ACETATE (ANIMAL CARCINOGEN BY IARC - GROUP 2B) *94-4* CAS:71-58-9 RTECS #:TU5010000 Fraction by Wt: 40% Ingred Name:NON HAZARDOUS INGREDIENTS Fraction by Wt: <3% ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT): >6.4 G/KG (SEE SUPP) Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:MEDROXYPROGESTERONE ACETATE-CERVICAL EROSION, EDEMA, ADVERSE CNS EFFECTS, THROMBOEMBOLIC DISORDERS, THROMBOENCEPHALITIS, PULMONARY EMBOLISM. MEDROXYPROGESTERONE ACETATE DOES HAVE POTENTIAL TO CAUSE TE RATOGENIC EFFECTS IN PREGNANT FEMALES W/GREATEST EFFECTS OCCURRING IN FIRST 4 MONTHS OF PREGNANCY. Explanation of Carcinogenicity:SEE INGREDIENTS Effects of Overexposure:BREAKTHROUGH BLEEDING/SPOTTING/CHANGES IN CERVICAL SECRETION/AMENORRHEA/WEIGHT GAIN-LOSS/CHOLESTATIC JAUNDICE/DISCOLORATION/MMENTAL DEPRESSION/ELEVATED BODY TEMP/NAUSEA/BREAST TENDERNESS/EXCESSIVE MIL K FLOW/REVERSIBLE DECREASE IN SPERM PRODUCTION/GYNECOMASTIA/NERVOUSNESS/INSOMNIA/FATIGUE/DIZZINESS/HEAD ACHES. Medical Cond Aggravated by Exposure:KNOWN SENSITIVITY TO MEDROXYPROGESTERONE ACETATE/THROMBOPHLEBITIS/THROMBOEMBOLIC DISORDERS/CERBRAL APOPLEXY/CARCINOMA OF BREAT/UNDIAGNOSED VAGINAL BLEEDING/PREGNANCY. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:WATER, CO2, DRY CHEMICAL. Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:PROVIDE VENTILATION & PERSONAL PROTECTIVE EQUIPMENT. KEEP PRODUCT OUT OF DRAINS & PREVENT ENTRY TO SURFACE WATER/GROUNDWATER/SOIL. SMALL: ABSORB W/PAPER TOWELS/OTHER APPROPRIATE MEDIA. LARGE: VACUUM/S COOP UP & PLACE IN A SUITABLE CONTAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE & PROTECT FROM LIGHT. Other Precautions:AVOID CONTACT W/SKIN, EYES & CLOTHING. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED Ventilation:LOCAL EXHAUST Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health ORAL LD50 INFORMATION IS FOR MEDROXYPROGESTERONE ACETATE. ================== Physical/Chemical Properties ================== Solubility in Water:COMPLETE Appearance and Odor:CLEAR LIQUID IN 10 ML VIALS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:LIGHT. Hazardous Decomposition Products:CO & CO2. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF BY INCINERATION IAW/INTERNATIONAL, FEDERAL, STATE & LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:MARE ISLAND EPOXY PART A-FORMULA 152, WHITE Preparer's Name:ERNEST CARTER CAGE:1L7D1 CAGE:1L7D1 ============= Composition/Information on Ingredients ============= Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Minumum % Wt:30. Maxumum % Wt:60. OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:1-BUTANOL CAS:71-36-3 RTECS #:EO1400000 Minumum % Wt:10. Maxumum % Wt:30. OSHA PEL:300 MG/M3;100 PPM ACGIH STEL:C152 MG/M3;C50 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:POLY(AMIDOAMINE) Minumum % Wt:10. Maxumum % Wt:30. Ingred Name:BENZYL ALCOHOL CAS:100-51-6 RTECS #:DN3150000 Minumum % Wt:5. Maxumum % Wt:10. Ingred Name:AMIDES, FROM ME EPOXYHYDROXYOCTADECANOATE, TETRAETHYLENEPENTAMINE AND VEGETABLE-OIL FATTY ACIDS CAS:68443-08-3 Minumum % Wt:1. Maxumum % Wt:5. ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: CAN CAUSE SEVERE RESPIRATORY IRRITATION, DIZZINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHE AND POSSIBLE UNCONSCIOUSNESS. SKIN CONTACT: CAN CAUSE MODERATE SKIN IRRITATION, DEFATTING, AND DERM ATITIS. NOT LIKELY TO CAUSE PREMANENT DAMAGE. EYE CONTACT: CAN CAUSE SEVERE IRRITATION.EYE CONTACT MAY RESULT IN CORNEAL INJURY. SYMPTOMS MAY INCLUDE DISCOMFORT OR PAIN, EXCESS BLINKING AND TEAR PRODU CTION, WITH MARKED REDNESS AND SWELLING OF THE CONJUNCTIVA.SKIN ABSORPTION: HARMFUL IF ABSORBED THROUGH THE SKIN.MAY CAUSE SEVERE IRRITATION AND SYSTEMIC DAMAG.INGESTION: CORROSIVE TO TISSUE.TARGET OR GAN ACUTE TOXICITY: NERVOUS SYSTEM. Explanation of Carcinogenicity:NOT A CARCINOGEN ACCORDING TO NTP, IARC, OR OSHA. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR.IF BREATHING IS DIFFICULT, HAVE A TRAINED INDIVIDUAL ADMINISTER OXYGEN ARTIFICIAL RESPIRATION AND HAVE A TRAINED INDIVIDUAL ADMINISTER OXYGEN. GET MEDICAL ATTENTION IMM EDIATELY.EYES: FLUSH AFFECTED EYE FOR AT LEAST TWENTY MINUTES.SEEK MEDICAL ADVICE AFTER FLUSHING.SKIN CONTACT: WASH WITH SOAP AND WATER.REMOVE CONTAMINATED CLOTHING AND LAUNDER. GET MEDICAL ATTENTION. INGESTION: CORROSIVE. DO NOT INDUCE VOMITING! DRINK ONE GLASS OF WATER FOLLOWED BY MILK IF AVAILABLE. SEEK MEDICAL ATTENTION IMMEDIATELY AND GIVE THE MEDICAL CARE PROVIDER THIS MSDS. ===================== Fire Fighting Measures ===================== Flash Point:=37.2C, 99.F Autoignition Temp:=343.C, 649.4F Extinguishing Media:USE ALCOHOL RESISTANT FOAM, CARBON DIOXIDE, OR DRY CHEMICAL EXTINGUISHING AGENTS. WATER MAY BE INEFFECTIVE BUT CAN BE USED TO CONTROL FIRE IF SWEPT ACROSS BASE OF FLAMES. Fire Fighting Procedures:DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTION INCLUDING SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT. Unusual Fire/Explosion Hazard:VAPORS MAY BE IGNITED BY SPARKS, FLAMES OR OTHER SOURCES OF IGNITION IF MATERIAL IS ABOVE THE FLASH POINT GIVING RISE TO A FIRE. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL TO A SOURCE OF IGNITION. ================== Accidental Release Measures ================== Spill Release Procedures:EXPOSURE TO THE SPILLED MATERIAL MAY BE SEVERELY IRRITATING OR HIGHLY TOXIC. FOLLOW PERSONAL PROTECTIVE EQUIPMENT RECOMMENDATIONS FOUND IN SECTION VIII OF THIS MSDS. PERSONAL PROTECTIVE EQUIPMENT NEED S MUST BE EVALUATED BASED ON INFORMATION PROVIDED ON THIS SHEET AND THE SPECIAL CIRCUMSTANCES CREATED BY THE SPILL INCLUDING; THE MATERIAL SPILLED, THE QUANTITY OF THE SPILL, THE AREA IN WHICH THE SPI ======================Handling and Storage ====================== Handling and Storage Precautions:HANDLING: USE ONLY IN A WELL VENTILATED AREA. STORAGE: STORE IN A COOL DRY VENTILATED LOCATION. USE SPARK PROOF TOOLS AND EXPLOSION PROOF EQUIPMENT. KEEP AWAY FROM SOURCES OF IGNITION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE A RESPIRATOR IF GENERAL ROOM VENTILATION IS NOT AVAILABLE. Ventilation:LOCAL EXHAUST VENTILATION. Other Protective Equipment:EYEWASH AND SAFETY SHOWER SHOULD BE NEARBY. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:1,408028 VOC Grams/Liter:3.7 Solubility in Water:LOW; 10-49% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES METALS; STRONG OXIDIZING AGENTS; ACIDS, CAUSTICS (BASES). Stability Condition to Avoid:SPARKS, OPEN FLAME, OTHER IGNITION SOURCES, AND ELEVATED TEMPERATURES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF BY INCINERATION FOLLOWING FEDERAL, STATE, LOCAL, OR PROVINCIAL REGULATIONS. ======================= Other Information =======================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:FINE SILVER ALLOY, 24919 Preparer's Name:SEE OTHER INFORMATION. CAGE:86337 CAGE:86337 ============= Composition/Information on Ingredients ============= Ingred Name:SILVER (FORMULA AG) CAS:7440-22-4 RTECS #:VW3500000 Minumum % Wt:99.8 Maxumum % Wt:99.99 Other REC Limits:N/K OSHA PEL:0.01 MG/M3 OSHA STEL:N/K ACGIH TLV:0.1 MG/M3 ACGIH STEL:N/K EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT AVAILABLE. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYES/SKIN: MAY CAUSE IRRITATION. INHALATION: MAY CAUSE IRRITATION IF EXPOSURE IS PROLONGED OR EXCESSIVE. INGESTION: NO ADVERSE EFFECTS EXPECTED. INGESTION OF LARGE AMOUNTS MAY BE HARMFUL. NOTE: THE POTENTIAL HEALTH EFFECTS DESCRIBED ABOVE ONLY APPLY IF DUST OR FUME IS FORMED. CHRONIC: THE ABSORPTION OF SILVER COMPOUNDS INTO THE CIRCULATION AND THE SUBSEQUENT DEPOSITION OF REDUCED SILVER IN VARIOUS TISSUES OF THE BODY MAY RESULT IN THE PRODUCTION OF A GENERALIZED GREYISH PIGMENTATION OF THE SKIN AND MUCOUS MEMBRANE (ARGYRIA). GENERALIZED ARGYRIA DEVELOPS AFTER 2 TO 25 YEARS OF EXPOSURE. (EFFECTS OF OVEREXPOSURE) Effects of Overexposure:HEALTH HAZARDS: THERE ARE NO SYSTEMIC EFFECTS OR SYMPTOMS AND NO PHYSICAL DISABILITY. ONCE DEPOSITED, THERE IS NO KNOWN MEANS BY WHICH THIS SILVER CAN BE ELIMINATED; THE PIGMENTATION IS PERMANENT. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. IF IRRITATION DEVELOPS, CALL A PHYSICIAN. SKIN: IMMEDIATELY WASH WITH SOAP AND PLENTY OF WATER. IF IRRITATION PERSISTS, CALL A PHYSICIAN. INHA LATION: REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, OXYGEN SHOULD BE ADMINISTERED BY QUALIFIED PERSONNEL. CALL A PHYSICIAN. INGESTION: PROCEDURES NORMALLY NOT NEEDED. IF LARGE QUANTITIES ARE INGES TED, SEEK MEDICAL ADVICE. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE CARBON DIOXIDE, CHEMICAL FOAM OR DRY CHEMICAL. USE ANY MEANS FOR EXTINGUISHING SURROUNDING FIRE. DO NOT USE WATER ON METAL FIRES. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NOT A FIRE OR EXPLOSION HAZARD IN SOLID FORM. FINELY DIVIDED DUST MAY IGNITE AND BURN RAPIDLY WHEN MIXED WITH AIR IN THE PROPER PROPORTIONS. TOXIC METAL FUMES MAY BE RELEASED IN A FIRE SITUATION. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN SPILLAGE & SCOOP UP/VACUUM. AVOID DUSTING. NOTIFICATION OF NATL RESPONSE CTR (800-424-8802) MAY BE REQUIRED. REFER TO EPA, DPT & APPLIC STATE & LOC REGS FOR CURRENT RESPONSE INFO. IT IS REC TH AT EACH USER ESTABLISH SPILL PREVENTION, CTL & COUNTERMEASURE PLAN (SPCC). SUCH PLAN SHOULD INCL PROC APPLIC TO PROPER STOR, CTL & CLEAN-UP OF SPILLS, INCL REUSE/DISP AS APPROP (SEE DISP). (SUP DAT) ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. KEEP AWAY FROM HEAT, SPARKS AND FLAME. STORE IN A COOL, DRY LOCATION AWAY FROM INCOMPATIBLE MATERIALS. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID BREATHING ANY DUST, MIST OR FUMES RESULTING FROM THE USE OF THIS PRODUCT. Other Precautions:USE ONLY WITH ADEQUATE VENTILATION. DO NOT EAT, DRINK, OR SMOKE IN WORK AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF DUST OR FUME IS GENERATED, A NIOSH APPROVED RESPIRATOR MAY BE NECESSARY. FOLLOW ALL REQUIREMENTS FOR RESPIRATORY PROGRAMS AND SELECTION SET FORTH IN THE OSHA REGULATIONS (29 CFR 1910.134) AND IN AN SI Z88.2-92 (PRACTICES FOR RESPIRATORY PROTECTION). Ventilation:GENERAL; LOCAL EXHAUST VENTILATION AS NECESSARY TO CONTROL ANY AIR CONTAMINANTS TO WITHIN THEIR PELS OR TLVS DURING THE USE OF THIS PRODUCT. Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . BODY PROTECTION AS NECESSARY TO PREVENT SKIN CONTACT. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. PERSONNEL SAMPLING PROCEDURE: FOR SILVER: REFER TO NIOSH MANUAL OF ANALYTICAL METHODS (NMAM), 4TH EDITION, METHOD 7300. Supplemental Safety and Health SPILL PROC: NOTE: IN THE EVENT OF AN ACCIDENTAL RELEASE OF THIS MATERIAL, THE ABOVE PROCEDURES SHOULD BE FOLLOWED. ADDITIONALLY, PROPER EXPOSURE CONTROLS AND PERSONAL PROTECTION EQUIPMENT SHOULD BE US ED (SEE CONTROL MEASURES SECTION), AND DISPOSAL OF THE MATERIAL SHOULD BE IN ACCORDANCE WITH WASTE DISPOSAL SECTION. ================== Physical/Chemical Properties ================== Boiling Pt:=2000.C, 3632.F Melt/Freeze Pt:=961.0C, ######F Spec Gravity:10.53 (H*2O=1) Solubility in Water:INSOLUBLE Appearance and Odor:METALLIC WIRE, RED OR STRIP; ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS AND BASES, ACETYLENE, AMMONIA, AND HYDROGEN PEROXIDE. Stability Condition to Avoid:NONE EXPECTED. Hazardous Decomposition Products:TOXIC METAL OXIDES ARE EMITTED WHEN HEATED ABOVE THE MELTING POINT. THE AMOUNT OF FUME EVOLVED INCREASES AS THE TEMPERATURE RISES. =================== Toxicological Information=================== Toxicological Information:LD50/LC50 NOT AVAILABLE. SEE HEALTH HAZARDS, CONTROL MEASURES, AND ECOLOGICAL INFORMATION FOR ADDITIONAL INFORMATION. EXPOSURE LIMITS: INGREDIENT: SILVER CAS NO.: 7440-22-4 PEL-OSHA: 0.01 MG/M3; TLV- ACGIH: 0.1 MG/M3. NOTE: BOTH OSHA AND THE ACGIH LIST WELDING FUMES AS HAVING AN EXPOSURE LIMIT OF 5 MG/M3 (TOTAL PARTICULATE NO OTHERWISE CLASSIFIED). HOWEVER, THE ACGIH STATES THAT WELDING FUMES MUS T BE TESTED FREQUENTLY FOR INDIVIDUAL COMPONENTS WHICH ARE LIKELY TO BE PRESENT TO DETERMINE WHETHER SPECIFIC EXPOSURE LIMITS ARE EXCEEDED. NOTE: THE PERMISSIBLE EXPOSURE LIMITS (PELS), THRESHOLD (E COLOGICAL INFO) ===================== Ecological Information ===================== Ecological:ECOTOXICITY: NO DATA AVAILABLE. ENVIRONMENTAL FATE: NO DATA AVAILABLE. TOXICOLOGICAL INFO: LIMIT VALUES (TLVS), POTENTIAL HLTH EFTS STATEMENTS AND SARA HAZ CATEGORIES MAY NOT BE APPLIC AS THE HAZ INGR ED LISTED ARE IN THE SOLID FORM. IF DUST, POWDER/FUME IS GENERATED THEN THESE STATEMENTS WILL BE APPLIC. UNLESS OTHERWISE NOTED, ALL VALUES ARE REPORTED AS 8-HR TIME-WEIGHTED AVERAGES (TWAS) & TOTAL DUST (PARTICULATES ONLY). ALL ACGIH TLVS REFER TO THE 1995-96 STDS. ALL OSHA PELS REFER TO 29 CFR PART 1910 AIR CONTAMINANTS: FINAL RULE, JAN 19, 1989*. (*NOTE: AS A RESULT OF THE JULY 7, 1992 DECISIO N BY (STATE REG INFO) ==================== Disposal Considerations ==================== Waste Disposal Methods:US EPA WASTE #: D011. PROD CONTAINS SILVER/SILVER CMPDS & DISP MAY BE REGULATED UNDER EPA HAZ WASTE REGS, WASTE # D011. BEFORE DISP, PROD/MIXTS CONTAINING PROD SHOULD BE TESTED FOR TOXICITY CHARACTS ( TC) UNDER CURRENT EPA HAZ WASTE REGS TCLP TESTING PROC, 40 CFR PART 261 ET SEQ. DISP/RECYCLING/RECLA MATION REQS WILL VARY BY LOCATION (OTHER INFO) =================== MSDS Transport Information =================== Transport Information:INTERNATIONAL: UN NUMBER: NOT REGULATED. UNITED STATES: EPA WASTE NUMBERL D011; DOT CLASSIFICATION: NOT REGULATED. CANADA: PIN NUMBER: NOT REGULATED; TDG CLASS: NOT REGULATED. EC: DGL: NOT DETERMINED. ===================== Regulatory Information ===================== SARA Title III Information:SARA 311 AND 312 HAZARD CATEGORIES: IMMEDIATE (ACUTE) HEALTH HAZARD: YES; DELAYED (CHRONIC) HEALTH HAZARD: YES; FIRE HAZARD: NO; REACTIVITY HAZARD: NO; SUDDEN RELEASE OF PRESSURE: NO. SARA SECTION 313 NOTIFICATION: THIS PRODUCT CONTAINS A TOXIC CHEMICAL (OR CHEMICALS) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 4 0 CFR PART 372: SILVER, CAS # 7440-22-4; 99.8-99.99% WEIGHT. Federal Regulatory Information:US FEDERAL REGULATIONS: TSCA: IN TSCA; OZONE DEPLETING SUBSTANCES (ODS): THIS PRODUCT NEITHER CONTAINS NOR IS MANUFACTURED WITH AN OZONE DEPLETING SUBSTANCE SUBJECT TO THE LABELLING REQUIREMENTS OF TH E CLEAN AIR ACT AMENDMENTS 1990 AND 40 CFR PART 82; VOLATILE ORGANIC COMPOUNDS (VOC): NONE. CANADIAN REGULATIONS: DSL/NDSL: DSL; WHMIS CLASSIFICATION: CLASS D DIVISION 2 SUBDIVISION B. EUROPEAN REGULA TIONS: EINECS: YES. OTHER REGULATIONS: MITI: YES; AICS: YES. State Regulatory Information:VOLATILE ORGANIC COMPOUND (CARB): NOT DETERMINED. ECOLOGICAL INFO: THE U.S. CIRCUIT COURT OF APPEALS (AFL-CIO B. OSHA) TO VACATE THE 1989 PELS, OSHA WILL NO LONGER ENFORCE THESE NEW LIMITS AND WILL R ETURN TO THE PRE-1989 PELS.) ======================= Other Information =======================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:M02-FINE CUT CLEANER CAGE:GO009 CAGE:GO009 CAGE:14088 ============= Composition/Information on Ingredients ============= Ingred Name:CONDITIONERS Fraction by Wt: 2-5% Ingred Name:XYLENE, DIMETHYLBENZENE, XYLOL (IARC - GROUP 3) *96-1* CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 2-7% Other REC Limits:100 PPM OSHA PEL:100 PPM ACGIH TLV:100 PPM, SKIN EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:DISTILLATES (PETROLEUM), ACID-TREATED LIGHT *96-1* CAS:64742-14-9 Fraction by Wt: 8-15% Ingred Name:SILICA CRYSTALLINE, TRIPOLI (SUSPECTED HUMAN & ANIMAL CARCINOGEN BY IARC - GROUP 2A) *96-1* CAS:1317-95-9 RTECS #:VV7336000 Fraction by Wt: 1-5% Other REC Limits:30 MG/CUM TOTAL DUST ACGIH TLV:0.1 MG/CUM Ingred Name:AMORPHOUS SILICA, AMORPHOUS-DIATOMACEOUS EARTH CAS:61790-53-2 RTECS #:HL8600000 Fraction by Wt: 1-3% Other REC Limits:20 MCCPF (MSHA) ACGIH TLV:10 MG/CUM DUST Ingred Name:GROG; CALCIUM-BARIUM PHOSPHOSILICATE, ALUMINUM SILICATE FLUX *96-1* CAS:66402-68-4 Fraction by Wt: 1-3% Ingred Name:ALUMINUM SILICATE, KAOLINITE *96-1* CAS:1318-74-7 Fraction by Wt: 0.5-3% Ingred Name:HYDROTREATED MIDDLE PETROLEUM DISTILLATE, PETROLEUM SOLVENT CAS:64742-46-7 RTECS #:JN9379645 Fraction by Wt: 1-5% Ingred Name:GLYCERINE, 1,2,3,-TRIHYDROXYPROPANE, GLYCEROL, ANHYDROUS GLYCERINE, GLYCERIN *96-1* CAS:56-81-5 RTECS #:MA8050000 Fraction by Wt: 1-5% ACGIH TLV:10 MG/CUM (VAPOR) Ingred Name:STODDARD SOLVENT (PETROLEUM DISTILLATE), MINERAL SPIRITS CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: 1-3% Other REC Limits:525 MG/CUM OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:LIGHT ALIPHATIC NAPHTHA, VM & P NAPHTHA, LACOLENE CAS:64742-89-8 Fraction by Wt: 1-3% OSHA PEL:300 PPM ACGIH TLV:300 PPM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:EYES/SKIN: IRRITATION. INHALATION: PROLONGED/INTENTIONAL EXPOSURE TO HIGH CONCENTRATIONS MAY CAUSE RESPIRATORY TRACT IRRITATION. INGESTION: MAY BE HARMFUL. WILL CAUSE PULMONARY DISEASE & INTESTINAL DI STRESS. Explanation of Carcinogenicity:SEE INGREDIENTS Effects of Overexposure:EYES/SKIN: IRRITATION. INHALATION: PROLONGED/INTENTIONAL EXPOSURE TO HIGH CONCENTRATIONS MAY CAUSE RESPIRATORY TRACT IRRITATION. INGESTION: MAY BE HARMFUL. WILL CAUSE PULMONARY DISEASE & CAN CAUSE INT ESTINAL DISTRESS. Medical Cond Aggravated by Exposure:POSSIBLE LUNG TISSUE, LIVER, KIDNEY & EYE DAMAGE & SKIN DERMATITIS. ======================= First Aid Measures ======================= First Aid:EYES: WASH W/COPIOUS AMOUNTS OF WATER. SKIN: THOROUGHLY WASH W/SOAP & WATER. INGESTION: GIVE SEVERAL GLASSES OF WATER, DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:>200F Extinguishing Media:DRY CHEMICAL, FOAM, CO2. Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN & ABSORB. MAY BE CONTAINED IN METAL, PLASTIC/GLASS. PRODUCT CONTAINS MIXED XYLENES. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM EXTREME HEAT. Other Precautions:AVOID BREATHING VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED RESPIRATOR RECOMMENDED. Ventilation:LOCAL EXHAUST/MECHANICAL VENTILATION: ADEQUATE. USE IN A WELL VENTILATED AREA. Other Protective Equipment:NONE Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>380F Vapor Pres:<10 Vapor Density:>1 Spec Gravity:1.05 pH:6 Evaporation Rate & Reference:(BU AC =1): <1 Solubility in Water:APPRECIABLE Appearance and Odor:CREAM TO LIGHT GREEN W/SWEET ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:EXTREME HEAT Hazardous Decomposition Products:CO2, CO & OTHER TOXIC GASES. ==================== Disposal Considerations ==================== Waste Disposal Methods:SANITARY LANDFILLS FOR ABSORBENT MATERIALS. DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:VV-L-800C Preparer's Name:N.R.NETZEL CAGE:VELSI CAGE:0Z6C4 CAGE:VELSI ============= Composition/Information on Ingredients ============= Ingred Name:PETROLEUM SULFONIC ACID SALT CAS:68608-26-4 Fraction by Wt: 5% Other REC Limits:NONE RECOMMENDED Ingred Name:DIETHYLENE GLYCOL MONO-N-HEXYL-2-ETHER CAS:112-59-4 RTECS #:KL2625000 Fraction by Wt: 2% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:TLV FOR OIL MIST IS 5MG/M3 Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES:MAY CAUSE IRRITATION.SKIN:LOW DERMAL TOXICITY.MAY CAUSE IRRITATION.INGEST:LOW ORAL TOXICITY.MAY CAUSE GI TRACT IRRITATION.INHAL:MAY CAUSE RESPIRATORY IRRITATION. Explanation of Carcinogenicity:NONE OF THE INGREDIENTS IN THIS PRODUCT IS LISTED BY NTP, IARC OR OSHA AS A CARCINOGEN. Effects of Overexposure:INGEST:VOMITING. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH SOAP AND WATER.EYES:FLUSH WITH WATER FOR 15 MINUTES.CALL PHYSICIAN IF IRRITATION DEVELOPS.INHAL:REMOVE TO FRESH AIR.GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED.INGEST:DO NOT INDUCE VOMITING.GET PROMPT QUALIFIED MEDICAL ATTENTION.NOTE TO PHYSICIAN:TREAT SYMPTOMATICALLY. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:275F,135C Extinguishing Media:WATER FOG,DRY CHEMICAL,CARBON DIOXIDE,FOAM.AVOID SPREADING BURNING LIQUID WITH WATER STREAM. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS. ================== Accidental Release Measures ================== Spill Release Procedures:SOAK UP WITH NON-COMBUSTIBLE INERT ADSORBANT(EG.CLAY);PLACE COLLECTED MATERIAL IN AN APPROPRIATE CONTAINER FOR DISPOSAL;CLEAN SPILL AREA TO REMOVE SLIPPERINESS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE WITH ADEQUATE VENTILATION. KEEP AWAY FROM HEAT, OPEN FLAMES AND STRONG OXIDANTS. KEEP CONTAINERS TIGHTLY CLOSED. Other Precautions:AVOID EYE AND SKIN CONTACT. DO NOT BREATHE VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. NIOSH/MSHA-APPROVED RESPIRATOR OR SCBA AS APPROPIATE FOR EXPOSURE OF CONCERN. Ventilation:USE GENERAL DILUTION VENTILATION. Other Protective Equipment:PROTECTIVE CLOTHING,AS NEEDED.PROVIDE A LOCAL EYE WASH STATION AND SAFETY SHOWER. Work Hygienic Practices:WASH HANDS.SEPERATE WORK CLOTHES FROM STREET CLOTHES.LAUNDER WORK CLOTHES BEFORE REUSE.KEEP FOOD OUT OF THE WORK AREA. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:B.P. Text:430F,221C Vapor Pres:<1 Vapor Density:>1 Spec Gravity:<1 Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR LIQUID,MILD ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES OF IGNITION Hazardous Decomposition Products:UNIDENTIFIED TOXIC FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTACT YOUR LOCAL ENVIRONMENTAL OFFICER. DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL,STATE AND LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:DINITROL AV30 Preparer's Name:LENA ALMESTRAND CAGE:0L040 CAGE:0L040 CAGE:0WG65 ============= Composition/Information on Ingredients ============= Ingred Name:ALIPHATIC HYDROCARBON SOLVENT WITH <3% AROMATICS. CAS:8030-30-6 RTECS #:DE3030000 Fraction by Wt: 40-50% Other REC Limits:50 PPM Ingred Name:BUTYLGLYCOL CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: 1.1-1.6% Other REC Limits:20 PPM OSHA PEL:S, 50 PPM ACGIH TLV:S, 25 PPM; 9293 Ingred Name:SEVERELY SOLVENT-REFINED LIGHT PARAFFINIC DISTILLATE CAS:64741-89-5 RTECS #:PY8041500 Fraction by Wt: 1-5% Other REC Limits:20 PPM Ingred Name:ALKYD RESIN CAS:68390-25-0 Fraction by Wt: 5-10% Other REC Limits:NONE SPECIFIED Ingred Name:HYDROCARBON RESIN CAS:68444-36-0 Fraction by Wt: 15-20% Other REC Limits:NONE SPECIFIED Ingred Name:POLYOLEFINE CAS:9002-88-4 RTECS #:TQ3325000 Fraction by Wt: 3-8% Other REC Limits:NONE SPECIFIED Ingred Name:LANOLINE CAS:8006-54-0 RTECS #:OE3201000 Fraction by Wt: 1-5% Other REC Limits:NONE SPECIFIED Ingred Name:WAX Fraction by Wt: 1-5% Other REC Limits:NONE SPECIFIED Ingred Name:INHIBITORS CAS:57855-77-3 Fraction by Wt: 8-14% Other REC Limits:NONE SPECIFIED Ingred Name:SURFACTANT CAS:25307-17-9 Fraction by Wt: 0-2% Other REC Limits:NONE SPECIFIED Ingred Name:BROWN PIGMENT AND PERFUME Fraction by Wt: 0-0.2% Other REC Limits:NONE SPECIFIED Ingred Name:DRYING AGENT Fraction by Wt: 0-1% Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: SMARTING, PAIN. SKIN: DEGREASES THE SKIN, WHICH MAY CAUSE REDDENING AND ECZEMA. INHALATION: HEADACHE, DIZZINESS, TIRESNESS, AND NAUSEA. INGESTION: NAUSEA, VOMITING, DIARRHEA, RISK FOR PNEUMONIA. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES: SMARTING, PAIN. SKIN: DEFATTING, REDDENING, ECZEMA. INHALATION: HEADACHE, DIZZINESS, TIREDNESS, NAUSEA. INGESTION: NAUSEA, VOMITING, DIARRHEA, PNEUMONIA. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH LARGE AMOUNTS OF WATER. IF SYMPTOMS PERSISTS GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. WASH AREA WITH SOAP AND WATER. INHALATION: MOVE TO FRESH AIR. INGESTION: DO NOT INDUCE VOMITING. IF MORE THAN INSIGNIFICANT AMOUNT HAS BEEN INGESTED GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:120F,49C Lower Limits:0.5 Upper Limits:7.0 Extinguishing Media:DRY POWDER, CARBON DIOXIDE, FOAM Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:MAY FORM EXPLOSIVE MIXTURES WITH AIR WHEN HEATED. ================== Accidental Release Measures ================== Spill Release Procedures:USE SAND OR OTHER ABSORBING MATERIAL. AVOID GETTING INTO THE SEWAGE. FOLLOW LOCAL REGULATIONS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY AREA AWAY FROM OXIDIZING AGENTS. AVOID DIRECT FLAMES. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENTILATION IS POOR, A RESPIRATOR IS RECOMMENDED WITH A SOLVENT ABSORBING FILTER. Ventilation:GENERAL (MECHANICAL) IS RECOMMENDED. Other Protective Equipment:PROTECTIVE CLOTHING, DISPOSABLE COVERALLS, HOOD OR HAT. Work Hygienic Practices:WASH AFTER HANDLING AND BEFORE EATING, DRINKING, OR SMOKING.LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:338F,170C Vapor Pres:< 1 KPA Vapor Density:> 1 Spec Gravity:886 KG/M3 Solubility in Water:NEGLIGIBLE Appearance and Odor:LIGHT BROWN LIQUID, SLIGHT SMELL Percent Volatiles by Volume:48 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONGLY OXIDIZING SUBSTANCES. Stability Condition to Avoid:LOW AND TOO HIGH TEMPERATURES. Hazardous Decomposition Products:NONE BY NORMAL USE. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. IF PERMITTED BURN UNDER CONTROLLED CONDITIONS.
