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===================== Product Identification ===================== Product ID:K-1 KEROSENE CAGE:0T116 CAGE:0T116 ============= Composition/Information on Ingredients ============= Ingred Name:KEROSENE, KEROSINE (SUSP ANIMAL CARC BY IARC) *96-4* CAS:8008-20-6 RTECS #:OA5500000 Other REC Limits:100 MG/CUM NIOSH Ingred Name:XYLENE, DIMETHYLBENZENE, XYLOL (IARC - GROUP 3) *96-4* CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 1-3% Other REC Limits:100 PPM OSHA PEL:100 PPM ACGIH TLV:100 PPM, SKIN EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:OCTANE CAS:111-65-9 RTECS #:RG8400000 Fraction by Wt: 1-2% Other REC Limits:300 PPM OSHA PEL:2350 MG/CUM ACGIH TLV:1400 MG/CUM Ingred Name:NONANE, N-NONANE CAS:111-84-2 RTECS #:RA6115000 Fraction by Wt: 0-1% Other REC Limits:200 PPM ACGIH TLV:1050 MG/CUM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: IRRITATION TO UPPER RESPIRATORY TRACT. SKIN: IRRITATION. EYES: IRRITATION (470 PPM/15 MIN). INGESTION: IRRITATION TO MUCOUS MEMBRANES OF THROAT, ESOPHAGUS & STOMACH. DEPRESSION MAY OCCUR I F ABSORBED. OVEREXPOSURE: CNS DEPRESSION. OXYGEN DEPRIVATION Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, DEPRESSION, DIZZINESS, HEADACHE, INCOORDINATION, ANESTHESIA, COMA, RESPIRATORY ARREST, DEFATTING, BURNING SENSATION, CHAPPING, PHOTOSENSITIVITY, SWELLING, VOMITING. OVEREXPOSURE: ANESTHESI A, COMA, RESPIRATORY ARREST, IRREGULAR HEART RATE. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED. INGESTION: DON'T INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. OBTAIN MEDICAL ATTENTION IN ALL CASES. NOTE TO PHYSICIANS: GASTRIC LAVAGE ONLY IF LARGE QUANTITY HAS BEEN INGESTED. (SEE SUPP) ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:<100F Extinguishing Media:FOAM, DRY CHEMICAL, CO2. Fire Fighting Procedures:WATER MAY BE INEFFECTIVE. WATER CAN BE USED TO COOL & PROTECT MATERIALS. USE AIR-SUPPLIED BREATHING APPARATUS IN ENCLOSED/CONFINED AREAS. Unusual Fire/Explosion Hazard:AUTOIGNITION TEMP: 450-500F. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE IGNITION SOURCES. CONFINE/VENTILATE AREA. USE EXPLOSION PROOF EQUIPMENT. ABSORB/CONFINE LIQUID W/SAND/OTHER SUITABLE MATERIALS. KEEP PRODUCT OUT OF SEWERS & WATERCOURSES. MINIMIZE BREATHING VAPORS & SKIN CONTACT. ======================Handling and Storage ====================== Handling and Storage Precautions:PROTECT FROM PHYSICAL DAMAGE. OUTSIDE/DETACHED STORAGE IS PREFERRED. STORE IN COOL, WELL VENTILATED AREA AWAY FROM IGNITION SOURCES & OXIDIZING AGENTS Other Precautions:TO PREVENT FIRE/EXPLOSION RISK FROM STATIC ACCUMULATION & DISCHARGE, GROUND PRODUCT TRANSFER SYSTEM IAW/NATIONAL FIRE PROTECTION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED UNDER NORMAL USE. USE NIOSH/MSHA APPROVED ORGANIC VAPOR RESPIRATORS WHERE SPRAY, MIST/VAPORS MAY CAUSE TLVS. SCBA IS REQUIRED IF CONCENTRATION EXCEEDS THE CAPACITY OF THE ORGANIC VAPOR CA NISTER. Ventilation:NOT REQUIRED UNDER NORMAL USE. Other Protective Equipment:STANDARD WORK CLOTHING. SHOWER, EYE WASH FACILITIES. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES BEFORE REUSE. DISCARD CLOTHES/FOOTWEAR THAT CAN'T BE DECONTAMINATED. Supplemental Safety and Health FIRST AID CONT'D: GUARD AGAINST ASPIRATION INTO LUNGS WHICH MAY RESULT IN CHEMICAL PNEUMONITIS. IRREGULAR HEART BEAT MAY OCCUR, USE OF ADRENALIN ISN'T ADVISABLE. TREAT SYMPTOMATICALLY. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:325-475F Vapor Pres:1 Vapor Density:>1 Spec Gravity:0.8 Solubility in Water:NEGLIGIABLE Appearance and Odor:CLEAR W/TYPICAL HYDROCARBON ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES LIQUID CHLORINE, CONCENTRATED OXYGEN, SODIUM HYPOCHLORITE, CALCIUM HYPOCHLORITE. Stability Condition to Avoid:IGNITION SOURCES. Hazardous Decomposition Products:FUMES, SMOKE, CO, ALDEHYDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:OBSERVE PRECAUTIONS FOR VOLATILE, COMBUSTIBLE VAPORS FROM ABSORBED MATERIAL. DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. CONTAMINATED MATERIAL WILL BE CONSIDERED A HAZARD IF THE FLASH POINT IS <140F.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:244-214 BRAKE LINING (NON-ASBESTOS) Preparer's Name:ROBERT M. TAMI CAGE:MO802 CAGE:65176 CAGE:MO802 CAGE:60250 ============= Composition/Information on Ingredients ============= Ingred Name:ALPHA-ALUMINA (ALUMINUM OXIDE) (SARA III) CAS:1344-28-1 RTECS #:BD1200000 Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:MINERAL WOOL CAS:65996-69-2 Other REC Limits:0.5 F/CC OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:BARIUM SULFATE CAS:7727-43-7 RTECS #:CR0600000 Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:COAL DUST (GREATER THAN OR EQUAL TO 5% SILICA) RTECS #:GF8281000 Other REC Limits:NONE RECOMMENDED OSHA PEL:0.1 MG/M3 RESP.FRACT ACGIH TLV:2 MG/M3 RESP.FRACT. Ingred Name:CALCIUM CARBONATE (MARBLE) (LIMESTONE) CAS:1317-65-3 RTECS #:EV9580000 Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:GRAPHITE, NATURAL CAS:7782-42-5 RTECS #:MD9659600 Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MPPCF RDUST ACGIH TLV:2 MG/M3 RDUST; 9293 Ingred Name:GLASS, FIBROUS RTECS #:LK3651000 Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 (DUST) ACGIH TLV:10 MG/M3 (DUST);9293 Ingred Name:MAN MADE VITREOUS FIBERS Other REC Limits:0.5 F/CC Ingred Name:IRON OXIDE CAS:1309-37-1 RTECS #:NO7400000 Other REC Limits:NONE RECOMMENDED OSHA PEL:10 MG/M3 (FE) ACGIH TLV:5 MG/M3(FE),B2; 9293 Ingred Name:CELLULOSE (PAPER FIBER) CAS:9004-34-6 RTECS #:FJ5691460 Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3; 9293 Ingred Name:CHSHEW/PHENOLIC RESINS Other REC Limits:5 MG/M3 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NOTE: PARTS ARE NOT INHERENTLY HAZARDOUS. ALL LISTED EFFECTS RELATE TO DUST RESIDUE ON PARTS OR TO DUST GENERATED IN INSTALLATION. MAY CAUSE TRANSIENT EYE IRRITATION WITH NO CORNEAL INJURY LIKELY IF F LUSHED IMMEDIATELY. MAY CAUSE SKIN IRRITATION. INHALATION MAY BE HARMFUL. INGESTION MAY IRRITATE GASTROINTESTINAL TRACT. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:EYE, SKIN & RESPIRATORY TRACT IRRITATION. LUNG DAMAGE MAY OCCUR IF EXPOSED TO LEVELS OF DUST ABOVE CURRENT LIMITS. Medical Cond Aggravated by Exposure:PEOPLE WITH HIGHLY SENSITIVE SKIN MAY DEVELOP A RASH. PERSONS WHO SMOKE OR HAVE A RESPIRATORY DISEASE MAY BE AT GREATER RISK WHEN EXPOSED TO DUST. ======================= First Aid Measures ======================= First Aid:SHOULD NOT BE NECESSARY DURING NORMAL HANDLING PROCEDURES. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:WATER. EXTINGUISHER CLASS A, B, AND C. Fire Fighting Procedures:POSITIVE PRESSURE, SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:FLAMMABLE ONLY IN OXYGEN-RICH ATMOSPHERE. ================== Accidental Release Measures ================== Spill Release Procedures:AVOID CREATING DUST. AVOID SWEEPING OR OTHERWISE GENERATING AIRBORNE PARTICULATE. USE APPROVED VACUUM METHODS. USE WET METHODS FOR CLEANING OR REMOVING DUST FROM DRUMS. DO NOT USE COMPRESSED AIR. AVOI D BREATHING DUST. USE RESPIRATOR FOR AIRBORNE DUST Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CREATING EXCESSIVE DUST. USE DUST COLLECTION IF GRINDING, DRILLING OR ALTERING PRODUCT IN ANY WAY. Other Precautions:PROTECTIVE CREAMS AND SLEEVES MAY BE NECESSARY FOR EMPLOYEES WITH SENSITIVE SKIN. CLEAN UP USING SOAP AND WATER PRIOR TO EATING. WASH CLOTHING SEPARATELY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED FOR PNEUMOCONIOSIS AND FIBROSIS PRODUCING DUSTS WITH TLV'S NOT LESS THAN 0.05 MG/M3. SUCH AS 3M 8710. FOLLOW RESPIRATOR STANDARD 1910.34 Ventilation:LOCAL EXHAUST IS RECOMMENDED TO MEET PEL/TLV IN SITUATIONS WHERE DUST IS GENERATED BY ABRASIVE ACTIONS. Other Protective Equipment:PROTECTIVE SLEEVES AND CREAMS FOR PERSONS WITH SENSITIVE SKIN. Work Hygienic Practices:CLEAN UP USING SOAP AND WATER PRIOR TO EATING. WASH CLOTHING SEPARATELY. Supplemental Safety and Health RECOMMEND MONITORING TO DETERMINE DUST & FIBER LIMITS IN ACCORDANCE WITH OSHA RECOMMENDED GUIDELINES. WORK AREAS SHOULD BE KEPT CLEAN & FREE FROM AIRBORNE DUST THROUGH ADEQUATE DUST COLLECTION & PROPE R VENTILATION. THIS IS A RESIN BONDED PRODUCT WHICH DOES NOT CONTAIN ASBESTOS & MEETS OSHA'S DEFINITION OF AN ARTICLE. ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:1.8-3.5 Evaporation Rate & Reference:0 Solubility in Water:NEGLIGIBLE Appearance and Odor:SOLID-LIGHT TAN TO DARK GRAY COLOR - SLIGHT SOUR ODOR Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN Hazardous Decomposition Products:NONE KNOWN ==================== Disposal Considerations ==================== Waste Disposal Methods:FOLLOW LOCAL, STATE AND FEDERAL REGULATIONS. PROPERLY MARK ALL CONTAINERS WITH APPROPRIATE LABELING AND DISPOSE IN LANDFILL IN COMPLIANCE WITH REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:9PR12 Kit Part:Y Preparer's Name:ABAYOMI I. OWEI CAGE:23373 CAGE:23373 ============= Composition/Information on Ingredients ============= Ingred Name:DIETHYLENE GLYCOL CAS:111-46-6 RTECS #:ID5950000 Fraction by Wt: >20% Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYES/SKIN:IRRITATION. INHALATION MINOR IRRITATION. INGESTION:STOMACH UPSET CHRONIC: NONE REPORTED BY MANUFACTURER. Explanation of Carcinogenicity:NONE OF THE CHEMICALS IN THIS PRODUCT IS LISTED BY IARC, NTP OR OSHA AS A CARCINOGEN. Effects of Overexposure:EYES/SKIN:IRRITATION. INHALATION:MINOR IRRITATION INGESTION:STOMACH UPSET. Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF SKIN AND RESPIRATORY DISORDERS MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:EYE: IMMEDIATELY FLUSH OF WATER FOR 15 MINUTES. GET MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER. INHALATION: REMOVE TO FRESH AIR AND GIVE ARTIFICIAL RES PIRATION IF NEEDED. SEEK MEDICAL HELP IMMEDIATELY. INGESTION:INDUCE VOMITING WITH 1-2 GLASSES WATER AND STICK FINGER DOWN THROAT. FOLLOW WITH 2-3 TABLESPOONS MILK OF MAGNESIAIN STRONG TEA WITH TOAST. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:200F,93C Autoignition Temp:Autoignition Temp Text:500F Extinguishing Media:USE WATER SPRAY, CARBON DIOXIDE, OR DRY CHEMICAL Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT, ELIMINATE SOURCES OF IGNITION, AND VENTILATE AREA AS REQUIRED. ABSORB SMALL SPILL WITH INERT ABSORBENT MATERIAL. KEEP LIQUID FROM ENTERING SEWERS/WATERWAYS. PLACE WASTE IN D OT APPROVED CONTAINER FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A WELL VENTILATED AREA AWAY FROM SOURCES OF IGNITION, STRONG ACIDS,OXIDIZERS OR DIRECT SUNLIGHT. KEEP CONTAINER CLOSED WHEN NOT IN USE. Other Precautions:DO NOT REUSE EMPTY CONTAINERS FOR ANYTHING ELSE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION EXPOSURES BELOW PEL (TLV), USE NIOSH/MSHA APPROVED RESPIRATOR AS PER CURRENT 29 CFR 1910.134, INSTRUCTIONS/WARNINGS AND NIOSH-RESPIRATOR SELECTION. USE NIOS H APPROVED ORGANIC VAPOR RESPIRATOR. Ventilation:MECHANICAL (GENERAL) VENTILATION IS USUALLY ADEQUATE. Other Protective Equipment:SAFETY SHOWER AND EYE BATH. INDUSTRIAL TYPE WORK CLOTHING AND APRON AS REQUIRED TO AVOID PROLONGED OR REPEATED CONTACT. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR DRINKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health KEY1:N1 THIS IS PART D UNDER THE SAME NSN. IT IS THE SECOND PART OF A TWO-PART SET. THE OTHER PART IS LISTED AS PART C UNDER THIS SAME NSN. (985-P13) ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:>200F,>93C Spec Gravity:1.094 pH:UNKNON Solubility in Water:GOOD Appearance and Odor:SLIGHTLY PINK VISCOUS LIQUID WITH MILD CHARACTERISTIC ODOR Percent Volatiles by Volume:UNKNON ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS AND STRONG ACIDS (NITRIC ACID) Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, AND OPEN FLAMES Hazardous Decomposition Products:CARBON DIOXIDE AND CARBON MONOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:807 2449;KODAK EKTACOLOR PRIME DEVELOPER REPLEN/RA-4; PT A Kit Part:Y CAGE:5K871 CAGE:19139 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 70-75% Other REC Limits:NONE RECOMMENDED Ingred Name:N,N-DIETHYLHYDROXYLAMINE CAS:3710-84-7 RTECS #:NC3500000 Fraction by Wt: 10-15% Other REC Limits:NONE RECOMMENDED Ingred Name:TRIETHANOLAMINE CAS:102-71-6 RTECS #:KL9275000 Fraction by Wt: 10-15% Other REC Limits:NONE RECOMMENDED ACGIH TLV:5 MG/M*3 Ingred Name:SUBSTITUED STILBENE CAS:82640-05-9 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CONTAINS TRIETHANOLAMINE;MAY CAUSE ADVERSE EFFECTS ON LIVER AND KIDNEYS.INHAL:HARMFUL IF INHALED.EYES:CAUSES IRRITATION.SKIN:CAUSES IRRITATION.HARMFUL IF ABSORBED THROUGH SKIN.INGEST:HARMFUL IF SWALLO WED. Explanation of Carcinogenicity:NOT A CARCINOGEN. Effects of Overexposure:CAUSES IRRITATION. Medical Cond Aggravated by Exposure:PERSONS WITH PREXISTING LIVER AND KIDNEY DISORDERS MAY BE AT RISK FROM EXPOSURE TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH WITH WATER.GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.SKIN:REMOVE CONTAMINATED CLOTHING;FLUSH WITH WATER FOR 15 MINUTES.GET MEDICAL ATTENTION.INHAL:MOVE TO FRESH AIR.TREAT SYMPTOMATICALLY.GET MEDICAL ATTENTION IF SYMPTOMS PERSIST.INGEST:CALL DOCTOR OR POISON CONTROL CENTER AT ONCE.INDUCE VOMITING AS DIRECTED BY MEDICAL PERSONNEL.DO NOT GIVE ANYTHING BY MOUTH. ===================== Fire Fighting Measures ===================== Flash Point:141F,61C Extinguishing Media:WATER SPRAY,CARBON DIOXIDE,DRY CHEMICAL,ALCOHOL FOAM. Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:**COMBUSTIBLE** COMBUSTIBLE VAPOR MAY ACCUMULATE IN THE CONTAINER HEADSPACE.ELEVATED TEMPERATURE MAY CAUSE DECOMPOSITION. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE SOURCES OF IGNITION.NEUTRALIZE PRIOR TO DISPOSAL.NEUTRALIZATION AND SEWERING MAY NOT BE ALLOWED.FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.OTHERWISE,ABSORB WITH VERMICULITE;PLACE IN CONTAINE R FOR CHEMICAL WASTE.CLEAN SPILL RESIDUE. Neutralizing Agent:DILUTE ACID(EG. VINEGAR). ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL PLACE.KEEP CONTAINERS CLOSED.KEEP AWAY FROM OXIDIZERS,HEAT AND FLAMES.USE WITH ADEQUATE VENTILATION. Other Precautions:AVOID PROLONGED OR REPEATED BREATHING OF MIST OR VAPOR.AVOID EYE AND SKIN CONTACT.USE WITH ADEQUATE VENTILATION.WASH HANDS AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE A NIOSH-MSHA APPROVED RESPIRATOR FOR ORGANIC VAPOR. Ventilation:USE GOOD GENERAL VENTILATION(TYPICALLY 10 AIR CHANGES PER HOUR).USE LOCAL EXHAUST WHERE VENTILATION IS POOR. Other Protective Equipment:EYE BATH,SAFETY SHOWER,WASHING FACILITIES. Work Hygienic Practices:USE REASONABLE CARE IN HANDLING THIS PRODUCT.WASH HANDS AFTER USE. Supplemental Safety and Health KEY1;F8. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:>212F,>100C Decomp Temp:Decomp Text:329F,165C Vapor Pres:18 Vapor Density:0.6 Spec Gravity:1.03 pH:10.8 Solubility in Water:COMPLETE Appearance and Odor:LIQUID;LIGHT YELLOW;SLIGHT AMINE Percent Volatiles by Volume:70-75 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:AVOID TEMPERATURES ABOVE 85C/149F. Hazardous Decomposition Products:CARBON MONOXIDE,CARBON DIOXIDE,OXIDES OF NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL STATE AND LOCAL REGULATIONS.NEUTRALIZATION AND SEWERING MAY NOT BE ALLOWED IN SOME STATES.SINCE CONTAINERS RETAIN RESIDUE;FOLLOW LABEL DIRECTIONS EVEN AFTER CONTA INER IS EMPTY.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FINISH, FLOOR, NONBUFFING Preparer's Name:J. P. GODINEZ CAGE:03256 CAGE:03256 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 57% Other REC Limits:NONE SPECIFIED Ingred Name:TRIBUTOXYETHYL PHOSPHATE CAS:78-51-3 RTECS #:KJ9800000 Fraction by Wt: 1.5% Other REC Limits:NONE SPECIFIED Ingred Name:ETHYLENE GLYCOL (SARA III) CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: 1.0% Other REC Limits:NONE SPECIFIED OSHA PEL:C 50 PPM ACGIH TLV:C 50 PPM,VAPOR; 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:DIPROPYLENE GLYCOL METHYL ETHER CAS:34590-94-8 RTECS #:JM1575000 Fraction by Wt: 1.1% Other REC Limits:NONE SPECIFIED OSHA PEL:S,100PPM/150STEL ACGIH TLV:S,100PPM/150STEL9192 Ingred Name:DIETHYLENE GLYCOL MONOETHYL ETHER CAS:111-90-0 RTECS #:KK8750000 Fraction by Wt: 2.6% Other REC Limits:NONE SPECIFIED Ingred Name:FLUORINATED SURFACTANT CAS:57534-41-5 RTECS #:ZI1800000 Fraction by Wt: 0.1% Other REC Limits:NONE SPECIFIED Ingred Name:ACRYLIC LATEX CAS:25987-66-0 Fraction by Wt: 35.5% Other REC Limits:NONE SPECIFIED Ingred Name:AMMONIUM HYDROXIDE(SARA III) CAS:1336-21-6 RTECS #:BQ9625000 Fraction by Wt: 0.3% Other REC Limits:NONE SPECIFIED EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:POLYESTER RESIN Fraction by Wt: 1.3% Other REC Limits:NONE SPECIFIED Ingred Name:POLYETHYLENE WAX EMULSION CAS:9002-88-4 RTECS #:TQ3325000 Fraction by Wt: 5.3% Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:UNKNOWN Skin:YES Ingestion:YES Health Hazards Acute and Chronic:SKIN AND EYES: POSSIBLE IRRITATION. INGESTION: POSSIBLE NAUSEA. ======================= First Aid Measures ======================= First Aid:SKIN & EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES, CALL PHYSICIAN IF IRRITATION PERSISTS. INGESTION: GIVE MILK OR WATER TO DRINK AND CALL PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:NONE Autoignition Temp:Autoignition Temp Text:*8.5 Extinguishing Media:WATER, FOAM, CO2, DRY CHEMICAL. Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:FLOOR MAY BE SLIPPERY, USE CAUTION TO AVOID FALLS. FLUSH AREA WITH WATER AND TAKE UP WITH WET VACUUM, FLUSH AND TAKE UP AGAIN. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE AT TEMPERATURES ABOVE 120 F OR BELOW 35 F. Other Precautions:USE NORMAL INDUSTRIAL HYGIENE PRACTICES. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED Ventilation:NORMAL VENTILATION Other Protective Equipment:NONE REQUIRED Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:212F,100C Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C Vapor Pres:20 MM HG Spec Gravity:1.03 pH:7.9-* Solubility in Water:SOLUBLE Appearance and Odor:OFF-WHITE MILKY EMULSION, VERY SLIGHT AMMONIA ODOR. Percent Volatiles by Volume:82 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:FOLLOW ALL FEDERAL AND LOCAL REGULATIONS. MAY BE SOLIDIFIED AND LANDFILLED OR USED IN SUPPLEMENTAL FUELS PROGRAM.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GLASS ENCLOSED MERCURY SWITCH CAGE:07187 CAGE:07187 CAGE:27319 ============= Composition/Information on Ingredients ============= Ingred Name:MERCURY CAS:7439-97-6 RTECS #:OV4550000 = Wt:100. Other REC Limits:NONE RECOMMENDED OSHA PEL:see Table Z-2 ACGIH TLV:0.025 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS: NONE FOR SWITCH (HMIS). IF RELEASED, MERCURY CAN BE ABSORBED SLOWLY THROUGH THE SKIN. EXCESSIVE EXPOSURE MAY CAUSE WEAKNESS, FATIGUE, LOSS OF WEIGHT, LOSS OF APPETITE, INSOMNIA, GASTRO INTESTINAL DISTURBANCES, TREMOR, GINGIVITIS. CHRONIC: UNKNOWN. Explanation of Carcinogenicity:NONE Effects of Overexposure:WEAKNESS, FATIGUE, LOSS OF WEIGHT, LOSS OF APPETITE, INSOMNIA, GASTROINTESTINAL DISTURBANCES, TREMOR, GINGIVITIS ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE AND/OR SUPPORT BREATHING AS NEEDED. ADMINISTER OXYGEN FOR CHEMICAL PNEUMONITIS. SEEK MEDICAL ATTENTION. EYE CONTACT: FLUSH WITH RUNNING WATER FOR 15 MINUTES. H OLD EYELIDS OPEN. SKIN: REMOVE CONTAMINATED CLOTHING. WASH AFFECTED AREAS WITH SOAP AND WATER. INGESTION: SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:SELECT MEDIA FOR SURROUNDING FIRE. Fire Fighting Procedures:SELF-CONTAINED BREATHING APPARATUS SHOULD BE USED IF METAL IS EXPOSED TO HEAT. Unusual Fire/Explosion Hazard:NON-FLAMMABLE. MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. ================== Accidental Release Measures ================== Spill Release Procedures:IF A SWITCH IS BROKEN, NOTIFY SAFETY PERSONNEL. PROVIDE ADEQUATE VENTILATION. CLEAN UP SPILL PROMPTLY. A SUCTION BOTTLE WITH CAPILLARY TUBE CAN BE USED FOR SMALL AMOUNTS. CALCIUM POLYSULFIDE WITH EXCE SS SULFUR CAN BE SPRINKLED ON THE MERCURY TO CONVERT IT TO MERCURY SULFIDE. COLLECT ALL PARTS OF BROKEN SWITCH IN SEALED CONTAINER. PREVENT SKIN CONTACT. Neutralizing Agent:CALCIUM POLYSULFIDE WITH EXCESS SULFUR ======================Handling and Storage ====================== Handling and Storage Precautions:SWITCHES MUST BE CUSHIONED FROM PHYSICAL DAMAGE. Other Precautions:KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH-APPROVED FULL FACE PIECE GAS MASK EQUIPPED WITH HIGH EFFIFCIENCY FILTER PLUS CANISTER CONTAINING IODINE-IMPREGNATED CHARCOAL. Ventilation:GENERAL OR LOCAL EXHAUST ADEQUATE TO MEET TLV. Other Protective Equipment:EYE BATH, WASHING FACILITY, LAB COAT OR UNIFORM. Work Hygienic Practices:AVOID EYE CONTACT. OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. WASH AFTER HANDLING AND BEFORE EATING, DRINKING OR SMOKING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:Z2 Boiling Pt:=354.4C, 670.F Vapor Pres:68F=0.0012, 260F=1.0 MMHG Vapor Density:DEPENDS Spec Gravity:(H2O=1) 13.55 Evaporation Rate & Reference:(ETHYL ETHER=1) N.D. Solubility in Water:NEGLIGIBLE Appearance and Odor:GLASS ENCLOSED MERCURY SWITCH (SILVERY WHITE, HEAVY LIQUID METAL) Percent Volatiles by Volume:N.A. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACETYLENES, AMMONIA, ALKALI METAL, CHLORINE DIOXIDE, METHYL AZIDE. Stability Condition to Avoid:BREAKAGE Hazardous Decomposition Products:INORGANIC MERCURY VAPORS ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT DISCHARGE MERCURY DOWN DRAIN. DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL LAWS AND REGULATIONS. ======================================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TOLUENE Preparer's Name:NISHANT CAGE:69267 Contract Num:SP0450-00-M-SB12 CAGE:1ELU0 CAGE:69267 ============= Composition/Information on Ingredients ============= Ingred Name:TOLUENE CAS:108-88-3 RTECS #:XS5250000 > Wt:60. OSHA PEL:SEE TABLE Z-2 ACGIH TLV:188 MG/M3;50 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: SEVERE IRRITATION SKIN: MODERATE IRRITATION, DEFATTING . BREATHING: NASAL AND RESPIRATORY IRRITATION. MAY BE POISONOUS IF INGALED OR ABSORBED THROUGH SKIN. VAPORS MAY CAUSE DIZZINESS OR SU FFOCATION. CONTACT MAY IRRITATE OR BURN SKIN AND EYES. Explanation of Carcinogenicity:NONE LISTED. Effects of Overexposure:EYES: SEVERE IRRITATION SKIN:MODERATE IRRITATION, DEFATTING . BREATHING: NASAL AND RESPIRATORY IRRITATION. MAY BE POISONOUS IF INHALED OR ABSORBED THROUGH SKIN. VAPORS MAY CAUSE DIZZINESS OR SU FFOCATION. CONTACT MAY IRRITATE OR BURN SKIN AND EYES. ======================= First Aid Measures ======================= First Aid:SKIN: WASH AREA WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING-WASH BEFORE RE-USE. EYES: FLUSH WITH LARGE AMTS OF WATER. SWALLOWED: DO NOT INDUCE VOMITING KEEP PERSON WARM, QUIET GET MEDICAL A TTENTION. BREATHED:REMOVE TO FRESH AIR. KEEP PERSON WARM, QUIET. ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:=4.4C, 40.F Lower Limits:1.2 Upper Limits:7.0 Extinguishing Media:DRY CHEMICAL, REGULAR FOAM. WATER FOG, CARBON DIOXIDE Fire Fighting Procedures:SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE. Unusual Fire/Explosion Hazard:VAPORS MAY TRAVEL ALONG THE GROUND AND CAUSE FLASH FIRES OR BE IGNITED BY PILOT LIGHTS, LFAMES, SPARKS. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL SPILL: ABSORB LIQUID ON PAPER, VERMICULITE, FLOOR ABSORBENT AND TRANSFER TO HOOD.LARGE SPILL: ELIMINATE ALL IGNITION SOURCES, EXCLUDE PEOPLE FROM AREA NOT WEARING PROTECTIVE EQUIPMENT. STOP S PILL AT SOURCE RESIDUAL LIQUID MAY BE TAKEN UPON SAND, CLAY. ======================Handling and Storage ====================== Handling and Storage Precautions:PROTECT CONTAINERS AGAINST PHYSICAL DAMAGE. OUTDOOR OR DETACHED STORAGE IS PREFERABLE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MESA JOINTLY APPROVED SELF-CONTAINED BREATHING APPARATUS. Ventilation:AS REQUIRED TO CONTROL TLV IN AIR Other Protective Equipment:WEAR IMPERVIOUS CLOTHING AND BOOTS. Supplemental Safety and Health SWALLOWING: STOMACH IRRITATION, NAUSEA, VOMITING, DIARRHEA, CHEMICAL PNEUMONITIS (FATAL). SELF CONTAINED BREATHING APPARATUS MUST BE OPERATED IN A PRESSURE DEMAND OR OTHER POSITIVE PRESSURE MODE. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:=111.1C, 232.F Vapor Pres:38(MM HG/70F) Vapor Density:4.5 (AIR=1 Spec Gravity:0.871 Solubility in Water:NEGLIGIBLE Appearance and Odor:COLORLESS, BENZENELIKE ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH STRONG OXIDIZING AGENTS Hazardous Decomposition Products:CO2, CO WHEN BURNED ==================== Disposal Considerations ==================== Waste Disposal Methods:SMALL SPILL: ALLOW VOLATILE PORTION TO EVAPORATE IN DESTROY BTY LIQUID INCINERATION UNDER CONTROLLED CONDITIONS. MATERIAL COLLECTED ON ABSORBENT MATERIAL MAY BE DEPOSITED IN LANDFILL. =================== MSDS Transport Information =================== Transport Information:DOT PROPER SHIPPING NAME: TOLUENE, CLASS 3, UN1294, PKG II.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:COSMOLUBRIC 684 Preparer's Name:DAVID H EADLINE CAGE:73227 CAGE:73227 CAGE:73277 ============= Composition/Information on Ingredients ============= Ingred Name:LEAD DIAMYLDITHIOCARBAMATE.LD50 RAT ORAL >5 ML/KG. CAS:36501-84-5 Fraction by Wt: <1% Other REC Limits:N/K OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:N/K Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SEE SIGNS AND SYMPTOMS OF OVEREXPOSURE. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES:IRRITATION.SKIN:PROLONGED CONTACT MAY BE MILDLY IRRITATING.INGESTION/INHALATION:N/K . Medical Cond Aggravated by Exposure:NONE KNOWN ======================= First Aid Measures ======================= First Aid:EYES:FLUSH WITH WATER FOR AT LEAST 15 MINUTES.CONSULT PHYSICIAN.SKIN:WASH WITH SOAP AND WATER.INGESTION:CONTACT A PHYSICIAN.INHALATION:REMOVE TO FRESH AIR.SUPPORT BREATHING (GIVE 02/ ARTIFICIAL RESPIR ATION) .MD NOTE:USE STOMACH PUMP IF INGESTED. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:420F,215.56C Extinguishing Media:CARBON DIOXIDE,FOAM,DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:HAZARDOUS DECOMPOSITION PRODUCTS:OXIDES OF CARBON. ================== Accidental Release Measures ================== Spill Release Procedures:APPLY DRY OIL ABSORBENT TYPE MATERIAL AND SWEEP UP. Neutralizing Agent:N/K ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTACT WITH STRONG OXIDIZERS.AVOID EXCESSIVE SKIN CONTACT.AVOID INGESTION. Other Precautions:SAME AS FOR HANDLING LUBRICANT OILS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED Ventilation:MECHANICAL (GENERAL) ADEQUATE FOR GENERAL USE. Other Protective Equipment:NOT REQUIRED Work Hygienic Practices:STANDARD HYGIENIC WORK PRACTICES ARE SATISFACTORY. Supplemental Safety and Health BOILING POINT:HIGH;WIDE RANGE.FIRE POINT: 450F,232.22C.PRODUCT CONTAINS A SMALL AMOUNT OF LEAD SOAP. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:SEE SUPP Decomp Temp:Decomp Text:N/K Vapor Pres:NIL Vapor Density:>1,AIR=1 Spec Gravity:0.915,WATER=1 Evaporation Rate & Reference:NIL Solubility in Water:INSOLUBLE Appearance and Odor:GREEN FLUID WITH A BLAND ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS Hazardous Decomposition Products:OXIDES OF CARBON Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS .MAY BE INCINERATED UNDER CONTROLLED CONDITIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HATCOL 4283, ,4282,4285 CAGE:3W990 CAGE:3W990 ============= Composition/Information on Ingredients ============= Ingred Name:SYNTHETIC HYDROCARBON-BASED SLUID Fraction by Wt: UNK Ingred Name:SYNTHETIC ESTER-BASED FLUID(OIL) Fraction by Wt: UNK ===================== Hazards Identification ===================== Effects of Overexposure:MAY BE A SLIGHT SKIN/EYE IRRITANT ALTHOUGH BELIEVD ESSENTIALLY NONTOXIC;MAY CAUSE DIARRHEA IF INGSTD ======================= First Aid Measures ======================= First Aid:SKIN:WASH W.SOAP & H*2O. EYES:FLUSH W. H*2O. INGESTED:DON'T INDUCE VOMITING. INHALED:REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEED. KEEP WARM & QUIET. REMOVE CONTAMINATED CLOTHING. NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point:400F-(COC) Lower Limits:UNK Upper Limits:UNK Extinguishing Media:CO*2, FOAM, DRY CHEM. Fire Fighting Procedures:DO NOT USE WATER Unusual Fire/Explosion Hazard:NONE KNOWN ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE UNPROTECTED PERSONS. ELIM IGNITION SOURCES. STOP LEAK. H*2O SPRAY COOL CONT/DIVERT SPILL FROM FIRE/HEAT. PROVIDE VENTILATION. ABSORB W COMMERCIAL ABSORBENT,SHOVEL INTO METAL DRUMS:LG SPILL:DI KE W COMMERCIAL ABSORBENT,PUMP INTO COVERED DRUMS. ======================Handling and Storage ====================== Handling and Storage Precautions:USE NORMAL PRECAUTIONS FOR HANDLING LUBRICANTS.KEEP CONTAINERS TIGHTLY CLOSED. Other Precautions:MAY ATTACK SOME PAINTS & RUBBER MATERIAL;USE/WEAR EXPOSURE/CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED UNDER NORMAL CONDITIONS Ventilation:LOCAL EXHAUST:IF ADEQUATE Other Protective Equipment:AS REQUIRED TO PREVENT PROLONGED CONTACT. Supplemental Safety and Health MSDS UNDATED;SPEC REFERENCE:MIL-H-83282B ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:B.P. Text:>500F Vapor Pres:<1 Spec Gravity:0.85 Evaporation Rate & Reference:NEGLIGIBLE Solubility in Water:NEGLIGIBLE Appearance and Odor:LIGHT AMBER MOBIL LIQD,ALIPHATIC HYDROCARBON ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDANTS,ACIDIC OR CAUSTIC CONDITIONS Hazardous Decomposition Products:NONE NOTED,BUT EXPECT CO, CO*2, H*2O. ==================== Disposal Considerations ==================== Waste Disposal Methods:KEEP IN COVERED DRUMS,PENDING DISPOSAL. HANDLE & DISPOSE IN FULL COMPLIANCE WITH ALL APPLICABLE INTERNATIONAL,FEDERAL,STATE, & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:08106 MOORWOOD SEMI TRANSPARENT STAIN TINTING BASE CAGE:09585 CAGE:09585 CAGE:91950 ============= Composition/Information on Ingredients ============= Ingred Name:CRYSTALLINE-QUARTZ SILICA, SILICA DUST (SUSPECTED HUMAN CARCINOGEN BY IARC-GROUP 2A; SUSPECTED CARCINOGEN NTP) *96-4* CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: <19.3% Other REC Limits:0.05 MG/CUM (NIOSH) OSHA PEL:10 MG/CUM %RESP SIO2 ACGIH TLV:0.1 MG/CUM RESP DUST Ingred Name:BENTONITE CLAY CAS:121888-66-2 Fraction by Wt: <3.3% Ingred Name:STODDARD SOLVENT (PETROLEUM DISTILLATE), MINERAL SPIRITS *96-4* CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: <31.1% Other REC Limits:525 MG/CUM OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:METHYL ETHYL KETOXIME CAS:96-29-7 RTECS #:EL9275000 Fraction by Wt: <0.1% Ingred Name:FOLPET, N-(TRICHLOROMETHYTHIO)PHTHALATE N-(TRICHLOROMETHYL) THIOPHTHALIMIDE CAS:133-07-3 RTECS #:TI5685000 Fraction by Wt: <1.4% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:INHALATION: HARMFUL. MAY AFFECT THE BRAIN/NERVOUS SYSTEM. EYES: IRRITATION. SKIN: MAY BE ABSORBED IN SUFFICIENT QUANTITIES TO CAUSE SYSTEMIC TOXICITY. INGESTION: IRRITATION TO DIGESTIVE TRACT & NERVOU S SYSTEM DEPRESSION. ASPIRATION OF MATERIAL INTO LUNGS MAY CAUSE LUNG INFLAMMATION & DAMAGE. (SEE SUPP) Explanation of Carcinogenicity:SEE INGREDIENTS Effects of Overexposure:DIZZINESS, HEADACHE, NAUSEA, IRRITATION, DROWSINESS, LOSS OF COORDINATION, FATIGUE. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. SKIN: REMOVE W/SOAP & WATER. EYES: FLUSH W/WATER. INGESTION: DRINK 1-2 GLASSES OF WATER TO DILUTE. DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:107F Lower Limits:1 Extinguishing Media:FOAM, CO2, DRY CHEMICAL, WATER FOG Fire Fighting Procedures:COOL EXPOSED CONTAINERS W/WATER. WEAR SCBA. DON'T USE WATER STREAM ON BURNING LIQUID. Unusual Fire/Explosion Hazard:TOXIC GASES MAY FORM WHEN PRODUCT BURNS. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE IGNITION SOURCES. AVOID BREATHING VAPORS. USE NON-SPARKING TOOLS TO RETURN MATERIALS TO CONTAINER. ABSORB RESIDUE W/FULLERS EARTH. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT & FLAME. CLOSE CONTAINER AFTER EACH USE. Other Precautions:AVOID CONTACT W/SKIN & BREATHING OF VAPOR SPRAY MIST/SANDING DUST. KEEP OUT OF REACH OF CHILDREN. DON'T TAKE INTERNALLY. NOTE: THIS PRODUCT CONTAINS PIGMENTS WHICH MAY BECOME A DUST NUISANCE WHEN REMO VED BY ABRASIVE BLASTING/SANDING, ETC. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR A PROPERLY FITTED VAPOR/PARTICULATE APPROVED BY NIOSH/MSHA FOR USE W/PAINTS DURING APPLICATION/SANDING. IN CONFINED SPACES, USE POSITIVE-PRESSURE, SUPPLIED AIR RESPIRATOR. Ventilation:MECHANICAL EXHAUST IN CONFINED AREAS. Other Protective Equipment:SAFETY GLASSES W/SIDE SHIELDS. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH THOROUGHLY BEFORE EATING, SMOKING/USING RESTROOMS. Supplemental Safety and Health HEALTH HAZARDS CONT'D: PROLONGED/REPEATED SKIN CONTACT MAY CAUSE DERMATITIS & ALLERGIC REACTION. REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS MAY CAUSE PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. INTENTIO NAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING THE CONTENTS MAY BE HARMFUL/FATAL. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:313-388F Vapor Density:>1 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:ALL COLORS Percent Volatiles by Volume:43.1 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:HEAT, FLAME, ELEVATED TEMP Hazardous Decomposition Products:BURNING: CO2, CO ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. DON'T INCINERATE SEALED CONTAINERS. COMBUSTIBLE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TT-E-2784 Preparer's Name:ONEY FLEMING CAGE:EO326 CAGE:EO326 CAGE:39934 ============= Composition/Information on Ingredients ============= Ingred Name:EKTASOLVE EEH SOLVENT CAS:1559-35-9 RTECS #:KK9625000 Fraction by Wt: 3.32% Other REC Limits:NONE RECOMMENDED Ingred Name:BENZYL ALCOHOL CAS:100-51-6 RTECS #:DN3150000 Fraction by Wt: 3.32% Other REC Limits:NONE RECOMMENDED Ingred Name:DIMETHYLAMINOETHANOL LOW VOE CAS:108-01-0 RTECS #:KK6125000 Fraction by Wt: 0.38% Other REC Limits:NONE RECOMMENDED Ingred Name:NON-HAZARDOUS INGREDIENTS Fraction by Wt: 92.98% Other REC Limits:NONE RECOMMENDED Ingred Name:VOC: 1.8 LB/GL; 211 G/LTR RTECS #:9999999VO Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CAN CAUSE IRRITATION OF RESPIRATORY PASSAGES. Effects of Overexposure:INHALATION OF VAPOR OR MIST CAN CAUSE HEADACHES, NAUSEA, IRRITATION OF NOSE, THROAT, AND LUNGS. EYE CONTACT CAN CAUSE SLIGHT IRRITATION. PROLONGED OR REPEATED SKIN CONTACT CAN CAUSE SLIGHT IRRITATION. Medical Cond Aggravated by Exposure:PRE-EXISTING LUNG DISEASE MAY BE AGGRAVATED BY EXPOSURE. ======================= First Aid Measures ======================= First Aid:EYE CONTACT: FLUSH WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES, CONSULT PHYSICIAN IF IRRITATION PERSISTS. SKIN CONTACT: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER. INGESTION: IF SWALLOWED, GIVE 2 GLASSES OF WATER TO DRINK, CONSULT PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:>212F,>100C Autoignition Temp:Autoignition Temp Text:216 F Lower Limits:NONE Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS (PRESSURE DEMAND MSHA/NIOSH APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR. Unusual Fire/Explosion Hazard:MATERIAL CAN SPLATTER ABOVE 100C. POLYMER FILM CAN BURN. ================== Accidental Release Measures ================== Spill Release Procedures:KEEP SPECTATORS AWAY. FLOOR MAY BE SLIPPERY, USE CARE TO AVOID FALLING. CONTAIN SPILLS WITH INERT MATERIALS (SAND, EARTH). TRANSFER LIQUIDS AND SOLID DIKING MATERIAL TO SEPARATE SUITABLE CONTAINERS FO R RECOVERY/DISPOSAL. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP FROM FREEZING. Other Precautions:DO NOT TAKE INTERNALLY. KEEP AWAY FROM CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:APPROVED MECHANICAL FILTER RESPIRATOR TO REMOVE SOLID AIRBORNE PARTICLES OF OVER SPRAY DURING SPRAY APPLICATION. Ventilation:NORMAL, SUCH AS A FAN Other Protective Equipment:EYE WASH STATION. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:212 TO 644F Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C Decomp Temp:Decomp Text:350F,177C Vapor Pres:NONE Vapor Density:> AIR Spec Gravity:1.01 (WATER=1) pH:9 MAX Viscosity:77-95 KU Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:SLIGHT Appearance and Odor:LT GRAY LIQUID WITH SLIGHT ODOR Percent Volatiles by Volume:60.6 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES THERE ARE NO KNOWN MATERIALS WHICH ARE INCOMPATIBLE WITH THIS PRODUCT. Stability Condition to Avoid:NONE Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY YIELD ACRYLIC MONOMERS. ==================== Disposal Considerations ==================== Waste Disposal Methods:KEEP SPILLS AND CLEANING RUN-OFF OUT OF MUNICIPAL SEWERS AND OPEN BODIES OF WATER. CONSULT FEDERAL, STATE, OR LOCAL AUTHORITIES FOR PROPER DISPOSAL PROCEDURES CONCERNING HEALTH AND ENVIRONMENT.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FOIL BACK WALLBOARD Preparer's Name:NORBERT W KALETA CAGE:85074 CAGE:85074 ============= Composition/Information on Ingredients ============= Ingred Name:CALCIUM (II) SULFATE, DIHYDRATE (1:1:2); (GYPSUM) CAS:10101-41-4 RTECS #:EW4150000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (QUARTZ) CAS:14808-60-7 RTECS #:VV7330000 OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 RDUST Ingred Name:CELLULOSE; (CELLULOSE (PAPER FIBER)) CAS:9004-34-6 RTECS #:FJ5691460 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: GOLD BOND BOARD PRODUCTS DO NOT PRESENT AN INHALATION, INGESTION OR CONTACT HEALTH HAZARD UNLESS SUBJECTED TO OPERATIONS SUCH AS SAWING, SANDING OR MACHINING WHICH RESULT IN THE GENERATION OF A IRBORNE PARTICULATE. SKIN: CONTINUED AND PROLONGED CONTACT MAY RESULT IN DRYING. EYES: DIRECT CONTACT (EFTS OF OVEREXP) Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ: IARC MONO, VOL 68, 1997: GROUP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994: ANTIC TO BE (SUP DAT) Effects of Overexposure:HLTH HAZ: MAY CAUSE MECHANICAL IRRITATION. INHALATION: TARGET ORGANS: RESPIRATORY SYSTEM. SIGNS AND SYMPTOMS OF EXPOSURE TO AIRBORNE DUST: CONTINUED AND PROLONGED EXPOSURE TO AIRBORNE DUST CONCENTRATI ONS IN EXCESS OF THE PEL/TLV MAY RESULTIN COUGH, DYSPNEA, WHEEZING AND IMPAIRED PULMONARY FUNCTION. Medical Cond Aggravated by Exposure:OVEREXPOSURE WOULD GENERALLY AGGRAVATE RESPIRATORY SYSTEM DYSFUNCTIONS. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES AND GET MEDICAL ATTENTION. SKIN: FLUSH AND WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. INHALATION: MOVE THE PERSO N TO FRESH AIR AT ONCE. IF NOT BREATHING INITIATE PULMONARY RESUSCITATION. GET MEDICAL ATTENTION. INGESTION: CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL, FOAM, WATER FOG OR SPRAY. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:PICKUP TO AVOID TRIPPING HAZARD. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP DRY TO PRESERVE USEFULNESS. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A NIOSH APPROVED RESPIRATOR FOR TOXIC DUSTS IS RECOMMENDED IF THE PEL/TLV IS EXCEEDED. Ventilation:PROVIDE VENTILATION TO MAINTAIN A DUST LEVEL BELOW THE PEL/TLV. Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:THE SCORE AND SNAP METHOD FOR CUTTING IS RECOMMENDED. SAWING, DRILLING OR MACHINING WILL PRODUCE DUST. Supplemental Safety and Health EXPLAN OF CARCIN: CARCIN. HUMAN: LUNG. ================== Physical/Chemical Properties ================== Appearance and Odor:GYPSUM CORE WRAPPED WITH PAPER; SURFACE FINISH WILL VARY WITH PRODUCT; NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:WHEN HEATED TO DECOMPOSITION OXIDES OF SULFUR AND CARBON WILL BE RELEASED. ==================== Disposal Considerations ==================== Waste Disposal Methods:NOT A HAZARDOUS WASTE. DISPOSE OF IN ACCORDANCE WITH APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: 1848B 001 ISO 100 KERR MCGEE PRIZE R & O TURBINE OIL Cage: 3F020 Box: 26868 Proprietary Ind: Y ======================================================= Preparer Co. when other than Responsible Party Co. ======================================================= Cage: 3F020 Box: 26868 ======================================================= Contractor Summary ======================================================= Cage: 3F020 Box: 26868 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: YES Skin: NO Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: INHALATION: PETROLEUM OIL MIST CAN CAUSE RESPIRATORY IRRITATION. SKIN: MINOR IRRITATION W/PROLONGED/REPEATED CONTACT. EYES: MINOR IRRITATION. INGESTION: MAY CAUSE IRRITATION. MAY BE HAMRFUL IF INHALDE D/SWALLOWED. Explanation Of Carcinogenicity: NONE Signs And Symptions Of Overexposure: IRRITATION, DISCOMFORT, NAUSEA & DIARRHEA. Medical Cond Aggravated By Exposure: PRE-EXISTING SKIN DISORDERS. First Aid: INHALATION: REMOVE TO FRESH AIR. GIVE CPR IF BREATHING HAS STOPPED. SKIN: WASH EXPOSED PORTION W/SOAP & WATER. EYES: FLUSH IMMEDIATLEY W/WATER FOR 15 MINS. INGESTION: DON'T INDUCE VOMITING. POSSIBLE A SIPATION HAZARD. OBTAIN MEDICAL ATTENTION IN ALL CASES. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: EVACUATE AREA & REMOVE IGNITION SOURCES. BUILD DIKE TO CONTAIN FLOW. REMOVE FREE LIQUID, DON'T FLUSH TO SEWER/OPEN WATER. PICK UP RESIDUE W/INERT-ABSORBANT & PLACE IN CLOSED CONTAINER FOR DISPOSAL. Waste Disposal Methods: LIQUIDS ARE BANNED FROM LANDFILLING. CONSIDER RECYCLING/CONTROLLED INCINERATION: DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. Handling And Storage Precautions: STORE CLEAN, DRY, <120F TO PRESERVE FOR INTENDED USE. DON'T STORE W/STRONG OXIDIZERS. STORE AS OSHA CLASS II COMBUSTIBLE LIQUID. Other Precautions: USE W/ADEQUATE VENTILATION. KEEP OUT OF REACH OF CHILDREN. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: 470F Extinguishing Media: CO2, DRY CHEMICAL/FOAM Fire Fighting Procedures: WATER STREAM MAY SPREAD FIRE. USE WATER SPRAY ONLY TO COOL CONTAINERS NOT ON FIRE. Unusual Fire/Explosion Hazard: WILL FORM FLAMMABLE MIXTURES W/AIR WHEN HEATED TO 470F. WILL NOT FLASH SPONTANEOUSLY. ======================================================= Control Measures ======================================================= Respiratory Protection: UP TO 25 MG/CUM, HALF-MASK ORGANIC VAPOR RESPIRATOR. UP TO 50 MG/CUM, FULL FACE ORGANIC VAPOR RESPIRATOR/FULL FACE SELF CONTAINED RESPIRATOR. >50 MG/CUM, FIRE FIGHTING/UNKOWN CONCENTRATION, USE SCBA W /POSITIVE PRESSURE. Ventilation: LOCAL/DILUTION TO KEEP AIR CONCENTRATION BELOW TLV/PEL. Other Protective Equipment: FACE SHIELD. Work Hygienic Practices: REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: >600F Vapor Density: >1 Spec Gravity: 0.88 Evaporation Rate & Reference: SLOWER THAN N-BU AC Appearance and Odor: AMBER LIQUID ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: OIL MIST & EXCESSIVE HEAT Materials To Avoid: STRONG OXIDIZERS Hazardous Decomposition Products: CARBON SMOKE, CO, VARIOUS HYDROCARBONS, OTHER TOXIC GASES/VAPORS. Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: 1848B 001 ISO 100 KERR MCGEE PRIZE R & O TURBINE OIL Cage: 3F020 Company Name: CATO OIL AND GREASE CO INC Street: 915 MARTIN LUTHER KING PO Box: 26868 Zipcode: 73126 Label Required IND: Y Date Of Label Review: 09/14/1994 Status Code: C Label Date: 09/14/1994 Origination Code: F Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Slight Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: INHALATION: PETROLEUM OIL MIST CAN CAUSE RESPIRATORY IRRITATION. SKIN: MINOR IRRITATION W/PROLONGED/REPEATED CONTACT. EYES: MINOR IRRITATION. INGESTION: MAY CAUSE IRRITATION. MAY BE HAMRFUL IF INHALDE D/SWALLOWED. TARGET ORGANS: RESPIRATORY& DIGESTIVE TRACTS. INOGENS: 2,4-TOLUENE DIISOCYANATE & SILICON DIOXIDE. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:REPROSIL HEAVY BODY CATALYST CAGE:11107 CAGE:11107 ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS FOR INGREDIENTS Fraction by Wt: 100% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY IRRITATES THE EYES/SKIN. SKIN: POSSIBLE REDDISH RASHES. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATES THE EYES/SKIN. SKIN: POSSIBLE REDDISH RASHES. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/LARGE AMOUNTS OF WATER, CONSULT PHYSICIAN. SKIN: WASH THOROUGHLY WITH SOAP & WATER. CONSULT PHYSICIAN. INGESTION: CONSULT PHYSICIAN IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:>415F Extinguishing Media:SAND, FOAM, CO2, DRY CHEMICAL Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & FULL PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:DURING A FIRE, IRRITATING/TOXIC GASES & AEROSOLS MAY BE FROM THE DECOMPOSITION/COMBUSTION PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:COVER WITH AN ABSORBENT MATERIAL SUCH AS SAND OR SAWDUST; SCOOP UP & PLACE IN AN APPROPRIATELY MARKED CONTAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM FOODSTUFFS, BEVERAGES, & EXTREME HEAT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED Ventilation:LOCAL EXHAUST Other Protective Equipment:RUBBER APRON Work Hygienic Practices:OBSERVE NORMAL CARE FOR WORKING WITH CHEMICALS. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>392F Spec Gravity:1.45 Evaporation Rate & Reference:(BU AC = 1): <1 Solubility in Water:NOT SOLUBLE Appearance and Odor:GREY COLORED PASTE WITH FAINT SWEET ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONDENSATION SILICONE Stability Condition to Avoid:EXTREME HEAT ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE MATERIAL MAY BE INCINERATED UNDER CONDITIONS WHICH MEET FEDERAL, STATE & LOCAL ENVIRONMENTAL CONTROL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:NORDEL HYDROCARBON RUBBER,1145 DIV) CAGE:1N612 CAGE:1N612 ============= Composition/Information on Ingredients ============= Ingred Name:1,4-HEXADIENE, POLYMER WITH ETHENE AND 1-PROPENE; (EPDM RUBBER) CAS:25038-37-3 Other REC Limits:PEL:5 MG/M3 RDUST(M) OSHA PEL:15 MG/M3 TDUST ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:(ORAL,RAT) >7,500 MG/KG. Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PROLONGED OR REPEATED CONTACT MAY CAUSE MILD SKIN IRRITATION IN SENSITIVE INDIVIDUALS. HOT POLYMER CAUSES THERMAL BURNS. EXPOSURE LIMITS: FOR PRODUCT - USE STANDARD FOR PARTICULATES, N.O.C. OSHA PEL/T WA: 15 MG/ CU M (TOTAL DUST), 5 MG/CU M (RESPIRABLE DUST). Explanation of Carcinogenicity:NONE. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:UNKNOWN. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES REPEATED BY HOLDING EYELIDS OPEN TO ENSURE PROPER IRRIGATION. SKIN: IF MOLTEN POLYMER GETS ON SKIN, COOL RAPIDLY WITH COLD WATER. DO NOT ATTEMPT TO PEEL POLYMER FROM SKIN. OBTAIN MEDICAL TREATMENT FOR THERMAL BURNS. INHALATION: REMOVE TO FRESH AIR. KEEP WARM & QUIET. GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING. CONSULT MD. INGESTION: SEEK MEDICAL ATT ENTION IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:>260.C, 500.F Autoignition Temp:>300.C, 572.F Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . REGULAR PROCEDURES FOR RUBBER FIRES. Unusual Fire/Explosion Hazard:NORDEL SOMETIMES CONTAINS LOWER MOLECULAR WEIGHT COMPONENTS WHICH CAN VOLATILIZE & MAY IGNITE DURING PROCESSING. MIXERS SHOULD BE VENTILATED & IGNITION SOURCES AVOIDED TO ELIMINATE POSSIBILITY OF A FI RE. NFPA ID SYSTEM: HEALTH: 1, FLAMMABILITY: 1, REACTIVITY: 0. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP SPILLAGE AND TRANSFER INTO A CLOSED CONTAINER FOR DISPOSAL. RECOVER UNDAMAGED MATERIAL FOR REUSE AND RECLAMATION. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID INHALING DUST OR FUMES. USE WITH ADEQUATE VENTILATION. STORE IN A WELL VENTILATED COOL PLACE. AVOID CONTACT WITH SKIN AND EYES. Other Precautions:READ BULLETIN ND-110.1 ENTITLED "TOXICITY AND HANDLING GUIDELINES FOR NORDEL" BEFORE USING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED RESPIRATORS SHOULD DUST OR FUMES BE GENERATED. Ventilation:EFFECTIVE VENTILATION TO DRAW VAPOR OR FUMES AWAY FROM WORKERS TO PREVENT ROUTINE INHAL. LOCAL EXHAUST IS REC W/MINIMUM CAPTURE VELOCITY OF 100-15O PPM. Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . IF THERE IS A POTENTIAL CONTACT WITH HOT/MOLTEN MATERIAL, WEAR HEAT RESISTANT CLOTHING & FOOTWEAR. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health FIRE & EXPLO HAZ: AUTO-OXIDATION TEMP: >190C,>374F. ================== Physical/Chemical Properties ================== HCC:T6 Spec Gravity:0.85-0.90 MG/M3 @ 25C Solubility in Water:INSOLUBLE Appearance and Odor:AMBER-GRAY PELLETS OR BALES'; SLIGHT AROMATIC ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:AVOID TEMPERATURES ABOVE 290C. PROCESSING AT TEMPERATURES ABOVE 295C MAY PRODUCE IRRITANTS. Hazardous Decomposition Products:OXIDES OF CARBON, HYDROCARBON OXIDATION PRODUCTS INCLUDING ORGANIC ACIDS, ALDEHYDES AND ALCOHOLS. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information=================== Toxicological Information:A HIGH VISCOSITY TYPE OF NORDEL HAS BEEN TESTED IN ORDER TO ASSESS THE ACUTE TOXICOLOGY. IT IS EXPECTED THAT ALL TYPES OF NORDEL HAVE SIMILAR LEVELS OF TOXICITY. SKIN IRRITATION: PATCH TESTS CONDUCTED ON RABBITS SHOWED NO SIGNS OF IRRITATION AFTER 24 HOURS CONTACT TIME. SKIN IRRITATION AND SENSITIZATION STUDIES ON HUMAN SUBJECTS SHOWED NO EVIDENCE OF IRRITATION AFTER 6 DAYS CONTACT TIME. ==================== Disposal Considerations ==================== Waste Disposal Methods:NOT A RCRA HAZARDOUS WASTE. DISPOSE OF BY INCINERATION OR LANDFILL IN COMPLIANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:DOT CLASSIFICATION: NOT REGULATED. ===================== Regulatory Information ===================== SARA Title III Information:SARA TITLE III SECTION 313 INGREDIENTS: NONE. Federal Regulatory Information:TSCA INVENTORY STATUS: LISTED. State Regulatory Information:
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SUPERKOTE TRAFFIC PAINT 71-102 BLACK Preparer's Name:THOMAS E MAREK CAGE:33200 CAGE:33200 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ALCOHOL (METHANOL) (SARA III) CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: 0.2% Other REC Limits:N/K OSHA PEL:S,200PPM/250STEL ACGIH TLV:S,200PPM/250STEL; 93 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:PETROLEUM NAPHTHA.VAPOR PRESSURE:15.0 MMHG. CAS:64742-89-8 Fraction by Wt: 22.9% Other REC Limits:100 PPM OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:N/K Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION OF HIGH CONCENTRATIONS CAN CAUSE CARDIAC STRESS,CNS DEPRESSION & COMA,VENTRICULAR FIBRILLATION & RESPIRATORY ARREST.SKIN CONTACT CAUSES DEFATTING WHICH LEADS TO DERMATITIS.EYE CONTACT W/ LI QUID CAN PRODUCE CONJUNCTIVITIS & CORNEAL BURNS. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES:BLURRED VISION,REDNESS,CONJ,CORNEAL BURNS.SKIN:IRRIT,DEFATTING,DRYNESS,BLISTERING,DERMAT.INGEST:N/K .INHAL:DIZZINESS.LOW CONC-UPPER RESPIRATORY TRACT IRRIT.HIGH CONC-DISTURBED VISION,T REMORS,CARDIAC STRESS,CNS DEPRESSION,COMA,RESPIRATORY DIFFICULTY,VENTRICULAR FIBRILLATION,RESPIRATORY ARREST. Medical Cond Aggravated by Exposure:PRE-EXISTING DISORDERS. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/ LARGE AMOUNTS OF WATER FOR AT LEAST 15 MIN,GETTING UNDER EYELIDS.CONTACT MD IF IRRITATION PERSISTS.SKIN:WASH W/ SOAP & WATER IMMEDIATELY.REMOVE & LAUNDER CONTAM CLOTHING.INGESTION:CALL M D IMMEDIATELY .INHALATION:REMOVE TO FRESH AIR.RESTORE BREATHING IF NECESSARY.ADMINISTER OXYGEN IF BREATHING DIFFICULTY PERSISTS & CONTACT PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:55F,12.78C Lower Limits:7% Upper Limits:0.9% Extinguishing Media:FOAM,DRY CHEMICAL,CARBON DIOXIDE. Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS WITH A FULL FACEPIECE OPERATED IN PRESSURE DEMAND OR OTHER POSITIVE PRESSURE MODE WHEN FIGHTING FIRES. Unusual Fire/Explosion Hazard:VAPORS HEAVIER THAN AIR,MAY TRAVEL ALONG GROUND/MOVE BY VENT & IGNITE BY HEAT,PILOT LIGHTS,OTHER FLAMES/IGNIT SOURCES AT DIST LOCATIONS.HAZ DECOMP:CO,CO*2. ================== Accidental Release Measures ================== Spill Release Procedures:WASH W/ WATER INTO RETAINING AREA OR CONTAINER.AVOID SPARKS,FIRE OR HOT METAL SURFACES.SMALL QUANTITIES MAY BE ABSORBED ONTO AN APPROPRIATE ABSORBANT. Neutralizing Agent:N/K ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP COOL & AWAY FROM SOURCES OF IGNITION.USE WITH ADEQUATE VENTILATION.AVOID PROLONGED OR REPEATED PERSONAL CONTACT. Other Precautions:N/K ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN .USE ORGANIC VAPOR CARTRIDGE RESPIRATOR WITH FULL FACEPIECE FOR EXPOSURES OVER TLV. Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR CONCENTRATION BELOW TLV . Other Protective Equipment:APRON,BARRIER CREAM. Work Hygienic Practices:LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health N/K ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:240F,115.5C Melt/Freeze Pt:M.P/F.P Text:N/K Decomp Temp:Decomp Text:N/K Vapor Pres:N/K Vapor Density:>1 (AIR=1) Spec Gravity:1.49 (WATER=1) Evaporation Rate & Reference:9.2 (ETHER=1) Solubility in Water:NONE Appearance and Odor:BLACK OPAQUE LIQUID,MILD PETROLEUM DISTILLATE ODOR. Percent Volatiles by Volume:46 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:N/K Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY YIELD CARBON MONOXIDE AND DIOXIDE. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS .INCINERATE UNDER SAFE CONDITIONS OR DISPOSE OF ACCORDING TO APPLICABLE REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: SILVER-COPPER-PHOSPHOROUS BRAZING ALLOYS, SIL-FOS 6 Cage: 91874 Box: 638 ======================================================= Contractor Summary ======================================================= Cage: 91874 ======================================================= Ingredients ======================================================= Cas: 7440-50-8 RTECS #: GL5325000 % Wt: >75 OSHA PEL: 0.1MG/M3 FUME/1 DUST ACGIH TLV: 0.2 MG/M3 FUME EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 7723-14-0 RTECS #: TH3500000 % Wt: 5-7.25 OSHA PEL: 0.1 MG/M3 ACGIH TLV: 0.02 PPM EPA Rpt Qty: 1 LB DOT Rpt Qty: 1 LB ------------------------------ Cas: 7440-22-4 RTECS #: VW3500000 % Wt: 0.9-18 OSHA PEL: 0.01 MG/M3 ACGIH TLV: 0.1 MG/M3 EPA Rpt Qty: 1 LB DOT Rpt Qty: 1 LB ------------------------------ & DIARR. CHRONIC:INHAL:SILVER:MAY PRDCE ----------------------------- & RESP TRACT. COPPER:MAY CAUSE DMG TO LIVER, ----------------------------- LIVER, KIDNEY, SPLEEN, PANCREAS, SKELETAL SYS & BRAIN. ----------------------------- CUTTING" (AMERICAN WELDING SOCIETY, MIAMI, FL 33135). ----------------------------- ----------------------------- Other REC Limits: NONE RECOMMENDED ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: INHAL:COPPER:ACUTE EXPOS MAY CAUSE RESP TRACT IRRIT, FEVER, MUSCLE ACHE, CHILLS, COUGH, WEAKNESS & METALLIC TASTE. PHOSPHORUS:STABLE & RELATIVELY NON-TOX AT ROOM TEMP. WHEN HEATED IN PRESENCE OF AIR, IT IS CONVERTED TO PHOSPHORUS PENTOXIDE, WHICH IS CORR & IRRIT TO EYES, NOSE, THROAT & MUC MEMBS. (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT Signs And Symptions Of Overexposure: HLTH HAZS:SKIN:CONT W/MATL IN SOLID FORMS IS NOT KNOWN TO BE HAZ. IN POWDERED FORM, MAY PRDCE LOCALIZED IRRIT, LOCALIZED ARGYRIA (FROM SILVER), & OR DISCOLORATION & CONT DERM (FROM COPPER). EYES:IN PO WDERED FORM MAY PRDCE LOCALIZED ARGYRIA, IRRIT, CONJUNCT, & ULCERATION OF CORNEA. INGEST:IN FINELY-DIVIDED FORM Medical Cond Aggravated By Exposure: PRE-EXISTING PULMONARY DISEASES (E.G., BRONCHITIS, EMPHYSEMA) MAY BE AGGRAVATED BY INHALATION EXPOSURE TO THIS MATERIAL, PARTICULARLY AS FUME. First Aid: INHAL:REMOVE FROM CONTAM AREA, ADMIN OXYG, & SEEK MED ATTN. KEEP WARM & AT REST. PERFORM ARTF RESP IF BRTHG HAS STOPPED. SKIN:REMOVE CONTAM CLTHG. WASH AFFECTED AREA W/LG QTYS OF WATER FOR AT LST 15 M IN. SEEK MED ATTN IF NEC. EYES:FLUSH AFFECTED AREAS W/WATER FOR AT LST 15 MIN. SEEK MED ATTN IF NEC. INGEST:IF CONSCIOUS, INDUCE VOMIT. IF UNCON/CONVULSIVE, SEEK IMMED MED ASSISTANCE. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: CLEAN UP SPILLED MATL SO AS TO MIN DISPERSION OF DUST. WET SWEEPING/VACUUMING USING HEPA FILTRATION ARE RECOM METHODS. RQ'S OF COMPONENT MATLS UNDER SARA TITLE III, SECTION 313 ARE AS FOLLOWS:SILVER:1 000 LBS, PHOSPHOROUS:1 LB, COPPER:5000 LBS. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS (FP N). RETURN TO MANUFACTURER OR RECLAIM. Handling And Storage Precautions: DO NOT STORE AT HIGHLY-ELEVATED TEMPS/IN PROXIMITY TO INCOMPATIBLE MATLS (SEE REACTIVITY DATA). AVOID FLAMMABLE FABRICS. Other Precautions: BRAZING ALLOYS MAY BE USED W/SEPARATELY-APPLIED FLUX WHICH, WHEN HEATED, MAY EMIT IRRIT &/OR TOX GASES & FUMES. CONSULT MSDS FOR SPEC FLUX IN USE TO DETERM ITS HAZS & APPROP PROT MEASURES. FOR GEN GUI DANCE, REFER TO AMERICAN NATL ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: USE DRY POWDER. DO NOT USE WATER. Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: IN FINELY-DIVIDED FORM, THIS MATL MAY IGNITE WHEN EXPOSED TO FLAME/BY RXN W/INCOMPATIBLE MATLS (SEE REACTIVITY DATA FOR INCOMPATIBLE MATLS). FIRES/EXPLO(SUPDAT) ======================================================= Control Measures ======================================================= Respiratory Protection: IF EXPOSURE LEVELS EXCEED THE OSHA PEL, WEAR A NIOSH/MSHA APPROVED RESPIRATOR HAVING A PROTECTION FACTOR APPROPRIATE TO THE AIRBORNE CONCENTRATIONS OF THE CONTAMINANTS GENERATED. Ventilation: USE MECH LOC EXHST VENT ADEQ TO MAINTAIN AIRBORNE CONCS OF ALL COMPONENTS & THEIR DECOMP PRODS TO W/IN THEIR Other Protective Equipment: EMER EYE BATH & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA (FPN). APPROP PROT CLTHG TO PVNT SKIN INJURIES (SUPDAT) Work Hygienic Practices: TO AVOID INGEST OF MATL, WASH HANDS & FACE BEFORE EATING, DRINKING, OR CONSUMPTION OF TOBACCO. Supplemental Safety and Health: EXPLO HAZS:INVOLVING MATL MAY RELS POTNTLY TOX EMISSIONS OF METAL, METAL OXIDE, & PHOSPHORUS FUMES (SEE INGS FOR HAZ COMPONENTS & DECOMP PRODS). MATL TO AVOID:PEROXYFORMIC ACID; F*2; PERMONOSULFURIC A CID; CHLORATES; CS*2; SEOCL; SEOF; SEF*4; BROMATES; IODATES. OTHER PROT EQUIP:FROM HAZS OF BRAZING &/OR FOR ======================================================= Physical/Chemical Properties ======================================================= M.P/F.P Text: 1190F,643C Spec Gravity: 7.86-8.44 Solubility in Water: INSOLUBLE Appearance and Odor: LIGHT-COPPER METAL IN FORM OF WIRE, ROD, STRIP, POWDER OR PREFORMED SHAPES. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: STABLE AT ROOM TEMPERATURE. Materials To Avoid: ACETYLENE; NH*3; HNO*3; AZIDES; ETHANOL; ETHYLENE IMINE; MG; CF*3; CL*2; CLO*2; CLO; INORG & ORG PEROXIDES; (SUPP DATA) Hazardous Decomposition Products: HEATING AT BRAZING TEMPS MAY LIBERATE OXIDES OF METALS & PHOSPHORUS (FOR SPEC HAZ COMPONENTS & DECOMP PRODS, SEE INGS). Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: SILVER-COPPER-PHOSPHOROUS BRAZING ALLOYS, SIL-FOS 6 Cage: 91874 Company Name: LUCAS-MILHAUPT INC A HANDY & HARMAN CO Street: 5656 SOUTH PENNSYLVANIA AVENUE Zipcode: 53110 Label Required IND: Y Date Of Label Review: 04/07/1995 Status Code: C Label Date: 04/07/1995 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE:INHAL:MAY CAUSE RESP TRACT IRRIT, FEVER, MUSCLE ACHE, CHILLS, COUGH, WEAKNESS & METALLIC TASTE. PHOSPHORUS PENTOXIDE IS CORR & IRRIT TO EYES, NOSE, THROAT & MUC MEMBS. SKIN:IN POWDERED FORM, MAY PRODUCE LOCALIZED IRRIT, LOCALIZED ARGYRIA (FROM SILVER), AND/OR DISCOLORATION & CONT DERM (FROM COPPER). EYES:IN POWDERED FORM MAY PRODUCE LOCALIZED ARGYRIA, IRRIT, CONJUNCT & ULCERATION OF CORNEA. INGEST:IN FINELY-DIVIDED FORM MAY PRDCE GASTRIC IRRIT, VOMIT, ABDOM PAIN, HEMORRHAGE & DIARR. CHRONIC:SILVER:MAY PRDCE ARGYRIA, PERM BLUE-GRAY DISCOLORATION OF SKIN, EYES, MUCOUS MEMBRANES AND RESPIRA TORY TRACT. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:820944 CAGE:53021 CAGE:53021 ============= Composition/Information on Ingredients ============= Ingred Name:POLYCHLORINATED BIPHENYLS (PCBS) (SARA III) CAS:1336-36-3 RTECS #:TQ1350000 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Effects of Overexposure:ABSORBED THRU SKIN,LUNGS,INTESTINE.CAUSES CANCER,LIVER,KIDNEY,STOMACH,EYE,HEARING DISORDER(SUP DATA) ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/WATER IMMEDIATELY.SKIN:WASH W/SOAP IMMEDIATELY.INHAL:REMOVE TO FRESH AIR,GIVE ART.RESPIR. AS NEEDED.INGEST:GET MEDICAL ATTN.GIVE LARGE QTY OF SALT WATER,INDUCE VOMITING,BUT DO NOT MAKE UN CONSCIOUS PERSON VOMIT. ================== Accidental Release Measures ================== Spill Release Procedures:USE ABSORBENT & DIKES TO PREVENT RUNOFF.ISOLATE & NOTIFY PROPER AUTHORITIES. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE MUST FOLLOW RCRA REQUIREMENTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SUPPLIED AIR W/FULL FACEPIECE,HELMET OR HOOD Ventilation:LOCAL EXHAUST Other Protective Equipment:FULL CLOTHING PREVENT SKIN CONTACT Supplemental Safety and Health OVEREXPOS:CAN CAUSE FORMATION OF CYSTS,CAUSES STILLBIRTHS.IRRITATES EYES,NOSE THROAT. ================== Physical/Chemical Properties ================== HCC:Z3 Appearance and Odor:LIGHT STRAW-COLORED LIQUID,AROMATIC ODOR ================= Stability and Reactivity Data ================= STRONG OXIDIZERS ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-GENERALLY HIGH TEMPERATURE INCINERATION.ONLY APPROVED DISPOSAL OPERATOR PERMITTED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PIG ALL PURPOSE WIPERS Kit Part:Y Resp. Party Other MSDS Num.:NSD-114 Preparer's Name:CAMERON W. SHERRY CAGE:1JA49 CAGE:1JA49 Contract Num:SP0450-00-D-4021 CAGE:29913 ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS INGREDIENT(S) = Wt:100. Other REC Limits:NOT PROVIDED OSHA PEL:NOT PROVIDED ACGIH TLV:NOT PROVIDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT PROVIDED Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:POTENTIAL HEALTH EFFECTS: EYE CONTACT: MAY CAUSE TEMPORARY, MILD IRRITATION. INGESTION: WILL NOT OCCUR UNDER NORMAL CONDITIONS OF USE. INHALATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS OF USE. NO TOX IC EFFECTS EXPECTED FROM PROLONGED EXPOSURE. SKIN CONTACT: NOT A KNOWN IRRITANT UNDER NORMAL CONDITIONS OF USE. CHRONIC: NO KNOWN EFFECTS. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYE CONTACT: MAY CAUSE TEMPORARY, MILD IRRITATION. Medical Cond Aggravated by Exposure:NOT PROVIDED ======================= First Aid Measures ======================= First Aid:EYE CONTACT: IF IRRITATION OCCURS, FLUSH EYES IMMEDIATELY WITH LARGE AMOUNT OF WATER FOR AT LEAST 15 MINUTES. CONTINUE FLUSHING UNTIL IRRITATION SUBSIDES. IF REDNESS PERSISTS, SEEK MEDICAL ATTENTION.INGESTION: NOT APPLICABLE. INHALATION: NOT APPLICABLE. SKIN CONTACT: IF IRRITATION OCCURS, SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NOT KNOWN Lower Limits:NONE KNOWN Upper Limits:NONE KNOWN Extinguishing Media:WATER, DRY CHEMICAL, CO2. Fire Fighting Procedures:FIRE FIGHTERS SHOULD WEAR SCBA IN CHEMICAL FIRES. Unusual Fire/Explosion Hazard:NONE KNOWN. ================== Accidental Release Measures ================== Spill Release Procedures:WASTE FROM THIS PRODUCT IS TYPICALLY NOT CONSIDERED A HAZARDOUS WASTE AND MAY BE DISPOSED OF IN A LANDFILL OR BY INCINERATION. CONSULT LOCAL, STATE, AND FEDERAL REGULATIONS. Neutralizing Agent:NOT PROVIDED ======================Handling and Storage ====================== Handling and Storage Precautions:NONE REQUIRED. Other Precautions:STORAGE TEMPERATURE: NOT ESTABLISHED. STORAGE PRESSURE: NOT ESTABLISHED. SHELF LIFE: 1 YEAR. GENERAL: NONE REQUIRED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED UNDER NORMAL CONDITIONS OF USE. Ventilation:NONE REQUIRED. GLASSES ARE RECOMMENDED. Other Protective Equipment:NONE REQUIRED UNDER NORMAL CONDITIONS OF USE. Work Hygienic Practices:NOT PROVIDED Supplemental Safety and Health ABBREVIATION: N/A=NOT APPLICABLE OR NOT AVAILABLE. N/K=UNKNOWN. N/P=NOT PROVIDED. N/R=NOT RELEVANT. N/D=NOT DETERMINED. N/E=NOT ESTABLISHED. ================== Physical/Chemical Properties ================== HCC:V5 NRC/State Lic Num:NOT RELEVANT Decomp Temp:Decomp Text:NOT PROVIDED Vapor Density:N/E Spec Gravity:<1 Solubility in Water:INSOLUBLE Appearance and Odor:SOLID BLUE COLOR; MINIMAL ODOR. Percent Volatiles by Volume:NOT PROVIDED Corrosion Rate:NOT PROVIDED ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NOT AVAILABLE. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:CAN PRODUCE ASPHYXIATES SUCH AS CO AND CO2. =================== Toxicological Information=================== Toxicological Information:NOT AVAILABLE ===================== Ecological Information ===================== Ecological:NO DATA AVAILABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM THIS PRODUCT IS TYPICALLY NOT CONSIDERED A HAZARDOUS WASTE AND MAY BE DISPOSED OF IN A LANDFILL OR BY INCINERATION. CONSULT LOCAL, STATE, AND FEDERAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:DOT (DEPARTMENT OF TRANSPORTATION): PROPER SHIPPING NAME: NOT APPLICABLE. HAZARD CLASS: NOT APPLICABLE. IDENTIFICATION NUMBER: NOT APPLICABLE. ===================== Regulatory Information ===================== SARA Title III Information:SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT): NO REPORTABLE QUANTITIES. Federal Regulatory Information:CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT): NO REPORTABLE QUANTITIES. OSHA HAZARDOUS COMMUNICATION STANDARD 29 CFR 1910.1200. NOT REGULATED. TSCA (TOXIC SUBSTANCES C ONTROL ACT): ALL INGREDIENTS ARE LISTED. State Regulatory Information:NOT PROVIDED ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:AEROSOL INK READI, 02340 CAGE:VARNP CAGE:VARNP ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL SPIRITS; (ISOPARAFFINIC HYDROCARBON). VP:10 @ 100F CAS:64475-85-0 RTECS #:PY8240000 Fraction by Wt: 55% OSHA PEL:100 PPM (MFR) ACGIH TLV:100 PPM (MFR) Ingred Name:MINERAL OIL, WHITE; (MINERAL OIL). VP:0.5 @ 68F CAS:8042-47-5 RTECS #:PY8047000 Fraction by Wt: 25% OSHA PEL:5 MG/M3 (MFR) ACGIH TLV:5 MG/M3 (MFR) Ingred Name:P-CRESOL, 2,6-DI-TERT-BUTYL-; (BUTYLATED HYDROXY TOLUENE). VP:1.0 @ 68F CAS:128-37-0 RTECS #:GO7875000 Fraction by Wt: <5% OSHA PEL:10 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:PETROLEUM GAS (LIQUEFIED); (LIQUEFIED PETROLEUM GAS). VP:760 @ 68F CAS:68476-85-7 RTECS #:SE7545000 Fraction by Wt: 20% OSHA PEL:1000 PPM ACGIH TLV:1000 PPM Ingred Name:2-BUTANONE, OXIME; (METHYL ETHYL KETOXIME). VP:8 @ 68F CAS:96-29-7 RTECS #:EL9275000 Fraction by Wt: <5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:MATERIAL VOLATILE ORGANIC COMPOUND:5.83 LB/GL (698 G/L) RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:INHALATION:EXCESSIVE VAPOR CONCENTRATIONS ARE ATTAINABLE. OVEREXPOSURE MAY IRRITATE NOSE, THROAT, LUNGS & CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION WITH SYMPTOMS SUCH AS DROWSINESS, DIZZINESS ANDUNCONSCIOUSNESS. SKIN:PROLONGED CONTACTMAY LEAD TO DRYING, IRRITATION AND DERMATITIS. EYES:MAY CAUSE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:BURNING AND IRRITATION. INGESTION:MAY PRODUCE GASTRO-INTESTINAL IRRITATION AND VOMITING. CHRONIC:REPEATED OR ABUSIVE BREATHING OF CONCENTRATED VAPORS MAY EFFECT PULMONARY, CARDIOVASCULAR, CEN TRAL NERVOUS SYSTEM AND CAUSE LIVER, LUNG AND KIDNEY EFFECTS. RPEATED SKIN CONTACT WILL DRY OUT AND CRACK SKIN. Medical Cond Aggravated by Exposure:SKIN CONTACT MAY AGGRAVATE PRE-EXISTING DERMATITIS. INHALATION MAY AGGRAVATE PRE-EXISTING ASTHMA-LIKE CONDITIONS. ======================= First Aid Measures ======================= First Aid:EYES:HOLD EYELID OPEN AND FLUSH W/WATER FOR AT LEAST 15 MINUTES. CONT PHYS IF IRRIT PERSISTS. SKIN:WASH W/SOAP & WATER. INGEST:CONT LOCAL POISON CONTROL CENTER OR PHYSICIAN IMMEDIATELY. INHAL:MOVE TO FRESH AIR. GIVE OXYGEN IF BREATHING IS LABORED. ===================== Fire Fighting Measures ===================== Flash Point:FLAMMABLE Lower Limits:0.6% Upper Limits:9.5% Extinguishing Media:FOAM, CO*2, DRY CHEMICAL. Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . KEEP CNTNRS COOL. USE SHIELDING TO PROTECT PERS AGAINST BURSTING, RUPTURING/VENTING CNTNRS. WATER MAY NOT (SUPDAT) Unusual Fire/Explosion Hazard:AT ELEVATED TEMPERATURES (OVER 130F) CONTAINER MAY VENT, RUPTURE OR BURST. PRODUCT IS CONSIDERED FLAMMABLE AS DESCRIBED IN 16CFR 1500.45. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. SOAK UP MATERIAL WITH ABSORBANT. TRANSFER INTO A CLOSED CONTAINER FOR LATER DISPOSAL. AEROSOL PROPELLENTS ARE EXTREMELY FLAMMABLE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM SUNLIGHT, EXCESS HEAT, & SOURCES OF IGNIT. STORE @ TEMP BELOW 130F. STORE AS LEVEL 3 AEROSOL (NFPA 30B). AVOID SKIN CONTACT. Other Precautions:AVOID BRTHG VAPS. WEAR PROPER PERSONAL PROT EQUIP & KEEP AWAY FROM SPKS, FLAMES & OTHER SOURCES OF IGNITION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN CONCENTRATIONS EXCEED THE ESTABLISHED EXPOSURE LIMITS IN INGRED SECTION, USE NIOSH APPRVD RESPIRATOR WITH APPROPRIATE ORGANIC VAPOR CARTRIDGES. Ventilation:IF CURRENT VENT IS INADEQ TO MAINTAIN CONCS BELOW ESTABLISHED EXPOS LIMS IN INGRED SECTION, ADDNL VENT/EXHAUST (SUPDAT) Other Protective Equipment:ANSI APPRVD EMERGENCY EYE WASH & DELUGE SHOWER . Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER PRODUCT CONTACT WITH SKIN. Supplemental Safety and Health FIRE FIGHT PROC:BE EFTIVE TO EXTING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED CNTNRS. VENT:SYSTEMS IS REQUIRED. EXPLOSION PROOF ELECTRICAL SYSTEMS MUST BE USED. ================== Physical/Chemical Properties ================== Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:0.7 (H*2O=1) Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:NEGLIGIBLE Appearance and Odor:AEROSOL CAN; MISTY SPRAY - MILD ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID MIXING WITH STRONG OXIDIZING MATERIALS. Stability Condition to Avoid:AVOID EXCESS HEAT (ABOVE 130F). Hazardous Decomposition Products:BURNING WILL PRODUCE OXIDES OF CARBON. ADDITIONAL TOXIC CHEMICALS MAY BE FORMED IN SMALL AMOUNTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT PUNCTURE OR INCINERATE. WHEN CONTENTS ARE DEPLETED CONTINUE TO DEPRESS BUTTON UNTIL ALL GAS IS EXPELLED. DISPOSE OF CONTAINERS I/A/W LOCAL, STATE AND FEDERAL REGULATIONS. CONT LICENSED HAZARDOU S WASTE HAULER FOR MORE INFORMATION.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:NEW COLOR HORIZONS CAGE:08882 CAGE:08882 ============= Composition/Information on Ingredients ============= Ingred Name:NAPHTHA (PETROLEUM SPIRITS OR BENZIN) CAS:8030-30-6 RTECS #:SE7555000 Fraction by Wt: 55% OSHA PEL:100 PPM ===================== Hazards Identification ===================== Effects of Overexposure:HEADACHE, DIZZINESS, STAGGERING GAIT, CONFUSION, UNCONSCIOUSNESS OR COMA. EYE/SKIN: IRRITANT. ======================= First Aid Measures ======================= First Aid:FUMES: REMOVE FROM EXPOSURE, RESTORE BREATHING AND NOTIFY A PHYSICIAN. EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. NOTIFY A PHYSICIAN. SKIN: WASH AFFECTED AREA WITH SOAP/WATER, REMOVE CONTAMINATED CLOTHING. ===================== Fire Fighting Measures ===================== Flash Point:104F (TCC) Lower Limits:0.9% Extinguishing Media:CO2, DRY CHEMICAL OR FOAM Fire Fighting Procedures:WEAR SCBA. WATER COOL CONTAINERS TO PREVENT PRESSURE BUILDUP Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION, VENTILATE AREA AND REMOVE WITH INERT ABSORBENT AND N-SPARKING TOOLS. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T STORE ABOVE 120F. STORE LARGE QUANTITIES IN BLDG DESIGNED AND PROTECTED FOR STORAGE OF NA CLASS II FLAMMABLE LIQUIDS. Other Precautions:CONTAINERS SHOULD BE GROUNDED WHEN POURING. DON'T TAKE INTERNALLY. EMPTY CONTAINERS MAY BE HAZARDOUS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN CONFINED AREAS: USE B OF M APPROVED AIR LINE TYPE RESP OR HOODS Ventilation:PROVIDE LOCAL EXHAUST VENTILATION TO KEEP BELOW TLV/LEL CONTACT. Supplemental Safety and Health WT/GAL: 7.5-11.0 LBS. MSDS DATED: 30 SEPT 1985 ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:313-386F Vapor Density:>AIR Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:66% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Hazardous Decomposition Products:CO AND CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF ACCORDING TO LOCAL, STATE AND FEDERAL REGULATIONS. DON'T INCINERATE CLOSED CONTAINERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:H1300-1 5-HEXEN-2-ONE,99% CAGE:21076 CAGE:60928 CAGE:63181 CAGE:21076 ============= Composition/Information on Ingredients ============= Ingred Name:5-HEXEN-2-ONE CAS:109-49-9 Fraction by Wt: 99% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:HARMFUL BY INHALATION, INGESTION/SKIN ABSORPTION. MAY CAUSE IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION. ======================= First Aid Measures ======================= First Aid:EYES/SKIN: IMMEDIATELY FLUSH W/COPIOUS AMOUNTS OF WATER FOR 15 MINS. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED. INGESTION: IF CONSCIOUS, WASH MOUTH OUT W/WATER. OBTAIN MEDICAL ATTENTI ON IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:75F Extinguishing Media:CO2, DRY CHEMICAL POWDER, APPROPRIATE FOAM. Fire Fighting Procedures:WATER MAY BE EFFECTIVE FOR COOLING, BUT MAY NOT EFFECT EXTINGUISHMENT. USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS. WEAR A SCBA & PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:VAPORS MAY TRAVEL TO DISTANT IGNITION SOURCE & FLASH BACK. CONTAINERS MAY EXPLODE UNDER FIRE CONDITIONS. FORMS EXPLOSIVE MIXTURES IN AIR. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA & REMOVE IGNITION SOURCES. WEAR CARBON ABSORBENT, TAKE UP & PLACE IN CLOSED CONTAINERS. TRANSPORT OUTDOORS. VENTILATE ARE A & WASH SITE AFTER MATERIAL PICKUP IS COMPLETE. ======================Handling and Storage ====================== Handling and Storage Precautions:USE NONSPARKING TOOLS. KEEP TIGHTLY CLOSED. KEEP AWAY FROM HEAT, SPARKS & OPEN FLAME. STORE IN A COOL DRY PLACE. Other Precautions:DON'T BREATHE VAPOR. AVOID CONTACT W/EYES, SKIN & CLOTHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR AN APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:MECHANICAL EXHAUST REQUIRED. Other Protective Equipment:SAFETY SHOWER, EYE BATH, RUBBER BOOTS & Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:262-264.2F Spec Gravity:0.847 Appearance and Odor:COLORLESS LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS, REDUCING AGENTS, STRONG BASES. Stability Condition to Avoid:FIRE & IGNITION SOURCES. Hazardous Decomposition Products:CO & CO2. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISSOLVE/MIX MATERIAL W/A COMBUSTIBLE SOLVENT & BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AN AFTERBURNER & SCRUBBER IAW/FEDERAL, STATE & LOCAL REGULATIONS. EXERT EXTRA CARE IN IGNITING AS THIS MATERIA L IS HIGHLY FLAMMABLE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FM GREASE, 1355 CAGE:15958 CAGE:15958 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL OIL, SLAB OIL; (SEVERELY HYDROPROCESSED, SOLVENT REFINED PARAFFINIC WHITE MINERAL OIL) CAS:8042-47-5 RTECS #:PY8047000 OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE/SKIN: NO SIGNIFICANT IRRITATION EXPECTED. INHAL: NOT APPLICABLE. INGEST: EXPECTED TO BE RELATIVELY NON- TOXIC. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MIN. SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER. CALL MD . INHAL: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O2/ARTF RESP). INGEST: IF A LA RGE AMOUNT IS SWALLOWED, INDUCE VOMITING. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:AGENTS APPROVED FOR CLASS B HAZARDS (E.G., DRY CHEMICAL, CARBON DIOXIDE, HALOGENATED AGENTS, FOAM, STEAM) OR WATER FOG. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN AND REMOVE BY MECHANICAL MEANS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NO SPECIAL REQUIREMENTS. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:V6 Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE, OR LOCAL REGULATIONS. ENCLOSED-CONTROLLED INCINERATION OR PERMITTED LANDFILL UNLESS DIRECTED OTHERWISE BY APPLICABLE ORDINANCES.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ACTIVATED CARBON Preparer's Name:D.E. KUBELDIS CAGE:86368 CAGE:86368 ============= Composition/Information on Ingredients ============= Ingred Name:GRAPHITE, SYNTHETIC CAS:7440-44-0 RTECS #:FF5250100 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:2 MG/M3 TDUST; 9394 ===================== Hazards Identification ===================== LD50 LC50 Mixture:ACUTE ORAL LD50 (RAT) >10 G/KG Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION- THE ACUTE INHALATION LC50 (RAT) IS >64.4 MG/L (NOMINAL CONCENTRATION) FOR ACTIVATED CARBON. SKIN- THE PRODUCT IS NOT A PRIMARY SKIN IRRITANT. EYES- THE PHYSICAL NATURE OF THE PRODUCT MAY P RODUCE EYE IRRITATION. CHRONIC: THE EFFECTS OF LONG-TERM, LOW-LEVEL EXPOSURES TO THIS PRODUCT HAVE NOT BEEN DETERMINED. Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES- FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. SKIN- WASH WITH SOAP AND WATER. ===================== Fire Fighting Measures ===================== Extinguishing Media:IF INVOLVED IN FIRE, FLOOD WITH PLENTY OF WATER. Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:CONTACT WITH STRONG OXIDIZERS SUCH AS OZONE, LIQUID OXYGEN, CHLORINE, PERMANGANATE, ETC. MAY RESULT IN FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP UNUSED CARBON AND DISCARD IN REFUSE CONTAINER OR REPACKAGE. ======================Handling and Storage ====================== Handling and Storage Precautions:WET ACTIVATED CARBON REMOVES OXYGEN FROM AIR CAUSING A SEVERE HAZARD TO WORKERS INSIDE CARBON VESSELS AND ENCLOSED OR CONFINED SPACES. Other Precautions:WASH THOROUGHLY AFTER HANDLING. EXERCISE CAUTION IN THE STORAGE AND HANDLING OF ALL CHEMICAL SUBSTANCES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A NIOSH-APPROVED PARTICULATE FILTER RESPIRATOR IS RECOMMENDED IF EXCESSIVE DUST IS GENERATED. Ventilation:LOCAL EXHAUST AND MECHANICAL VENTILATION RECOMMENDED. Other Protective Equipment:NOT REQUIRED. Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER HANDLING THIS MATERIAL. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:2.3 G/CC Solubility in Water:INSOLUBLE Appearance and Odor:BLACK PARTICULATE SOLID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS SUCH AS OZONE, LIQUID OXYGEN, CHLORINE, PERMANGANATE, ETC. Stability Condition to Avoid:NONE Hazardous Decomposition Products:CARBON MONOXIDE MAY BE GENERATED IN THE EVENT OF FIRE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF UNUSED CARBON IN REFUSE CONTAINER. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SURGICAL MILK, 192132 CAGE:05730 CAGE:05730 ============= Composition/Information on Ingredients ============= Ingred Name:ATLAS G-1086 LD 50: > 31.6 G/KG Fraction by Wt: 5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ATLAS G-1096 LD50: > 31.6 G/KG Fraction by Wt: 2.2% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:HT-10 LD50: 5000 MG/KG Fraction by Wt: 11.8% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SODIUM BENZOATE LD50: 4100 MG/KG CAS:532-32-1 RTECS #:DH6650000 Fraction by Wt: 3.0% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENTS. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: SKIN/EYES: ITCHING AND REDNESS, IRRITATION. INGESTION/INHALATION: SLIGHT NAUSEA, IRRITATION. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:SENSITIVE SKIN. ======================= First Aid Measures ======================= First Aid:SKIN: WASH AFFECTED AREA THOROUGHLY WITH LARGE AMOUNTS OF WATER. EYES: FLUSH WITH POTABLE WATER FOR AT LEAST 15 MINUTES. SEE MD . INHALATION: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE OXYGEN OR ARTIFICIAL RESPIRATION) . INGESTION: CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, WATER FOG OR FOAM. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:WIPE UP WITH DAMP TOWEL; WASH DOWN DRAIN WITH LARGE AMOUNT OF WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID EXCESSIVE COLD OR HEAT. KEEP CONTAINER TIGHTLY CLOSED. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Solubility in Water:SOLUBLE Appearance and Odor:MILKY WHITE LIQUID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDANTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CARBON MONOXIDE UPON COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DRAIN TO SEWER WITH LARGE AMOUNTS OF WATER. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:NAPA 84-220, 84-221 FLUX COATED MANGANESE BRONZE ROD (32) CAGE:EO393 CAGE:EO393 CAGE:050Q3 ============= Composition/Information on Ingredients ============= Ingred Name:IRON CAS:7439-89-6 RTECS #:NO4565500 Fraction by Wt: 0-1.5% Other REC Limits:NONE RECOMMENDED Ingred Name:MANGANESE (SARA 313) CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: 0-1.5% Other REC Limits:NONE RECOMMENDED OSHA PEL:C, 5 MG/M3 (FUME) ACGIH TLV:0.2 MG/M3; 9596 Ingred Name:NICKEL (SARA 313) (CERCLA) CAS:7440-02-0 RTECS #:QR5950000 Fraction by Wt: 0-13% Other REC Limits:NONE RECOMMENDED OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3; 9596 Ingred Name:SILICON CAS:7440-21-3 RTECS #:VW0400000 Fraction by Wt: 0-3.5% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9596 Ingred Name:TIN CAS:7440-31-5 RTECS #:XP7320000 Fraction by Wt: 0-3% Other REC Limits:NONE RECOMMENDED OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3; 9596 Ingred Name:SILVER (SARA 313) (CERCLA) CAS:7440-22-4 RTECS #:VW3500000 Fraction by Wt: 0-0.7% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.01 MG/M3 ACGIH TLV:0.1 MG/M3; 9596 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:FLUX COATING (PER MSDS:THE CONSTITUENTS OF THE FLUX COATING DON;T MEET REPORTABLE QUANT UNDER OSHA 1910.120 HCS). Fraction by Wt: NA Other REC Limits:NONE RECOMMENDED RTECS #:9999999ZZ Fraction by Wt: NA Other REC Limits:NONE RECOMMENDED Ingred Name:COPPER (SARA 313) (CERCLA) CAS:7440-50-8 RTECS #:GL5325000 Fraction by Wt: 44-97% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.1MG/M3 FUME/1 DUST ACGIH TLV:0.2 MG/M3 FUME; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ZINC (SARA 313) (CERCLA) CAS:7440-66-6 RTECS #:ZG8600000 Fraction by Wt: 0-45% Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:DON'T PRESENT SIGNIFICANT HEALTH HAZ UNDER NORMAL HNDLG/STORAGE CONDITIONS.USE OF PROD IN FUME PRODUCING OPERATIONS(WELD/BRAZE)RESULT IN EXPO TO AIRBORN METAL PARTICULATES/FUME.INHAL OF FUMES/GASES/PA RTICULATES.INGEST OF PARTICULATES.CHRONIC:CU/ZN/MN CAUSE METAL FUME FEVER,CNS EFFECTS,SKIN/HAIR DICOLOR.(SUPPLEMENTAL) Explanation of Carcinogenicity:PER MSDS:CARCINOGENICITY:YES FOR NICKEL. Effects of Overexposure:METAL FUME FEVER SYMPTOMS:FEVER,FATIGUE,DRYNESS OF THROAT,HEAD/BODY ACHE,CHILL. AFFECT CNS LEADING TO EMOTIONAL DISTURBANCES,GAIT,BALANCE DIFFICULTIES & PARALYSIS. OVEREXPO TO CU:SKIN/HAIR DISCOLORATI ON.NI POTENTIAL CANCER CAUSING AGENT. AG EXPO:GREYISH-BLUISH DISCOLORATION OF SKIN. DERMATITIS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST:SIGNIFICANT AMTS OF COPPER ALLOY ARE UNLIKELY.SEEK MED HELP IF LG QUANTITIES OF PRODUCT ARE INGESTED. INHAL:REMOVE FROM EXPO TO DUST/FUME IF PRESENT.SEEK MED HELP IF REQUIRED. SKIN:WASH THOROUG HLY W/SOAP/WATER. EYE:FLUSH W/WATER FOR@LEAST 15MINS.SEEK MED HELP IF REQUIRED. ===================== Fire Fighting Measures ===================== Flash Point:NA Autoignition Temp:Autoignition Temp Text:NA Lower Limits:NA Upper Limits:NA Extinguishing Media:NEVER USE WATER AS EXTINGUISHING AGENT AROUND MOLTEN METAL. WATER WILL REACT VIOLENTLY W/ANY MOLTEN METAL. Unusual Fire/Explosion Hazard:THERE'RE NO FIRE/EXPLO HAZ W/THESE ALLOYS.ALLOY IS STABLE NONHAZ SOLID @ROOM REMP.MATL MAY REACT W/ACIDS/BASES/OXIDIZERS. ================== Accidental Release Measures ================== Spill Release Procedures:PRODUCT IS NON-HAZ SOLID.NO SPECIAL PRECAUTIONS ARE REQUIRED FOR SPILLS OF BULK MATL.SCRAP METAL CAN BE RETAINED FOR REUSE. ======================Handling and Storage ====================== Handling and Storage Precautions:CONSULT LATEST NIOSH REQMTS & AMER NAT STD Z49.1 "SAFETY IN WELDING & CUTTING".WET MATL SHOULD NEVER BE CHARGED INTO MOLTEN BATH. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WELDING MAY PRODUCE FUMES & GASES HAZARDOUS TO HUMAN HELATH. AVOID BREATHING THESE FUMES OR GASES. Ventilation:USE ADEQUATE VENTILATION. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER USE ESPECIALLY BEFORE EATING/DRINKING/SMOKING. Supplemental Safety and Health HEALTH HAZ:PARTICULATES MAY CAUSE DERM DUE TO MECHANICAL IRRIT.SILVER EXPO PRODUCE GREYISH-BLUE DISCOLORATION OF SKIN. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:NA Melt/Freeze Pt:M.P/F.P Text:1600F,871C Decomp Temp:Decomp Text:NP Vapor Pres:NA Vapor Density:NA Spec Gravity:8.3-8.5 G/CC pH:NP Viscosity:NP Evaporation Rate & Reference:NA Solubility in Water:INSOLUBLE. Appearance and Odor:SILVER OR YELLOW TO RED @ROOM TEMP & EXHIBITS NO ODOR. Percent Volatiles by Volume:NA Corrosion Rate:NP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:FOLLOW FED/STATE/LOC REGS REGARDING DISPOSAL.
0
eyes_protection_not_mandatory
======================================================= Product ID: EASY-FLO Cage: 91874 Box: 638 ======================================================= Contractor Summary ======================================================= Cage: 91874 ======================================================= Ingredients ======================================================= IRRIT, CONJUNCTIVITIS, & ULCERATION OF ----------------------------- GASTRIC IRRIT, VOMIT, ABDOMINAL PAIN, ----------------------------- PRODUCE DAMAGE TO THE LIVER, KIDNEY, SPLEEN, ----------------------------- BRAIN. ----------------------------- MUSCULOSKELETAL SYSTEM. ----------------------------- DETERMINE ITS HAZS & APPROP PROT MEASURES. ----------------------------- INSTITUTE (ANSI) Z49.1, "SAFETY IN WELDING & ----------------------------- ----------------------------- Cas: 7440-43-9 RTECS #: EU9800000 % Wt: 5-24 OSHA PEL: N/K (FP N) ACGIH TLV: 0.01 MG/M3 DUST EPA Rpt Qty: 10 LBS DOT Rpt Qty: 10 LBS ------------------------------ Cas: 7440-50-8 RTECS #: GL5325000 % Wt: 15-45 OSHA PEL: 0.1MG/M3 FUME;1 DUST ACGIH TLV: 0.2MG/M3 FUME EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 7440-22-4 RTECS #: VW3500000 % Wt: 20-50 OSHA PEL: 0.01 MG/M3 ACGIH TLV: 0.1 MG/M3 EPA Rpt Qty: 1 LB DOT Rpt Qty: 1 LB ------------------------------ Cas: 7440-66-6 RTECS #: ZG8600000 % Wt: 16-30 OSHA PEL: 10 MG ZNO/M3 ACGIH TLV: 10 MG ZNO/M3 EPA Rpt Qty: 1000 LBS DOT Rpt Qty: 1000 LBS ------------------------------ SYSTEM EFFECTS. OSHA REG: 29 CFR 1910.1027. ----------------------------- BRAIN. ZINC:ACUTE EXPOSURE MAY CAUSE RESP TRACT ----------------------------- THE FOLLOWING SYMPS: METALLIC TASTE, DRY ----------------------------- NAUS, VOMIT, & FATIGUE. CHRONIC: EXPOSURE ----------------------------- EFFECTS IN MAN. SKIN: SKIN CNTCT WITH ----------------------------- FORM, SKIN CNTCT MAY PRODUCE LOCALIZED ----------------------------- DERMATITIS (FROM COPPER). EYE: EXPOSURE TO ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: NO Ingestion: YES Carcinogenicity Inds - NTP: YES IARC: YES OSHA: YES Effects of Exposure: INHAL OF THE COMPONENTS OF THIS MATL MAY PRODUCE THE FOLLOWING: SILVER:CHRONIC EXPOSURE MAY PRODUCE ARGYRIA, A PERMANENT BLUE-GRAY DISCOLORATION OF THE SKIN, EYES, MUCOUS MEMBS, & THE RESP TRACT. CADM IUM:ACUTE EXPOSURE TO CADMIUM OXIDE FUME MAY PRODUCE PNEUMONITIS, TRACHEOBRONCHITITS, AND PULM EDEMA. (EFTS OF OVEREXP) Explanation Of Carcinogenicity: CADMIUM: IARC MONOGRAPHS, SUPPLEMENT, VOL 7, PG 139, 1987: GRP 2A. NTP 6TH ANNUAL REPORT ON CARCINS, 1991: Signs And Symptions Of Overexposure: HLTH HAZ: CHRONIC EXPOSURE TO CADMIUM (DUST/FUME) MAY PRODUCE GI SYMPS, ANEMIA, EOSINOPHILIA, RHINITIS, DISCOLORATION OF TEETH, MICROFRACTURES, KIDNEY DISEASE, AND CANCER. COPPER: ACUTE EXPOSURE MAY C AUSE RESP TRACT IRRIT, FEVER, MUSCLE ACHE, CHILLS, COUGH, WEAKNESS, & A METALLIC TASTE. CHRONIC EXPOSURE MAY Medical Cond Aggravated By Exposure: PRE-EXISTING PULM DISEASES (E.G., BRONCHITIS, EMPLYSEMA) MAY BE AGGRAVATED BY INHAL EXPOSURE TO THIS MATL, PART AS FUME. ADDNLY, EXPOSURE TO CADMIUM BY INHAL &/OR INGEST MAY AGGRAVATE PRE-EXIST(ING16) First Aid: INHAL:REMOVE FROM CONTAM AREA, ADMIN O*2, & SEEK MED ATTN. KEEP SUBJECT WARM & AT REST. PERFORM ARTF RESP IF BRTHG HAS STOPPED. SKIN: REMOVE CONTAM CLTHG. WASH AFFECTED AREA W/LRG QTYS OF WATER FOR @ LST 5 MIN. SEEK MED ATTN IF NEC. EYE: FLUSH AFFECTED AREAS W/WATER FOR @ LST 15 MIN. SEEK MED ASSISTANCE IF NEC. INGEST: IF CONSCIOUS, INDUCE VOMIT. IF UNCON OR CONVULSIVE, SEEK IMMED MED ASSISTANCE. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: CLEAN UP SPILLED MATL SO AS TO MINIMIZE DISPERSION OF DUST. WET SWEEPING OR VACUUMING USING HEPA FILTRATION ARE RECOMMENDED METHODS. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: RETURN TO MANUFACTURER FOR RECLAIM. DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS (FP N). Handling And Storage Precautions: DO NOT STORE AT HIGHLY-ELEVATED TEMPERATURES OR IN PROXIMITY TO INCOMPATIBLE MATERIALS. Other Precautions: NONE SPECIFIED BY MANUFACTURER. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: USE DRY POWDER. DO NOT USE WATER. Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: IN FINELY-DIVIDED FORM, THIS MATL MAY IGNITE WHEN EXPOSED TO FLAME OR BY RXN W/INCOMATIBLE MATLS. FIRE/EXPLO INVOLVING THIS MATL MAY REL POTENTIALLY (SUPP DATA) ======================================================= Control Measures ======================================================= Respiratory Protection: IF EXPOSURE LEVELS EXCEED OSHA PEL(S), WEAR A NIOSH/MSHA APPROVED RESP HAVING A PROTECTION FACTOR APPROP TO THE AIRBORNE CONCENTRATTTIONS OF THE CONTAMINANTS GENERATED. Ventilation: NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment: BRAZING ALLOYS MAY BE USED W/A SEPARATELY-APPLIED FLUX WHICH, WHEN HEATED, MAY EMIT IRRIT &/OR TOX GASES & Work Hygienic Practices: TO AVOID INGESTION OF MATL, WASH HANDS AND FACE BEFORE EATING, DRINKING, OR CONSUMPTION OF TOBACCO. Supplemental Safety and Health: EXPLO HAZ: TOX EMISSIONS OF METAL OR METAL OXIDE FUMES. MATLS TO AVOID: INORGANIC & ORGANIC PEROXIDES; PEROXY FORMIC ACID; CHLORINE & FLUORINE; PERMONSULFURIC ACID; CHLORATES; CRO*3; MN AND CA CHLORID ES; CS*2; HYDRAZINE MONONITRATE; FE(CO)*5; SELENINYL BROMIDE. ======================================================= Physical/Chemical Properties ======================================================= M.P/F.P Text: >1110F,>599 Spec Gravity: 8.79-9.53 Solubility in Water: INSOLUBLE Appearance and Odor: LIGHT YELLOW METAL IN FORM OF WIRE/ROD/STRIP/POWDER/PREFORMED SHAPES. ODORLESS. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: STABLE AT ROOM TEMPERATURE. Materials To Avoid: STRONG OXIDIZIERS; SE;TE;MG/ACETYLENE; NH*3; AZIDES, ETHANOL, ETHYLENE IMINE; CLF*3" (CHLORINE TRIFLUORIDE);(SUPP DATA) Hazardous Decomposition Products: HEATING AT BRAZING TEMPS MAY LIBERATE OXIDES OF METALS AS FUME FOR SPECIFIC HAZ COMPONENTS & DECOMP PRODS, SEE ING SECT. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: EASY-FLO Cage: 91874 Company Name: LUCAS-MILHAUPT INC A HANDY & HARMAN CO Street: 5656 SOUTH PENNSYLVANIA AVENUE Zipcode: 53110 Label Required IND: Y Date Of Label Review: 03/14/1994 Status Code: C Label Date: 03/14/1994 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE: INHAL: IRRITATION. EYES: IRRITATION. SKIN: DISCOLORATION. INGEST: IRRITATION. VAPORS MAY CAUSE METAL FUME FEVER. CHRONIC: CANCER HAZARD. CONTAINS CADMIUM WHICH IS LISTED AS A LUNG CARCINOGEN TO HUMANS (FP N). MAY CAUSE KIDNEY DISEASE, LIVER, SPLEEN, PANCREAS, BRAIN & KIDNEY DAMAGE. MAY CAUSE SKIN, EYE & RESPIRATORY TRACT DISCOLORATION. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:IONAC C-267 CAGE:76465 CAGE:27580 CAGE:76465 ============= Composition/Information on Ingredients ============= Ingred Name:ION EXCHANGE RESINS (CATION EXCHANGE POLYMER) (45-60%) Fraction by Wt: 52.5% ACGIH TLV:NOT SPECIFIED Ingred Name:WATER,CAS#7732-18-5 (40-55%) CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 47.5% ===================== Hazards Identification ===================== Effects of Overexposure:PRODUCT CAN CAUSE EYE IRRITATION. AVOID SKIN AND EYES CONTACT. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/LG AMT WATER FOR 15 MINUTES. GET MED ATTN. SKIN: WASH W/SOAP & WATER. IF IRRIT PERSISTS, GET MED ATTN. INGEST: GET MED ATTN. DO NOT INDUCE VOMITING. ===================== Fire Fighting Measures ===================== Autoignition Temp:Autoignition Temp Text:800F Extinguishing Media:DRY CHEMICAL,CO*2,WATER FOG. Fire Fighting Procedures:WEAR MSHA/NIOSH APPROVED SCBA FOR FIRES AND CONFINED AREA. Unusual Fire/Explosion Hazard:MAY GIVE TOXIC DECOMPOSITION PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTION.SLIPPERY FLOOR MAY CAUSE FALLS.SWEEP UP SPILLED MATERIAL AND TRANSFER TO A CONTAINER FOR PROPER DISPOAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE MATL INDOORS BETWEEN 32 TO 140F. DO NOT FREEZE. DO NOT ALLOW TO DRY OUT. REPLACE DAMAGED BAGS & REWET RESIN. Other Precautions:AVOID CONTACT WITH EYES AND SKIN.STRONG OXIDIZING AGENTS SUCH AS HNO*3 CAN CAUSE EXPLOSIVE REACTIONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO SPECIAL REQMNTS UNDER ORDINARY CONDITIONS/ADEQUATE VENT. Ventilation:NORMAL ROOM VENTILATION. Other Protective Equipment:SAFETY SHOWER & EYE BATH Supplemental Safety and Health MSDS DATED 21 OCT 1985. PH OF SLURRY = 2 TO 4. ================== Physical/Chemical Properties ================== HCC:N1 Vapor Pres:17 Vapor Density:0.62 Spec Gravity:1.3 Evaporation Rate & Reference:1 (WATER=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:DARK SPHERICAL BEADS, ODORLESS Percent Volatiles by Volume:45% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. HNO*3 Stability Condition to Avoid:TEMPERATURES ABOVE 40 OF. Hazardous Decomposition Products:CO,CO*2,SO*2 SO*3,STYRENE,DIVINYLBENZENE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF COLLECTED MATERIAL IN ACCORDANCE WITH LOCAL,STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BROMINE TRIFLUORIDE Kit Part:=== Responsible Party === 780-471-4036 780-471-4036 CAGE:Company Name:MATHESON TRI-GAS, INC. 780-471-4036 CAGE: ============= Composition/Information on Ingredients ============= Ingred Name:BROMINE TRIFLUORIDE CAS:7787-71-5 Fraction by Wt: >98% ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:No IARC:NoOSHA:No Health Hazards Acute and Chronic:INHALATION: SHORT TERM EXPOSURE: burns, difficulty breathing, dizziness, bluish skin color, lung congestion LONG TERM EXPOSURE: tooth decay, digestive disorders SKIN CONTACT: SHORT TERM EXPOSURE: burns LONG TERM EXPOSURE: same as effects reported in short term exposure EYE CONTACT: SHORT TERM EXPOSURE: burns, tearing, blindness LONG TERM EXPOSURE: same as effects reported in short term exposure INGESTION: SHORT TERM EXPOSURE: burns, nausea, vomiting, diarrhea, stomach pain, difficulty breathing, kidney damage, convulsions, coma LONG TERM EXPOSURE: same as effects reported in short term exposure Medical Cond Aggravated by Exposure: ======================= First Aid Measures ======================= First Aid: INHALATION: If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. SKIN CONTACT: Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get immediate medical attention. Thoroughly clean and dry contaminated clothing and shoes before reuse. Destroy contaminated shoes. EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. INGESTION: Contact local poison control center or physician immediately. Never make an unconscious person vomit or drink fluids. Give large amounts of water or milk. Allow vomiting to occur. When vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get medical attention immediately. NOTE TO PHYSICIAN: For inhalation, consider oxygen. Avoid gastric lavage or emesis. ===================== Fire Fighting Measures ===================== Flash Point:No data available. Extinguishing Media:regular dry chemical, soda ash, water Large fires: Flood with water. Apply water from a protected location or from a safe distance. Fire Fighting Procedures:Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. Unusual Fire/Explosion Hazard:Negligible fire hazard. ================== Accidental Release Measures ================== Spill Release Procedures:Avoid contact with combustible materials. Do not touch spilled material. Stop leak if possible without personal risk. Reduce vapors with water spray. Do not get water inside container. Small spills: Flood with water. Large spills: Dike for later disposal. Keep unnecessary people away, isolate hazard area and deny entry. Ventilate closed spaces before entering. Neutralizing Agent: ======================Handling and Storage ====================== Handling and Storage Precautions:Store and handle in accordance with all current regulations and standards. Protect from physical damage. Keep separated from incompatible substances. Keep separated from incompatible substances. NFPA 430 Code for the Storage of Liquid and Solid Oxidizing Materials. Other Precautions: ============= Exposure Controls/Personal Protection ============= Respiratory Protection:Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with full facepiece and operated in a pressure-demand or other positive-pressure mode in combination with a separate escape supply. Any self-contained breathing apparatus with a full facepiece. Ventilation:Provide local exhaust or process enclosure ventilation system. Ensure compliance with applicable exposure limits. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Other Protective Equipment:Wear appropriate chemical resistant clothing. Supplemental Safety and Health BROMINE TRIFLUORIDE: INORGANIC FLUORIDES (as F): 2.5 mg/m3 OSHA TWA 2.5 mg/m3 ACGIH TWA 2.5 mg/m3 NIOSH recommended TWA 10 hour(s) ================== Physical/Chemical Properties ================== Boiling Pt:261 F (127 C) Melt/Freeze Pt:48 F (9 C) Vapor Pres:769 mmHg @ 257 C Vapor Density:Not available Spec Gravity:2.8 pH:Not available Evaporation Rate & Reference:Not available Solubility in Water:decomposes violently Appearance and Odor:PHYSICAL STATE:liquid COLOR:colorless, yellow or gray PHYSICAL FORM:fuming liquid ODOR:irritating odor Corrosion Rate: ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:Stable at normal temperatures and pressure. Stability Condition to Avoid:Avoid contact with combustible materials. Keep dry. Dangerous gases may accumulate in confined spaces. Keep out of water supplies and sewers. Hazardous Decomposition Products:Thermal decomposition products: acid halides, acid halides Thermal decomposition products: acid halides, acid halides Conditions to Avoid Polymerization:Will not polymerize. =================== Toxicological Information=================== Toxicological Information:BROMINE TRIFLUORIDE: LOCAL EFFECTS: Corrosive: inhalation, skin, eye, ingestion ===================== Ecological Information ===================== Ecological:Not available ==================== Disposal Considerations ==================== Waste Disposal Methods:Dispose in accordance with all applicable regulations. =================== MSDS Transport Information =================== Transport Information:U.S. DOT 49 CFR 172.101: PROPER SHIPPING NAME: Bromine trifluoride ID NUMBER: UN1746 HAZARD CLASS OR DIVISION: 5.1 PACKING GROUP: I LABELING REQUIREMENTS: Oxidizer; Poison; Corrosive QUANTITY LIMITATIONS: PASSENGER AIRCRAFT OR RAILCAR: Forbidden CARGO AIRCRAFT ONLY: Forbidden ===================== Regulatory Information ===================== SARA Title III Information: SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.30): Not regulated. SARA TITLE III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.40): Not regulated.SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS CATEGORIES (40 CFR 370.21): ACUTE: Yes CHRONIC: Yes FIRE: Yes REACTIVE: Yes SUDDEN RELEASE: YesSARA TITLE III SECTION 313 (40 CFR 372.65): Not regulated. Federal Regulatory Information:CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR 302.4): Not regulated. OSHA PROCESS SAFETY (29CFR1910.119): BROMINE TRIFLUORIDE: 15000LBSTQ State Regulatory Information: California Proposition 65: Not regulated. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CERAMAFORM CAGE:62500 CAGE:62500 ============= Composition/Information on Ingredients ============= Ingred Name:ALUMINOSILICATE FIBER OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:COLLOIDAL SILICA (PRECIPITATED) OSHA PEL:N/K ACGIH TLV:5 MG/M3 (MFR) Ingred Name:AMORPHOUS SILICA OSHA PEL:80 MG/M3 (MFR) ACGIH TLV:20 PPM (MFR) ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE/CHRONIC: MAY BE HARMFUL IF INGEST/INHALED. MAY BE IRRIT TO SKIN, EYES & RESP TRACT. POSS CANCER HAZ BASED ON TESTS W/LAB ANIMALS. INGEST: SLIGHTLY TOX. MAY CAUSE GI DISTURB, IRRIT, NAUS, VOMIT & DIARR. SKIN: SLIGHTLY TO MOD IRRIT. MAY CAUSE IRRIT & INFLAMM, REDNESS, RASH DUE TO MECH RXN TO SHARP,(EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: BROKEN ENDS OF FIBERS. EYE: SLIGHTLY TO MOD IRRIT. ABRASIVE ACTION MAY CAUSE DMG TO OUTER SURF OF EYE. MECH SCRATCH, REDDENING OF EYE SURF. INHAL: MAY CAUSE RESP TRACT IRRIT. BASED UPON LIM TESTING W/LAB ANIMALS, REFRACTORY CERAMIC FIBERS ARE SUSPECTED CARCIN IN LAB ANIMALS. Medical Cond Aggravated by Exposure:PREEXISTING MEDICAL CONDITIONS MAY BE AGGRAVATED BY EXPOSURE: SPECIFICALLY, BRONCHIAL HYPER-REACTIVITY AND CHRONIC BRONCHIAL OR LUNG DISEASE. ======================= First Aid Measures ======================= First Aid:INGEST: DO NOT INDUCE VOMIT. GET MED ATTN IF IRRIT PERSISTS. SKIN: WASH AREA THORO W/SOAP & WATER. DO NOT RUB/SCRATCH EXPOS SKIN. SKIN CREAM/LOTION AFTER WASHING MAY BE HELPFUL. GET MED ATTN IF IRRIT PERSISTS. EYES: FLUSH IMMED W/LGE AMTS OF WATER FOR AT LEAST 15 MIN. DO NOT RUB EYES. INHAL: REMOVE PERS FROM SOURCE OF EXPOS. GET MED ATTN. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:WHERE POSSIBLE, USE VACUUM SUCTION TO CLEAN UP SPILLED MATERIAL. USE DUST SUPPRESSANT WHERE SWEEPING IS NECESSARY. PERSONAL SAFETY AND EXPOSURE RECOMMENDATIONS DESCRIBED ELSEWHERE IN THIS DOCUMENT APP LY TO EXPOSURE DURING CLEAN-UP OF SPILLED MATL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:PROD WHICH HAS BEEN IN SERVICE AT ELEVATED TEMPS (>1600F) MAY UNDERGO PARTIAL CONVERSION TO CRISTOBALITE, A FORM OF CRYSTALLINE SILICA WHICH (SUP DAT) Other Precautions:CARE SHOULD BE TAKEN WHEN WORKING W/"USED" MATL TO MIN GENERATION OF DUST. WHEN REMOVING & HNDLG CERAMIC FIBER USED IN HIGH TEMP APPLICATNS, SPEC CAUTION SHOULD BE TAKEN TO AVOID UNNEC CUTTING & TEARI NG OF USED MATL TO MIN DUST GENERATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATORS WHEN AIRBORNE EXPOSURE LIMITS ARE EXCEEDED. Ventilation:LOC EXHAUST & MECH (GEN) VEN REC (FOLLOW OSHA STD 29 CFR 1910.94). USE LOC EXHAUST/OTHER PREC DURING BINDER BURN-OFF. Other Protective Equipment:LONG SLEEVE, LOOSE FITTING CLTHG & BARRIER CREAM. ANSI APPRVD EMER EYEWASH & DELUGE SHOWER . Work Hygienic Practices:DO NOT EAT/SMOKE IN WORK AREA. WASH HANDS THORO AFTER HNDLG. WASH CLTHG SEPARATELY. USE SEPARATE LOCKER FOR WORK CLTHG. Supplemental Safety and Health HNDLG/STOR PREC: CAN CAUSE SEV RESP DISEASE (PNEUMOCONIOSIS). AMT OF CRISTOBALITE SILICA PRESENT WILL DEPEND ON TEMP & LENGTH IN SERVICE. CO, CO*2, OXIDES OF NITROGEN, REACTIVE HYDROCARBONS & A SML AM T OF FORMALDEHYDE MAY ACCOMPANY BINDER BURN-OFF DURING FIRST HEAT. ================== Physical/Chemical Properties ================== Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES INCOMPATIBLE WITH HYDROFLUORIC ACID AND CONCENTRATED ALKALI. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CONTAINS ALUMINOSILICATE FIBER WHICH COULD TRANSFORM UPON HEATING TO MULLITE & CRISTOBALITE(FORM OF CRYSTALLINE SILICA). ==================== Disposal Considerations ==================== Waste Disposal Methods:THE TRANSPORTATION, STORAGE, TREATMENT, AND DISPOSAL OF THIS MATERIAL MUST BE CONDUCTED IN COMPLIANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BATTERY DRY BA 65 Preparer's Name:DGSC-SSH CAGE:71092 CAGE:71092 ============= Composition/Information on Ingredients ============= Ingred Name:MERCURY CAS:7439-97-6 RTECS #:OV4550000 Other REC Limits:0.05 MG/M3 OSHA PEL:S, C, 0.1 MG/M3 ACGIH TLV:S, 0.05 MG/M3; 9091 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ZINC CHLORIDE FUME CAS:7646-85-7 RTECS #:ZH1400000 Other REC Limits:NONE SPECIFIED BY M. OSHA PEL:1 MG/M3/2 STEL ACGIH TLV:1 MG/M3/2STEL FUME93 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:AMMONIUM CHLORIDE CAS:12125-02-9 RTECS #:BP4550000 Other REC Limits:NONE SPECIFIED BY M. OSHA PEL:10 MG/M3/20 STEL ACGIH TLV:10 MG/M3 FUME; 9091 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:MANGANESE DIOXIDE CAS:1313-13-9 RTECS #:OP0350000 Other REC Limits:NONE SPECIFIED BY M. OSHA PEL:5 MG MN/M3 CEILING ACGIH TLV:5 MG MN/M3 Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 Other REC Limits:NONE SPECIFIED BY M. OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3; 9091 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NONE UNDER NORMAL CONDITIONS. IF BATTERY IS MECHANICALLY BROKEN, THERE IS POSSIBILITY OF EXPOSURE TO MERCURY. AND DRY CHEMICALS CAN CAUSE IRRITATION/BURNS OF SKIN, AND CAN CAUSE PERMANENT DAMAGE TO EY ES. IF INGESTED:MAY CAUSE BURNING OF GITRACT, MERCURY IS HIGHLY TOXIC. CHRONIC:CNS, KIDNEY & EYES. Effects of Overexposure:IF EXPOSED TO BROKEN BATTERY: BURNING OR IRRITATION OF SKIN AND EYES. INGESTION:BURNING SENSATION OF MOUTH AND STOMACH, TREMOR, INSOMNIA, FATIGUE, WEAKNESS. INHALATION OF MERCURY VAPORS: COUGH AND CHE ST PAIN. Medical Cond Aggravated by Exposure:NONE ======================= First Aid Measures ======================= First Aid:IN CASE OF INGESTION:DRINK 1-2 GLASSES OF WATER, CONTACT THE NATIONAL CAPITOL POISON CENTER, WASHINGTON, DC., (202)- 625-3333. INHALATION:REMOVE TO FRESH AIR, PROVIDE CPR IF NEEDED. SKIN:WASH WITH SOA P AND WATER. EYES:RINSE WITH WATER FOR 15 MIN AND SEEK MEDICAL HELP. IN ALL CASES, IF SYMPTOMS PERSIST SEE PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE CARBON DIOXIDE, FOAM, OR DRY POWDER. Fire Fighting Procedures:USE SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:CELLS MAY RUPTURE WHEN EXPOSE TO EXCESSIVE HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:COLLECT BATTERIES. BROKEN BATTERIES MUST BE DRUMS FOR PROPER DISPOSAL. DO NO INHALE VAORS. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE UNPACKAGED CELLS TOGETHER SO CONTACTS CAN TOUCH. THIS SITUATION WILL RESULT IN CELL SHORTING AND HEAT BUILD-UP. Other Precautions:DO NOT RECHARGE OR SHORT CIRCUIT BATTERIES. DO NOT INCINERATE. DO NOT MECHANICALLY BREAK BATTERIES. WHEN HANDLING ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. WHEN HANDLING BROKEN BATTERIES, WEAR SELF BREATHING APPARATUS. Ventilation:NORMAL VENTILATION. Other Protective Equipment:NONE STATED Work Hygienic Practices:DO NOT EAT, DRINK OR SMOKE IN WORK AREA. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Appearance and Odor:SOLID RECTANGULAR W/CORNER OPTIONAL/D/. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE STATED Stability Condition to Avoid:NONE STATED Hazardous Decomposition Products:IN THE HEAT OF FIRE OXIDES OF CARBON, ZINC, MANGANESE, AMMONIA AND MERCURY VAPORS MAY BE EVOLVED. ==================== Disposal Considerations ==================== Waste Disposal Methods:IN SMALL QUANTITIES, IT CAN BE DISPOSED OF WITH HOUSHOLD TRASH. FOR LARGE QUANTITIES, DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:JET-LUBE MP-50 Preparer's Name:D. A. OLDIGES CAGE:07431 CAGE:07431 ============= Composition/Information on Ingredients ============= Ingred Name:SOLVENT REFINED HYDROTREATED RESIDUAL OIL; (PETROLEUM OILS; ALTERNATE MFR CAS NO: 64742-62-7) CAS:64742-57-0 Fraction by Wt: 50%MAX OSHA PEL:5MG/M3 OIL MIST(MFR) ACGIH TLV:5MG/M3 OIL MIST(MFR) Ingred Name:MOLYBDENUM DISULFIDE (LIMITS GIVEN AS INSOL MO COMPOUNDS) CAS:1317-33-5 RTECS #:QA4697000 Fraction by Wt: 60%MAX Other REC Limits:15 MG/M3 (MFR) OSHA PEL:10 MG/M3 ACGIH TLV:10 MG/M3 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:REPEATED SKIN CONTACT FOR PERSONS HYPERSENSITIVE TO PETROLEUM PRODUCTS CAN CAUSE REDNESS AND IRRITATION OF SKIN. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:REDNESS AND IRRITATION OF SKIN. Medical Cond Aggravated by Exposure:UNKNOWN. ======================= First Aid Measures ======================= First Aid:INHAL: CLEAR AIR PASSAGE, CALL MD. INGEST: DO NOT INDUCE VOMITING; CALL MD. EYES: WASH WITH COPIOUS QUANTITIES OF WATER FOR AT LEAST 15 MINUTES. SKIN: REMOVE BY WIPING, OR WATERLESS HAND CLEANER, FOLL OWED BY WASHING. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:561F,294C Lower Limits:0.9% Upper Limits:7% Extinguishing Media:USE FOAM, DRY CHEMICAL, WATER SPRAY (FOG), CO2, OR VAPORIZING LIQUID-TYPE EXTINGUISHING AGENTS. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:SCOOP UP EXCESS, WIPE UP WITH RAGS, PICK-UP RESIDUE WITH DIATOMACEOUS EARTH TO AVOID WALKING HAZARD. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NORMAL PRECAUTIONS AS WITH ANY PETROLEUM PRODUCT. Other Precautions:NOT REQUIRED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NOT REQUIRED. Other Protective Equipment:PERSONS WITH HYPERSENSITIVE SKIN SHOULD USE Work Hygienic Practices:WASH HANDS BEFORE EATING. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:B.P. Text:826F,441C Vapor Pres:<0.01 Vapor Density:>5 Spec Gravity:1.44 (H2O=1) Evaporation Rate & Reference:<0.01 (N-BUTYL ACETATE=1) Solubility in Water:NONE Appearance and Odor:BLUE-BLACK PASTE, PETROLEUM ODOR. Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING MATERIALS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:HYDROGEN, CO, ALDEHYDES, SMOKE & FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT FEDERAL, STATE AND LOCAL REGULATIONS FOR PETROLEUM PRODUCTS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:F-152, EPOXY POLYAMIDE, COMPONENT A AND B MIXED Preparer's Name:HENRY SIMMONS CAGE:9D157 CAGE:9D157 ============= Composition/Information on Ingredients ============= Ingred Name:HARDNER-AMIDO AMIDE Minumum % Wt:.25 Maxumum % Wt:1. Ingred Name:TETRAETHYLENEPENTAMINE CAS:112-57-2 RTECS #:KH8585000 < Wt:5. Ingred Name:POLYAMINE AMID = Wt:95. Ingred Name:RESIN HARDNER-POLYAMIDE Ingred Name:RESIN SOLUTION Minumum % Wt:10. Maxumum % Wt:14. Ingred Name:N-BUTYL ALCOHOL CAS:71-36-3 RTECS #:EO1400000 Minumum % Wt:12. Maxumum % Wt:14. OSHA PEL:300 MG/M3;100 PPM ACGIH STEL:C152 MG/M3;C50 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TRIETHYLENETETRAMINE CAS:112-24-3 RTECS #:YE6650000 < Wt:4. Ingred Name:MODIFIED POLYAMIDE RESIN = Wt:75. Ingred Name:RHEOLOGICAL ADDITIVE Minumum % Wt:.01 Maxumum % Wt:1. Ingred Name:MAGNESIUM SILICATE HYDRATE Minumum % Wt:20. Maxumum % Wt:25. Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Minumum % Wt:20. Maxumum % Wt:28. OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:N-BUTYL ALCOHOL Minumum % Wt:12. Maxumum % Wt:14. OSHA PEL:100 PPM ACGIH TLV:50 PPM Ingred Name:EPICHLOROHYDRIN BIS PHENOL A Ingred Name:EPOXY RESIN CAS:25068-38-6 RTECS #:CE6880000 Minumum % Wt:20. Maxumum % Wt:27. Ingred Name:RHEOLOGICAL ADDITIVE Minumum % Wt:.25 Maxumum % Wt:.45 Ingred Name:AROMATIC HYDROCARBON MIXTURE CAS:64742-95-6 RTECS #:WF3400000 Minumum % Wt:10. Maxumum % Wt:14. Ingred Name:XYLENE CAS:1330-20-7 RTECS #:ZE2100000 Minumum % Wt:2. Maxumum % Wt:5. OSHA PEL:100 PPM ACGIH TLV:434 MG/M3;100 PPM ACGIH STEL:651 MG/M3;150 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BENZENE, TRIMETHYL- CAS:25551-13-7 RTECS #:DC3220000 Minumum % Wt:24. Maxumum % Wt:29. OSHA PEL:25 PPM ACGIH TLV:123 MG/M3;25 PPM Ingred Name:CUMENE CAS:98-82-8 RTECS #:GR8575000 Minumum % Wt:1. Maxumum % Wt:4. OSHA PEL:245 MG/M3;50 PPM ACGIH TLV:246 MG/M3;50 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:MAGNESIUM SILICATE HYDRATE Minumum % Wt:10. Maxumum % Wt:15. ===================== Hazards Identification ===================== Health Hazards Acute and Chronic:ACUTE: NAUSEA, DIZZINESS, HEADACHE AND CONVULSIONS. CHRONIC: POSSIBLE SKIN SENSITIZATION. Explanation of Carcinogenicity:PROP 65 CA (THIS PRODUCT CONTAINS A CHEMICAL TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. Effects of Overexposure:INHALED: COUGHING, SHORTNESS OF BREATH MAY CAUSE DIZZINESS. CONTACT WITH SKIN OR EYES: BURNING SENSATION, RASH BREAKOUT WITH SKIN TURNING PINK AND REDNESS OF EYES. ABSORBED THROUGH SKIN: SKIN RASH M AY CAUSE BURNING OF SKIN AND INFLAMMATION. SWALLOWED: VOMITING DUE TO UNPLEASANT TASTE. MAY CAUSE DIARRHEA OR STOMACH CRAMPS. Medical Cond Aggravated by Exposure:ASTHMAS, EMPHYSEMA AND OTHER RESPIRATORY DISEASES. ======================= First Aid Measures ======================= First Aid:EYE CONTACT: FLUSH IMMEDIATELY WITH FRESH WATER BY AN EYE WASH APPARATUS AT HAND. SEEK MEDICAL ATTENTION. SKIN CONTACT: WASH IMMEDIATELY WITH WATER. THEN WASH WITH SOAP AND WATER, RINSE IMMEDIATELY. IF BURNING SENSATION, RASH BREAKOUT, OR OTHER SYMPTOMS OCCUR SEEK MEDICAL ATTENTION. INHALED: MOVE PERSON TO FRESH AIR; ARTIFICIAL RESPIRATION IF NECESSARY. SEEK MEDICAL ATTENTION.SWALLOWED: SEEK ME DICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:=38.3C, 101.F Lower Limits:1.4 Upper Limits:11.2 Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM, DRY CHEMICAL. Fire Fighting Procedures:BLANKET FIRE WITH ONE OF THE ABOVE. DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTION AND EQUIPMENT INCLUDING NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:KEEP MATERIAL AWAY FROM HEAT, SPARKS, AND OPEN FLAMES. EXPLOSIVE WHEN HEATED. STAY A SAFE DISTANCE FROM FIRE WHEN EXTINGUISHING. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL TYPES OF IGNITION SOURCES. PROVIDE SUFFICIENT VENTILATION. PROTECT CLEANUP MAN WITH NIOSH APPROVED ======================Handling and Storage ====================== Handling and Storage Precautions:PROTECT AGAINST PHYSICAL DAMAGE TO CONTAINERS AND SPILLAGE. STORE IN A COOL WELL VENTILATED AREA WITH SPRINKLER SYSTEM. KEEP AWAY FROM HEAT. POST NO SMOKING SIGNS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE DUST/MIST RESPIRATOR (HIGH EFFICIENCY CARTRIDGES ADVISED) IF SPRAYING OR SANDING. USE NIOSH APPROVED ORGANIC VAPOR AND SPRAY PAINT PREFILTERS IF TLV FOR SOLVENT COMPOUNDS MAY BE EXCEEDED. WHEN USI NG IN CONFINED AREA, WEAR AIR-FED HOOD. Ventilation:USE LOCAL EXHAUST WHEN APPLYING THIS PAINT IN CONFINED AREAS. KEEP AREAS BELOW TLV. Other Protective Equipment:USE PROTECTIVE CLOTHING AND CHANGE CONTAMINATED IMMEDIATELY. PROVIDE EMERGENCY SHOWERS AND EYEWASH AT STATIONARY PAINT APPLICATION FACILITIES. Work Hygienic Practices:TRAIN EMPLOYEES IN ALL SPECIAL HANDLING PROCEDURES IN THIS SECTION BEFORE THEY WORK WITH THIS PRODUCT. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:=53.3C, 128.F Vapor Pres:4.4 AT 60F Vapor Density:2.1 Spec Gravity:1.3 VOC Pounds/Gallon:340 Evaporation Rate & Reference:(BUTYL ACETATE = 1): .43 Solubility in Water:POOR Appearance and Odor:TYPICAL PAINT APPEARANCE WITH STRONG SOLVENT ODOR TYPICAL OF BUTANOL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WHEN "A" OR "B" ARE MIXED, KEEP AWAY FROM HEAT. HEAT WILL CREATE A RAPID CHEMICAL REACTION. EMITS HEAT. Stability Condition to Avoid:HEAT, SPARKS AND OPEN FLAME. DO NOT ALLOW VAPOR TO ACCUMULATE. Hazardous Decomposition Products:COMBUSTIBLE FUMES MAY ACCUMULATE IN CONFINED AREAS AND SPARKS OR OPEN FLAMES MAY IGNITE IT. ==================== Disposal Considerations ==================== Waste Disposal Methods:USE METAL CONTAINER MARK ?DO NOT REUSE?. PUT MATERIAL IN THIS CONTAINER. USE VERMICULITE OR OTHER INERT ABSORBENT. KEEP AWAY FROM SEWER. DISPOSE OF ALL WASTE IN ACCORDANCE WITH FEDERAL, STATE, AND LO CAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PERMA-LOK (R) MM 115 P/N 78-4310 Preparer's Name:PHILIP A TOSCANO CAGE:85091 CAGE:85091 ============= Composition/Information on Ingredients ============= Ingred Name:TETRAETHYLENE GLYCOL DIMETHACRYLATE CAS:109-17-1 Fraction by Wt: >1% Other REC Limits:NONE SPECIFIED Ingred Name:HYDROXYETHYL METHACRYLATE (ORAL LD50 1250.0 MG/KG RAT) CAS:868-77-9 RTECS #:OZ4725000 Fraction by Wt: >1% Other REC Limits:MFR: 3.000 PPM Ingred Name:CUMENE HYDROPEROXIDE (SARA III) (ORAL LD50 800.0 MG/KG RAT; DERMAL LD50 1.1 ML/KG RAT; INHAL LC50 700.0 PPM/6 HR RAT) CAS:80-15-9 RTECS #:MX2450000 Fraction by Wt: >1% Other REC Limits:NONE SPECIFIED EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:VOC: 0.09 LBS/GAL (10 G/L) RTECS #:9999999VO Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE: IRRITATING, INJURE TISSUE IF NOT REMOVED PROMPTLY. SKIN: FREQUENT OR PROLONGED CONTACT: IRRITATE, DERMATITIS. SENSITIZATION, DERMATITIC RASH. INHALATION:NOT RESPIRATORY HAZARD UNDER NORMAL CONDIT IONS. IRRITATING/TOXIC VAPORS AT ELEVATED TEMPERATURES. INGESTION: NOT EVALUATED, ASSUMED TO CAUSE NAUSEA AND VOMITING. Effects of Overexposure:CHRONIC: IN CERTAIN INDIVIDUALS SENSITIZATION MAY OCCUR CAUSING DERMATITIS WITH EVEN MINIMAL CONTACT. DUE TO SKIN ABSORPTION WITH EXCESSIVE CONTACT, PRODUCT MAY PRODUCE NERVOUS SYSTEM EFFECTS, I.E., A TAXIA. TARGET ORGANS: SKIN AND EYES. ======================= First Aid Measures ======================= First Aid:EYE:IMMED FLUSH W/WATER 15 MIN,LIFT EYELIDS. GET PROMPT MED AID. SKIN:FLUSH W/SOAP & WATER TILL CHEMICAL GONE. REMOVE CONTAM CLOTHING,WASH BEFORE REUSE. INHAL:FIRST AID NOT NORMALLY REQUIRED. REMOVE T O FRESH AIR. IF BREATHING DIFFICULT,GIVE OXYGEN;IF STOPPED,GIVE ARTIF RESP.GET MED AID. INGEST:DON'T INDUCE VOMITING. IF CONSCIOUS,GIVE MILK/WATER(NOTHING TO UNCONSCIOUS).KEEP WARM/QUIET. GET MED AID. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:230F,110C Extinguishing Media:CO2, DRY CHEMICAL, FOAM, WATER FOG Fire Fighting Procedures:EQUIP FIRE FIGHTERS WITH SELF-CONTAINED BREATHING APPARATUS TO PROTECT AGAINST POTENTIALLY TOXIC AND IRRITATING FUMES. COOL EXPOSED EQUIPMENT WITH WATER SPRAY. Unusual Fire/Explosion Hazard:POLYMERIZATION MAY TAKE PLACE AT ELEVATED TEMPERATURES. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE CLOTHING. STOP LEAK IF WITHOUT RISK. SMALL SPILL: TAKE UP WITH SAND, ETC. PLACE IN CONTAINERS (LATER DISPOSAL). LARGE SPILL: ABSORBED PRODUCT MAY POLYMERIZE (GENERATE HEAT & PRESSURE). VENT CONTAINER TO PREVENT BUILDUP OF PRESSURE. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID EXCESSIVE HEAT. STORE AT ROOM TEMPERATURE OUT OF DIRECT SUNLIGHT IN A DRY AREA. MAXIMUM STORAGE TEMPERATURES IS 100 F. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED UNDER NORMAL HANDLING CONDITIONS. USE NIOSH APPROVED RESPIRATOR IF VAPOR OR MIST LEVELS ARE IRRITATING. Ventilation:GENERAL Other Protective Equipment:NO SPECIAL CLOTHING REQUIRED FOR LOW VOLUME ACTIVITY. REMOVE CLOTHES, WASH BEFORE REUSE IF CONTAMINATED WITH PRODUCT. Work Hygienic Practices:WASH HANDS WITH SOAP & WATER OR BEFORE EATING, DRINKING, SMOKING, OR USING TOILET FACILITIES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Vapor Pres:0.01 @ 77F Vapor Density:1.01 Viscosity:1000 CPS Evaporation Rate & Reference:NOT NOTED Percent Volatiles by Volume:<1 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES METALS AND THEIR SALTS, PERMA-LOK (R) ANAEROBIC SURFACE CONDITIONERS. Hazardous Decomposition Products:THERMAL DECOMPOSITION COULD PRODUCE CARBON MONOXIDE, CARBON DIOXIDE, AND UNIDENTIFIED ORGANIC COMPOUNDS. Conditions to Avoid Polymerization:ANAEROBIC. POLYMERIZE IN ABSENCE OF AIR. SUNLIGHT,EXCESSIVE HEAT,ANAEROBIC SURFACE CONDI (LRG QTY) CAUSE POLYMERIZATION. ==================== Disposal Considerations ==================== Waste Disposal Methods:CAN CAREFULLY SOLIDIFY WITH ANAEROBIC SURFACE CONDITIONER AND DISPOSE OF AS SOLID WASTE. WASTE DISPOSAL SHOULD BE IN ACCORDANCE WITH EXISTING FEDERAL, STATE, AND LOCAL ENVIRONENTAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ZL-22D ZYGLO PENETRANT Preparer's Name:BRUCE C.GRAHAM CAGE:37676 CAGE:37676 ============= Composition/Information on Ingredients ============= Ingred Name:DISTILLATES(PETROLEUM),HYDROTREATED MIDDLE CAS:64742-46-7 RTECS #:JN9379645 Fraction by Wt: 25.0% Ingred Name:KEROSENE CAS:8008-20-6 RTECS #:OA5500000 Fraction by Wt: 10.0% ACGIH TLV:100MG/CUM Ingred Name:DISTILLATES(PETROLEUM),CATALYTIC REFORMER FRACTIONATER RESIDUE,LOW BOILING CAS:68477-31-6 Fraction by Wt: 20.0% Ingred Name:UNIDENTIFIED COMPONENTS Fraction by Wt: 45.0% ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:IRRITATES EYES,MILDLY. Effects of Overexposure:INHALATION:SPRAY MIST MAY IRRITATE TO BREATHING PASSAGES; EYES:LIQUID CONTACT MAY CAUSE IRRITATION; SKIN:SOLVENT IN THE PRODUCT MAY IRRITATE SKIN; INGESTION:NOT NOTED BY MANUFACTURER. Medical Cond Aggravated by Exposure:NOT STATED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE TO FRESH AIR.IF BREATHING IS DIFFICULT,GIVE OXYGEN; SKIN:REMOVE CONTAMINATED CLOTHES.WASH OFF WITH FLOWING WATER.USE SOOTHING LOTION.IF IRRITATION PERSISTS,GET MEDICAL ATTN; EYES:IMM EDIATELY RINSE/FLUSH WITH COPIOUS AMOUNT OF RUNNING WATER,AND GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:>200F/>93C Extinguishing Media:CARBON DIOXIDE,FOAM Fire Fighting Procedures:KEEP CONTAINERS COOL WITH WATER SPRAY.DO NOT SPRAY ON BURNING PRODUCT. Unusual Fire/Explosion Hazard:WHEN INVOLVE IN COMBUSTION,MAY EMIT TOXIC GASES AT OR ABOVE DECOMPOSITION TEMPERATURE. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE IGNITION SOURCES.SM QTY:WIPE UP OR MOP UP BUT DO NOT BREATHE VAPORS.PLACE RAGS IN CLOSED DRUMS; LG QTY:WEAR PERSONAL SAFETY EQUIPMENTS.DIKE AREA FAR AHEAD.ABSORB LIQUID WITH COMMERCIAL ABSORBEN T.TRANSFER WASTE MATL IN SALVAGE TANKS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM HEAT SOURCES IN WELL VENTILATED AREA.AVOID AGAINST PHYSICAL DAMAGE TO CONTAINERS.KEEP CONTAINERS TIGHTLY CLOSED. Other Precautions:DO NOT BREATHE VAPORS.DO NOT SMOKE WHILE USING.DO NOT HEAT ABOVE 130F(54C).AVOID FREQUENT OR PROLONGED SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR A RESPIRATOR WITH CHEMICAL CARTRIDGE. IN CONFINED AREAS,WEAR A FULL MASK WITH SEPARATE AIR SUPPLY. Ventilation:GENERAL VENTILATION TO KEEP BELOW 350PPM LIMIT. Other Protective Equipment:EITHER USE IN A SPRAY BOOTH OR NEXT TO AN EXHAUST VENT. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING OR USE.LAUNDER CONTAMINATED CLOTHES BEFORE REUSE. Supplemental Safety and Health NSN FOR TYPE I,METHOD D,LEVEL 3 MATERIAL OF MIL-I-25135D ZL-22D PENETRANT IS A QUALIFIED PRODUCT OF QPL-25135-15 FOR TYPE I,METHOD D,LVL 3;THE QPL SPECIFIED THE PENETRANT CAN ALSO BE A PART OF KIT WIT H ZR-10A EMULSIFIER;SEE PNI B FOR OTHERQUALIFIED PENETRANT FOR SAME TYPE,METHOD & LEVEL. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:410F/210C Vapor Pres:0.5 @ 100F Vapor Density:>1.0 Spec Gravity:0.95 Solubility in Water:NEGLIGIBLE Appearance and Odor:GREEN LIQUID WITH PETROLEUM DISTILLATE ODOR Percent Volatiles by Volume:5.0% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MFR STATED "NONE" Stability Condition to Avoid:HEAT,HIGH TEMPERATURES Hazardous Decomposition Products:EMITS OXIDES OF CARBON AND NITROGEN ON COMBUSTION ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE OR DISPOSE OF AS EPA HAZARDOUS WASTE D001 (IGNITABLE WASTE),IN ACCORDANCE WITH ALL APPLICABLE FEDERAL,STATE,LOCAL REGULATIONS;IF LOCAL AUTHORIES PROHIBIT DUMPING RINSINGS DOWN THE SEWER,PUR IFY RINSINGS W/MAGNAFLUX WASTEWATER TREATMNT SYSTM