1
gloves_mandatory
======================================================= Product ID: A2485, SINGLE ELEMENT SOLUTION (SUPDAT) Cage: IO225 ======================================================= Contractor Summary ======================================================= Cage: IO225 Cage: 0L438 ======================================================= Ingredients ======================================================= Cas: 13548-38-4 RTECS #: GB6280000 % Wt: 0.1-1.0 OSHA PEL: 0.5 MG/M3 (MFR) ACGIH TLV: 0.5 MG/M3 (MFR) ------------------------------ Cas: 7697-37-2 RTECS #: QU5775000 % Wt: 2 OSHA PEL: 2 PPM ACGIH TLV: 2 PPM/4 STEL EPA Rpt Qty: 1000 LBS DOT Rpt Qty: 1000 LBS ------------------------------ Cas: 7732-18-5 RTECS #: ZC0110000 % Wt: 98 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE:SKIN/EYE IRRITATION OR INFLAMMATION. Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. Medical Cond Aggravated By Exposure: NONE. First Aid: EYE CONT:FLUSH WITH WATER FOR AT LEAST 15 MINUTES. SKIN CONT:FLUSH WITH WATER FOR 15 MINUTES. WASH CONTAMINATED CLOTHING BEFORE RE-USE. INHAL:REMOVE TO FRESH AIR. INGEST:DO NOT INDUCE VOMITING. GIVE W ATER OR MILK. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: TAKE UP WITH INERT, ABSORBENT MATERIAL. CONTAINERIZE FOR DISPOSAL. FLUSH SPILL AREA WITH WATER. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: CORROSIVE WASTE IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. Handling And Storage Precautions: STORE IN COOL, DRY PLACE. KEEP CONTAINER SEALED. Other Precautions: NONE. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: WATER OR CO*2. Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: NONE. ======================================================= Control Measures ======================================================= Respiratory Protection: NIOSH APPROVED RESPIRATOR WHEN NEEDED. Ventilation: NONE REQUIRED. LOCAL EXHAUST, WHEN NEEDED. Other Protective Equipment: LAB COAT. ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N). Work Hygienic Practices: USUAL. Supplemental Safety and Health: MFR TRADE NAME/PART NO:STANDARD, CHROMIUM +3, NITRIC ACID MATRIX. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: 212F,100C Spec Gravity: 1 (H*2O=1) Evaporation Rate & Reference: H*2O=1 Solubility in Water: SOLUBLE Appearance and Odor: CLEAR, BLUE-GREY SOLUTION. NO ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: EXCESSIVE HEAT OR EXTREME COLD. Materials To Avoid: STRONG BASES OR STRONG REDUCING AGENTS. Hazardous Decomposition Products: NO*X. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: A2485, SINGLE ELEMENT SOLUTION (SUPDAT) Cage: IO225 Assigned IND: Y Company Name: PLASMA CHEM CORP Street: 5142 WEST HURLEY POND ROAD Zipcode: 07727 Label Required IND: Y Date Of Label Review: 01/06/1997 Status Code: C Label Date: 01/06/1997 Origination Code: G Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Moderate Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE:SKIN/EYE IRRITATION OR INFLAMMATION. CHRONIC:NONE LISTED BY MANUFACTURER. =======================================================
1
gloves_mandatory
======================================================= Product ID: PVC CLEAR REGULAR BODY CEMENT, 2200 Cage: UNIEL ======================================================= Contractor Summary ======================================================= Cage: UNIEL ======================================================= Ingredients ======================================================= Cas: 109-99-9 RTECS #: LU5950000 % Wt: 20-30 OSHA PEL: 200 PPM ACGIH TLV: 200 PPM; 250 STEL EPA Rpt Qty: 1000 LBS DOT Rpt Qty: 1000 LBS ------------------------------ Cas: 78-93-3 RTECS #: EL6475000 % Wt: 30-60 OSHA PEL: 200 PPM ACGIH TLV: 200 PPM; 300 STEL EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 67-64-1 RTECS #: AL3150000 % Wt: 0-1 OSHA PEL: 1000 PPM ACGIH TLV: 750 PPM; 1000 STEL EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 108-94-1 RTECS #: GW1050000 % Wt: 5-15 OSHA PEL: 50 PPM, S ACGIH TLV: 25 PPM, S EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 9002-86-2 RTECS #: KV0350000 % Wt: 10-20 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: INHALATION: MAY CAUSE IRRITATION OF MUCOUS MEMBRANE, NOSE & THROAT, HEADACHE, DIZZINESS, NAUSEA, NUMBNESS OF EXTREMITIES & NARCOSIS IN HIGH CONCENTRATIONS. HAS CNS DEPRESSION, LIVER DAMAGE IN ANIMALS & HIGH CONCENTRATIONS HAVE CAUSED RETARDATION OF FETAL DEVELOPMENT IN RATS. INGESTION: MAY BE (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT Signs And Symptions Of Overexposure: HLTH HAZ: ASPIRATED INTO LUNGS OR CAUSE SYSTEMIC EFFECTS AS WITH INHALATION. SKIN: CHRONIC CONTACT MAY LEAD TO IRRITATION & DERMATITIS. CHRONIC EXPOSURE TO VAPORS OF HIGH CONCENTRATION MAY CAUSE DERMA TITIS. MAY POSSIBLY BE ABSORBED THROUGHTHE SKIN. EYES: VAPORS OF DIRECT CONTACT MAY CAUSE IRRITATION. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: INHAL: MOVE TO FRESH AIR & CALL EMER MED CARE. IF BRTHG IS DFCLT, GIVE OXYGEN. IF NOT BRTHG, GIVE ARTF RESP. KEEP WARM & QUIET. SKIN: FLUSH W/WATER, THEN WASH THORO W/SOAP & WATER. REMOVE & ISOLATE CO NTAMD CLTHG & SHOES AT SITE. CALL POIS CTL CTR OR MD IF IRRIT PERSISTS. EYES: FLUSH W/RUNNING WATER FOR AT LEAST 15 MIN & CALL POIS CTL CTR OR MD IF ANY IRRIT PERSISTS. INGEST: DRINK PLENTY (SUPDAT) ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: VENTILATE AREA. STOP LEAK IF IT CAN BE DONE WITHOUT RISK. TAKE UP WITH SAND, EARTH OR OTHER NON-COMBUSTIBLE ABSORBENT MATERIAL. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSE OF ACCORDING TO LOCAL, STATE AND FEDERAL REGULATIONS ONLY. Handling And Storage Precautions: KEEP AWAY FROM HEAT, SPARKS AND FLAMES; STORE IN COOL, DRY PLACE. Other Precautions: CONTAINERS, EVEN THOSE THAT HAVE BEEN EMPTIED, WILL RETAIN RESIDUE & VAPORS. HANDLE EMPTY CONTAINERS AS IF THEY WERE FULL. CONTACT LOCAL & STATE AGENCIES FOR PROPER DISPOSAL OF THESE CONTAINERS. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: TCC Flash Point Text: >0F,>-18C Lower Limits: 1.8% Upper Limits: 11.8% Extinguishing Media: SMALL FIRES: USE DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR ALCOHOL RESISTANT FOAM. Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). LARGE FIRES: EVACUATE AREA. CALL FIRE DEPARTMENT IMMEDIATELY. Unusual Fire/Explosion Hazard: NONE SPECIFIED BY MANUFACTURER. ======================================================= Control Measures ======================================================= Respiratory Protection: NIOSH/MSHA APPROVED CANISTER RESPIRATOR IN ABSENCE OF ADEQUATE VENTILATION. Ventilation: GEN MECH:EXHST VENT CAPABLE OF MAINTAINING EMISSIONS AT POINT OF USE BELOW PEL. LOC EXHST:OPEN DOORS & WINDOWS. (SUPDAT) Other Protective Equipment: EYE WASH AND SAFETY SHOWER SHOULD BE AVAILABLE. Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health: VP: 145 @ 20 PSI. FIRST AID PROC: OF WATER. DO NOT INDUCE VOMIT & CALL POIS CTL CTR OR MD IMMED. AVOID ALCOHOLIC BEVERAGES. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON. VENT: IF USED IN ENCLSD AREA U SE EXHST FAN TO REMOVE FUMES. (NOTE: CHECK UL LISTING ON FAN BEFORE USING.) ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: 151F,66C Vapor Pres: SUPDAT Vapor Density: 2.5 Spec Gravity: 0.94 +/- 0.01 Evaporation Rate & Reference: 5.5-8.0 (BUAC) Solubility in Water: NEGLIGIBLE Appearance and Odor: LIQUID; ETHER-LIKE ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: HEAT, SPARKS, OPEN FLAMES. Materials To Avoid: ACIDS, OXIDIZING MATLS, ALKALIS, CHLORINATED INORGS (POTASSIUM, CALCIUM & SODIUM HYPOCHLORITE) COPPER OR COPPER ALLOYS. Hazardous Decomposition Products: CARBON MONOXIDE/CARBON DIOXIDE/HYDROGEN CHLORIDE/SMOKE. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: PVC CLEAR REGULAR BODY CEMENT, 2200 Cage: UNIEL Company Name: UNITED ELCHEM INDUSTRIES INC Street: 11535 REEDER RD Zipcode: 75229 Label Required IND: Y Date Of Label Review: 04/26/1995 Status Code: C Label Date: 04/26/1995 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Slight Fire Hazard: Severe Reactivity Hazard: None Hazard And Precautions: EXTREMELY FLAMMABLE. ACUTE: INHALATION: MAY CAUSE IRRITATION OF MUCOUS MEMBRANE, NOSE & THROAT, HEADACHE, DIZZINESS, NAUSEA, NUMBNESS OF EXTREMITIES & NARCOSIS IN HIGH CONCENTRATIONS. INGESTION: MAY B E ASPIRATED INTO LUNGS OR CAUSE SYSTEMIC EFFECTS. EYES: VAPORS OF DIRECT CONTACT MAY CAUSE IRRITATION. CHRONIC: SKIN CONTACT MAY LEAD TO IRRITATION AND DERMATITIS. CHRONIC EXPOSURE TO VAPORS OF HIGH C ONCENTRATION MAY CAUSE DERMATITIS. MAY BE ABSORBED THROUGH THE SKIN. =======================================================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:3112 BAN-QUIT Preparer's Name:RICK GLISSON CAGE:FO866 CAGE:66086 CAGE:FO866 ============= Composition/Information on Ingredients ============= Ingred Name:ISOPROPYL ALCOHOL; (ISOPROPANOL ALCOHOL) CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 40-60% OSHA PEL:400 PPM;500 PPM STEL ACGIH TLV:400 PPM;500 PPM STEL ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: CAN CAUSE SEV IRRIT, RED, TEAR & BLURRED VISION. SKIN: PRLNG/RPTD CONT CAN CAUSE MOD IRRIT, DEFAT, DERM. INHAL: EXCESS INHAL OF VAPS CAN CAUSE NASAL & RESP IRRIT, DIZZ, WEAK, FATG, NAUS, HDCH. I NGEST: CAN CAUSE GI IRRIT, NAUS, VOMIT & DIARRHEA. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/LG AMTS OF H*2O FOR @ LST 15 MIN, LIFTING LIDS OCCAS, GET MED ATTN. SKIN: THORO WASH EXPOSED AREA W/SOAP/H*2O. REMOVE CONTAMD CLTHG. LAUNDER CONTAMD CLTHG BEFORE RE-USE. INHAL: REMOVE TO FRESH AIR. IF BRTHG IS DFCLT, KEEP WARM, QUIET & GET MED ATTN. INGEST: IMMED DRINK 2 GLASSES OF WATER & INDUCE VOMIT BY EITHER GIVING IPECAC SYRUP/BY PLACING FINGER @ BACK OF THROAT. (SUPP DATA) ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:74.0F,23.3C Lower Limits:2.5% Upper Limits:12.1% Extinguishing Media:DRY CHEMICAL, FOAM, CO*2, WATER. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:FLAMMABLE. KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL SPILL: FLUSH AREA WITH PLENTY OF WATER. LARGE SPILL: SOAK UP WITH ABSORBENT MATERIAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:ALWAYS STORE UNUSED PORTION IN ORIGINAL CONTAINER W/CAP SECURE. NEVER STORE IN UNLABELED OR IMPROPERLY LABELED CONTAINER. FLAMMABLE. Other Precautions:KEEP AWAY FROM HEAT/SPARKS/OPEN FLAME. DO NOT STORE NEAR OXIDIZIERS. STORE IN A COOL, DRY PLACE. AS W/ALL CHEM, USE W/DUE CARE ACCORDING TO LABEL INSTRUCTIONS & PRECAUTIONS. KEEP OUT OF REACH OF CHILD REN. FOR COMMERCIAL/INDUST USE ONLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:SUFFICIENT TO KEEP AIRBORNE CONCENTRATIONS BELOW PEL AND LEL . Other Protective Equipment:NONE NORMALLY NEEDED. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health PH: NEUTRAL. FIRST AID PROC: NEVER GIVE ANYTHING TO AN UNCON PERSON. GET MEDICAL ATTENTION IMMEDIATELY. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:180F,82C Vapor Pres:33 Vapor Density:HVR/AIR Spec Gravity:0.9(H*2O=1) pH:SUPDAT Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:FORMS AN EMULSION Appearance and Odor:THIN, CLEAR, AMBER LIQUID WITH PLEASANT ODOR. Percent Volatiles by Volume:>90 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Hazardous Decomposition Products:CO*2 & CO. ==================== Disposal Considerations ==================== Waste Disposal Methods:SMALL SPILL: FLUSH DOWN DRAIN WITH PLENTY OF WATER. LARGE SPILL: DISPOSE ABSORBENT MATERIAL IN A LANDFILL IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:ROTANIUM SS 1500, 95387 Preparer's Name:SSL SAME CAGE:18399 CAGE:18399 ============= Composition/Information on Ingredients ============= Ingred Name:TOLUENE (SARA 313) (CERCLA) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 10-20% OSHA PEL:200 PPM ACGIH TLV:50 PPM, S EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:NICKEL (SARA 313) (CERCLA) CAS:7440-02-0 RTECS #:QR5950000 Fraction by Wt: 1-2% OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3 Ingred Name:XYLENE (SARA 313) (CERCLA) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 20-30% OSHA PEL:100 PPM ACGIH TLV:100 PPM/150STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHANOL, 2-BUTOXY-; (2-BUTOXYETHANOL) CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: 1-5% OSHA PEL:50 PPM, S ACGIH TLV:25 PPM, S Ingred Name:CHROMIUM (SARA 313) (CERCLA) CAS:7440-47-3 RTECS #:GB4200000 Fraction by Wt: 1-2% OSHA PEL:1 MG/M3 ACGIH TLV:0.5 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ETHANE, 1,1,1-TRICHLORO-; (1,1,1-TRICHLOROETHANE) (SARA 313) (CERCLA) CAS:71-55-6 RTECS #:KJ2975000 Fraction by Wt: 5-10% OSHA PEL:350 PPM ACGIH TLV:350 PPM/450STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ozone Depleting Chemical:1 Ingred Name:IRON CAS:7439-89-6 RTECS #:NO4565500 Fraction by Wt: 5-10% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ALKYD RESIN MIXTURE Fraction by Wt: 20-30% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:VOLATILE ORGANIC CONTENT 2.9 LBS/GAL, 336 G/L RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUP DAT: ETHYLENE GLYCOL MONOBUTYL ETHER (EGBE) (EXTRACTED FROM DHHS (NIOSH) PUBLICATION # 90-118) . (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: CHLOROCARBON MATLS HAVE PRODUCED SENSIT OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE A (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: SIMILAR EFT IN HUMANS. ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE CONTRAINDICATED EXCEPT FOR LIFE- (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: SUSTAINING USES IN HUMANS ACUTELY OR CHRONICALLY EXPOSED TO CHLOROCARBONS . RTECS #:9999999ZZ Ingred Name:OTHER PREC: DRAINS. ALWAYS READ & FOLLOW DIRECTIONS ON PROD LABEL. ADDN TECHNICAL DATA SHEETS &/MATL SFTY DATA (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14: SHEETS (MSDS) ARE AVAIL UPON REQUEST. FOR PROFESSIONAL & INDUSTRIAL USE ONLY. NO SMKNG IN AREA OF USE. (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15: DO NOT USE IN GEN VICINITY OF ARC WELDING, OPEN FLAMES/HOT SURF. HEAT &/UV RADIATION MAY CAUSE THE (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: FORMATION OF HCL &/PHOSGENE . RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: EYES: CAUSES IRRIT. INHAL: VAPS IN HIGH CONCS ARE ANESTHETIC & IRRIT UPPER RESP SYS. EXCESS INHAL MAY CAUSE DIZZ, GIDD, & NAUS. INGEST: HARMFUL/FATAL IF SWALLOWED. PRLNG & RPTD INHAL MAY BE HAR MFUL TO RESP SYS, LIVER, KIDNEYS, & CNS. SKIN: CONT CAUSES IRRIT. CHRONIC: LONG TERM EXPOS MAY RSLT IN (EFTS OF OVEREXP) Explanation of Carcinogenicity:NICKEL: IARC MONOGRAPHS ON EVALUATION OF CARCINOGENIC RISK OF CHEM TO MAN, VOL 49, PG 257, 1990: GROUP 2B. (SUP DAT) Effects of Overexposure:HLTH HAZ: BIRTH DEFECTS/OTHER REPRO HARM. NOTE: TOLUENE APPEARS ON NAVY LISTING OF OCCUPATIONAL CHEM REPRO HAZ. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS INFO . ANIMAL STUDIES CLEARLY DEMONSTRATED DOSE-RELATED ADVERSE EFTS ON CNS, HEMATOPOIETIC (SUP DAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN & CALL MD. SKIN: WASH THORO W/PLENTY OF WATER & SOAP. INHAL: IF AFFECTED, REMOVE TO FRESH AIR, ADMINISTER OXYGEN & CALL MD. INGEST: SEEK MD IMME D, SHOW MSDS/LABEL. DO NOT INDUCE VOMIT. ===================== Fire Fighting Measures ===================== Flash Point:40.0F,4.4C Lower Limits:1.0% Upper Limits:12.7% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:VAPS MAY CAUSE FLASH FIRE. EXPOS TO FIRE, HEAT/PRLNG SUNLIGHT MAY CAUSE BURSTING. IF USED IN CONFINED SPACES, HAZ VAPS MAY SPREAD/BUILD UP IN LOW (SUP DAT) ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA. REMOVE ALL SOURCES OF IGNIT. VENT AREA. WEAR APPROVED RESP PROT. CLEAN UP W/ABSORBENT MATL. CONTAIN & PICK-UP WASTE MATLS. PUT IN SEALED APPROVED CONTR. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP IN COOL PLACE. KEEP AWAY FROM HEAT, SPARKS, FLAMES/SOURCES OF IGNIT. AVOID PRLNG/RPTD BRTHG OF GAS, FUMES, VAP/SPRAY MIST. Other Precautions:AVOID CONT W/SKIN & EYES. DO NOT TAKE INTERNALLY. CONT W/FLAME/HOT SURF MAY PRODUCE TOXIC GASES. WASH THORO AFTER USING. IN CASE OF ACCIDENT/ILLNESS, SEEK MD IMMED, SHOW LABEL/MSDS. KEEP OUT OF REACH OF CHILDREN. DO NOT EMPTY INTO (ING 14) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR, DESIGNED HOOD, SUPPLIED AIR MASK, APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL AND MECHANICAL VENTILATION REQUIRED. Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH THORO AFTER HANDLING. Supplemental Safety and Health EXPLO HAZ: AREAS. CONT W/FLAME/HOT SURF MAY PRODUCE TOXIC GASES. THERMAL DECOMP PROD MAY INCLUDE HCL & PHOSGENE . CARCIN EXPLAN: NTP 7TH ANNUAL REPORT ON CARCINOGENS, 1994: ANTICIPATED TO BE CAR CINOGEN. HUMAN: LUNGS, NASAL CAVITIES. EFTS OF OVEREXP: TISS, BLOOD, KIDNEYS & LIVER, ASSOC W/ADMINISTRATION OF (ING 10) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:165F,74C Vapor Density:4.55 Spec Gravity:1.13 Solubility in Water:NIL Appearance and Odor:SILVER GRAY COATING WITH CHLORINATED SOLVENT ODOR Percent Volatiles by Volume:52.5 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS, ALKALIES. Stability Condition to Avoid:KEEP AWAY FROM HEAT, SPARKS, FLAMES, OR SOURCES OF IGNITION. Hazardous Decomposition Products:CO, CO*2, CHLORIDES, PYROLYSIS PRODS. HCL, PHOSGENE . ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF WASTES IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. DO NOT PUNCTURE, INCINERATE (OR BURN) CONTAINERS.
1
gloves_mandatory
======================================================= Product ID: TP-3200 Cage: 20772 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 20772 Box: 483 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE:EYES:DIRECT CONTACT WITH PRODUCT MAY CAUSE IRRITATION. SKIN:PROLONGED OR REPEATED CONTACT MAY CAUSE IRRITATION. INHALATION:INHALATION IS NOT A ROUTE OF EXPOSURE. CHRONIC:NO ANTICIPATED CHRONIC E FFECTS. Explanation Of Carcinogenicity: NOT RELEVANT Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. Medical Cond Aggravated By Exposure: NO KNOWN EFFECTS ON OTHER ILLNESSES. First Aid: INGEST:CALL MD IMMEDIATELY (FP N). INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) (FP N). EYES:FLUSH IMMEDIATELY W/WATER FOR AT LEAST 15 MINUTES. CONSULT MD IF IRRITATION PERSISTS. SKIN:WASH MATERIAL FROM SKIN W/SOAP & WATER. ======================================================= Handling and Disposal ======================================================= MATERIAL. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISP MUST BE I/A/W FED, STATE & LOCAL REGS (FP N). THIS PROD DOES NOT MEET THE DEFINITION OF HAZ WASTE UNDER THE U.S. EPA HAZ WASTE REGS 40 CFR 261. STATE/LOC HAZ WASTE REGS MAY APPLY IF THEY ARE DIFF FROM FED REG. INCIN IN AN APPROVED FACILITY. Handling And Storage Precautions: STORE IN A COOL, DRY LOCATION. Other Precautions: NONE SPECIFIED BY MANUFACTURER. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: TCC Flash Point Text: >200F,>93C Lower Limits: SEE ING 1 Extinguishing Media: USE WATER SPRAY, FOAM, DRY CHEMICAL OR CARBON DIOXIDE. Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: NONE KNOWN. ======================================================= Control Measures ======================================================= Respiratory Protection: NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N). NOT NORMALLY REQUIRED. Ventilation: STANDARD INDUSTRIAL VENTILATION. Other Protective Equipment: ANSI APPRVD EYE WASH FOUNTAIN & DELUGE SHOWER (FP N). PREVENT PRLNG/RPTD CONT BY USING APPROPRIATE PROTECTIVE CLOTHING. Work Hygienic Practices: LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health: NOTE:USERS OF "L" VERSION SHOULD CONSULT "LR" VERSION FOR ADDITIONAL INFORMATION (FP N). ======================================================= Physical/Chemical Properties ======================================================= Vapor Pres: SEE ING 1 Spec Gravity: 0.87 (FP N) Appearance and Odor: HEAVY LIQUID. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER. Materials To Avoid: NOT ESTABLISHED. Hazardous Decomposition Products: INCOMPLETE COMBUSTION CAN YIELD LOW MOLECULAR WEIGHT HYDROCARBONS, CARBON MONOXIDE & NITROGEN COMPOUNDS. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: TP-3200 Cage: 20772 Company Name: SPECTRONICS CORP Street: 956 BRUSH HOLLOW RD PO Box: 483 Zipcode: 11590 Label Required IND: Y Date Of Label Review: 10/30/1996 Status Code: C Label Date: 10/30/1996 Origination Code: G Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Slight Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: ACUTE:EYES:DIRECT CONTACT WITH PRODUCT MAY CAUSE IRRITATION. SKIN:PROLONGED OR REPEATED CONTACT MAY CAUSE IRRITATION. CHRONIC:NONE LISTED BY MANUFACTURER. =======================================================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:SODIUM ACETATE ANHYDROUS, S-210 CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM ACETATE CAS:126-96-5 RTECS #:AJ4375000 Fraction by Wt: 100% Ingred Name:FIRST AID PROC: CHEM REMAINS (AT LEAST 15-20 MIN). GET MD IMMED. INGEST: IF VICTIM IS CONSCIOUS, IMMED GIVE (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2: 2 TO 4 GLASSES OF WATER & INDUCE VOMIT BY TOUCHING FINGER TO BACK OF THROAT. GET MD IMMED. ANTIDOTE: (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: NO SPECIFIC ANTIDOTE. TREAT SYMPTOMATICALLY & SUPPORTIVELY. RESP PROT: EFFICIENCY FILTER W/FULL (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: FACEPIECE. TYPE 'C' SUPPLIED-AIR RESP W/FULL FACEPIECE OPER IN PRESS-DMD/OTHER POSITIVE PRESS MODE/ (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: W/FULL FACEPIECE, HELMET/HOOD OPER IN CONTINUOUS-FLOW MODE. SCBA W/FULL FACEPIECE OPER IN PRESS-DMD/ (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: OTHER POSITIVE PRESS MODE. FOR FIREFIGHTING & OTHER IDLH CNDTNS: SCBA W/FULL FACEPIECE OPER IN PRESS (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: DMD/OTHER POSITIVE PRESS MODE. SUPPLIED-AIR RESP W/FULL FACEPIECE & OPER IN PRESS-DMD/OTHER POSITIVE (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: PRESS MODE IN COMBINATION W/AUXILIARY SCBA OPER IN PRESS-DMD/OTHER POSITIVE PRESS MODE. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL:(ACUTE)INHAL OF DUSTS MAY CAUSE IRRIT W/COUGHING & SHORTNESS BREATH. (CHRONIC)NO DATA AVAIL. SKIN:(ACUTE) APPLICATN OF 500 MG ANHYDROUS SODIUM ACETATE TO RBT SKIN FOR 24 HR PRODUCED MILD IRRIT. (CHRONIC)NO DATA AVAIL. EYE: (ACUTE)APPLICATN OF 10 MG OF ANHYDROUS SODIUM ACETATE TO RBT EYES PRODUCED (EFTS OF OVEREXP Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: MILD IRRIT. (CHRONIC)NO DATA AVAIL. INGEST:(ACUTE)INGEST MAY CAUSE ABDOM PAIN & VOMIT. ANIMAL STUDIES W/ MONOHYDRATE INDICATE THAT EFTS ON FEMALE FERTILITY MAY OCCUR WHEN ADMIN DURING GESTAT ION. (CHRONIC)ANIMAL STUDIES W/MONOHYDRATE INDICATE THAT EFTS ON FEMALE FERTILITY MAY OCCUR WHEN ADMIN DURING GESTATION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE FROM EXPOS TO FRESH AIR IMMED. IF BRTHG STOPS, PERFORM ARTF RESP. KEEP PERSON WARM & AT REST. GET MD IMMED. SKIN: REMOVE CONTAM CLTHG & SHOES IMMED. WASH AFFECTED AREA W/SOAP/ MILD DETER GENT & LRG AMTS OF WATER UNTIL NO EVIDENCE OF CHEM REMAINS (APPROX 15-20 MIN). GET MD IMMED. EYE: WASH IMMED W/LRG AMTS OF WATER, OCCASNLY LIFTING UPPER & LOWER LIDS, UNTIL NO EVIDENCE OF (ING 2) ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL, CO2, HALON, WATER SPRAY/STANDARD FOAM. FOR LRG FIRES, USE WATER SPRAY, FOG/STANDARD FOAM. Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . MOVE CNTNR FROM FIRE AREA IF POSS. DO NOT SCATTER SPILLED MATL W/HIGH PRESS WATER STREAMS. DIKE (SUPP DATA) Unusual Fire/Explosion Hazard:SLIGHT FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP AND PLACE IN SUITABLE CLEAN, DRY CONTAINERS FOR LATER DISPOSAL. DO NOT FLUSH WITH WATER. KEEP UNNEC PEOPLE AWAY. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:OBSERVE ALL FED, ST & LOC REGS WHEN STORING SUBSTANCE. STORE AWAY FROM INCOMP SUBSTANCES. Other Precautions:CONTACT LENSES SHOULD NOT BE WORN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:THE FOLLOWING NIOSH/MSHA APPRVD RESP MUST BE BASED ON CONTAM LEVS FOUND IN WORK PLACE: CHEM CARTRIDGE RESP W/ORG VAP CARTRIDGE(S) W/HEPA FILTER & FULL FACEPIECE. HEPA RESP W/FULL FACEPIECE. POWERED AI R-PURIFYING RESP W/HIGH (ING 4) Ventilation:PROVIDE LOCAL EXHAUST VENTILATION AND/OR GENERAL DILUTION VENTILATION TO MEET PEL. Other Protective Equipment:PROTECTIVE (IMPERVIOUS) CLOTHING & EQUIPMENT. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health PH: 7.5-9.2 (5% SOLN). APPEAR & ODOR: CRYSTALS/CRYSTALLINE POWDER W/SLIGHTLY BITTER, SALINE TASTE; EFFLORESCES IN WARM DRY AIR. FIRE FIGHT PROC: FIRE CONTROL WATER FOR LATER DISP. USE AGENTS SUITABLE FOR TYPE OF SURROUNDING FIRE. AVOID BRTHG HAZ VAPS, KEEP UPWIND. ================== Physical/Chemical Properties ================== HCC:N1 Melt/Freeze Pt:M.P/F.P Text:615F,324C Spec Gravity:1.528 pH:SUPDAT Solubility in Water:119% @ 0C Appearance and Odor:ODORLESS, WHITE TO GRAYISH-WHITE, HYGROSCOPIC MASSES, MONOCLINIC (SUPP DATA) ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS (STRONG), DIKETENE, FLUORINE, POTASSIUM NITRATE. Stability Condition to Avoid:NONE REPORTED. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY RELEASE ACRID SMOKE AND IRRITATING FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS WHEN DISPOSING OF THIS SUBSTANCE.