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:N-4165 GREEN TREE MARKING Preparer's Name:MIKE LICHATOWICH CAGE:02388 CAGE:02388 ============= Composition/Information on Ingredients ============= Ingred Name:STODDARD SOLVENT CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: 55% OSHA PEL:500 PPM ACGIH TLV:100 PPM; 9293 Ingred Name:ALKYD RESIN Fraction by Wt: 20% Ingred Name:COBALT (SARA III) CAS:7440-48-4 RTECS #:GF8750000 Fraction by Wt: <1% OSHA PEL:0.1 MG/M3;AS CO ACGIH TLV:0.05 MG/M3;DUST 9293 Ingred Name:MANGANESE (SARA III) CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: <1% OSHA PEL:(C) 5 MG/M3 DUST ACGIH TLV:5 MG/M3 DUST 9293 Ingred Name:MANUFACTURER STATES UNIDENTIFIED INGREDIENTS ARE NOT CONSIDERED HAZARDOUS UNDER FEDERAL HAZARD COMMUNICATION REGULATIONS RTECS #:9999999ZZ Ingred Name:VOC. 4.57 LBS/GAL. RTECS #:9999999VO Ingred Name:VOC: 4.46 LBS/GAL RTECS #:9999999VO Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: SEVERE IRRIT, LACRIMATION, BLURRED VISION, VISUAL DISTRUB & EYE BURNS. SKIN: MAY BE ABSORBED IN TOXIC AMTS FROM PROLONGED/REPEATED EXPOSURE. INHALED: NASAL & RESPIRATORY IRRIT, CNS DEPRESSION, V ERTIGO, UNCONSCIOUSNESS, EVEN ASPHYXIATION. IF SWALLOWED: GASTROINTEST IRRIT & ABDOMINAL PAIN, BLINDNESS & EVEN DEATH. Explanation of Carcinogenicity:NOT LISTED BY NTP, IARC OR OSHA. Effects of Overexposure:EYES: SEVERE IRRITATION, REDNESS, BLURRED VISION, VISUAL DISTURB, EYE BURNS. SKIN: HARMFUL IF ABSORBED. INHALED: DIZZINESS, DROWSINESS, WEAKNESS, FATIGUE, CONFUSION, NAUSEA, HEADACHE, VERTIGO, UNCONSC IOUSNESS, EVEN ASPHYXIATION. SWALLOWED:GASTROINTESTINAL IRRITATION, ABDOMINAL PAIN, NAUSEA, VOMITING & DIARRHEA. Medical Cond Aggravated by Exposure:NONE KNOWN ======================= First Aid Measures ======================= First Aid:INHALE: MOVE TO FRESH AIR IMMED. IF NOT BREATHING, GIVE CPR. GET MED ATTN IMMED. SKIN: WASH WITH SOAP & WATER. EYES: FLUSH WITH LARGE AMOUNTS OF WATER, AT LEAST 15 MIN, LIFTING LIDS. GET MED ATTN IMME D. DO NOT WEAR CONTACT LENSES WHEN WORKING WITH THIS MATERIAL. SWALLOW: DRINK 1 OR 2 GLASSES WATER. DO NOT INDUCE VOMIT. CONSULT PHYSICIAN/POISON CONTROL CENTER IMMEDIATELY. TREAT SYMPTOMATICALLY. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:85 F/29 C Lower Limits:0.8 Upper Limits:36 Extinguishing Media:DRY CHEMICAL, FOAM, CO2. Fire Fighting Procedures:WEAR SCBA W/FULL FACEPIECE-POSITIVE PRESS MODE & FULL PROTECT CLOTHES. USE WTR TO COOL CLOSED CONTAINER, PREVENT PRESS BUILD-UP/AUTO-IGNITE/EXPLOSION FROM HEAT Unusual Fire/Explosion Hazard:KEEP CONTAINER TIGHTLY CLOSED. ISOLATE FROM HEAT, SPARKS, ELEC EQUIP, OPEN FLAME. CLOSED MAY EXPLODE FROM EXTREME HEAT. APPLICATION TO HOT SURFACES REQUIRES * ================== Accidental Release Measures ================== Spill Release Procedures:SMALL SPILL:ELIM ALL IGNITE SOURCES. AVOID BREATHING VAPORS/SKIN CONTACT. USE INERT ABSORB(CLAY,SOIL)SHOVEL RECLAIMED LIQ/ABSORB INTO RECOVERY/SALVAGE DRUMS. LARGE SPILL:SAME AS ABOVE. ALSO DIKE TO PR EVENT FURTHER MOVEMENT, RECLAIM INTO DRUMS/DISPOSE ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID STORAGE IN HIGH TEMPERATURE AREAS OR NEAR FIRE OR OPEN FLAME. KEEP CONTAINERS CLOSED WHEN NOT IN USE. AVOID ROUGH HANDLING. Other Precautions:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTY. DO NOT WELD OR FLAME CUT ON EMPTY DRUMS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR APPROPRIATE(TY TC-23C-75)PROPERLY FITTED HALF-MASK OR FULL FACEPIECE RESPIRATOR (NIOSH/MSHA) DURING & AFTER APPLICATION UNLESS AIR MONITOR DEMONSTRATES VAPOR/MIST LEVEL BELOW APPLICABLE LIMITS.FO LLOW RESPIRATOR MFR'S DIRECTIONS FOR USE Ventilation:VENT IN VOL/PATTERN TO KEEP AIR CONCENTRATE BELOW CURRENT APPLICABLE OSHA PEL/TLV LIMIT & REMOVE DECOMP PRODUCTS FORMED Other Protective Equipment:WEAR CHEMICAL RESISTANT (NITRILE OR VITON) CLOTHING AS NEEDED TO PREVENT SKIN CONTACT. Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING OR USING RESTROOMS. Supplemental Safety and Health EMPLOYEES SHOULD WASH PROMPTLY WHEN SKIN BECOMES CONTAMINATED. REMOVE ANY CLOTHING THAT BECOMES WET (TO AVOID FLAMMABILITY HAZARD) AND WASH BEFORE REUSE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:146 TO 330F Decomp Temp:Decomp Text:N/E Vapor Density:> THAN AIR Viscosity:19 Z#2 Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:SLIGHT Appearance and Odor:LIQUID, ODOR OF SOLVENTS. Percent Volatiles by Volume:71.86 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:HIGH TEMP, SHOCK FROM DROPPING. (THIS MATERIAL HAS BEEN FOUND TO BE STABLE UNDER REASONABLE CONDITIONS OF STORAGE & USE) Hazardous Decomposition Products:CAN PRODUCE CARBON MONOXIDE AND/OR CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:AGEAN BLUE, RFK-402-SB CAGE:30806 CAGE:30806 CAGE:72556 ============= Composition/Information on Ingredients ============= Ingred Name:EPOXY RESIN. VP: 0.01 Fraction by Wt: 35% Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 5% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:(ACUTE) EYE: POSSIBLE IRRIT. INHAL: MAY CAUSE HDCH & RESP IRRIT. SKIN: POSSIBLE IRRIT/SENSIT. (ING 1) INGEST: LOW ORDER OF TOX. POSS DEPRESS OF CNS. INHAL: IRRIT, BUT NOT A LIKELY ROUTE OF EXPOS DUE T O VERY LOW VOLATILITY. EYE: SEVERE IRRIT & POSS DMG. SKIN: MODERATE TO SEVERE IRRIT. POSS ALLERGIC (SEE EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: SKIN RXN IN SUSCEPTIBLE INDIVIDUALS. (ING 2) INGEST: LOW ORAL TOX. NO TOX EFTS DUE TO INGEST ARE DESCRIBED IN LITERATURE. INHAL: IRRIT TO UPPER RESP TRACT. EYE: IRRIT. (CHRONIC) (ING 1) IN V ITRO LAB STUDIES HAVE SHOWN THAT SOME EPOXY RESINS HAVE MUTAGENIC CAPABILITIES. ALL EPOXY RESINS SHOULD BE (SUPP DATA) Medical Cond Aggravated by Exposure:(ING 1) MAY AGGRAVATE EXISTING SKIN CONDITIONS, A DERMAL ALLERGEN. ======================= First Aid Measures ======================= First Aid:INGEST: DRINK 1 OR 2 GLASSES OF WATER AND INDUCE VOMITING BY PLACING FINGER AT BACK OF THROAT. CONSULT MD OR POIS CTL CTR IMMED. INHAL: REMOVE FROM AREA TO FRESH AIR. EYE: IMMEDIATELY BEGIN FLUSHING E YES WITH COOL WATER, OCCASIONALLY LIFTING LIDS TO ENSURE THORO RINSING. CONTINUE FOR AT LEAST 15 MIN. WHILE FLUSHING EYES, SEND FOR MD. SKIN: WASH THOROUGHLY WITH SOAP AND WATER. ===================== Fire Fighting Measures ===================== Flash Point:>200F,>93C Lower Limits:40 G/M3 Extinguishing Media:FOAM, CO2, DRY CHEMICAL, DRY SAND. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:DUST CLOUD OF 40 GRAMS PER CUBIC METER CAN BE IGNITED BY A SPARK OF 20 MILLIJOULES. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP CAREFULLY OR USE EXPLOSION-PROOF VACUUM CLEANER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP ALL EQUIP CLEAN & PROPERLY GROUNDED TO AVOID STATIC ELEC BUILD-UP. KEEP WORK AREAS FREE OF DUST THRU ADEQ VENT. AVOID PRLNGD CONT W/SKIN. Other Precautions:DO NOT INGEST. KEEP OUT OF THE REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE A PROPERLY FITTED NIOSH/MSHA APPROVED MECHANICAL RESPIRATOR OR MASK TO AVOID BREATHING DUST. CAREFULLY FOLLOW MFR INSTRUCTIONS FOR USE. Ventilation:PROVIDE SUFFICIENT VENT IN VOLUME & PATTERN TO KEEP AIR CONTAMINATION BELOW APPLICABLE OSHA PEL/ACGIH'S TLV TWA LIMIT. Other Protective Equipment:PROTECTIVE OVERALLS RECOMMENDED. REMOVE AND WASH CONTAMINATED CLOTHING. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EFTS OF OVEREXP: TREATED AS POTENTIAL MUTAGENS. (ING 2) LABORATORY STUDIES SHOW THAT INHAL EXPOS TO HIGH LEVELS (250 MG/KG) OF TITANIUM DIOXIDE CAUSES CANCEROUS TUMORS IN RATS. THIS RESPONSE DID NOT O CCUR AT LOWER EXPOS LEVS & MAY BE DUE TO HIGH LEVS OF DUST OVERWHELMED THE NORMAL LUNG CLEARANCE MECHANISMS. ================== Physical/Chemical Properties ================== HCC:N1 Vapor Pres:SEE INGRED Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER. Stability Condition to Avoid:STATIC ELECTRICAL CHARGES. Hazardous Decomposition Products:MAY PRODUCE FUMES WHEN HEATED TO DECOMPOSITION. FUMES MAY CONTAIN CO, CO2 AND NO2. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TURCOAT ALUMIGOLD B CAGE:0BYN5 CAGE:0BYN5 CAGE:61102 ============= Composition/Information on Ingredients ============= Ingred Name:ZINC SILICOFLUORIDE (SARA 313) (CERCLA RQ 5000) CAS:16871-71-9 RTECS #:VV8754000 Fraction by Wt: 50.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:2.5 MG/M3 ACGIH TLV:2.5 MG/M3 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:CHROMIC ACID (SARA 313)(CERCLA RQ 10) CAS:1333-82-0 RTECS #:GB6650000 Fraction by Wt: 40.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.1 MG/M3 ACGIH TLV:0.05 MG/M3 Ingred Name:BORIC ACID CAS:10043-35-3 RTECS #:ED4550000 Other REC Limits:NONE RECOMMENDED Ingred Name:HEXAVALENT CHROMIUM COMPOUNDS Fraction by Wt: 20.3% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:EYE: CHEMICAL BURNS, PERMANENT DAMAGE. SKIN: IRRIT, ULCERATION, CHEMICAL BURNS, SENSITIZATION. INHAL: ULCERATION, PERFORATION OF NASAL SEPTUM, IRRIT/DAMAGE TO RESPIRATORY SYSTEM. IRRIT MAY RESEMBLE AS THMA. LUNG CANCER. Explanation of Carcinogenicity:HEXAVALENT CHROMIUM COMPOUNDS LISTED BY IARC GROUP 1, NTP GROUP A. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH W/WATER FOR 5 MIN, THEN W/NORMAL SALINE 30-60 MIN LIFTING LIDS. SKIN: FLUSH W/WATER FOR 15 MIN. INHAL: GET FRESH AIR. OXYGEN IF NEEDED. INGEST: DONT INDUCE VOMIT. DRINK LARGE AMOUNTS MILK. GET IMMED MED AID IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Extinguishing Media:WATER FLOOD Fire Fighting Procedures:USE SCBA. ANY WATER RUN-OFF MAY CONTAIN HEXAVALENT CHROMIUM, SHOULD NOT BE ALLOWED TO ENTER SEWER OR WATERWAYS. Unusual Fire/Explosion Hazard:MAY INCREASE FIRE INTENSITY WHEN IN CONTACT W/COMBUSTIBLES. ================== Accidental Release Measures ================== Spill Release Procedures:SHOVEL DRY SPILL INTO DRUMS. KEEP DRY UNTIL SWEPT UP & SHOVELED INTO DISPOSAL DRUMS. DISOLVE RESIDUE IN WATER. COLLECT SOLUTION IN DRUMS. DONT LET ENTER SEWER/WATERWAYS. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP DRY PROTECTED. MIXING: CAREFULLY ADD TO WATER, AVOID SPLASHING. ADD TO IN USE TANK SLOWLY/CAUTIOUSLY. Other Precautions:REPAIR & MAINTANANCE OF CONTAM EQUIPMENT: RELIEVE PRESSURE. COVER OPENINGS TO AVOID SPURTING. FLUSH INTERIOR/EXTERIOR W/WATER. COLLECT FLUSHINGS FOR DISPOSAL. USE PROTECTIVE EQUIPMENT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOR MIST/VAPORS/DUST, NIOSH APPROVED RESPIRATOR FOR TOXIC MISTS OR HYDROGEN FLUORIDE IS ADVISED. IF RESPIRATORS ARE USED, FORMAL TRAINING & SCREENING PROGRAM MUST BE INITIATED. Ventilation:SUFFICIENT MECHANICAL TO KEEP CONCENTRATIONS BELOW TLV. Other Protective Equipment:BOOTS/APRON MADE OF ACID RESISTANT MATERIAL (VITON/PVC). Work Hygienic Practices:WASH W/SOAP & WATER BEFORE SMOKING/EATING. REMOVE CONTAM CLOTHES, WASH SEPARATELY BEFORE REUSE. DISCARD CONTAM SHOES. Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:NA Vapor Pres:NA Vapor Density:NA Spec Gravity:NA pH:* Evaporation Rate & Reference:NA Solubility in Water:APPRECIABLE Appearance and Odor:DARK RED BROWN GRANULAR MIX, LITTLE OR NO ODOR. Percent Volatiles by Volume:NA ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, STRONG ALKALIES, REACTIVE METALS. Hazardous Decomposition Products:ON HEATING MAY EVOLVE CORROSIVE & TOXIC FUMES OF HYDROGEN FLUORIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:TRANSFER TO RECLAIMING CENTER FOR RECYCLE/REUSE IF POSSIBLE. TRANSFER TO LICENSED WASTE TREATMENT/DISPOSAL SITE ACCORDING TO FEDERAL, STATE & LOCAL REGULATIONS. DISOLVE SMALL AMOUNTS IN WATER/RELEASED TO SEWER IF LOCAL REGULATIONS PERMIT.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CEE-BEE CLEANER C-41 Preparer's Name:TSCA CORP CAGE:71361 CAGE:71361 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANOL, 2-BUTOXY-; (2-BUTOXYETHANOL) (SARA III) CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: <5% OSHA PEL:S, 50 PPM ACGIH TLV:S, 25 PPM Ingred Name:ISOPROPYL ALCOHOL (SARA III) CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: <5% OSHA PEL:400 PPM ACGIH TLV:400 PPM/500 STEL Ingred Name:SILICIC ACID (H2SIO3), DISODIUM SALT; (SODIUM SILICATES) (MFR CAS #6834-98-0) CAS:6834-92-0 RTECS #:VV9275000 Fraction by Wt: <5% OSHA PEL:120 MG/CU (MFR) ACGIH TLV:120 MG/CU (MFR) Ingred Name:VOLATILE ORGANIC CONTENT:70 (GRAMS/LITER) RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CORROSIVE. ACUTE:EYES:STINGING OR BURNING SENSATION. SKIN:POSSIBLE IRRITATION. INGESTION:IRRITATION OR BURNING OF MOUTH AND THROAT. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:ANIMAL STUDIES HAVE CLEARLY DEMONSTRATED DOSE-RELATED ADVERSE EFTS ON THE CNS, HEMATOPOIETIC TISS, BLOOD, KIDNEYS & LIVER ASSOC W/ADMIN OF ETHYLENE GLYCOL MONOBUTYL ETHER (EGBE). (EXTRACTED FROM DHHS (NIOSH) PUB NO. 90-118) . Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O2/ARTIFICIAL RESPIRATION) . EYES & SKIN:FLUSH WITH WATER FOR @ LEAST 15 MINUTES. IF ANY IRRITATION PERSISTS SEEK MEDICAL ATTENTION. INGEST:IF CONSCIOUS, GIVE LARGE QUANTITY OF WATEROR MILK. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:MOP UP AND FLUSH AREA WITH WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AT 32-100F. KEEP CONTAINERS TIGHTLY CLOSED. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TWA EXCEEDED, MUST BE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:SUFFICIENT TO KEEP BELOW TWA LIMITS. Other Protective Equipment:SUFFICIENT TO PREVENT SKIN CONTACT. EMERGENCY EYEWASH & DELUGE SHOWER WHICH MEET ANSI DESIGN STANDARDS . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EYE PROT:& FULL LENGTH FACESHIELD. ================== Physical/Chemical Properties ================== HCC:C2 Boiling Pt:B.P. Text:213F,101C Spec Gravity:1.04 pH:13.0 Evaporation Rate & Reference:<BUTYL ACETATE Solubility in Water:COMPLETE Appearance and Odor:CLEAR, PINK LIQUID. PLEASANT ODOR. Percent Volatiles by Volume:90 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:OXIDES OF CARBON. ==================== Disposal Considerations ==================== Waste Disposal Methods:NEUTRALIZE TO PH WITHIN DISCHARGE LIMITS AND SEWER. FOLLOW ALL LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:M-NITROPHENOL CAGE:HO851 CAGE:HO851 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:PHENOL, M-NITRO-; (M-NITROPHENOL) (CERCLA) CAS:554-84-7 RTECS #:SM1925000 Fraction by Wt: 90-100% OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: IRRITATION OF MUCOUS MEMBRANES. INGESTION: NONE IDENTIFIED. SKIN CONTACT: IRRITATION; PROLONGED CONTACT MAY CAUSE DERMATITIS. EYE CONTACT: IRRITATION. CHRONIC: CENTRAL NERVOUS SYSTEM DEPRE SSION. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NO INFORMATION FOUND. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. PROMPT ACTION IS ESSENTIAL. INGEST: INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MEDICA L PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION. SKIN: FLUSH SKIN WITH WATER. EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NOT EXPECTED TO BE A FIRE HAZARD. EXPLOSION: NO INFORMATION FOUND. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND COVER. REMOVE FROM AREA. FLUSH SPILL AREAWITH WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE AREA. Other Precautions:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTY SINCE THEY RETAIN PRODUCT RESIDUES (DUST, SOLIDS); OBSERVE ALL WARNINGS AND PRECAUTIONS LISTED FOR THE PRODUCT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOR CNDTNS OF USE WHERE EXPOS TO SUBSTANCE IS APPARENT, CONSULT INDUS HYGIENIST. FOR EMERS OR INSTANCES WHERE EXPOS LEVELS ARE NOT KNOWN, USE NIOSH APPRVD FULL-FACEPIECE POS-PRESS, AIR-SUPPLIED RESP. WARNING: AIR PURIFYING RESPS DO (SUPDAT) Ventilation:SYS OF LOC &/OR GEN EXHST RECOM TO KEEP EMPLOYEE EXPOS AS LOW AS POSS. LOC EXHST VENT GENERALLY PREF BECAUSE IT (SUPDAT) Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . WEAR IMPERVIOUS CLTHG, INCL BOOTS, LAB COAT, APRON OR COVERALLS, AS APPROP. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health WASTE DISP METH: UNUSED CONTENTS I/A/W FED, STATE & LOCAL REQS. RESP PROT: NOT PROTECT WORKERS IN OXYG-DEFICIENT ATMS. VENT: CAN CTL EMISSION OF CONTAMINANT AT ITS SOURCE, PREVENTING DISPERSION OF IT INTO GEN WORK AREA. REFER TO ACGIH DOCUMENT, INDUS VENT, A MANNUAL OF RECOM PRACTS, MOST RECENT EDITION, FOR DETAILS. ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:207F,97C Spec Gravity:1.48 Solubility in Water:SLIGHT (0.1-1%) Appearance and Odor:YELLOW TO TAN CRYSTALLINE SOLID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NO INFORMATION FOUND. Stability Condition to Avoid:NO INFORMATION FOUND. Hazardous Decomposition Products:NO INFORMATION FOUND. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY/RECYCLING SHOULD BE MANAGED IN APPROP & APPRVD WASTE DISP FACILITY. PROCESSING, USE/CONTAM OF PROD MAY CHG WASTE MANAGEMENT OPTIONS. STATE & LOC DISP REGS MAY DIF FER FROM FED DISP REGS. DISP OF CNTNR &(SUPDAT)
1
eyes_protection_mandatory
======================================================= Product ID: CF STARTER K1, CF911P Cage: 23736 Resp. Party Other MSDS No.: PPC-137 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 23736 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: SEE TOXICOLOGICAL INFORMATION. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: YES OSHA: NO Effects of Exposure: NO SYMPTOMS EXPECTED WITH INTENDED USE. CHRONIC: PROLONGED INHALATION OF EXCESSIVE DUST MAY CAUSE LUNG DAMAGE. IT IS ATTRIBUTED TO "LUNG OVERLOADING", A GENERIC RESPONSE TO EXCESSIVE AMOUNTS OF ANY DU ST RETAINED IN THE LUNGS FOR A PROLONGED INTERVAL. USE OF THIS PRODUCT, AS INTENDED, DOES NOT RESULT IN INHALATION OF EXCESSIVE DUST. Explanation Of Carcinogenicity: CARBON BLACK: IARC MONOGRAPHS, VOLUME 65, PAGE 149, 1998: GROUP 2B. ANIMAL: LUNG. Signs And Symptions Of Overexposure: SEE HLTH HAZS. TOX INFO: LEV TO POTNTL HUMAN EXPOS. CARCIN: IARC MONO/NTP(USA)/OSHA REG(USA): NOT LISTED. IN 1996 IARC REEVAL CARBON BLACK AS GROUP 2B CARCIN (POSS HUMAN CARCIN). THIS EVAL IS GIVEN TO CARBON BLACK FOR WHICH THER IS INADEQ HUMAN EVID, BUT SUFFICIENT ANIMAL EVID. THE LATTER IS BASED UPON DEVEL OF LUNG TUMORS IN RATS RECEIVING CHRONIC INHAL EXPOS TO FREE CARBON BLACK @ LEVS THAT INDU CE PARTICLE OVERLOAD OF LUNG. STUDIES PERFORMED IN ANIMAL MODELS OTHER THAN RATS HAVE NOT DEMONSTRATED ASSOC BETWEEN CARBON BLACK & LUNG TUMORS. MOREOVER, 2-YR CANCER BIOASSAY USING TYPICALTONER PREPA RATION CNTNG CARBON BLACK (OTHER INFO) First Aid: INHAL: IF SYMPTOMS ARE EXPERIENCED, REMOVE SOURCE OF CONTAMINATION/MOVE VICTIM TO FRESH AIR & OBTAIN MED ADVICE. SKIN: FLUSH W/GENTLY FLOWING WATER (PREFERABLY LUKEWARM) & SOAP FOR 15 MINUTES/UNTIL PA RTICLE IS REMOVED. IF IRRIT DOES OCCUR, OBTAIN MED ADVICE. EYES: DO NOT ALLOW VICTIM TO RUB EYE(S). FLUSH W/GENTLY FLOWING WATER (PREFERABLY LUKEWARM) FOR AT LEAST 15 MINUTES/UNTIL PARTICLE IS REMOVED . HAVE VICTIM LOOK RIGHT & LEFT, &, THEN UP & DOWN. IF IRRIT DOES OCCUR, OBTAIN MED ATTN. DO NOT ATTEMPT TO MANUALLY REMOVE ANYTHING STUCK TO EYE(S). INGEST: IF IRRIT/DISCOMFORT OCCURS, OBTAIN MED ATT N IMMED. NOTE TO MD/FURTHER INFO: NONE. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: PERSONAL PRECAUTIONS: NONE. ENVIRONMENTAL PRECAUTIONS: NONE. METHODS FOR CLEANING UP: WIPE OFF WITH PAPER OR CLOTH. DO NOT USE VACUUM CLEANER WHEN A LARGE AMOUNT IS RELEASED. IT, LIKE MOST FINELY DIVI DED ORGANIC POWDERS, MAY CREATE A DUST EXPLOSION. FURTHER INFORMATION: NONE. Waste Disposal Methods: WASTE MAY BE DISPOSED OR INCINERATED UNDER CONDITIONS WHICH MEET ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. CONTAMINATED PACKAGING: WASTE MAY BE DISPOSED OR INCINERATED UNDER CONDITIONS W HICH MEET ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. Handling And Storage Precautions: HANDLING: TECHNICAL MEASURES/PRECAUTIONS: NONE. TRY NOT TO DISPERSE THE PARTICLES. STORAGE: TECHNICAL MEASURES: NONE. STORAGE CONDITIONS: KEEP CONTAINER CLOSED. STORE IN A COOL AND DRY PLACE. INCOMPAT IBLE PRODUCTS: NONE. Other Precautions: PACKING MATERIALS: BOTTLES OR CARTRIDGE DESIGNATED BY MINOLTA. FURTHER INFORMATION: NONE. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: CARBON DIOXIDE, WATER SPRAY, FOAM AND DRY CHEMICAL. AVOID FULL WATER JET. Fire Fighting Procedures: NONE. WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: IF DISPERSED IN AIR, LIKE MOST FINELY DIVIDED ORGANIC POWDERS, MAY FORM AN EXPLOSIVE MIXTURE. ======================================================= Control Measures ======================================================= Respiratory Protection: NONE REQUIRED WHEN USED AS INTENDED IN MINOLTA EQUIPMENT. WEAR NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N). Ventilation: NONE REQUIRED WITH INTENDED USE. Other Protective Equipment: EYEWASH & DELUGE SHOWER MTG ANSI DESIGN CRITERIA (FP N). FOR USE OTHER THAN NORMAL CUSTOMER-OPERATING PROCEDURES (SUCH AS IN Work Hygienic Practices: WASH HANDS AFTER HANDLING. Supplemental Safety and Health: PHYS/CHEM PROPERTIES: PARTICLE SIZE (UM): 5-15 (TONER 40-75 (CARRIER); SOFTENING POINT (C): 95C-110C (203F-230F) (BASED ON DATA FOR OTHER MINOLTA PRODS W/SIMILAR INGS); EXPLO/OXIDIZING PROPERTIES: N/K ; DENSITY (G/CM3): ABOUT 5.0 (BULK DENSITY: 1.7 (BASED ON DATA FOR OTHER MINOLTA PRODS W/SIMILAR INGS); FLAMM: N/K. ======================================================= Physical/Chemical Properties ======================================================= Solubility in Water: NEGLIGIBLE Appearance and Odor: BLACKSOLID POWDER WITH FAINT ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: ELECTRONIC DISCHARGE, THROWING INTO FIRE. Materials To Avoid: OXIDIZING MATERIALS. HAZARDOUS REACTIONS: DUST EXPLOSION, LIKE MOST FINELY DIVIDED ORGANIC POWDERS. Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE. ======================================================= Toxicological Information ======================================================= Toxicological Information: ACUTE TOX: INHAL, LC50 (RATS): >5.02 G/M3/4H* (HIGHEST ATTAINABLE CONC). INGEST, LD50 (ORAL, RAT): >2.0 G/KG. DERMAL, LD50: NO DATA AVAIL. EYE IRRIT: MIN IRRIT (RABBITS). SKIN IRRIT: NOT AN IRRITANT ( RABBITS). SKIN SENSIT: NO SIGNS (GUINEA PIG)*. MUTAGENICITY: NEG (AMES TEST). IN A STUDY IN RATS BY CHRONIC INHAL EXPOS TO A TYPICAL TONER, A MILD TO MOD DEGREE OF LUNG FIBROSIS WAS OBSERVED IN 92% OF RATS IN HIGH CONC (16 MG/M3) EXPOS GROUP, & MIN TO MILD DEGREE OF FIBROSIS WAS NOTED IN 22% OF ANIMALS IN MIDDLE (4 MG/M3) EXPOS GROUP. BUT NO PULM CHANGE WAS REPORTED IN LOWEST (1 MG/M3) EXPOS GROUP , MOST RELEVANT (EFTS OF OVEREXP) ======================================================= Ecological Information ======================================================= Ecological: MOBILITY/PERSISTENCE/DEGRADABILITY/BIOACCUMULATION/ECOTOXICITY (BEHAVIOR IN SEWAGE WORKS/AQUATIC TOXICITY)/ECOLOGICAL (EC)/AOX-REMARK (EC)/BSB5 VALUE (EC): NO DATA ARE AVAIL ON ADVERSE EFTS OF THIS MA TL ON ENVIRON. SIGNIFICANT COMPONENTS (EC): N/A.-- EFTS OF OVEREXP: DEMONSTRATED NO ASSOC BETWEEN TONER EXPOS & TUMOR DEVEL IN RATS. (*=BASED ON DATA FOR OTHER MINOLTA PRODS W/SIMILAR INGS).--OTHER IN FO: INKS, CARBON BLACK & SOME NITRO CMPDS, LYON, PP. 149-261; H. MUHLE, B. BELLMAN, O. CREUTZENBERG, C. DASENBROCK, H. ERNST, R. KILPPER, J.C. MACKENZIE, P. MORROW, U. MOHR, S. TAKENAKA & R. MERMERLST EIN (1991) PULM RESPONSE TO (TRANS INFO) ======================================================= ======================================================= Transport Information: SPECIAL PREC: NONE. INFO ON CODE & CLASSIFICATION ACCORDING TO INTERNATIONAL REGS: UN CLASSIFICATION/LAND RID (EC), ADR (EC), DOT (USA)/INLAND WATERWAYS ADNR (RHINE R.)/SEA IMDG/AIR ICAO-TI, IATA-DGR: NONE.-- ECOLOGICAL INFO: TONER UPON CHRONIC INHAL EXPOS IN RATS. FUNDAMENTAL & APPLIED TOXICOLOGY 17, PP. 280-299. ======================================================= Regulatory Information ======================================================= Sara Title III Information: SARA (SUPERFUND AMENDMENTS & REAUTHORIZATION ACT) TITLE III: 302 EXTREME HAZARDOUS SUBSTANCES: NONE; 311/312 HAZARD CATEGORIES: NONE; 313 REPORTABLE INGREDIENTS: NONE. Federal Regulatory Information: US INFORMATION: INFORMATION ON THE LABEL: NOT REQUIRED. TSCA (TOXIC SUBSTANCES CONTROL ACT): ALL CHEMICAL SUBSTANCES IN THIS PRODUCT COMPLY WITH ALL APPLICABLE RULES OR ORDER UNDER TSCA. EU INFORMATIO N: SYMBOL AND INDICATION: NOT REQUIRED; R-PHRASE: NOT REQUIRED; S-PHRASE: NOT REQUIRED. 76/769/EEC: ALL CHEMICAL SUBSTANCES IN THIS PRODUCT COMPLY WITH ALL APPLICABLE RULES OR ORDER UNDER 76/769/EEC. State Regulatory Information: CALIFORNIA PROPOSITION 65: THIS PRODUCT CONTAINS NO CHEMICAL SUBSTANCES SUBJECT TO CALIFORNIA PROPOSITION 65. ======================================================= Other Information ======================================================= Other Information: NFPA HAZ RATING: NATL FIRE PROT AGENCY (USA): HLTH: 1; FLAMM: 1; REACTIVITY: 0. RATING: NATL PAINT & COATING ASSOC (USA): HLTH: 1; FLAMM: 1; REACTIVITY: 0. RECOM USES: STARTER FOR PHOTOCOPIER CF9 00, CF910, CF911P. LITERATURE REFS: ANSI Z400.1-1993.; TRGS 220: SICHERHEITSDATENBLATT FUR GEFAHRLICHE STOFFE UND ZUBEREITUNGEN; ISO 11014-1; COMMISSION DIRECTIVE 91/155/EEC; MATL SFTY DATA SHEET: A P RAC GUIDE TO FIRST AID: CANADIAN CENTRE FOR OCCUP HLTH & SFTY'S PUB; IMPLEMENTATION MANUAL: NATL PAINT & COATINGS ASSOC; IARC (1996): IARC MONO ON EVAL OF CARCIN RISK OF CHEMS TO HUMANS, VOL 65, PRINTING PROCESS & PRINTING(ECOL INFO) ======================================================= HAZCOM Label ======================================================= Product ID: CF STARTER K1, CF911P Cage: 23736 Company Name: MINOLTA CORPORATION Street: 101 WILLIAMS DRIVE Zipcode: 07446 Label Required IND: Y Date Of Label Review: 08/31/1999 Status Code: A Origination Code: F Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Slight Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: ACUTE: NO SYMPTOMS EXPECTED WITH INTENDED USE. CHRONIC: CANER HAZARD. CONTAINS MATERIAL LISTED AS AN ANIMAL LUNG CARCINOGEN (FP N). PROLONGED INHALATION OF EXCESSIVE DUST MAY CAUSE LUNG DAMAGE. IT IS ATTRIBUTED TO "LUNG OVERLOADING", A GENERIC RESPONSE TO EXCESSIVE AMOUNTS OF ANY DUST RETAINED IN THE LUNGS FOR A PROLONGEDINTERVAL. USE OF THIS PRODUCT, AS INTENDED, DOES NOT RESULT IN INHALATION OF EXCESSIVE DUST. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CO-211-3 ( PRODUCT CODE 032107-05) Preparer's Name:DELMAR BEIGHT CAGE:0FGH2 CAGE:0FGH2 Contract Num:SP0490-95-D-4037 CAGE:0VYG8 ============= Composition/Information on Ingredients ============= Ingred Name:COBALT CAS:7440-48-4 RTECS #:GF8750000 Minumum % Wt:20. Maxumum % Wt:50. OSHA PEL:0.1 MG/M3 ACGIH TLV:0.02 MG/M3 Ingred Name:NICKEL CAS:7440-02-0 RTECS #:QR5950000 Minumum % Wt:20. Maxumum % Wt:50. OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3 Ingred Name:CHROMIUM CAS:7440-47-3 RTECS #:GB4200000 Minumum % Wt:20. Maxumum % Wt:50. OSHA PEL:1 MG/M3 ACGIH TLV:0.5 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ALUMINIUM CAS:7429-90-5 RTECS #:BD0330000 Minumum % Wt:5. Maxumum % Wt:20. OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): UNKNOWN. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:REPEATED OVEREXPOSURE: MAY CAUSE SENSITIZATION IN SUSCEPTIBLE INDIVIDUALS. CHRONIC EXPOSURE TO THE EYE CAN CAUSE CORNEAL DAMAGE, POLYCYTHEMIA, HYPERPLASIA OF THE THYROID GLAND, & DAMAGE TO THE ALPHA CELLS OF THE PANCREAS. REPEATED INHALATION MAY CAUSE EMPHYSEMA OR PULMONARY FIBROTIC DISEASE. CHRONIC SKIN CONTACT MAY SPREAD TO THE WHOLE BODY WITH LESIONS, ITCHING, SORENESS, BURNING SENSATION & RED NESS. Explanation of Carcinogenicity:NICKEL IS LISTED AS A PROBABLE HUMAN CARCINOGEN. CHROMIUM IS LISTED AS A HUMAN CARCINOGEN. NICKEL & CHROMIUM HAVE BEEN DETERMINED TO CAUSE CANCER IN EXPERIMENTAL ANIMALS (IARC, NTP). Effects of Overexposure:SKIN-MAY CAUSE ALLERGIC DERMATITIS, WITH REDNESS & PAPULAR FORMATION IN SUSCEPTIBLE INDIVIDUALS, WHICH USUALLY OCCURS IN THE FOLDS OF THE SKIN. MAY CAUSE ULCERS PROGRESSING TO DRY & SCALY SKIN, FEVER . EYE-MAY CAUSE IRRITATION, EXPERIENCED AS REDNESS & EXCESS REDNESS OF THE CONJUNCTIVA. SWALLOWING-MAY CAUSE NAUSEA, ABDOMIAL PAIN, VOMITING, DIARRHEA, CNS DEPRESSION, & BURNING SENSATION. INHALATION- MAY CAUSE RESPIRATORY TRACT IRRITATION, WITH CHEST PAIN, VOMITING, DIARRHEA, BURNING SENSATION, & CNS DEPRESSION. MAY ALSO CAUSE INTERSTITIAL PNEUMONITIS & SENSITIZATION OF THE RESPIRATORY TRACT IN SU SCEPTIBLE INDIVIDUALS. Medical Cond Aggravated by Exposure:BREATHING OF DUST MAY AGGRAVATE ASTHMA AND INFLAMMATORY OR FIBROTIC PULMONARY DISEASE. MAY ALSO AGGRAVATE AN EXISTING DERMATITIS. ======================= First Aid Measures ======================= First Aid:SWALLOWING-GIVE AT LEAST 2 GLASSES OF MILK OR WATER. INDUCE VOMITING, UNLESS PATIENT IS UNCONSCIOUS. CALL A PHYSICIAN. SKIN-WASH THOROUGHLY WITH SOAP AND WATER. INHALATION-REMOVE TO FRESH AIR. GIVE AR TIFICIAL RESPIRATION IF NOT BREATHING. OXYGEN MAY BE GIVEN IF NECESSARY. CALL A PHYSICIAN. EYES-FLUSH THOROUGHLY WITH PLENTY OF WATER. IF DISCPMFORT PERSISTS, SEEK MEDICAL ATTENTION, PREFERABLY AN OPT HALMOLOGIST. ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:NONE Upper Limits:NONE Extinguishing Media:USE SPECIAL DRY POWDER METAL EXTINGUISHING MATERIAL TO EXTINGUISH METAL FIRES. USE APPROPRIATE EXTINGUISHER TO EXTINGUISH COMBUSTABLE MATERIALS THAT MAY BE IGNITED BY THERMAL FLAME. Fire Fighting Procedures:CONSULT AND COMPLY WITH ANSI Z49.1 SAFETY IN WELDING AND CUTTING, NFPA51B STANDARD FOR FIRE PREVENTION IN USE OF CUTTING AND WELDING PROCESSES. NFPA51 OXYGEN-FUEL GAS SYSTEMS FOR WELDING AND CUTTING, AND NFPA58 STANDARD FOR THE STORAGE AND HANDLING OF LIQUIFIED PETROLEUM GASES. Unusual Fire/Explosion Hazard:AIRBORNE DUST PARTICLES, ESPECIALLY METAL DUST, AND ACCUMULATION OF SUCH SHOULD BE TREATED AS EXPLOSIVES. TO MINIMIZE DANGER FROM DUST EXPLOSIONS, ADEQUATE VENTILATION SHOULD BE PROVIDED TO SPRAY BOOT H IN ACCORDANCE WITH AMERICAN WELDING SOCIETY PUBLICATION AWSC2.1-73, AND ACGIH PUBLICATION "INDUSTRIAL VENTILATION". ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT TO PROTECT AGAINST HAZARDS AND DISPOSE OF PER WASTE DISPOSAL METHOD. ======================Handling and Storage ====================== Other Precautions:CAUTION: WHEN THERMAL SPRAYING - ELECTRICITY CAN CAUSE FATAL SHOCK! DO NOT TOUCH LIVE ELECTRICAL PARTS! ARC RAYS CAN BURN EYES AND SKIN! WEAR RECOMMENDED EYE AND BODY PROTECTION. FUMES, GAS, & DUST CA N HARM YOUR HEALTH. PROVIDE ENOUGH VENTILATION AND WEAR RESPIRATORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:DEPENDS UPON SPECIFIC USE, CONDITION, AND LOCATION. IF THERE IS DUSTINESS, WEAR RESPIRATOR SELECTED PER OSHA 1910.134, AND OSHA 29 CFR 1910.252 AND ANSI Z49.1 Ventilation:LOCAL DUST PICK UP AND VENTILATION RECOMMENDED. Other Protective Equipment:SEE ANSI Z49.1, ANSI Z87.1, ANSI Z88.2 FOR Supplemental Safety and Health CAUTION: WHEN THERMAL SPRAYING-ELECTRICITY CAN CAUSE FATAL SHOCK! DO NOT TOUCH LIVE ELECTRICAL PARTS! ARC RAYS CAN BURN EYES AND SKIN! WEAR RECOMMENDED EYE ANDBODY PROTECTION. FUMES, GAS, AND DUST CAN HARM YOUR HEALTH. PROVIDE ENOUGH VENTILATION AND WEAR RESPIRATORS. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:NONE Vapor Density:N/VOLATILE Appearance and Odor:DUSTY DARK GRAY POWDER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN Stability Condition to Avoid:NONE KNOWN Hazardous Decomposition Products:WHEN THERMAL SPRAYING, DECOMPOSITION PRODUCTS WILL VARY WITH OPERATING CONDITIONS. REASONABLY EXPECTED. DECOMPOSITION PRODUCTS OF NORMAL OPERATION FROM THIS THERMAL SPRAY POWDER (OXIDES, SUB-OXIDES, ETC ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF WASTE PERS LOCAL, STAET, AND FEDERAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:PROPER SHIPPING NAME: METAL ALLOY POWDER NOI ITEM 136500 SUB 1. ===================== Regulatory Information ===================== SARA Title III Information:7440-48-4, COBALT, <50 PERCENT BY WEIGHT. 7440-02-0, NICKEL, <50 PERCENT BY WEIGHT . 7440-47-3, CHROMIUM, <50 PERCENT BY WEIGHT. Federal Regulatory Information:ALL INGREDIENTS IN THIS PRODUCT ARE LISTED IN THE T.S.C.A. INVENTORY. State Regulatory Information:PROP 65 (CARCINOGEN): WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER. CAS #7440-02-0, NICKEL; CAS #7440-47-3, CHROMIUM. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GAF ABSORBER 892-400 CAGE:03641 CAGE:24299 CAGE:03641 ============= Composition/Information on Ingredients ============= Ingred Name:CITRIC ACID (NO TLV; PERCENTAGE NOT GIVEN) RTECS #:GE7350000 ===================== Hazards Identification ===================== Effects of Overexposure:WHEN SOLUTION COLOR CHANGES TO BLUE, TOXIC AMMONIA FUMES MAY BE EMITTED. ======================= First Aid Measures ======================= First Aid:INGESTION MAY BE HARMFUL. AVOID EXCESSIVE SKIN & EYE CONTACT. FIRST AID: CALL A PHYSICIAN. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE MEDIA PROPER TO PRIMARY CAUSE OF FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP & DISPOSE OF WITH SOLID WASTE IN ACCORDANCE WITH ALL LOCAL, STATE, & FEDERAL REGULATIONS. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID SKIN & EYE CONTACT. ============= Exposure Controls/Personal Protection ============= Ventilation:MECHANICAL EXHAUST SATISFACTORY Supplemental Safety and Health MFG INDICATES PRODUCT CONTAINS NO HAZARDOUS INGREDIENT. ================== Physical/Chemical Properties ================== Spec Gravity:1.665 Appearance and Odor:WHITE, ODORLESS; GRANULAR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ETHANE Kit Part:=== Responsible Party === 780-471-4036 780-471-4036 CAGE:Company Name:MATHESON TRI-GAS, INC. 780-471-4036 CAGE: ============= Composition/Information on Ingredients ============= Ingred Name:ETHANE CAS:74-84-0 Fraction by Wt: 100.0% ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:No IARC:NoOSHA:No Health Hazards Acute and Chronic:INHALATION: SHORT TERM EXPOSURE: mild irritation, nausea, vomiting, dizziness, tingling sensation, suffocation, convulsions, coma LONG TERM EXPOSURE: no information on significant adverse effects SKIN CONTACT: SHORT TERM EXPOSURE: blisters, frostbite LONG TERM EXPOSURE: no information is available EYE CONTACT: SHORT TERM EXPOSURE: frostbite, blurred vision LONG TERM EXPOSURE: no information is available INGESTION: SHORT TERM EXPOSURE: frostbite LONG TERM EXPOSURE: no information is available Medical Cond Aggravated by Exposure: ======================= First Aid Measures ======================= First Aid: INHALATION: If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. SKIN CONTACT: If frostbite or freezing occur, immediately flush with plenty of lukewarm water (105-115 F; 41-46 C). DO NOT USE HOT WATER. If warm water is not available, gently wrap affected parts in blankets. Get immediate medical attention. EYE CONTACT: Contact with liquid: Immediately flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. INGESTION: If a large amount is swallowed, get medical attention. NOTE TO PHYSICIAN: For inhalation, consider oxygen. ===================== Fire Fighting Measures ===================== Flash Point:-211 F (-135 C) (CC) Autoignition Temp:882 F (472 C) Lower Limits:3.0% Upper Limits:12.5% Extinguishing Media:carbon dioxide, regular dry chemical Large fires: Flood with fine water spray. Fire Fighting Procedures:Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. For tank, rail car or tank truck: Stop leak if possible without personal risk. Let burn unless leak can be stopped immediately. For smaller tanks or cylinders, extinguish and isolate from other flammables. Evacuation radius: 800 meters (1/2 mile). Stop flow of gas. Unusual Fire/Explosion Hazard:Severe fire hazard. Severe explosion hazard. The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. Vapor/air mixtures are explosive. Electrostatic discharges may be generated by flow or agitation resulting in ignition or explosion. ================== Accidental Release Measures ================== Spill Release Procedures:Avoid heat, flames, sparks and other sources of ignition. Do not touch spilled material. Stop leak if possible without personal risk. Reduce vapors with water spray. Keep unnecessary people away, isolate hazard area and deny entry. Remove sources of ignition. Ventilate closed spaces before entering. Neutralizing Agent: ======================Handling and Storage ====================== Handling and Storage Precautions:Store and handle in accordance with all current regulations and standards. Grounding and bonding required. Subject to storage regulations: U.S. OSHA 29 CFR 1910.101. Keep separated from incompatible substances. Other Precautions: ============= Exposure Controls/Personal Protection ============= Respiratory Protection:Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with full facepiece and operated in a pressure-demand or other positive-pressure mode in combination with a separate escape supply. Any self-contained breathing apparatus with a full facepiece. Ventilation:Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits. Contact lenses should not be worn. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Other Protective Equipment:For the gas: Protective clothing is not required. For the liquid: Wear appropriate protective, cold insulating clothing. Supplemental Safety and Health ETHANE: ACGIH (simple asphyxiant) ================== Physical/Chemical Properties ================== Boiling Pt:-128 F (-89 C) Melt/Freeze Pt:-297 F (-183 C) Vapor Pres:28842 mmHg @ 21 C Vapor Density:1.05 Spec Gravity:Not applicable pH:Not applicable Evaporation Rate & Reference:>1 (butyl acetate=1) Solubility in Water:4.7% @ 20 C Appearance and Odor:PHYSICAL STATE:gas COLOR:colorless ODOR:sweet odor Corrosion Rate: ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:Stable at normal temperatures and pressure. Stability Condition to Avoid:Avoid heat, flames, sparks and other sources of ignition. Minimize contact with material. Containers may rupture or explode if exposed to heat. Hazardous Decomposition Products:Thermal decomposition products: oxides of carbon Thermal decomposition products: oxides of carbon Conditions to Avoid Polymerization:Will not polymerize. =================== Toxicological Information=================== Toxicological Information:ETHANE: ADDITIONAL DATA: Stimulants such as epinephrine may induce ventricular fibrillation. ===================== Ecological Information ===================== Ecological:FATE AND TRANSPORT: KOW: 933.25 (log = 2.97) (estimated from water solubility) KOC: 1862.09 (log = 3.27) (estimated from water solubility) HENRY'S LAW CONSTANT: 2.4 E -2 atm-m3/mol BIOCONCENTRATION: 1.43 (estimated from water solubility) AQUATIC PROCESSES: 1.4256224 hours (River Model: 1 m deep, 1 m/s flow, 3 m/s wind) ENVIRONMENTAL SUMMARY: Relatively non-persistent in the environment. Leaches through the soil or the sediment at a slow rate. Accumulates very little in the bodies of living organisms. Highly volatile from water. ==================== Disposal Considerations ==================== Waste Disposal Methods:Dispose in accordance with all applicable regulations. Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001. =================== MSDS Transport Information =================== Transport Information:U.S. DOT 49 CFR 172.101: PROPER SHIPPING NAME: Ethane ID NUMBER: UN1035 HAZARD CLASS OR DIVISION: 2.1 LABELING REQUIREMENTS: Flammable gas QUANTITY LIMITATIONS: PASSENGER AIRCRAFT OR RAILCAR: Forbidden CARGO AIRCRAFT ONLY: 150 kg ===================== Regulatory Information ===================== SARA Title III Information: SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.30): Not regulated. SARA TITLE III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.40): Not regulated.SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS CATEGORIES (40 CFR 370.21): ACUTE: Yes CHRONIC: No FIRE: Yes REACTIVE: No SUDDEN RELEASE: Yes SARA TITLE III SECTION 313 (40 CFR 372.65): Not regulated. Federal Regulatory Information:CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR 302.4): Not regulated. OSHA PROCESS SAFETY (29CFR1910.119): Not regulated. State Regulatory Information: California Proposition 65: Not regulated. ======================= Other Information =======================
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:FUEL OIL 6 BUNKER C CAGE:81355 CAGE:81355 ============= Composition/Information on Ingredients ============= Ingred Name:FUEL OIL, RESIDUAL CAS:68476-33-5 RTECS #:LS8960000 Fraction by Wt: >95% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SULFUR CAS:7704-34-9 RTECS #:WS4250000 Fraction by Wt: 1-5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:EFTS OF OVEREXP: EXHAUST AS PROBABLY CARCIN (GROUP 2A) & NIOSH REGARDS DIESEL EXHAUST AS "POTNTL OCCUP CARCIN." (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: WHILE EXCESS CANCER RISK FOR WORKERS EXPOSED TO DIESEL EXHAUST IS CURRENTLY UNKNOWN, EXPOSURE SHOULD BE (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: MINIMIZED TO REDUCE POTENTIAL RISK. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: AIR. IF BRTHG IS DFCLT, ADMIN OXYGEN. IF BRTHG HAS STOPPED GIVE ARTF RESP. KEEP PERSON WARM, (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: QUIET & GET MEDICAL ATTENTION. RTECS #:9999999ZZ Ingred Name:SPILL PROC: WEARING PROT EQUIP SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED. CONTAIN (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: SPILL TO SMALLEST AREA POSS. DIKE AREA TO PVNT SPREADING. PVNT FROM ENTERING DRAINS, SEWERS, STREAMS OR (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: OTHER BODIES OF WATER. RECOVER AS MUCH OF PROD AS POSS BY METHS SUCH AS VACUUMING & USE OF ABSORB. (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: TRANSFER CONTAMD ABSORB, SOIL & OTHER MATLS IN PROPER CNTNRS FOR ULTIMATE DISPOSAL. RTECS #:9999999ZZ APPROP PROT EQUIP ESSNTL FOR YOUR OPERATION. MINIMIZE (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:TRANSFER TO UNLABELED CNTNR. DO NOT USE CUTTING/WELDING TORCH ON THIS CNTNR (EVEN EMPTY). FOR INDUSTRIAL (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13: USE ONLY. BEFORE USE, REVIEW MSDS FOR MORE DETAILED INFO, INCL CHRONIC HLTH EFTS. 24-HR EMER # 800-ASHLAND. RTECS #:9999999ZZ Ingred Name:RESP PROT: SPECIFIED CONDITIONS (SEE INDUSTRIAL HYGIENIST). ENGINEERING/ADMINISTRATIVE CONTROLS SHOULD BE (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15: IMPLEMENTED TO REDUCE EXPOSURE. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:EYES: MAY CAUSE SEV IRRIT, REDNESS, TEARING, BLURRED VISION. SKIN: PRLNG/RPTD CNTCT MAY CAUSE MOD IRRIT, DEFAT, DERM. INHAL: EXCESS INHAL OF VAPS MAY CAUSE NASAL & RESP IRRIT, CNS EFTS INCL DIZZ, WEAK , FATG, NAUS, HDCH & POSS UNCON & EVEN ASPHY. INGEST: MAY CAUSE GI IRRIT, NAUS, VOMIT & DIARR. ASPIR (EFTS OF OVEREXP) Explanation of Carcinogenicity:FUEL OIL, RESIDUAL:IARC MONOGRAPHS ON THE EVALUATION OF CARCINOGENIC RISK OF CHEMS TO MAN, VOL 45, PG 239,1989:GROUP 2B. Effects of Overexposure:HLTH HAZ: OF MATL INTO LUNGS MAY CAUSE CHEM PNEUM WHICH MAY BE FATAL. CHRONIC: THIS PROD CONTAINS FUEL OIL #2. MATLS SIMILAR TO FUEL OIL #2 HAVE BEEN SHOWN TO PRDCE SKIN CANCER IN LAB ANIMALS FOLLOWIN G RPTD SKIN EXPOS W/OUT WASHING/REMOVAL. IF THIS FUEL IS BURNED IN DIESEL ENGINES: IARC CLASSIFIES WHOLE DIESEL (ING 3) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN: THORO WASH EXPOSED AREA W/SOAP & WATER. REMOVE CONTAMD CLTHG. LAUNDER CONTAMD CLTHG BEFORE REUSE. EYES: FLUSH W/LG AMTS OF WATER, LIFTING UPPER & LOWER LIDS OCCAS. GET MED ATTN. INGEST: DO NOT I NDUCE VOMIT. CALL MD/POIS CTL CTR IMMED. ASPIR HAZ IF SWALLOWED. CAN ENTER LUNGS & CAUSE DMG. NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERSON. INHAL: IF AFFECTED, REMOVE INDIVIDUAL TO FRESH (ING 6) ===================== Fire Fighting Measures ===================== Flash Point:180F,82C Extinguishing Media:REGULAR FOAM OR CARBON DIOXIDE OR DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. WATER/FOAM MAY CAUSE FROTHING WHICH CAN BE VIOLENT & POSS ENDANGER LIFE OF FIREFIGHTER, ESP IF (SUPDAT) Unusual Fire/Explosion Hazard:VAPS ARE HVR/AIR & MAY TRAVEL ALONG GROUND/ BE MOVED BY VENT & IGNITED BY HEAT, PILOT LIGHTS, OTHER FLAMES & IGNIT SOURCES AT LOCATIONS DISTANT FROM (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:SM SPILL: ELIM ALL SOURCES OF IGNIT SUCH AS FLARES, FLAMES (INCL PILOT LIGHTS) & ELEC SPKS. ABSORB LIQ ON VERMICULITE, FLOOR ABSORB/OTHER ABSORB MATL. LG SPILL: ELIM ALL IGNIT SOURCES (FLARES, FLAMES, INCL PILOT LIGHTS, ELEC SPKS). PERS NOT (ING 8) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT & OPEN FLAME. USE/STORE ONLY W/ADEQ VENT. MAINTAIN AMBIENT AIR CONC(S) OF VOLAT COMPONENT(S) BELOW PERMISSIBLE EMPOSURE LIMITS. Other Precautions:CNTNRS OF THIS MATL MAY BE HAZ WHEN EMPTIED. SINCE EMPTIED CNTNRS RETAIN PROD RESIDUES (VAP, LIQ &/OR SOLID) ALL HAZ PRECAUTIONS GIVEN IN MSDS MUST BE OBSERVED. COMBUST LIQ & VAP. AVOID CNTCT W/EYES & PRLNG/RPTD CNTCT W/SKIN. WEAR (ING 12) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF WORKPLACE EXPOS LIM(S) OF PROD OR ANY COMPONENT IS EXCEEDED, NIOSH/MSHA APPRVD AIR SUPPLIED RESP IS ADVISED IN ABSENCE OF PROPER ENVIRON CONTROL. OSHA REGS ALSO PERMIT OTHER NIOSH/MSHA APPRVD RESPS (NEGATIVE PRESS TYPE) UNDER (ING 15) Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL &/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S). Other Protective Equipment:TO PREVENT REPEATED OR PROLONGED SKIN CONTACT, WEAR IMPERVIOUS CLOTHING AND BOOTS. Work Hygienic Practices:MINIMIZE EXPOSURE THROUGH GOOD HYGIENIC PRACTICES. Supplemental Safety and Health FIRE FIGHT PROC: SPRAYED INTO CNTNRS OF HOT, BURNING LIQ. EXPLO HAZ: MATL HNDLG POINT. NEVER USE WELDING/CUTTING TORCH ON/NEAR DRUM (EVEN EMPTY) BECAUSE PROD (EVEN JUST RESIDUE) CAN IGNITE EXPLO. ALL 5 GAL PAILS & LARGER METAL CNTNRS INCL TANK CARS & TANK TRUCKS SHOULD BE GROUNDED &/OR BONDED WHEN MATL IS TRANSFERRED. ================== Physical/Chemical Properties ================== HCC:V4 Boiling Pt:B.P. Text:>400F,>204C Vapor Density:HVR/AIR Spec Gravity:1 @ 60F Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:OPAGUE BLACK LIQUID. Percent Volatiles by Volume:<1 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:MAY FORM TOXIC MATERIALS: CARBON DIOXIDE & CARBON MONOXIDE, VARIOUS HYDROCARBONS, SULFUR COMPOUNDS, ETC. ==================== Disposal Considerations ==================== Waste Disposal Methods:SMALL & LARGE SPILLS: DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SIMICHROME POLISH Preparer's Name:I.V. SOHNGEN CAGE:D8905 CAGE:D8905 ============= Composition/Information on Ingredients ============= Ingred Name:IRON OXIDE CAS:1309-37-1 RTECS #:NO7400000 Fraction by Wt: TRACE OSHA PEL:10 MG/M3 (FE) ACGIH TLV:5 MG/M3 FUME (FE) Ingred Name:GLYCINE CAS:56-40-6 RTECS #:MB7600000 Fraction by Wt: <1% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SOLVENT NAPHTHA, PETROLEUM, MEDIUM ALIPHATIC; (WHITE SPIRIT (WITHOUT TURPENTINE)) CAS:64742-88-7 RTECS #:WF3450000 Fraction by Wt: 11% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:KEROSENE CAS:8008-20-6 RTECS #:OA5500000 Fraction by Wt: 11% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:9-OCTADECENOIC ACID (Z)-, AMMONIUM SALT; (AMMONIUM OLEATE) CAS:544-60-5 RTECS #:RG3700000 Fraction by Wt: 13% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ALUMINUM OXIDE (SARA 313) CAS:1344-28-1 RTECS #:BD1200000 Fraction by Wt: 27% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:COCAMIDE DIETHANOLAMINE; (FATTY ACID DIETHANOLAMIDE) CAS:61791-31-9 Fraction by Wt: 1% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:IRRITANT; AT VERY HIGH LEVELS OF EXPOSURE THIS CAN CAUSE HEADACHE AND NAUSEA. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NOT APPLICABLE. ======================= First Aid Measures ======================= First Aid:INGEST: CALL MD IMMEDIATELY . INHAL: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE OXYGEN/ARTIFICIAL RESPIRATION) . EYES: IMMEDIATELY FLUSH W/POTABLE WATER FOR A MINIMUM OF 15 MINUTES, SEEK ASSISTANCE FROM MD . CALL MD. SKIN: WASH WELL WITH SOAP AND WATER. ===================== Fire Fighting Measures ===================== Flash Point:NOT FLAMMABLE Extinguishing Media:ANY MEDIUM SUITABLE FOR EXTINGUISHING THE SUPPORTING FIRE. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:NOT APPLICABLE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:PROTECT AGAINST PHYSICAL DAMAGE. STORE IN COOL, DRY, WELL VENTILATED AREA. Other Precautions:NONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT APPLICABLE. USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NOT APPLICABLE. Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . Work Hygienic Practices:NOT APPLICABLE. Supplemental Safety and Health PH: 9.5 (1% DISPERSED IN WATER). ================== Physical/Chemical Properties ================== Spec Gravity:1.150 (H*2O=1) pH:SUPDAT Solubility in Water:DISPERSABLE Appearance and Odor:PINK PASTE; SLIGHTLY TO AMMONIA. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:UNKNOWN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS . COVER SPILL WITH VERMICULITE OR SAND MIX AND SHOVEL INTO CONTAINERS FOR DISPOSAL IN LANDFILL PERMITTED TO ACCEPT LISTED COMPONENTS.