1
gloves_mandatory
Product ID:101 3259 LIQUID DEVELOPER SYSTEM CLEANER CO CAGE:19139 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 65-70% % Other REC Limits:NONE RECOMMENDED Ingred Name:SODIUM BICHROMATE (SARA 313) (CERCLA) CAS:10588-01-9 RTECS #:HX7700000 Fraction by Wt: 18% % Other REC Limits:NONE RECOMMENDED OSHA PEL:C 0.1 MG (CRO3)/M3 ACGIH TLV:0.05 MG(CR)/M3;A1;95 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:SULFURIC ACID (SARA 302/313) (CERCLA) CAS:7664-93-9 RTECS #:WS5600000 Fraction by Wt: 15-20% % Other REC Limits:NONE RECOMMENDED OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3/3 STEL; 9495 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT GIVEN Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:HARMFUL IF INHALED. PRODUCT NOT EXPECTED TO GENERATE MISTS OR VAPORS WHEN INSTRUCTIONS FOR MIXING AND USE ARE FOLLOWED. CAUSES SEVERE EYE BURNS. CAUSES SEVERE SKIN BURNS. MAY CAUSE ALLERGIC SKIN REACT ION. HARMFUL IF SWALLOWED. MAY CAUSE BURNS OF THE GASTROINTESTINAL TRACT. CAN CAUSE KIDNEY DAMAGE. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:EYE BURNS, SKIN BURNS, ALLERGIC SKIN REACTION, GI TRACT BURNS, KIDNEY DAMAGE. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES: WASH OUT IMEEDIATELY WITH WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN: WASH WITH SOAP AND WATER . GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. INGESTION: DO NOT INDUCE VOMITING. GIVE A GLASS OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE ================== Accidental Release Measures ================== Spill Release Procedures:MAY REQUIRE NEUTRALIZATION. FLUSH TO SEWER IF ALLOWABLE WITH LARGE AMOUNTS OF WATER. OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLE AN SURFACE TO REMOVE RESIDUAL CONTAMINATION. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP FROM CONTACT WITH INCOMPATIBLE MATERIALS. KEEP CONTAINER TIGHTLY CLOSED. Other Precautions:KEEP AWAY FROM INCOMPATIBLE MATERIALS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENTILATION EQUIPMENT IS NOT SUFFICIENT TO KEEP AIRBORNE CONCENTRATIONS BELOW LIMITS, A NIOSH APPROVED RESPIRATOR SHOULD BE WORN. Ventilation:GOOD GENERAL VENTILATION, TYPICALLY 10 AIR CHANGES PER HOUR, SHOULD BE USED. RATES SHOULD MATCH CONDITIONS. Other Protective Equipment:CHEMICAL RESISTANT CLOTHING AS NECESSARY TO PREVENT SKIN CONTACT. AN EMERGENCY EYEWASH AND SHOWER SHOULD BE AVAILABLE. Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES. Supplemental Safety and Health REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE. ================= Stability and Reactivity Data ================= Hazardous Decomposition Products:SULFUR DIOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE OR LOCAL LAWS. MAY REQUIRE NEUTRALIZATION IF PH < 2.0 OR PH > 12.5. DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE ANDLOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:F-23 CAGE:05192 CAGE:05192 CAGE:54840 ============= Composition/Information on Ingredients ============= Ingred Name:CORK Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NONHAZARDOUS Explanation of Carcinogenicity:NONE Effects of Overexposure:NONHAZARDOUS Medical Cond Aggravated by Exposure:NONE ======================= First Aid Measures ======================= First Aid:INHALED: REMOVE PERSON TO FRESH AIR. EYES: FLUSH WITH WATER FOR 15 MINUTES. SEE DOCTOR. SKIN: WASH WITH SOAP AND WATER. INGESTED: CALL DOCTOR. ===================== Fire Fighting Measures ===================== Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, WATER Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP AND PLACE IN CONTAINER FOR DISPOSAL. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP DRY. Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. Ventilation:USE ADEQUATE MECHANICAL VENTILATION. Other Protective Equipment:NONE Work Hygienic Practices:WASH HANDS AFTER USE AND BEFORE EATING, DRINKING, OR SMOKING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:0.8 (WATER=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:GRANULATED CORK GASKET Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE Hazardous Decomposition Products:OXIDES OF CARBON ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
0
gloves_not_mandatory
===================== Product Identification ===================== Product ID:BRAKE LINING Preparer's Name:ROBERT M. TAMI CAGE:9H368 CAGE:65176 CAGE:9H368 CAGE:89619 ============= Composition/Information on Ingredients ============= Ingred Name:ALPHA-ALUMINA (ALUMINUM OXIDE) (EPA LISTS ONLY FIBROUS FORMS) (SARA III) CAS:1344-28-1 RTECS #:BD1200000 Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:MINERAL WOOL FIBERS CAS:65996-69-2 Other REC Limits:0.5 F/CC OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:BARIUM SULFATE CAS:7727-43-7 RTECS #:CR0600000 Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:COAL DUST (OSHA PEL RESPIRABLE QUARTZ FRACTION 2 MG/M3 IF < 5% SILICA; 0.1 MG/M3 IF > OR = 5% SILICA) RTECS #:GF8281000 Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE INGREDIENT ABOVE ACGIH TLV:2 MG/M3 RESP.FRACT. Ingred Name:CALCIUM CARBONATE (MARBLE) (LIMESTONE) CAS:1317-65-3 RTECS #:EV9580000 Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:GRAPHITE, NATURAL CAS:7782-42-5 RTECS #:MD9659600 Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MPPCF RDUST ACGIH TLV:2 MG/M3 RDUST; 9293 Ingred Name:GLASS, FIBROUS RTECS #:LK3651000 Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 (DUST) ACGIH TLV:10 MG/M3 (DUST);9293 Ingred Name:MAN-MADE FIBERS Other REC Limits:0.5 F/CC (5 MG/M3) Ingred Name:IRON OXIDE CAS:1309-37-1 RTECS #:NO7400000 Other REC Limits:NONE RECOMMENDED OSHA PEL:10 MG/M3 (FE) ACGIH TLV:5 MG/M3(FE),B2; 9293 Ingred Name:CELLULOSE (PAPER FIBER) CAS:9004-34-6 RTECS #:FJ5691460 Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3; 9293 Ingred Name:CASHEW/PHENOLIC RESINS Other REC Limits:5 MG/M3 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYE, SKIN AND RESPIRATORY IRRITATION. CHRONIC: PNEUMOCONIOSIS, ANTHROCOSILICOSIS, FIBROTIC CHANGES. SMOKING MAY AGGRAVATE THE EFFECTS OF EXPOSURE. Effects of Overexposure:EYES: IRRITATION. SKIN: IRRITATION, RASH ON SENSITIVE INDIVIDUALS. INHALATION: DRYNESS OF THROAT AND SHORTNESS OF BREATH. Medical Cond Aggravated by Exposure:INDIVIDUALS WITH A HISTORY OF RESPIRATORY OR SKIN CONDITIONS MAY BE AT INCREASED RISK. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH PLENTY OF WATER. IF IRRITATION PERSISTS, SEE DOCTOR. SKIN: REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. IF IRRITATION PERSISTS SEE DOCTOR. INHALATION: REMOVE TO FRESH AIR.GIVE CPR/OXYGEN IF NEEDED. SEE DOCTOR. INGESTION: DRINK LARGE AMOUNT OF WATER, INDUCE VOMITING. SEE DOCTOR. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER, EXTINGUISHERS CLASS A, B AND C. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:FLAMMABLE ONLY IN OXYGEN RICH ATMOSPHERE. COMBUSTION OR HEAT OF FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE. CLEAN UP USING METHODS THAT AVOID DUST GENERATION SUCH AS VACUUM, WET DUST MOP OR WET CLEAN UP AND PLACE IN APPROPIATE DISPOSAL CONTAINER AND COVER. IF DUST IS GENERATED USE NIOSH/MSHA APPR OVED RESPIRATOR WITH DUST CARTRIDGE. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CREATING EXCESSIVE DUST. USE DUST COLLECTION IF GRINDING, DRILLING OR ALTERING PRODUCT IN ANY WAY. DO NOT USE COMPRESSED AIR. Other Precautions:PROTECTIVE CREAMS AND SLEEVES MAY BE NECESSARY FOR EMPLOYEES WITH SENSITIVE SKIN. PERIODIC MEDICAL EXAMINATIONS ARE RECOMMENDED FOR INDIVIDUALS REGULARLY EXPOSED TO DUST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA-APPROVED RESPIRATOR WITH DUST CARTRIDGE IF TLV IS EXCEEDED. FOLLOW RESPIRATOR STANDARD 1910.34. Ventilation:LOCAL EXHAUST TO MAINTAIN EXPOSURE LEVEL BELOW TLV. Other Protective Equipment:PROTECTIVE SLEEVES AND CREAMS FOR EMPLOYEES WITH SENSITIVE SKIN. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DO NOT SHAKE CLOTHING. REMOVE DUST BY WASHING OR VACUUMING. Supplemental Safety and Health BRAKE LINING IS A RESIN BONDED PRODUCT WHICH DOES NOT CONTAIN ASBESTOS. WHEN USED AS INTENDED THIS PRODUCT MEETS TH OSHA DEFINITION OF AN ARTICLE AND IS EXEMPT FROM THE HCS. A POTENTIAL FOR EXPOSURE T O DUST WHEN GRINDING, DRILLING, MILLING, ETC., EXISTS AND THEREFORE ALL INFORMATION CONTAINED WITHIN SHOULD BE FOLLOWED. ================== Physical/Chemical Properties ================== HCC:T6 Spec Gravity:1.8-3.5 Solubility in Water:INSOLUBLE. Appearance and Odor:BRAKE LINING. SOLID. LIGHT TAN TO DARK GREY COLOR. SLIGHT SOUR ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Hazardous Decomposition Products:CARBON MONOXIDE, SMOKE. ==================== Disposal Considerations ==================== Waste Disposal Methods:NOTIFY YOUR LOCAL ENVIRONMENTAL OFFICER. KEEP IN COVERED CONTAINERS PENDING DISPOSAL. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:115F FIXER HARDENER CAGE:KO586 CAGE:KO586 CAGE:60349 ============= Composition/Information on Ingredients ============= Ingred Name:ALUMINUM SULFATE (SARA III) CAS:10043-01-3 RTECS #:BD1700000 Fraction by Wt: 27.5% OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SULFURIC ACID (SARA III) CAS:7664-93-9 RTECS #:WS5600000 Fraction by Wt: 03.0% OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:WATER;CAS #7732-18-5 CAS:7732-18-5 RTECS #:ZC0110000 ===================== Hazards Identification ===================== Effects of Overexposure:INHAL:MIST MAY IRRIT RESP TRACT;EYES:MAY CAUSE BURNS;SKIN:PRLNGD CONTACT MAY CAUSE IRRIT/ALLRGC ACT. ======================= First Aid Measures ======================= First Aid:INHALE:REMOVE TO FRESH AIR, GIVE CPR/O*2 IF NEED;EYES/SKIN:FLUSH W LG AMTS H*2O FOR 15 MIN;INGEST:RINSE MOUTH; GET MEDICAL ATTENTION FOR EYES, BREATHING DIFFICULTY, OR OTHER SYMPTOMS OF OVEREXPOSURE. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:EXTINGUISH WITH AGENT SUITABLE FOR SURROUNDING FIRE Fire Fighting Procedures:WEAR SELF-CNTD BRTHG,APP H*20 SPRAY TO COOL CONTR. Unusual Fire/Explosion Hazard:NONE NOTED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE IGNITION SOURCES. STOP LEAK. EVACUATE AREA.DO NOT TOUCH SPILLAGE. SM SPILL:ABSORB W. INERT ABSORBENT. PLACE IN CLOSED CONTAINER. FLUSH AREA W. WATER. LG SPILL: DIKE AHEAD FOR LATER DISPOSAL. NOTIFY AUTHORITIES. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED AREA. PROTECT FROM PHYSICAL DAMAGE.AVOID ANY PHYSICAL CONTACT. KEEP CONTAINERS TIGHTLY CLOSED Other Precautions:STORE BETWEEN 45-80F; AVOID CONTACT W/SKIN,EYES,& CLOTHG; AVOID BREATHG MIST. WASH THOROUGHLY AFTER HANDLG & USE GOOD PERSONAL HYGIENE & GOOD HOUSEKEEPING.HANDLE CAREFULLY TO AVOID SPLASHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED Ventilation:MECHANICAL (GENERAL/LOCAL EXHAUST) Other Protective Equipment:LAB APRON OR LAB COAT SHOULD BE WORN TO PROTECT CLOTHING. Supplemental Safety and Health MSDS FROM MFR DATED: JULY 3,1985. ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:B.P. Text:>212F(>100C Spec Gravity:1.30 Solubility in Water:COMPLETE Appearance and Odor:CLEAR COLORLESS LIQUID, ODORLESS. Percent Volatiles by Volume:75% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALIES, MOST METALS. Stability Condition to Avoid:EXCESSIVE HEAT Hazardous Decomposition Products:THRML DECOMPOSITION MAY EMIT OXIDES OF SULFUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:KEEP IN COVERED DRUMS,PENDING DISPOSAL. HANDLE & DISPOSE IN FULL COMPLIANCE WITH ALL APPLICABLE INTERNATIONAL,FEDERAL,STATE, & LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:ZINC OXIDE, Z0225 Resp. Party Other MSDS Num.:ACC 25490 CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:ZINC OXIDE (ZNO); (ZINC OXIDE) EINECS/ELINCS: 215-222-5. CAS:1314-13-2 RTECS #:ZH4810000 = Wt:100. Other REC Limits:N/K OSHA PEL:15 MG/M3 OSHA STEL:N/K ACGIH TLV:5 MG/M3 ACGIH STEL:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE TOXICOLOGICAL INFORMATION. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYES: DUST MAY CAUSE MECHANICAL IRRITATION. SKIN: MAY CAUSE SKIN IRRITATION. INGESTION: MODERATELY TOXIC TO HUMANS BY INGESTION. INHALATION: EFFECTS MAY BE DELAYED. INHALATION OF FUMES MAY CAUS E METAL FUME FEVER, WHICH IS CHARACTERIZED BY FLU-LIKE SYMPTOMS WITH METALLIC TASTE, FEVER, CHILLS, COUGH, WEAKNESS, CHEST PAIN, MUSCLE PAIN AND INCREASED WHITE BLOOD CELL COUNT. ZINC OXIDE DUST IS CO NSIDERED TO BE OF LOW TOXICITY AND IS CLASSIFIED AS A NUISANCE PARTICULATE BY THE ACGIH. HOWEVER, INHALATION OF FUMES OR VERY FINE DUST MAY CAUSE "ZINC FUME FEVER", WHICH IS CHARACTERIZED BY FLU-LIKESYMPTOMS WITH (EFFECTS OF OVEREXPOSURE) Explanation of Carcinogenicity:NOT LISTED. Effects of Overexposure:HEALTH HAZARDS: METALLIC TASTE, COUGHING, WEAKNESS, FATIGUE, MUSCULAR PAIN, AND NAUSEA, FOLLOWED BY FEVER AND CHILLS. ONSET OF SYMPTOMS OCCURS ABOUT 4-12 HOURS AFTER EXPOSURE. CHRONIC: NO INFORMATION FOUND. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, OCCASIONALLY LIFTING THE UPPER AND LOWER LIDS. GET MEDICAL AID. SKIN: GET MEDICAL AID. FLUSH WITH PLENTY OF SOAP AND WATER FOR AT LEAST 15 MIN UTES, WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. INGESTION: IF VICTIM IS CONSCIOUS AND ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER. GET MEDICAL AID. INHALATION: REMOVE FROM EXPOSURE TO FRESH AIR IMM EDIATELY. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL AID. NOTES TO PHYSICIAN: THE ONSET OF SYMPTOMS MAY OCCUR 4-12 HOURS AFTER EXPOSURE. ===================== Fire Fighting Measures ===================== Extinguishing Media:SUBSTANCE IS NON-COMBUSTIBLE; USE AGENT MOST APPROPRIATE TO EXTINGUISH SURROUNDING FIRE. Fire Fighting Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NFPA RATING: NOT PUBLISHED. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS INDICATED IN CONTROL MEASURES SECTION. VACUUM OR SWEEP UP MATERIAL AND PLACE INTO A SUITABLE DISPOSAL CONTAINER. AVOID GENERATING DUSTY CONDITIONS. ======================Handling and Storage ====================== Handling and Storage Precautions:USE WITH ADEQUATE VENTILATION. MINIMIZE DUST GENERATION AND ACCUMULATION. AVOID BREATHING DUST, VAPOR, MIST, OR GAS. AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. STORE IN A DRY AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS. . Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE. Supplemental Safety and Health MOLECULAR FORMULA: ZNO. FED REGS: OSHA: NONE OF CHEMS IN PROD ARE CONSIDERED HIGHLY HAZ BY OSHA. EUROPEAN/INTERNATIONAL REGS: EUROPEAN LABELING I/A/W EC DIRECTIVES: HAZ SYMBOLS: NOT AVAIL. WGK (WATER DANGER/PROT): CAS # 1314-13-2: 0. CANADA: CAS # 1314-13-2 IS LISTED ON CANADA'S DSL/NDSL LIST. (ECOL INFO) ================== Physical/Chemical Properties ================== Melt/Freeze Pt:=1800.C, ######F Spec Gravity:5.68 Solubility in Water:NEGLIGIBLE Appearance and Odor:WHITE TO YELLOW-WHITE SOLID; ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REACTS EXPLOSIVELY WITH MAGNESIUM WHEN HEATED. MIXTURES OF CHLORINATED RUBBER AND ZINC OXIDE CAN EXPLODE VIOLENTLY WHEN HEATED TO 419F. Stability Condition to Avoid:INCOMPATIBLE MATERIALS. Hazardous Decomposition Products:TOXIC FUMES OF ZINC OXIDE. =================== Toxicological Information=================== Toxicological Information:RTECS #: CAS # 1314-13-2: ZH4810000. LD50/LC50: INHALATION, MOUSE: LC50 = 2500 MG/M3. ORAL, MOUSE: LD50 = 7950 MG/KG. EPIDEMIOLOGY, TERATOGENICITY, REPRODUCTIVE EFFECTS, NEUROTOXICITY, MUTAGENICITY, O THER STUDIES: NO DATA AVAILABLE. ===================== Ecological Information ===================== Ecological:ECOTOXICITY, ENVIRONMENTAL FATE, PHYSICAL/CHEMICAL, OTHER: NO INFO FOUND. --SUPDAT: PROD HAS A WHMIS CLASSIFICATION OF D2B. PROD IS NOT LISTED ON CANADA'S ING DISCLOSURE LIST. EXPOS LIMS: OEL-ARAB REP UBLIC OF EGYPT: TWA 5 MG/M3. OEL-AUSTRALIA: TWA 10 MG/M3. OEL-AUSTRALIA: TWA 5 MG/M3; STEL 10 MG/M3 (FUME). OEL-BELGIUM: TWA 10 MG/M3. OEL-BELGIUM: TWA 5 MG/M3; STEL 10 MG/M3 (FUME) JAN9. OEL-CZECHOSL OVAKIA: TWA 5 MG/M3; STEL 15 MG/M3 JAN9. OEL-DENMARK: TWA 4 MG/M3 (FUME). OEL-DENMARK: TWA 4 MG/M3 (DUST). OEL-FINLAND: TWA 5 MG/M3 (FUME). OEL-FRANCE: TWA 10 MG/M3. OEL-FRANCE: TWA 5 MG/M3 (FUME). OE L-GERMANY: TWA 5 MG/M3 (TRANSPORT INFO) ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE, AND LOCAL REGULATIONS. RCRA D-SERIES MAXIMUM CONCENTRATION OF CONTAMINANTS: NONE LISTED. RCRA D-SERIES CHRONIC TOXICITY REFERENCE LEVELS: NONE LI STED. RCRA F-SERIES: NONE LISTED. RCRA P-SERIES: NONE LISTED. RCRA U-SERIES: NONE LISTED. =================== MSDS Transport Information =================== Transport Information:US DOT, IATA, RID/ADR, IMO, CANADA TDG: NO INFORMATION AVAILABLE. --ECOL INFO: (FUME). OEL-HUNGARY: TWA 5 MG/M3. OEL-JAPAN: TWA 5 MG/M3 (FUME). OEL-THE NETHERLANDS: TWA 5 MG/M3. OEL-THE PHILIPPINES: TWA 1 MG/M3. OEL-POLAND: TWA 4 MG/M3 (FUME). OEL-SWEDEN: TWA 5 MG/M3. OEL-SWITZERLAND: TWA 5 MG/M3. OEL-SWITZERLAND: TWA 5 MG/M3 (FUME). OEL-THAILAND: TWA 5 MG/M3 (FUME). OEL-TURKEY: TWA 5 MG/M3. OEL- UNITED KINGDOM: TWA 5 MG/M3; STEL 10 MG/M3 JAN9. OEL-UNITED KINGDOM: TWA 5 MG/M3; STEL 10 MG/M3 (FUME). OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA, NEW ZEALAND, SINGAPORE, VIETNAM CHECK ACGIH TLV. ===================== Regulatory Information ===================== SARA Title III Information:SECTION 302 (RQ): NONE OF THE CHEMICALS IN THIS MATERIAL HAVE AN RQ. SECTION 302 (TPQ): NONE OF THE CHEMICALS IN THIS PRODUCT HAVE A TPQ. SARA CODES: CAS # 1314-13-2: ACUTE. SECTION 313: THIS MATERIALCONTAINS ZINC OXIDE (LISTED AS ZINC), 100%, (CAS # 1314-13-2) WHICH IS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF SARA TITLE III AND 40 CFR PART 373. Federal Regulatory Information:TSCA: CAS # 1314-13-2 IS LISTED ON TSCA INVENTORY. HLTH & SFTY REPORTING LIST: NONE OF CHEMS ARE ON HLTH & SFTY REPORTING LIST. CHEM TEST RULES: NONE OF CHEMS IN PROD ARE UNDER CHEM TEST RULE. SECTION 12B: NONE OF CHEMS ARE LISTED UNDER TSCA SECTION 12B. TSCA SIGNIFICANT NEW USE RULE: NONE OF CHEMS IN MATL HAVE SNUR UNDER TSCA. CLEAN AIR ACT: MATL DOES NOT CONTAIN ANY HAZ AIR POLLUTANTS, ANY CLASS 1 OZONE DEPLETORS/ANY CLASS 2 OZONE DEPLETORS. CLEAN WATER ACT: NONE OF CHEMS IN PROD ARE LISTED AS HAZ SUBSTANCES, PRIORITY POLLUTANTS/TOX POLLUTANTS UNDER CWA. (SUP DAT) State Regulatory Information:CAS # 1314-13-2 CAN BE FOUND ON THE FOLLOWING STATE RIGHT-TO-KNOW LISTS: CALIFORNIA, NEW JERSEY, FLORIDA, PENNSYLVANIA, MINNESOTA, MASSACHUSETTS. CALIFORNIA NO SIGNIFICANT RISK LEVEL: NONE OF THE CHEM ICALS IN THIS PRODUCT ARE LISTED. ======================= Other Information =======================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:TASK FORCE, HEAVY DUTY DEGREASER CAGE:58396 CAGE:58396 ============= Composition/Information on Ingredients ============= Ingred Name:SILICIC ACID (H2SIO3), DISODIUM SALT; (SODIUM METASILICATE) CAS:6834-92-0 RTECS #:VV9275000 Fraction by Wt: 5-10% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:POTASSIUM HYDROXIDE (CERCLA) CAS:1310-58-3 RTECS #:TT2100000 Fraction by Wt: 5-10% OSHA PEL:2 MG/M3, C ACGIH TLV:2 MG/M3, C EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES/SKIN:MAY IRRITATE. INGESTION:MAY IRRITATE GASTROINTESTINAL TRACT & AFFECT OTHER INTERNAL ORGANS. DETECTABLE AMOUNTS OF "CHEMICALS KNOWN TO STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR OT HER REPRODUCTIVE HARM" MAY BE FOUND IN VARIOUS PRODUCTS & THEIR VAPORS OR RESULT FROM THEIR USE. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:UNKNOWN. ======================= First Aid Measures ======================= First Aid:QUICKLY FOLLOW DIRECTIONS BELOW; CALL POIS CTL CTR/MD. GET QUICK MED ATTN IF ANY ILL EFTS CONTINUE/DEVELOP LATER. INHAL:REMOVE TO FRESH AIR. SUPPORT BRTHG (GIVE O*2/ARTF RESP) . EYES:FLUSH W/PLE NTY OF WATER FOR AT LST 15 MINS WHILE REMOVING ANY CONT LENSES, THEN HOLD EYELIDS OPEN & CONTINUE FLUSHING THORO. SKIN:REMOVE ANY CONTAM CLTHG, THEN WASH AFFECTED SKIN W/SOAP & WATER. INGEST: (SUPDAT) ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE CLOTHING. WIPE OR MOP UP SPILLS THEN RINSE W/WATER. FLOORS MAY BE SLIPPERY; USE CAUTION TO AVOID FALLS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:WARNING:MAY IRRITATE EYES & SKIN. AVOID CONT W/EYES OR SKIN. KEEP OUT OF REACH OF CHILDREN. STORE IN COOL, DRY AREA. DO NOT TAKE INTERNALLY. Other Precautions:KEEP FROM FREEZING. DO NOT MIX W/OTHER CHEMS. DO NOT CONSUME FOOD/BEVERAGE WHILE USING PROD. DO NOT SMOKE IN WORK AREA. KEEP CNTNR CLSD WHEN NOT IN USE. READ ENTIRE LBL BEFORE USING PROD. READ & FOLLO W LBL DIRECTIONS & OTHER PROD (SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . NONE REQUIRED IF ADEQUATE VENTILATION AVAILABLE. Ventilation:MECHANICAL (GENERAL) ADEQUATE VENTILATION. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER USE. READ PRODUCT LABEL BEFORE USE. Supplemental Safety and Health FIRST AID PROC:RINSE MOUTH W/WATER, SPIT OUT RINSE, THEN DRINK GLASSFUL OF WATER. DO NOT INDUCE VOMIT UNLESS DIRECTED BY MED PERS. GET IMMED MED ATTN. OTHER PREC:SFTY & HLTH INFO WHICH YOU HAVE BEEN P ROVIDED W/WHEN HNDLG/USING MFR'S PRODUCTS. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:214F,101C Vapor Pres:18 Vapor Density:<1 Spec Gravity:1.04 Evaporation Rate & Reference:<1 (BUTYL=1) Solubility in Water:COMPLETE Appearance and Odor:CLEAR GREEN LIQUID; LIGHT SOLVENT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:NONE KNOWN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . TRIPLE RINSE CONTAINER THEN DISCARD IN TRASH.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:57253 ANTI-IGG CLEAR MONOSPECIFIC CAGE:67018 CAGE:67018 CAGE:67823 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM AZIDE, AZIDE *98-1* CAS:26628-22-8 RTECS #:VY8050000 Fraction by Wt: 0.1% Other REC Limits:0.1 PPM ACGIH TLV:C 0.29 MG/CUM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): 27 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:HARMFUL IF SWALLOWED. MAY BE ABSORBED THROUGH SKIN. MAY CAUSE ALLERGENIC REACTION IN SUSCEPTIBLE INDIVIDUALS. Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:EYES: FLUSH THOROUGHLY W/WATER FOR 15 MINS. SKIN: RINSE W/PLENTY OF WATER FOR 15 MINS. INHALATION: AID IN BREATHING IF NECESSARY. INGESTION: FLUSH MOUTH. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:DRY CHEMICAL/CO2 ================== Accidental Release Measures ================== Spill Release Procedures:SMALL: WEAR PROTECTIVE CLOTHING TO GUARD AGAINST EYE & SKIN CONTACT. USE SPILL PILLOWS/OTHER APPROPRIATE ABSORBENT. PLACE MATERIALS IN SEALED CONTAINER FOR PROPER DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE BETWEEN 35.6F-46.4F. DON'T STORE NEAR ACIDS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED, UNDER NORMAL PRODUCT USE. Ventilation:USE W/ADEQUATE VENTILATION. Other Protective Equipment:CHEMICAL RESISTANT APRON, PROTECTIVE CLOTHING. Work Hygienic Practices:GOOD HYGIENE PRACTICES SHOULD BE FOLLOWED TO AVOID EYE & SKIN CONTACT W/THIS PRODUCT. Supplemental Safety and Health WHILE THE PRODUCTS LISTED ARE NOT CONSIDERED HAZARDOUS AS DEFINED BY OSHA, BCA WOULD LIKE TO MAKE YOU AWARE OF THE FOLLOWING HANDLING PRECAUTIONS: THESE PRODUCTS CONTAIN 0.1%/LESS SODIUM AZIDE AS A PR ESERVATIVE. THEREFORE, WE HAVE ENCLOSEDA MSDS FOR 0.1% SODIUM AZIDE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F Vapor Pres:AS WATER Evaporation Rate & Reference:(WATER=1): 1 Appearance and Odor:COLORLESS LIQUID W/NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS Hazardous Decomposition Products:TOXIC GAS, MAY FORM EXPLOSIVE LEAD/COPPER IN LABORATORY PLUMBING ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. MAY FORM EXPLOSIVE LEAD/COPPER AZIDE IN LABORATORY PLUMBING.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:8855 BRIGHT RED, 8091997 CAGE:DO804 CAGE:DO804 CAGE:38360 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANOL, 2-(2-PHENOXYETHOXY)-; (DIETHYLENE GLYCOL MONOPHENYL ETHER) CAS:104-68-7 RTECS #:KM0875000 Fraction by Wt: 1-5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:2-PROPANOL, 1,1'-OXYDI-; (DIPROPYLENE GLYCOL). LD50:(ORAL,RAT) 14850 MG/KG CAS:110-98-5 RTECS #:UB8785000 Fraction by Wt: 10-30% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ETHANOL, 2-PHENOXY-; (ETHYLENE GLYCOL PHENYL ETHER) CAS:122-99-6 RTECS #:KM0350000 Fraction by Wt: 10-30% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT:IMMED & BE PROVIDED W/THIS MSDS. RECENT INFO SUGGEST THAT RISK ASSOC W/INDUCING VOMIT EXCEEDS POISONING (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4:RISK OF SUBSTANCE, ESPECIALLY FOR SM QTYS LIKELY TO BE INGESTED UNDER NORMAL INDUST USE. GET MED ATTN (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:IMMED. DRINK 2 GLASSES OF WATER. CONT POISON INFO SERVICE. STOM EVAC MAY BE APPROP, AS REC BY MEDICAL (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:PROFESSIONALS, ONLY IF SIGNIFICANT QTY OF MATLS HAS BEEN INGESTED. STOMACH EVAC SHOULD ONLY BE CARRIED (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:OUT BY TRAINED & PROPERLY EQUIPPED MEDICAL PERSONNEL. RTECS #:9999999ZZ Ingred Name:SPILL PROC:ANY SIZE. PERSONAL PROT EQUIP NEEDS MUST BE EVAL BASED ON INFO PROVIDED ON THIS MSDS & SPECIAL (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:CIRCUMSTANCES CREATED BY SPILL INCL; MATL SPILLED, THE QTY OF SPILL, THE AREA IN WHICH SPILL OCCURRED, & (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:EXPERTISE OF EMPLOYEES IN AREA RESPONDING TO SPILL. NEVER EXCEED ANY OCCUP EXPOS LIMS & CONSIDER THAT (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:EVAPORATION OF VOLAT SOLVS CAN LEAD TO DISPLACEMENT OF AIR CREATING ENVIR THAT CAN CAUSE ASPHXYIATION. RTECS #:9999999ZZ Ingred Name:WASTE DISP METH:FEDERAL OR OTHER REGULATIONS. RTECS #:9999999ZZ Ingred Name:OTHER PREC:POSSIBLE SINCE IT IS MISCIBLE IN WATER. IF RELEASED TO SOIL, DIPROPYLENE GLYCOL IS EXPECTED TO (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:LEACH READILY. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 2 Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:EYE:CAN CAUSE SEV IRRIT, TEARING & REDDENING, BUT NOT LIKELY TO PERMANENTLY INJURE TISSUE. SKIN:CAN CAUSE IRRIT & DERMATITIS. SKIN ABSORP:MINIMAL HAZ IN NORMAL INDUST USE. INHALATION:CAN CAUSE R ESPIRATORY IRRIT, DIZZINESS, WEAKNESS, FATIGUE, NAUS, HEADACHE & POSSIBLE UNCON. INGESTION:IRRITATING (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:TO MOUTH, THROAT, & STOMACH. CAN CAUSE ABDOM DISCOMFORT, NAUSEA, VOMITING & DIARRHEA. TARGET ORGANS:EYES; SKIN; NERVOUS SYSTEM; BLOOD; LIVER; KIDNEYS; THYROID. ETHYLENE GLYCOL PHENYL EHTER:MF R HAS ESTABLISHED INTERNAL INDUST HYGIENE GUIDE OF 25PPM (SKIN) (8-HR TWA) FOR EXPOS. SKIN MAY CONTRIBUTE TO EXPOSURE. Medical Cond Aggravated by Exposure:NO DATA FOUND. ======================= First Aid Measures ======================= First Aid:EYE:IMMED FLUSH W/PLENTY OF WATER FOR @ LST 15 MINS RETRACTING EYELIDS OFTEN. GET IMMED MED ATTN. SKIN:WASH W/SOAP & WATER. REMOVE CONTAMD CLTHG & LAUNDER. GET MED ATTN IF IRRIT DEVELOSP/PERSISTS. IMM ED REMOVE ALL LEATHER GOODS, INCL SHOES, BELTS, & CLTHG & INCIN. INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP/HAVE TRAINED INDIVIDUAL ADMIN OXYG. GET MED ATTN IMMED. INGEST:INFO (SUPDAT) ===================== Fire Fighting Measures ===================== Flash Point:250F,121C Extinguishing Media:USE ALCOHOL FOAM, CARBON DIOXIDE, OR WATER SPRAY WHEN FIGHTING FIRES. Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . FIGHT FIRE FROM SAFE DIST & PROTECTED LOCATION. HEAT MAY BUILD PRESS & RUPTURE CLSD CNTNRS, SPREADING FIRE (SUPDAT) Unusual Fire/Explosion Hazard:GEN HAZS:MATL MAY BE IGNITED IF PREHEATED TO TEMPS ABOVE FLASH POINT IN PRESENCE OF SOURCE OF IGNITION. HAZ COMBUST PRODS:CARBON DIOXIDE; CARBON MONOXIDE. ================== Accidental Release Measures ================== Spill Release Procedures:PVNT SPREAD OF ANY SPILL TO MINIMIZE HARM TO HUMAN HLTH & ENVIR. DIKE W/SUITABLE ABSORB MATL LIKE SPEEDIDRI. WEAR COMPLETE & PROPER PERSONAL PROT EQUIP & VENTILATE SPACE INVOLVED. FOLLOW GUIDELINES OF 29 CFR 1910.120 FOR DEALING W/SPILL OF(ING 9) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY PLACE. ISOLATE FROM INCOMPAT MATLS. AVOID CONT W/MATL, AVOID BRTHG VAPORS, USE ONLY IN WELL VENTILATED AREA. Other Precautions:ECOLOGICAL INFO:DIPROPYLENE GLYCOL:IF RELEASED TO AIR, DIPROPYLENE GLYCOL WILL DEGRADE RELATIVELY RAPIDLY BY RXN W/PHOTOCHEMICALLY PRDCED HYDROXYL RADICALS (EST HALF=LIFE OF 13 HRS). PHYSICAL REMOVAL FROM AIR VIA WET DEPOSITION IS (ING 14) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPRVD RESP APPROP FOR EXPOS OF CONCERN . MAY NOT BE REQD UNDER NORM CNDTNS OF USE. Ventilation:USE PROCESS ENCLOSURES, LOC EXHAUST VENT/OTHER ENGINEERING CONTROLS TO MIN EXPOS & MAINTAIN OPERATOR COMFORT. Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . APRON, BOOTS. Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN. ALL EQUIP SHOULD BE CLEANED THOROUGHLY AFTER EACH USE & SHOULD NOT LEAVE WORK PLACE. Supplemental Safety and Health FIRE FIGHT PROC:& INCR RISK OF BURN/INJURIES. USE WATER SPRAY/FOG FOR COOLING. EVEN IF MATL IS WATER SOL, IT MAY NOT BE PRACTICAL TO EXTINGUISH FIRE BY WATER DILUTION. NOTIFY AUTH IF LIQ ENTERS SEWERS /OTHER PUBLIC WATERS. FIRST AID PROC:PRESENTED IN THIS SECTION IS ONLY A GUIDE. EMER PERS SHOULD BE CONTACTED (ING 4) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>450F,>232C Melt/Freeze Pt:M.P/F.P Text:51.0F,10.6C Vapor Pres:0.01-0.1 Vapor Density:HVR/AIR Spec Gravity:1.10 (G/ML) Evaporation Rate & Reference:NOT KNOWN Solubility in Water:NOT KNOWN Appearance and Odor:LIQUID, SEMI-SOLID, OR SOLID. MILD SOLVENT ODOR. Percent Volatiles by Volume:50 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:ELEVATED TEMPERATURES IN COMBINATION WITH SPARKS, OPEN FLAMES, OR OTHER SOURCES OF IGNITION. Hazardous Decomposition Products:CARBON DIOXIDE; CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCARDED/SPENT PROD/OTHER NON-HAZ SOLID WASTE CONTAMD W/THIS MATL IS NOT LIKELY RCRA HAZ WASTE. PERFORM HAZ WASTE DETERMINATION PER 40 CFR 261 TO CONFIRM. DISPOSE IN LINED LANDFILL, INCIN/OTHERWISE T REAT WASTE MATL AS REQD BY LOCAL, STATE, (ING 13)
1
gloves_mandatory
===================== Product Identification ===================== Product ID:AIRLIFT FLORAL (BULK) Preparer's Name:THOMAS J. MITCHELL CAGE:23212 CAGE:23212 ============= Composition/Information on Ingredients ============= Ingred Name:ISOPROPYL ALCOHOL (SARA III) CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 1-5% Other REC Limits:400 PPM OSHA PEL:400 PPM/500 STEL ACGIH TLV:400 PPM/500STEL;9192 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN/EYES: IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:SKIN/EYES: IRRITATION. ======================= First Aid Measures ======================= First Aid:INGESTION: DRINK LARGE QUANTITIES OF WATER. EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:NONE ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH W/WATER THROUGH SANITARY SEWER SYSTEM. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTAMINATION OF FOOD. AVOID CONTACT W/SKIN, EYES, & CLOTHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AS REQUIRED Ventilation:LOCAL EXHAUST REQUIRED Other Protective Equipment:NONE Supplemental Safety and Health SOLID BY WEIGHT: 3-5% ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F Vapor Pres:18 Spec Gravity:1.0 pH:5-7 Evaporation Rate & Reference:(BU AC = 1): <1 Solubility in Water:COMPLETE Appearance and Odor:YELLOW TO AMBER LIQUID, PLEASANT FLORAL ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:SCOTCHCAST BRAND ELECTRICAL RESIN 9 5240,PA Kit Part:Y CAGE:75037 CAGE:75037 ============= Composition/Information on Ingredients ============= Ingred Name:EPOXY RESIN (PART A CONTAINS INGREDIENTS 1 THROUGH 5) CAS:25068-38-6 RTECS #:KC2100000 Fraction by Wt: 62 - 66% Other REC Limits:NONE SPECIFIED Ingred Name:TALC (CONTAINING ASBESTOS) CAS:14807-96-6 RTECS #:MW2700000 Fraction by Wt: 15 - 20% Other REC Limits:NONE SPECIFIED OSHA PEL:0.2 FIBERS/CC ACGIH TLV:0.2 FIBERS/CC; 9192 Ingred Name:MICA - SILICATES (< 1% CRYSTALLINE SILICA) CAS:12001-26-2 RTECS #:VV8760000 Fraction by Wt: 15 - 20% Other REC Limits:NONE SPECIFIED OSHA PEL:20 MPPCF ACGIH TLV:3 MG/M3 RDUST; 9293 Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 Fraction by Wt: 0.1-1.0% Other REC Limits:NONE SPECIFIED OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3; 9192 Ingred Name:IRON OXIDE CAS:1309-37-1 RTECS #:NO7400000 Fraction by Wt: 0.1 - 1% Other REC Limits:NONE SPECIFIED OSHA PEL:10 MG/M3 (FE) ACGIH TLV:5 MG/M3(FE),B2; 9293 Ingred Name:POLYMERIZED FATTY ACID AMIDE (PART B CONTAINS INGREDIENTS 6 THROUGH 11). CAS:68650-54-4 Fraction by Wt: 50 - 55% Other REC Limits:NONE SPECIFIED Ingred Name:TALC (CONTAINING ASBESTOS) CAS:14807-96-6 RTECS #:MW2700000 Fraction by Wt: 15 - 20% Other REC Limits:NONE SPECIFIED OSHA PEL:0.2 FIBERS/CC ACGIH TLV:0.2 FIBERS/CC; 9192 Ingred Name:MICA - SILICATES (< 1% CRYSTALLINE SILICA) CAS:12001-26-2 RTECS #:VV8760000 Fraction by Wt: 15 - 20% Other REC Limits:NONE SPECIFIED OSHA PEL:20 MPPCF ACGIH TLV:3 MG/M3 RDUST; 9293 Ingred Name:POLYSTYRENE RESIN,OR SEE INGREDIENT #2 CAS:9003-53-6 Fraction by Wt: 10 - 15% Other REC Limits:NONE SPECIFIED Ingred Name:NONYLPHENOL CAS:25154-52-3 RTECS #:SM5600000 Fraction by Wt: 1.0-5.0% Other REC Limits:NONE SPECIFIED Ingred Name:DIETHYLENE TRIAMINE CAS:111-40-0 RTECS #:IE1225000 Fraction by Wt: 1.0-5.0% Other REC Limits:NONE SPECIFIED OSHA PEL:1 PPM ACGIH TLV:S, 1 PPM; 9192 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE-PART A/B/MIXTURE.EYE:IRRITATING.SKIN:IRRITATION & IN SUSCEPTIBLE INDIVIDUALS MAY CAUSE SENSITIZATION.INHALATION:IRRITATION OF RESPIRATORY SYSTEM.MAY CAUSE SENSITIZATION IN SOME SUSCEPTIBLE INDIV IDUALS.INGESTION:MAY IRRITATE DIGESTIVESYSTEM.MAY DAMAGE TISSUE OR DIGESTIVE SYSTEM.CHRONIC-UNKNOWN. Explanation of Carcinogenicity:THE AVAILABLE DATA PROVIDE INADEQUATE EVIDENCE TO EVALUATE THE CARCINOGENICITY TO HUMANS OF CARBON BLACKS. Effects of Overexposure:PART A/B/MIXTURE.EYES, SKIN, RESPIRATORY TRACT AND DIGESTIVE SYSTEM IRRITATION. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS MAY BE SUSCEPTIBLE TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:PART A/B/MIXTURE.EYES:FLUSH WITH WATER FOR AT LEAST 10 MINUTES.CALL A PHYSICIAN.SKIN:WASH THOROUGHLY WITH SOAP & WATER.INHALATION:REMOVE TO FRESH AIR.IF COUGHING,WHEEZING OR SHORTNESS OF BREATH DEVELO P,CALL A PHYSICIAN.INGESTION:IF CONSCIOUS,DRINK ONE TO TWO GLASSES OF WATER.CALL A PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:>350F,>177C Extinguishing Media:CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. WATER MAY BE INEFFECTIVE. BUT IT CAN BE USED TO COOL CONTAINERS EXPOSED TO FIRE. Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:PART A/PART B OR MIXTURE:OBSERVE PRECAUTIONARY INFORMATION. USE ABSORBENT MATERIAL AS NEEDED. AND SWEEP UP. CLEAN UP SPILL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE-STORE AWAY PART A/PART B/MIXTURE FROM HEAT AND OPEN FLAME. Other Precautions:AVOID EYE AND SKIN CONTACT. DO NOT BREATHE VAPORS OR HEATED MIXTURE. COOL DOWN AREA SHOULD BE VENTILATED TO PREVENT VAPORS FROM ENTERING THE WORK AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE VENTILATION IS INSUFFICIENT, USE A NIOSH APPROVED RESPIRATOR WITH ORGANIC VAPOR CARTRIDGES. Ventilation:LOCAL EXHAUST Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER. WEAR INDUSTRIAL TYPE WORK CLOTHING AND RUBBER APRON AS REQUIRED. Work Hygienic Practices:CHANGE CONTAMINATED CLOTHING AS SOON AS POSSIBLE. WASH HANDS BEFORE EATING. Supplemental Safety and Health THE PRODUCT IS A MIXTURE OF PART A (INGREDIENTS 1 THROUGH 5) AND B (INGREDIENTS 6 THROUGH 11). FORMULATION CHANGED. FOR PREVIOUS FORMULATION, SEE P/N A AND B SAME NSN. ================== Physical/Chemical Properties ================== HCC:N1 Solubility in Water:NIL Appearance and Odor:RED TO BROWN VISCOUS LIQUID Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:HIGH TEMPERATURES AND OPEN FLAMES Hazardous Decomposition Products:NORMAL PRODUCTS OF INCOMPLETE COMBUSTION.CARBON MONOXIDE, CARBON DIOXIDE AND POSSIBLY OXIDES OF NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL LAWS AND REGULATIONS CONCERNING HEALTH AND POLLUTION.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:DIRT FIGHTER EXTERIOR LATEX FLAT FINISH, (S CAGE:85231 CAGE:59019 CAGE:85231 ============= Composition/Information on Ingredients ============= Ingred Name:NO INGREDIENT FOR THIS FORMULATION_INGREDIENT ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE:IRRIT OF EYES, SKIN & UPPER RESP SYS. IN CONFINED AREA VAPS IN HIGH CONC MAY CAUSE HDCH, NAUS OR DIZZ. REDNESS & ITCHING/BURNING SENSATION MAY INDICATE EYE/EXCESSIVE SKIN EXPOS. CHRONIC:LONG TER M EXPOS TO HIGH LEVELS OF SILICA DUST, WHICH CAN OCCUR ONLY WHEN SANDING/ABRADING DRY FILM, MAY CAUSE (EFTS OF OVEREXP) Explanation of Carcinogenicity:CRYSTALLINE SILICA:GROUP 2A (IARC). Effects of Overexposure:HLTH HAZ:LUNG DMG (SILICOSIS) & POSS CANCER. ETHYLENE GLYCOL IS CONSIDERED AN ANIMAL TERATOGEN. IT HAS BEEN SHOWN TO CAUSE BIRTH DEFECTS IN RATS & MICE @ HIGH DOSES WHEN GIVEN IN DRINKING H*2O/BY GAVA GE. THERE IS NO EVID TO INDICATE IT CAUSES BIRTH DEFECTS IN HUMANS. PRLNG OVEREXP TO SOLV INGREDS MAY CAUSE (SUPP DATA) Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM & QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE RE-USE. EYES:FLUSH W/LARGE AMOUNTS OFWATER FOR AT LEAST 15 MINUTES. GET MD.INGEST:CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:>199F,>93C Extinguishing Media:CO*2, DRY CHEMICAL, ALCOHOL FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . H*2O SPRAY MAY BE INEFT. IF H*2O IS USED, FOG NOZZ ARE PREF. H*2O MAY BE USED TO COOL CLSD CNTNRS (SUPDAT) Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE & REMOVE W/INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CNTNR CLSD WHEN NOT IN USE. TRANSFER ONLY TO APPRVD CNTNRS W/COMPLETE & APPROP LABELING. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. Other Precautions:USE ONLY W/ADEQ VENT. AVOID BRTHG VAP & SPRAY MIST. AVOID CNTCT W/SKIN & EYES. THIS COATING MAY CONTAIN MATLS CLASSIFIED AS NUISANCE PARTICULATES, SUCH AS TITANIUM DIOXIDE/CALCIUM CARBONATE, WHICH MAY BE PRESENT @ HAZ LEVELS ONLY (ING 7) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW APPLIC LIMS BY VENT, WEAR PROPERLY FITTED NIOSH/MSHA APPRVD ORG VAP/PARTICULATE RESP FOR PROT AGAINST MATLS IN INGREDS. WHEN SANDING, WIREBRUSHING, ABRADIN G, BURNING/WELDING DRIED FILM, (ING 8) Ventilation:LOC EXHST PREF. GEN EXHST ACCEPT IF EXPOS TO MATLS IN INGREDS IS MAINT BELOW APPLIC EXPOS LIMS. REFER TO OSHA (ING 9) Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:WASH HANDS AFTER USING. Supplemental Safety and Health MFR'S TRADE NAME/PART NO:17-86 LEXINGTON GREEN. PH:9.2-9.7. FIRE FIGHT PROC:TO PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN EXPOSED TO EXTREME HEAT. EFTS OF OVEREXP:ADVERSE EFTS TO LIVER & URINARY SYS. RATS EXPOSED TO TITANIUM DIOXIDE DUST @ 250 MG/M3 DEVELOPED LUNG CANCER, HOWEVER, SUCH EXPOS LEVELS ARE NOT (ING 6) ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:212F,100C Vapor Pres:SEE INGRED Vapor Density:HVR/AIR pH:SUPDAT Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:59-78 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:BY FIRE:CO*2, CO, OXIDES OF METALS IN INGREDIENTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM PROD IS NOT HAZ AS DEFINED UNDER RCRA 40CFR261. INCIN IN APPRVD FACILITY. DO NOT INCIN CLSD CNTNR. DISPOSE OF I/A/W FEDERAL, STATE & LOCAL REGULATIONS REGARDING POLLUTION.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:EP GEAR OIL ISO 68 CAGE:5X735 CAGE:5X735 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-REFINED HEAVY PARAFFINIC, LUBRICATING OIL BASE STOCK CAS:64741-88-4 RTECS #:PY8040500 Fraction by Wt: <100% OSHA PEL:5 MG/CUM ACGIH TLV:5 MG/CUM Ingred Name:PROTECTOR GEAR OILS ISO #68 Fraction by Wt: <100% Ingred Name:NON-HAZARDOUS INGREDIENTS Fraction by Wt: <100% Ingred Name:SOLVENT REFINED HYDROTREATED HEAVY PARAFFINIC DISTILLATE, HYDROTREATED HEAVY PARAFFINIC DISTILLATE *96-3* CAS:64742-54-7 RTECS #:PY8035500 Fraction by Wt: <100% OSHA PEL:5 MG/CUM (MIST) Ingred Name:OIL PETROLEUM DISTILLATES, SOLVENT-DEWAXED HEAVY PARAFFINIC CAS:64742-65-0 RTECS #:PY8038500 Fraction by Wt: <100% Other REC Limits:5 MG/CUM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Explanation of Carcinogenicity:NONE Effects of Overexposure:NONE Medical Cond Aggravated by Exposure:NONE ======================= First Aid Measures ======================= First Aid:EYES: WASH W/WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER. INHALATION: REMOVE TO SOURCE OF FRESH AIR. INGESTION: INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:310F Lower Limits:1 Upper Limits:7 Extinguishing Media:DRY CHEMICAL, CO2, FOAM. Fire Fighting Procedures:WEAR AIR SUPPLIED BREATHING EQUIPMENT WHEN FIRE FIGHTING IN ENCLOSED SPACES. Unusual Fire/Explosion Hazard:DON'T USE WATER AS A SOLID STREAM ON ANY QUANTITY OF BURNING OIL AS IT MAY CAUSE FROTHING OF OIL & SPREAD THE FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP W/OIL ABSORBENT. ======================Handling and Storage ====================== Handling and Storage Precautions:EMPTY CONTAINERS MAY CONTAIN EXPLOSIVE VAPORS/DANGEROUS RESIDUES. DON'T CUT, PUNCTURE/WELD ON/NEAR CONTAINER. Other Precautions:ALL LABELED HAZARDOUS PRECAUTIONS MUST BE OBSERVED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE IS NEEDED UNDER ANTICIPATED USE W/ADEQUATE VENTILATION. Ventilation:NONE NEEDED. Other Protective Equipment:NONE NEEDED. Work Hygienic Practices:WASH AFTER SKIN CONTACT. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:500F Vapor Pres:1 Spec Gravity:0.86-0.93 Solubility in Water:NEGLIGIBLE Appearance and Odor:LUBER OIL ODOR & COLOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, ALKALINES, OXIDIZERS, LIQUID CHLORINE & OXYGEN. Hazardous Decomposition Products:GASES/VAPORS. ==================== Disposal Considerations ==================== Waste Disposal Methods:SHOVEL UP & DISPOSE OF AT AN APPROPRIATE WASTE DISPOSAL FACILITY IAW/FEDERAL, STATE & LOCAL REGULATIONS.
0
gloves_not_mandatory
===================== Product Identification ===================== Product ID:01893 TDH OIL CAGE:2R503 CAGE:0T186 CAGE:2R503 ============= Composition/Information on Ingredients ============= Ingred Name:CATALYTIC DEWAXED LIGHT PETROLEUM PARAFFIN OIL OR KEROSENE 1-K CAS:64742-71-8 RTECS #:PY8046000 Fraction by Wt: 35-49.9% Other REC Limits:NONE RECOMMENDED Ingred Name:DISTILLATES, SOLVENT-DEWAXED LIGHT PARAFFINIC CAS:64742-56-9 RTECS #:PY8039500 Fraction by Wt: 35-49.9% Other REC Limits:NONE RECOMMENDED OSHA PEL:300 PPM ACGIH TLV:300 PPM Ingred Name:MINERAL OIL, HYDROTREATED (SEVERE), PETROLEUM DISTILLATE, HEAVY PARAFFINIC CAS:64742-54-7 RTECS #:PY8035501 Fraction by Wt: 3-9.99% Other REC Limits:NONE RECOMMENDED Ingred Name:ADDITIVES Fraction by Wt: 1-2.99% Other REC Limits:NONE RECOMMENDED Ingred Name:PHOSPHORODITHOIC ACID, O-O-D1 C1-14-ALKYL ESTERS, ZINC SALTS (2:1) (ZDDP) CAS:68649-42-3 Fraction by Wt: 1-2.99% Other REC Limits:NONE RECOMMENDED Ingred Name:HYDROTREATED LIGHT NAPHTHENIC PETROLEUM DISTILLATES OR MINERAL OIL CAS:64742-53-6 RTECS #:PY8036000 Fraction by Wt: 1-2.99% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 (OIL MIST) ACGIH TLV:5 MG/M3 (OIL MIST) Ingred Name:METHACRYLIC ACID, COPOLYMER OF "BUTYL", "LAURYL" & "STEARYL" ESTERS WITH 3-DIMETHYL-AMINOPROPYLMETHACRYLAMIDE CAS:50867-55-5 Fraction by Wt: 1-2.99% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS >5.00 G/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: MAY CAUSE MINIMAL EYE IRRITATION. BRIEF CONTACT MAY CAUSE SLIGHT SKIN IRRITATION. INHALATION MAY CAUSE TEMPORARY IRRITATION OF THE NOSE AND THROAT. NO ADVERSE EFFECTS HAVE BEEN DOCUMENTED IN HU MANS AS A RESULT OF CHRONIC EXPOSURE. Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1% OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN. Effects of Overexposure:EYES-MAY EXPERIENCE TEMPORARY DISCOMFORT. SKIN-LOCAL REDNESS AND SWELLING. INHALATION-HEADACHE, NAUSEA AND DROWSINESS. INGESTION-ABDOMINAL DISCOMFORT, NAUSEA AND DIARRHEA MAY OCCUR. Medical Cond Aggravated by Exposure:BECAUSE OF ITS IRRITATING PROPERTIES, REPEATED SKIN CONTACT MAY AGGRAVATE AN EXISTING DERMATITIS. ======================= First Aid Measures ======================= First Aid:EYES-FLUSH WITH WATER FOR SEVERAL MIN. GET MEDICAL AID. SKIN-WASH SKIN WITH PLENTY OF SOAP & WATER FOR SEVERAL MIN. GET MEDICAL AID. INGESTION-IF MORE THAN SEVERAL MOUTHFULS ARE SWALLOWED, GIVE 2 GLAS SES OF WATER (16 OZ). GET MEDICAL AID. INHALATION-REMOVE TO FRESH AIR. GET MEDICAL AID IF BREATHING BECOMES DIFFICULT OR RESPIRATORY IRRITATION PERSISTS. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:380F,193C Extinguishing Media:USE WATER SPRAY, DRY CHEMICAL, FOAM, OR CARBON DIOXIDE TO EXTINGUISH FLAMES. USE WATER SPRAY TO COOL FIRE EXPOSED CANS. Fire Fighting Procedures:WATER OR SPRAY MAY CAUSE FROTHING. NO SPECIAL EQUIPMENT OR PROCEDURES REQUIRED FOR FIREFIGHTERS. Unusual Fire/Explosion Hazard:HYDROGEN SULFIDE MAY BE RELEASED IF OVERHEATED. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. AVOID BREATHING VAPOR. WEAR APPROPIATE PERSONAL PROTECTIVE EQUIPMENT, INCLUDING RESPIRATORY PROTECTION. CONTAIN SPILL IF POSSIBLE. WIPE UP OR ABSORB ON SUITABLE MATERIAL AND SHOVEL UP PREVENT ENTRY INTO SEWERS & WATERWAYS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:MINIMUM FEASIBLE HANDLING TEMPERATURES SHOULD BE MAINTAINED. PERIOIDS OF EXPOSURE TO HIGH TEMPERATURES SHOULD BE MINIMIZED. AVOID WATER CONTAMINATION. Other Precautions:AVOID CONTACT WITH SKIN, EYES OR CLOTHING. UNDER EXTREME TEMPERATURES OR EXTENDED STORAGE PERIODS, HYDROGEN SULFIDE GAS MAY ACCUMULATE IN THE HEADSPACE OF THE CONTAINER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURE LIMITS ARE EXCEEDED, USE APPROPIATE NIOSH OR MSHA APPROVED AIR PURIFYING OR AIR SUPPLIED RESPIRATOR AFTER DETERMINING THE AIRBORNE CONCENTRATIONN OF THE CONTAMINANT. Ventilation:ADEQUATE TO MEET COMPONENT OCCUPATIONAL EXPOSURE LIMITS. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:SOILED WORK CLOTHING SHOULD BE LAUNDERED OR DRY CLEANED. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:V6 Spec Gravity:0.8927 Viscosity:9.1 CST Solubility in Water:NOT DETERMINED Appearance and Odor:DARK RED LIQUID. PETROLEUM OIL ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:TOXIC LEVELS OF CARBON MONOXIDE, CARBON DIOXIDE, IRRITATING ALDEHYDES & KETONES & COMBUSTION PRODUCTS OF ZINC, SULFUR. Conditions to Avoid Polymerization:DOES NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:THIS PRODUCT HAS BEEN EVALUATED FOR RCRA CHARACTERISTICS AND DOES NOT MEET THE CRITERIA OF A HAZARDOUS WASTE IF DISCARDED IN ITS PURCHASED FORM. UNDER RCRA IT IS THE RESPONSIBILITY OF THE USER TO DETE RMINE AT THE POINT OF DISPOSAL IF ITS HAZARDOUS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:0152, IRONCLAD CAGE:72674 CAGE:27674 CAGE:72674 ============= Composition/Information on Ingredients ============= Ingred Name:ING 6:ON CNS, HEMATOPOIETIC TISS,BLOOD, KIDNEYS & LIVER, ASSOC W/ADMIN OF ETHYLENE GLYCOL MONOBUTYL ETHER (EGBE).(ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: (EXTRACTED FROM DHHS (NIOSH) PUBLICATION NO. 90-118) . RTECS #:9999999ZZ Ingred Name:SPILL PROC: RINSE WELL WITH WATER. RTECS #:9999999ZZ Ingred Name:WASTE DISP METH: LOCAL, STATE AND FEDERAL AGENCIES FOR PROPER DISPOSAL METHOD IN YOUR AREA. RTECS #:9999999ZZ Ingred Name:OTHER PREC: MAY CAUSE FORMATION OF HCL AND/OR PHOSGENE . RTECS #:9999999ZZ Ingred Name:MINERAL SPIRITS CAS:64741-41-9 RTECS #:SE7555000 Fraction by Wt: 30-40% OSHA PEL:300 PPM ACGIH TLV:300 PPM Ingred Name:ETHANE, 1,1,1-TRICHLORO-; (METHYL CHLOROFORM) CAS:71-55-6 RTECS #:KJ2975000 Fraction by Wt: 10-20% OSHA PEL:350 PPM;450 STEL ACGIH TLV:350 PPM;450 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ozone Depleting Chemical:1 Ingred Name:ETHANOL, 2-BUTOXY-; (ETHYLENE GLYCOL MONOBUTYL ETHER) CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: <5% OSHA PEL:S, 50 PPM ACGIH TLV:S, 25 PPM; 9293 Ingred Name:SUPP DATA: HAVE PRDCED SENSIT OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIMILAR EFT IN HUMANS. (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4:ADRENOMIMETICS (E.G., EPINEPHRINE)MAY BE CONTRAINDICATED EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS ACUTELY/(ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: CHRONICALLY EXPOS TO CHLOROCARBONS . ANIMAL STUDIES CLEARLY DEMONSTRATED DOSE-RELATED ADVERSE EFTS (ING 7) RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:INHAL OF VAP CAN PRDCE CNS DEPRESS CHARACT BY DIZZ, HDCH, NAUS, CARD &/OR RESP DEPRESS, STUPOR, UNCON & DEATH, IN EXTREME CASES. EXPOS TO HIGH CONC OF VAPS BY DIRECT CONT/INHAL CAN BE IRRIT TO M UC MEMB, SUCH AS EYES & UPPER RESP TRACT. SEV EYE EXPOS TO LIQ CAN CAUSE REVERSIBLE EYE DMG. SKIN CONT (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:MAY CAUSE BURNING SENSATION & REDDENING OF SKIN. INTRODUCTION OF SOLV TO LUNGS,AS IN ASPIR OF VOMIT FLUIDS, MAY CAUSE CHEM PNEUM.INHAL OF AEROSOL MIST MAY PRDCE CHEM PNEUM. CHRONIC: RPTD/PRLN GD CONT BY INHAL/SKIN ABSORP MAY PRDCE LIVER/KIDNEY DMG/ DMG TO CNS(CHARACT BY TINGLING/NUMB IN EXTREM, BLURRED (SUPDAT) Medical Cond Aggravated by Exposure:EXPOSURE TO THIS PRODUCT MAY AGGRAVATE EXISTING RESPIRATORY AND CARDIAC CONDITIONS. ======================= First Aid Measures ======================= First Aid:SKIN: WASH CONTAM SKIN THORO WITH SOAP OR MILD DETERGENT. APPLY SKIN CREAM W/LANOLIN. GET MED ATTENTION IF IRRITATION PERSISTS. EYES: IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTE S, OCCAS LIFTING UPPER & LOWER LIDS. GET MED ATTN AT ONCE. INHAL: MOVE EXPOSED PERSON TO FRESH AIR AT ONCE. IF BRTHG HAS STOPPED, PERFORM ARTF RESP. GET MED ATTN IMMED. INGEST: CALL MD IMMED . ===================== Fire Fighting Measures ===================== Flash Point:FLAMMABLE Extinguishing Media:CO2, FOAM, DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA AND FULL PROTECTIVE EQUIPMENT . DIRECT WATER ONTO INTACT CONTAINERS. Unusual Fire/Explosion Hazard:CONTAINER MAY BURST IF HEATED ABOVE 120F. THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE HCL AND PHOSGENE . ================== Accidental Release Measures ================== Spill Release Procedures:OBSERVE SAFTEY PREC IN SPECIAL PROT & SPECIAL PREC DURING SPILL CLEAN-UP. LRG SPILLS ARE UNLIKELY DUE TO PACKAGING. SPILL MAY BE ABSORB ON AN INERT ABSORB (EG ZEP-O-ZORB), PLACED IN SUITABLE CNTNR FOR DISP. WASH AREA THORO W/DETERGENT SOLN& (ING 9) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:CONC VAP MAY IGNIT IF EXPOS TO SPARK. DO NOT STORE AT TEMP >120F/IN DIRECT SUNLIGHT. DO NOT PUNCTURE/INCIN CNTNR. KEEP OUT OF REACH OF CHILDREN. Other Precautions:KEEP PROD AWAY FROM SKIN & EYES.VAPS ARE HVR/AIR & WILL ACCUMULATE AT LOW POINTS.VENT SHOULD INCL FLOOR LEV EXHAUSTING. NO SMOKING IN AREA OF USE. DO NOT USE IN GEN VICINITY OF ARC WELDING, OPEN FLAME S/HOT SURFS. HEAT &/OR UV RADIA (ING 11) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENTILATION IS INADEQUATE, WEAR NIOSH/MSHA APPROVED PROPERLY FITTING RESPIRATOR. Ventilation:VENTILATION SHOULD BE EQUIVALENT TO OUTDOORS. USE EXHAUST FANS AND OPEN WINDOWS IN ENCLOSED SPACES. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING WITH MATERIAL. Supplemental Safety and Health EFTS OF OVEREXP: VISION/CONFUSN). SKIN WHICH IS DEFAT BY RPTD EXPOS TO SOLV,IS MORE SUSCEPTIBLE TO IRRIT, INFECTION,& DERM. ANIMAL STUDIES INDICATE POTNTL FOR LIVER, KIDNEY/RED BLOOD CELL DMG. RELEVAN CE OF THESE STUDIES/EXPOS LEVS WHICH MIGHT PRDCE EFTS IN HUMANS HAS NOT BEEN ESTABLISHED. CHLOROCARBON MATLS (ING 4) ================== Physical/Chemical Properties ================== HCC:V3 Boiling Pt:B.P. Text:313F,156C Vapor Pres:2 @ 20C Spec Gravity:0.84 Evaporation Rate & Reference:0.06 (TOLUENE=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:SLIGHTLY VISCOUS, TAN, OPAQUE LIQUID WITH SOLVENT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, AND ACIDS. Stability Condition to Avoid:HEAT. Hazardous Decomposition Products:CO2, CO, HCL, AND SMALL AMOUNTS OF PHOSGENE & CHLORINE GAS. ==================== Disposal Considerations ==================== Waste Disposal Methods:PROD IS CONSUMED IN USE.DO NOT CRUSH,PUNCTURE OR INCIN SPENT CNTNRS. LRG NUMBERS OF AEROSOL CNTNRS MAY REQ HNDLG AS HAZ WASTE, BUT IN MOST STATES TOTAL HAZ WASTE QTYS <220 LBS PER MONTH MAY ALLOW DISP IN CHEM/INDUST WASTE LANDFILL. CONSULT(ING 10)
1
gloves_mandatory
===================== Product Identification ===================== Product ID:WOC200131, WINTON OIL COLOURS COBALT BLUE H CAGE:03103 CAGE:03103 ============= Composition/Information on Ingredients ============= Ingred Name:NON HAZARDOUS INGREDIENTS. ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PROLONGED CONTACT WITH SKIN MAY CAUSE DERMATITIS. NAUSEA AND SICKNESS IF LARGE QUANTITIES INGESTED. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: WASH OUT WITH WATER FOR AT LEAST 15 MINUTES. SKIN: WASH WITH SOAP AND WATER. INHAL: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTIFICIAL RESPIRATION) CALL MD . INGEST: GIVE WATER TO DRINK. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:>230F,>110C Extinguishing Media:CARBON DIOXIDE OR DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . KEEP COOL. Unusual Fire/Explosion Hazard:BLACK SMOKE EVOLVED MAY AFFECT EYES AND LUNGS. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB ON INERT MATERIAL. DO NOT USE COTTON WASTE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM HEAT. Other Precautions:AVOID INGESTION. AVOID CONTACT WITH SKIN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Other Protective Equipment:USE BARRIER CREAMS. Work Hygienic Practices:NORMAL HYGIENE. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:>300F,>149C Spec Gravity:1-3 Solubility in Water:IMMISCIBLE Appearance and Odor:COLORED PASTE; CHARACTERISTIC VEGETABLE OIL ODOR. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES COMBUSTIBLE MATTER E.G., COTTON WASTE. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:ACROLEIN MAY BE EVOLVED IN FIRE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE ACCORDING TO LOCAL REGULATIONS. CONTROLLED LANDFILL. DISPOSE I/A/W ALL FEDERAL, STATE AND LOCAL REGULATIONS .