1
eyes_protection_mandatory
======================================================= Product ID: 116DA PERMATEX SILICONE SPRAY LUBRICANT Cage: 08028 ======================================================= Preparer Co. when other than Responsible Party Co. ======================================================= Cage: 08028 ======================================================= Contractor Summary ======================================================= Cage: 08028 ======================================================= Ingredients ======================================================= Cas: 8052-41-3 RTECS #: WJ8925000 % Wt: 15-20 Other REC Limits: 350 MG/CUM OSHA PEL: 500 PPM ACGIH TLV: 100 PPM; 9293 ------------------------------ Cas: 74-98-6 RTECS #: TX2275000 % Wt: <30 Other REC Limits: 1800 MG/CUM OSHA PEL: 1000 PPM ACGIH TLV: 1000 PPM ------------------------------ Cas: 75-28-5 RTECS #: TZ4300000 % Wt: <30 Other REC Limits: 1000 PPM OSHA PEL: 1000 PPM ACGIH TLV: 1000 PPM ------------------------------ Cas: 7732-18-5 RTECS #: ZC0110000 % Wt: 50-55 ------------------------------ % Wt: <5 ----------------------------- % Wt: <1 ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: YES Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: MAY CAUSE SKIN & UPPER RESPIRATORY TRACT IRRITATION. Explanation Of Carcinogenicity: NONE Signs And Symptions Of Overexposure: INHALATION: HEADACHE, NAUSEA, DIZZINESS, & ANESTHETIC EFFECTS. First Aid: INGESTION: DON'T INDUCE VOMITING. INHALATION: REMOVE TO FRESH AIR. SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/WATER FOR AT LEAST 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: REMOVE ALL IGNITION SOURCES. VENTILATE AREA WELL. REMOVE RESIDUE W/INERT ABSORBENT. Waste Disposal Methods: DON'T INCINERATE. DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS. UN1950. Handling And Storage Precautions: DON'T STORE ABOVE 120F. DON'T EXPOSE TO DIRECT SUNLIGHT. DON'T PUNCTURE. DON'T SPRAY NEAR FIRE OR OPEN FLAME. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: TOC Flash Point Text: <0F PROPELLANT Extinguishing Media: CO2, FOAM, DRY CHEMICAL Unusual Fire/Explosion Hazard: EXPOSURE TO HEAT MAY CAUSE BURSTING. ======================================================= Control Measures ======================================================= Ventilation: SUFFICIENT TO MAINTAIN VAPOR CONCENTRATION BELOW TLV Supplemental Safety and Health: PROPANE/ISOBUTANE PRESSURE AT ROOM TEMPERATURE: 52 PSIG. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: <0F (PROP.) Vapor Pres: SEE SUPP. Vapor Density: >1 Solubility in Water: COMPLETE Appearance and Odor: CLEAR LIQUID SPRAY, ODORLESS ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: OPEN FLAME, HEAT, TEMP >120F, DIRECT SUNLIGHT Hazardous Decomposition Products: OXIDES OF CARBON Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: 116DA PERMATEX SILICONE SPRAY LUBRICANT Cage: 08028 Company Name: LOCTITE CORP AUTOMOTIVE AND CONSUMER GROUP Street: 4450 CRANWOOD COURT Zipcode: 44128-4004 Label Required IND: Y Date Of Label Review: 08/05/1993 Status Code: C Label Date: 08/05/1993 Origination Code: F Skin Protection IND: YES Signal Word: DANGER Health Hazard: Slight Contact Hazard: Slight Fire Hazard: Severe Reactivity Hazard: Slight Hazard And Precautions: MAY CAUSE SKIN & UPPER RESPIRATORY TRACT IRRITATION. DIGESTIVE TRACTS, LIVER. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:LEADED BRONZE CAGE:11045 CAGE:11045 ============= Composition/Information on Ingredients ============= Ingred Name:COPPER (SARA III) CAS:7440-50-8 RTECS #:GL5325000 Fraction by Wt: 70-99% OSHA PEL:0.1MG/M3 FUME/1 DUST ACGIH TLV:0.2MG/M3 FUME; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:NICKEL (SARA III) CAS:7440-02-0 RTECS #:QR5950000 Fraction by Wt: 0-14% OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3; 9192 Ingred Name:ALUMINUM (SARA III) CAS:7429-90-5 RTECS #:BD0330000 Fraction by Wt: 0-14% OSHA PEL:15MG/M3 DUST/5 FUME ACGIH TLV:10MG/M3 DUST; 9192 Ingred Name:IRON (PEL/TLV GIVE AS IRON OXIDE) CAS:7439-89-6 RTECS #:NO4565500 Fraction by Wt: < 5% OSHA PEL:10 MG/M3 (MFR) ACGIH TLV:5 MG/M3 Ingred Name:SILICON CAS:7440-21-3 RTECS #:VW0400000 Fraction by Wt: < 4% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:MANGANESE (SARA III) CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: < 4% OSHA PEL:(C) 5 MG/M3 DUST ACGIH TLV:5 MG/M3 DUST 9293 Ingred Name:COBALT (SARA III) CAS:7440-48-4 RTECS #:GF8750000 Fraction by Wt: < 2% OSHA PEL:0.1 MG/M3;AS CO ACGIH TLV:0.05 MG/M3;DUST 9293 Ingred Name:TIN CAS:7440-31-5 RTECS #:XP7320000 Fraction by Wt: < 1% OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3; 9192 Ingred Name:ZINC OXIDE CAS:1314-13-2 RTECS #:ZH4810000 Fraction by Wt: < 1% OSHA PEL:15MG/M3 TDUST/5 FUME ACGIH TLV:10MG/M3 TDUST; 9293 Ingred Name:LEAD (SARA III) CAS:7439-92-1 RTECS #:OF7525000 Fraction by Wt: < 1% OSHA PEL:0.05 MG/M3;1910.1025 ACGIH TLV:0.15 MG/M3;DUST 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE EXPOSURE TO FUMES/DUST MAY PRODUCE IRRIT OF EYES & RESP SYS. INHAL OF HIGH CONC OF FRESHLY FORMED OXIDE FUMES OF COPPER AND LEAD MAY CAUSE METAL FUME FEVER CHARACTERIZED BY A METALLIC TASTE IN M OUTH, DRYNESS OF THE THROAT AND INFLUENZALIKE SYMPTOMS. INHAL OR INGEST OF LEAD PARTICLES MAY (SEE EFTS OR OVEREXP) Explanation of Carcinogenicity:NICKEL: GROUP 1 (IARC), GROUP 2 (NTP) Effects of Overexposure:HLTH HAZ: RESULT IN LEAD-INDUCED SYSTEMIC TOXICITY. SYMP OF LEAD POISONING INCLUDE ABDOMINAL CRAMPS, ANEMIA, MUSCLE WEAKNESS & HDCH. PRLNGD EXPOSURE CAN CAUSE BEHAVIORAL CHANGES, KIDEY DAMAGE, CNS DAM AGE & REPRODUCTIVE EFFECTS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:IF EXPOSED TO EXCESSIVE LEVELS OF METAL FUMES, REMOVE TO FRESH AIR, SEEK MEDICAL AID IMMEDIATELY. EYES: FLUSH WITH WATER FOR AT LEAST 15 MIN. SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER. CALL MD . INHAL: REMOVE TO FRESH AIR. SUPPORT BREATHING. (GIVE O2/ARTF RESP). INGEST: GET MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Extinguishing Media:NOT APPLICABLE. EXTINGUISHING MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:PRODUCTS IN THE SOLID STATE PRESENT NO FIRE OR EXPLOSION HAZARD. WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:DUST HAZARDS EXIST UNDER FAVORING CONDITIONS OF SMALL PARTICLE SIZE. DISPERSION IN AIR AND STRONG IGNITION SOURCES MAY RESULT IN AN EXPLOSION. ================== Accidental Release Measures ================== Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:IN WELDING, PRECAUTIONS SHOULD BE TAKEN FOR AIRBORNE CONTAMINANTS WHICH MAY ORIGINATE FROM COMPONENTS OF THE WELDING ROD. Other Precautions:ARC OR SPARK GENERATED WHEN WELDING OR BURNING COULD BE A SOURCE OF IGNITION FOR COMBUSTIBLE AND FLAMMABLE MATERIALS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED DUST AND FUME, RESPIRATOR SHOULD BE USED TO AVOID EXCESSIVE INHAL OF PARTICULATES WHEN EXPOSURE EXCEEDS TLV'S. Ventilation:LOC EXHST VENT SHOULD BE UTILIZED WHEN WELDING, BURNING, SAWING, BRAZING, GRINDING/MACHINING WHEN EXPOS EXCEEDS TLV'S. Other Protective Equipment:OTHER PROTECTIVE EQUIPMENT SHOULD BE UTILIZED AS REQUIRED BY THE WELDING STANDARDS. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health HAZ DECOMP PROD: CONTACTING MATERIALS ARE INVOLVED. ================== Physical/Chemical Properties ================== HCC:N1 Melt/Freeze Pt:M.P/F.P Text:>1700F Spec Gravity:> 7 Appearance and Odor:SOLID, RED-GOLD METALLIC, ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MERCURY, AMMONIA, ACETYLENE. Stability Condition to Avoid:EXPOSURE DURING STORAGE TO STRONG ACIDS, BASES OR OXIDIZING AGENTS. Hazardous Decomposition Products:TOX GASES, AEROSOLS & VAPS MAY BE RELEASED IN A FIRE INVOLVING COPPER ALLOYS IF FUME OF OTHER CMPNDS/OTHER (SUPP DATA) ==================== Disposal Considerations ==================== Waste Disposal Methods:ACCORDING TO LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:5130 NOX-ICE Preparer's Name:R. W. KLUG CAGE:FO778 CAGE:FO778 CAGE:0WT79 ============= Composition/Information on Ingredients ============= Ingred Name:ISOPROPANOL (ISOPROPYL ALCOHOL), 2-PROPANOL, DIMETHYL CARBINOL CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 100% Other REC Limits:400 PPM OSHA PEL:400 PPM ACGIH TLV:400 PPM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE: IRRITATION/BURNING SENSATION/TEARING/REDNESS/SWELLING/PAIN. SKIN: REDNESS. INGESTION: GASTRO-INTESTINAL IRRITATION. INHALATION: MUCOUS MEMBRANE IRRITATION/INTOXICATION/COUGHING/SHORTNESS OF BREAT H/DIZZINESS. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYE: IRRITATION/BURNING SENSATION/TEARING/REDNESS/SWELLING/PAIN. SKIN: REDNESS. INGESTION: GASTRO-INTESTINAL IRRITATION. INHALATION: MUCOUS MEMBRANE IRRITATION/INTOXICATION/COUGHING/SHORTNESS OF BREAT H/DIZZINESS. Medical Cond Aggravated by Exposure:EYE & RESPIRATORY DISORDERS ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/CLEAN WATER FOR 20-30 MINS. IF PAIN, BLINKING, TEARS, OR REDNESS CONTINUE, CONTACT OPHTHALMOLOGIST. SKIN: WASH W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. RESTORE NORMAL BREATHING.INGESTION: IF CONSCIOUS, GIVE 1 PINT LUKEWARM WATER. DON'T INDUCE VOMITING. RISK OF ASPIRATION INTO LUNGS EXCEEDS THAT OF SYSTEMIC POISONING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:53F Lower Limits:2% Upper Limits:12% Extinguishing Media:DRY CHEMICAL, CO2, ALCOHOL-TYPE FOAM Fire Fighting Procedures:WATER SPRAY MAY BE INEFFECTIVE, BUT MAY BE USED TO COOL FIRE-EXPOSED SURFACES. WEAR RESPIRATORY PROTECTION. Unusual Fire/Explosion Hazard:VAPORS ARE >AIR/TRAVEL TO IGNITION SOURCE/FLASHBACK. WHEN MIXED W/AIR/EXPOSED TO IGNITION SOURCE/CONFINED AREA VAPORS BURN/EXPLODE/BUILD-UP PRESSURE. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. VENTILATE & EVACUATE AREA. WEAR PROTECTIVE EQUIPMENT. CONTAIN & COLLECT PRODUCT W/INERT ABSORBENT. PLACE IN CLOSED CONTAINERS W/NON-SPARKING TOOLS. PREVENT PRODUCT FROM ENTERING WATER SUPPLY. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTACT W/SKIN & EYES. AVOID INHALATION OF VAPORS. KEEP CONTAINERS CLOSED DURING STORAGE. STORE AWAY FROM IGNITION SOURCES. Other Precautions:EMPTY CONTAINERS MAY RETAIN PRODUCT RESIDUES WHICH MAY BE CONSIDERED HAZARDOUS. FOLLOW ALL PRECAUTIONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE AIR-SUPPLIED MASK IN CONFINED AREA OR IN EMERGENCY SITUATIONS. Ventilation:SUFFICIENT MECHANICAL TO KEEP <TLV Other Protective Equipment:FACE SHIELD, EYE WASH STATIONS, & SAFETY SHOWER Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health BOILING RANGE: 180-200F. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:SEE SUPP Vapor Pres: 33 Vapor Density: 2 Spec Gravity:0.7864 Solubility in Water:100% Appearance and Odor:CLEAR, COLORLESS LIQUID W/ALCOHOL ODOR. Percent Volatiles by Volume:100% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, OPEN FLAMES, & OTHER SOURCES OF IGNITION Hazardous Decomposition Products:CO ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FREON 116/NITROUS OXIDE CAGE:19898 CAGE:18873 CAGE:19898 ============= Composition/Information on Ingredients ============= Ingred Name:HEXAFLUOROETHANE (FREON 116),CAS#76-16-4 RTECS #:KI4110000 Fraction by Wt: 90.0% Ingred Name:NITROUS OXIDE CAS:10024-97-2 RTECS #:QX1350000 Fraction by Wt: 10.0% ACGIH TLV:50 PPM; 9192 ===================== Hazards Identification ===================== Effects of Overexposure:EYES:FROSTBITE;SKIN:FROSTBITE;INHAL:LIGHT HEADEDNESS,GIDDINESS,SHORTNESS OF BREATH;NARCOSIS OR DEATH ======================= First Aid Measures ======================= First Aid:INHALE:REMOVE TO FRESH AIR, GIVE CPR/O*2 IF NEED;EYES/SKIN:FLUSH W LG AMTS H*2O FOR 15 MIN;INGEST:RINSE MOUTH; GET MEDICAL ATTENTION FOR EYES, BREATHING DIFFICULTY, OR OTHER SYMPTOMS OF OVEREXPOSURE. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:NON-FLAMMABLE;USE SUITABLE MEDIA FOR SURROUNDING FIRES. Fire Fighting Procedures:USE NIOSH/MSHA APROVED SCBA IF CYLINDER REPTURE OR RELEASE G Unusual Fire/Explosion Hazard:DECOMPOSITION MAY OCCUR ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTION;VENTILATE AREA,ESPECIALLY LOW PLACES WHERE HEAVY VAPORS MIGHT COLLECT.REMOVE FLAMES. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE CONTAINERS IN A CLEAN,DRY AREA.DO NOT HEAT ABOVE 125F. Other Precautions:AVOID CONTACT WITH EYES AND SKIN.DO NOT BREATHE VAPORS. ============= Exposure Controls/Personal Protection ============= Ventilation:PROVIDE MECHAN(GEN/LOCAL EXHAUST)VENT TO MAINTN <TLV Other Protective Equipment:FULL WORK CLOTHING TO PREVENT REPEATED OR PROLONGED CONTACT. Supplemental Safety and Health MSDS DATED:11/85 ================== Physical/Chemical Properties ================== HCC:G3 Boiling Pt:B.P. Text:-129F Vapor Pres:431 Vapor Density:4.5 Spec Gravity:1.54 Appearance and Odor:CLEAR,COLORLESS,SLIGHT ETHEREAL ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKAL,ALKALINEEARTH METALS,POWDER AL,ZN,BE,ETC.OILS OR R.AGN Stability Condition to Avoid:HIGH TEMP,OPEN FLAME Hazardous Decomposition Products:DECOMPOSES:HF ACID OR POSSIBLE CARBONYL FLUORIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:COMPLY WITH ALL FEDERAL,STATE & LOCAL REGULATIONS;RECLAIM BY DISTILLATION OR REMOVE TO A PERMITTED WASTE DISPOSAL FACILITY.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FA9973 CAGE:JO764 CAGE:81831 CAGE:JO764 ============= Composition/Information on Ingredients ============= Ingred Name:POLYCHLORINATED BIPHENYLS (PCBS) (SARA III) CAS:1336-36-3 RTECS #:TQ1350000 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Effects of Overexposure:ABSORBED THRU SKIN,LUNGS,INTESTINE.CAUSES CANCER,LIVER,KIDNEY,STOMACH,EYE,HEARING DISORDER(SUP DATA) ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/WATER IMMEDIATELY.SKIN:WASH W/SOAP IMMEDIATELY.INHAL:REMOVE TO FRESH AIR,GIVE ART.RESPIR.AS NEEDED.INGEST:GET MEDICAL ATTN.GIVE LARGE QTY OF SALT WATER,INDUCE VOMITING,BUT DO NOT MAKE UNC ONSCIOUS PERSON VOMIT. ================== Accidental Release Measures ================== Spill Release Procedures:USE ABSORBENT & DIKES TO PREVENT RUNOFF.ISOLATE & NOTIFY PROPER AUTHORITIES. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE MUST FOLLOW RCRA REQUIREMENTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SUPPLIED AIR W/FULL FACEPIECE,HELMET OR HOOD Ventilation:LOCAL EXHAUST Other Protective Equipment:FULL CLOTHING TO PREVENT SKIN CONTACT Supplemental Safety and Health OVEREXPOS:CAN CAUSE FORMATION OF CYSTS,CAUSES STILLBIRTHS.IRRITATES EYES,NOSE THROAT. ================== Physical/Chemical Properties ================== HCC:Z3 Appearance and Odor:LIGHT STRAW-COLORED LIQUID,AROMATIC ODOR ================= Stability and Reactivity Data ================= STRONG OXIDIZERS ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-GENERALLY HIGH TEMPERATURE INCINERATION.ONLY APPROVED DISPOSAL OPERATOR PERMITTED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ENAMEL ALKYD GLOSS BLUE 15123 ID742518 Preparer's Name:W.A. ELLISON CAGE:FO127 CAGE:FO127 CAGE:61196 ============= Composition/Information on Ingredients ============= Ingred Name:VM&P NAPHTHA (LIGROINE) CAS:8032-32-4 RTECS #:OI6180000 OSHA PEL:300 PPM/400 STEL ACGIH TLV:300 PPM; 9192 Ingred Name:MINERAL SPIRITS (VAPOR PRESSURE 2 MMHG @ 20C) CAS:64475-85-0 RTECS #:PY8240000 OSHA PEL:500 PPM 2950 MG/CU.M ACGIH TLV:100 PPM 525 MG/CU.M. Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:VOC. ORGANIC CMPD 3.9 LB/GAL LESS WATER & NPRS* 468 G/L LESS WATER VOC. 9.8 LB/GAL SOLIDS 1176 G/L SOLIDS CALCU RTECS #:9999999VO ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:ASPIRATION OF MATL INTO LUNG MAY CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. HIGH CONCENT. MAY CAUSE ACUTE CNTRL NERVOUS SYS. DEPRESS. PROLONGED/REPEATED OVEREXPOSURE TO SOLVENTS W/PERMANENT BRA IN & NERVOUS SYSTEM DAMAGE. INTENTIONALMISUSE CAN BE HARMFUL OR FATAL. Effects of Overexposure:EYE: MAY CAUSE IRRITATION. SKIN: MAY CAUSE IRRITATION & DEFATTING OF SKIN INHAL: NOSE/THROAT IRRITATION, HEADACHES , DIZZINESS, NAUSEA & CONFUSIONINGST: GASTROINTESTINAL IRRITATION, NAUSEA, AND VOMITING. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH W/LG AMNTS OF WTR,LIFTING EYELIDS,FOR 15 MINS.,GET MEDICAL ATTENTION.SKIN: WASH AFFECTED AREA W/SOAP & WTR,REMOVE CONTAMINATED CLOTHES,GET MED. ATTN INHAL: REMOVE TO FRESH AIR IMMEDIATELY,G IVE ARTIFICIAL RESP. IF NEEDED,GET MED.ATTENTION IMMEDIATELY INGST: DO NOT INDUCE VOMITING, CALL A PHYSICIA OR HOSPITAL IMMEDIATELY ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:<102F/38.89C Extinguishing Media:NFPA CLASS B FIRE EXTINGUISHER. POLYMER FOAM IS PREFERREDFOR LARGE FIRES. Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS. USE WATER TO COOL EXPOSED CONTAINERS TOPREVENT PRESSURE BUILD-UP AND POSSIBLE EXPLOSION. FOG NOZZLE PREFERRED W/WATER. Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT,ELEC. EQUIP.,SPARKS, & FLAME. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. DIKE & CONTAIN SPILL W/INER MATL. USE ONLY NON SPARKING TOOLS. PLACE ABSORBENT DIKING MATL IN COVERED METAL CONTAINERS FOR DISPOSAL. PREVENT CONTAMINATION OF SEWER STREAMS, GROUNDWTR W/SPILLED MATL OR USED ABSORBNT ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STOFE ABOVE 95F. STORE LG QTYS IN COMPLIANCW/OSHA 29CFR1910.106. CLOSE CONTAINER AFTER EACH USE. NEVER USE PRESSURE TO EMPTY CONTAINERS. Other Precautions:DO NOT TAKE INTERNALLY. DO NOT BREATH SANDING DUST. EMPTY CONTAINERS MUST NOT BEWASH AND RE-USED FOR ANY PUPOSE. DO NOT WELD, BRAZE, OR CUT ON EMPTY CONTAINERS.CONTAINERS SHOULD BE GROUNDED & BONDED T O THE RECEIVING CONTAINER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN RESTRICTED AREAS USE A NIOSH APPROVED CHEMICAL CARTRIDGE RESPIRATOR. FOR SPRAYING USE A MECHANICAL PREFILTER. CONFINED AREAS USE A NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR. Ventilation:PROVIDE GENERAL DILUTION AND LOCAL EXHAUST Other Protective Equipment:NOT LIKELY TO BE NEEDED Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:280F-388F Vapor Density:>AIR Evaporation Rate & Reference:SLOWER THEN ETHER Percent Volatiles by Volume:59 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS OR ALKALINE MATERIALS Stability Condition to Avoid:AVOID EXCESSIVE HEAT AND SOURCES OF IGNITION. Hazardous Decomposition Products:BURNING,INCLUDING WHEN HEATED BY WELDING OR CUTTING, WILL PRODUCE SMOKE, CARBON MONOXIDE/DIOXIDE. Conditions to Avoid Polymerization:KEEP AWAY FROM HEAT SPARK OR FLAME ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS. DO NOT INCINERATE CLOSED CONTAIENRS. INCINERATE ONLY IN EPA PERMITTED FACILITY. CONTAMINATED ABSORBANT MAY BE DISPOSED IN A HAZARDOUS WASTE LANDFILL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TONER FOR LZR 650 PRINTER, ST9500, 6100 CAGE:ARLIN CAGE:ARLIN ============= Composition/Information on Ingredients ============= Ingred Name:STYRENE ACRYLATE CAS:67953-61-1 Fraction by Wt: 63.5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:PROPENE POLYMERS; (POLYPROPYLENE) CAS:9003-07-4 RTECS #:UD1842000 Fraction by Wt: 3.5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:MAGNETITE CAS:1309-38-2 RTECS #:OM4800000 Fraction by Wt: 32% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:METAL COMPLEX OF AZO COMPOUND Fraction by Wt: 1% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MINIMAL IRRITATION TO RESPIRATORY TRACT MAY OCCUR AS WITH EXPOSURE TO ANY NON-TOXIC DUST. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:ACCUMULATION OF DUST IN THE RESPIRATORY SYSTEM. ======================= First Aid Measures ======================= First Aid:SKIN: FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . INGESTION: RINSE MOUTH WITH WATER. CALL MD. INHALATION: REMOVE TO FRESH AIR. IF EFFECTS OCCUR, CONSULT LOCAL MEDICAL PERSONNEL. EYES: IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. ===================== Fire Fighting Measures ===================== Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM OR WATER. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP OR CLEAN UP WITH A VACUUM CLEANER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED UNDER NORMAL USE. USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NONE REQUIRED UNDER NORMAL USE. Other Protective Equipment:NONE REQUIRED UNDER NORMAL USE. Work Hygienic Practices:INHALATION SHOULD BE AVOIDED. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:1.47 Solubility in Water:NEGLIGIBLE Appearance and Odor:FINE, BLACK POWDER; PRACTICALLY ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, NOX. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE MATERIAL MAY BE DUMPED OR INCINERATED UNDER CONDITIONS WHICH MEET ALL REGULATIONS. COMPLY WITH ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ALL BOND 2 PRIMER B Kit Part:Y CAGE:0WNJ1 CAGE:0WNJ1 ============= Composition/Information on Ingredients ============= Ingred Name:ACETONE (SARA 313) (CERCLA) CAS:67-64-1 RTECS #:AL3150000 OSHA PEL:1000 PPM ACGIH TLV:750 PPM; 1000 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:BPDM BIPHENYL DIMETHACRYLATE OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAINLY THOSE OF ACETONE INHALATION: HEADACHE, FATIGUE, EXCITEMENT, BRONCHIAL IRRITATION. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL: AVOID FURTHER CONTACT, INHALE FRESH AIR & SEE MD. SKIN: WASH CONTACTED SKIN WITH WATER FOR SEVERAL MINUTES. EYES: FLUSH W/POTABLE WATER FOR AT LEAST 15 MINUTES. CALL MD. INGEST: CALL MD I MMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:0F,-18C Extinguishing Media:WATER, CARBON DIOXIDE. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:DOUSE WITH COPIOUS QUANTITIES OF COLD WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT & FLAMES. Other Precautions:AVOID INHALATION, INGESTION OR CONTACT WITH SKIN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPRVD RESPIRATOR EFFECTIVE WITH ACETONE. Ventilation:USE LOCAL EXHAUST. Other Protective Equipment:PROTECT ALL SKIN SURFACES. Work Hygienic Practices:NORMAL SAFE PRACTICES. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:131F,55C Spec Gravity:< (H*2O=1) Solubility in Water:SOLUBLE Appearance and Odor:COLORLESS LIQUID WITH CHARACTERISTIC ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT POUR INTO SEWER, BUT FOLLOW PERTINENT LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DM DYKEM STAINING GREEN CAGE:EO153 CAGE:EO153 CAGE:98148 ============= Composition/Information on Ingredients ============= Ingred Name:N-BUTYL ACETATE (SARA III) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 30-40% OSHA PEL:150 PPM/200 STEL ACGIH TLV:150 PPM/200STEL;9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHYL ALCOHOL (ETHANOL) CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: 50-60% OSHA PEL:1000 PPM ACGIH TLV:1000 PPM; 9192 Ingred Name:N-BUTYL ALCOHOL (SARA III) CAS:71-36-3 RTECS #:EO1400000 Fraction by Wt: 3-6% OSHA PEL:100 PPM ACGIH TLV:S, C 50 PPM; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:BRILLANNT GREEN CAS:633-04-4 Fraction by Wt: 1-3% Ingred Name:CELLULOSE NITRATE (PROPORTIONAL 70/30 WITH ISOPROPANOL) CAS:9004-70-0 RTECS #:QW0970000 Fraction by Wt: 2.1-4.2% Ingred Name:ISOPROPYL ALCOHOL (SARA III) CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 0.9-1.8% OSHA PEL:400 PPM/500 STEL ACGIH TLV:400 PPM/500STEL;9192 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PRODUCT IS IRRITATING TO BODY TISSUES. PROLONGED/REPEATED SKIN CONTACT MAY CAUSE DERMATITIS. INHALATION MAY PRODUCE CENTRAL NERVOUS SYSTEM EFFECTS. NO INFORMATION WAS READILY AVAILABLE ON CHRONIC EFFE CTS. Effects of Overexposure:EYE:IRRITATION,BURNING. SKIN;DRYING,DERMATITIS WITH PROLONGED/REPEATED CONTACT. INHALED:RESPIRATORY IRRITATION,DIZZINESS,HEADACHE,NAUSEA. INGESTED:G/I IRRITATION ,NAUSEA. Medical Cond Aggravated by Exposure:NONE REPORTED ======================= First Aid Measures ======================= First Aid:EYE:FLUSH WITH WATER 15 MIN. SKIN:REMOVE CONTAMINATED CLOTHING. WASH AREA WITH SOAP AND WATER. LAUNDER CLOTHING BEFORE REUSE. INHALED:REMOVE FROM EXPOSURE. GIVE ARTIFICIAL RESPIRATION OR OXYGEN IF NEE DED. INGESTED:DO NOT INDUCE VOMITING. GIVE WATER OR MILK. (NOTHING BY MOUTH IF UNCONSCIOUS) GET IMMEDIATE MEDICAL CARE. IF SYMPTOMS PERSISTS OR ARE SEVERE,GET MEDICAL CARE. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:37F/14C Lower Limits:1.4 Upper Limits:11.2 Extinguishing Media:CARBON DIOXIDE,DRY CHEMICAL,FOAM,WATER FOG. Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS. WATER MAY BE USED TO COOL FIRE EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR AND FLASHBACK ALLONG VAPOR TRAIL MAY OCCUR. ================== Accidental Release Measures ================== Spill Release Procedures:WIPE UP WITH PAPER,CLOTH. STORE IN CLOSED CONTAINER. USE APPROPRIATE PRECAUTIONS TO PROTECT PERSONNEL AND PREVENT IGNITION. Neutralizing Agent:NONE - USE ALCOLHOL AS SOLVENT FOR CLEANING. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,DRY,WELL VENTILATED AREA. KEEP AWAY FROM HEAT,SPARKS,OTHER IGNITION SOURCES. Other Precautions:AVOID PROLONGED SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE EXPECTED TO BE NECESSARY. USE NIOSH/MSHA RESPIRATOR IF SYMPTOMS OCCUR OR PEL/TLV ARE EXCEEDED. Ventilation:NORMAL ROOM VENTILATION. LOCAL EXHAUST MAY BE REQUIRED UNDER SOME CONDITIONS. Other Protective Equipment:AS NEEDED TO PREVENT PROLONGED/REPEATED CONTACT. Work Hygienic Practices:USE GOOD INDUSTRIAL HYGIENE PRACTICE. AVOID UNNEXESSARY CONT. Supplemental Safety and Health MFR DATES MSDS ON DAY MAILED,NOT DAY REVISED. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:160F/71C Vapor Pres:36 MM Vapor Density:>1 Spec Gravity:0.86 Evaporation Rate & Reference:>1 BUAC Solubility in Water:APPRECIABLE Appearance and Odor:INTENSE GREEN COLOR,SWEET SOLVENT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HEAT,IGNITION SOURCES. Hazardous Decomposition Products:CARBON MONOXIDE,CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE I/A/W FEDERAL,STATE,LOCAL,REGULATIONS. MFR SUGGESTS INCINERATION.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DELRIN ACETAL RESIN, 900CL NC010 Preparer's Name:J.B. ARMITAGE CAGE:18897 CAGE:18897 CAGE:18873 ============= Composition/Information on Ingredients ============= Ingred Name:POLYOXYMETHYLENE, POLYACETAL CAS:9002-81-7 Ingred Name:ADDITIVES:ANTIOXIDANTS, LUBRICANTS & STABILIZERS. ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:INGEST:NOT A PROBABLE ROUTE OF EXPOSURE. SKIN:NOT TOXIC. HOT POLYMER WILL CAUSE THERMAL BURNS. EYE:MECHANICAL IRRITATION. INHAL:FORMALDEHYDE IS HIGHLY IRRITATING TO EYES & UPPER RESP TRACT. CHRO NIC:FORMALDEHYDE RELEASED IN SMALL QUANTITY DURING MELT PROCESSING IS CLASSIFIED AS ANIMAL CARCINOGEN. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER. Medical Cond Aggravated by Exposure:PERSONS W/PRE-EXISTING DISEASES OF LUNGS MAY HAVE INCREASED SUSCEPTIBILITY TO TOXICITY OF EXCESSIVE EXPOSURE TO FORMALDEHYDE. ======================= First Aid Measures ======================= First Aid:INHAL:MOVE TO FRESH AIR. CALL MD IF SYMPTOMS PERSIST. EYES:FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN. CALL MD IF SYMPTOMS PERSIST. SKIN:IF MOLTEN POLYMER CONTACTS SKIN, COOL RAPIDLY W/COLD WATER. DO NOT ATTEMPT TO PEEL POLYMER FROM SKIN.GET MD FOR THERMAL BURN. INGEST:CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Flash Point:612F,322C Extinguishing Media:WATER, CARBON DIOXIDE, FOAM, DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . PROTECTION FROM FUMES OF FORMALDEHYDE. Unusual Fire/Explosion Hazard:BURNS W/COLORLESS FLAME. DELRIN DUST CLOUD IGNITION TEMPERATURE 440C. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP TO PREVENT SLIPPING HAZARD. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DRY STORAGE. KEEP CNTNRS CLOSED TO PREVENT CONTAM. OPEN CNTNRS ONLY IN WELL-VENT AREA. READ "SAFETY PRECAUTIONS TO OBSERVE WHEN HANDLING (SUPP DATA) Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR IF LOCAL EXHAUST VENTILATION DOES NOT KEEP FORMALDEHYDE CONCENTRATION BELOW 1 PPM. Ventilation:LOCAL EXHAUST AT PROCESSING EQUIPMENT. Other Protective Equipment:LONG SLEEVE COTTON SHIRT AND LONG PANTS IF HANDLING MOLTEN POLYMER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FL PT METH:ASTM 1929-62. HAZ DECOMP PROD:SHORT TERM EXPOSURE LIMIT OF 2 PPM (15-MIN). HNDLG/STOR PREC:MOLTEN DELRIN ACETAL RESIN" E-49703 & "SAFETY PRECAUTIONS" IN MOLDING MANUAL E-09143, BEFORE USING DELRIN. AVOID PROLONGED HEATING ABOVE MELTING POINT (178C). ================== Physical/Chemical Properties ================== HCC:N1 Melt/Freeze Pt:M.P/F.P Text:342F,172C Spec Gravity:1.42 Solubility in Water:INSOLUBLE. Appearance and Odor:GRANULES OR POWDER, SLIGHT FORMALDEHYDE ODOR. ================= Stability and Reactivity Data ================= STRONG ACIDS AND BASES (DECOMPOSES FORMING FORMALDEHYDE). STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HEATING ABOVE 230C FORMS FORMALDEHYDE. Hazardous Decomposition Products:CO. FORMALDEHYDE IS CLASSIFIED AS ANIMAL CARCINOGEN & HAS OSHA PERMISSIBLE EXPOS LIM OF 1 PPM (8-HR TWA), & (SUPP DATA) ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATION OR LANDFILL IN COMPLIANCE W/FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CASTROL R RACING SAE 40 MOTOR OIL Preparer's Name:CHARLES R. PROSS CAGE:DO826 CAGE:DO826 ============= Composition/Information on Ingredients ============= Ingred Name:NO HAZARDOUS MATERIALS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE SKIN IRRITATION. Effects of Overexposure:SAME AS ACUTE AND CHRONIC EXPOSURE. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE FROM AREA OF VAPORS.EYES:FLUSH WITH CLEAR WATER UNTIL IRRITATION SUBSIDES.CONTACT A PHYSICIAN AS SOON AS POSSIBLE.SKIN:WIPE OR USE WATERLESS HANDCLEANER,WASH SKIN WITH SOAP AND WATER .INGESTION:DONOT INDUCE VOMITING. CONTACT A PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:420-440F Lower Limits:1.0 Upper Limits:6.0 Extinguishing Media:DRY CHEMICAL,CARBON DIOXIDE,FOAM,WATER FOG Fire Fighting Procedures:USE AIR-SUPPLIED RESCUE EQUIPMENT FOR ENCLOSED AREAS.COOL EXPOSED CONTAINERS WITH WATER Unusual Fire/Explosion Hazard:STORE IN CLOSED CONTAINERS AWAY FROM SOURCES OF IGNITION AND OXIDIZING SUBSTANCES. ================== Accidental Release Measures ================== Spill Release Procedures:MOP OR WIPE UP OR ABSORB WITH CLAY,DIATOMACEOUS EARTH OR OTHER INERT MATERIAL AND STORE IN CLOSED METAL CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS CLOSED AND AWAY FROM EXTREME HEAT. Other Precautions:AVOID BREATHING OF OIL MIST. REMOVE OIL IMPREGNATED CLOTHING.WASH THOROUGHLY AFTER EXPOSURE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORMALLY NEEDED.USE SUPPLIED AIR (SPECIFY TYPE)RESPIRATORY PROTECTION IN CONFINED OR ENCLOSED AREAS. Ventilation:MAINTAIN EXPOSURE BELOW 5MG PER CUBIC METER. FAN IF NEEDED. Other Protective Equipment:USE CHEMICALLY RESISTANT APRON OR OTHER CLOTHING TO AVOID PROLONGED SKIN CONTACT. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:500F Vapor Pres:.01 @ 20C Vapor Density:1.0 Spec Gravity:0.95-0.96 Evaporation Rate & Reference:.01 Solubility in Water:NEGLIGIBLE Appearance and Odor:YELLOW TO AMBER LIQUID,PETROLEUM ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID STRONG OXIDIZING AGENTS LIKE LIQUID CHLORINE AND CONCENTRATED OXYGEN. Hazardous Decomposition Products:COMBUSTION MAY PRODUCE SMOKE,CARBON MONOXIDE AND OXIDES OF SULFUR AND NITROGEN ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTROLLED INCINERATION OR METHOD IN COMPLIANCE WITH LOCAL,STATE AND FEDERAL REGULATIONS REGARDING HEALTH,AIR AND WATER POLLUTION.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TKB168 CAGE:09023 CAGE:09023 CAGE:14655 ============= Composition/Information on Ingredients ============= Ingred Name:POLYCHLORINATED BIPHENYLS (PCBS) (SARA III) CAS:1336-36-3 RTECS #:TQ1350000 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Effects of Overexposure:ABSORBED THRU SKIN,LUNGS,INTESTINE.CAUSES CANCER,LIVER,KIDNEY,STOMACH,EYE,HEARING DISORDER(SUP DATA) ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/WATER IMMEDIATELY.SKIN:WASH W/SOAP IMMEDIATELY.INHAL:REMOVE TO FRESH AIR,GIVE ART.RESPIR.AS NEEDED.INGEST:GET MEDICAL ATTN.GIVE LARGE QTY OF SALT WATER,INDUCE VOMITING,BUT DO NOT MAKE UNC ONSCIOUS PERSON VOMIT. ================== Accidental Release Measures ================== Spill Release Procedures:USE ABSORBENT & DIKES TO PREVENT RUNOFF.ISOLATE & NOTIFY PROPER AUTHORITIES. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE MUST FOLLOW RCRA REQUIREMENTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SUPPLIED AIR W/FULL FACEPIECE,HELMET OR HOOD Ventilation:LOCAL EXHAUST Other Protective Equipment:FULL CLOTHING TO PREVENT SKIN CONTACT Supplemental Safety and Health OVEREXPOS:CAN CAUSE FORMATION OF CYSTS,CAUSES STILLBIRTHS.IRRITATES EYES,NOSE THROAT. ================== Physical/Chemical Properties ================== HCC:V1 Appearance and Odor:LIGHT STRAW-COLORED LIQUID,AROMATIC ODOR ================= Stability and Reactivity Data ================= STRONG OXIDIZERS ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-GENERALLY HIGH TEMPERATURE INCINERATION.ONLY APPROVED DISPOSAL OPERATOR PERMITTED.
1
eyes_protection_mandatory
======================================================= Product ID: ABRASIVE DISCS, SILICONE CARBIDE, 812-214-200 Cage: FO436 ======================================================= Contractor Summary ======================================================= Cage: 94174 Cage: FO436 Box: NK/ ======================================================= Ingredients ======================================================= Cas: 409-21-2 RTECS #: VW0450000 % Wt: 20-50 OSHA PEL: 15 MG/M3 TDUST ACGIH TLV: 10 MG/M3 TDUST ------------------------------ % Wt: 15-60 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ----------------------------- % Wt: 10-40 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE:EYES:DUST FROM ABRADED SURFACE MAY CAUSE MECHANICAL IRRITATION. SKIN/INGESTION:NO ADVERSE HEALTH EFFECTS EXPECTED. INHALATION:OVEREXPOSURE TO DUST FROM ABRADED SURFACE MAY CAUSE RESPIRATORY SYST EM IRRITATION. HAZARD DEGREE BASED ON MATERIAL BEING ABRADED. CHRONIC:NOT AVAILABLE. Explanation Of Carcinogenicity: NOT RELEVANT Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. Medical Cond Aggravated By Exposure: NOT AVAILABLE. First Aid: INGEST:CALL MD IMMEDIATELY (FP N). SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD (FP N). EYES:FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINUTES & CALL MD IF IRRITATION PERSISTS. INHAL:PROVIDE FRESH AIR , TREAT FOR SUBSTRATE MATERIAL BEING ABRADED. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: NO SPECIAL PROCEDURES. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: COLLECT MATERIAL & DISPOSE IN A LOCAL SANITARY LANDFILL. FOLLOW FEDERAL, STATE & LOCAL REGULATIONS. Handling And Storage Precautions: KEEP CONTAINER CLOSED. NO SPECIAL HANDLING PRECAUTIONS. Other Precautions: AVOID BREATHING DUST FROM MATERIAL BEING GROUND. PREVENT SKIN OR EYE CONTACT W/DUST CREATED FROM GRINDING SUBSTRATE. NO UNUSUAL FIRE OR SPILL HAZARD; NUISANCE-LEVEL HEALTH RISK. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: NONE Lower Limits: NONE Upper Limits: NONE Extinguishing Media: WATER, CARBON DIOXIDE, FOAM. Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: NON-FLAMMABLE. ======================================================= Control Measures ======================================================= Respiratory Protection: WEAR A NIOSH APPROVED PARTICULATE FACE MASK WHERE DUST IS GENERATED. Ventilation: NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment: EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA (FP N). Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health: NONE SPECIFIED BY MANUFACTURER. ======================================================= Physical/Chemical Properties ======================================================= Appearance and Odor: SOLID ABRASIVE PRODUCT; NO ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER. Materials To Avoid: NOT DETERMINED. Hazardous Decomposition Products: THERMAL DEGRADATION WILL PRODUCE CARBON MONOXIDE, CARBON DIOXIDE & SMOKE PARTICULATES. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: ABRASIVE DISCS, SILICONE CARBIDE, 812-214-200 Cage: FO436 Assigned IND: Y Company Name: LECO CORPORATION Street: 3000 LAKEVIEW AVENUE PO Box: NK/ Zipcode: 49085 Label Required IND: Y Date Of Label Review: 11/16/1998 Status Code: C Label Date: 11/16/1998 Origination Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE:EYES:DUST FROM ABRADED SURFACE MAY CAUSE MECHANICAL IRRITATION. INHALATION:OVEREXPOSURE TO DUST FROM ABRADED SURFACE MAY CAUSE RESPIRATORY SYSTEM IRRITATION. HAZARD DEGREE BASED ON MATERIAL BEIN G ABRADED. CHRONIC:NONE LISTED BY MANUFACTURER. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CLEANING COMPOUND, SEPTIC TANK A-A-11 CAGE:WINST CAGE:WINST ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS INGREDIENTS Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CHRONIC EXPOSURE MAY LEAD TO ALLERGIC SENSITIZATION, BASED ON EXPOSURE LEVEL DURATION AND SUSCEPTIBILITY. SUBSEQUENT CHRONIC OR ACUTE EXPOSURE IN SENSITIZED INDIVIDUALS CAN CAUSE A RESPIRATORY ALLERGI C REACTION WITHIN MINUTES OR DELAYED UPTO 24 HOURS, OR A MIXTURE OF BOTH. Explanation of Carcinogenicity:NOT CLASSIFIED AS A CARCINOGEN. Effects of Overexposure:INHALATION:RESPIRATORY IRRITATION, BREATHLESSNESS, COUGHING, CHEST TIGHTNESS AND DIFFICULTY BREATHING. SKIN CONTACT:MAY CAUSE IRRITATION. EYE CONTACT:MAY CAUSE IRRITATION. INGESTION:MAY CAUSE SYMPTOMS OF GASTROINTESTINAL IRRITATION. ======================= First Aid Measures ======================= First Aid:INHALATION:IMMEDIATELY REMOVE INDIVIDUAL TO FRESH AIR.SKIN CONTACT:WASH EXPOSED SKIN THOROUGHLY WITH SOAP AND WATER. REMOVE AFFECTED CLOTHES AND WASH.EYE CONTACT:FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES.INGESTION:DRINK WATER,THEN INDUCE VOMITING BY HAVING PERSON STICK FINGER DOWN THROAT.KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION INTO LUNGS.GET MED ATTN. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY OR WATER FLOODING. Fire Fighting Procedures:TOXIC FUMES OF AMMONIA & SULFUR OXIDES MAY BE RELEASED VIOLENTLY AT HIGH TEMPS,FULL PROTECT CLOTHING/SCBA SHOULD BE WORN.USE H2O TO COOL FIRE EXPOSED CONTAINERS Unusual Fire/Explosion Hazard:MAY EXPLODE IF MIXED WITH OXIDIZERS, SUCH AS POTASSIUM NITRATE, POTASSIUM NITRITE OR POTASSIUM CHLORATE. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP SPILLED MATERIAL AND DISPOSE OF IN A MANNER APPROVED BY CITY, STATE AND FEDERAL REGULATIONS. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE. STORE IN COOL DRY AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED UNDER NORMAL CONDITIONS OF USE. IF RISK OF INHALATION MAY OCCUR, RESPIRATORY PROTECTIVE EQUIPMENT MUST BE SELECTED AND USED IN ACCORDANCE WITH OSHA/NIOSH GUIDELINES. Ventilation:RECOMMEND WELL VENTILATED WORK ENVIRONMENT. LOCAL EXHAUST AS NEEDED TO PREVENT DUST OR AEROSOL GENERATION. Other Protective Equipment:WEAR LONG-SLEEVED SHIRT AND TROUSERS TO AVOID CONTACT. SAFETY SHOWER, EYE BATH AND WASHING FACILITIES AVAILABLE. Work Hygienic Practices:FOLLOW GOOD INDUSTRIAL HYGIENE PRACTICES. Supplemental Safety and Health *AMMONIA IS RELEASED UPON REACTION WITH SULFUR DYES. CORROSIVE TO CARBON STEEL. ================== Physical/Chemical Properties ================== Solubility in Water:APPRECIABLE Appearance and Odor:TAN POWDER WITH SLIGHT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXYGEN,PEROXIDE,STRONG BASES,OXIDIZERS,E.G.POTASSIUM SALTS-NITRITE,NITRATE,CHLORATE,ZINC CLAD,COPPER/COPPER BEAR MAT'L. Stability Condition to Avoid:AVOID HEATING ABOVE 212 F TO AVOID DECOMPOSITION. Hazardous Decomposition Products:AMMONIA, SULFUR TRIOXIDE AND SULFUR DIOXIDE GASES BY DECOMPOSITION ABOVE 536 DEGREES F. ==================== Disposal Considerations ==================== Waste Disposal Methods:SWEEP UP MATERIAL AND DISPOSE OF IN A MANNER APPROVED BY CITY, STATE AND FEDERAL REGULATIONS.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:CATALYZED HYDRAZINE 7% CAGE:64713 CAGE:64713 ============= Composition/Information on Ingredients ============= Ingred Name:HYDRAZINE (SARA 302/313) (CERCLA) CAS:302-01-2 RTECS #:MU7175000 Fraction by Wt: 7% Other REC Limits:NONE RECOMMENDED OSHA PEL:S, 1 PPM ACGIH TLV:S, 0.01 PPM, A3;9596 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:HYDROQUINONE (SARA 302/313) (CERCLA) CAS:123-31-9 RTECS #:MX3500000 Fraction by Wt: 0.1% Other REC Limits:NONE RECOMMENDED OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3; 9596 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:CORROSIVE TO BODY TISSUES. EYES:SEVERE IRRITATION, BURNS. INGESTION:MAY BURN MOUTH AND GI TRACT. SKIN:CORROSIVE,CAUSES BURNS AND SENSITIZATI0N.CHRONIC:DAMAGES LIVER,RED BLOOD CELLS,SUSPECTED CARCINOGE N. Explanation of Carcinogenicity:HYDRAZINE IS LISTED NTP-AC AND IARC-2B. Effects of Overexposure:IRRITATION/BURNS OF EYES AND SKIN. INGESTION:MOUTH BURNS, VOMITING, DIARRHEA. Medical Cond Aggravated by Exposure:PERSON WITH PREEXISTING LIVER AND EYE DISEASES OF THE MAY BE AT INCREASED RISK FROM EXPOSURE TO THIS ITEM. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH WITH WATER UNTIL ALL TRACES OF THIS MATERIAL ARE GONE.SKIN:REMOVE CONTAMINATED CLOTHING.WASH WITH SOAP AND WATER.INHAL:REMOVE FROM EXPOSURE.GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF NESCESSA RY.INGEST:GET PROMPT QUALIFIED MEDICAL ATTENTION.IF CONSCIOUS,INDUCE VOMITING WITH SYRUP OF IPECAC. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:FLUSH WITH WATER Fire Fighting Procedures:IF HYDRAZINE HAS EVAORATED TO 50%-DILUTE W/ WATER Unusual Fire/Explosion Hazard:HYDRAZINE IS EXTREMELY FLAMMABLE IN CONCENTRATIONS ABOVE 50%. ================== Accidental Release Measures ================== Spill Release Procedures:USE NIOSH/MSHA APPROVED SELF-CONTAINED BOOTS.SOAK UP WITH AN INERT,NON-COMBUSTIBLE ABSORBANT.WASH SPILL AREA. Neutralizing Agent:DILUTE HYPOCHLORITE SOLUTIONS. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID EYE AND SKIN CONTACT.DO NOT INHALE VAPORS. Other Precautions:MAINTAIN ATMOSPHERE OF NITROGEN OVER HYDRAZINE.BOND OR GROUND CONTAINER DURING TRASNFER OF LIQUIDS.ADEQUATE WATER SUPPLY MUST BE AVAILABLE FOR FLUSHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE A NIOSH-MSHA APPROVED CARTRIDGE TYPE RESPIRATOR FOR ORGANIC VAPORS. Ventilation:USE DILUTION VENTILATION. Other Protective Equipment:RUBBER APRON,COVERALLS.PROVIDE A LOCAL EYE WASH STATION AND QUICK DRENCH SHOWER. Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER HANDLING. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:T4 Boiling Pt:B.P. Text:215F,102C Vapor Pres:WATER Vapor Density:WATER Spec Gravity:1.003 Evaporation Rate & Reference:1 WATER=1 Solubility in Water:MISCIBLE Appearance and Odor:CLEAR,COLORLESS,LIQUID,SLIGHTLY FISHY ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS AND OXIDIZERS Stability Condition to Avoid:HIGH TEMPERATURES. Hazardous Decomposition Products:AMMONIA ==================== Disposal Considerations ==================== Waste Disposal Methods:FLUSH WITH LARGE AMOUNTS OF WATER AND FLUSH INTO A CATCH BASIN.TRANSFER INTO AN APPROVED DOT CONTAINER AND SEAL.NEUTRALIZE RESIDUE WITH DILUTE HYPOCHLORITE SOLUTION AND WASH W/WATER.DISPOSE OF IN ACCO RDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:EPK 1105, HARDENER Kit Part:Y Preparer's Name:KEN DECOSTA CAGE:1JB33 CAGE:12405 CAGE:1JB33 ============= Composition/Information on Ingredients ============= Ingred Name:POLYGLYCOLDIAMINE CAS:4246-51-9 RTECS #:ID6475000 Fraction by Wt: <80% Other REC Limits:NONE SPECIFIED OSHA PEL:1 PPM ===================== Hazards Identification ===================== Health Hazards Acute and Chronic:MAY CAUSE SKIN IRRITATION AND POSSIBLE ALLERGIC REACTIONS. PROLONGED AND REPEATED CONTACT MAY CAUSE SENSITIZATION WHICH WILL RESULT IN ALLERGIC REACTIONS. CORROSIVE. ======================= First Aid Measures ======================= First Aid:FLUSH SKIN AND EYE CONTACT WITH PLENTY OF WATER. WASH SKIN THOROUGHLY WITH SOAP AND WATER, RUBBING ALCOHOL OR HAND CLEANER. DO NOT USE SOLVENTS. REMOVE SOILED CLOTHING AND WASH BEFORE REUSE. IF IRRITA TION PERSISTS OR INCREASES, SEE PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:300F,149C Extinguishing Media:DRY CHEMICAL OR HALON FIRE EXTINGUISHER, OR WATER SPRAY, FOAM OR FOG. Fire Fighting Procedures:USE SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRES IN CONFINED AREAS. Unusual Fire/Explosion Hazard:DENSE SMOKE AND TOXIC GASSES MAY BE LIBERATED. ================== Accidental Release Measures ================== GLASSES. COVER WITH ABSORBENT MATERIAL, THEN SCRAPE UP AND TRANSFER TO METAL CONTAINER. WIPE UP REMAINING RESIDUE WITH SOLVENTS, OBSERVING SOLVENT FLAMMABIL ITY. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP PRODUCT COOL IN ACCORDANCE WITH LABEL INSTRUCTIONS. Other Precautions:FOLLOW RECOMMENDED CURING SCHEDULE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED WITH GOOD INDUSTRIAL VENTILATION. Ventilation:MECHANICAL EXHAUST IS HELPFUL Other Protective Equipment:AS NEEDED TO PROTECT SKIN AND CLOTHING Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:435F,224C Vapor Pres:<0.001 Vapor Density:7.6 Spec Gravity:1.02 Evaporation Rate & Reference:>0.0001 (BU AC=1) Solubility in Water:100% Appearance and Odor:TRANSLUCID GEL; AMMONIACAL ODOR Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG LEWIS OR MINERAL ACIDS. Stability Condition to Avoid:NONE Hazardous Decomposition Products:CO, NOX, ALDEHYDES, ACIDS AND UNDETERMINED ORGANICS Conditions to Avoid Polymerization:DONT HEAT UNLESS CURING SURFACE TO BE BONDED. HEATING IN MASSES > 1.2 LB MAY RESULT IN EXCESSIVE HEAT BLDUP & TOXIC GAS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF AS HAZARDOUS WASTE ACCORDING TO DOT HAZARD CLASS. IF NOT REGULATED BY DOT, DISPOSE OF AS ORM-E. DISPOSAL METHOD CAN BE LAND BURIAL OR CHEMICAL INCINERATION AS REGULATED BY ALL GOVERNMENTAL AGENCIES.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PLUMBERS HEAT-PRUF GREASE, GR-1X Preparer's Name:I LIEBMAN CAGE:77628 CAGE:77628 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, HYDROTREATED (SEVERE) HEAVY NAPHTHENIC; (HEAVY NAPHTHENIC DISTILLATE) CAS:64742-52-5 RTECS #:PY8035000 Fraction by Wt: <75% OSHA PEL:N/K ACGIH TLV:5 MG/M3 (MIST) (MFR) Ingred Name:NON-HAZARDOUS INGREDIENTS OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE:MILD IRRITANT. SKIN:MILD IRRITANT ON PROLONGED EXPOSURE. INHALATION:NOT LIKELY (GREASE). INGESTION:NOT LIKELY (GREASE). HARMFUL IF SWALLOWED! Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH WITH WATER FOR AT LEAST 15 MINUTES. IF ADVERSE EFFECTS PERSIST, CONSULT A PHYSICIAN IMMEDIATELY. SKIN:WASH WITH SOAP AND WATER. IF INJECTED UNDER THE SKIN (HIGH PRESSURE), TREAT AS MEDICALEMERGENCY. INHALATION:MOVE TO FRESH AIR. INGESTION:DO NOT INDUCE VOMITING! CONSULT A PHYSICIAN IMMEDIATELY. DO NOT ADMINISTER ADRENALIN OR EPINEPHRINE! ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:380F,193C Extinguishing Media:WATER FOG, FOAM, CO*2, DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . COOL CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:NONE KNOWN. ================== Accidental Release Measures ================== Spill Release Procedures:OBSERVING HEALTH HAZARDS, REMOVE IGNITION SOURCE. SOAK UP WITH ABSORBENT CLAY AND TRANSFER TO WASTE DRUM. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL PLACE AWAY FROM IGNITION SOURCE, OXIDIZING AGENTS. Other Precautions:KEEP AWAY FROM CHILDREN AND ANIMALS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . NONE REQUIRED. Ventilation:USE WITH ADEQUATE LOCAL EXHAUST VENTILATION. Other Protective Equipment:EMERGENCY EYE WASH & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . CHEMICAL RESISTANT APRON. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EYE PROT:AND FULL LENGTH FACE SHIELD . ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:<500F,<260C Spec Gravity:1.0 (H*2O=1) pH:6-7 Solubility in Water:INSOLUBLE Appearance and Odor:BROWN GREASE WITH PETROLEUM-LIKE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:FIRE:NORMAL PRODUCTS OF COMBUSTION:CARBON MONOXIDE, CARBON DIOXIDE AND SMOKE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE GOVERNMENT, FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PT-107,FUNGUS RESISTANT,AIR DRY, CLEAR VARNISH Preparer's Name:STEPHEN JABS CAGE:06341 CAGE:06341 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 9.18% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM/300 STEL ACGIH TLV:200 PPM/300STEL 9394 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SALICYLANILIDE CAS:87-17-2 RTECS #:VN7850000 Fraction by Wt: 4.06% Other REC Limits:10 MG/M3 Ingred Name:TUNG OIL CAS:8001-20-5 Fraction by Wt: 31.99% Other REC Limits:NONE RECOMMENDED Ingred Name:ADDITIVE (CONTAINS XYLENE)(SARA III) Fraction by Wt: 0.36% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM, 150 STEL ACGIH TLV:100 PPM/150STEL 9394 Ingred Name:ADDITIVE (NON-HAZARDOUS) Fraction by Wt: 0.36% Other REC Limits:NONE RECOMMENDED Ingred Name:PHENOLIC RESIN CAS:27553-53-3 Fraction by Wt: 26.17% Other REC Limits:NONE RECOMMENDED Ingred Name:MINERAL SPIRITS CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: 18.30% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:100 PPM; 9394 Ingred Name:2-ETHOXYETHYL ACETATE (CELLOSOLVE ACETATE) (EGEEA)(SARA III) CAS:111-15-9 RTECS #:KK8225000 Fraction by Wt: 3.92% Other REC Limits:NONE RECOMMENDED OSHA PEL:S,100 PPM ACGIH TLV:S, 5 PPM; 9394 Ingred Name:N-PROPANOL CAS:71-23-8 RTECS #:UH8225000 Fraction by Wt: 3.92% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM/250 STEL ACGIH TLV:S,200PPM/250STEL9394 Ingred Name:COBALT DRIER (SARA III) Fraction by Wt: 0.34% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.05 PPM CO ACGIH TLV:0.05 PPM CO 9394 Ingred Name:ZIRCONIUM DRIER CAS:22464-99-9 Fraction by Wt: 0.66% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 PPM ZR ACGIH TLV:5 PPM ZR9394 Ingred Name:ADDITIVE (NON-HAZARDOUS) CAS:96-29-7 Fraction by Wt: 0.66% Other REC Limits:NONE RECOMMENDED Ingred Name:VOLATILE ORGANIC COMPOUND CONTENT (350 GMS/LITER) RTECS #:9999999VO Other REC Limits:NONE RECOMMENDED Ingred Name:INGREDIENTS OF PROPELLANT FOR AEROSOL ARE INGREDIENT NUMBERS 15, 16, 17, AND 18. RTECS #:9999999ZZ Ingred Name:PROPANE (PROPELLANT) CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 22% Other REC Limits:NONE RECOMMENDED OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT; 9394 Ingred Name:ACTTONE CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 73% Other REC Limits:NONE RECOMMENDED OSHA PEL:750 PPM ACGIH TLV:750 PPM 9394 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHYL-3-ETHOXYPROPIONATE CAS:763-69-9 RTECS #:UF3325000 Fraction by Wt: 6% Other REC Limits:NONE RECOMMENDED Ingred Name:VOLATILE ORGANIC COMPOUNDS RTECS #:9999999VO Fraction by Wt: 100% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYES: STINGING, TEARING, REDNESS, SWELLING, DAMAGE. SKIN: REDNESS, BURNING, DRYING, CRACKING. INHALATION: HEADACHE, DIZZINESS, LOSS OF COORDINATION, FATIGUE. INGESTION: NONE SPECIFIED. CHRONIC: PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTINAL MISUSE BY CONCENTRATING AND INHALING MAY BE HARMFUL OR FATAL. Explanation of Carcinogenicity:CONTAINS 2-ETHOXYETHYL ACETATE KNOWN IN CALIFORNIA TO CAUSE CANCER OR REPRODUCTIVE TOXICITY. Effects of Overexposure:EYES: STINGING, TEARING, REDNESS, SWELLING, DAMAGE. SKIN: REDNESS, BURNING, CRACKING. INHALATION: HEADACHE, DROWSINESS, DIZZINESS, LOSS OF COORDINATION, FATIGUE, DEATH. INGESTION: NONE SPECIFIED BY MA NUFACTURER. Medical Cond Aggravated by Exposure:PRE-EXISTING MEDICAL CONDITIONS MAY BE AGGRAVATED BY USE OF THIS PRODUCT. TWO COMMON CONDITIONS THAT MAY BE AGGRAVATE BY THIS PRODUCT ARE DERMATITIS AND ASTHMA. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. WASH AREA WITH SOAP AND WATER. IF IRRITATION DEVELOPS, GET MEDICAL ATTENTION. INHALATION: MOVE TO FR ESH AIR. IF NOT BREATHING, GIVE CPR. IFBREATHING DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION. INGESTION: GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:24.0F,-4.4C Lower Limits:0.9 Upper Limits:13.7 Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, UNIVERSAL TYPE FOAM. Fire Fighting Procedures:WEAR PROTECTIVE EQUIPMENT INCLUDING RESPIRATORY PROTECTION. MOVE CONTAINERS FROM FIRE AREA. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS AND DISPERSE VAPORS. Unusual Fire/Explosion Hazard:VAPORS,HEAVIER THAN AIR, MAY TRAVEL TO DISTANT IGNITION SOURCES AAND FLASHBACK OR EXPLODE; MAY CREATE VAPOR/AIR EXPLOSION HAZARD INDOORS,OUTDOORS,OR IN SEWERS. ================== Accidental Release Measures ================== Spill Release Procedures:KEEP ALL SOURCES OF IGNITION AND HOT METAL SURFACES AWAY FROM SPILL. WEAR APPROPRIATE PROTECTIVE EQUIPMENT. DIKE SPILL WITH ABSORBENT AND PUMP OR ABSORB AND SCOOP MATERIAL INTO CONTAINERS FOR PROPER D ISPOSAL OR REUSE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE AND STORE THIS MATERIAL IN COOL, DRY, WELL VENTILATED AREA AWAY FROM HEAT, DIRECT SUNLIGHT, HOT METAL SURFACES AND IGNITION SOURCES. Other Precautions:POST AREA "NO SMOKING OR OPEN FLAME". BOND AND GROUND ALL EQUIPMENT WHEN TRANSFERRING FROM ONE VESSEL TO ANOTHER. PROTECT CONTAINERS FROM PHYSICAL DAMAGE. USE OF EXPLOSIVE-PROOF EQUIPMENT IS RECOMMEND ED. KEEP CONTAINERS CLOSED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN CONCENTRATIONS EXCEED EXPOSURE LIMITS, USE A NIOSH APPROVED RESPIRATOR OR GAS MASK WITH NIOSH APPROVED CARTRIDGES OR CANNISTERS, OR NIOSH APPROVED SUPPLIED AIR EQUIPMENT. Ventilation:PROVIDE ADEQUATE MECHANICAL (GENERAL) AND LOCAL EXHAUST TO MAINTAIN AIRBORNE CONCENTRATIONS BELOW ESTABLISHED LIMITS. Other Protective Equipment:PROVIDE AN EYE WASH STATION AND SAFETY SHOWER. IMPERVIOUS CLOTHING AND SHOES SHOULD BE WORN. Work Hygienic Practices:WASH AFTER HANDLING AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health EMPTY CONTAINERS RETAIN RESIDUE LIQUID AND VAPORS AND CAN BE DANGEROUS. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE TO HEAT, FLAME, SPARKS, OTHER IGNITION SOURCES; THEY MAY EX PLODE AND CAUSE INJURY OR DEATH. ================== Physical/Chemical Properties ================== HCC:V3 Boiling Pt:B.P. Text:175 TO 395F Vapor Density:>1 Spec Gravity:0.92 Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1) Appearance and Odor:CLEAR VARNISH Percent Volatiles by Volume:40.32 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS AND BASES, OXIDIZERS, AND SELECTED AMINES. Stability Condition to Avoid:AVOID ALL POSSIBLE SOURCES OF IGNITION. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE. OTHER KNOWN HAZARDOUS PRODUCTS ARE POSSIBLE. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. EMPTY CONTAINERS SHOULD BE COMPLETELY DRAINED, RINSED, AND PROPERLY DISPOSE OF IN AN ENVIRONMENTALLY SAFE MANNER AND IN ACCORD ANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HI-BILD ALIPHATIC POLYURETHANE ENAMEL CAGE:54636 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYL BENZENE CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 5% Other REC Limits:100 PPM OSHA PEL:435 MG/CUM ACGIH TLV:434 MG/CUM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENE, DIMETHYLBENZENE, XYLOL CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 31% Other REC Limits:100 PPM OSHA PEL:100 PPM ACGIH TLV:100 PPM, SKIN EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SOLVENT NAPHTHA, PETROLEUM, LIGHT AROMATIC, HIGH FLASH AROMATIC NAPHTHA CAS:64742-95-6 RTECS #:WF3400000 Fraction by Wt: 1% Ingred Name:1,3,5,-TRIMETHYLBENZENE CAS:108-67-8 RTECS #:OX6825000 Fraction by Wt: 1% OSHA PEL:25 PPM ACGIH TLV:25 PPM Ingred Name:1,2,4-TRIMETHYLBENZENE CAS:95-63-6 RTECS #:DC3325000 Fraction by Wt: 2% OSHA PEL:25 PPM ACGIH TLV:25 PPM Ingred Name:HEXONE, METHYL ISOBUTYL KETONE (MIBK), 4-METHYL-2-PENTANONE CAS:108-10-1 RTECS #:SA9275000 Fraction by Wt: 7% Other REC Limits:50 PPM OSHA PEL:100 PPM/75 STEL ACGIH TLV:50 PPM/75 STEL; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:BARIUM SULFATE, BARYTES CAS:7727-43-7 RTECS #:CR0600000 Fraction by Wt: 12% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:BARIUM (SOLUBLE COMPOUNDS) CAS:7440-39-3 RTECS #:CQ8370000 Fraction by Wt: 12% OSHA PEL:0.5 MG/CUM ACGIH TLV:0.5 MG/CUM Ingred Name:WEIGHT PER GALLON IN POUNDS: 8.64 RTECS #:9999999WG Ingred Name:VOL ORGANIC CMPD: 4.25 RTECS #:9999999VO ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE, SKIN, OR RESPIRATORY IRRITANT. NERVOUS SYSTEM DEPRESSION. EXTREME OVEREXPOSURE MAY CAUSE DEATH. OVEREXPOSURE TO SOLVENTS MAY CAUSE PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE & ADVERSE EFFECTS TO THE LIVER, URINARY, BLOOD-FORMING, CARDIO-VASCULAR & REPRODUCTIVE SYSTEMS. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: HEADACHE, DIZZINESS, NAUSEA, LOSS OF COORDINATION, UNCONSCIOUSNESS, DEATH. EYES/SKIN: REDNESS, ITCHING OR BURNING SENSATION. Medical Cond Aggravated by Exposure:SUSCEPTIBLE PERSONS OR SENSITIZATION. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. KEEP WARM & QUIET. SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/PLENTY OF WATER FOR 15 MINS. INGESTION: OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:60F Lower Limits:0.7% Upper Limits:6.7% Extinguishing Media:CO2, DRY CHEMICAL, FOAM Fire Fighting Procedures:USE FULL PROTECTIVE EQUIP & SCBA. WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. USE WATER TO COOL FIRE EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. APPLICATION TO HOT SURFACES REQUIRES SPECIAL PRECAUTIONS. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM IGNITION SOURCES. DURING USE & UNTIL ALL VAPORS ARE GONE: KEEP AREA VENTILATED. DON'T SMOKE. CONSULT NFPA CODE. DON'T TAKE INTERNALLY. Other Precautions:EXTINGUISH ALL FLAMES, PILOT LIGHTS, & HEATERS. TURN OFF STOVES, ELECTRIC TOOLS & APPLIANCES. USE APPROVED BONDING & GROUNDING PROCEDURES. KEEP CONTAINER CLOSED WHEN NOT IN USE. TRANSFER ONLY TO APPRO VED CONTAINERS W/COMPLETE LABELING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE OVERSPRAY IS PRESENT, USE A POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR (TC19C NIOSH/MSHA APPROVED). IF UNAVAILABLE, USE A PROPERLY FITTED ORGANIC VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/MS HA. WEAR RESPIRATOR THE WHOLE TIME. Ventilation:LOCAL EXHAUST: PREFERABLE. GENERAL EXHAUST: ACCEPTABLE IF THE EXPOSURE TO HAZARDOUS INGREDIENTS IS KEPT BELOW TLV. Other Protective Equipment:BARRIER CREAM ON EXPOSED SKIN Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH HANDS AFTER USING. Supplemental Safety and Health KEEP OUT OF REACH OF CHILDREN. THIS PRODUCT MUST BE MIXED W/OTHER COMPONENTS BEFORE USE. BEFORE OPENING THE PACKAGES, READ & FOLLOW WARNING LABELS ON ALL COMPONENTS. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING THE CONTENTS CAN BE HARMFUL OR FATAL. AVOID BREATHING VAPOR/SPRAY MIST & CONTACT W/SKIN/EYES. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:237-395F Vapor Density:>1 Spec Gravity:0.96-1.21 Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:55-60 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONTAMINATION W/WATER, ALCOHOLS, AMINES & OTHER COMPOUNDS THAT MAY REACT W/ISOCYANATES (POSSIBLE BURSTING). Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAME OR OTHER IGNITION SOURCES. Hazardous Decomposition Products:BY FIRE: CO2, CO, OXIDES OF NITROGEN, POSSIBILITY OF HYDROGEN CYANIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE MAY BE HAZARDOUS UNDER THE RCRA. TEST WASTE FOR IGNITABILITY TO DETERMINE THE APPLICABLE EPA HAZARDOUS WASTE NUMBERS. INCINERATE IN APPROVED FACILITY. DON'T INCINERATE CLOSED CONTAINER. DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:175 6725 T-90-04 CYAN DEVELOPER AND REPLENISHER,PART A Kit Part:Y CAGE:19139 CAGE:19139 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: BALANCE Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT Ingred Name:PHOSPHONIC ACID,(1-HYDROXYETHYLIDENE)DI-/SUBSTITUTED PHOSPHONATE CAS:2809-21-4 RTECS #:SZ8562100 Fraction by Wt: 40 - 45% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS NOT KNOWN. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYES. ACUTE- EYES:NO SPECIFIC HAZARD KNOWN. MAY CAUSE TRANSIENT IRRITATION. SKIN:LOW HAZARD FOR RECOMMENDED HANDLING. INHALATION:EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED HANDLING. ORA L:EXPECTED TO BE A LOW INGESTION HAZARD. CHRONIC- UNKNOWN. Explanation of Carcinogenicity:NONE Effects of Overexposure:TRANSIENT EYE IRRITATION Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING EYE DISORDERS MAY BE MORE SUCCEPTIBLE TO THE EFFECTS FROM EXPOSURE TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:REMOVE TO FRESH AIR. EYES:FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER. ORAL:DO NOT INDUCE VOMITING. IF CONSCIOUS, D RINK 1-2 GLASSES OF WATER. SEEK MEDICALATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE WATER SPRAY, CARBON DIOXIDE (CO2), ALCOHOL FOAM OR DRY CHEMICAL. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. HAZARDOUS DECOMPOSITION PRODUCTS MAY BE FORMED. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNT OF WATER. OTHERWISE, ABSORB SPILL WITH INERT MATERIAL SUCH AS VERMICULITE, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CO NTAMINATION. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL PLACE AWAY FROM STRONG OXIDIZING AGENTS. KEEP CONTAINER TIGHTLY CLOSED. Other Precautions:KEEP OUT OF REACH OF CHILDREN. AVOID EYE CONTACT. USE WITH ADEQUATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES/HR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. WASH THOROUGHLY BEFORE EATING, DRINKING/SMOKING. Supplemental Safety and Health KEY1:C4. ECOLOGICAL INFORMATION: THIS MATERIAL IS EXPECTED TO HAVE THE FOLLOWING PROPERTIES: A LOW BIOCHEMICAL OXYGEN DEMAND, A LOW POTENTIAL TO AFFECT SOME AQUATIC ORGANISMS. AFTER DILUTION WITH LARG E AMOUNT OF WATER, THIS MATERIAL IS NOTEXPECTED TO CAUSE ADVERSE ENVIRONMENTAL EFFECTS. ================== Physical/Chemical Properties ================== HCC:B3 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:18 @ 68F Vapor Density:0.6 Spec Gravity:1.40 pH:10.2 Solubility in Water:COMPLETE Appearance and Odor:LIGHT YELLOW LIQUID - AMMONIA ODOR Percent Volatiles by Volume:60 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:NONE Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, OXIDES OF PHOSPHORUS ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE OR LOCAL REGULATIONS. FLUSH TO SEWER WITH LARGE AMOUNT OF WATER, IF PERMITTED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PHOSPHORIC ACID, 5592 CAGE:70829 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:PHOSPHORIC ACID CAS:7664-38-2 RTECS #:TB6300000 Minumum % Wt:74. Maxumum % Wt:95. OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3 ACGIH STEL:3 MG/M3 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Minumum % Wt:5. Maxumum % Wt:26. ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION: IS NOT AN EXPECTED HAZARD UNLESS MISTED OR HEATED TO HIGH TEMPERATURES. MIST OR VAPOR INHALATION CAN CAUSE IRRITATON TO THE NOSE, THROAT, AND UPPER RESPIRATORY TRACT. SEVERE EXPOSUR ES CAN LEAD TO CHEMICAL PNEUMONITIS. INGESTION: CORROSIVE. MAY CAUSE SORE THROAT, ABDOMINAL PAIN, NAUSEA, AND SEVERE BURNS OF THE MOUTH, THROAT, AND STOMACH. SEVERE EXPOSURES CAN LEAD TO SHOCK, CIRCUL ATORY COLLAPSE, AND DEATH. SKIN CONT: CORROSIVE. MAY CAUSE REDNESS, PAIN, AND SEVERE SKIN BURNS. EYE CONT: CORROSIVE. MAY CAUSE REDNESS, PAIN, BLURRED VISION, EYE BURNS, AND (EFTS OF OVEREXP) Effects of Overexposure:HLTH HAZS: PERMANENT EYE DAMAGE. CHRONIC: NO INFORMATION FOUND. Medical Cond Aggravated by Exposure:PERSONS WITH PRE EXISITING SKIN DISORDERS OR EYE PROBLEMS, OR IMPAIRED RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYG. CALL PHYS IMMED. INGEST: DO NOT INDUCE VOMIT. GIVE LG QTYS OF WATER. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSO N. GET MED ATTN IMMED. SKIN CONT: IMMED FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS WHILE REMOVING CONTAMD CLTHG & SHOES. CALL PHYS IMMED. WASH CLTHG BEFORE REUSE. EYE CONT: IMMED FLUSH W/GENTLE BUT LG STREAM OF WATER FOR AT LST 15 MINS, LIFTING LOWER & UPPER EYELIDS OCCASIONALLY. CALL PHYS IMMED. ===================== Fire Fighting Measures ===================== Extinguishing Media:FIRE: NOT CONSIDERED TO BEFIRE HAZARD. CONTACT WITH MOST METALS CAUSES FORMATION OF FLAMM AND EXPLOSIVE HYDROGEN GAS. USE ANY MEDIA SUITABLE FOR EXTINGUISHING SURROUNDING FIRE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL. IF WATER IS USED, USE IN ABUNDANCE TO CONTROL HEAT AND ACID BUILD-UP. Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE AN EXPLOSION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF LEAK/SPILL. WEAR APPROP PERSONAL PROT EQUIP AS SPECIFIED IN EXPOSURE CONTROLS/PERSONAL PROT SECTION. ISOLATE HAZARD. KEEP UNNEC & UNPROTECTED PERS FROM ENTERING. CNTN & RECOVER LIQ W HEN POSS. NEUT W/ALKALINE MATL (SODA ASH LIME) THEN ABSORB W/INERT MATL (E.G. VERMICULITE, DRY SAND, EARTH), & PLACE IN CHEM WASTE CNTNR. DO NOT USE COMBUST MATLS, (SUPDAT) Neutralizing Agent:J.J. BAKER NEUTRASORB(TM) OR TEAM(TM) 'LOW NA+' ACID NEUTRALIZERS ARE RECOMMENDED FOR SPILLS OF THIS PRODUCT. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP IN TIGHTLY CLSD CNTNR. PROTECT FROM PHYSICAL DMG. STORE IN COO, DRY, VENTILATED AREA AWAY FROM SOURCES OF HEAT,MOISTURE, INCOMPATIBILITIES, & DIRECT SUNLIGHT. CORR! MILD STEEL. STORE IN RUBB LINE D/316 STAINLESS STEEL DESIGNED FOR PHOSPHORIC ACID. DO NOT WASH OUT CNTNR & USE FOR OTHER PURPOSES. Other Precautions:WHEN DILUTING, ACID SHOULD ALWAYS BE ADDED SLOWLY TO WATER & IN SM AMTS. NEVER USE HOT WATER & NEVER ADD WATER TO ACID. WATER ADDED TO ACID CAN CAUSE UNCONTROLLED BOILING & SPLASHING. PROTECT FROM FRE EZING. CNTNRS OF MATL MAY BE HAZ WHEN EMPTY SINCE THEY RETAIN PROD RESIDUES(VAPS, LIQ): OSBSERVE ALL(OTHER INFO) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOS LIMIT IS EXCEEDED, A NIOSH APPRVD FULL FACEPIECE RESP W/HIGH EFFICIENCY DUST/MIST FILTER MAY BE WORN UP TO 50 TIMES EXPOS LIMT/MAX USE CONC SPECIFIED BY APPROP REGULATORY AGENCY/RESP SUPPLIE R, WHICHEVER IS LOWEST. FOR EMER/INSTANCES WHERE EXPOS LEVELS ARE NOT KNOWN, USE NIOSH APPRVD FULL-FACEPIECE POS-PRESS AIR-SUPPLIED RESP. WARNING: (OTHER INFO) Ventilation:SYS OF LOC AND/OR GEN EXHST IS REC TO KEEP EMPLOYEE EXPOS BELOW AIRBORNE EXPOS LIMITS. LOC EXHST VENT IS GENERALLY PREF (OTHER INFO) Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . WEAR IMPERVIOUS CLTHG, INCL BOOTS, LAB COAT, APRON OR COVERALLS, AS APPROP TO PVNT SKIN CONT. Work Hygienic Practices:WASH CLOTHING BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health SPILL PROC: SUCH AS SAW DUST. DO NOT FLUSH TO SEWER. US REGS (CERCLA) REQ RPTG SPILLS & RELEASES TO SOIL, WATER & AIR IN EXCESS OF REPORTABLE QTYS. TOLL FREE NUMBER FOR US COAST GUARD NATL RESPONSE CT R IS (800)424-8802. WASTE DISP METH: & UNUSED CONTENTS I/A/W FED, STATE & LOC REQUIREMENTS. PH: 1.5(0.1 N AQUEOUS SOLN). ================== Physical/Chemical Properties ================== Boiling Pt:=158.C, 316.4F Melt/Freeze Pt:=21.C, 69.8F Vapor Pres:0.03 @ 20C Vapor Density:3.4 Spec Gravity:1.69 @ 25C pH:SUPDAT Evaporation Rate & Reference:NO INFORMATION FOUND Solubility in Water:MISCIBLE Appearance and Odor:CLEAR, COLORLESS SYRUPY LIQUID. ODORLESS. Percent Volatiles by Volume:100 @ 21C ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES LIBERATES EXPLO HYDROGEN GAS WHEN REACTING W/CHLORIDES & STAINLESS STEEL. CAN REACT VIOLENTLY W/SODIUM TETRAHYDROBORATE. EXOTHERMIC RXNS W/ALDEHYDES, AMINES, AMIDES, ALCOHOLS & GLYCOLS, AZO-CMPDS, CARBAMATES, ESTERS, CAUSTI Stability Condition to Avoid:STABLE UNDER ORDINARY CNDTNS OF USE & STORAGE. SUBSTANCE CAN SUPERCOOL WITHOUT CRYSTALLIZING. INCOMPATIBILITIES. Hazardous Decomposition Products:PHOSPHORUS OXIDES MAY FORM WHEN HEATED TO DECOMPOSITION. =================== Toxicological Information=================== Toxicological Information:ORAL RAT LD50: 1530 MG/KG: INVESTIGATED AS A MUTAGEN. OTHER INFO: IT ALSO FORMS TOXIC FUMES WITH EYANIDES, SULFIDE, FLUORIDES, ORGANIC PEROXIDES AND HALOGENATED ORGANICS. MIXTURES WITH NITROMETHANE AR E EXPOLOSIVE. ===================== Ecological Information ===================== Ecological:ENVIRONMENTAL FATE: WHEN RELEASED INTO SOIL, THIS MATL MAY LEACH INTO GROUNDWATER. WHEN RELEASED TO WATER, ACIDS MAY BE READILY REDICED BY NATURAL WATER HARDNESS MINERALS. THE PHOSPHATE, HOWEVER, MAY PERSIST INDEFINITELY. ENVIRONMENTAL TOX: NO INFORMATION FOUND. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY/RECYCLING SHOULD BE HNDLD AS HAZ WASTE & SENT TO RCRA APPRVD INCIN/DISPOSED IN RCRA APPRVD WASTE FACILITY. PROCESSING, USE/CONTAM OF PROD MAY CHANGE WASTE MANAGEM ENT OPTIONS. STATE & LOC DISP REGS MAY DIFFER FROM FED DISP REGS. DISPOSE OF CNTNR (SUPDAT) =================== MSDS Transport Information =================== Transport Information:DOMESTIC (LAND, D.O.T.). PROPER SHIPPING NAME: PHOSPHORIC ACID. HAZARD CLASS: 8. UN/NA: UN;805. PACKING GROUP: III. INFORMATION REPORTED FOR PRODUCT/SIZE: 355LB. INTERNATIONAL (WATER, I.M.O.). PROPER SHIPPING NAME: PHOSPHORIC ACID. LIQUID. HAZARD CLASS: 8. UN/NA: UN850. PACKING GROUP: III. INFORMATION REPORTED FOR PRODUCT/SIZE: 355LB. ===================== Regulatory Information ===================== SARA Title III Information:FED, STATE & INTERNATION REGS - PART 1. INGRED: PHOSPHORIC ACID(7664-38-2). SARA 302 - RQ, NO, TPO-NO, SARA 313- LIST-YES, CHEM CATG-NO. INGRED: WATER(7732-18-5). SARA 302- RQ-NO, TPO-NO, SARA 313-LIS T-NO, CHEMICAL CATG-NO. CHEMICAL WEAPONS CONVENTION: NO. TSCA 12(B): NO. CDTA: NO. SARA 311/312: ACUTE: YES. CHRONIC: NO. FIRE: NO. PRESSURE: NO. REACTIVITY: NO. (PURE/LIQUID). Federal Regulatory Information:CHEM INVENTORY STATUS-PART 1. INGRED: PHOSPHORIC ACID(7664-38-2). TSCA-YES, EC-YES, JAPAN-YES, AUSTRALIA-YES. INGRED: WATER(7732-18-5). TSCA-YES, EC-YES, JAPAN-YES, AUSTRALIA-YES. CHEM INVENTORY STATU S-PART 2. INGRED: PHOSPHORIC ACID(7664-38-2). CANADA - KOREA-YES, DSL-YES, NDSL-NO, PHIL-YES. INGRED: WATER (7732-18-5). KOREA-YES, DSL-YES, NDSL-NO, PHIL-YES. FED, STATE & INTERNATION REGS-PART 2. IN GRED: PHOSPHORIC ACID(7664-38-2). CERCLA-5000, RCRA 261.33-NO, TSCA-8(D)-NO. INGRED: WATER(7732-18-5 ). CERCLA-NO, RCRA 261.33-NO, TSCA-8(D)-NO. State Regulatory Information:AUSTRALIAN HAZCHEM CODE: 2R. POISON SCHEDULE S5. WHMIS: THIS MSDS HAS BEEN PREPARED ACCORD TO HAZ CRITERIA OF CONTROLLED PRODS REGS (CPR) & MSDS CNTNS ALL OF INFO REQD BY CPR. OTHER INFO: NFPA RATINGS : HLTH: 3. FLAMM: 0. REACTIVITY:0. LBL HAZ WARNING: DANGER! CORR. CAUSES SEV IRRIT & BURNS TO EVERY AREA OF CONT. HARMFUL IF SWALLOWED/INHALED. LABEL PRECAUTIONS: DO NOT GET IN EYES, ON SKIN/ON CLTHG.KEEP CNTNR CLSD. USE ONLY W/ADEQ VENT. DO NOT BREATH VAP/MIST. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SUPER SHINE CAGE:60930 CAGE:60930 ============= Composition/Information on Ingredients ============= Ingred Name:NAPHTHA, MEDIUM ALIPHATIC CAS:64742-88-7 Fraction by Wt: > 1% Other REC Limits:NONE RECOMMENDED Ingred Name:NON HAZARDOUS INGREDIENTS Fraction by Wt: BALANCE Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT GIVEN Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:THIS IS A SOLVENT PRODUCT WHICH CAN IRRITATE TISSUE. ASPIRATION OF MATERIAL INTO THE LUNGS CAN CAUSE PNEUMONITIS WHIHC CAN BE FATAL. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:SKIN IRRITATION, EYE IRRITATION, CHEMICAL PNEUMONITIS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND QUIET. GET MEDICAL ATTENTION. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION.EYES: FLUSH WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION. IF VOMITING OCCURS, KEEP HEAD BELOW HIPS. ===================== Fire Fighting Measures ===================== Flash Point:140F,60C Lower Limits:1.0 % Upper Limits:NOT GIVEN Extinguishing Media:FOAM, CARBON DIOXIDE, OR DRY CHEMICAL Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND FULL FACE-PIECE SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:VAPOR IS HEAVIER THAN AIR AND MAY TRAVEL ALONG THE GROUND OR BE MOVED BY VENTILATION AND IGNITED BY PILOT LIGHTS. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL FLAMES, PILOT LIGHTS OR IGNITION SOURCES FROM THE AREA AND CONTAIN SPILL WITH SAND, VERMICULITE OR ORGANIC SOLVENTS. PLAC E IN DOT APPROVED CONTAINER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY AREA AWAY FROM INCOMPATIBLE MATERIALS. KEEP CONTAINER TIGHTLY SEALED WHEN NOT IN USE. KEEP OUT OF REACH OF CHILDREN. Other Precautions:WASH CONATMINATED CLOTHING BEFORE REUSE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED WITH GOOD VENTILATION. OTHERWISE USE NIOSH-APPROVED RESPIRATOR FOR ORGANIC SOLVENTS. Ventilation:LOCAL EXHAUST AND MECHANICAL (GENERAL) VENTILATION TO MAINTAIN EXPOSURE LEVELS. Other Protective Equipment:RUBBER APRON AND BOOTS Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT AND BEFORE EATING DRINKING OR SMOKING. Supplemental Safety and Health USE CARE AND COMMON SENSE. ================== Physical/Chemical Properties ================== HCC:V2 Boiling Pt:B.P. Text:355F,179C Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN Vapor Pres:0.5 Vapor Density:5 Spec Gravity:0.850 Evaporation Rate & Reference:0.08 (BUTYL ACETATE = 1) Solubility in Water:INSOLUBLE Appearance and Odor:CLEAR, YELLOW LIQUID DISPERSED IN CARRIER IN AEROSOL CAN, LEMON ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS SUCH AS CHLORINE BLEACH Stability Condition to Avoid:HEAT, FLAMES, SPARKS Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS. ======================================================================
1
eyes_protection_mandatory
======================================================= Product ID: SODIUM HYDROXIDE, PURUM PELLETS, S320-10 Cage: 1B464 Resp. Party Other MSDS No.: 21300 ======================================================= Contractor Summary ======================================================= Cage: 1B464 Cage: SO010 ======================================================= Toxicological Information ======================================================= Toxicological Information: CARCINOGENICITY: SODIUM HYDROXIDE - NOT LISTED BY ACGIH, IARC, NIOSH, NTP OR OSHA. EPIDEMIOLOGY: NO INFO REPORTED. TERATOGENICITY: NO INFO REPORTED. REPRODUCTIVE EFTS: NO INFO REPORTED. NEUROTOXICITY: NO INFO REPORTED. MUTAGENICITY: MUTATION DATA REPORTED. OTHER STUDIES: NO INFO REPORTED. ======================================================= Ecological Information ======================================================= Ecological: ECOTOXICITY: TLM, MOSQUITO FISH, 125 PPM/96HR (FRESH WATER); TLM, BLUEGILL, 88 MG/48HR (TAP WATER). ENVIRONMENTAL FATE: THIS CHEM IS NOT MOBILE IN SOLID FORM, ALTHOUGH IT ABSORBS MOISTURE VERY EASILY. ONCE LIQUID, SODIUM HYDROXIDE LEACHES RAPIDLY INTO THE SOIL, POSSIBLY CONTAMINATING WATER SOURCES. PHYSICAL/CHEMICAL: NO INFO FOUND. OTHER: NO INFO FOUND. ======================================================= ======================================================= Transport Information: US DOT - SHIPPING NAME: SODIUM HYDROXIDE, SOLID. HAZ CLASS: 8. UN NUMBER: UN1823. PACKING GROUP: II. IMO - SHIPPING NAME: SODIUM HYDROXIDE, SOLID. HAZ CLASS: 8. UN NUMBER: 1823. PACKING GROUP: 2. IATA - SHIPPING NAME: SODIUM HYDROXIDE, SOLID. HAZ CLASS: 8. UN NUMBER: 1823. PACKING GROUP: 2. RID/ADR - SHIPPING NAME: SODIUM HYDROXIDE, SOLID. DANGEROUS GOODS CODE: 8(41B). UN NUMBER: 1823. ======================================================= Regulatory Information ======================================================= Sara Title III Information: SECTION 302 (RQ) CAS #1310-73-2: FINAL RQ = 1000 LBS (454 KG). SECTION 302 (TPQ) NONE OF CHEMS IN PROD HAVE TPQ. SARA CODES CAS #1310-73-2: ACUTE, REACTIVE. SECTION 313 NO CHEMS ARE REPORTABLE UNDER S ECTION 313. CLEAN AIR ACT: THIS MATL DOES NOT CNTN ANY HAZ AIR POLLUTANTS. THIS MATL DOES NOT CNTN ANY CLASS 1 OZONE DEPLETORS. THIS MATL DOES NOT CNTN ANY CLASS 2 OZONE DEPLETORS. CLEAR WATER ACT: C AS #1310-73-2 IS LISTED AS HAZ SUBSTANCE UNDER CWA. NONE OF CHEMS IN PROD ARE LISTED AS PRIORITY POLLUTANTS UNDER CWA. NONE OF CHEMS IN PROD ARE LISTED AS TOX POLLUTANTS UNDER CWA. OSHA: NONE OF CHEMS IN PROD CONSIDERED HIGHLY HAZ BY OSHA. Federal Regulatory Information: TSCA CAS #1310-73-2 IS LISTED ON THE TSCA INVENTORY. HEALTH & SAFETY REPORTING LIST: NONE OF THE CHEMICALS IN THIS PRODUCT ARE UNDER A CHEMICAL TEST RULE. SECTION 12B: NONE OF THE CHEMICALS ARE LISTED UNDER TSCA SECTION 12B. TSCA SIGNIFICANT NEW USE RULE: NONE OF THE CHEMICALS IN THIS MATERIAL HAVE A SNUR UNDER TSCA. State Regulatory Information: SODIUM HYDROXIDE CAN BE FOUND ON THE FOLLOWING STATE RIGHT TO KNOW LISTS: CALIFORNIA, NEW JERSEY, FLORIDA, PENNSYLVANIA, MINNESOTA, MASSACHUSETTS. CALIFORNIA NO SIGNIFICANT RISK LEVEL: NONE OF THE CHE MICALS IN THIS PRODUCT ARE LISTED. ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: SODIUM HYDROXIDE, PURUM PELLETS, S320-10 Cage: 1B464 Company Name: FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Street: 1 REAGENT LANE Zipcode: 07410-2802 Label Required IND: Y Date Of Label Review: 06/01/1999 Status Code: A Origination Code: F Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: DANGER Respiratory Protection: YES Health Hazard: Moderate Contact Hazard: Severe Fire Hazard: None Reactivity Hazard: Slight Hazard And Precautions: GENERATES LARGE AMOUNTS OF HEAT WHEN IN CONTACT WITH WATER. ACUTE: EYE: CAUSES SEVERE EYE BURNS. SKIN: CAUSES SKIN BURNS. MAY CAUSE DEEP, PENETRATING ULCERS OF THE SKIN. INGESTION: HARMFUL IF SWALLOWE D. CAUSES GASTROINTESTINAL TRACT BURNS. CAUSES SEVERE PAIN, NAUSEA, VOMITING, DIARRHEA AND SHOCK. INHALATION: IRRITATION MAY LEAD TO CHEMICAL PNEUMONITIS AND PULMONARY EDEMA. CAUSES SEVERE IRRITATION OF UPPER RESPIRATORY TRACT WITH COUGHING, BURNS, BREATHING DIFFICULTY AND POSSIBLE COMA. CHRONIC: PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE DERMATITIS. TARGET ORGANS: NONE. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CPS235101/CPS238049 CHEVRON DELO 400 MULTIGRADE SAE 15W-40 CAGE:81230 CAGE:81230 CAGE:04BH0 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-REFINED HEAVY PARAFFINIC, LUBRICATING OIL BASE STOCK CAS:64741-88-4 RTECS #:PY8040500 Fraction by Wt: <70% OSHA PEL:5 MG/CUM ACGIH TLV:5 MG/CUM Ingred Name:PETROLEUM DISTILLATE - STREIGHT RUN MIDDLE CAS:64741-89-5 RTECS #:PY8041500 Fraction by Wt: <70% Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-REFINED HEAVY NAPHTHENIC DISTILLATE CAS:64741-96-4 RTECS #:PY8040000 Fraction by Wt: <70% Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-REFINE LIGHT NAPHTHENIC CAS:64741-97-5 RTECS #:PY8041000 Fraction by Wt: <70% OSHA PEL:5 MG/CUM (MIST) ACGIH TLV:5 MG/CUM (MIST) Ingred Name:SOLVENT-REFINED RESIDUUM, REFINED PETROLEUM OILS *94-4* CAS:64742-01-4 Fraction by Wt: <70% Ingred Name:PETROLEUM OIL, HYDROTREATED HEAVY NAPHTHENIC DISTILLATE (PETROLEUM), PETROLEUM DISTILLATES, MINERAL OIL (SEVERE) CAS:64742-52-5 RTECS #:PY8035001 Fraction by Wt: <70% Ingred Name:LIGHT NAPHTHALIC DISTILLATE, HYDROTREATED LIGHT NAPHTHENIC DISTILLATE CAS:64742-53-6 RTECS #:PY8036000 Fraction by Wt: <70% Ingred Name:SOLVENT REFINED HYDROTREATED HEAVY PARAFFINIC DISTILLATE, HYDROTREATED HEAVY PARAFFINIC DISTILLATE, LUBRICATING OIL. CAS:64742-54-7 RTECS #:PY8035500 Fraction by Wt: <70% OSHA PEL:5 MG/CUM (MIST) Ingred Name:PETROLEUM HYDROCARBONS, SOLVENT DEWAXED RESIDUAL OIL (PETROLEUM) *94-4* CAS:64742-62-7 Fraction by Wt: <70% Ingred Name:OIL PETROLEUM DISTILLATES, SOLVENT-DEWAXED HEAVY PARAFFINIC CAS:64742-65-0 RTECS #:PY8038500 Fraction by Wt: <70% Other REC Limits:5 MG/CUM Ingred Name:HYDROTREATED C25 BRIGHT STOCK BASED LUBRICATING OIL *94-4* CAS:72623-83-7 Fraction by Wt: <70% Ingred Name:DIALKYL (ALKYL) DITHIOPHOSPHORIC ACID, ZINC SALT *94-4* CAS:68649-42-3 Fraction by Wt: <1.5% Ingred Name:HEXANE, N-HEXANE CAS:110-54-3 RTECS #:MN9275000 Fraction by Wt: <0.1% Other REC Limits:50 PPM OSHA PEL:1800 MG/CUM ACGIH TLV:50 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES/SKIN: IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/FRESH WATER FOR 15 MINS. REMOVE CONTACT LENSES IF WORN. SKIN: WASH THOROUGHLY W/SOAP & WATER. INGESTION: GIVE WATER/MILK TO DRINK. DON'T INDUCE VOMITING W/OUT FIRST CONSULTING MEDICAL PE RSONNEL. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:399F Extinguishing Media:CO2, DRY CHEMICAL, FOAM, WATER FOG. Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS FOR FIRES INVOLVING THIS MATERIAL, WHEN ENTERING ANY ENCLOSED/CONFINED FIRE SPACE. ================== Accidental Release Measures ================== Spill Release Procedures:STOP SOURCE OF LEAK/RELEASE. CLEAN UP AS SOON AS POSSIBLE. CONTAIN LIQUID TO PREVENT FURTHER CONTAMINATION OF SOIL, SURFACE/GROUNDWATER. SMALL: CLEAN UP W/SORBENT MATERIALS/PUMPING. WHERE FEASIBLE & A PPROPRIATE, REMOVE CONTAMINATED SOIL. ======================Handling and Storage ====================== Other Precautions:DON'T WELD/HEAT/DRILL CONTAINER. RESIDUE MAY IGNITE W/EXPLOSIVE VIOLENCE IF HEATED SUFFICIENTLY. DON'T USE PRESSURE TO EMPTY DRUM, MAY RUPTURE W/EXPLOSIVE FORCE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. WEAR APPROVED RESPIRATOR IF OPERATING CONDITIONS CREATE AIRBORNE CONCENTRATIONS WHICH EXCEED RECOMMENDED EXPOSURE STANDARDS. Ventilation:ADEQUATE TO KEEP AIRBORNE CONCENTRATIONS BELOW RECOMMENDED EXPOSURE STANDARDS. Other Protective Equipment:PROTECTIVE CLOTHING. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:0.89 Solubility in Water:INSOLUBLE Appearance and Odor:DARK BROWN LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, CHLORATES, NITRATES, PEROXIDES. Hazardous Decomposition Products:CO, CO2, WATER VAPOR, OXIDES OF SULFUR/NITROGEN/PHOSPHOROUS. ==================== Disposal Considerations ==================== Waste Disposal Methods:PLACE CONTAMINATED MATERIALS IN DISPOSABLE CONTAINERS & DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:PRINT-A-CLEANER CAGE:05685 CAGE:05685 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III) CAS:71-55-6 RTECS #:KJ2975000 Fraction by Wt: > 80% OSHA PEL:350 PPM/450 STEL ACGIH TLV:350 PPM/450STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ozone Depleting Chemical:1 ===================== Hazards Identification ===================== Effects of Overexposure:EYE: IRRIT. SKIN: IRRIT,DEFATTING. ACUTE TOX: CNS DEPRESS;HDCH;LASSITUDE. POSS CARDIAC ARRHYTHMIA. ======================= First Aid Measures ======================= First Aid:NEVER ADMINISTER ADRENALIN TO PERSON EXPOSED TO 1,1,1-TRICHLOROETHANE. INH:REMOVE FROM EXPOS,GIVE ARTIFICIAL RESP IF NECESSARY. CALL PHYSICIAN. SKIN: WASH WITH SOAP AND WATER. EYES: FLUSH WITH WATER F OR 15 MIN.CALL MD. INGEST: INDUCE VOMIT. CALL MD. ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICALS, CO*2, FOAM Fire Fighting Procedures:USE FULL PROTECT CLOTH INCL SELF-CONT BREATHING APPARATUS. Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE HCL & PHOSGENE. ================== Accidental Release Measures ================== Spill Release Procedures:CLEANUP MATERIAL WITH RAGS OR MOP. PLACE RAGS OR MOP IN CLOSED CONTAINERS AND STORE OUTSIDE UNTIL THEY CAN BE PROPERLY DRIED. WEAR ADEQUATE PERSONAL PROTECTIVE EQUIPMENT. REMOVE CONTAMINATED CLOTHING IMMEDIATELY. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP IN COOL. THE DRUM BUNGS SHOULD BE UPRIGHT AND KEPT TIGHTLY CLOSED WHEN NOT IN USE. VENTILATE AREA WELL. DO NOT STORE IN PITS OR DEPRESSIONS. Other Precautions:CONTACT NAVY ENVIRONMENTAL HEALTH CENTER FOR ADDITIONAL INFORMATION. NO SMOKING IN AREA OF USE. DO NOT USE IN VICINITY OF ARC WELDING,OPEN FLAMES, OR HOT SURFACES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPRVD RESP IF REQUIRED. Ventilation:KEEP CONC BELOW TLV. VENT SHOULD ALSO BE PROVIDED AT FLOOR Supplemental Safety and Health PHYSICAL DATA/ VP = 144 MMHG AT 30C; SPECIFIC GRAVITY IS 1.288-1.321 AT 25C. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:158-190F Vapor Density:4.55 Appearance and Odor:CLEAR WITH SLIGHT GREEN TINT ================= Stability and Reactivity Data ================= Hazardous Decomposition Products:HCL, PHOSGENE ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE DISPOSAL METHOD MUST BE IAW FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:17016 ORANGE, I17016 CAGE:DO642 CAGE:DO642 CAGE:09800 ============= Composition/Information on Ingredients ============= Ingred Name:PROPANE. VP: 760.00 CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 14% OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT; 9495 Ingred Name:BUTANE. VP: 760.00 CAS:106-97-8 RTECS #:EJ4200000 Fraction by Wt: 13% OSHA PEL:800 PPM ACGIH TLV:800 PPM; 9495 Ingred Name:BENZENE, ETHYL-; (ETHYL BENZENE) (SARA 313). VP: 7.10 CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 4% OSHA PEL:100 PPM ACGIH TLV:100 PPM/125STEL;9495 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENE (SARA 313) (CERCLA). VP: 180.00 CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 23% OSHA PEL:100 PPM ACGIH TLV:100 PPM/150STEL;9495 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ACETONE (SARA 313) (CERCLA). VP: 180.00 CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 27% OSHA PEL:1000 PPM ACGIH TLV:750PPM/1000STEL;9495 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:WASTE DISP METH:OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS REGARDING POLLUTION. RTECS #:9999999ZZ Ingred Name:OTHER PREC:UNDER PRESS. DO NOT PUNCTURE, INCIN/EXPOSE TO TEMP ABOVE 120F. HEAT FROM SUNLIGHT, RADIATORS, (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:STOVES, HOT WATER, & OTHER HEAT SOURCES COULD CAUSE CNTNR TO BURST. DO NOT TAKE INTERNALLY. INTENTIONAL (ING 9) RTECS #:9999999ZZ Fraction by Wt: M/K Ingred Name:ING 8:MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS CAN BE HARMFUL OR FATAL. RTECS #:9999999ZZ Ingred Name:RESP PROT:APPROVED BY NIOSH FROM DUST WHICH MAY BE GENERATED FROM THIS PRODUCT, UNDERLYING PAINT/THE ABRASIVE. RTECS #:9999999ZZ Ingred Name:VENT:REFER TO OSHA STANDARDS 1910.94, 1910.107, 1910.108. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERVOUS SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCONSCIOUSNESS & POSSIBLY DEATH. SIGNS & SYMPS OF OVEREXP: HDCH, DIZZ, NAUS, & LOSS OF COORDINATION A RE INDICATIONS OF EXCESSIVE EXPOSURE TOVAPS/SPRAY MISTS. REDNESS & ITCHING/BURNING SENSATION (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:MAY INDICATE EYE/EXCESSIVE SKIN EXPOS. CHRONIC:PRLNGD OVEREXP TO SOLV INGREDIENTS IN SECTION 2 MAY CAUSE ADVERSE EFTS TO THE LIVER, URINARY & REPRO SYS. RATS EXPOSED TO TITANIUM DIOXIDE DUST AT 250 MG/M3 DEVELOPED LUNG CANCER, HOWEVER, SUCH EXPOS LEVELS ARE NOT ATTAINABLE IN THE WORKPLACE. RPTS (SUPDAT) Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED. ======================= First Aid Measures ======================= First Aid:INHAL: IF AFFECTED, REMOVE FORM EXPOSURE. RESTORE BREATHING, KEEP WARM & QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE RE-USE. FLUSH EYES W/L ARGE AMOUNTS OF H*2O FOR AT LEAST 15 MIN. GET MED ATTN. INGEST: NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. DO NOT INDUCE VOMIT. GIVE SEVERAL GLASSES OF WATER. SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:<0F,<-18C Lower Limits:1.0% Upper Limits:12.8% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER SPRAY MAY BE INEFT. IF H*2O IS USED, FOG NOZZLES ARE PREF. H*2O MAY BE USED TO COOL CLSD (SUPDAT) Unusual Fire/Explosion Hazard:CNTNRS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. APPLICATION TO HOT SURFS REQS SPECIAL PRECS. DURING EMER CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE A (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME. VAPORS WILL ACCUMULATE READILY & MAY IGNITE EXPLOSIVELY. TURING USE AND UNTIL ALL VAPORS ARE GONE:Other Precautions:KEEP AREA VENT-DO NOT SMOKE-EXTING ALL FLAMES, PILOT LIGHTS, & HEATERS-TURN OFF STOVES, ELECTRIC TOOLS & APPLIANCES, & ANY OTHER SOURCES OF IGNITION. CONSULT NFPA CODE. USE APPRVD BONDING & GROUNDING PROCEDURES. CONTENTS (ING 7) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERS EXPOS CANNOT BE CONTROLLED BELOW APPLIC LIMS BY VENT, WEAR A PROPERLY FITTED ORG VAP/PARTICULATE RESP APPRVD BY NIOSH FOR PROT AGAINST MATLS IN SECTION 2. WHEN SANDING/ADRADING THE DRIED FILM, WEAR A DUST/MIST RESP (ING 10) Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS MATLS IN SECTION 2 IS MAINTAINED BELOW APPLIC EXPOS LIMITS. (ING 11) Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRE FIGHT PROC: CNTNRS TO PVNT PRESS BUILD-UP & POSS AUTOIGNITION/EXPLOSION WHEN EXPOSED TO EXTREME HEAT. FLASH POINT < 0F PROPELLANT. EXPLO HAZ: HLTH HAZ. SYMPS MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN. EFTS OF OVEREXP: HAVE ASSOCIATEDRPTD & PRLNG OVEREXP TO SOLVS W/PERM BRAIN & NERVOUS SYSTEM DAMAGE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:<0F,<-18C Vapor Pres:SEE ING Vapor Density:HVR/AIR Spec Gravity:0.76 Evaporation Rate & Reference:FASTER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:88 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM THIS PROD MAY BE HAZ AS DEFINED UNDER THE RESOURCE CONSERVATION & RECOVERY ACT (RCRA) 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERM THE APPLIC EPA HAZS WASTE NUMBERS. DO NOT I NCIN. DEPRESSURIZE CNTNR. DISPOSE (ING 6)