1
gloves_mandatory
===================== Product Identification ===================== Product ID:803 CROWN LATEX ARCHITECTURAL COATING CAGE:85207 CAGE:72556 CAGE:85207 ============= Composition/Information on Ingredients ============= Ingred Name:VOLATILE ORGANIC CONTENT: <200 G/L RTECS #:9999999VO Ingred Name:CALCIUM CARBONATE, DOMOLITE, LIMESTONE, WHITING *97-2* CAS:1317-65-3 RTECS #:EV9580000 Fraction by Wt: 5% Other REC Limits:5 MG/M3 RESP DUST OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/CUM TOTAL DUST Ingred Name:CRYSTALLINE-QUARTZ SILICA, SILICA DUST (SUSPECTED HUMAN CARCINOGEN BY IARC-GROUP 2A; SUSPECTED CARCINOGEN NTP) *97-2* CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: <5% Other REC Limits:0.05 MG/CUM (NIOSH) OSHA PEL:10 MG/CUM %RESP SIO2 ACGIH TLV:0.1 MG/CUM RESP DUST Ingred Name:SILICA CRYSTALLINE, SILICA (CRISTOBALITE) (SUSPECTED HUMAN CARCINOGEN BY IARC, SUSP CARC BY NTP; IARC GROUP 2A) *97-2* CAS:14464-46-1 RTECS #:VV7325000 Fraction by Wt: <5% Other REC Limits:0.05 MG/CUM NIOSH ACGIH TLV:0.05 MG/CUM Ingred Name:ETHYLENE GLYCOL *97-2* CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: <5% Other REC Limits:10 MG/CUM OSHA PEL:50 PPM ACGIH TLV:C 127 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ETHYLENE OXIDE (SUSP HUMAN CARCINOGEN BY ACGIH, IARC, SUSP CARC BY NTP; OSHA CANCER HAZARD; IARC - GROUP 1) *97-2* CAS:75-21-8 RTECS #:KX2450000 Fraction by Wt: <0.1% ACGIH TLV:1.8 MG/CUM (A2) EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:FORMALDEHYDE, FORMALIN (SUSPECTED HUMAN CARCINOGEN BY IARC; ACGIH; SUSPECTED CARCINOGEN BY NTP; IARC - GROUP 2A) *97-2* CAS:50-00-0 RTECS #:LP8925000 Fraction by Wt: <0.1% ACGIH TLV:0.37 MG/CUM IC (2A) EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:1,2-PROPANEDIOL (PROPYLENE GLYCOL) CAS:57-55-6 RTECS #:TY2000000 Fraction by Wt: <5% Ingred Name:AMORPHOUS SILICA GEL, SILICON DIOXIDE *97-2* CAS:7631-86-9 Fraction by Wt: 10% Ingred Name:PROPANOIC ACID, 2-METHYL, MONOESTER W/2,2,4-TRIMETHYL-1,3-PENTANEDIOL, TEXANOL(ESTER ALCOHOL) CAS:25265-77-4 RTECS #:UF6000000 Fraction by Wt: <5% Ingred Name:TITANIUM DIOXIDE, TITANIUM OXIDE (SUSPECTED ANIMAL CARCINOGEN, IARC GROUP 3)*97-2* CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 15% OSHA PEL:15 MG/CUM ACGIH TLV:10 MG/CUM (DUST) Ingred Name:VINYL ACETATE CAS:108-05-4 RTECS #:AK0875000 Fraction by Wt: <0.1% Other REC Limits:10 PPM ACGIH TLV:35 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:2-(2-BUTOXYETHYOXY)-ETHANOL, DIETHYLENE GLYCOL MONOBUTYL ETHER (BUTYL CARBITOL) *97-2* CAS:112-34-5 RTECS #:KJ9100000 Fraction by Wt: <5% ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT): 9500 MG/KG (SEE SUPP) Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:PRIMARY IRRITANT. HAZARDS OF INDIVIDUAL INGREDIENTS; EYE: IRIDOCYCLITIS, BURNS, POSSIBLE PERMANENT DAMAGE. SKIN: BURNS, DERMATITIS. INHALATION: LUNG INJURY, CNS DEPRESSION, SILICOSIS, PNEUMONIA, EDEMA . INGESTION: CNS EFFECTS, GI TRACT IRRITATION. ADVERSE REPRODUCTIVE EFFECTS & CHROMOSOME DAMAGE. (SEE SUPP) Explanation of Carcinogenicity:SEE INGREDIENTS Effects of Overexposure:IRRITATION, ECZEMA-LIKE CONDITION, DEFATTING, HEADACHE, NAUSEA, VOMITING, DIFFICULTY BREATHING, DIZZINESS, COUGH, CYANOSIS, DROWSINESS, PAIN, DIARRHEA, UNCONSCIOUSNESS Medical Cond Aggravated by Exposure:LUNG DISEASE, SKIN & RESPIRATORY CONDITIONS. ======================= First Aid Measures ======================= First Aid:INGESTION: DRINK 2 GLASSES OF WATER & INDUCE VOMITING BY PLACING FINGER AT BACK OF THROAT. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. INHALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. EY ES: FLUSH W/COOL WATER FOR 15 MINS. SKIN: WASH THOROUGHLY W/SOAP & WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:>200F Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:SOAK UP & REMOVE W/INERT ABSORBENT MATERIAL. PROVIDE ADEQUATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE APPROVED MECHANICAL RESPIRATOR OR MASK TO AVOID BREATHING SPRAY MISTS. Ventilation:PROVIDE SUFFICIENT VENTILATION IN VOLUME & PATTERN TO KEEP BELOW TLV. Other Protective Equipment:PROTECTIVE OVERALLS Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. DISCARD CONTAMINATED SHOES. Supplemental Safety and Health THIS IS A LATEX PAINT. PRIMARY HEALTH HAZARD IS POSSIBLE IRRITATION TO EYES & SKIN. HEALTH HAZARDS ARE FOR EACH INGREDIENT. LD50 INFORMATION IS FOR TITANIUM DIOXIDE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F Vapor Density:<1 Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:65 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:EXTREME HEAT Hazardous Decomposition Products:CO, CO2, NITROGEN OXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. DON'T INCINERATE IN CLOSED CONTAINERS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:TT-E-2784 Preparer's Name:ONEY FLEMING CAGE:JO954 CAGE:JO954 CAGE:39934 ============= Composition/Information on Ingredients ============= Ingred Name:PROPYLENE GLYCOL CAS:57-55-6 RTECS #:TY2000000 Fraction by Wt: 3.8% Other REC Limits:NONE RECOMMENDED Ingred Name:2,2,4-TRIMETHYL-1-3-PENTANEDIOL MONOISOBUTYRATE CAS:25265-77-4 RTECS #:UF6000000 Fraction by Wt: 3.51% Other REC Limits:NONE RECOMMENDED Ingred Name:DIMETHYLAMINOETHANOL LOW VOC CAS:108-01-0 RTECS #:KK6125000 Fraction by Wt: 0.22% Other REC Limits:NONE RECOMMENDED Ingred Name:2-N-OCTYL-4-ISOTHIAZOLIN-3-ONE CAS:26530-20-1 Fraction by Wt: 0.18% Other REC Limits:NONE RECOMMENDED Ingred Name:NON HAZARDOUS INGREDIENTS Fraction by Wt: 92.29% Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CAN CAUSE IRRITATION OF RESPIRATORY PASSAGES. Effects of Overexposure:INHALATION OF VAPOR/MIST CAN CAUSE HEADACHES, NAUSEA, IRRITATION OF NOSE/THROAT/LUNGS. EYES: CAN CAUSE SLIGHT IRRITATION. CHRONIC SKIN CONTACT CAN CAUSE SLIGHT IRRITATION. Medical Cond Aggravated by Exposure:PREEXISTING LUNG DISEASE MAY BE AGGRAVATED BY EXPOSURE. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/LARGE AMTS WATER 15 MINUTES. CONSULT DR. IF IRRITATION PERSISTS. SKIN: WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. INGESTION: GIVE 2 GLASSES WATER. CONSULT DR. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:>212F,>100C Lower Limits:NA Upper Limits:NA Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:WEAR SCBA (PRESSURE DEMAND MSHA/NIOSH APPROVED OR EQUIVALENT) & FULL PROTECTIVE GEAR. Unusual Fire/Explosion Hazard:MATERIAL CAN SPLATTER ABOVE 212F/100C. POLYMER FILM CAN BURN. ================== Accidental Release Measures ================== Spill Release Procedures:KEEP SPECTATORS AWAY. FLOOR MAY BE SLIPPERY. USE CARE TO AVOID FALLING. CONTAIN W/INERT MAT'L (SAND/EARTH). TRANSFER LIQ/SOLID DIKING MAT'L TO SEPARATE SUITABLE CONTAINERS FOR RECOVERY/DISPOSAL. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP FROM FREEZING. DO NOT TAKE INTERNALLY. KEEP AWAY FROM CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:APPROVED MECHANICAL FILTER RESPIRATOR TO REMOVE SOLID AIRBORNE PARTICLES OF OVER-SPRAY DURING SPRAY APPLICATION. Ventilation:NORMAL, SUCH AS FAN. Other Protective Equipment:EYEWASH STATION. Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212 TO 644F Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C Decomp Temp:Decomp Text:350F,177C Vapor Pres:NONE Vapor Density:>AIR Spec Gravity:1.13 VOC Pounds/Gallon:193 pH:9 MAX VOC Grams/Liter:1.61 Viscosity:77-95 KU Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:SLIGHT Appearance and Odor:GREEN LIQUID, SLIGHT ODOR Percent Volatiles by Volume:60.6 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN Stability Condition to Avoid:NONE Hazardous Decomposition Products:ACRYLIC MONOMERS ==================== Disposal Considerations ==================== Waste Disposal Methods:KEEP SPILLS/CLEANING RUN-OFF OUT OF SEWERS & OPEN BODIES OF WATER. CONSULT FEDERAL/STATE/LOCAL AUTHORITIES FOR PROPER DISPOSAL PROCEDURES CONCERNING HEALTH & ENVIRONMENT.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:1205 RAW SIENNA 100% ACRYLIC BASE ACRI-COLO Preparer's Name:LENY O. BALANGA CAGE:SINCL CAGE:SINCL ============= Composition/Information on Ingredients ============= Ingred Name:LEAD CAS:7439-92-1 RTECS #:OF7525000 Fraction by Wt: 0.0007% OSHA PEL:0.05 MG/M3 ACGIH TLV:0.15 MG/M3 DUST EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:UNDETERMINED. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:MAY CAUSE EYE, THROAT OR SKIN IRRITATION, HEADACHE AND NAUSEA OR DIZZINESS. Medical Cond Aggravated by Exposure:UNDETERMINED. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. EYES: WASH EXPOSED EYES WITH WATER FOR AT LEAST 15 MINUTES. SKIN: WASH EXPOSED SKIN WITH SOAP AND WATER. INGEST: DO NOT INDUCE VOMITING. CALL MD. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:CLOSED CONTAINERS CAN BUILD UP PRESSURE AND MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. WATER MAY BE HELPFUL IN COOLING UNRUPTURED CONTAINERS. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR SUITABLE CLOTHING. SPILLS MUST BE CLEANED UP IMMEDIATELY WITH ABSORBENTS SUCH AS CLAY, SAND OR OTHER SUITABLE MATERIALS. PLACE IN NON-LEAKING CONTAINERS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP COOL, DRY AND AWAY FROM EXCESSIVE HEAT & OPEN FLAMES. KEEP CONTAINER CLOSED AND UPRIGHT WHEN NOT IN USE. Other Precautions:AVOID EXCESSIVE OR UNNECESSARY PERSONNEL EXPOSURE. DO NOT TAKE INTERNALLY. USE WITH ADEQUATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AVOID EXCESSIVE VAPOR INHALATION. USE A NIOSH/MSHA APPROVED MECHANICAL FILTER TO REMOVE SOLID AIRBORNE PARTICLES DURING SPRAY APPLICATION. Ventilation:EXPLOSION PROOF. Other Protective Equipment:EYEWASHES AND SAFETY SHOWERS AS NEEDED. Work Hygienic Practices:MAKE USE OF PROTECTIVE CLOTHING WHILE WORKING. KEEP SURROUNDINGS AND EQUIPMENT CLEAN. Supplemental Safety and Health SPEC GRAVITY: 1205-1.35 +/- 0.05, 1202-1.17 +/-0.05, 1201-1.19 +/- 0.05. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:212F,100C Vapor Density:HVR/AIR Spec Gravity:SUPP DATA Evaporation Rate & Reference:SLOWER (BUTYL ACETATE=1) Solubility in Water:SOLUBLE Appearance and Odor:SIENNA, YELLOW AND BLACK NON-IRRITATING PAINTS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG ACIDS, BASES AND SELECTED AMINES. Stability Condition to Avoid:HEAT, OPEN FLAMES, SPARKS. Hazardous Decomposition Products:CO, CO2 AND UNIDENTIFIED ORGANIC COMPOUNDS. Conditions to Avoid Polymerization:OPEN FLAMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:PLACE IN NON-LEAKING CONTAINERS & DISPOSE IN ACCORDANCE WITH APPLICABLE LOCAL, COUNTY, STATE & FEDERAL REGULATIONS. BEFORE BEGINNING CLEAN UP, REFER TO ALL SECTIONS OF MSDS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:ALUMINUM OXIDE; P/N 90-5 CAGE:65024 CAGE:65024 ============= Composition/Information on Ingredients ============= Ingred Name:ALPHA-ALUMINA (ALUMINUM OXIDE) (SARA III) CAS:1344-28-1 RTECS #:BD1200000 Fraction by Wt: 96.4% % Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9394 Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 2.7% % Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9394 Ingred Name:SILICA GEL CAS:112945-52-5 RTECS #:VV7310000 Fraction by Wt: 0.5% % Other REC Limits:NONE RECOMMENDED OSHA PEL:6 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:MAGNESIUM OXIDE CAS:1309-48-4 RTECS #:OM3850000 Fraction by Wt: 0.2% % Other REC Limits:NONE RECOMMENDED OSHA PEL:10 MG/M3 PARTICULATE ACGIH TLV:10 MG/M3, FUME; 9394 Ingred Name:IRON OXIDE CAS:1309-37-1 RTECS #:NO7400000 Fraction by Wt: 0.1% % Other REC Limits:NONE RECOMMENDED OSHA PEL:10 MG/M3 (FE) ACGIH TLV:5MG(FE)/M3FUME,B2;94 Ingred Name:CALCIUM OXIDE CAS:1305-78-8 RTECS #:EW3100000 Fraction by Wt: 0.1% % Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 ACGIH TLV:2 MG/M3; 9394 ===================== Hazards Identification ===================== LD50 LC50 Mixture:TLV 10 MG/M3 (ALUMINUM OXIDE) Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EXPOSURE TO EXCESSIVE AIRBORNE CONCENTRATIONS MAY RESULT IN ACUTE RESPIRATORY DISORDERS. SYMPTOMS OF OVEREXPOSURE MAY INCLUDE IRRITATION OF EYES, EARS, NASAL PASSAGES AND RESPIRATORY TRACT. IRRITATIONOF THE SKIN MAY ALSO OCCUR. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:RESPIRATORY IRRITATIONS, EYE IRRITATION, EAR IRRITATION, NASAL IRRITATION, SKIN IRRITATION. Medical Cond Aggravated by Exposure:INDIVIDUALS WITH IMPAIRED PULMONARY FUNCTION SHOULD NOT BE SUBJECT TO EXCESSIVE AIRBORNE CONCENTRATIONS. ======================= First Aid Measures ======================= First Aid:REMOVE FROM EXPOSURE. IRRIGATE EYES AND SKIN WITH COPIOUS QUANTITIES OF WATER. SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Lower Limits:NOT GIVEN Upper Limits:NOT GIVEN Extinguishing Media:NONFLAMMABLE. USE MEDIA SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures:NONFLAMMABLE. USE PROCEDURES SUITABLE FOR SURROUNDING FIRE. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:NORMAL PRECAUTIONS FOR INERT OR NUISANCE DUST AND PARTICULATES. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE HANDLING PROCEDURES WHICH WILL LIMIT EXPOSURE TO EXCESSIVE AIRBORNE DUST. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVE RESPIRAATOR FOR NUISANCE DUST Ventilation:LOCAL EXHAUST Other Protective Equipment:ARM SLEEVES AND BARRIER CREAM FOR PREVENTION OF DERMATITIS. Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT AND BEFORE EATING DRINKING OR SMOKING. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:5400F,2982C Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN Vapor Pres:NOT GIVEN Vapor Density:NOT GIVEN Spec Gravity:3.5-4.0 Evaporation Rate & Reference:NIL Solubility in Water:INSOLUBLE Appearance and Odor:USUALLY BROWN CRYSTALLINE SOLID, NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:FERROX NON-SKID FLOOR AND DECK COATING CAGE:AMABR CAGE:AMABR ============= Composition/Information on Ingredients ============= Ingred Name:XYLENE (SARA 313) (CERCLA) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 25% OSHA PEL:100 PPM ACGIH TLV:100 PPM/150STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:2-PROPANOL, 1-METHOXY-; (PROPYLENE GLYCOL MONOMETHYL ETHER) CAS:107-98-2 RTECS #:UB7700000 Fraction by Wt: 2% OSHA PEL:100 PPM ACGIH TLV:100 PPM/150STEL Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (SILICON DIOXIDE, CRYSTALLINE) CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: 44% OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 RDUST ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION: DIZZINESS, UNCONSCIOUSNESS. SKIN: IRRITATION, SENSITIZATION. EYES: IRRITATION, EYE DAMAGE. Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ: IARC MONOGRAPHS, SUPPLEMENT, VOL 7, PG 341, 1987: GROUP 2A. NTP 7TH ANNUAL REPORT (SUP DAT) Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:RESPIRATORY DISEASES, SKIN CONDITIONS, KIDNEY OR LIVER DISEASE. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INHALATION: FRESH AIR, OXYGEN, ARTIFICIAL RESPIRATION. SKIN: WASH WITH SOAP AND WATER. INGESTION: DO NOT INDUCE VOMITING. CALL MD. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:81.0F,27.2C Lower Limits:1.1% Upper Limits:7.0% Extinguishing Media:CHEMICAL FOAM, DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR; MAY TRAVEL ALONG GROUND AND BE IGNITED BY FLAMES, SPARKS AND OTHER IGNITION SOURCES. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES (FLAMES, FLARES, PILOT LIGHTS, ELECTRICAL SPARKS). Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:WARNING! IRRITANT: DO NOT GET INTO EYES. AVOID CONT W/SKIN & CLTHG. AVOID INHAL OF VAPS/MIST. USE W/ADEQ VENT. Other Precautions:CAUTION: WHEN REMOVING OLD COATING BY SANDING/SANDBLASTING, WEAR PROPER NIOSH APPRVD DUST MASK TO AVOID INHAL OF SILICA DUST. AVOID EXTREME HEAT. KEEP AWAY FROM FLAME. DO NOT EXCEED 100F IN STORAGE AR EA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV'S ARE EXCEEDED, WEAR NIOSH APPROVED SCBA. Ventilation:LOCAL EXHAUST. SPECIAL VENT SUFFICIENT TO MAINTAIN LEVEL BELOW TLV'S. MECHANICAL (GENERAL) PREFERABLE. Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . TO PREVENT REPEATED OR PROLONGED (SUP DAT) Work Hygienic Practices:WASH THORO AFTER HNDLG, & BEFORE EATING, DRINKING/SMKNG. REMOVE CONTAM CLTHG & WASH BEFORE REUSE. (SUP DAT) Supplemental Safety and Health EXPLAN OF CARCIN: ON CARCINOGENS, 1994: ANTICIPATED TO BE CARCINOGEN. ANIMAL: LUNG. OTHER PROT EQUIP: SKIN CONTACT, WEAR PROTECTIVE CLOTHING. HYGIENE PRACT: DO NOT EAT OR SMOKE WHEN HANDLING. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:243F,117C Vapor Pres:8 @ 20C Vapor Density:3.7 Spec Gravity:1.65 (H*2O=1) Evaporation Rate & Reference:0.7 (BUTYL ACETATE=1) Solubility in Water:SLIGHT Appearance and Odor:VISCOUS PASTE, MILD ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, ALKALIES, AMINES, OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE, AND TOXIC FUMES WHEN BURNING. ==================== Disposal Considerations ==================== Waste Disposal Methods:ABSORB ON SAND, CLAY, OR OTHER ABSORBENT MATERIAL AND SHOVEL INTO CONTAINERS. DISPOSE BY CONTROLLED BURNING OR AUTHORIZED LANDFILL. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS ( ).
1
gloves_mandatory
===================== Product Identification ===================== Product ID:FLOOR CLEANER CAGE:ACEHA CAGE:ACEHA ============= Composition/Information on Ingredients ============= Ingred Name:BENZYLETHYLDIMETHYLAMMONIUM CHLORIDE; (QUATERNARY AMMONIUM CHLORIDE) CAS:5197-80-8 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:OCTYLPHENOXY POLYETHOXYETHANOL; (NONIONIC SURFACTANTS) CAS:9036-19-5 RTECS #:MD0907600 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:EYES:MAY CAUSE IRRITATION. SKIN:PROLONGED EXPOSURE MAY CAUSE IRRITATION. INGEST:MAY CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, DIARRHEA. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:FLUSH W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES HOLDING EYELIDS OPEN. SKIN:WASH W/MILD SOAP & WARM WATER. INGEST:D RINK 2 GLASSES OF WATER. DO NOT INDUCE VOMITING. CALL MD. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE MEDIA PROPER TO PRIMARY CAUSE OF FIRE. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:COLLECT & REUSE IF POSSIBLE, OR FLUSH TO SEWER, IF PERMITTED BY FEDERAL, STATE & LOCAL REGULATIONS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NORMAL GOOD HOUSEKEEPING TO PREVENT SPILLS. Other Precautions:KEEP OUT OF THE REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . NONE REQUIRED. Ventilation:MECHANICAL (GENERAL): SATISFACTORY. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . OTHER PROT CLTHG/EQUIP AS NEEDED TO (SUPDAT) Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health OTHER PROT EQUIP:PREVENT WETTING OF SKIN. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Vapor Pres:<30 Vapor Density:<1 Spec Gravity:1.025 (H*2O=1) pH:7 Evaporation Rate & Reference:<0.4 (BUTYL ACETATE=1) Solubility in Water:COMPLETE Appearance and Odor:CLEAR BLUE LIQUID; BLAND ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING MATERIALS. Hazardous Decomposition Products:NONE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER APPROVED BY ALL FEDERAL, STATE & LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:NITRIC ACID, A509 500 CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:NITRIC ACID (SARA 302/313) (CERCLA) CAS:7697-37-2 RTECS #:QU5775000 Fraction by Wt: 69-71% OSHA PEL:2 PPM ACGIH TLV:2 PPM/4 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:WATER. LD50: (ORAL,RAT) >90 ML/KG CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 29-31% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 2 Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYE: CAUSES SEVERE BURNS. MAY CAUSE IRREVERSIBLE EYE INJURY. SKIN: MAY CAUSE SEVERE IRRITATION. CAUSES BURNS. MAY CAUSE DEEP PENETRATING ULCERS OF SKIN. INGESTION: CAUSES GASTROINTESTINAL TRACT BURNS. MAY CAUSE PERFORATION OF DIGESTIVE TRACT. INHALATION: MAY BE FATAL. EFFECTS MAY BE DELAYED. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: MAY CAUSE IRRITATION OF RESPIRATORY TRACT WITH BURNING PAIN IN NOSE & THROAT, COUGHING, WHEEZING, SHORTNESS OF BREATH & PULMONARY EDEMA. CHRONIC: REPEATED INHALATION MAY CAUSE CHRONIC BRONCH ITIS. REPEATED EXPOSURE MAY CAUSE EROSION OF TEETH. TARGET ORGANS: NONE. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR @ LST 15 MINS, OCCASNLY LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. DO NOT ALLOW VICTIM TO RUB/KEEP EYES CLSD. SKIN: GET MED AID IMMED. FLUSH W/PLENTY OF SOAP & WA TER FOR @ LST 15 MINS WHILE REMOVING CONTAMD CLTHG & SHOES. WASH CLTHG BEFORE REUSE. INGEST: DO NOT INDUCE VOMIT. IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. NEVER GIVE (SUPDAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:SUBSTANCE IS NONCOMBUSTIBLE; USE AGENT MOST APPROPRIATE TO EXTINGUISH SURROUNDING FIRE. Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . STRONG OXIDIZER. CONT W/COMBUST MATLS MAY CAUSE FIRE. USE WATER SPRAY TO KEEP FIRE EXPOSED CONTAINERS COOL. Unusual Fire/Explosion Hazard:SUBSTANCE IS NONCOMBUSTIBLE. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROT EQUIP AS INDICATED. ABSORB SPILL W/INERT MATERIAL, (E.G., DRY SAND/EARTH), THEN PLACE INTO CHEMICAL WASTE CNTNR. NEUT SPILL W/SODIUM BICARBONATE. A VAPOR SUPPRESSING FOAM MAY BE USED TO REDUCE VAPORS. Neutralizing Agent:SODIUM BICARBONATE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A TIGHTLY CLOSED CONTAINER. STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES. Other Precautions:USE W/ADEQUATE VENTILATION. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. KEEP CONTAINER TIGHTLY CLOSED. DO NOT INGEST OR INHALE. DANGER! STRONG OXIDIZER. CONT W/OTHER MATL MAY CAUSE A FIRE. CORROSIVE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29CFR 1910.134. ALWAYS USE A NIOSH-APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE WITH ADEQUATE VENTILATION. Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . WEAR APPROP CLOTHING TO PREVENT SKIN EXPOSURE. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE CONTAMD CLOTHING & WASH BEFORE REUSE. Supplemental Safety and Health FIRST AID PROC: ANYTHING BY MOUTH TO UNCON PERSON. GET MED AID IMMED. INHAL: REMOVE TO FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYG. GET MED AID. NOTE TO PHYS: TREAT SYM PTOMATICALLY & SUPPORTIVELY. EYE PROT: & FULL LENGTH FACESHIELD . ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:187F,86C Melt/Freeze Pt:M.P/F.P Text:-44F,-42C Vapor Pres:6.8 Spec Gravity:1.50 pH:1.0 Evaporation Rate & Reference:NOT KNOWN Solubility in Water:SOLUBLE Appearance and Odor:CLEAR TO YELLOW LIQUID. STRONG ODOR, ACRID ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REACTS W/OVER 150 CHEM COMBINATIONS. REFER TO NFPA FIRE PROT GUIDE FOR SPECIFICS. REACTS EXPLO W/ORG MATLS & COMBUST. Stability Condition to Avoid:DECOMPOSES WHEN IN CONTACT W/AIR, LIGHT, OR ORGANIC MATTER. HIGH TEMPS, COMPAT MATLS, MOISTURE, REDUCING AGENTS. Hazardous Decomposition Products:NITROGEN OXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE, AND LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:HOT SOAK ALKALINE CLEANER Preparer's Name:AZ- TECH LABS CAGE:0DTK9 CAGE:0DTK9 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM METASILICATE (ANHYDROUS) CAS:6834-92-0 RTECS #:VV9275000 Ingred Name:PRIMARY SODIUM PHOPHATE,MONOBASIC,ANHYDROUS CAS:7558-80-7 RTECS #:WA1900000 Ingred Name:TRISODIUM PHOSPHATE,ANHYDROUS OSHA PEL:N?K Ingred Name:ANIONIC SURFACTANT Ingred Name:NON-IONIC SURFACTANTS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:ACUTE:SEVERE BURNS TO EYES AND SKIN,IRRITATIONS;CORNEAL DAMAGE POSSIBLE;DUST MAY CAUSE RESPIRATORY IRRITATION OR CHEMICAL PNEUMONIA IF LARGE QUANITY OF DUST INHALED. CHRONIC;NO DATA AVAILABLE. Explanation of Carcinogenicity:NO DATA AVAILABLE Effects of Overexposure:SEE HEALTH HAZARDS DATA. Medical Cond Aggravated by Exposure:PRE-EXISTING CONDITIONS MAY BE WORSEN. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH WITH WATER FOR 15 MINUTES AND SEEK MEDICAL HELP, SKIN:WASH THOROUGHLY WITH SOAP AND WATER AND RINSE WELL. INHALATION:REMOVE PERSONS TO FRESH AIR;USE CPR OR GET MEDICAL HELP. INGESTION:DO NO T INDUCE VOMITING,DRINK TWO GLASSES OF WATER AND GET MEDICAL, HELP AT ONCE. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:NON-FLAMMABLE;USE SUITABLE MEDIA FOR SURROUND FIRE. Fire Fighting Procedures:NONE NOTED. Unusual Fire/Explosion Hazard:NONE NOTED ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTION;SWEEP UP OR VACUUM AND RECOVER FOR PROPER DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL DRY AND WELL VENTILATED AREA:KEEP AWAY FROM MOISTURE;KEEP CONTAINER TIGHTLY CLOSED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR FOR DUST/MIST IF ABOVE PEL/TLV. Ventilation:LOCAL EXHAUST OR GENERAAL TO MAIN/TLV Other Protective Equipment:PROTECTIVE CLOTHING,EYE-WASH FACILITIES. Work Hygienic Practices:AVOID CONTACT WITH SKIN AND EYES;DO NOT BREATHE DUST/MIST. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Solubility in Water:GOOD Appearance and Odor:WHITE TO OFF WHITE POWDER WITH MILD ODOR Percent Volatiles by Volume:0.0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDANTS OR REDUCING AGENTS:ACID Stability Condition to Avoid:EXTREME HEAT. Hazardous Decomposition Products:NONE NOTED ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF COLLECTED MATERIAL IN ACCORDANCE WITH LOCAL STATE AND FEDERAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:TIGTECTIC 21 CAGE:72271 CAGE:72271 CAGE:5N977 ============= Composition/Information on Ingredients ============= Ingred Name:ALUMINUM (SARA 313) CAS:7429-90-5 RTECS #:BD0330000 Fraction by Wt: >90% OSHA PEL:15 MG/M3 DUST ACGIH TLV:10 MG/M3 DUST Ingred Name:SILICON CAS:7440-21-3 RTECS #:VW0400000 OSHA PEL:15 MG/M3 DUST ACGIH TLV:10 MG/M3 DUST Ingred Name:SUPDAT: AS NOTED ABOVE. REASONABLY EXPECTED CONSTITUENTS OF FUME MAY INCL COMPLEX OXIDES OF METALS LISTED. FLUX (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: COATINGS MAY PRDCE FLUORIDE CMPDS, METAL OXIDES, CARBON & SILICA. GASEOUS RXN PRODS MAY INCL OZONE, (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: CO, CO*2, NITROGEN OXIDES & CERTAIN INERT GASES USED AS SHIELDING GASES. OSHA SPECIFIES CHROMIUM VI CMPDS,(ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: NICKEL & ITS CMPDS MUST BE CONSIDERED AS CARCINS BECAUSE THEY ARE SO CLASSIFIED BY NTP/IARC. TO MFR (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: KNOWLEDGE THEIR ARE NO RELIABLE SCIENTIFIC STUDIES WHICH SHOW WORKERS EXPOSED TO ALLOYS CNTNG CHROMIUM/ (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: NICKEL RUN INCR RISK OF LUNG CANCER BECAUSE OF EXPOS TO FORMS OF NICKEL & CHROMIUM FOUND IN FUMES. ONE REC(ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: WAY TO DETERM COMPOSITION & QTY OF FUMES & GASES TO WHICH WORKERS ARE EXPOS IS TO TAKE AIR SAMPLE INSIDE (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: WORKER'S HELMET IF WORN/IN WELDER'S BRTHG ZONE. SEE ANSI/AWSF11 AVAIL FROM AMERICAN WELDING SOCIETY, P.O.(ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: BOX 351040, MIAMI, FL 33135. FOR MORE COMPLETE INFORMATION, CONTACT NECH . RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP: (IRON DEPOSITS IN LUNG). METAL FUME FEVER CAN BE CAUSED BY INHAL OF CERTAIN METALLIC CMPDS (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: DURING WELDING, HEATING, BRAZING, SOLDERING/CUTTING OPERATIONS. SYMPS ARE SIMILAR TO INFLUENZA TYPE (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13: SICKNESS INCL CHILLS, FEVER, HEAD & MUSCLE ACHE, TIGHTNESS OF CHEST, DRYNESS OF NOSE & MOUTH, MUSCULAR (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14: PAIN, NAUS & VOMIT. SYMPS USUALLY OCCUR W/IN SEVERAL HRS AFTER OVEREXP & MAY LAST 6-24 HRS. GEN NUISANCE(ING 16) RTECS #:9999999ZZ Ingred Name:ING 15: DUSTS: SKIN CONT HAS SHOWN POSS DRYING & MECH IRRIT. EYE CONT CAN PRDCE PARTICULATE IRRIT. EXCESS INHAL (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: CAN PRDCE MILD PULM IRRIT & POSS NONDISABLING SLIGHT FIBROSIS OF LUNGS. SILICON, SILICON OXIDES (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17: (AMORPHOUS SILICA): SHORT TERM OVEREXP MAY POSE AS POSS EYE IRRITANT. RPTD INHAL OF AMORPHOUS SILICA (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18: CAN CAUSE PNEUMOCONIOSIS OR NON DISABLING FIBROSIS OF LUNG. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: LOCAL POISON CONTROL CENTER. ADVISE OF INGREDIENTS LISTED IN SECTION 2. RTECS #:9999999ZZ Ingred Name:VENT: TRAIN WELDER TO KEEP HIS/HER FACE AWAY FROM FUME OR DUST PLUME. RTECS #:9999999ZZ Ingred Name:EYE PROT:. WEAR HELMET/USE FACE SHIELD W/APPROP FILTER LENS. PROIVDE PROT SCREENS & FLASH GOGGS IF NEC, TO(ING 23) RTECS #:9999999ZZ Ingred Name:ING 22: SHIELD OTHERS. AS RULE, START W/SHADE THAT IS TOO DARK TO SEE WELD ZONE, THEN GO TO NEXT LIGHTER SHADE (ING 24) RTECS #:9999999ZZ Ingred Name:ING 23: WHICH GIVES SUFFICIENT VIEW OF WELD ZONE. RTECS #:9999999ZZ Ingred Name:OTHER PROT EQUIP: SPKS, & ELEC SHOCK. FOR MORE SPECIFIC INFORMATION CONT NEHC RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: INHAL: FUMES ASSOC W/HEATING, WELDING, BRAZING, SOLDERING/CUTTING METALS CAN BE DANGEROUS TO YOUR HLTH & OVEREXP CAN CAUSE LUNG DMG AND/OR OTHER ORGAN DMG. EYE/SKIN: ARC RAYS & ULTRAVIOLET LIGH T CAN INJURE EYES & BURN SKIN. ELEC SHOCK CAN KILL. INGEST: DANGER! MAY BE HARMFUL/FATAL IF SWALLOWED. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: ELEC ARC WELDING, BRAZING, SOLDERING/THERM SPRAYING MAY CREATE 1/MORE OF FOLLOWING: FUMES, GASES & DUSTS CAN BE DANGEROUS TO YOUR HLTH. SHORT TERM OVEREXP MAY RSLT IN DIZZ, NAUS/DRYNESS OR I RRIT OF NOSE, THROAT OR EYES. EXCESS OVEREXP MAY CAUSE BRONCHIAL ASTHMA, LUNG FIBROSIS, PNEUMOCONIOSIS/SIDEROSIS(ING 12) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL OVEREXP: MOVE TO FRESH AIR SOURCE. CONT PHYS & ADVISE ON INGREDS IN SECTION 2. SKIN CONT: THORO WASH HANDS/EFFECTED AREAS W/SOAP & WATER TO REMOVE ALL RESIDUE. IF RASH/BURN DEVELOPS, CONSULT PHY S. EYE CONT: THORO FLUSH W/WATER FOR ATLST 15 MINS TO REMOVE ALL RESIDUE. OBTAIN PROMPT MED ADVICE FOR FLUXES & CHEM AIDS. ADVISE PHYS OF INGREDS IN SECTION 2. INGEST: CALL PHYS AND/OR (ING 20) ===================== Fire Fighting Measures ===================== Extinguishing Media:CO*2, DRY CHEMICAL FOAM TYPE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . TOXIC FUMES MAY BE PRODUCED. SEE HAZARDOUS DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:GENERALLY NONFLAMMABLE; WELDING ARC, SPARKS AND FLAMES CAN IGNITE COMBUSTIBLES AND FLAMMABLES. REFER TO ANSI Z49.1 FOR FIRE PREVENTION DURING USE OF (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:DISPOSE OF WASTE MATL, POWDERS/FILTER RESIDUES IN ENVIRONMENTALLY SENSITIVE MANNER I/A/W FEDERAL, STATE & LOCAL REGS. USE APPROP MEASURES TO KEEP AIRBORNE DUST LEVELS CONTAINED I/A/W EXPOS LEVELS OF I NGRED SECTION. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:PLEASE READ & UNDERSTAND PRODUCT LABEL INFORMATION FOR PROPER PROCEDURES AND USE. Other Precautions:SEE ANSI Z49.1 "SAFETY IN WELDING & CUTTING" & CHAPTER 11 OF "THERMAL SPRAYING" PUBLISHED BY AMERICAN WELDING SOCIETY & OSHA PUBLICATION 2206(29 CFR 1910) FOR MORE DETAIL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF WORK STATION IS NOT PROPERLY VENTILATED TO EXHAUST ALL FUMES, VAPORS AND DUSTS BELOW RECOMMENDED EXPOSURE LIMITS, USE A NIOSH APPROVED RESPIRATOR. Ventilation:USE ENOUGH GEN VENT & LOC EXHAUST @ WORK SITE TO KEEP ALL FUMES & DUST FROM WORKER'S BRTHG ZONE & GEN AREA. (ING 21) Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . WEAR HAND, HEAD, & BODY PROT WHICH HELP PVNT INJURY FROM RADIA, (ING 25) Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EXPLO HAZ: WELDING & ALLIED PROCESSES. SOME FLUXES & CHEMICAL AIDS MAY GIVE OFF HYDROGEN CHLORIDE, PHOSGENE & CHLORINE GASES. CANS UNDER PRESS & FLAMMS MAY EXPLODE. HAZ DECOMP PRODS: NORM OPERATION IN CL THOSE ORIGINATING FROM VOLAT RXN/OXIDATION OF MATLS SHOWN IN INGREDS PLUS THOSE OF BASE METAL & COATING, ETC (ING 3) ================== Physical/Chemical Properties ================== Evaporation Rate & Reference:NOT KNOWN Solubility in Water:NOT KNOWN Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:DUNNG WELDING FUME & GAS DECOMP PRODS GENERATED ARE DIFFERENT IN PERCENT & FORM FROM INGREDS. DECOMP PRODS OF (SUPDAT) ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS .
1
gloves_mandatory
======================================================= Product ID: 76 1991 B LAMP BLACK, 76-0001991 Cage: GO453 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 3D043 Cage: GO453 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: YES IARC: YES OSHA: NO Effects of Exposure: ACUTE: MAY CAUSE IRRIT OF GI TRACT, NOSE & THROAT IRRIT, LUNG IRRIT, EYE IRRIT, SKIN IRRIT, DELAYED EYE IRRIT, RESP TRACT IRRIT, NAUS & VOMIT. CHRONIC: PRLNG EXPOS TO RESP CRYSTALLINE QUARTZ (SILICA) MAY CAUSE DELAYED (CHRONIC) LUNG INJURY(SILICOSIS). CONTAINS INGS WHICH MAY CAUSE DERM, LIVER, KIDNEY, & NERV SYS DMG. Explanation Of Carcinogenicity: USERS OF THE "L" VERSION OF SHOULD CONSULT "LR" VERSION (INGREDIENT 10) FOR ADDITIONAL INFORMATION (FP N). Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. Medical Cond Aggravated By Exposure: ANY RESPIRATORY OR SKIN CONDITION. First Aid: EYES: FLUSH IMMEDIATELY WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES AND GET MEDICAL ATTENTION. SKIN: WASH THOROUGHLY WITH SOAP AND WATER. INHALATION: IF AFFECTED BY INHALATION OF VAPOR OR SPRAY MIST, REMOVE TO FRESH AIR. INGESTION: IF SWALLOWED, INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION IMMEDIATELY. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: VENTILATE AREA. REMOVE SPILLS WITH INERT ABSORBENT. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSE IN CHEMICAL DISPOSAL AREA OR IN A MANNER THAT COMPLIES WITH LOCAL, STATE, AND FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS. Handling And Storage Precautions: KEEP CONTAINERS CLOSED WHEN NOT IN USE. DO NOT STORE ABOVE 120F. KEEP FROM FREEZING. EMPTY CONTAINERS MAY CONTAIN PRODUCT RESIDUE. Other Precautions: DO NOT CUT, PUNCTURE OR WELD CONTAINERS. ALL LABEL WARNINGS MUST BE OBSERVED UNTIL CONTAINER HAS BEEN CLEANED, RECONDITIONED OR PROPERLY DISPOSED OF. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: TCC Flash Point Text: 240F,116C Lower Limits: 3.00% Upper Limits: 15.00% Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM, AND/OR WATER FOG. Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). CONTAINERS EXPOSED SHOULD BE COOLED WITH WATER SPRAY. Unusual Fire/Explosion Hazard: NONE. ======================================================= Control Measures ======================================================= Respiratory Protection: UNLESS AIR MONITORING DEMONSTRATES VAP/MIST LEVELS ABOVE APPLIC LIMITS, NO RESP IS REQUIRED. IF RESP IS REQUIRED, APPROP, PROPERLY FITTED RESP (NIOSH APPRVD) SHOULD BE WORN DURING APPLICATION. FOLLOW RESP MFR'S DIRECTIONS FOR RESP USE. Ventilation: REQUIRED WHEN SPRAYING OR APPLYING IN CONFINED AREA. Other Protective Equipment: EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA (FP N). USUAL CLOTHING FOR PAINTING OPERATIONS. Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health: NONE SPECIFIED BY MANUFACTURER. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: 212F,100C Vapor Pres: 24 @ 77F Vapor Density: 3.7 Spec Gravity: 1.33 Evaporation Rate & Reference: 0.4 (BUTYL ACETATE=1) Solubility in Water: NO Appearance and Odor: NORMAL FOR A COLORANT PRODUCT Percent Volatiles by Volume: 59.38 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE. Materials To Avoid: AVOID WATER-REACTIVE MATERIALS. Hazardous Decomposition Products: SILICON DIOXIDE, CARBON DIOXIDE/MONOXIDE, METAL OXIDES. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: 76 1991 B LAMP BLACK, 76-0001991 Cage: GO453 Assigned IND: Y Company Name: COLOR CORP OF AMERICA DIV OF VALSPAR Street: 1215 NELSON BLVD Zipcode: 00000-1104 Label Required IND: Y Date Of Label Review: 05/08/1998 Status Code: C Label Date: 05/08/1998 Origination Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Slight Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: COMBUSTIBLE. ACUTE: MAY CAUSE IRRITATION OF GASTROINTESTINAL TRACT, NOSE AND THROAT IRRITATION, LUNG IRRITATION, EYE IRRITATION, SKIN IRRITATION, DELAYED EYE IRRITATION, RESPIRATORY TRACT IRRITATION, NAUSEA AND VOMITING. CHRONIC: CANCER HAZARD. CONTAINS MATERIALS LISTED AS HUMAN AND ANIMAL LUNG CARCINOGENS (FP N). PROLONGED EXPOSURE TO RESPIRABLE CRYSTALLINE QUARTZ (SILICA) MAY CAUSE DELAYED (CHRO NIC) LUNG INJURY (SILICOSIS). CONTAINS INGREDIENTS WHICH MAY CAUSE DERMATITIS, AND LIVER, KIDNEY, AND NERVOUS SYSTEM DAMAGE. =======================================================
1
gloves_mandatory
======================================================= NIIN: 01-438-8978 Product ID: PPC DEVELOPER TYPE 1, 889455 Cage: RICOH Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 2Z665 Cage: RICOH ======================================================= Item Description Information ======================================================= Item Name: DEVELOPER,INDIRECT ELECTROSTATIC PROCESS ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: LD50:(ORAL) >5 G/KG BODYWEIGHT Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: YES OSHA: NO Effects of Exposure: ACUTE: EYES: MAY CAUSE TEMPORARY DISCOMFORT. SKIN: NON-IRRITANT. NO CORR/IRRITATING EFTS ARE EXPECTED FROM INTENDED USE AS DEVELOPER. INHAL: GASPING. INGEST: ACUTE OR TOX: >5 G/KG BODYWEIGHT. CHRONIC: PRLNGD INHAL OF EXCESS DUST MAY CAUSE LUNG DMG THAT IS ATTRIBUTED TO "LUNG OVERLOADING", A GENERIC (EFTS OF OVEREXP) Explanation Of Carcinogenicity: CARBON BLACK: IARC MONO ON EVAL OF CARCIN, RISK OF CHEMS TO MAN, VOL 65, PG 149, 1996: GROUP 2B. Signs And Symptions Of Overexposure: HLTH HAZ: RESPONSE TO EXCESS AMTS OF ANY DUST RETAINED IN LUNGS FOR PRLNGD INTERVAL. USE OF PROD AS INTENDED DOES NOT RSLT IN INHAL OF EXCESS DUST. CARCIN:IN 1996 IARC REEVALUATED CARBON BLACK AS GROU P 2B CARCIN (POSS HUMAN CARCIN) BASED ON RSLT OF INHAL STUDIES OF RATS. THIS WAS DETERM ON DEVELOPMENT OF LUNG (SUPDAT) Medical Cond Aggravated By Exposure: WILL NOT OCCUR. First Aid: EYES: TRY TO REMOVE WITH SOAP & WATER FOR @ LST 15 MINS. SKIN: WASH THOROUGHLY WITH SOAP AND WATER. INHALATION: REMOVE FROM EXPOSURE. INGESTION: DILUTE STOMACH CONTENTS WITH SEVERAL GLASSES OF WATER. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: IF SPILLED, SWEEP UP USING AN APPRVD TONER VACUUM CLEANER WITH .5 MICRON FILTER/SMALLER SUCH AS ATRIX AAA TONER VACUUM (RICH EPD CODE: 342MIU). USE VACUUM CLEANER NOT RATED FOR TONER PARTICULATE COULD BE POTNTL FIRE HAZARD AND/OR RESULT IN Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: USED DEVELOPER SHOULD BE DISPOSED OF IN AN ENVIRONMENTALLY SAFE MANNER & I/A/W FEDERAL, STATE, & LOCAL REGS. DISP REGS VARY FROM LOCALITY TO LOCALITY, THEREFORE, CONSULT LOCAL OFFICE OF EPA TO DETERM PROPER METH OF DISP. DO NOT INCIN LOOSE/ Handling And Storage Precautions: STORE IN A COOL, DRY PLACE. CLEANSE SKIN THOROUGHLY AFTER CONTACT, BEFORE BREAKS & MEALS, AND AT END OF WORK PERIODS. Other Precautions: DO NOT HANDLE IN WINDY AREAS. FLYING POWDER MAY ENTER EYES. MINIMIZE INHALATION OF DUST. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: CARBON DIOXIDE, DRY CHEMICALS, FOAM OR WATER SPRAY MAY BE SUITABLE. Fire Fighting Procedures: NO SPECIAL FIRE-FIGHTING PROCEDURE IS NECESSARY. USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: AIRBORNE DISPERSAL OF MOST FINELY DIVIDED ORGANIC POWDERS SUCH AS DEVELOPER MAY FORM AN EXPLOSIVE MIXTURE. DO NOT INCINERATE LOOSE OR SPILLED DEVELOPER. ======================================================= Control Measures ======================================================= Respiratory Protection: NONE NEEDED UNDER NORMAL CONDITIONS OF USE. NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N). Ventilation: MECHANICAL (GENERAL): ADEQUATE VENTILATION. Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N). Work Hygienic Practices: CLEANSE SKIN THOROUGHLY AFTER CONT, BEFORE BREAKS & MEALS, AND @ END OF WORK PERIODS. KEEP OUT OF REACH OF CHILDREN. Supplemental Safety and Health: USERS OF "L" VERSION OF SHOULD CONSULT "LR" VERSION FOR ADDNL INFO (FP N). EFTS OF OVEREXP:TUMORS IN RATS RECEIVING CHRONIC (LG AMTS OVER LONG PERIOD OF TIME) INHAL EXPOS OF FREE CARBON BLACK @ L EVELS THAT INDUCE PARTICLE OVERLOAD OF LUNGS. THERE WERE NO OBSERVED INCIDENCE OF TUMORS IN EITHER DERM/ORAL ======================================================= Physical/Chemical Properties ======================================================= Spec Gravity: 4.8 Appearance and Odor: BLACK POWDER WITH SLIGHT PLASTIC ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Hazardous Decomposition Products: CARBON MONOXIDE AND OTHER DECOMPOSITION PRODUCTS IN THE CASE OF INCOMPLETE COMBUSTION. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Trans ID NO: 136775 Product ID: PPC DEVELOPER TYPE 1, 889455 Review Date: 06/01/1998 Multiple KIT Number: 0 Review IND: Y ======================================================= Detail DOT Information ======================================================= DOT PSN Code: ZZZ DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail IMO Information ======================================================= IMO PSN Code: ZZZ IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION ======================================================= Detail IATA Information ======================================================= IATA PSN Code: ZZZ IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail AFI Information ======================================================= AFI PSN Code: ZZZ AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= HAZCOM Label ======================================================= Product ID: PPC DEVELOPER TYPE 1, 889455 Cage: RICOH Assigned IND: Y Company Name: RICOH CORP Street: 5 DEDRICK PLACE Zipcode: 07006 Label Required IND: Y Date Of Label Review: 12/15/1997 Status Code: C Label Date: 12/15/1997 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE: EYES: MAY CAUSE TEMPORARY DISCOMFORT. SKIN: NON-IRRITANT. NO CORROSIVE OR IRRITATING EFFECTS ARE EXPECTED FROM INTENDED USE AS DEVELOPER. INHAL: GASPING. INGEST: ACUTE OR TOXICITY: >5 G/KG BODY WEIGHT. CHRONIC: CANCER HAZARD. CONTAINS CARBON BLACK WHICH IS LISTED AS AN ANIMAL LUNG CARCINOGEN (FP N). PROLONGED INHALATION OF EXCESSIVE DUST MAY CAUSE LUNG DAMAGE THAT IS ATTRIBUTED TO "LUNG OVER LOADING", A GENERIC RESPONSE TO EXCESSIVE AMOUNTS OF ANY DUST RETAINED IN THE LUNGS FOR A PROLONGED INTERVAL. =======================================================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:CAN DO HEAVY DUTY ENAMEL, 300 AB CAGE:HO230 CAGE:6F145 CAGE:HO230 ============= Composition/Information on Ingredients ============= Ingred Name:STODDARD SOLVENT; (MINERAL SPIRITS). CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: 34-40% Other REC Limits:125 PPM (MFR) OSHA PEL:100 PPM ACGIH TLV:100 PPM ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:DATA AVAIL FOR SIMILAR MATL INDICATES THAT THIS MATL IS NOT EXPECTED TO BE ACUTELY TOXIC. SIGNS/SYMPS OF CNS DEPRESS MAY INCLUDE ONE/MORE OF THE FOLLOWING:HDCH, DIZZ, LOSS OF APPETITE, WEAKNESS, & LOS S OF COORDINATION. EFFTD PERSONS WILL EXPERIENCE COMPLETE RECOVERY WHEN REMOVED FROM AREA. Explanation of Carcinogenicity:NONE SPECIFIED BY MANUFACTURER. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST:DO NOT INDUCE VOMITING. CALL MD IMMED. INHAL:MOVE THE PERSON TO FRESH AIR. IF BREATHING HAS STOPPED, APPLY ARTIFICIAL RESPIRATION. CALL A MD IMMED. EYES:RINSE WITH WATER FOR AT LEAST 15 MINUTES . SKIN:WASH THOROUGHLY WITH SOAP AND WATER. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:105F,41C Lower Limits:1% Upper Limits:6% Extinguishing Media:CO*2, DRY CHEMICAL, FOAM, WATER SPRAY. Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:LIQUID EVAP & FORMS VAP (FUMES) WHICH CAN CATCH FIRE & BURN W/EXPLO VIOLENCE. INVISIBLE VAP SPREADS EASILY & CAN BE SET ON FIRE BY MANY SOURCES SUCH AS (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP SPILLS AS SOON AS POSSIBLE. ABSORB LG SPILLS WITH ABSORBENT CLAY, DIATOMACEOUS EARTH, OR OTHER SUITABLE MATL. A FIRE OR VAPOR HAZ MAY EXIST SINCE THESE CLEANUP MATERIALS WILL ONLY ABSORB LIQU ID THEY WILL NOT ABSORB VAPOR. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE OR USE NEAR FLAME, SPARKS, OR HOT SURFACES. USE ONLY IN WELL-VENTILATED AREA. Other Precautions:KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR AN NIOSH/MSHA APPRVD RESPIR PROT SUCH AS ORG VAP CARTRIDGE RESPIR/AIR-SUPPLYING RESPIR UNLESS VENT EQUIP IS ADEQUATE TO KEEP AIRBORNE CONCENTRATIONS BELOW THE EXPOS STANDARD. Ventilation:LOCAL EXHAUST:PROVIDE VOLUME TO PREVENT VAPOR CONCENTRATION IN EXCESS OF TLV. Other Protective Equipment:ANSI APPRVD EYE WASH FACILITIES SHOULD BE ACCESSIBLE IN THE WORK AREA. SOLVENT RESISTANT CLOTHING IF NEEDED TO (SUPP) Work Hygienic Practices:INDIVIDUALS WORKING W/THIS MATL SHOULD WASH HANDS THORO BEFORE EATING, DRINKING, SMOKING/USING TOILET FACILITIES. Supplemental Safety and Health VP:5MM HG @77F. EXPLO HAZ:PILOT LIGHTS, WELDING EQUIP, & ELECTRICAL MOTORS & SWITCHES. FIRE HAZ IS GREATER AS LIQUID TEMPERATURE RISES ABOVE 85F. OTHER PROT EQUIP: AVOIDSKIN CONTACT. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>314F,>157C Vapor Pres:SUPP DATA Vapor Density:4.9 Spec Gravity:1.(H*20=1) Evaporation Rate & Reference:0.13 (BUAC=1) Appearance and Odor:OPAQUE LIQUID, PETROLEUM DISTILLATE ODOR. Percent Volatiles by Volume:50 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MAY REACT WITH STRONG OXIDIZING MATERIALS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NORMAL COMBUSTION FORMS CARBON DIOXIDE AND WATER VAPOR; INCOMPLETE COMBUSTION CAN PRODUCE CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF MATL IN APPROVED LOCAL, FED, OR STATE FACILITY FOR HANDLING HAZ WASTE.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:MIL-L-6082, GRADE 1100 (BASE OIL) CENTER(JOAP-TSC Preparer's Name:DIRECTOR, JOAP-TSC CAGE:UO325 CENTER(JOAP-TSC CAGE:UO325 ============= Composition/Information on Ingredients ============= Ingred Name:BASE METALS: AG, AL, B, CU, CR, FE, MG, NI, NA, PB, SI, SN, TI, ZN, MO. = Wt:.03 ===================== Hazards Identification ===================== LD50 LC50 Mixture:RAT ORAL LD50: 29000 MG/KG Health Hazards Acute and Chronic:THIS PRODUCT MAY BE IRRITATING TO THE EYES AND MAY CAUSE SLIGHT SKIN IRRITATION. Effects of Overexposure:BECAUSE OF THE LOW LEVEL OF TOXICIT ASSOCIATED WITH THESE SAMPLES, OVEREXPOSURE IS UNLIKELY. ======================= First Aid Measures ======================= First Aid:REMOVE FROM EXPOSURE SITUATION, WASH EYES 15 MINUTES WITH CLEAR WATER, SEE PHYSICIAN. WASH SKIN WITH SOAP AND WATER. CONSULT PHYSICIAN IF INGESTED. DO NOT INDUCE VOMITING. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:=215.6C, 420.F Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:TREAT AS AN OIL SPILL. CLEAN WITH TOWEL OR RAG. DISPOSE OF RAG IN TRASH. DO NOT STORE WITH OXIDIZERS. FLOOR MAY BE SLIPPERY. DETERGENT WASH MAY BE REQUIRED. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE WITH OXIDIZERS. NORMAL GOOD HOUSEKEEPING PROCEDURES. Other Precautions:EXHAUST SYSTEM SHOULD BE IN PROPER WORKING ORDER TO FURNISH NORMAL WORKPLACE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORMALLY NEEDED UNLESS OIL MIST OCCURS THEN USE DUST/MIST CARTRIDGE. Ventilation:NOTHING BEYOND NORMAL VENTILATION. Supplemental Safety and Health CHEMICAL NAME & SYNONYMS: D12-300, -100, -50, -30, -10, -5, D-19-0, D3-100 OIL STANDARD. SPECIFICATION NUMBER: MIL-L-6082, GRADE 1100 (BAS EOIL). CHEMICAL FAMILY: METALLO-ORGANIC SULFONATES & MINERAL OIL. FORMULA: RNC6H5-NSO3M R-ALKYL GROUPS, M-METAL. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:VERY HIGH RANGE Vapor Pres:NIL Vapor Density:UNK Spec Gravity:0.9119 Evaporation Rate & Reference:NIL Solubility in Water:NIL Appearance and Odor:D19-0 IS GOLDEN BROWN, AMBER TO PEALESCENT BLACK COLOR, LUBE OIL ODOR Percent Volatiles by Volume:NIL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES DO NOT MIX WITH STRONG OXIDIZERS. Hazardous Decomposition Products:PARTIALLY BURNED HYDROCARBONS, METAL OXIDES. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:SMALL SPILL RESIDUES OF THESE PRODUCTS ARE NOT CONSIDERED HAZARDOUS AND MAY E DISCARDED AS TRASH. ===================== Regulatory Information ===================== Federal Regulatory Information:THIS PRODUCT IS NOT HAZARDOUS AS DEFINED BY THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200). MIL-L-6082, GRADE 1100 OIL REPRESENTS 99+% OF THE TOTAL VOLUME. ======================= Other Information =======================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:147 7280,89016EG Preparer's Name:NOT PROVIDED CAGE:19139 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:SILICA (AMORPHOUS) CAS:7631-86-9 < Wt:1. Other REC Limits:NOT PROVIDED OSHA PEL:NONE ACGIH TLV:NONE Ingred Name:STYRENE ACRYLATE COPOLYMER CAS:60806-47-5 < Wt:1. Other REC Limits:NOT PROVIDED OSHA PEL:NONE ACGIH TLV:NONE Ingred Name:POLYMER WITH 2-(METHYLAMINO)ETHANOL AND HEXANEDIOIC ACID CAS:124350-34-1 < Wt:1. Other REC Limits:NOT PROVIDED OSHA PEL:NONE ACGIH TLV:NONE ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT PROVIDED Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EFFECTS OF EXPOSURE: INHALATION: EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED HANDLING. EYES: NO SPECIFIC HAZARD KNOWN. MAY CAUSE TRANSIENT IRRITATION. SKIN: EXPECTED TO BE A LOW HAZARD FOR RECOMMENDE D HANDLING. INGESTION: EXPECTED TO BE A LOW INGESTION HAZARD. Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION (COMPONENTS PRESENT AT 0.1% OR MORE): INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC): NONE. AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): NONE. NATIONAL TOXICOLOGY PROGRAM (NTP): NONE. OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA): NONE. Effects of Overexposure:EYES: MAY CAUSE TRANSIENT IRRITATION. Medical Cond Aggravated by Exposure:NOT PROVIDED ======================= First Aid Measures ======================= First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES: ANY MATERIAL THAT CONTACTS THE EYE SHOULD BE WASHED OUT IMMEDIATELY WITH WATER. GET MEDICAL ATTENTION I F SYMPTOMS OCCUR. SKIN: WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. INGESTION: DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOU S PERSON. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY, CARBON DIOXIDE (CO2), DRY CHEMICAL Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:POWDERED MATERIAL MAY FORM EXPLOSIVE DUST-AIR MIXTURES. ================== Accidental Release Measures ================== Spill Release Procedures:DO NOT USE A VACUUM CLEANER TO CLEAN UP SPILLS OF POWDERED TONERS. THE VERY FINE PARTICLES CAN CAUSE A FIRE OR EXPLOSION. SWEEP MATERIAL ONTO PAPER AND PLACE IN A FIBER CARTON. CLEAN SURFACE THOROUGH LY TO REMOVE RESIDUAL CONTAMINATION. AVOID GENERATION OF DUST. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. KEEP FROM CONTACT WITH OXIDIZING MATERIALS. KEEP AWAY FROM SOURCES OF IGNITION. Other Precautions:AVOID BREATHING DUST. AVOID CONTACT WITH EYES AND PROLONGED OR REPEATED CONTACT WITH SKIN. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. POWDERED MATERIAL MAY FORM EXPLOSIVE DUST-AIR MIXTURES. MINIMIZE DUST GENERATION AND ACCUMULATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. Other Protective Equipment:EYE BATH, SAFETY SHOWER, WASHING FACILITIES Work Hygienic Practices:IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO MINIMIZE EYE CONTACT. IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO MINIMIZE SKIN CONTACT. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:NOT RELEVANT Melt/Freeze Pt:M.P/F.P Text:NOT AVAILABLE Decomp Temp:Decomp Text:NOT PROVIDED Vapor Pres:NEGLIGIBLE Spec Gravity:NOT AVAILABLE Viscosity:NOT RELEVANT Evaporation Rate & Reference:NEGLIGIBLE Solubility in Water:INSOLUBLE Appearance and Odor:WHITE POWDER, SLIGHT ODOR Percent Volatiles by Volume:NEGLIGIBLE Corrosion Rate:NOT PROVIDED ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:NOT PROVIDED Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE =================== Toxicological Information=================== Toxicological Information:EFFECTS OF EXPOSURE: INHALATION: EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED HANDLING. EYES: NO SPECIFIC HAZARD KNOWN. MAY CAUSE TRANSIENT IRRITATION. SKIN: EXPECTED TO BE A LOW HAZARD FOR RECOMMENDE D HANDLING. INGESTION: EXPECTED TO BE A LOW INGESTION HAZARD. ===================== Ecological Information ===================== Ecological:IT IS EXPECTED TO HAVE THE FOLLOWING PROPERTIES: IT IS A HIGH MOLECULAR WEIGHT POLYMER WITH A VERY LOW WATER SOLUBILITY. AS SUCH, IT IS EXPECTED TO HAVE A LOW BIOCHEMICAL OXYGEN DEMAND AND TO CAUSE ES SENTIALLY NO OXYGEN DEPLETION IN AQUATIC SYSTEMS. IT IS EXPECTED TO HAVE A LOW POTENTIAL TO AFFECT AQUATIC ORGANISMS, SECONDARY WASTE TREATMENT MICROORGANISMS AND THE GERMINATION AND EARLY GROWTH OF P LANTS. IT IS EXPECTED TO BE NONBIODEGRADABLE AND UNLIKELY TO BIOCONCENTRATE. WHEN FLUSHED TO SECONDARY WASTE TREATMENT BY A LARGE AMOUNT OF WATER, THIS MATERIAL IS NOT EXPECTED TO CAUSE ADVERSE ENVIRO NMENTAL EFFECTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE, OR LOCAL LAWS. INCINERATE OR LANDFILL. =================== MSDS Transport Information =================== Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS 722-1732. ===================== Regulatory Information ===================== SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART 372: NONE Federal Regulatory Information:NOT PROVIDED State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER: NONE. MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE ======================= Other Information =======================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:ONE-COAT LETTERING ENAMELS, WHITE 412-0101 CAGE:AKZNB CAGE:AKZNB Contract Num:N00406-98-M-R436 CAGE:00L47 ============= Composition/Information on Ingredients ============= CAS:7440-48-4 RTECS #:GF8750000 = Wt:.02 Other REC Limits:N/K OSHA PEL:0.1 MG/M3 OSHA STEL:N/K ACGIH TLV:0.02 MG/M3 ACGIH STEL:N/K Ingred Name:METHYL ETHYL KETOXIME; VP: 2.0; LD50 (ORAL RAT): 930 MG/M3 CAS:96-29-7 RTECS #:FL9275000 = Wt:.2 Other REC Limits:N/K OSHA PEL:N/K OSHA STEL:N/K ACGIH TLV:N/K ACGIH STEL:N/K CAS:14808-60-7 RTECS #:VV7330000 < Wt:.01 Other REC Limits:N/K OSHA PEL:see Table Z-3 OSHA STEL:N/K ACGIH TLV:0.1 MG/M3 ACGIH STEL:N/K Ingred Name:STODDARD SOLVENT; VP: 2.0; LEL: 1%. CAS:8052-41-3 RTECS #:WJ8925000 Minumum % Wt:20. Maxumum % Wt:40. Other REC Limits:N/K OSHA PEL:2900 MG/M3;500 PPM OSHA STEL:N/K ACGIH TLV:525 MG/M3;100 PPM ACGIH STEL:N/K Ingred Name:LEAD; VP: N/A; LD50 (ORAL RAT): 7000 MG/M3 CAS:7439-92-1 RTECS #:OF7525000 = Wt:.2 Other REC Limits:N/K OSHA PEL:0.05 MG/M3 OSHA STEL:N/K ACGIH TLV:0.15 MG/M3 ACGIH STEL:N/K EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB CAS:1333-86-4 RTECS #:FF5800000 Minumum % Wt:1. Maxumum % Wt:5. Other REC Limits:N/K OSHA PEL:3.5 MG/M3 OSHA STEL:N/K ACGIH TLV:3.5 MG/M3 ACGIH STEL:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENTS. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHAL: NASAL & RESP IRRIT, DIZZ, WEAK, FATG, NAUS, HDCH, POSS UNCON, CHEM PNEUMIT, CNS DEPRESS & EVEN ASPHY. SKIN: EXTRACTION OF NATRL OILS W/RSLTG DRY SKIN, IRRIT, REDNESS & DERM. SOME SOLVSMAY PASS THRU SKIN INTO BLOOD. EYES: IRRIT, REDNESS, PAIN, BLURRED VISION, SENSATION OF SEEING HALOS AROUND LIGHTS & REVERSIBLE DMG. INGEST: GI IRRIT, NAUS, VOMIT & DIARR. CHRONIC: INHAL: DELAYED LUNG DMG, KIDNEY, LIVER, & CARD DISORDERS, RED BLOOD CELL & LEUKOCYTE DISORDERS WHICH MAY RSLT IN ANEMIA.SKIN: SENSIT MAY OCCUR. INGEST: KIDNEY DMG, BLOOD SYS DMG. (EFTS OF OVEREXP) Explanation of Carcinogenicity:CARBON BLACK: IARC MONOGRAPHS, SUPPLEMENT, VOLUME 65, PAGE 149, 1996: GROUP 2B. ANIMAL: LUNG. Effects of Overexposure:HLTH HAZ: INTENTIONAL MISUSE BY DELIB CONCENTRATING & INHALING CONTENTS MAY BE HARMFUL/FATAL. RPTS HAVE ASSOC RPTD & PRLNG OCCUP OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS DMG. RPTD INTAKE OF LEAD BY INHAL &/OR INGEST MAY CAUSE LEAD POIS, BIRTH DEFECTS, ANEMIA & KIDNEY DMG. LEAD APPEARS ON THE NAVY OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS LIST. SEEK CONSULTATION FROM APPROPRIATE HEALTH PROFESS IONALS CONCERNING LATEST HAZARD LIST INFORMATION AND SAFE HANDLING AND EXPOSURE INFORMATION . Medical Cond Aggravated by Exposure:PULMONARY CONDITIONS, SKIN DISORDERS. ======================= First Aid Measures ======================= First Aid:IN ALL CASES, IF SYMPTOMS PERSIST, SEEK MEDICAL ATTENTION. INHALATION: MOVE TO FRESH AIR, GIVE ARTIFICIAL RESPIRATION IF NECESSARY.SKIN: REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER OR R ECOGNIZED SKIN CLEANER.DO NOT USE SOLVENTS OR THINNERS. EYES: CONTACT LENSES MUST BE REMOVED. FLUSH WITH WATER FOR AT LEAST 15 MINUTES. CONSULT MD IMMEDIATELY. INGESTION: DRINK ONE OR TWO GLASSE S OF WATER TO DILUTE. DO NOT INDUCE VOMITING. CONSULT MD OR POISON CONTROL CENTER IMMEDIATELY. TREAT SYMPTOMATICALLY. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:>33.9C, 93.F 93-107F(34-42C) Lower Limits:0.6% Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL OR WATER FOG OR SPRAY. WATER JET OR STREAM IS UNSUITABLE. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . WATER SHOULD BE USED TO COOL CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:NFPA FLAMMABILITY: IC & II. KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELEC EQUIP, SPARKS & OPEN FLAME. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. FIRE WILL PRODUCE DENSE B LACK SMOKE CONTAINING HAZARDOUS PRODS OF COMBUSTION. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT. OBTAIN MED ATTENTION. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. AVOID BREATHING VAPORS, VENTILATE CONFINED AREA.DIKE TO REDUCE EXTENT OF SPILL. REMOVE WITH INERT ABSORBENT USING NON-SPARKING TOOLS. IF NECESSARY REPORT TO APPLIC ABLE GOVERNMENT AGENCY. ======================Handling and Storage ====================== Handling and Storage Precautions:USE APPRVD BONDING & GROUNDING PROC WHEN TRANSFERRING LIQ TO ANOTHER CONTR. DO NOT TRANSFER TO UNLABELLED CONTRS.NO SMKNG. STORE CONTRS OUT OF SUN & AWAY FROM HEAT, SPKS, & OPEN FLAMES.CLOSE ALL CONTRS AFTER EACH USE. CONSULT NFPA & LOC CODES FOR ADDITIONAL STOR REQS. Other Precautions:VAPS ARE HVR/AIR & MAY TRAVEL ALONG FLOORS. USE EXPLO PROOF EQUIP IN AREAS WHERE THERE IS SPRAYING/OPEN CONTRS. DO NOT TAKE INTERNALLY. OBSERVE LABEL PREC. KEEP CLOSURES TIGHT & CONTR UPRIGHT TO P VNT LEAKAGE. AVOID BRTHG SANDING DUST. INFO CONTAINED IN THIS MSDS DOES NOT CONSTITUTE THE USER'S O WN(SUP DAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ADEQ VENT REQUIRED. WHEN PERS, WHETHER SPRAYING/NOT, ARE INSIDE SPRAY BOOTH, VENT IS UNLIKELY TO BE SUFFICIENT TO CTL PARTICULATES & CHEM VAP IN ALL CASES. IN SUCH CASES NIOSH APPRVD AIR SUPPLIED RE SP EQUIP IS REC UNTIL PARTICULATE & VAP CONC HAS FALLEN BELOW EXPOS LIMS. IF MONITORING DEMONSTRATES LEVELS BELOW TLV/PEL WEAR NIOSH APPRVD RESP. (OTHER INFO) Ventilation:PROVIDE SUFFICIENT VENTILATION TO KEEP VAPOR CONCENTRATION BELOW TLV &/OR PEL. FOR BAKING FINISHES, EXHAUST VAPORS EMITTED DURING HEATING. (OTHER INFO) Other Protective Equipment:ANSI APPRVD EMER EYEWASH & DELUGE SHOWER . IN CASES WHERE NO MONITORING FOR AIRBORNE CONTAMS HAS BEEN CARRIED (OTHER INFO) Work Hygienic Practices:DO NOT EAT, DRINK OR SMOKE IN WORK AREAS. WASH HANDS BEFORE EATING, SMOKING, OR USING THE WASHROOM. LAUNDER CLOTHING BEFORE REUSE. BARRIER CREAMS ARE NOT SUBSTITUTES FOR FULL PHYSICAL PROTECTION. Supplemental Safety and Health OTHER PREC: ASSESSMENT OF WORKPLACE RISKS AS REQUIRED BY REGS.MATL HAS OFFENSIVE ODOR. PRLNG EXPOS MAY REDUCE USER'S SENSITIVITY TO ODOR, THUS REDUCING EFFECTIVENESS OF ODOR AS WARNING AGAINST EXPO S.DO NOT HANDLE UNTIL MFR'S SFTY PREC HAVE BEEN READ & UNDERSTOOD. (ECOLOGICAL INFO) ================== Physical/Chemical Properties ================== Boiling Pt:>150.C, 302.F B.P. Text:302-399F(150-204C) Vapor Pres:SEE INGREDIENTS Vapor Density:HVR/AIR Spec Gravity:0.92-1.49 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:BLACK COLORED LIQUID WITH ORGANIC ODOR. Percent Volatiles by Volume:48-56 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALIS, ACIDS, OXIDIZERS, ALKALI METALS, NITRIC ACID, SODIUM HYDROXIDE. Stability Condition to Avoid:HIGH TEMPERATURES, FLAME, SPARKS. Hazardous Decomposition Products:OXIDES OF CARBON, VARIOUS HYDROCARBONS. =================== Toxicological Information=================== Toxicological Information:LEAD IS LISTED BY ACGIH AS A SUSPECTED HUMAN CARCINOGEN (A2), AND BY IARC AS POSSIBLY BEING CARCINOGENIC TO HUMANS (GROUP 1). COBALT COMPOUNDS ARE KNOWN TO IARC AS POSSIBLY CARCINOGENIC (GROUP 2B). METHYL ETHYL KETOXIME HAS BEEN SHOWN TO CAUSE CANCER IN LABORATORY ANIMALS BY INHALATION. QUARTZ CRYSTALLINE SILICA (CRISTOBALITE) IS KNOWN TO IARC AS CARCINOGENIC TO HUMANS (1) AND TO NTP AS REASONA BLY ANTICIPATED TO BE CARCINOGENIC (2). ===================== Ecological Information ===================== Ecological:HAZ AIR POLLUTANTS: LEAD COMPOUNDS.HAZ WASTE: WHEN DISCARDED IN THEIR SUPPLIED FORM, THESE PRODS MEET THE HAZ CRITERIA OF "IGNITABILITY" & MUST BE CONSIDERED AS HAZ WASTE D001. IN ADDITION, ONE-COA T LETTERING ENAMELS CONTAIN SUFFICIENT LEAD TO BE CONSIDERED D007 & D008. SUPDAT: REGS REQUIRE THAT ALL EMPLOYEES BE TRAINED ON MATL SFTY DATA SHEETS FOR ALL PRODS W/WHICH THEY COME IN CONT. OTHER INF O: LIQ MAY PENETRATE SHOES & LEATHER CAUSING DELAYED IRRIT. WASTE DISP:DETERM WHETHER CONTAM ITEMS ARE HAZ & DISP OF AS APPROP. CLEAN PREFERABLY W/DETERGENT, AVOID USE OF SOLVS. ==================== Disposal Considerations ==================== Waste Disposal Methods:HAZ WASTE: WHEN DISCARDED IN SUPPLIED FORM, PROD MEETS HAZ CRITERIA OF "IGNITABILITY" & MUST BE CONSIDERED AS HAZ WASTE D001. PROD ALSO CNTNS LEAD WHICH HAS HAZ WASTE CODE D007. DISP OF I/A/W/FED, ST & LOCAL POLLUTION REQS. IN ADDN, RAGS, SPRAY BOOTH FILTERS, PAINT SUITS, EMPTY CANS, ETC, CONTAM W/ PROD MAY BE HAZ WASTE. (ECOL INFO) =================== MSDS Transport Information =================== Transport Information:GROUND SHIPMENTS: PROPER SHIPPING NAME: PAINT RELATED MATL. HAZARD CLASS/DIVISION: 3. UN IDENTIFICATION NUMBER: UN1263. PACKAGING GROUP: III. HAZARD LABEL: FLAMMABLE LIQ. IMO/IMDG (OCEAN) SHIPMEN TS: PROPER SHIPPING NAME: PAINT RELATED MATL. HAZARD CLASS/DIVISION: 3.3.UN IDENTIFICATION NUMBER: UN1263. PACKAGING GROUP: III. HAZARD LABEL: FLAM LIQ. IMDG PAGE (ENGLISH TRANSLATION) 3372. MA RINE POLLUTANT: NO. ICAO/IATA (AIRCRAFT) SHIPMENTS: PACKAGING INSTRUCTIONS PASSENGER AIRCRAFT (IATA ENGLISH TRANSLATION): 309/Y309. PACKAGING INSTRUCTIONS CARGO AIRCRAFT (IATA ENGLISH TRANSLATION): 310.SPECIAL PROVISIONS: A3, A7, A72. ===================== Regulatory Information ===================== SARA Title III Information:SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES: NONE. SECTION 311/312 HAZARD CATEGORIES: IMMEDIATE HEALTH, DELAYED HEALTH, FIRE HAZARD. SECTION 313 TOXIC CHEMICALS:LEAD COMPOUNDS. YOU MAY BE REQUIRED TO SUBMIT THIS MSDS TO STATE AND LOCALEMERGENCY RESPONSE AGENCIES (SERC AND LEPC) AND TO YOUR LOCAL FIRE DEPARTMENT. ALSO, YOU MAY BE AFFECTED BY OTHER SECTIONS OF THIS LAW, DEPENDING ON THE CHEMICA LS AND AMOUNTS THAT YOU INVENTORY AT YOUR LOCATION. TO LEARN MORE ABOUT YOUR RESPONSIBILITIES, CALL THE EPA HOTLINE (800) 535-0202. Federal Regulatory Information:OSHA: THESE PRODUCTS ARE CONSIDERED HAZARDOUS UNDER THE FEDERAL OSHA HAZARD COMMUNICATION STANDARD. TSCA STATUS: ALL INGREDIENTS ARE TSCA REGISTERED. CEPA STATUS: ALL INGREDIENTS ARE LISTED ON THE D SL OR NDSL. State Regulatory Information:PROPOSITION 65: WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER. CONTAINS LEAD. WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM AND CANCER. ======================= Other Information =======================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:4080, DIO-TRONIC. LIQUID CAGE:1H6M8 CAGE:1H6M8 Contract Num:SP0450-00-M-SF81 CAGE:0V485 ============= Composition/Information on Ingredients ============= Ingred Name:DICHLOROFLUOROETHANE CAS:1717-00-6 RTECS #:KI0997000 = Wt:100. Ozone Depleting Chemical:2 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS: LIVER, KIDNEY. INHALATION: EXCESSIVE INHALATION MAY PRODUCE SYMTOMS OF CENTRAL NERVOUS SYSTEM DEPRESSION. SKIN: MILDLY IRRITATING TO SKIN. SKIN CONTACT MAY PRODUCE A BURNING SENSATION- PROLONGED OR REPEATED CONTACT MAY CAUSE DERMATITIS. MAY BE ABSORBED THROUGH THE SKIN, ALTHOUGH NOT EXPECTED TO PRODUCE TOXICITY THROUGH THIS ROUTE. EYE CONTACT: AN IRRITANT OF THE EYES. CAUSING PAIN, LACRIMATION AND GENERAL INFLAMMATION. INGESTION: MAY CAUSE IRRITATION OF THE GASTROINTESTINAL TRACT. IF VOMITING RESULTS IN ASPIRATION, CHEMICAL PNEUMONIA MAY FOLLOW. Effects of Overexposure:ACUTE: EXCESSIVE INHALATION ORINGESTION MAY PRODUCE SYMPTOMS OF CENTRAL NERVOUS SYSTEM DEPRESSION RANGING FROM LIGHT HEADEDNESS, TO UNCONSCIOUSNESS AND DEATH. OVEREXPOSURE MAY RESULT IN LIVER AND KI DNEY DAMAGE. EXPOSURE TO THE EYES AND SKIN MAY PRODUCE IRRITATION. ANIMALS EXPOSED TO HIGH LEVELS HAVE SHOWN CARDIAC SENSITIZATION. CHRONIC: CAN CAUSE HEADACHE, MENTAL CONFUSION, DEPRESSION, FATIGUE, LOSS OF SENSE OF BALANCE, AND VISUAL DISTRUBANCES. PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE DERMITITIS. ======================= First Aid Measures ======================= First Aid:EYES: IRRIGATE WITH FLOWING WATER IMMEDIATELY AND CONTINUOSLY FOR 15 MINUTES. CONSULT MEDICAL PERSONNEL. SKIN: WASH OFF IN FLOWING WATER OR SHOWER. INGESTION: DO NOT INDUCE VOMITING. CALL A PHYSICIAN AND/OR TRANSPORT TO EMERGENCY FACILITY IMMEDIATELY. INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, OXYGEN SHOULD BE ADMINISTERED BY QUALIF IED PERSONNEL. CALL A PHYSICIAN OR TRANSPORT TO A MEDICAL FACILITY. ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:NONE Upper Limits:NONE Extinguishing Media:FIRES INVOLVING THIS PRODUCT ARE UNLIKELY, BUT SHOULD ONE OCCUR, IT MAY BE CONTROLLED BY CARBON DIOXIDE, DRY CHEMICALS OR WATER SPRAY. Fire Fighting Procedures:PRESSURE-DEMAND, SELF-CONTAINED BREATHING APPARATUS SHOULD BE PROVIDED FOR FIRE FIGHTERS IN BUILDING OR CONFINED AREAS WHERE PRODUCT IS STORED. STORAGE CONTAINERS EXPOSED TO FIRE SHOULD BE KEPT COOL W ITH A WATER SPRAY, IN ORDER TO PREVENT PRESSURE BUILDUP. Unusual Fire/Explosion Hazard:AT HIGH TEMPERATURES, THIS PRODUCT DECOMPOSES TO GIVE OFF HYDROCHLORIC ACID GAS PLUS OTHER TOXIC AND IRRITATING VAPORS SUCH AS PHOSGENE. IF STORAGE CONTAINERS ARE EXPOSED TO EXCESSIVE HEAT, OVER-PRESS URIZATION OF CONTAINERS CAN RESULT. ================== Accidental Release Measures ================== Spill Release Procedures:LEAKS SHOULD BE STOPPED. SPILLS SHOULD BE CONTAINED AND CLEANED UP IMMEDIATELY. LARGE SPILLS--SHOULD BE REMOVED BY USING A VACUUM TRUCK. SMALLER SPILLS--MAYBE SOAKED UP WITH COMPATIBLE ABSORBENT MATER IALS WHICH SHOULD THEN BE PLACED IN APPROVED CONTAINERS, LABELED AND STORED IN A PLACE OUT OF DOORS TO AWAIT PROPER DISPOSAL. THE SPILL AREA SHOULD THEN BE FLUSHED WITH WATER. CONTAINERIZE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE DRUMS IN A COOL PLACE. VENTILATION SHOULD BE PROVIDED AT THE FLOOR LEVEL. DO NOT STORE IN PITS, DEPRESSIONS, BASEMENTS OR UNVENTILATED AREAS. Other Precautions:NOTE TO PHYSICIAN: BECAUSE RAPID ABSORPTION MAY OCCUR THROUGH LUNGS IF ASPIRATED AND CAUSE SYSTEMIC EFFECTS, THE DECISION OF WHETHER TO INDUCE VOMITIMG OR NOT SHOULD BE MADE BY A PHYSICIAN. IF LAVAGE IF PERFORMED, SUGGEST ENDOTRACHEAL AND/OR ESPOPHAGEAL CONTROL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN SITUATIONS WHERE VAPOR CONCENTATIONS EXCEED THE RECOMMENDED EXPOSURE LIMITS, A NIOSH APPROVED ORGANIC VAPOR CARTRIDGE OR AIR-SUPPLYING RESPIRATOR SHOULD BE WORN. SUGGESTED. WORN. Work Hygienic Practices:AVOID CONTACT WITH SKIN AND AVOID BREATHING VAPORS. DO NOT EAT, DRINK OR SMOKE IN WORK AREA. WASH HANDS PRIOR TO EATING, DRINKING OR USING RESTROOM. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:=32.C, 89.6F Vapor Pres:10.02 PSIA@70 D.F. Vapor Density:4.1 Spec Gravity:1.24 @ 70 D.F. Solubility in Water:0.17 @ 70 D.F. Appearance and Odor:COLORLESS LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACTING PRODUCT WITH PURE OXYGEN, ALKALI METALS, OPEN FLAMES. Stability Condition to Avoid:UNDER NORMAL CONDITIONS THIS MATERIAL IS STABLE. Hazardous Decomposition Products:AT HIGH TEMPERATURES, THIS PRODUCT DECOMPOSES TO GIVE OFF HYDROGEN CHLORIDE GAS AND SMALL QUANTITIES OF OTHER TOXIC AND IRRITATION VAPORS SUCH AS PHOSGENE. Conditions to Avoid Polymerization:MATERIAL IS NOT KNOWN TO POLYMERIZE. ===================== Ecological Information ===================== Ecological:AVOID DISCHARGE TO NATURAL WATERS. ==================== Disposal Considerations ==================== Waste Disposal Methods:THE MATERIALS RESULTING FROM CLEAN UP OPERATIONS MAY BE HAZARDOUS WASTES AND, THEREFORE, SUBJECT TO SPECIFIC REGULATIONS. PACKAGE, STORE, TRANSPORT AND DISPOSE OF ALL CLEAN UP MATERIALS AND ANY CONTAM INATED EQUIPMENT IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL HEALTH AND ENVIRNMENTAL REGULATIONS. ===================== Regulatory Information ===================== SARA Title III Information:PURSUANT TO TITTLE THREE OF THE SUPERFUND AMMENDMENT AND REAUTHORIZATION ACT OF 1986 (SARA) AND 40 CFR PART 372, THIS PRODUCT CONTAINS, OR MAY CONTAIN A TOXIC CHEMICAL IN THE QUANTITY SUBJECT TO THE R EPORTING REQUIREMENTS UNDER SECTION 313. Federal Regulatory Information:US POSTAL REGULATIONS: NON-HAZARDOUS, NON-FLAMMABLE, OKAY TO SHIP BY MAIL. ======================= Other Information =======================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:DT885 WARM TEMP REDUCER CAGE:DO542 CAGE:DO542 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ETHYL KETONE, 2-BUTANONE *97-3* CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 15-20% Other REC Limits:590 MG/CUM OSHA PEL:200 PPM ACGIH TLV:590 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TOLUENE (IARC CARC- GROUP 3) *97-3* CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 10-15% Other REC Limits:375 MG/CUM OSHA PEL:100 PPM ACGIH TLV:100 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:LIGHT ALIPHATIC NAPHTHA, VM & P NAPHTHA, LACOLENE *97-3* CAS:64742-89-8 Fraction by Wt: 25-30% OSHA PEL:300 PPM ACGIH TLV:300 PPM Ingred Name:PROPYLENEGLYCOL MONOMETHYL ETHER ACETATE, 1-METHOXY-2-PROPANOL ACETATE CAS:108-65-6 RTECS #:AI8925000 Fraction by Wt: 25-30% Ingred Name:XYLENE, DIMETHYLBENZENE, XYLOL (IARC - GROUP 3) *97-3* CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 5-10% Other REC Limits:100 PPM OSHA PEL:100 PPM ACGIH TLV:100 PPM, SKIN EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHYL 3-ETHOXYPROPIONATE, PROPANOIC ACID, 3-ETHOXY-, ETHYL ESTER *97-3* CAS:763-69-9 RTECS #:UF3325000 Fraction by Wt: 10-15% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INGESTION: HARMFUL. EYES: SEVERE IRRITATION. SKIN: MODERATE IRRITATION. INHALATION: HARMFUL, IRRITATES EYES, NOSE & THROAT. IRRITATION OF THE RESPIRATORY SYSTEM, PERMANENT BRAIN & NERVOUS SYSTEM DAMAG E. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, EYE WATERING, HEADACHES, NAUSEA, DIZZINESS, LOSS OF COORDINATION, REDNESS, ITCHING, BURNING, VISUAL DISTURBANCES, DRYNESS, CRACKING, SWELLING. ======================= First Aid Measures ======================= First Aid:INGESTION: DON'T INDUCE VOMITING. EYES: FLUSH W/PLENTY OF WATER FOR 15 MINS. SKIN: FLUSH W/PLENTY OF WATER FOLLOWED BY WASHING W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OTHER SUPPORTIV E MEASURES AS REQUIRED. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:32F Lower Limits:1.4 Extinguishing Media:CO2, DRY CHEMICAL/UNIVERSAL AQUEOUS FILM FORMING FOAM. Fire Fighting Procedures:WATER SPRAY MAY BE INEFFECTIVE. WATER SPRAY MAY BE USED TO COOL CLOSED CONTAINERS. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. WEAR SCBA. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. DON'T APPLY ON HOT SURFACES. TOXIC GASES MAY FORM BY FLAME/HOT SURFACES. ================== Accidental Release Measures ================== Spill Release Procedures:USE MAXIMUM VENTILATION. ONLY PERSONNEL EQUIPPED W/PROPER EQUIPMENT SHOULD BE PERMITTED. REMOVE SOURCES OF IGNITION. TAKE UP W/SAND, VERMICULITE/NONCOMBUSTIBLE ABSORBENT MATERIAL & PLACE IN CLEAN, EMP TY CONTAINERS FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T STORE >120F. STORE LARGE AMOUNTS IN BUILDINGS DESIGNED & PROTECTED FOR STORAGE . Other Precautions:CONTAINERS SHOULD BE GROUNDED WHEN POURING. AVOID FREE FALL OF LIQUIDS IN EXCESS OF A FEW INCHES. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING THE CONTENTS CAN BE HARMFUL/FATAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:OVEREXPOSURE TO VAPORS MAY BE PREVENTED BY ENSURING VENTILATION CONTROLS, VAPOR EXHAUST/FRESH AIR ENTRY. NIOSH/MSHA APPROVED (TC-23C)AIR PURIFYING/AIR SUPPLIED(TC-19C)RESPIRATORS MAY ALSO REDUCE EXPOS URE. Ventilation:GENERAL DILUTION/LOCAL EXHAUST: TO KEEP THE CONCENTRATION BELOW EXPOSURE LIMIT & LEL. Other Protective Equipment:PROTECTIVE CLOTHING, IMPERMEABLE APRON. Work Hygienic Practices:REMOVE/DISCARD CONTAMINATED CLOTHING, Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:172.4-338F Vapor Pres:27.2 Vapor Density:>1 Spec Gravity:0.85 Evaporation Rate & Reference:(BUO AC = 100): 218 Solubility in Water:10.9 Appearance and Odor:NON-VISCOUS LIQUID W/A CHARACTERISTIC ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ALKALIS, STRONG MINERAL ACIDS/STRONG OXIDIZING AGENTS. Stability Condition to Avoid:SOURCES OF IGNITION. Hazardous Decomposition Products:WHEN HEATED: CO. ==================== Disposal Considerations ==================== Waste Disposal Methods:EMPTY CONTAINERS SHOULD BE RECYCLED/DISPOSED OF THROUGH AN APPROVED WASTE MANAGEMENT FACILITY, IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:ORANGE LOTION HAND CLEANER WITH PUMICE, 0951 Preparer's Name:DONALD H SINNER CAGE:GO199 CAGE:GO199 CAGE:02905 ============= Composition/Information on Ingredients ============= Ingred Name:CYCLOHEXENE, 1-METHYL-4-(1-METHYLETHENYL)-,(R)-; (D-LIMONENE) CAS:5989-27-5 RTECS #:GW6360000 Fraction by Wt: 7-15% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ALKOXYLATED FATTY ALCOHOL; (LINEAR ALCOHOL ALKOXYLATE) CAS:69227-21-0 Fraction by Wt: 5-10% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES:DIRECT CONTACT MAY CAUSE IRRITATION. INGESTION:MAY CAUSE GASTRIC UPSET. SKIN:PROLONGED CONTACT OR REPEATED OVEREXPOSURE MAY CAUSE IRRITATION. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . EYES:DO NOT RUB EYES. FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES. IF CONDITION WORSENS OR IRRITATION PERSISTS, CONTACT A PHYSICIAN. INGESTION:DRINK PLENTY OF MILK OR WATER. CALL PHYSICIAN OR POISON CONTROL CENTER IN CASE OF SYMPTOMS OR ILLNESS. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:>200F,>93C Extinguishing Media:WATER FOG, ALCOHOL FOAM, CO*2, DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE KNOWN. ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP WITH ABSORBENT MATERIAL. CONTAIN AND PICK UP WASTE MATERIALS. PUT IN A SEALED APPROVED CONTAINER. FLUSH AREA WITH WATER TO REDUCE SLIPPING HAZARD. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT TAKE INTERNALLY. WASH THOROUGHLY WITH PLENTY OF WATER AFTER ACCIDENTAL CONTACT. Other Precautions:KEEP OUT OF REACH OF CHILDREN. KEEP FROM FREEZING. AVOID EXCESSIVE HEAT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . NOT REQUIRED WHEN USED AS DIRECTED. Ventilation:NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment:NOT REQUIRED WHEN USED AS DIRECTED. Work Hygienic Practices:GOOD HOUSEKEEPING AND PERSONAL CARE. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:201F,94C Vapor Pres:15 Vapor Density:0.6 Spec Gravity:1.02 (H*2O=1) pH:6-7 Evaporation Rate & Reference:0.7 (H*2O=1) Solubility in Water:80% Appearance and Odor:CREAMY OPAQUE VISCOUS GEL, ORANGE FRAGRANCE. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:NONE KNOWN. ==================== Disposal Considerations ==================== Waste Disposal Methods:ACCORDING TO APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS.
0
gloves_not_mandatory
===================== Product Identification ===================== Product ID:CALCIUM LEAD BATTERY, WET (KC SERIES) CAGE:LO354 CAGE:80531 CAGE:LO354 CAGE:7L867 ============= Composition/Information on Ingredients ============= Ingred Name:LEAD (SARA III) CAS:7439-92-1 RTECS #:OF7525000 Fraction by Wt: >60% Other REC Limits:NONE SPECIFIED OSHA PEL:0.05 MG/M3;1910.1025 ACGIH TLV:0.15 MG/M3;DUST 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:CALCIUM, METAL CAS:7440-70-2 RTECS #:EV8040000 Fraction by Wt: 1.0% Other REC Limits:NONE SPECIFIED Ingred Name:SULFURIC ACID (SARA III) CAS:7664-93-9 RTECS #:WS5600000 Fraction by Wt: 7-9% Other REC Limits:NONE SPECIFIED OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:POLYPROPYLENE Fraction by Wt: 18% Other REC Limits:NONE SPECIFIED Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 20% Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE:INHALATION OF ACID VAPORS MAY CAUSE SEVERE IRRITATION OR BURNS OF THE RESPIRATORY SYSTEM, PULMONARY EDEMA, OR LUNG INFLAMMATION. MAY CAUSE SEVERE BURNS TO SKIN OR EYES. INGESTION MAY CAUSE SEVER E BURNS TO MOUTH, THROAT, AND STOMACH. MAY AFFECT KIDNEY FUNCTION. CHRONIC:MAY DAMAGE LUNGS,TEETH EROSION. Explanation of Carcinogenicity:LEAD IS CONSIDERED A POSSIBLE CARCINOGEN. Effects of Overexposure:ACID:SEVERE IRRITATION OR BURNS TO EYES, NOSE AND THROAT. PULMONARY EDEMA, BRONICAL EMPHYSEMA, CONJUNCTIVITIS, STOMATITIS, DENTAL EROSION, NAUSEA AND VOMITING. LEAD:STOMACH CRAMPS, ANEMIA AND NERVE DA MAGE. Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS OR WITH A PRE-EXISTING DISEASE INVOLVING THE RESPIRATORY TRACT MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING. GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN:REMOVE CONTAMINATED CLOTHING. WASH WITH PLENTYOF WATER FOR 15 MINUTES. GET MEDICAL ADVICE. INGESTION:DO NOT INDUCE VOMITING. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:IF ON CHARGE, SHUT OFF POWER. Unusual Fire/Explosion Hazard:WILL GENERATE HYDROGEN ON OVERCHARGE. MAY EXPLODE IN FIRE AND PRODUCE HAZARDOUS FUMES AND OXIDE OF SULFUR GASES. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. STOP LEAK IF YOU CAN DO SO WITHOUT RISK. DO NOT USE WATER. NEUTRALIZE SPILL AND/OR WASHINGS WITH SODA ASH OR LIME. WITH CLEAN SHOV EL, PLACE MATERIAL INTO CLEAN, DRY CONTAINER. Neutralizing Agent:J.T.BAKER'S NEUTRASORB (R) OR TEAM 'LOW NA+' ACID NEUTRALIZERS ARE RECOMMENDED. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE IN CORROSION-PROOF AREA. KEEP CONTAINERS OUT OF SUN AND AWAY FROM HEAT. ISOLATE FROM INCOMPATIBLE MATERIALS. Other Precautions:DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. DO NOT BREATHE VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER. LOOSEN CLOSURE CAUTIOUSLY. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF SPILL NEUTRALIZE WITH SODA ASH OR LIME. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED WHERE ADEQUATE VENTILATION CONDITIONS EXIST. IF AIRBORNE CONCENTRATION EXCEEDS TLV, A NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS IS RECOMMENDED. Ventilation:USE MECHANICAL (GENERAL) OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER. INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO NOT BREATHE VAPORS OR MISTS. ================== Physical/Chemical Properties ================== HCC:C1 Spec Gravity:1.215-1.250 pH:<2.0 Appearance and Odor:LEAD/ACID BATTERY, PLASTIC CASING. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, COMBUSTIBLES, ORGANIC MATERIAL, PROLONGED OVERCHARGE. Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES . Hazardous Decomposition Products:OXIDES OF SULFUR, HYDROGEN GAS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:GLOSSY STUF CAGE:IO406 CAGE:IO406 CAGE:0C3Y2 ============= Composition/Information on Ingredients ============= Ingred Name:NO HAZARDOUS COMPONENTS (NON-HAZARDOUS) Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN: IRRITATION, REDNESS. ======================= First Aid Measures ======================= First Aid:EYES: FLOOD W/WATER. SKIN: WASH W/WATER. INGEST: GET IMMED MED AID. ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:NA Upper Limits:NA Extinguishing Media:CO2 & FOAM. Fire Fighting Procedures:USE SCBA. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE LARGE SPILLS. SMALL SPILL: FLUSH THROUGH NORMAL SEWAGE SYSTEM. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HIGH TEMPS. KEEP OUT OF REACH OF CHILDREN. USE PRODUCT ACCORDING TO DIRECTIONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NEEDED. Ventilation:LOCAL EXHAUST RECOMMENDED. Other Protective Equipment:APRON. Work Hygienic Practices:WASH CLOTHES BEFORE REUSE. Supplemental Safety and Health * PH = 6 +/- 0.5 ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Melt/Freeze Pt:M.P/F.P Text:NA Vapor Pres:NA Vapor Density:NA Spec Gravity:1.0 pH:* Evaporation Rate & Reference:NA Solubility in Water:EMULSIFIABLE. Appearance and Odor:WHITE LIQUID, VERY LITTLE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS. Stability Condition to Avoid:NONE Hazardous Decomposition Products:SILICON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:RENDER CONTAINER USELESS. DISPOSE IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS.
0
gloves_not_mandatory
======================================================= Product ID: WHITE WATERBORNE S.B.C., 00015093 Cage: FO846 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 75604 Cage: FO846 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: YES IARC: YES OSHA: YES Effects of Exposure: ACUTE:INHALATION:MAY CAUSE DIZZINESS, NAUSEA OR FATIGUE. MAY CAUSE IRRITATION TO RESPIRATORY TRACT. SKIN:PROLONGED OR REPEATED CONTACT CAN CAUSE MODERATE IRRITATION, DEFATTING OR DERMATITIS. REDNESS A ND ITCHING MAY OCCUR. SKIN MAY DRY AND CRACK. EYE:CAN CAUSE IRRITATION, REDNESS, TEARING, AND BLURRED (EFTS OF OVEREXP) Explanation Of Carcinogenicity: USERS OF "L" VERSION CONSULT "LR" VERSION. INGREDIENT 9 Signs And Symptions Of Overexposure: HLTH HAZ:VISION. INGESTION:MAY IRRITATE DIGESTIVE TRACT AND CAUSE NAUSEA, VOMITING, AND DIARRHEA. IF TAKEN INTERNALLY, CONSULT PHYSICIAN. CHRONIC:REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OVEREXP OSURE TO HIGH CONCENTRATIONS OF SOLVENTS WITH DEGENERATIVE BRAIN AND NERVOUS SYSTEM DISORDERS. FORMALDEHYDE HAS (SUPDAT) Medical Cond Aggravated By Exposure: PRE-EXISTING EYE, SKIN, AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. First Aid: EYE:FLUSH W/WATER AT LEAST 15 MINS LIFTING UPPER & LOWER LIDS OCCASNLY. GET MED ATTN. SKIN:REMOVE CONTAMD CLTHG. WASH EXPOSED AREAS WELL W/SOAP & WATER. IF IRRIT PERSISTS, GET MED ATTN. INHAL:REMOVE T O FRESH AIR & GET MED ATTN. IF BRTHG STOPS, ADMIN ARTF RESP. CONT PHYS IMMED. INGEST:CALL PHYS IMMED. NOTE:DO NOT INDUCE VOMIT W/OUT PHYSICIAN'S ADVICE AS MATL COULD ASPIRATE INTO LUNGS. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: ELIM ALL IGNIT SOURCES. WEAR PROPER PERSONAL PROT EQUIP. DIKE AREA OF SPILL TO PVNT SPREADING. USE INERT, NONSPARKING MATLS TO ABSORB LIQ. PVNT RUN-OFF TO SEWERS & OTHER WATER SOURCES. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS. Handling And Storage Precautions: KEEP CNTNRS CLSD WHEN NOT IN USE. ALL HNDLG EQUIP MUST BE ELECTRICALLY GROUNDED. Other Precautions: VAPS ARE HVR/AIR & MAY TRAVEL ALONG GROUND/BY VENT TO IGNIT SOURCES FAR FROM MATL HNDLG POINT. EXTING ALL PILOT LIGHTS & TURN OFF ALL HEATERS, & OTHER SOURCES OF IGNIT DURING USE & UNTIL ALL VAPS ARE GONE. SINCE EMPTY CNTNRS RETAIN ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: SCC Flash Point Text: >200F,>93C Extinguishing Media: FOAM, CO*2, DRY CHEMICAL. Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). CLEAR AREA OF UNPROTECTED PERSONNEL. USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard: KEEP CNTNRS TIGHTLY CLSD WHEN NOT IN USE. VAPS ARE HVR/AIR & MAY TRAVEL & FLASH BACK FROM IGNIT SOURCES. CLSD CNTNRS MAY EXPLODE DUE TO PRESS BUILD UP (SUPDAT) ======================================================= Control Measures ======================================================= Respiratory Protection: NIOSH/MSHA APPROVED VAPOR-TYPE RESPIRATOR REQUIRED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. Ventilation: AS NECESSARY TO MAINTIAN EXPOS LEV BELOW OCCUPATIONAL EXPOSURE LIMITS OF ALL OF COMPONENTS. Other Protective Equipment: IMPERVIOUS PROT CLTHG. ANSI APPRVD EMER EYE WASH & DELUGE SHOWER (FP N). Work Hygienic Practices: REMOVE CONTAM CLTHG IMMED & WASH BEFORE WEARING AGAIN. WASH HANDS THORO BEFORE EATING, DRINKING, SOAKING/ANY Supplemental Safety and Health: USERS OF "L" VERSION OF TO CONSULT "LR" VERSION FOR MORE INFO (FP N). EXPLO HAZ:WHEN EXPOS TO EXTREME HEAT. DURING EMER CNDTNS, OVEREXP TO DECOMP PROD MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE IMMED A PPARENT. EFTS OF OVEREXP:POTNTL TO CAUSE CANCER IN HUMANS. RPTD/PRLNGD EXPOS INCREASES RISK. FORMALDEHYDE EXPOS ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: 212F,100C Vapor Density: HVR/AIR Spec Gravity: 1.1 (H*2O=1) Evaporation Rate & Reference: SLOWER THAN ETHER Solubility in Water: SOLUBLE Appearance and Odor: WHITE LIQUID/MILD ODOR ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: HEAT AND IGNITION SOURCES. Materials To Avoid: AVOID STRONG OXIDIZERS AND/OR MATL THAT REACTS VIOLENTLY OR EXPLOSIVELY WITH WATER. Hazardous Decomposition Products: MAY CONTAIN CARBON MONOXIDE, CARBON DIOXIDE, AND FORMALDEHYDE. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: WHITE WATERBORNE S.B.C., 00015093 Cage: FO846 Assigned IND: Y Company Name: LILLY INDUSTRIAL COATINGS, INC Street: 546 W. ABBOTT STREET Zipcode: 46225 Label Required IND: Y Date Of Label Review: 04/16/1995 Status Code: C Label Date: 04/16/1995 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: ACUTE:INHAL:MAY CAUSE DIZZINESS, NAUSEA OR FATIGUE. MAY CAUSE IRRIT TO RESP TRACT. SKIN:PROLONGED OR REPEATED CONTACT CAN CAUSE MODERATE IRRITATION, DEFATTING OR DERMATITIS. REDNESS AND ITCHING MAY OC CUR. SKIN MAY DRY AND CRACK. EYE:CAN CAUSE IRRIT, REDNESS, TEARING, AND BLURRED VISION. INGESTION:MAY IRRITATE DIGESTIVE TRACT AND CAUSE NAUSEA, VOMITING, AND DIARRHEA. IF TAKEN INTERNALLY, CONSUL PHY SCIAN. CHRONIC:REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OVEREXPOSURE TO HIGH CONCENTRATIONS OF SOLVENTS W/DEGENERATIVE BRAIN & NERVOUS SYSTEM DISORDERS. CANCER HAZARD. CONTAINS MATL WHICH IS REG ULATED AS A RESPIRATORY TRACT CARCINOGEN (FP N). =======================================================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:EA 956 PART B, PRODUCT CODE:AB9112. Kit Part:Y Preparer's Name:MSDS DEPT CAGE:33564 CAGE:33564 CAGE:03355 ============= Composition/Information on Ingredients ============= Ingred Name:POLYAMIDE RESIN (PROPRIETARY) Fraction by Wt: 40-70% Other REC Limits:NONE RECOMMENDED Ingred Name:DIETHYLENE TRIAMINE CAS:111-40-0 RTECS #:IE1225000 Fraction by Wt: 10-30% Other REC Limits:NONE RECOMMENDED OSHA PEL:1 PPM ACGIH TLV:S, 1 PPM; 9394 Ingred Name:TRIETHYLENE TETRAMINE CAS:112-24-3 RTECS #:YE6650000 Fraction by Wt: 5-10% Other REC Limits:NONE RECOMMENDED Ingred Name:VOLATILE ORGANIC COMPOUNDS RTECS #:9999999VO Fraction by Wt: <10% G/L Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:MIXTURE HAS NOT BEEN TESTED AS A WHOLE. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:THIS MATERIAL IS CORROSIVE TO EYES & SKIN. BRIEF CONTACT MAY CAUSE CHEMICAL BURNS. VAPORS & MISTS WILL IRRITATE NOSE & THROAT. REPEATED OR PROLONGED SKIN CONTACT MAY RESULT IN BURNS AND POSSIBLE ALLER GIC SENSITIZATIN. Explanation of Carcinogenicity:PER MSDS NEITHER THIS MATERIAL NOR ANY OF ITS COMPONENTS IS CONSIDERED A CARCINOGEN. Effects of Overexposure:SKIN & EYE IRRITATION. CHEST DISCOMFORT. Medical Cond Aggravated by Exposure:SKIN SENSITIZATION. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/LOTS OF RUNNING WATER FOR 15MINS. GET MED ATTN IMMED. SKIN:WASH THOROUGHLY W/SOAP & WATER. IF IRRIT PERSISTS GET MED ATTN. INHAL:REMOVE VICTIM TO FRESH AIR. IF SYMPTOMS PERSIST GET MED ATT N. INGEST:DRINK PLENTY OF WATER. GET MED ATTN IMMED. ===================== Fire Fighting Measures ===================== Flash Point:NOT TESTED Extinguishing Media:DRY CHEMICAL, OR HALON FIRE EXTINGUISHER, OR WATER SPRAY, FOAM OR FOG. (NOTE:HALON IS AN ODS). Fire Fighting Procedures:WEAR SCBA & FULL PROTECTIVE CLOTHING, SUCH AS TURN-OUT GEAR. CARTRIDGE RESP DO NOT PROVIDE ADEQUATE PROTECTION FOR FIREFIGHTERS OR EXOTHERM MITIGATION. Unusual Fire/Explosion Hazard:MAY LIBERATE LARGE QUANTITIES OF DENSE FOUL-SMELLING SMOKE WHICH MAY CONTAIN UNIDENTIFIED TOXIC GASES. ================== Accidental Release Measures ================== GLASSES. ABSORB SPILL WITH SORBENT MATERIAL SUCH AS VERMICULITE OR SAND. SCRAPE UP OR SHOVEL INTO DOT APPROVED WASTE CONTAINERS. Neutralizing Agent:NOT APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:PRODUCT MAY BE STORED @ RM TEMP FOR UP TO 12 MONTHS.KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE.EMPTY CONTIANERS RETAIN RESIDUE;HANDLE AS IF FULL. Other Precautions:FOLLOW CURING SCHEDULE AS RECOMMENDED IN PRODUCT LITERATURE.DON'T CUT/GRIND/WELD/DRILL ON/NEAR CONTAINER.AVOID MIXING PARTS A&B IN BATCHES >1LB UNLESS PLAN TO USE IMMED.DON'T HEAT MIXED ADHESIVE >125F UNLESS CURING SURFACES TO BE BONDED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF LOCAL EXHAUST VENTILATION IS INADEQUATE A RESPIRATOR EQUIPPED WITH ORGANIC VAPOR CARTRIDGES MAY BE APPROPRIATE. Ventilation:LOCAL EXHAUST VENTILATION AT THE POINT OF USE. Other Protective Equipment:AN EYEWASH AND SAFETY SHOWER SHOULD BE NEARBY AND READY FOR USE. LONG-SLEEVED SHIRT AND TROUSERS. Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER HANDLING MATERIALS. Supplemental Safety and Health VISCOSITY:BROOKFIELD, SPDKL 1. FAILURE TO OBSERVE PRECAUTIONS IN MIXING/HEATING MAY RESULT IN EXCESSIVE HEAT BUILD-UP CAUSING AN EXOTHERM. THE EXOTHERM HAS POTENTIAL FOR RELEASE OF TOXIC GASES. OBEY H AZ WARNINGS & HANDLE EMPTY CONTAINERS AS IF THERY WERE FULL. SEE SAME NSN/CAGE PNIND:E FOR PART A OF 2-PART KIT. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:405F,207C Vapor Pres:NIL Vapor Density:>1 Spec Gravity:0.96 pH:UNDEFI Viscosity:10-30 Solubility in Water:COMPLETE (100%) Appearance and Odor:LIQUID, AMBER LIQUID WITH AMMONIACAL ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG LEWIS OR MINERAL ACIDS. Stability Condition to Avoid:AVOID MIXING PARTS A&B IN BATCHES >1LB & HEATING MIXTURE >125F. Hazardous Decomposition Products:CO, NOX, ALDEHYDES, ACIDS & UNDETERMINED ORGANICS. ==================== Disposal Considerations ==================== Waste Disposal Methods:MATL AS WASTE IS NOT RCRA HAZ WASTE.HOWEVER,INCINERATION IN EPA APPROVED WASTE INCINERATOR IS PREFERRED.CHEM ADDITIONS/PROCESSING/OTHERWISE ALTERING MATL MAY MAKE WASTE MANAGEMENT INFOR HEREIN INCOMPL ETE/INACCURATE/INAPPROPRIATE.CONSULT STATE/LOC REG
1
gloves_mandatory
===================== Product Identification ===================== Product ID:BACGUARD-X, 0225 Preparer's Name:KELLY SEALS/TS CHEMIST CAGE:20913 CAGE:53417 CAGE:20913 ============= Composition/Information on Ingredients ============= Ingred Name:1,2-PROPANEDIOL (PROPYLENE GLYCOL) CAS:57-55-6 RTECS #:TY2000000 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:DIRECT CNTCT W/EYES MAY CAUSE IRRIT. PRLNG SKIN CNTCT MAY CAUSE REDDENING OF SKIN IRRIT & POSSIBLE DISCOMFORT TO SENSITIVE SKIN. CHRONIC:DIRECT CNTCT W/EYES FOR PRLNG PERIOD OF TIME CAN CAUSE CO RNEAL DMG. PRLNG SKIN CNTCT MAY CAUSE REDDENING OF SKIN, IRRIT, LEADING POTENTIALLY TO DERMATITIS. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:NOT A HAZARD. EYE CONTACT:PERSON IS TO SEEK MD ATTENTION IMMED. IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN HOLDING EYELIDS APART TO ENSURE FLUSHING OF THE ENTIRE EYE SURF. SEEK MD ATTENTI ON IF ANY IRRIT PERSISTS. SKIN CNTCT:WASH W/PLENTY OF WATER. INGEST:IF SWALLOWED, DO NOT INDUCE VOMIT. GIVE LRG QTY OF WATER IF AVAILABLE. GIVE SEVERAL GLASSES OF CITRUS JUICE. NEVER (SEE SUPP DATA) ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:NONE SPECIFIED BY MANUFACTURER. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . ================== Accidental Release Measures ================== Spill Release Procedures:SMALL SPILL:FLUSH SURF W/LRG VOL OF WATER & FLUSH DOWN DRAIN. LARGE SPILL:STOP LEAK. CONTAIN SPILL. REMOVE BY WET VACUUM OR ABSORBENT. REUSE SPILLED MATL IF POSSIBLE. PLACE IN CLOSED LABELED CONTAINE RS. Neutralizing Agent:LARGE AMOUNTS OF WATER WILL NEUTRALIZE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AT MODERATE TEMPERATURES (MAX:120F & MIN:32F). Other Precautions:KEEP OUT OF REACH OF CHILDREN. READ ENTIRE LABEL BEFORE USING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NONE REQUIRED Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRST AID PROC:GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. SEEK MEDICAL ATTENTION. ================== Physical/Chemical Properties ================== HCC:C2 Boiling Pt:B.P. Text:212F,100C Vapor Pres:18 Vapor Density:0.6 Spec Gravity:1.11 pH:11 Evaporation Rate & Reference:0.10 (BU AC = 1) Solubility in Water:COMPLETE Appearance and Odor:BLUE GREEN, TRANSPARENT, ODORLESS Percent Volatiles by Volume:63 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH STATE, FEDERAL, AND LOCAL REGULATIONS CONCERNING HEALTH POLLUTION.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:THOMPSON'S WATER SEAL BRAND WATERPROOFING F CAGE:25458 CAGE:25458 ============= Composition/Information on Ingredients ============= Ingred Name:ALIPHATIC PETROLEUM DISTILLATE (MINERAL SPIRITS) CAS:64475-85-0 RTECS #:PY8240000 Fraction by Wt: 32% Other REC Limits:NONE SPECIFIED OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:MINERAL OIL (MINERAL OIL MIST) CAS:64742-54-7 RTECS #:PY8035500 Fraction by Wt: 52% Other REC Limits:NONE SPECIFIED OSHA PEL:5 MG/M3 Ingred Name:VOC: LESS THAN 400 (GRAMS PER LITER LESS WATER) RTECS #:9999999VO Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Effects of Overexposure:EYE: IRRITATE/RED/TEAR/BLURRED VISION. SKIN: MODERATE IRRITATE/DEFAT/DERMATITIS. INHALE: NASAL/RESPIRATORY IRRITATION/ DIZZY/WEAK/FATIGUE/NAUSEA/HEADACHE/UNCONSCIOUS/ASPHYXIATION. INGEST: GASTROINTEST INAL IRRITATE/NAUSEA/VOMIT/DIARRHEA. ASPIRATION OF MATERIAL INTO LUNGS CAN CAUSE CHEMICAL PNEUMONITIS-CAN BE FATAL. ======================= First Aid Measures ======================= First Aid:SKIN: THOROUGHLY WASH AREA W/SOAP/WATER. REMOVE CONTAMINATED/LAUNDER CLOTHING BEFORE REUSE. EYE: FLUSH W/WATER LIFT LIDS OCCAS. GET MED AID. INGEST: DO NOT INDUCE VOMITING, KEEP WARM/QUIET. GET MED AI D. INHALE: MOVE TO FRESH AIR. ARTIFICIAL RESPIRATION/OXYGEN AS NEEDED. KEEP WARM/QUIET. GET MED AID. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:>100F,>38C Lower Limits:1.0 Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS WITH A FULL FACE-PIECE OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE MODE WHEN FIGHTING FIRES. Unusual Fire/Explosion Hazard:VAPORS HEAVIER THAN AIR/TRAVEL ALONG GROUND/ MOVED BY VENTILATION/IGNITED BY PILOT LIGHT/OTHER FLAMES/IGNITION SOURCES AT LOCATIONS DISTANT FROM HANDLING POINT. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB ON SAND/CLAY/OTHER ABSORBENT MATERIALS. ELIMINATE IGNITION SOURCES. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS CLOSED. STORE/USE AWAY FROM HIGH TEMPS/SPARKS/OPEN FLAME. GROUND CONTAINERS WHEN POURING/LIMIT FREE FALL TO FEW INCHES TO PREVENT Other Precautions:AVOID PROLONGED/REPEATED BREATHING OF VAPOR OR CONTACT WITH SKIN. KEEP OUT OF REACH OF CHILDREN. STATIC SPARKS. USE ONLY WITH ADEQUATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV IS EXCEEDED USE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:USE WITH ADEQUATE VENTILATION TO PREVENT EXCEEDING TLV. Other Protective Equipment:NONE Work Hygienic Practices:AVOID SKIN CONTACT. WASH CONTAMINATED SKIN/ CLOTHING WITH SOAP/WATER. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:300 TO 430F Vapor Pres:<1 Vapor Density:>AIR Spec Gravity:.840 Appearance and Odor:COLORLESS LIQUID WITH PETROLEUM DISTILLATE ODOR. Percent Volatiles by Volume:WT: 40 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXYGEN AND STRONG OXIDIZERS. Stability Condition to Avoid:KEEP AWAY FROM HEAT/SPARKS/FLAME/OTHER SOURCES OF IGNITION. Hazardous Decomposition Products:CARBON DIOXIDE AND CARBON MONOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:PLACE IN CLOSED CONTAINERS. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS GOVERNING COMBUSTIBLE WASTE.
1
gloves_mandatory