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:4445 SAVIN 9350 DISPERSANT Preparer's Name:KRISTINA SAGE CAGE:54726 CAGE:7T839 CAGE:54726 CAGE:29382 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROTREATED HEAVY NAPHTHA (ISOPAR) CAS:64742-48-9 Fraction by Wt: >99% Other REC Limits:300 PPM (MFG) Ingred Name:RESIN MALEATED POLYMER Fraction by Wt: <1% Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: EYES: SLIGHT CONJUNCTIVAL IRRITATION. SKIN: MILD IRRITATION WITH EXCESSIVE EXPOSURE. INHALATION: NO UNTOWARD EFFECTS. INGESTION: PRACTICALLY NON-TOXIC. CHRONIC: HEALTH STUDIES HAVE SHOWN THAT M ANY PETROLEUM HYDROCARBONS POSE POTENTIAL HEALTH RISKS WHICH MAY VARY FROM PERSON TO PERSON. Explanation of Carcinogenicity:NONE GIVEN BY MANUFACTURER. Effects of Overexposure:HIGH VAPOR CONCENTRATIONS (GREATER THAN 1000 PPM) ARE IRRITATIVE TO EYES AND RESPIRATORY TRACT, MAY CAUSE HEADACHES AND DIZZINESS, ARE ANESTHETIC AND MAY HAVE OTHER NERVOUS SYSTEM EFFECTS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH LARGE AMOUNTS OF WATER. SKIN: REMOVE ANY CONTAMINATED CLOTHING. WASH AREA WITH SOAP AND WATER. INHALATION: MOVE TO FRESH AIR. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:109F,43C Lower Limits:0.7% Upper Limits:6.5% Extinguishing Media:FOAM, WATER SPRAY, DRY CHEMICALS, OR CARBON DIOXIDE. Fire Fighting Procedures:USE STANDARD FIRE-FIGHTING PROCEDURE FOR PETROLEUM BASED LIQUIDS. USE NIOSH/MSHA APPROVED SCBA FOR ENCLOSED OR CONFINED SPACES. MINIMIZE BREATHING VAPORS/FUMES. Unusual Fire/Explosion Hazard:DO NOT STORE OR MIX WITH STRONG OXIDIZING AGENTS. ================== Accidental Release Measures ================== Spill Release Procedures:SHUT OFF AND ELIMINATE ALL IGNITION SOURCES. RECOVER FREE PRODUCT. APPLY SAND, EARTH, OR OTHER SUITABLE ABSORBENT TO SPILL AREA. COLLECT CONTAMINATED ABSORBENT IN SUITABLE CONTAINERS FOR DISPOSAL.KEEP PRODUCT OUT OF SEWERS AND WATERCOURSESBY DIKING. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, OPEN FLAME AND SPARKS. KEEP OUT OF REACH OF CHILDREN. Other Precautions:EMPTY CONTAINERS RETAIN RESIDUE (LIQUID/VAPOR) AND CAN BE DANGEROUS. TO AVOID THE RISK OF EXPLOSION, DO NOT PUNCTURE, INCINERATE, OR EXPOSE EMPTY CONTAINERS TO HEAT, FLAME, SPARKS, OR OTHER SOURCES OF IGNITION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NEEDED UNDER NORMAL CONDITIONS OF USE. Ventilation:MECHANICAL: GENERAL VENTILATION ADEQUATE. Other Protective Equipment:NONE NEEDED UNDER NORMAL CONDITIONS OF USE. Work Hygienic Practices:WASH AFTER HANDLING AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health MINIMIZE BREATHING VAPOR OR MIST. AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. CLEANSE SKIN THOROUGHLY AFTER CONTACT. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:=161.1C, 322.F B.P. Text:322F,161C Vapor Pres:<10 (@26C) Vapor Density:>5 (AIR=1) Spec Gravity:0.75 (15C) Evaporation Rate & Reference:0.3 (N-BUTYL ACETATE=1) Solubility in Water:NEGLIGIBLE. <0.1% Appearance and Odor:CLEAR WATER WHITE LIQUID, FAINT PETROLEUM HYDROCARBON ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH STRONG OXIDIZERS SUCH HAS LIQUID CHLORINE OR CONCENTRATED OXYGEN. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CARBON MONOXIDE AND OTHER DECOMPOSITION PRODUCTS IN THE CASE OF INCOMPLETE COMBUSTION. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTACT YOUR LOCAL ENVIRONMENTAL OFFICER. DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:KRYLON HIGH HEAT SPRAY PAINT, 1505 WHITE CAGE:EO732 CAGE:EO732 CAGE:87187 ============= Composition/Information on Ingredients ============= Ingred Name:ACETONE (SARA III) CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 37% OSHA PEL:1000PPM ACGIH TLV:750PPM/1000STEL;9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 18% OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT; 9192 Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 36% OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Effects of Overexposure:INHALATION: MAY BE HARMFUL IF INHALED. LIQUID OR VAPOR CAN CAUSE IRRITATION OF NOSE/THROAT/LUNGS. ======================= First Aid Measures ======================= First Aid:INGESTION: IF SWALLOWED, DON'T INDUCE VOMITING. INHALATION: REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. SKIN: FLUSH W/WATER. EYE: FLUSH W/WATER FOR AT LEAST 15 MINUTES. CALL A PHYSICI AN. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE DRY CHEMICAL, FOAM OR CO2, WATER Fire Fighting Procedures:WATER MAY BE INEFFECTIVE. WATER COOL CONTAINERS. Unusual Fire/Explosion Hazard:EXPOSURE TO HIGH TEMP CAUSE BURSTING. DON'T PUNCTURE OR INCINERATE CONTAINER. DON'T SPRAY NEAR FLAME ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. SOAK UP WITH ABSORBENT MATERIAL AND REMOVE TO A CHEMAL DISPOSAL AREA. PREVENT ENTRY INTO NATURAL BODIES OF WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T STORE AT TEMPERATURES >120F. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATORY PROTECTION IF >TLV. Ventilation:PROVIDE VENTILATION TO KEEP BELOW TLV. PREVENT SKIN CONTACT. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Vapor Pres:60 Vapor Density:>AIR Spec Gravity:<WATER Evaporation Rate & Reference:FASTER THAN BU AC Solubility in Water:SLIGHT Appearance and Odor:WHITE Percent Volatiles by Volume:85% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:AVOID RADIATORS/STOVES/DIRECT SUNLIGHT OR OTHER HEAT SOURCE. Hazardous Decomposition Products:CO, CO2. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF ACCORDING TO LOCAL, STATE AND FEDERAL REQUIREMENTS. EMPTY CONTAINER: MAY CONTAIN EXPLOSIVE VAPORS. DON'T CUT, PUNCTURE OR WELD ON OR NEARBY. INCINERATION WILL CAUSE CONTAINER TO BURSTING VI OLENTLY.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:LIQUEFIED PETROLEUM GAS OR PROPANE CAGE:HICKG CAGE:HICKG ============= Composition/Information on Ingredients ============= Ingred Name:AIR OSHA PEL:1000 PPM (MFR) ACGIH TLV:ASPHYXIANT Ingred Name:PROPANE. %:2.15-9.60. CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: SEE ING OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT Ingred Name:OTHER PREC:DANGEROUS. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND/EXPOSE SUCH CNTNRS TO HEAT, (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3:FLAME, SPKS/OTHER SOURCES OF IGNIT; THEY MAY EXPLODE & CAUSE INJURY/DEATH. DO NOT ATTEMPT TO CLEAN SINCE (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4:RESIDUE IS DIFFICULT TO REMOVE. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL:CONCENTRATIONS CAN LEAD TO SYMPTOMS RANGING FROM DIZZINESS TO ANESTHESIA & RESPIRATORY ARREST. EYES:MODERATE IRRITATION. SKIN:CONTACT W/LIQUID CAUSES BURNS SIMILAR TO FROST BITE. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR. GUARD AGAINST SELF INJURY. APPLY ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED. INGEST:CALL MD IMMEDIATELY . EYES:IMMEDIATELY FLUSH W/POTABLE WATER FOR MINIMUM OF 15MINUTES, SEEK ASSISTANCE FROM MD . SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:-156F,-104C Lower Limits:2.15% Upper Limits:9.6% Extinguishing Media:WATER SPRAY - CLASS A, B, C OR BC FIRE EXTINGUISHER. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . STOP FLOW OF GAS. USE H*2O TO KEEP FIRE EXPOSED CNTNRS COOL. USE H*2O SPRAY TO DISPERSE UNIGNITED (SUPDAT) Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:KEEP PUBLIC AWAY. SHUT OFF SUPPLY OF GAS. ELIMINATE SOURCES OF IGNITION. VENTILATE AREA. DISPERSE W/WATER SPRAY. CONTACT BETWEEN SKIN & THESE GASES IN LIQUID FORM CAN CAUSE FREEZING OF TISSUE CAUSINGINJURY SIMILAR TO THERMAL BURN. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CNTNRS AWAY FROM HEAT SOURCES & STORE IN UPRIGHT POSITION. CNTNRS SHOULD NOT BE DROPPED. KEEP CNTNR VALVE CLOSED WHEN NOT IN USE. Other Precautions:INSTALL PROTECTIVE CAPS & PLUG CONTAINER SERVICE VALVE WHEN NOT CONNECTED FOR USE. GENERALLY RECOGNIZED AS SAFE (GRAS) AS DIRECT HUMAN FOOD INGREDIENT WHEN USED AS PROPELLANT, AERATING AGENT & GAS AS DEFINED IN SECTION 170.3(O)(25).(SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:STAY OUT OF GAS OR VAPOR (BECAUSE OF FIRE HAZARD). USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:EXPLOSION-PROOF MOTORS. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health VP:205 PSIG @ 100F. FIRE FIGHT PROC:GAS/VAP. IF IGNIT HAS OCCURRED & NO H*2O AVAIL, TANK METAL MAY WEAKEN FROM OVERHEATING. EVACUATE AREA. IF GAS HAS NOT IGNITED, LP-GAS LIQ/VAP MAY BE DISPERSED BY H* 2O SPRAY/FLOODING. HAZ DECOMP PROD:ENGINE FUEL. OTHER PREC:"EMPTY" CNTNRS RETAIN RESIDUE (LIQ &/OR VAP) & CAN BE (ING 3) ================== Physical/Chemical Properties ================== HCC:G2 Boiling Pt:B.P. Text:-44F,-42C Vapor Pres:SUPP DATA Vapor Density:1.52 Spec Gravity:0.51 (H*2O=1) Evaporation Rate & Reference:GAS @ NORM AMBIENT TEMPS Solubility in Water:SLIGHTLY Appearance and Odor:COLORLESS VAPOR & LIQUID; UNPLEASANT ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MIXING W/OXYGEN OR AIR, EXCEPT AT BURNER. Stability Condition to Avoid:KEEP SOURCES OF IGNITION AT SAFE DISTANCES. Hazardous Decomposition Products:UNDER FIRE CNDTNS:FUMES, SMOKE, CO, ALDEHYDES & OTHER DECOMP PRODS IN CASE OF INCOMPLETE COMBUST/WHEN USED AS (SUPDAT) ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTROLLED BURNING. CONTACT SUPPLIER. DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . ALL CNTNRS SHOULD BE DISPOSED OF IN ENVIRONMENTALLY SAFE MANNER & I/A/W GOVERNMENTAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PREMIUM UNLEADED GASOLINE CAGE:DO839 CAGE:58326 CAGE:DO839 ============= Composition/Information on Ingredients ============= Ingred Name:GASOLINE CAS:8006-61-9 RTECS #:LX3300000 OSHA PEL:300 PPM/500 STEL ACGIH TLV:300 PPM/500STEL;9192 Ingred Name:BENZENE (SARA III) CAS:71-43-2 RTECS #:CY1400000 OSHA PEL:1PPM/5STEL;1910.1028 ACGIH TLV:10 PPM; A2; 9192 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:ETHYL BENZENE (SARA III) CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 2.0% OSHA PEL:100 PPM/125 STEL ACGIH TLV:100 PPM/125STEL 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:CUMENE (SARA III) CAS:98-82-8 RTECS #:GR8575000 Fraction by Wt: 1.0% OSHA PEL:S, 50 PPM ACGIH TLV:S, 50 PPM; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:1,2,4-TRIMETHYLBENZENE (SARA III) CAS:95-63-6 RTECS #:DC3325000 Fraction by Wt: 2.0% OSHA PEL:25 PPM ACGIH TLV:25 PPM; 9192 Ingred Name:METHYL TERT-BUTYL ETHER (SARA III) CAS:1634-04-4 RTECS #:KN5250000 Fraction by Wt: 0-15% EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 15.0% OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENES (O-,M-,P- ISOMERS) (SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 12.0% OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL RAT LD50 18,800 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:PRODUCT IS IRRITATING TO EYES,SKIN,RESPIRATORY TRACT AND DEPRESSES THE CENTRAL NERVOUS SYSTEM DAMAGE. MFR SHOWS "NO" FOR ALL THREE CARCINOGEN LISTS,BUT SHOWS BENZENE AS AN INGREDIENTS. Explanation of Carcinogenicity:CONTAINS BENZENE;LISTED BY ALL THREE. ALSO,AN API STUDY FOUND LIVER CANCER IN MICE EXPOSED TO GASOLINE VAPORS. Effects of Overexposure:EYE/SKIN CONTACT:TRANSITORY IRRITATION. INHALED:RESPIRATORY IRRITATION,CENTRAL NERVOUS SYSTEM DEPRESSION INCLUDING,EUPHORIA,HEADACHE,DIZZINESS,DROWSINESS,FATIGUE,TREMORS,CO NVULSIONS,NAUSEA,VOMITING,DI ARRHEA,LOSS OF CONSCIOUSNESS AND FINALLYDEATH. INGESTED:G/I IRRITATION,PLUS SYMPTOMS SIMILAR TO THOSE UNDER "INHALED". Medical Cond Aggravated by Exposure:PRE-EXISTING EYE,SKIN CONDITIONS OR IMPAIRED LIVER,KIDNEY FUNCTION MAY BE AGGRAVATED BY THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH WITH WATER 15 MIN. SKIN:WASH WITH SOAP & WATER. REMOVE CONTAMINATED CLOTHING;LAUNDER BEFORE REUSE. INHALED:REMOVE TO FRESH AIR.RESUSCITATE OR GIVE OXYGEN AS NEEDED. GET MEDICAL CARE. INGESTE D:GET IMMEDIATE MEDICAL ATTENTION. DO NOT INDUCE VOMITING. IF VOMITING OCCURS,MINIMIZE ASPIRATION HAZARD. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:AS LOW AS -50F Lower Limits:1.3 Upper Limits:7.6 Extinguishing Media:DRY CHEMICAL,CARBON DIOXIDE,FOAM,WATER FOG. WATER MAY BE INEFFECTIVE,AS PRODUCT WILL FLOAT AND MAY SPREAD FIRE. Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS IN ENCLOSED AREAS. WATER SPRAY MAY BE USED TO COOL FIRE EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR,ACCUMULATING IN LOW AREAS,TRAVELING ALONG GROUND AND MAY FLASH BACK FROM DISTANT IGNITION SOURCE. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE IGNITION SOURCES. ISOLATE AREA. USE PROTECTIVE EQUIPMENT AS NECESSARY. STOP LEAK AND CONTAIN SPILL. DIKE AS NEEDED TO KEEP SPILL FROM DRAINS,WATER WAYS,ETC. WATER FOG MAY BE USED TO REDUCE V APORS & PERSONAL HAZARD. REPORT SPILL PER LAW. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,DRY,ISOLATED,WELL VENTILATED AREA. KEEP IGNITION SOURCES AWAY. GROUND CONTAINERS TO PREVENT STATIC DISCHARGE DURING TRANSFERS. Other Precautions:FIRE AND EXPLOSION ARE THE ACUTE HAZARDS OF THIS PRODUCT. TAKE EXTRAORDINARY STEPS TO PREVENT THEM. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF NEEDED,USE NIOSH/MSHA RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE OR PREFERRABLY,A POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR OR SELF CONTAINED BREATHING APPARATUS. Ventilation:USE EXPLOSION PROOF VENTILATION EQUIPMENT TO MAINTAIN EXPOSURE BELOW PEL/TLV. Other Protective Equipment:SAFETY SHOWER/EYE WASH. WORK CLOTHING AS NEEDED TO PROTECT FROM PROLONGED/REPEATED CONTACT. Work Hygienic Practices:USE GGOD CHEMICAL HYGIENE PRACTICE. AVOID UNNECESSARY CONTACT. MINIMIZE ALL CONTACT. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F1 Boiling Pt:B.P. Text:85-437 Vapor Density:3.5 (AIR) Spec Gravity:0.72-0.76 Solubility in Water:NEGLIGIBLE Appearance and Odor:RED LIQUID;GASOLINE ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:HEAT,SPARKS AND OTHER IGNITION SOURCES,VAPOR ACCUMULATIONS. Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE I/A/W FEDERAL,STATE,LOCAL REGULATIONS. PRODUCT QUALIFYS AS IGNITABLE WASTE AND CANNOT BE LANDFILLED. IF RECOVERY OR RECYCLE ARE UNACCEPTABLE, INCINERATION MAY BE ACCEPTABLE DISPOSAL METHOD.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ARC-PREP ELECTRODE 1/8 16140000 Preparer's Name:J MICHAEL COLE CAGE:HO989 CAGE:HO989 CAGE:55649 ============= Composition/Information on Ingredients ============= Ingred Name:IRON OXIDE CAS:1309-37-1 RTECS #:NO7400000 OSHA PEL:10 MG/M3 (FE) ACGIH TLV:5 MG/M3(FE),B2; 9293 Ingred Name:CELLULOSE (PAPER FIBER) CAS:9004-34-6 RTECS #:FJ5691460 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3; 9192 Ingred Name:SILICON CAS:7440-21-3 RTECS #:VW0400000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:BASE METAL CARBONATES Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:IRON CAS:7439-89-6 RTECS #:NO4565500 Fraction by Wt: 5% OSHA PEL:10 MG/M3 TDUST ACGIH TLV:5 MG/M3 Ingred Name:MANGANESE (SARA III) CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: 3.5% OSHA PEL:(C) 5 MG/M3 DUST ACGIH TLV:5 MG/M3 DUST 9293 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: FUMES & GASES CAN BE DANGEROUS TO YOUR HLTH. SHORT TERM OVEREXP TO WELDING FUMES MAY RSLT IN DISCOMFORT SUCH AS: DIZZ, NAUS, OR DRYNESS/IRRIT OF NOSE, THROAT/EYES. CHRONIC: LONG TERM OVEREXP MA Y LEAD TO SIDEROSIS (IRON DEPOSITS IN LUNG) & IS BELIEVED BY SOME INVESTIGATORS TO AFFECT PULM (SEE EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: FUNCTION. ARC RAYS CAN INJURE EYES & BURN SKIN. ELECTRIC SHOCK CAN KILL. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE FROM EXPOS AREA & CALL FOR MED AID. ADMIN RESP IF NO DETECTABLE PULSE. BEGIN EXTERNAL HEART MASSAGE. EMPLOY FIRST AID TECHNIQUES RECOM BY AMERICAN RED CROSS. IN CASE OF ELEC SHOCK TURN O FF POWER PRIOR TO RMOVAL FROM EXPOS AREA & ADMIN FIRST AID. EYE: FLUSH W/H2O FOR AT LEAST 15 MIN. SKIN: REMOVE CONTAM CLTHG. WASH SKIN W/SOAP & H2O. INGEST: DO NOT INDUCE VOMIT. OBTAIN MED ATTN. ===================== Fire Fighting Measures ===================== Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING CONDITIONS . DO NOT USE WATER ON MOLTEN METAL. Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . SEE AMERICAN NATIONAL STD Z49.1 "SAFTEY IN WELDING & CUTTING" PUB BY AMERICAN WELDING SOCIETY,(SUPP DATA) Unusual Fire/Explosion Hazard:NON-FLAMMABLE: WELDING ARC AND SPARK CAN IGNITE COMBUSTIBLES. WATER ON MOLTEN METAL CAN FORM HAZ METAL FUMES. USE H2O TO KEEP METAL COOL IN FIRE SITUATIONS. ================== Accidental Release Measures ================== Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:ARC AND SPARK COULD BE SOURCE OF COMBUSTIBLE PRODUCTS. Other Precautions:FOLLOW ANSI 249.1. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NORMAL NIOSH/MSHA APPROVED RESPIRATORY PROTECTION FOR WELDING. Ventilation:USE ENOUGH VENT, LOCAL EXHST AT ARC/BOTH TO KEEP FUMES & GASES BELOW TLV'S IN WORKER'S BRTHG ZONE & GEN AREA.(SUPP DATA) Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRE FIGHT PROC: AND OSHA PUBLICATION 2206 (29C.F.R.192-1910). VENT: TRAIN WELDER TO KEEP HIS HEAD OUT OF FUMES. HAZ DECOMP PROD: AS COMPLEX CMPDS & NOT METALS. SEE MSDS FOR REASONABLY EXPECTED DECOMP FUMES. ================== Physical/Chemical Properties ================== HCC:N1 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:WHEN ELCTRODE IS CONSUMED,HAZ DECOMP PROD ARE DIFFERENT IN % & FORM FROM INGREDS.COMPONENTS ARE ALWAYS PRESENT (SUP DAT) ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER, OR LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER IN FULL COMPLIANCE WITH FEDERAL, STATE AN D LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:A356.0 ALUMINUM WELDING ALLOYS CAGE:69482 CAGE:69482 ============= Composition/Information on Ingredients ============= Ingred Name:ALUMINUM (SARA 313) CAS:7429-90-5 RTECS #:BD0330000 Fraction by Wt: BALANCE Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 DUST ACGIH TLV:10 MG/M3 DUST; 9495 Ingred Name:COPPER (SARA 313) (CERCLA) CAS:7440-50-8 RTECS #:GL5325000 Fraction by Wt: 0.2% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.1MG/M3 FUME/1 DUST ACGIH TLV:0.2 MG/M3 FUME; 9495 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:IRON CAS:7439-89-6 RTECS #:NO4565500 Fraction by Wt: 0.2% Other REC Limits:NONE RECOMMENDED Ingred Name:MAGNESIUM CAS:7439-95-4 RTECS #:OM2100000 Fraction by Wt: <0.45% Other REC Limits:NONE RECOMMENDED Ingred Name:MANGANESE (SARA 313) CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: 0.1% Other REC Limits:NONE RECOMMENDED OSHA PEL:C 5 MG/M3 DUST ACGIH TLV:5 MG/M3 DUST 9495 Ingred Name:SILICON CAS:7440-21-3 RTECS #:VW0400000 Fraction by Wt: 6.5-7.5% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9495 Ingred Name:TITANIUM CAS:7440-32-6 RTECS #:XR1700000 Fraction by Wt: 0.2% Other REC Limits:NONE RECOMMENDED Ingred Name:ZINC (SARA 313) (CERCLA) CAS:7440-66-6 RTECS #:ZG8600000 Fraction by Wt: 0.1% Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EXPOSURE TO DUSTS, FUMES, GASES FROM WELDING MAY CAUSE LUNG, NOSE, THROAT & EYE IRRITATION; PULMONARY EDEMA, ASPHYXIATION OR DEATH. CHRONIC: PROLONGED OR REPEATED EXPOSURE TO WELDING FUMES, GAS ES, DUSTS MAY CAUSE REDUCED LUNG FUNCTION OR DISEASE; MAY CAUSE RESPIRATORY IRRITATION. Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1% OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN. Effects of Overexposure:WATERY EYES, NOSE & THROAT IRRITATION, HEADACHE, DIZZINESS, DIFFICULTY IN BREATHING, FREQUENT COUGHING, CHEST PAIN, LANQUOR, SLEEPINESS, MUSCULAR WEAKNESS, EMOTIONAL DISTURBANCES AND SPASTIC GAIT. Medical Cond Aggravated by Exposure:INDIVIDUALS WITH ALLERGIES OR IMPAIRED RESPIRATORY FUNCTION MAY HAVE SYMPTOMS WORSENED BY EXPOSURE TO WELDING FUMES. ======================= First Aid Measures ======================= First Aid:IN CASE OF EMERGENCY, CALL FOR MEDICAL ASSISTANCE. EMPLOY FIRST AID TECHNIQUES RECOMMENDED BY RED CROSS. GIVE OXYGEN IF BREATHING DIFFICULT. FOR ELECTRICAL SHOCK; TURN-OFF ELECTRICAL POWER. GIVE ARTIF ICIAL RESPIRATION IF BREATHING STOPPED.IF NO PULSE, BEGIN CPR. IMMEDIATELY CALL FOR MEDICAL ASSISTANCE. FOR ARC BURN; APPLY COLD, CLEAN COMPRESSES AND CALL FOR MEDICAL ASSISTANCE. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. PRODUCT WILL NOT BURN BUT, SPARKS FROM WELDING CAN IGNITE COMBUSTIBLES. Fire Fighting Procedures:NONE SPECIFIED BY MANUFACTURER. Unusual Fire/Explosion Hazard:DAMP ALUMINUM DUST MAY SPONTANEOOUSLY HEAT & LIBERATE HYDROGEN GAS TO FORM EXPLOSIVE AIR MIXTURES.DO NOT USE WATER OR HALOGEN ON DUST FIRES-USE DRY POWDER/SAND. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP OR PICK-UP SPILLED MATERIALS AND PLACE IN A CONTAINER FOR REUSE OR DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NO SPECIAL STORAGE RECOMMENDATIONS. WEAR PROPER PROTECTIVE CLOTHING AS RECOMMENDED IN ANSI Z-49.1. Other Precautions:TRAIN THE WELDER TO NOT TOUCH LIVE ELECTRICAL PARTS AND TO INSULATE HIMSELF FROM WORK AND GROUND. ACIDS AND BASES IN CONTACT WITH ALUMINUM MAY GENERATE EXPLOSIVE MIXTURES WITH HYDROGEN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED RESPIRATOR OR AN AIR-SUPPLIED RESPIRATOR OR SCBA, AS REQUIRED. USE IN ACCORDANCE WITH 29 CFR 1910.13 4 AND MANUFACTURER'S RECOMMENDATIONS. Ventilation:USE ADEQUATE MECHANICAL VENTILATION OR LOCAL EXHAUST AT ARC TO MAINTAIN EXPOSURE BELOW TLV(S). Other Protective Equipment:HARD HAT, DARK SUBSTANTIAL CLOTHES, ARM PROTECTORS, APRONS, SHOULDER PROTECTION. PROTECTIVE SCREENS TO SHIELD OTHERS. Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Appearance and Odor:METALLIC SILVER SOLID; ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ANHYDROUS BROMINE. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:WELDING FUMES & GASES CANNOT BE EASILY CLASSIFIED.COMPOSITION & QUANTITY OF BOTH DEPENDENT ON MATERIAL BEING WELDED. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER OR LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HOME SAFEGUARD,SMOKE DETECTOR TESTER,HOMSA 05/127865 A CAGE:7K472 CAGE:7K472 CAGE:61908 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROCARBON PROPELLANT (PROPANE/ISOBUTANE) CAS:68476-86-8 Fraction by Wt: 98% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS NOT KNOWN. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, RESPIRATORY TRACT. ACUTE- EYES:MAY CAUSE IRRITATION. MAY RESULT IN IRREVERSIBLE DAMAGE. SKIN:UNKNOWN. INHALE:UNKNOWN. ORAL:NOT LIKELY TO OCCUR. CHRONIC- UNKNOWN. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, DISCOMFORT, TEARING, BLURRING OF VISION, HEADACHE, NAUSEA Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING DISEASES OF THE EYE, SKIN, RESPIRATORY TRACT MAY HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES. ======================= First Aid Measures ======================= First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES:FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER. ORAL:SEEK MEDI CAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:FLAMMABL.AEROSOL Autoignition Temp:Autoignition Temp Text:875F Lower Limits:1.8% Upper Limits:9.5% Extinguishing Media:CARBON DIOXIDE, HALON OR DRY CHEMICAL. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:AEROSOL CANS UNDER PRESSURE AND CONTAINS FLAMMABLE GASES. CANS MAY RUPTURE OR EXPLODE. ================== Accidental Release Measures ================== Spill Release Procedures:LEAKING CONTAINERS SHOULD BE PLACED OUTDOORS, IN AN OPEN CONTAINER, AWAY FROM OPEN FLAMES. ALLOW PRESSURE TO DISSIPATE. VENTILATE AREA. ABSORB LIQUID WITH INERT ABSORBENT MATERIALS AND PLACE IN CONTAI NER FOR DISPOSAL. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, VENTILATED AREA AWAY FROM DIRECT SUNLIGHT & STRONG OXIDIZING AGENTS. DO NOT STORE ABOVE 120F. Other Precautions:KEEP THIS AND ALL CHEMICALS OUT OF REACH OF CHILDREN. FOR INDUSTRIAL USE ONLY. AVOID BREATHING VAPORS. AVOID CONTACT WITH EYES AND SKIN. USE WITH ADEQUATE VENTILATION. DO NOT TAKE INTERNALLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED WHERE ADEQUATE VENTILATION CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS HIGH, WEAR A NIOSH-APPROVED ORGANIC VAPOR RESPIRATOR. Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP VAPOR OR MIST LEVELS AS LOW AS POSSIBLE. Other Protective Equipment:APRON AND WORK CLOTHING TO MINIMIZE EXPOSURE. EYE WASH STATION & SAFETY SHOWER RECOMMENDED. Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. WASH AFTER HANDLING AND BEFORE EATING OR DRINKING. Supplemental Safety and Health FORMULA CHANGED. FOR PREVIOUS FORMULATION, SEE PNI A, SAME NSN. ================== Physical/Chemical Properties ================== HCC:V3 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:-44F,-42C Vapor Pres:4379-4896 Vapor Density:1.76 Spec Gravity:0.537 Evaporation Rate & Reference:>1 (N-BUTYL ACETATE=1) Solubility in Water:0.008% @ 70F Appearance and Odor:FINE MIST AEROSOL SPRAY - ESSENTIALLY ODORLESS Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS SUCH AS OXYGEN OR FLUORINE Stability Condition to Avoid:HIGH TEMPERATURES (ABOVE 120F), DIRECT SUNLIGHT, IGNITION SOURCES Hazardous Decomposition Products:MAY FORM CARBON MONOXIDE, CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. DO NOT PUNCTURE OR INCINERATE CONTAINERS. CONTRACT WITH A LICENSED FACILITY CAPABLE OF HANDLING AEROSOLS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:8100700 8100/B700 BASE COMPONENT Kit Part:Y CAGE:83574 CAGE:83574 ============= Composition/Information on Ingredients ============= Ingred Name:TITANIUM DIOXIDE, TITANIUM OXIDE (SUSPECTED ANIMAL CARCINOGEN, IARC GROUP 3)*96-1* CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 30% OSHA PEL:15 MG/CUM ACGIH TLV:10 MG/CUM (DUST) Ingred Name:POLYESTER POLYOL Ingred Name:EPSILON-CAPROLACTONE, PENTAERYTHRITOL POLYMER *96-1* CAS:35484-93-6 Ingred Name:ETHYLENE, TETRAFLUORO- POLYMER (POLYTETRAFLUOROETHYLENE), PTFE, TEFLON CAS:116-14-3 RTECS #:KX4025000 Ingred Name:POLYETHYLENE, POLYETHYLENE RESIN (HOMOPOLYMER); POLYWAX 1000 (CARCINOGEN BY IARC GROUP 3) *96-1* CAS:9002-88-4 RTECS #:TQ3325000 Ingred Name:2-HEPTANONE, METHYL N-AMYL KETONE CAS:110-43-0 RTECS #:MJ5075000 Fraction by Wt: 10% Other REC Limits:50 PPM OSHA PEL:465 MG/CUM ACGIH TLV:233 MG/CUM Ingred Name:METHYL PROPYL KETONE CAS:107-87-9 RTECS #:SA7875000 Fraction by Wt: <5% Other REC Limits:200 PPM OSHA PEL:700 MG/CUM ACGIH TLV:705 MG/CUM Ingred Name:HEXONE, METHYL ISOBUTYL KETONE (MIBK), 4-METHYL-2-PENTANONE CAS:108-10-1 RTECS #:SA9275000 Fraction by Wt: 5% Other REC Limits:50 PPM OSHA PEL:410 MG/CUM ACGIH TLV:205 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TOLUENE (IARC CARC- GROUP 3) *96-1* CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: <1% Other REC Limits:375 MG/CUM OSHA PEL:100 PPM ACGIH TLV:100 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENE, DIMETHYLBENZENE, XYLOL (IARC - GROUP 3) *96-1* CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: <5% Other REC Limits:100 PPM OSHA PEL:100 PPM ACGIH TLV:100 PPM, SKIN EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:XYLENE-SKIN: DERMATITIS. MAY BE ABSORBED. INHALATION: MAY CAUSE LIVER/KIDNEY DAMAGE. INGESTION: IRRITATION OF THE DIGESTIVE TRACT, NERVOUS SYSTEM DEPRESSION. ASPIRATION OF MATERIAL ENTERING LUNGS DURI NG SWALLOWING/VOMITING CAN CAUSE LUNG INFLAMMATION & DAMAGE. Explanation of Carcinogenicity:NONE Effects of Overexposure:XYLENE-BURNING, TEARING, REDDENING, DRYING, CRACKING, DIZZINESS, DROWSINESS, FATIGUE, IRRITATION, LOSS OF COORDINATION. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER. DON'T USE SOLVENTS. INHALATION: REMOVE TO FRESH AIR. GIVE CPR IF NEEDED. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:75F Extinguishing Media:CO2, DRY CHEMICAL/FOAM. Fire Fighting Procedures:WATER SPRAY MAY BE INEFFECTIVE. COOL CONTAINERS W/WATER. FOG NOZZLES ARE PREFERRABLE. WEAR NIOSH/MSHA APPROVED SCBA & PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:VAPORS ACCUMULATE IN INADEQUATELY VENTILATED/CONFINED AREAS, FORM EXPLOSIVE MIXTURES W/AIR, TRAVEL LONG DISTANCE, FLASHBACK/FLAME TO HANDLING SITE. (SEE SUPP) ================== Accidental Release Measures ================== Spill Release Procedures:PROTECT FROM IGNITION. UNVENTILATED AREAS-WEAR AIR-SUPPLIED RESPIRATOR. COVER W/ABSORBENT MATERIAL & SCOOP INTO CONTAINER. CLEAN RESIDUE W/SUITABLE SOLVENT. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. ISOLATE FROM HEAT & OTHER IGNITION SOURCES. DON'T STORE >120F. DON'T CUT, PUNCTURE/WELD ON/NEAR DRUM. Other Precautions:EMPTY DRUMS MAY CONTAIN EXPLOSIVE VAPORS. AVOID SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN SPRAYING/APPLYING & TLVS ARE EXCEEDED, USE AN ORGANIC VAPOR CARTRIDGE/AIR SUPPLIED RESPIRATOR. Ventilation:GENERAL VENTILATION TO MAINTAIN VAPORS BELOW TLV & PEL. Other Protective Equipment:SAFETY SHOWER, EYE BATH, WASHING FACILITIES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:213-300F Vapor Density:>1 Spec Gravity:1.321 VOC Pounds/Gallon:356 Appearance and Odor:GRAY LIQUID W/SOLVENT ODOR. Percent Volatiles by Volume:35.9 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE RECOGNIZED. Stability Condition to Avoid:HEAT, ELECTRICAL EQUIPMENT, SPARKS, FLAME, TEMP >120F. Hazardous Decomposition Products:CO, CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:WHEN DISPOSING, ENSURE THAT IT'S PACKAGED, STORED, TRANSPORTED & OTHERWISE MANAGED IAW/FEDERAL, STATE & LOCAL REGULATIONS. FLAMMABLE LIQUID UN1263. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MAGNESIUM METAL POWDER,37 W 2850 Preparer's Name:MICHAEL RASZEJA CAGE:63759 CAGE:63759 ============= Composition/Information on Ingredients ============= Ingred Name:MAGNESIUM CAS:7439-95-4 RTECS #:OM2100000 Fraction by Wt: 99.8% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 MG/M3 AS MGO FUME ACGIH TLV:10 MG/M3 AS MGO FUME ===================== Hazards Identification ===================== LD50 LC50 Mixture:TLV FOR MAGNESIUM OXIDE FUME: 10 MG/M3 Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, RESPIRATORY TRACT. HEALTH HAZARDS ARE DUE TO DUSTS/FUMES. ACUTE- EYE:MAY CAUSE BURNS. SKIN: PARTICLES OF MAGNESIUM EMBEDED IN SKIN CAN CAUSE LESIONS. INHALE:FUMES MAY CAUSE CH ILLS & METAL FUME FEVER. DUSTS MAY CAUSE IRRITATION. ORAL:UNLIKELY. CHRONIC- UNKNOWN. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, NAUSEA, VOMITING, COUGHING, CHILLS, FEVER, WEAKNESS, MUSCULAR PAIN, EYE BURNS ======================= First Aid Measures ======================= First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES:FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. GET IMMEDIAATE MEDICAL ATTENTION. SKIN:FLUS H THOROUGHLY WITH WATER. ORAL:IF SWALLOWED, IF CONSCIOUS, INDUCE VOMITING & CALL PHYSICIAN. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point:FLAMMABLE SOLID Autoignition Temp:Autoignition Temp Text:950F Lower Limits:NOT RELEVANT Upper Limits:NOT RELEVANT Extinguishing Media:SMOTHER WITH DRY SAND, DRY GRAPHITE, TALC, PURPLE K. DO NOT USE WATER, FOAM, HALOGENATED EXTINGUISHERS/CARBON DIOXIDE. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. WEAR FIRE GLASSES. PREVENT WATER CONTACT WITH MOLTEN MAGNESIUM. Unusual Fire/Explosion Hazard:DUST FORMS EXPLOSIVE MIXTURE WITH AIR. FINE POWDER, THIN SHEETS, CHIPS AND TURNINGS ARE EASILY IGNITED AND BURNS. MOLTEN METAL MAY REACT VIOLENTLY WITH WATER. ================== Accidental Release Measures ================== Spill Release Procedures:USE APPROPRIATE SAFETY EQUIPMENT. CLEAN UP USING NON-SPARKING TOOLS. NO SMOKING/OPEN FLAME. RECOVER FOR USE IF NOT CONTAMINATED. CLEAN, DRY PRODUCT MAY BE RETURNED TO DRY CONTAINER AND SEALED. PLACE C ONTAMINATED SPILL IN VENTED CONTAINER FOR DISPOSAL Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AT ROOM TEMPERATURE IN DRY PLACE, AWAY FROM INCOMPATIBLE MATERIALS. KEEP CONTAINER TIGHTLY CLOSED. GROUND ALL HANDLING & TRANSFERRING OPERATIONS Other Precautions:AVOID CREATING DUSTS. AVOID EYE/SKIN CONTAT. AVOID INHALATION OF DUST/FUME. KEEP OUT OF REACH OF SMALL CHILDREN. STORE AWAY FROM OTHER COMBUSTIBLE MATERIALS. STORAGE IN HIGH HUMIDITY AREA WILL LEAD TO CORROSION OF PRODUCT. FOR LAB USE ONLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. IF DUSTY CONDITIONS PREVAIL, WORK IN VENTILATION HOOD OR WEAR NIOSH-APPROVED DUST RESPIRATOR. Ventilation:ADEQUATE Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, FIRE- RESISTANT CLOTHING AND/OR UNIFORM Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:R2 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:2030F,1110C Melt/Freeze Pt:M.P/F.P Text:1202F,650C Spec Gravity:1.74 Viscosity:NOT RELEVANT Evaporation Rate & Reference:NOT RELEVANT Solubility in Water:NEGLIGIBLE (DECOMP.) Appearance and Odor:SILVERY GRAY METAL POWDER - ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS, ACIDS, WATER, CHLORINE, BROMINE, IODINE Stability Condition to Avoid:HEAT, MOISTURE, SPARKS, FLAME (DANGEROUS WHEN WET). Hazardous Decomposition Products:MAY FORM MAGNESIUM OXIDE. HYDROGEN WILL BE PRODUCED WHEN EXPOSED FOR LONG TIME TO WATER AND ACIDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. DISPOSE OF IN AN APPROVED INCINERATOR OR IN AN APPROVED CHEMICAL LANDFILL OR CONTRACT WITH A LICENSED WASTE DISPOSAL FACILITY.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PH 6.86 BUFFER SOLUTION CAGE:KENST CAGE:KENST ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM MONOHYDROGEN PHOSPHATE (2:1:1); (SODIUM PHOSPHATE) (SARA III) CAS:7558-79-4 RTECS #:WC4500000 Fraction by Wt: 0.5% OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:POTASSIUM PHOSPHATE, MONOBASIC; (POTASSIUM PHOSPHATE) CAS:7778-77-0 Fraction by Wt: 0.5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SODIUM AZIDE (SARA III) CAS:26628-22-8 RTECS #:VY8050000 Fraction by Wt: 0.0002% OSHA PEL:0.1 PPM(HN3), S, C ACGIH TLV:0.11 PPM, C EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 99% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY IRRITATE EYES, SKIN AND RESPIRATORY TRACT. CHRONIC SKIN EXPOSURE MAY CAUSE DERMATITIS. HIGH EXPOSURE TO EYES MAY CAUSE CONJUNCTIVITIS. IF SWALLOWED, MAY CAUSE NAUSEA, VOMITING OR DIARRHEA. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE CONTACT:FLUSH WITH WATER FOR AT LEAST 15 MINUTES. GET MEDICAL HELP IF IRRITATION PERSISTS OR EYES ARE RED. SKIN CONTACT:WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF RASH PERSISTS. INGEST:DRI NK LOTS OF WATER AND INDUCE VOMITING. GET MEDICAL HELP. INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTIFICIAL RESPIRATION) . ===================== Fire Fighting Measures ===================== Extinguishing Media:USE EXTINGUISHING MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NO TOXIC GASES ARE PRODUCED. THERE IS NO FIRE OR EXPLOSION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:IN CASE OF SPILL, FLUSH WITH WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:MINIMIZE INHALATION AND SKIN AND EYE CONTACT. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO RESPIRATORY PROTECTION IS REQUIRED. NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NO SPECIAL VENTILATION IS REQUIRED. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health APPEAR/ODOR:CONSISTS OF 99% OF PRODUCT. ================== Physical/Chemical Properties ================== Evaporation Rate & Reference:NOT KNOWN Solubility in Water:NOT KNOWN Appearance and Odor:THESE BUFFER SOLUTIONS HAVE SAME CHARACTERISTICS AS WATER WHICH (SUPP DATA) ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:WESGO METAL PRODUCTS & ALLOYS NIBSI (AMS-4779) CAGE:WESGO CAGE:WESGO ============= Composition/Information on Ingredients ============= Ingred Name:BORON CAS:7440-42-8 RTECS #:ED7350000 Fraction by Wt: 1.8% Ingred Name:NICKEL (SOLUBLE) INTENDED CHANGE (IC) CAS:7440-02-0 RTECS #:QR5950000 Fraction by Wt: 94.7% Other REC Limits:1 MG/CUM OSHA PEL:1 MG/CUM ACGIH TLV:0.05 MG/CUM IC (A1) Ingred Name:SILICON CAS:7440-21-3 RTECS #:VW0400000 Fraction by Wt: 3.5% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION/DISCOLORATION. SKIN: IRRITATION/ALLERGIC REACTION/RASH/DERMATITIS/DISCOLORATION. INHALATION: NOSE/THROAT IRRITATION/SENSITIZED RESPIRATORY DISEASE/COUGH/SHORTNESS OF BREATH/NERVOUS SY STEM EFFECTS/WALKING/BALANCING DIFFICULTY/WEAKNESS/CRAMPS IN LEGS/HOARSENSS OF VOICE/MEMORY/JUDGMENT TROUBLE. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: BENIGN PNEUMOCONIOSIS CALLED STANNOSIS, MUCOUS MEMBRANE DISCOLORATION, UNSTABLE EMOTIONS, PNEUMONIA-LIKE ILLNESS. COPPER MAY PRODUCE KERATINIZATION OF HANDS/SOLES OF FEET. COBALT MAY PRODU CE PERMANENT DISABILITY OR DEATH. BORONMAY PRODUCE SHOCK/COMA. TITANIUM MAY PRODUCE LUNG FIBROSIS/CHRONIC BRONCHITIS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. SUPPORT RESPIRATION AS NEEDED. SKIN: WASH W/MILD DETERGENT & WATER. EYES: FLUSH W/WATER FOR AT LEAST 15 MINS. INGESTION: OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:DON'T USE WATER USE DRY CHEMICAL, SAND OR OTHER APPROPRIATE EXTINGUISHING AGENT FOR SURROUNDING FIRE Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:MAY OCCUR W/CERTAIN METAL DUST FIRES. ================== Accidental Release Measures ================== Spill Release Procedures:USE NORMAL CLEAN-UP PROCEDURES USING WET SWEEPING OR VACUUM, TAKING CARE TO AVOID EXCESSIVE DUSTING. ======================Handling and Storage ====================== Other Precautions:AVOID DUST INHALATION & CONTACT OF MATERIALS W/EYES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRATOR WHEN AIRBORNE DUST CONCENTRATIONS >PEL/TLV. Ventilation:SUFFICIENT GENERAL & LOCAL EXHAUST TO KEEP <PEL/TLV Other Protective Equipment:EYEWASH FOUNTAIN Work Hygienic Practices:MAINTAIN GOOD HOUSEKEEPING TECHNIQUES SUCH AS WET SWEEPING OR VACUUMING TO REMOVE DUST ACCUMULATION Supplemental Safety and Health ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:842-3272F Spec Gravity:6-9 Solubility in Water:INSOLUBLE Appearance and Odor:SOLID METAL OR POWDER W/NO ODOR Percent Volatiles by Volume:0% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, STRONG OXIDIZERS, STRONG BASES, & MOISTURE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:EVEREADY BATTERY ENERGIZER CAGE:66571 CAGE:66571 ============= Composition/Information on Ingredients ============= Ingred Name:GRAPHITE CAS:7782-42-5 RTECS #:MD9659600 Fraction by Wt: 0-3% Other REC Limits:2.5MG/CUM ACGIH TLV:2 MG/CUM RESP IC Ingred Name:MANGANESE DIOXIDE, MANGANESE PEROXIDE *98-1* CAS:1313-13-9 RTECS #:OP0350000 Fraction by Wt: 0-20% OSHA PEL:5 MG/CUM ACGIH TLV:5 MG/CUM Ingred Name:MERCURY, QUICKSILVER (IARC GROUP 3) *98-1* CAS:7439-97-6 RTECS #:OV4550000 Fraction by Wt: 0.3-1% Other REC Limits:INORGANIC 0.1 MG/CUM ACGIH TLV:0.01 MG/CUM (SKIN) EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:POTASSIUM HYDROXIDE, KOH CAS:1310-58-3 RTECS #:TT2100000 Fraction by Wt: 0-7% Other REC Limits:2 MG/CUM (CEILING) ACGIH TLV:2 MG/CUM (CEILING) EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SILVER OXIDE CAS:20667-12-3 RTECS #:VW4900000 Fraction by Wt: 10-35% Ingred Name:SODIUM HYDROXIDE, CAUSTIC SODA, LYE *98-1* CAS:1310-73-2 RTECS #:WB4900000 Fraction by Wt: 0-7% Other REC Limits:2MG/M3 CEILING NIOSH OSHA PEL:2 MG/CUM ACGIH TLV:2 MG/CUM CEILING EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ZINC *98-1* CAS:7440-66-6 RTECS #:ZG8600000 Fraction by Wt: 6-14% EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INGESTION: CAN BE HARMFUL. OPENED BATTERY CAN CAUSE SERIOUS CHEMICAL BURNS OF MOUTH, ESOPHAGUS & GASTROINTESTINAL TRACT. MAY CAUSE DAMAGE TO LIVER & KIDNEY & CNS DISORDERS. INHALATION: RESPIRATORY IRR ITANT. SKIN: IRRITATION/CHEMICAL BURNS/ABSORPTION. EYES: SEVERE IRRITATION/CHEMICAL BURNS. Explanation of Carcinogenicity:NONE Effects of Overexposure:CHEMICAL BURNS, IRRITATION, ABDOMINAL PAIN, VOMITING, DIARRHEA, ======================= First Aid Measures ======================= First Aid:INGESTION: DON'T INDUCE VOMITING/GIVE FOOD/DRINK. INHALATION: PROVIDE FRESH AIR. SKIN: WASH W/SOAP & WATER. IMMEDIATELY FLUSH THOROUGHLY W/WATER FOR 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE ANY CLASS OF EXTINGUISHING MEDIUM. Fire Fighting Procedures:COOL EXTERIOR OF BATTERIES IF EXPOSED TO FIRE TO PREVENT RUPTURE. WEAR SELF CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:BATTERY CONTAINS MERCURY WHICH PRODUCES HIGHLY TOXIC MERCURY VAPORS UNDER FIRE CONDITIONS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, WELL VENTILATED AREA. ELEVATED TEMPS CAN RESULT IN SHORTENED BATTERY LIFE. KEEP AWAY FROM SMALL CHILDREN. Other Precautions:DON'T OBSTRUCT SAFETY RELEASE VENTS ON BATTERIES. ENCAPSULATION OF BATTERIES WILL NOT ALLOW CELL VENTING & CAN CAUSE HIGH PRESSURE RUPTURE. RECHARGING CAN CAUSE BATTERY LEAKAGE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NECESSARY UNDER NORMAL CONDITIONS. Ventilation:NOT NECESSARY UNDER NORMAL CONDITIONS. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health PROLONGED SHORT CIRCUIT WILL CAUSE THE BATTERY TO LOSE ENERGY & CAN CAUSE THE SAFETY RELEASE VENT TO OPEN. SOURCES OF SHORT CIRCUIT INCLUDE JUMBLED BATTERIES IN BULK CONTAINERS, METAL JEWELRY, METAL C OVERED TABLES/METAL BELTS USED FOR ASSEMBLY OF BATTERIES INTO DEVICES. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:ELEVATED TEMPERATURES, FIRE, RECHARGING, SHORT CIRCUITS, HIGH TEMPERATURES, STATIC SPARKS Hazardous Decomposition Products:HYDROGEN & OXYGEN FROM THE AIR, CAN PRODUCE A COMBUSTIBLE/EXPLOSIVE MIXTURE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DON'T DISPOSE OF IN FIRE/RECHARGE. MAY EXPLODE/LEAK. DISPOSE OF IAW/LOCAL, STATE & FEDERAL REGULATIONS. RCRA AS A D009 (MERCURY) & D011 (SILVER) HAZARDOUS WASTE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:NC-300, NON-BUTYL CLEANER/DEGREASER ALKALINE LIQUID CAGE:0AV13 CAGE:70842 CAGE:050Q3 CAGE:0AV13 CAGE:0ZUM2 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Other REC Limits:NONE RECOMMENDED Ingred Name:SODIUM METASILICATE CAS:6834-92-0 RTECS #:VV9275000 Other REC Limits:NONE RECOMMENDED Ingred Name:OCTYLPHENOXY POLYETHOXYETHANOL CAS:9036-19-5 RTECS #:MD0907600 Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:PRODUCT'S LD50 (ORAL RAT) WAS NOT STATED Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE CONTACT MAY CAUSE BURNS, IRRITATION, REDNESS, TEARING. INGESTION MAY CAUSE IRRITATION. INHALATION MAY CAUSE IRRITATION. REPEATED OR PROLONGED SKIN CONTACT MAY CAUSE IRRITATION. Explanation of Carcinogenicity:MANUFACTURER GAVE NO INFORMATION ABOUT CARCINOGENICITY. HMIS FOUND NO LISTING & DOES NOT EXPECT IT TO BE CARCINOGENIC. Effects of Overexposure:EYE BURNS/IRRITATION/REDNESS/TEARING, SKIN IRRITATION, GASTROINTESTINAL TRACT IRRITATION, RESPIRATORY TRACT IRRITATION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER USING EYECUP OR FOUNTAIN FOR 15 MINUTES. SEEK MEDICAL ATTENTION IF DISCOMFORT PERSISTS. INGESTION: DO NOT INDUCE VOMITING. DRINK 2 LARGE GLASSES OF WATER. SEEK MEDICAL ATTENTION . INHALATION: REMOVE TO FRESH AIR AND REST. SKIN: REMOVE CONTAMINATED CLOTHIGN. WASH WITH SOAP AND WATER. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Autoignition Temp:Autoignition Temp Text:N/A. Lower Limits:NOT GIVEN Upper Limits:NOT GIVEN Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:NONFLAMMABLE. USE STANDARD FIREFIGHTING PROCEDURES FOR SURROUNDING MATERIALS IN THE FIRE. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:STOP SPILL AT SOURCE. COLLECT & REUSE SALVAGEABLE MATERIAL. FLUSH RESIDUE W/LARGE AMOUNTS OF WATER TO SEWER. TREATABLE IN ORDINARY SEWAGE TREATMENT FACILITY. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:HARMFUL IF SWALLOWED. DO NOT GET CONCENTRATE IN EYES. AVOID CONTAMINATION OF FOOD. Other Precautions:KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SPECIFIED BY MANUFACTURER. Ventilation:USE OF MECHANICAL (GENERAL) VENTILATION ACCEPTABLE. Other Protective Equipment:AS NEEDED TO PREVENT WETTING OF CLOTHING. Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NONE Boiling Pt:B.P. Text:212F,100C Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN Decomp Temp:Decomp Text:NOT GIVEN Vapor Pres:NOT GIVEN Vapor Density:<1 Spec Gravity:1.038 Evaporation Rate & Reference:<0.4 BUTYL ACETATE = 1 Solubility in Water:COMPLETE Appearance and Odor:CLEAR GREENISH/YELLOW LIQUID, BLAND ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:FLUSH TO DRAIN W/LARGE AMOUNTS OF WATER IF I/A/W FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TT-P-38LE 7B MED CHROME YELLOW/OIL TP0403 CAGE:DO396 CAGE:33201 CAGE:DO396 ============= Composition/Information on Ingredients ============= Ingred Name:LEAD CHROMATE (OSHA PEL FOR LEAD FROM 29CFR 1910.1025),(CRO3 CEILING 0.1 MG/M3) CAS:7758-97-6 RTECS #:GB2975000 Fraction by Wt: 65% Other REC Limits:0.05MG/CUM ASPB/CR OSHA PEL:0.05 MG/M3 (PB) ACGIH TLV:0.05MG/M3(CR)A2;8990 Ingred Name:MINERAL SPIRITS CAS:64742-88-7 Fraction by Wt: 5% Other REC Limits:100-500 PPM OSHA PEL: ACGIH TLV: ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Explanation of Carcinogenicity:ACGIH:SUSPECTED HUMAN CARCIARC:HUMAN CARC(GROUP 1) NTP:KNOWN TO BE CARCINOGENIC Effects of Overexposure:INHAL:(SOLVENTS)ANESTHETIC IRRIT OF THE RESP TRACT OR ACUTE NERVOUS SYSTEM DEPRESS.CHARACTERIZED BY HEADACHE.DIZZY,STAGGERING GAIT.CONFUSION,UNCONSCIOUSNESS/COMA,(PIGMENT)REPET/PROLONGED EXPOS MAY CAU SE DELAY EFFECTS INVOLV BLOOD, GASTROINTESTINAL, NERVOUS & REPRODUCTIVE SYSTEMS. ======================= First Aid Measures ======================= First Aid:INHA:FUMES,REMOVE FROM EXPOS.RESTORE BREATHING.NOTIFY PHYS.EYE:FLUSH IMMED W/COPIOUS QUANTITIES OF RUNNING H*2O FOR AT LEAST 15 MIN. TAKE TO A PHYSICIAN FOR DEFINITIVE MED.TREATMENT.SKIN:REMOVE W/ SOA P & H*2O.REMOVE CONTAM CLOTHING THERE ARE NO FIRST AID MEASURES FOR LEAD INTOXICATION. ===================== Fire Fighting Measures ===================== Flash Point:104F-40.0C Lower Limits:1.0 Extinguishing Media:CO*2, FOAM, DRY CHEM Fire Fighting Procedures:USE FULL PROTECTIVE EQUIP.INCLUDING SCBA Unusual Fire/Explosion Hazard:KEEP AWAY FROM SOURCES OF IGNITION.CLOSED CONT MAY EXPLOD,EXPOS TO EXTREME HEAT APPLY TO HOT SURFACE,SPEC PRECAUT. LEAD CHROMATFS/ORGANIC COMP MAY CREATE HAZ. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION(FLAMES HOT SURFACES & ELECTRICAL,STATIC OR FRICTIONAL SPARKS.AVOID BREATHING VAPORS VENT AREA REMOVE W/INERT ABSORBENT & NON SPARKING TOOLS ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE ABOVE 120F STORE LG QT IN BUILDINGS DESIGNED FOR STORAGE OF NFPA CLASS 2 FLAMMABLE LIQUIDS. Other Precautions:DO NOT TAKE INTERNALLY CONT SHOULD BE GROUNDED WHEN POURING DO NOT FLAME CUT, BRAZE OR WELD W/OUT NIOSH APPROVED RESP OR APPROPRIATE VENT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:OUTDOOR/OPEN AREAS,NIOSH MECHANICAL FILTER. RESTRICT VENT AREA.NIOSH CHEMICAL/MECHANICAL FILTER TO REMOVE COMBINATION OF PARTICULATE,GAS,VAPOR.CONFINED AREAS.NIOSH APPROVED AIR LINE TYPE RESP OR HOODS Ventilation:PROVIDE GENERAL DILUTION OR LOCAL EXHAUST VENT IN VOL & PATTERN TO KEEP TLV OF MOST HAZ BELOW ACCEPTABLE LIMIT Other Protective Equipment:NONE Supplemental Safety and Health WT/GAL 16.4+-.5LB/GAL. ================== Physical/Chemical Properties ================== HCC:F4 NRC/State Lic Num:NA Boiling Pt:B.P. Text:300-385F Vapor Density:HEAV> AIR Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:6+- ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS Hazardous Decomposition Products:HEATED TO DECOMP AS IN WELDING WILL PRODUCE FUMES CONT OXIDES OF CARBON,LEAD,+CHROMIUM ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW LOCAL,STATE & FEDERAL REGS.DO NOT INCINERATE. PRODUCT MAY REQUIRE SPECIAL HANDLING AS A HAZARDOUS WASTE
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:1311 (CERAMIC R-METAL) SOLIFIER, 1101/0948 Preparer's Name:W FAUPEL CAGE:67020 CAGE:0PX05 CAGE:67020 ============= Composition/Information on Ingredients ============= Ingred Name:DIETHYLENETRIAMINE. LD50:(ORAL,RAT) 1080 MG/KG CAS:111-40-0 RTECS #:IE1225000 Fraction by Wt: 5-10% OSHA PEL:1 PPM ACGIH TLV:S, 1 PPM Ingred Name:TALC (POWDER), CONTAINING NO ASBESTOS FIBERS CAS:14807-96-6 RTECS #:WW2710000 Fraction by Wt: 5-10% OSHA PEL:0.2 FIBERS/CC ACGIH TLV:0.2 FIBER/CC, A1 Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 1-5% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:PHENOL (SARA 302/313) (CERCLA). LD50:(ORAL,RAT) 414 MG/KG CAS:108-95-2 RTECS #:SJ3327000 Fraction by Wt: 1-5% OSHA PEL:S, 5 PPM ACGIH TLV:S, 5 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:PHENOL, 2,4,6-TRIS(DIMETHYLAMINOMETHYL)-; (TRIS- DIMETHYLAMINO-METHYL PHENOL). LD50:(ORAL,RAT) 1637 MG/KG CAS:90-72-2 RTECS #:SN3500000 Fraction by Wt: 1-5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:EYE PROT:& FULL LENGTH FACESHIELD . RTECS #:9999999ZZ Ingred Name:OTHER PROT EQUIP:CONTAMINATION OF FOOTWEAR, SAFETY BOOTS SHOULD BE WORN AND CLEANED THOROUGHLY BEFORE REUSE. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENTS Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: CAUSES BURNS TO SKIN AND EYES. CHRONIC: CHEMICAL BURNS AND SENSITIZATION. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:SKIN AND EYE CONDITIONS. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE SOURCE OF CONTAM AND/OR MOVE VICTIM TO FRESH AIR. IF RECOVERY IS DELAYED/THERE ARE SIGNS OF DISTRESS OBTAIN MED ATTN IMMED. EYE:FLUSH W/WATER FOR @ LST 15 MINS. IMMED FIRST AID IS NEC TO PVNT DMG. SEEK MED ADVICE IF ANY IRRIT PERSISTS. SKIN:IMMED REMOVE EXCESS W/CLEAN CLOTH & WASH SKIN THORO W/SOAP & WATER. IF IRRIT /INFLAMM PERSISTS, SEEK MED ADVICE. INGEST:DO NOT INDUCE (SUPDAT) ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:>212F,>100C Extinguishing Media:WATER FOG (NOT A DIRECT STREAM OF WATER), FOAM, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . USE SAND TO CONTAIN BURNING MATERIAL. Unusual Fire/Explosion Hazard:DECOMPOSITION AND COMBUSTION PRODUCTS MAY BE HAZARDOUS. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB WITH AN INERT MATERIAL (E.G. EARTH OR SAND). SWEEP UP, PLACE INTO SUITABLE LABELLED CONTAINERS, SEAL AND DISPOSE OF PROPERLY. FLUSH AREA WITH DETERGENT AND WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:WHERE MACHINING/ABRADING OF CURED MATL LEAD TO PRODUCTION OF RESPIRABLE &/OR NUISANCE DUST, AN APPROP NIOSH APPRVD RESP SHOULD BE WORN. Other Precautions:AVOID BRTHG VAPS & CONT W/SKIN & EYES. OVERHEATING MAY CAUSE CNTNRS TO RUPTURE. CNTNRS SHOULD BE STORED UNDER COOL, DRY CNDTNS. EMTPY CNTNRS WILL RETAIN RESIDUE & MAY BE DANGEROUS. CHECK ALL CNTNRS FO R LEAKS @ REGULAR INTERVALS & (SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN CONFINED AREAS/WHERE GOOD NATURAL/MECH VENT IS NOT AVAIL, LEADING TO RISK OF EXCEEDING TLV'S INDICATED, AN APPROP NIOSH APPROVED RESPIRATOR SHOULD BE WORN. Ventilation:WHERE ADEQUATE NATURAL VENT IS NOT AVAIL PROVIDE SUITABLE LOCAL EXHAUST VENTILATION. Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . SUITABLE PROTECTIVE CLTHG TO MINIMIZE SKIN CONT. WHERE RISK OF (ING 7) Work Hygienic Practices:WASH HANDS W/SOAP & WATER & USE HAND CREAM. REMOVE CONTAMD CLTHG & WASH BEFORE REUSE. WHEN USING, DO NOT EAT, (SUPDAT) Supplemental Safety and Health FIRST AID PROC:VOMIT. RINSE MOUTH W/WATER & DRINK 1 CUP OF WATER EVERY 10 MINS FOR 30 MINS. CALL TAMPA BAY REGIONAL POIS CTR(TEL. NO.1-800-282-3171) AND/OR SEEK MED ADVICE. OTHER PREC:BEFORE USE. CONTAMD CLTHG & LAUNDER BEFORE REUSE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>347F,>175C Vapor Pres:0.22 @ 25C Vapor Density:HVR/AIR Spec Gravity:1.66 Evaporation Rate & Reference:NOT KNOWN Solubility in Water:SLIGHT (01.-1.0%) Appearance and Odor:LIGHT GRAY PASTE WITH AMMONICAL ODOR. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, ACIDS, EPOXY RESINS AND ISOCYANATES. Stability Condition to Avoid:NOT APPLICABLE. Hazardous Decomposition Products:GASEOUS COMBINATIONS OF CARBON, HYDROGEN, NITROGEN AND OXYGEN MAY OCCUR AT ELEVATED TEMPERATURES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MARINE SPAR VARNISH 149-10 Preparer's Name:THOMAS E. MAREK CAGE:33200 CAGE:33200 ============= Composition/Information on Ingredients ============= Ingred Name:STODDARD SOLVENT; (MINERAL SPIRITS). VP: 2 CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: 49% Other REC Limits:130 PPM (MFR) OSHA PEL:100 PPM ACGIH TLV:100 PPM ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYES: CAN CAUSE SEVERE IRRITATION, REDNESS, TEARING, BLURRED VISON. SKIN: PRLNGD/RPTD CONTACT CAN CAUSE MODERATE IRRITATION, DEFATTING, DERMATITIS. INHAL: EXCESSIVE INHAL OF VAPS CAN CAUSE NASA L AND RESPIRATORY IRRITATION, DIZZINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHE, POSSIBLE UNCON, (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: & EVEN ASPHY. INGEST: CAN CAUSE GI IRRITATION, NAUSEA, VOMITING, AND DIARRHEA. ASPIRATION INTO LUNGS CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. Medical Cond Aggravated by Exposure:NO KNOWN. ======================= First Aid Measures ======================= First Aid:SKIN: THORO WASH EXPOSED AREA W/SOAP & WATER. REMOVE CONTAMD CLTHG. LAUNDER CONTAMD CLTHG BEFORE REUSE. EYES: FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES, LIFTING LIDS OCCAS, GET MED ATT N. INGEST: DO NOT INDUCE VOMIT. KEEP WARM & GET MED ATTN. INHAL: REMOVE TO FRESH AIR. IF BRTHG IS DFCLT, ADMINISTER OXYEN. IF BRTHG HAS STOPPED, APPLY ARTF RESP. KEEP WARM, QUIET & GET MED ATTN. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:108F,42C Lower Limits:0.7% Upper Limits:6% Extinguishing Media:FOAM, DRY CHEMICAL, CARBON DIOXIDE. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:VAPS ARE HVR/AIR & MAY TRAVEL ALONG GROUND/BE MOVED BY VENT & IGNITED BY HEAT PILOT LIGHTS, OTHER FLAMES & IGNIT SOURCES @ LOCATIONS DISTANT FROM HNDLG POINT. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB LIQUID ON PAPER, VERMICULITE, FLOOR ABSORBANT OR OTHER ABSORBANT MATERIAL AND PICK UP WITH SHOVEL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID PROLONGED OR REPEATED SKIN CONTACT. KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES. USE W/ADEQUATE VENTILATION. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR IF TLV IS EXCEEDED. Ventilation:LOCAL EXHAUST AS NEEDED TO REMAIN BELOW PEL. Other Protective Equipment:BARRIER CREAM. EYEWASH FOUNTAIN AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:301F,149C Vapor Pres:SEE INGRED Vapor Density:HVR/AIR Spec Gravity:0.913(H*2O=1) Evaporation Rate & Reference:<1(BUTYL ACETATE=1) Solubility in Water:NONE Appearance and Odor:CLEAR AMBER LIQUID, MILD SOLVENT ODOR Percent Volatiles by Volume:50.5 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:EXCESSIVE HEAT, SPARKS, OPEN FLAME. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY YIELD CARBON DIOXIDE &/OR CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE UNDER SAFE CONDITIONS. DISPOSE OF I/A/W LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:COMPETITVE EDGE HIGH PERFORMANCE WAX STRIPPER CAGE:FO931 CAGE:63180 CAGE:FO931 ============= Composition/Information on Ingredients ============= Ingred Name:POTASSIUM HYDROXIDE (SARA III) CAS:1310-58-3 RTECS #:TT2100000 Fraction by Wt: 5% Other REC Limits:2 MG/CUM (CEILING) OSHA PEL:C, 2 MG/M3 ACGIH TLV:C 2 MG/M3; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHANOLAMINE CAS:141-43-5 RTECS #:KJ5775000 Fraction by Wt: 3% Other REC Limits:3 PPM OSHA PEL:3 PPM/6 STEL ACGIH TLV:3 PPM/6 STEL; 9192 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: INJURY, BURNS, CORROSIVE. SKIN: SEVERE IRRITATION & CORROSIVE. INHALATION: UPPER RESPIRATORY TRACT IRRITATION. INGESTION: NAUSEA, VOMITING & ABDOMINAL PAIN. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES: INJURY, BURNS & CORROSIVE. SKIN: SEVERE IRRITATION & CORROSIVE. INHALATION: UPPER RESPIRTORY TRACT IRRITATION. INGESTION: NAUSEA, VOMITING & ABDOMINAL PAIN. Medical Cond Aggravated by Exposure:ASTHMATIC CONDITIONS ======================= First Aid Measures ======================= First Aid:EYES: REMOVE CONTACT LENSES. FLUSH W/WATER FOR 15 MIN. SKIN: WASH W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR, GIVE OXYGEN IF BREATHING DIFFICULTY. INGESTION: DRINK PLENTY OF LIQUID (WATER) TO DIL UTE. DON'T INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:>200F Extinguishing Media:WATER SPRAY, CO2, DRY CHEMICAL OR UNIVERSAL-TYPE FOAM Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & FULL PROTECTIVE CLOTHING. COOL FIRE-EXPOSED CONTAINERS W/WATER. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS EXPOSED TO SOURCES OF INTENSE HEAT MAY EXPLODE FROM INTERNAL PRESSURE BUILDUP. ================== Accidental Release Measures ================== Spill Release Procedures:CONFINE THE SPILL & REMOVE THE LIQUID W/VACUUM TRUCK OR FLUSH INTO THE CHEMICAL SEWER W/LARGE QUANTITIES OF WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY LOCATION IN TIGHTLY CLOSED CONTAINERS. USE W/ADEQUATE VENTILATION. KEEP OUT OF THE REACH OF CHILDREN. Other Precautions:AVOID CONTACT W/EYES, SKIN & CLOTHING. ============= Exposure Controls/Personal Protection ============= Ventilation:PROVIDE ADEQUATE VENTILATION Other Protective Equipment:PROTECTIVE CLOTHING, EYEWASH STATION & SAFETY SHOWER Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH HANDS BEFORE EATING/DRINKING OR USING TOILET FACILITIES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:1.07 pH:13.1 Solubility in Water:COMPLETE Appearance and Odor:CLEAR, PINK/ROSE, WATER-TYPE LIQUID W/CITRUS FRAGRANCE Percent Volatiles by Volume:87% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG, CONCENTRATED ACIDS, STRONG OXIDIZING AGENTS & SUBSTANCES WHICH REACT VIGOROUSLY W/WATER Stability Condition to Avoid:HEAT Hazardous Decomposition Products:CO, CO2, OXIDES OF NITROGEN, AMMONIA, UNIDENTIFIED ORGANIC COMPOUNDS ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:42376 DILUENT FOR URIC ACID Kit Part:Y CAGE:1Z582 CAGE:1Z582 CAGE:66002 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL PARAHYDROXYBENZOATE, METHYLPARABEN CAS:99-76-3 RTECS #:DH2450000 Fraction by Wt: 0.1% Ingred Name:BENZOIC ACID, 4-HYDROXY-, PROPYL ESTER, PROPYLPARABEN CAS:94-13-3 RTECS #:DH2800000 Fraction by Wt: 0.02% Ingred Name:GAMMA-GLOBULINS CAS:9007-83-4 RTECS #:LZ3450000 Fraction by Wt: 0.01% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: DIRECT CONTACT MAY CAUSE IRRITATION. CONTACT W/SOLUTIONS CONTAINING BOVINE GAMMA GLOBALIN, METHYL PRABEN & PROPYL PARABEN MAY CAUSE ALLERGIC REACTIONS IN RARE INSTANCES. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION Medical Cond Aggravated by Exposure:INDIVIDUALS W/HYPERSENSITIVITY TO BOVINE GAMMA GLOBULIN & PARABENS, METHYLPARABEN & PROPYLPARABEN. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER. SKIN: FLUSH W/PLENTY OF WATER & WASH W/SOAP & WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:AS APPROPRIATE FOR FIRE IN SURROUNDING MATERIALS. Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS & FULL PROTECTIVE CLOTHING. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB W/ABSORBENT MATERIAL. PLACE ABSORBENTS INTO SUITABLE LABELED CONTAINER. WASH AREA W/SOAPY WATER & FLUSH WASH TO SEWER W/PLENTY OF WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP REAGENT BOTTLE CLOSED WHEN NOT IN USE. Other Precautions:FOLLOW GOOD/SAFE LABORATORY PRACTICES & PROCEDURES. AVOID CONTACT W/EYES & SKIN. DON'T EAT/DRINK/SMOKE WHERE KIT REAGENTS ARE HANDLED. DON'T PIPET BY MOUTH, USE MECHANICAL PIPETTING DEVICE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED IF USED ACCORDINGLY. Ventilation:MECHANICAL (GENERAL): RECOMMENDED. Other Protective Equipment:LAB COAT. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health NOTE: PHYSICAL & HEALTH HAZARD INFORMATION ON REAGENT MIXTURES HAVE NOT BEEN DTERMINED. ALL PHYSICAL & HEALTH EFFECTS NOTED ARE BASED ON EXTRAPOLATION OF DATA FROM THE PURE INGREDIENTS. ================== Physical/Chemical Properties ================== Solubility in Water:COMPLETE Appearance and Odor:CLEAR, COLORLESS TO PALE BLUE SOLUTION. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY EMIT TOXIC PRODUCTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:LANDFILL/INCINERATE IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:54K13 LVP ELECTRIC BLUE METALLIC EN CAGE:51716 CAGE:51716 ============= Composition/Information on Ingredients ============= Ingred Name:XYLENE CAS:1330-20-7 RTECS #:ZE2100000 < Wt:25. OSHA PEL:100 PPM ACGIH TLV:434 MG/M3;100 PPM ACGIH STEL:651 MG/M3;150 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ACETONE CAS:67-64-1 RTECS #:AL3150000 < Wt:10. OSHA PEL:2400 MG/M3;1000 PPM ACGIH TLV:1780 MG/M3;750 PPM ACGIH STEL:2380 MG/M3;1000 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHYL BENZENE CAS:100-41-4 RTECS #:DA0700000 < Wt:5. OSHA PEL:435 MG/M3;100 PPM ACGIH TLV:434 MG/M3;100 PPM ACGIH STEL:543 MG/M3;125 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:2-BUTANONE CAS:78-93-3 RTECS #:EL6475000 < Wt:5. OSHA PEL:590 MG/M3;200 PPM ACGIH TLV:590 MG/M3;200 PPM ACGIH STEL:885 MG/M3;300 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:N-BUTANOL CAS:71-36-3 RTECS #:EO1400000 < Wt:1. OSHA PEL:300 MG/M3;100 PPM ACGIH STEL:C152 MG/M3;C50 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:HYDROCARBON MIXTURE CAS:64742-89-8 < Wt:1. Ingred Name:PETROLEUM DISTILLATE CAS:8052-41-3 RTECS #:WJ8925000 < Wt:1. OSHA PEL:2900 MG/M3;500 PPM ACGIH TLV:525 MG/M3;100 PPM Ingred Name:ZIRCONIUM SALT OF AN ORGANIC ACID CAS:22464-99-9 < Wt:.1 Ingred Name:COBALT SALT SOLUTION CAS:61789-51-3 RTECS #:QK8925000 < Wt:.1 Ingred Name:METHYL CARBITAL CAS:111-77-3 RTECS #:KL6125000 < Wt:.1 ===================== Hazards Identification ===================== Health Hazards Acute and Chronic:EYES: SEVERE IRRITATION, MAY INJURE EYE TISSUE RESULTING IN PERMANENT DAMAGE. SKIN: PROLONGED/REPEATED CONTACT CAN RESULT IN DERMATITIS. INHALATION: REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS MAY CAU SE BRAIN & NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY INHALING THE CONTENTS MAY BE HARMFUL. INGESTION: THIS MATERIAL MAY BE HARMFUL/FATAL IF SWALLOWED. Effects of Overexposure:IRRITATION, PAIN, TEARING, REDDENING, SWELLING, STINGING SENSATION, DEFATTING/DRYING OF SKIN, RASH ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH W/PLENTY OF WATER. SKIN: WASH W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NECESSARY. INGESTION: INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MEDICAL PERSO NNEL. NEVER GIVE ANYTHING BY MOUTH IF UNCONSCIOUS. ASPIRATION HAZARD IF SWALLOWED. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:=-17.2C, 1.F Lower Limits:1 Upper Limits:12.8 Extinguishing Media:CO2, DRY CHEMICAL, FOAM, WATER FOG Fire Fighting Procedures:USE SCBA PRESSURE-DEMAND NIOSH/MSHA APPROVED & FULL PROTECTIVE GEAR. WATER RUNOFF CAN CAUSE ENVIRONMENTAL DAMAGE. DIKE, COLLECT WATER USED TO FIGHT FIRES. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE; DANG EROUS. EMPTY DRUMS SHOULD BE COMPLETELY DRAINED, PROPERLY BUNGED, PROMTLY RETURNED TO A DRUM RECONDITIONER/DISPOSED OF. Unusual Fire/Explosion Hazard:VAPORS MAY FORM EXPLOSIVE MIXTURE W/AIR. VAPORS CAN TRAVEL TO A SOURCE OF IGNITION & FLASHBACK. MATERIAL WILL READILY IGNITE AT ROOM TEMPERATURE. DON'T PRESSURIZE/CUT/WELD/BRAZE/SOLDER/DRILL/GRIND/EXP OSE CONTAINERS TO HEAT/FLAME/SPARKS/STATIC ELECTRICITY/ANY OTHER IGNITION SOURCE. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB W/INERT MATERIAL; DRYS AND/EARTH, THEN PLACE IN A CHEMICAL WASTE CONTAINER. AVOID RUNOFF INTO STORM SEWERS, DITCHES, WATERWAYS. WEAR A SELF CONTAINED BREATHING APPARATUS & APPROPRIATE PROTECTIV E EQUIPMENT. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS & FLAME. KEEP CONTAINER CLOSED WHEN NOT IN USE. PRODUCT IS TO BE USED FOR INDUSTRIAL/PROFESSIONAL USES ONLY & APPLIED ONLY BY THOSE TRAINED IN ITS SAFE & PROPER APPLICATION . Other Precautions:WHEN TRANFERRING MATERIAL, GROUND & BOND CONTAINERS & USE SPARK PROOF TOOLS & EXPLOSION PROOF EQUIPMENT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE A NIOSH/MSHA APPROVED AIR PURIFYING RESPIRATOR W/AN ORGANIC VAPOR CARTRIDGE/CANISTER WHERE AIRBORNE CONCENTRATIONS EXCEED EXPOSURE LIMITS. USE A POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR FOR UNCON TROLLED RELEASES, EXPOSURE LEVELS UNKNOWN/WHERE AIR PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE PROTECTION. Ventilation:SUFFICIENT TO KEEP AIR CONTAMINATION BELOW CURRENT OSHA PEL/ACGHI'S TLV LIMIT. GENERAL: TO CONTROL AIRBORNE LEVELS. LOCAL EXHAUST: TO CONTROL AIR CONTAMINANTS. Other Protective Equipment:CHEMICAL SUIT, RUBBER BOOTS, Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health FIRE HAZ: IGNITION SOURCES MAY CAUSE CONTAINERS TO EXPLODE & CAUSE INJURY/DEATH. ================== Physical/Chemical Properties ================== Boiling Pt:=141.1C, 286.F B.P. Text:133-286F Vapor Density:>1 Spec Gravity:0.9654 pH:0.0 Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:INSOLUBLE Appearance and Odor:BLUE W/SOLVENT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAMES, =================== Toxicological Information=================== Toxicological Information:NO PRODUCT/COMPONENT TOXICOLOGICAL INFORMATION AVAILABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:NO TRANSPORTATION INFORMATION AVAILABLE. ===================== Regulatory Information ===================== SARA Title III Information:CERCLA-SARA HAZARD CATEGORY: THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA HAZARD CATEGORIES UNDER SECTION 311, 312 OF THE SUPERFUND AMENDMENT & REAUTHORIZATION ACT OF 1986 (SARA TITLE III. Federal Regulatory Information:OSHA: HAZARDOUS BY DEFINITION OF HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200). ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PURE TUNGSTEN WELDING ELECTRODES CAGE:76254 CAGE:76254 ============= Composition/Information on Ingredients ============= Ingred Name:ING 4:SUCH AS PHOSGENE (TLV 0.1 PPM) EVEN IN THE CHLORINATED HYDROCARB SOLV CONC IS BELOW ITS TLV. THE LIGHT (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:FROM THE ARC/ARC ITSELF, CAN PRDCE OZONE, (TLV 0.1 PPM), OXIDES THE NITROGEN (TWA 3 PPM W/5 PPM CEILING) (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:& CO (TLV 50 PPM), ALL OF WHICH ARE HAZ. RTECS #:9999999ZZ Ingred Name:RESP PROT:AIR RESP; FOR TUNGSTEN & ZIRCONATED TUNGSTEN ELECTRODES USE DUST RESP. THE RESP SELECTED WILL DEPEND (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:UPON THE CONC. USE ONLY NIOSH/MSHA APPRVD RESP I/A/W 29CFR1910.134. RTECS #:9999999ZZ Ingred Name:VENT:ANSIZ49.1 SFTY IN WELDING & CUTTING. CONFINED SPACES REQUIRE SPEC ATTN TO PROVIDE ADEQUATE VENTILATION. RTECS #:9999999ZZ Ingred Name:EYE PROT:LENS SHADE IS REQD WHILE WELDING. SELECT WELDING LENS SHADE FROM AWS PUBLICATION F2.2 SFTY GLASSES OR (ING 12) RTECS #:9999999ZZ RTECS #:9999999ZZ Ingred Name:TUNGSTEN CAS:7440-33-7 RTECS #:YO7175000 Fraction by Wt: >99.9% OSHA PEL:5 MG/M3; 10 STEL ACGIH TLV:5 MG/M3; 10 STEL Ingred Name:EFTS OF OVEREXP:POLISHING OPERATION, EXPOS IN EXCESS OF THE NRC LIMITS MAY INCR RISK/LUNG CANCER. THE LIGHT FROM (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2:THE ARC CAN CAUSE EYE DAM, INFLAM OF THE MUC MEMB COVERING THE EYE/EYELIDS (FLASH BURN) & SKIN DAM. THE (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3:LIGHT FROM THE ARC/ARC ITSELF, CAN DECOMPOSE CHLORINATED HYDROCARB SOLV INTO DANGEROUS CONC OF TOX GASES (ING 5) RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:FUMES & GASES FROM WELDING & HIGH TEMP CUTTING WILL DEPEND UPON COMPOSITION OF METAL BEING WELDED, PROCESS PROCEDURES, ELECTRODE USED, COATING (SUCH AS LEAD BASED PAINT), FILLER METAL & FLUX BEING USE D & OTHER FACTORS. THE FUMES MAY INCL OXIDES, CHROMITES, FLUORIDES & OTHER HAZ MATLS. INHAL OF (SEE EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:TUNGSTEN DUST, FUME OR MIST MAY OR MAY NOT CAUSE TRANSIENT OR PERMANENT LUNG DAMAGE. THE SKIN MAY BE IRRITATED BY DUST, FUME OR MIST CONTAINING TUNGSTEN. ELEC SHOCK CAN KILL. NO INHALATION HA ZARD IS POSSIBLE FROM SOLID, FORMED PARTS. IF POWDER OR DUST MAY BE GENERATED, AS FROM MACHINING OR (SEE INGRED 2) Medical Cond Aggravated by Exposure:CHRONIC RESPIRATORY DISEASE & ASTHMA MAY BE AGGRAVATED BY EXPOS TO DUST, FUME OR MIST. OTHER CNDTNS THAT MAY BE AGGRAVATED ARE NOT KNOWN & WILL DEPEND UPON CNDTNS DURING ELECTRODE USE. ======================= First Aid Measures ======================= First Aid:SKIN:WASH AREA OF CONTACT W/SOAP & WATER. IF IRRITATION OR RASH OCCURS, SEEK MD. EYE:WASH W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINS. IF IRRITATION OCCURS, SEEK MD. INHAL:REMOVE FROM EXPOSURE. SEEK MD. IF NECESSARY AID BREATHING. INGEST:SEEK MD. OTHER:WOUNDS CONTAMINATED W/DUST, FUME OR MIST SHOULD BE IMMEDIATELY & THOROUGHLY CLEANED. ===================== Fire Fighting Measures ===================== Extinguishing Media:FOR THE SURROUNDING FIRE. FOR TUNGSTEN DUST FIRES USE CLASS D EXTINGUISHING MEDIA, DRY POWDERS. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . FOR A TUNGSTEN FIRE CONFINED TO A SMALL AREA, USE A NIOSH/MSHA APPRVD RESP FOR TOX DUST & FUMES. Unusual Fire/Explosion Hazard:WHEN TUNGSTEN IS HEATED IN AIR, TUNGSTEN TRIOXIDE (TWA 5 MG(ASW)/M3) BEGINS TO SUBLIME ABOVE 750C. THESE WELDING ELECTRODES DO NOT READILY BURN. (SEE SUPP DATA) ================== Accidental Release Measures ================== Spill Release Procedures:DISPOSE OF THE MATERIAL FOLLOWING ALL APPLICABLE REGULATIONS. TUNGSTEN SCRAP & DUST HAVE VALUE & CAN BE RECLAIMED. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:MAINTIAN GOOD HOUSEKEEPING PROCEDURES TO PREVENT DUST ACCUMULATION FROM GRINDING, ETC. Other Precautions:FOLLOW ALL PROCEDURES IN ANSIZ49.1 & OSHA 29CFR1910. PERIODIC MECIAL EXAMINATIONS ARE RECOM FOR INDIVIDUALS REGULARLY EXPOSED TO DUST OR FUME. NOTE:TUNGSTEN, THORIUM OXIDE & ZIRCONIUM OXIDE WERE REPOR TED IN THE EPA TSCA INVENTORY, 1980. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NEEDED FOR ELECTRODES AS RECD. REQD DURING GRINDING (DRESSING ELECTRODE) OR WELDING, IF THE LIMITS ARE EXCEEDED. FOR THORIATED ELECTRODES USE A DUST MASK (FOR RADIONUCLIDE PARTICLES), SPEC CANIST ER GAS MASK OR SUPPLIED (SEE INGRED 8) Ventilation:LOC VENT IS RECOM FOR DRESSING THE ELCTRODES. FOR WELDING FOLLOW THE OSHA REQUIREMENTS 29CFR1910 & (SEE INGRED 10) Other Protective Equipment:WHEN WELDING, WEAR FLAME RETARDANT CLOTHING SUCH THAT SKIN IS NOT EXPOSED. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EXPLO HAZ:FOR ORDINARY CONDITIONS THEY CAN BE CONSIDERED NON-FLAMMABLE. HOWEVER, WELDING ARCS & SPARKS CAN IGNITE FLAMMABLE LIQUIDS, VAPORS & COMBUSTIBLE SOLIDS. TUNGSTEN DUST (FROM GRINDING, FOR EG) MAY PRESENT A MODERATE FIRE HAZARD IF ALLOWED TO ACCUMULATE. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:10652F Melt/Freeze Pt:M.P/F.P Text:6152F,3400C Spec Gravity:19 Solubility in Water:INSOLUBLE Appearance and Odor:TIN-WHITE METAL; NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID STRONG ACIDS, BROMINE TRIFLUORIDE, FLUORINE, IODINE PENTAFLUORIDE & MIXING LEAD OXIDE W/TUNGSTEN DUST. Stability Condition to Avoid:THE ALLOYS ARE CHEMICALLY STABLE. AVOID OXIDIZERS ESPECIALLY AT ELEVATED TEMPERATURES. Hazardous Decomposition Products:NONE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:1055 MODIFIED VINYL ACETATE WATER BASED Preparer's Name:STEVE BASCH CAGE:TITAN CAGE:33150 CAGE:TITAN ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE VINYL ACETATE CAS:24937-78-8 Other REC Limits:NONE SPECIFIED Ingred Name:PROPRIETARY (NJEIN 36288800-5107P) Other REC Limits:NONE SPECIFIED Ingred Name:VINYL ACETATE (SARA III) CAS:108-05-4 RTECS #:AK0875000 Other REC Limits:NONE SPECIFIED OSHA PEL:10 PPM/15 STEL ACGIH TLV:10 PPM/15,A3 STEL;93 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:PROPRIETARY (NJEIN 36088800-5047P) Other REC Limits:NONE SPECIFIED OSHA PEL:1 PPM ACGIH TLV:1 PPM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION:MAY CAUSE SLIGHT IRRITATION TO NASAL TRACT. INGESTION: NOT PROBABLE OR LIKELY. EYES MAY CAUSE SLIGHT IRRITATION. SKIN: MAY CAUSE SLIGHT IRRITATION. Explanation of Carcinogenicity:HAS NOT BEEN IDENTIFIED AS A CARCINOGEN OR PROBABLE CARCINOGEN BY NTP, IARC OR OSHA. ======================= First Aid Measures ======================= First Aid:EYES: IRRIGATE IMMEDIATELY WITH WATER FOR AT LEAST 15 MINUTES. SKIN: WASH OFF IN FLOWING WATER. WASH CONTAMINATED CLOTHING BEFORE REUSE. INGESTION: DRINK WATER AND/OR MILK. DO INDUCE VOMITING. CALL A PHYSICIAN AND/OR TRANSPORT TO EMERGENCYFACILITY IF REQUIRED. INHALATION: REMOVE TO FRESH AIR AND IF SYMPTOMS OF OVER EXPOSURE DEVELOP SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:LIQUID WILL NOT BURN. DRY FILM CAN BURN. EXTINGUISH WITH WATER, FOAM, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS WHEN EXTINGUISHING FIRE. Unusual Fire/Explosion Hazard:MATERIAL MAY SPLATTER OVER 212 F. ================== Accidental Release Measures ================== Spill Release Procedures:SHOVEL OR CLEAN UP SPILLED MATERIAL WITH SUITABLE ABSORBENT AND PLACE IN AN APPROVED CONTAINER. LET FILM DRY AND THEN SCRAPE UP. ======================Handling and Storage ====================== Handling and Storage Precautions:FOR BEST RESULTS OF PRODUCT STORE AT TEMPERATURES BETWEEN 50 AND 90 F. Other Precautions:KEEP FROM FREEZING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED. Ventilation:LOCAL EXHAUST WITH MECHANICAL ASSISTANCE IF REQUIRED. Other Protective Equipment:NO SPECIAL CLOTHING REQUIRED. Work Hygienic Practices:GOOD HOUSEKEEPING PRACTICES ARE IMPORTANT. WASH THOROUGHLY AFTER USING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:212F,100C Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C Vapor Pres:18 @ 20 C Vapor Density:>1 Spec Gravity:9.0 LBS/GL pH:5-6 Viscosity:3000 CPS Evaporation Rate & Reference:1 (WATER=1) Solubility in Water:MISCIBLE Appearance and Odor:MOBILE WHITE LIQUID WITH SWEET ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY RELEASE CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL OF CONTENTS AND/OR CONTAINER SHOULD COMPLY WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GALXYL C Preparer's Name:DR. F. CIACCI CAGE:OOO26 CAGE:OOO26 ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS FOR INGREDIENTS ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:EYES/SKIN: WASH THOROUGHLY W/PLENTY OF WATER. ===================== Fire Fighting Measures ===================== Extinguishing Media:CO2, FOAM & WATER Fire Fighting Procedures:USE SELF-CONTAINED BREATHING EQUIPMENT IS SUGGESTED. Unusual Fire/Explosion Hazard:DUST DISPERSION IN AIR MUST BE AVOID. ================== Accidental Release Measures ================== Spill Release Procedures:USE VACUUM CLEANER ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID FORMATION OF DUST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:CHEMICAL CARTRIDGE RESPIRATOR/SUPPLIED AIR RESPIRATOR. Ventilation:MECHANICAL: SUGGESTED Other Protective Equipment:EYE BATH & SAFETY SHOWER. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:160F Vapor Pres:23 Spec Gravity:1.34 Solubility in Water:<0.001% Appearance and Odor:WHITE GRANULAR SOLID, SLIGHT AROMATIC ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE EXPECTED Stability Condition to Avoid:NONE Hazardous Decomposition Products:HYDROGEN CHLORIDE, CO, CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:BURY IN CONTROLLED LANDFILL - DON'T INCINERATE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ORTHO LEAF POLISH (AEROSOL SPRAY) CAGE:0AHD1 CAGE:0AHD1 ============= Composition/Information on Ingredients ============= Ingred Name:ISOPROPYL ALCOHOL (SARA III) CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 74% OSHA PEL:400 PPM/500 STEL ACGIH TLV:400 PPM/500STEL;9192 Ingred Name:METHYLENE CHLORIDE(SARA III) CAS:75-09-2 RTECS #:PA8050000 Fraction by Wt: 20% OSHA PEL:500 PPM/C,1000; Z2 ACGIH TLV:50 PPM, A2; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:CARBON DIOXIDE CAS:124-38-9 RTECS #:FF6400000 Fraction by Wt: 4% OSHA PEL:5000 PPM ACGIH TLV:5000PPM/30000STEL;93 Ingred Name:POLISHING AGENTS AND FRAGRANCE ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:EXPECTED TO HAVE SLIGHT ACUTE TOXICITY BY INGESTION. THE ACUTE ORAL LD50 (RAT) WAS 3.8 G/KG (MALE) AND 2.7 G/KG. (FEMALE). ======================= First Aid Measures ======================= First Aid:EYES-FLUSH EYES IMMEDIATELY WITH FRESH WATER FOR AT LEAST 15 MINUTES WHILE HOLDING THE EYELIDS OPEN. SEE A DOCTOR. SKIN-WASH SKIN THOROUGHLY WITH SOAP & WATER. INHALATION-IF THERE ARE SIGNS OR SYMPTOM S DUE TO BREATHING THIS MATERIAL AS DESCRIBED IN THIS MSDS, MOVE THE PERSON TO FRESH AIR. INGESTION-IF SWALLOWED, GIVE WATER OR ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:72.0F,22.2C Lower Limits:NDA Upper Limits:NDA Extinguishing Media:CO2, DRY CHEMICAL, ALCOHOL-TYPE FOAM, WATER FOG. Fire Fighting Procedures:DO NOT ENTER ANY ENCLOSED OR CONFINED FIRE SPACE WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:READ AND OBSERVE ALL PRECAUTIONS ON PRODUCT LABEL. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION IN VICINITY OF SPILL OR RELEASED VAPOR. CLEAN UP SPILLS IMMEDIATELY, OBSERVING PRECAUTIONS IN SPECIAL PROTECTIVE INFORMATION. COVER SPILL W/A GENEROUS AMOUNT OF OIL D RY, CAT LITTER, CLAY, RAGS OR OTHER ABSORBENT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO SPECIAL RESPIRATORY PROTECTION IS NORMALLY REQUIRED. HOWEVER, IF OPERATING CONDITIONS CREATE AIRBORNE CONCENTRATIONS WHICH EXCEED THE RECOMMENDED EXPOSURE STANDARD, THE USE OF AN APPROVED RESPIRATO R IS RECOMMENDED. Ventilation:USE THIS MATERIAL ONLY IN WELL VENTILATED AREAS. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:NDA Melt/Freeze Pt:M.P/F.P Text:NDA Vapor Pres:NDA Vapor Density:NDA Spec Gravity:0.86 @ 21 C Evaporation Rate & Reference:NDA Solubility in Water:IN ISOPROPY ALCOHOL Appearance and Odor:COLORLESS LIQUID WITH CHARACTERISTIC FRAGRANCE. Percent Volatiles by Volume:98% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MAY REACT WITH STRONG OXIDIZING MATERIALS. Hazardous Decomposition Products:NORMAL COMBUSTION FORMS CARBON DIOXIDE & WATER VAPOR & MAY PRODUCE TOXIC CHLORINE COMPOUNDS; ==================== Disposal Considerations ==================== Waste Disposal Methods:PLACE CONTAMINATED MATERIALS IN DISPOSABLE CONTAINERS AND DISPOSE OF IN A MANNER CONSISTENT WITH APPLICABLE REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:(17A) MARKING PAINT-ALL COLORS, 224 GREEN (FLUORESCENT) Preparer's Name:MIKE A TRAQUINA CAGE:0UPL1 CAGE:0UPL1 ============= Composition/Information on Ingredients ============= Ingred Name:XYLENE (SARA 313) (CERCLA) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 14% OSHA PEL:100 PPM ACGIH TLV:100 PPM/150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:VM & P NAPHTHA; (SS 9 PETROLEUM NAPHTHA) CAS:64742-89-8 Fraction by Wt: 20% OSHA PEL:400 PPM (MFR) ACGIH TLV:400 PPM (MFR) Ingred Name:STODDARD SOLVENT; (SS 01 MINERAL SPIRITS) CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: <5% OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:PROPANE; (PR 01 A PROPANE) CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 15% OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT Ingred Name:PROPANE, 2-METHYL-; (ISOBUTANE) (PR 01 B ISOBUTANE) CAS:75-28-5 RTECS #:TZ4300000 Fraction by Wt: <5% OSHA PEL:800 PPM (MFR) ACGIH TLV:800 PPM (MFR) Ingred Name:BUTANE; (PR 01 C NORMAL BUTANE) CAS:106-97-8 RTECS #:EJ4200000 Fraction by Wt: 5% OSHA PEL:800 PPM ACGIH TLV:800 PPM Ingred Name:VOLATILE ORGANIC COMPOUND: 5.65 LBS/IMP GAL; 4.70 LBS/US GAL; 564 G/L RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION: ANESTHETIC. IRRIT OF RESPIRATORY TRACT/NERVOUS SYSTEM DEPRESS W/HEADACHE, DIZZINESS, NAUSEA/POSSIBLE UNCONSCIOUSNESS. SKIN CONTACT/ABSORPTION: MAY CAUSE IRRITATION/BURNING SENSATION . EYES: PRIMARY IRRITATION. CHRONIC: SKIN: PROLONGED/REPEATED CONTACT MAY CAUSE DERMATITIS - EXERCISE DUE CARE. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE FROM EXPOSURE AND RESTORE BREATHING. SEEK MEDICAL ATTENTION. SKIN: WASH AFFECTED AREA. REMOVE CONTAMINATED CLOTHING. SEE MD IF ANY IRRITATION PERSISTS. EYES: FLUSH IMMEDIATELY WITH WATER FOR AT LEAST 15 MINUTES. TAKE TO MD. INGESTION: CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:-26F,-32C Lower Limits:0.7% Extinguishing Media:FOAM, ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER SPRAY MAY BE INEFFECTIVE, BUT MAY BE USED TO COOL CONTRS EXPOSED TO HEAT/FIRE TO PVNT PRESS BUILD-UP. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE DUE TO BUILD-UP OF PRESSURE FROM EXTREME HEAT OR FIRE. AEROSOL SPRAY IS EXTREMELY FLAMMABLE. DO NOT PUNCTURE. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION: FLAMES, SPARKS, STATIC ELECTRICITY, AND ELECTRICAL. VENTILATE AREA AND SOAK UP WITH INERT ABSORBENT USING NON-SPARKING TYPE TOOLS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE ABOVE 120F. DO NOT STORE/USE NEAR HEAT, SPARKS/FLAME. DO NOT GET IN EYES. DO NOT BREATHE VAPS. AVOID SKIN CONT. DO NOT TAKE INTERNALLY. Other Precautions:SMOKING WHILE USING THIS PRODUCT MUST BE STRICTLY PROHIBITED. IN ADDITION TO ALL OTHER HAZARDS & PRECAUTIONS, DUST FROM SANDING DRY PAINT FILMS SHOULD BE TREATED AS A NUISANCE DUST WITH A TLV OF 10 MG /M3. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:OUTDOORS: MANUFACTURER RECOMMENDS A NIOSH APPROVED PARTICULATE FILTER TO REMOVE ANY AIRBORNE OVERSPRAY. IN RESTRICTED AREAS WITH POOR VENTILATION & CLOSE TO TLV, A NIOSH APPROVED RESPIRATOR WITH ORGAN IC VAPOR CARTRIDGE IS RECOMMENDED. Ventilation:ALL APPLICATION AREAS SHOULD BE ADEQUATELY VENTILATED IN ORDER TO KEEP INGREDIENTS BELOW THEIR EXPOSURE LIMITS. Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH & DELUGE SHOWER . IMPERVIOUS APRON IS RECOMMENDED TO PREVENT SKIN CONTACT. Work Hygienic Practices:AVOID PROLONGED OR REPEATED CONTACT. DO NOT BREATHE VAPORS. WASH CONTAMINATED CLOTHING PRIOR TO REUSE. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:-10F,-23C Vapor Density:HVR/AIR Spec Gravity:0.8 (H*2O=1) Evaporation Rate & Reference:FASTER THAN N-BU AC Solubility in Water:NEGLIGIBLE Appearance and Odor:OPAQUE LIQUID WITH SOLVENT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HIGH TEMPERATURES. Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS.
1
eyes_protection_mandatory
======================================================= Product ID: ALUMICUT Cage: OO209 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: OO209 ======================================================= Item Description Information ======================================================= ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE: EYES: MAY CAUSE SLIGHT TRANSIENT(TEMPORARY) IRRITATION WITH SLIGHT TRANSIENT CORNEAL INJURY, CAUSING REDNESS, TEARING OR BLURRED VISION. CONTACT LENSES MUST NOT BE WORN WHEN POSSIBILITY EXISTS FOR EYE CONTACT DUE TO SPRAYING LIQUID OR AIRBORNE PARTICLES. SKIN: PROLONGED OR REPEATED CONTACT MAY CAUSE MILD IRRITATION, DEFATTING, AND DERMATITIS (REDNESS, BURNING, DRYING AND CRACKING) AND POSSI BLE ALLERGIC SKIN REACTION. BREATHING: EXCESSIVE INHALATION OF VAPORS CAN CAUSE NASAL AND RESPIRATORY IRRITATION, CENTRAL NERVOUS SYSTEM EFFECTS INCLUDING DIZZINESS, WEAKNESS, FATIGUE, NAUSEA, (EFTS O F OVEREXP) Signs And Symptions Of Overexposure: HLTH HAZS: HEADACHE AND POSSIBLE UNCONSCIOUSNESS. SWALLOWING: SINGLE DOSE ORAL TOXICITY IS LOW. SWALLOWING LARGE AMOUNTS MAY BE HARMFUL AND MAY CAUSE GASTROINTESTINAL IRRITATION (NAUSEA, VOMITING, DIA RRHEA). THIS MATERIAL CAN ENTER THE LUNGS DURING SWALLOWING OR VOMITING AND CAN CAUSE LUNG INFLAMMATION AND/OR DAMAGE. CHRONIC HEALTH EFFECTS: CHRONIC OVEREXPOSURE MAY AGGRAVATE EXISITNG SKIN, EYE AND LUNG CONDITIONS. Medical Cond Aggravated By Exposure: PRE-EXISTING SKIN DISORDERS MAY BE AGGRAVATED BY OVER EXPOSURE. First Aid: INHAL: REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. IF BREATHING HAS STOPPED, GIVE ARTIFICIAL RESPIRATION. KEEP PERSON WARM, QUIET & GET MEDICAL ATTENTION. SKIN CONTACT: WASH THO ROUGHLY W/ SOAP & WATER. REMOVE CONTAMINATED CLOTHING. LAUNDER CONTAMINATED CLOTHING BEFORE RE-USE. EYES: FLUSH W/ COPIOUS AMOUNTS OF WATER FOR AT LST 15 MINS. GET MEDICAL ATTN. INGESTION: DO NOT INDU CE VOMITING. IMMED DRINK 2 GLASSES OF WATER. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON. GET MED ATTN IMMED. ASPIRATION OF MATERIAL INTO LUNGS DUE TO VOMITING CAN CAUSE CHEMICAL PNEUMONITIS WHICH CA N BE FATAL. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: ELIMINATE ALL IGNIT SOURCES (FLARES, FLAMES INCL PILOT LIGHTS, ELEC SPKS, ETC.). SM SPILL: ABSORB LIQ ON PAPER, VERMICULITE, FLOOR ABSORB/OTHER ABSORB MATL & TRANSFER TO VENTED AREA. LG SPILL: PERSONS NOT WEARING PROT EQUIP SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEANUP HAS BEEN COMPLETED. STOP SPILL AT SOURCE. DIKE AREA OF SPILL TO PVNT SPREADING. PUMP LIQ TO SALVAGE TANK.(SUPDAT) Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. Handling And Storage Precautions: TO AVOID SKIN CONTACT & INGESTION, WASH HANDS & FACE WELL BEFORE EATING OR SMOKING. DO NOT PERMIT FOOD IN WORK AREA. AVOID BREATHING MISTS IF GENERATED. STORE AT ROOM TEMPERATURE. DO NOT FREEZE. Other Precautions: CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED, SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES (VAPOR, LIQUID, AND/OR SOLID). ALL HAZARD PRECAUTIONS GIVEN IN THIS DATA SHEET MUST BE OBSER VED. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: TCC Flash Point: =61.C, 141.8F Lower Limits: 1% Upper Limits: 6% Extinguishing Media: REGULAR FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER MIST. Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: NEVER USE WELDING OR CUTTING TORCH ON OR NEAR DRUM (EVEN EMPTY) BECAUSE PRODUCT (EVEN JUST RESIDUE) CAN IGNITE EXPLOSIVELY. ======================================================= Control Measures ======================================================= Respiratory Protection: IF WORKPLACE EXPOSURE LIMIT(S) OF PROD IS EXCEEDED, NIOSH APPRVD AIR SUPPLIED RESP IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. OSHA REGS ALSO PERMIT OTHER NIOSH RESPIRATORS(NEGATIVE PRESSUR E TYPE) UNDER SPECIFIED CONDITIONS. ENGINEERING OR ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO REDUCE EXPOSURE. Ventilation: PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN MINIMUM EXPOSURE. Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N). TO PREVENT RPTD/PRLNGD SKIN CONT, WEAR IMPERVIOUS CLOTHING AND BOOTS. CONSULT YOUR SUPERVISOR. Work Hygienic Practices: WASH HANDS & FACE WELL BEFORE EATING/SMOKING. DO NOT PERMIT FOOD IN WORK AREA. Supplemental Safety and Health: SPILL PROC: REMAINING LIQ MAY BE TAKEN UP ON SAND, CLAY, EARTH, FLOOR ABSORB/OTHER ABSORB MATL & SHOVELED INTO CNTNRS. PREVENT RUN-OFF TO SEWERS, STREAMS OR OTHER BODIES OF WATER. NOTIFY PROPER AUTHOR ITIES, AS REQD, THAT SPILL HAS OCCURRED. % VOLATILES BY VOLUME (EPA METHOD 24): 62. VOM: 2000 GRAMS PER GALLON. ======================================================= Physical/Chemical Properties ======================================================= Boiling Point: =87.8C, 190.F Vapor Pres: <0.1 @ 68F Vapor Density: 5 Spec Gravity: 0.86 Solubility in Water: INSOLUBLE Appearance and Odor: LIQUID, MILD ORGANIC ODOR. Percent Volatiles by Volume: SUPDAT ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: STORAGE ABOVE 100F. Materials To Avoid: AVOID CONTACT WITH; EXCESSIVE HEAT, STRONG OXIDIZING AGENTS, AND STRONG BASES. Hazardous Decomposition Products: CARBON MONODIOXIDES, WATER. Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= Transport Information: CONTAINERS OF LESS THAN 110 GALLONS (DRUMS) - COMBUSTIBLE LIQUID N.O.S. ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= Other Information: CODES: HEALTH-1, FLAMMABILITY-2, REACTIVITY-1, PERSONAL PROTECTION -D. NFPA CODES: HEALTH-1, FLAMMABILITY-2, REACTIVITY-1. HAZ INGREDS: PEL/TLV ARE NOT ESTABLISHED FOR THIS MATERIAL. COMPONENTS O F THIS PROD ARE NOT LISTED IN SARA TITLE III CONSOLIDATED LIST. COMPONENT OF THIS PROD ARE NOT LISTED IN 40 CFR 302.4. REFERENCES: 29 CFR 1910.1000, ACGIH "THRESHOLD LIMIT VALUES FOR CHEMICALS IN THEWORKPLACE", NATL TOXICOLOGY PROGRAM ANNUAL RPT, INTERNATIONAL AGENCY FOR RESEARCH ON CANCER MONOGRAPHS, & 40 CFR PART 372. ALL COMPONENTS OF THIS PROD ARE IN COMPLIANCE WITH TSCA. ======================================================= HAZCOM Label ======================================================= Product ID: ALUMICUT Cage: OO209 Assigned IND: Y Company Name: MISTIC METAL MOVER INC. Street: 1160 N 6TH ST Zipcode: 61356 Label Required IND: Y Date Of Label Review: 12/28/1999 Status Code: A Origination Code: F Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Slight Fire Hazard: Moderate Reactivity Hazard: None Hazard And Precautions: COMBUSTIBLE! ACUTE: EYES: MAY CAUSE SLIGHT TRANSIENT(TEMPORARY) IRRIT W/SLIGHT TRANSIENT CORNEAL INJURY, CAUSING REDNESS, TEARING/BLURRED VISION. SKIN: PRLNGD/RPTD CONT MAY CAUSE MILD IRRIT, DEFATTIN G, & DERM (REDNESS, BURNING, DRYING ANDCRACKING). BREATHING: EXCESSIVE INHAL OF VAPORS CAN CAUSE NASAL & RESP IRRIT, CNS EFTS INCLUDING DIZZ, WEAKNESS, FATIGUE, NAUS, HDCH & POSS UNCON. INGEST: LOW TOXICITY. MAY BE HARMFUL & MAY CAUSE GI IRRITATION (NAUSEA, VOMIT, DIARRHEA). MATL CAN ENTER LUNGS DURING VOMIT/SWALLOWING AND CAUSE LUNG INFLAMM/DMG.CHRONIC: SKIN ALLERGIC REACTION. MAY AGGRAV ATE EXISTING SKIN, EYE AND LUNG CONDITIONS. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:R.P. X-RAY DEV./REPL.-PART B CAGE:FO211 CAGE:FO211 CAGE:47220 ============= Composition/Information on Ingredients ============= Ingred Name:WATER (20-40%) CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 40% Ingred Name:ACETIC ACID (SARA III) CAS:64-19-7 RTECS #:AF1225000 Fraction by Wt: 70% OSHA PEL:10 PPM ACGIH TLV:10 PPM/15 STEL; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:1-PHENYL-3-PYRAZOLIDONE CAS:92-43-3 RTECS #:UQ8750000 Fraction by Wt: 3-10% Ingred Name:5-NITROBENZIMIDAZOLE (0.1-0.5%) CAS:94-52-0 RTECS #:DD9800000 Fraction by Wt: 0.5% ===================== Hazards Identification ===================== Effects of Overexposure:RESPIRATORY IRRITATION/EYE & SKIN BURNS, IRRITATION & AN ALLERGIC SKIN REACTION. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE FROM EXPOSURE. EYES/SKIN: FLUSH WITH PLENTY OF WATER; GET MEDICAL ATTENTION. IF ALLERGIC SKIN REACTION DEVELOPS, GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:>200F (CC) Lower Limits:NONE Upper Limits:NONE Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CO2, FOAM Fire Fighting Procedures:WEAR SCBA/PROTECTIVE CLOTHING TO PREV. CONTACT W/SKIN & EYES Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:NEUTRALIZE WITH BAKING SODA (SODIUM BICARBONATE) SMALL AMOUNT: FLUSH TO SEWER WITH LGE AMOUNT OF WATER. LARGE AMOUNT: ABSORB MATERIAL IN VERMICULITE OR OTHESUITABLE ABSORBENT & PLACE IN IMPERVIOUS CON TAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP FROM CONTACT WITH OXIDIZING MATERIALS AND STRONG ALKALI. KEEP CONTAINER TIGHTLY CLOSED. Other Precautions:LOCAL EXHAUST OR AN ENCLOSED HANDLING SYSTEM MAY BE NEEDED TO CONTROL AIR CONTAMINATION TO ACCEPTABLE LEVELS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED ORGANIC VAPOR RESPIRATOR, IF >TLV. Ventilation:LOCAL EXHAUST/MECH: GIVE 10 ROOM VOLUMES PER HOUR. Other Protective Equipment:AS NECESSARY TO PREVENT SKIN & EYE CONTACT. Supplemental Safety and Health MSDS DATE: 01/86. PH: 2 ================== Physical/Chemical Properties ================== Spec Gravity:1.1 Solubility in Water:COMPLETE Appearance and Odor:CLEAR, ORANGE-BROWN COLORED SOLUTION; PUNGENT. Percent Volatiles by Volume:90% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS & STRONG ALKALI Hazardous Decomposition Products:CO, CO2, NOX ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN AN APPROVED INCINERATOR OR CONTRACT WITH LICENSED CHEMICAL WASTE DISPOSAL AGENCY. DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT TO FEDERAL, STATE OR LOCAL LAWS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:494E LIGHTWEIGHT BODY FILLER CAGE:16522 CAGE:16522 ============= Composition/Information on Ingredients ============= Ingred Name:DIETHYLENE GLYCOL, MALEIC ANHYDRIDE, PHTHALIC ANHYDRIDE POLYMER*97-2* CAS:26123-45-5 Fraction by Wt: <35% Ingred Name:STYRENE, STYRENE MONOMER (SUSPECTED ANIMAL/HUMAN CARCINOGEN BY IARC GROUP 2B) *97-2* CAS:100-42-5 RTECS #:WL3675000 Fraction by Wt: <18% EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TALC (POWDER), (ASBESTOS FREE), TALCUM; HYDROUS MAGNESIUM SILICATE (IARC - GROUP 3) *97-2* CAS:14807-96-6 RTECS #:WW2710000 Fraction by Wt: <50% OSHA PEL:2 MG/CUM (RESP DUST) ACGIH TLV:2 MG/CUM (RESP DUST) Ingred Name:GLASS OXIDE, FIBER GLASS WOOL, LEAD BOROSILICATE GLASS ENAMEL FLUX CAS:65997-17-3 Fraction by Wt: <50% Ingred Name:VOLATILE ORGANIC CONTENT: 216 G/L RTECS #:9999999VO ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:EYES/SKIN: MAY CAUSE IRRITATION. INHALATION: VAPORS MAY CAUSE MUCOUS MEMBRANE & UPPER RESPIRATORY TRACT IRRITATION. REPEATED EXPOSURE TO HIGH CONCENTRATIONS OF VAPOR MAY CAUSE LIVER & KIDNEY DAMAGE. Explanation of Carcinogenicity:SEE INGREDIENTS. Effects of Overexposure:IRRITATION, DISCOMFORT. Medical Cond Aggravated by Exposure:INDIVIDUALS W/CHRONIC RESPIRATORY CONDITIONS (ASTHMA, CHRONIC BRONCHITIS, EMPHYSEMA). ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/LARGE AMOUNTS OF WATER. SKIN: WASH THOROUGHLY W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED. INGESTION: DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN AL L CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:90F (SEE SUPP) Lower Limits:1.1 Upper Limits:6.1 Extinguishing Media:SMALL FIRES: CO2, DRY CHEMICAL. LARGE FIRES: FOAM, WATER FOG. Fire Fighting Procedures:DENSE SMOKE SERIOUSLY LIMITS VISIBILITY. VENT SMOKE & USE GAS MASK/REMOTE AIR SUPPLY. WEAR MSHA/NIOSH APPROVED SCBA W/PROTECTIVE EQUIPMENT. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE SOURCES OF IGNITION. INCREASE VENITLATION TO MAXIMIZE VAPOR DISPERSAL. DIKE TO PREVENT RUNOOF INTO SEWERS/WATERWAYS. MATERIAL MAY BE REMOVED BY SHOVELING, WIPING. SWEEP/CLEAN W/INERT MATERIALS & PLACE IN CLOSED CONTAINER FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY AREA. DON'T STORE IN DIRECT SUNLIGHT. USE W/ADEQUATE GENERAL & LOCAL EXHAUST VENTILATION TO MINIMIZE EXPOSURE TO VAPORS. Other Precautions:BOND & GROUND CONTAINERS FOR TRANSFER OF PRODUCT TO PREVENT STATIC SPARKS. AVOID PROLONGED/REPEATED CONTACT W/SKIN & EYE CONTACT. STYRENE VAPORS ARE UNIHIBITED & MAY CAUSE BLOCKAGE OF VENTILATION VENT S DUETO POLYMERIZATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED ORGANIC VAPOR/DUST RESPIRATOR TO AVOID INHALATION OF EXCESSIVE AIR CONTAMINANTS. Ventilation:LOCAL EXHAUST SHOULD BE USED TO CONTROL THE EMISSION OF AIR CONTAMINANTS. GENERAL DILUTION MAY REDUCE AIR CONCENTRATIONS Other Protective Equipment:SAFETY SHOWERS & EYE WASH STATIONS. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. CLEAN HANDS W/SOAP & WATER AFTER EVERY USAGE. Supplemental Safety and Health THE PHYSICAL DATA INFORMATION IS FOR STYRENE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:293F(SUPP) Vapor Pres:5.2(SUPP) Vapor Density:3.6(SUPP) Spec Gravity:1.05-1.35 Evaporation Rate & Reference:LESS THAN ETHER Solubility in Water:NEGLIGIBLE Appearance and Odor:WHITE PASTE W/STYRENE ODOR Percent Volatiles by Volume:18 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, PEROXIDES, OXIDIZING AGENTS. Stability Condition to Avoid:HEAT, ELECTRICAL EQUIPMENT, SPARKS, OPEN FLAME. Hazardous Decomposition Products:CO, CO2, HYDROCARBONS, ORGANIC ACIDS. Conditions to Avoid Polymerization:UNREGULATED CONTACT W/ORGANIC PEROXIDES, EXPOSURE TO HEAT, OPEN FLAME & PROLONGED STORAGE >100F. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. IF DISCARDED, MATERIAL & CONTAINERS ARE CONSIDERED RCRA HAZARDOUS WASTES BASED ON THE CHARACTERISTIC OF IGNITABILITY. UN1866.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SOLUTION "B" KSTS Preparer's Name:BRUCE L. POLAK CAGE:75384 CAGE:75384 ============= Composition/Information on Ingredients ============= Ingred Name:BARIUM CHLORIDE DIHYDRATE; (BARIUM CHLORIDE). BP: 96F,35.6C.MP: 235F,113C. CAS:10326-27-9 RTECS #:CQ8751000 Fraction by Wt: <25% OSHA PEL:0.5 MG/M3 (BA) ACGIH TLV:0.5 MG/M3 (BA) Ingred Name:WATER; (DEIONIZED WATER) CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: BALANCE OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN CONTACT MAY CAUSE IRRITATION. EYE CONTACT MAY CAUSE INJURY. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:RED OR INFLAMED SKIN WITH A POSSIBLE BURNING SENSATION. Medical Cond Aggravated by Exposure:OPE CUSTS OR SKIN ABRASIONS. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE OXYGEN/ARTIFICIAL RESPIRATION) . SKIN: FLUSH WITH PLENTY OF WATER. EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES, INCLUDING UNDER THE EYELIDS . INGEST: INDUCE VOMITING AND SEEK IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NON FLAMMABLE Extinguishing Media:USE SUITABLE MEANS FOR EXTINGUISHING FIRE. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NO APPLICABLE INFORMATION FOUND. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN SPILL AND ABSORB WITH AN INERT MATERIAL (I.E. SAND, ETC.). HOLD FOR PROPER DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE IN DIRECT SUNLIGHT. KEEP AT ROOM TEMPERATURE WITH CAP TIGHTLY CLOSED. Other Precautions:NO APPLICABLE INFORMATION FOUND. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF AIRBORNE, USE A NIOSH/MSHA APPROVED RESPIRATOR TO REDUCE EXPOSURE TO BELOW LISTED LIMITS. Ventilation:LOCAL EXHAUST TO REDUCE EXPOSURE TO BELOW LISTED LIMITS. MECHANICAL (GENERAL) NOT REQUIRED IN SOLUTION FORM. Other Protective Equipment:ADEQUATE TO PROTECT THE CLOTHING (I.E. LAB COAT OR RUBBER APRON). EYEWASH FOUNTAIN & DELUGE SHOWER MEETING (SUP DAT) Work Hygienic Practices:WASH THOROUGHLY WITH SOAP AND WATER AFTER USE. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. OTHER PROT EQUIP:ANSI DESIGN CRITERIA . ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:SEE ING 1 Melt/Freeze Pt:M.P/F.P Text:SEE ING 1 Spec Gravity:>1 (H*2O=1) pH:5 Solubility in Water:COMPLETE Appearance and Odor:COLORLESS, ODORLESS SOLUTION. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NO APPLICABLE INFORMATION FOUND. Stability Condition to Avoid:NO APPLICABLE INFORMATION FOUND. Hazardous Decomposition Products:MAY RELEASE TOXIC FUMES UNDER FIRE CONDITIONS. ==================== Disposal Considerations ==================== Waste Disposal Methods:ACCORDING TO FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory