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===================== Product Identification ===================== Product ID:FORMULA 84 H2-017 Preparer's Name:DAVID SCHMETTERER CAGE:DO165 CAGE:DO165 CAGE:5V430 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL SPIRITS/66 (VAPOR PRESSURE 3.4 MM HG) CAS:8032-32-4 RTECS #:OI6180000 Fraction by Wt: 10% Other REC Limits:NONE RECOMMENDED OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:ZINC MOLYBDATE CAS:22914-58-5 Fraction by Wt: 5.9% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:ZINC OXIDE (SARA 313) (CERCLA) CAS:1314-13-2 RTECS #:ZH4810000 Fraction by Wt: 15% Other REC Limits:NONE RECOMMENDED ACGIH TLV:10 MG/M3 Ingred Name:100 SOLVENT (VAPOR PRESSURE 9 MM HG) CAS:64742-95-6 Fraction by Wt: 11% Other REC Limits:NONE RECOMMENDED OSHA PEL:50 PPM ACGIH TLV:50 PPM Ingred Name:VOC: <340 GPL RTECS #:9999999VO Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Health Hazards Acute and Chronic:ACUTE TOXICITY, ERSULT IN HEADACHE, DIZZINESS, NAUSEA, & LOSS OF CONSCIOUSNESS. SEVERE EYE IRRITATION POSSIBLY RESULTING IN PERMANENT DAMAGE. IRRITATED MUCOUS MEMBRANES. VOMITING DUE TO INGESTION. DEF ATTING & DRYING OF SKIN, WHICH MAY RESULT IN IRRITATION & DERMATITIS. SENSITIZATION AFTER REPEATED CONTACT. ======================= First Aid Measures ======================= First Aid:NEVER GIVE UNCONSIOUS LIQUID. EYE:FLUSH W/WATER 15 MIN HOLDING EYELIDS OPEN.GET MED AID. INHAL:REMOVE TO FRESH AIR.GIVE OXYGEN IF BREATHING DIFFICULT.GIVE ARTIF RESP IF NOT BREATHING.GET MED AID.KEEP WARM & COMFORTABLE. INGEST:CALL DR IMMED.ONLY INDUCE VOMIT ON DR'S INSTRUCTIONS.IF VOMITING OCCURS SPONTANEOUSLY,KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION. SKIN:FLUSH W/H2O WHILE REMOVING CONTAM ** ===================== Fire Fighting Measures ===================== Flash Point:110F,43C Lower Limits:0.9 Extinguishing Media:FOAM, CO2, OR DRY CHEMICAL Fire Fighting Procedures:WATER MAY BE USED TO COOL EXPOSED CONTAINER, & TO KEEP FLAMMABLE STRUCTURES WET. DON'T ENTER FIRE AREA WITHOUT PROTECTION BECAUSE DECOMP PRODUCT MAY BE PRESENT. Unusual Fire/Explosion Hazard:WATER PRESSURE MAY SPREAD A FLAMMABLE LIQUID FIRE. SEALED CONTAINERS MAY EXPLODE IF OVERHEATED. ================== Accidental Release Measures ================== Spill Release Procedures:WARNING - FLAMMABLE. ELIMINATE ALL IGNITIOIN SOURCES. HANDLING EQUIPMENT MUST BE GROUNDED TO PREVENT SPARKING. SOAK UP WITH AN ABSORBENT AND PLACE IN NON-LEAKING CONTAINERS. SEAL TIGHTLY FOR PROPER DI SPOSAL. Neutralizing Agent:N/K ** CLOTHES & SHOES. FOLLOW BY WASHING W/SOAP & H2O. DON'T REUSE CLOTHES *** ======================Handling and Storage ====================== Handling and Storage Precautions:COMBUSTBL.STORE IN COOL,DRY PLACE IN BLDG FOR COMBUST STORAGE.WARNING:HOT ORGANIC CHEM VAPOR/MIST SUSCEPTIBLE TO SPONTANEOUS COMBUSTN WHEN MIXED W/AIR Other Precautions:IGNIT MAY OCCUR AT TEMP BELOW AUTOIGNIT/IGNIT TEMPS.IGNIT TEMPS DECREASE W/INCREASING VAPOR VOLUME & VAPOR/AIR CONTACT TIME & INFLUENCED BY PRESSR CHANGE.IGNIT MAY OCCUR AT ELEVATED TEMP,ESPECIALLY IN VACUUM IF SUDDEN INGRESS AIR OR # ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED ORGANIC VAPOR RESPIRATORS WHERE VENTILATION IS INADEQUATE. Ventilation:MUST PROVIDE ADEQUATE VENTILATION. Other Protective Equipment:HAVE EYE BATH AND SAFETY SHOWER AVAILABLE. Supplemental Safety and Health # OTHER PRECAUTIONS CONT'D: OUTSIDE PROCESS EQUIPMENT OPERATING UNDER ELEVATED PRESSURE IF SUDDEN ESCAPE OF VAPOR OR MIST TO THE ATMOSPHERE OCCURS. ANY PROPOSED USE SHOULD BE THOROUGHLY EVALUATED TO A SSURE THAT SAFE OPERATING CONDITIONS ARE ESTABLISHED AND MAINTAINED. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:308 TO 396F Vapor Density:> AIR Spec Gravity:1.56 Viscosity:90 KU Evaporation Rate & Reference:0.13 X N-BUTYL ACETATE Solubility in Water:SLIGHT Appearance and Odor:YELLOW LIQUID / SOLVENT ODOR Percent Volatiles by Volume:40.5 Corrosion Rate:NOT CORR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MAY BE INCOMPATIBLE WITH OXIDIZING AGENTS AND STRONG ALKALIES. Stability Condition to Avoid:AVOID HEAT, SPARKS, OPEN FLAMES, & INCOMPATIBILITIES. ALSO AIRCRAFT TRANSPORT MUST BE IN STRICK ACCORDANCE W/REGULATIONS Hazardous Decomposition Products:INCOMPLETE COMBUSTION FOR PRODUCTS LIKE THIS MAY GENERATE HIGHLY POISONOUS CARBON MONOXIDE AND OTHER TOXIC GASES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH CURRENT LOCAL, STATE, AND FEDERAL REGULATIONS. CONTACT AN APPROVED DISPOSAL FACILITY. EPA HAZARDOUS WASTE CODE: D001, IGNITABLE. *** OR SHOES UNTIL C LEANED. IF IRRITATION PERSISTS, GET MEDICAL AID.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:AT143 ALPHA CRYL AT BASES & COLORS W/O LEAD CAGE:0PK40 CAGE:0PK40 CAGE:BASSF ============= Composition/Information on Ingredients ============= Ingred Name:2-BUTANONE (METHYL ETHYL KETONE) (MEK) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 9% Other REC Limits:590 MG/CUM OSHA PEL:200 PPM ACGIH TLV:590 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TOLUENE (IARC CARC- GROUP 3) *96-1* CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 29% Other REC Limits:375 MG/CUM OSHA PEL:100 PPM ACGIH TLV:100 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ACETONE; DIMETHYL KETONE; 2-PROPANONE CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 19% OSHA PEL:2400 MG/CUM ACGIH TLV:750 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:BUTYL BENZYL PHTHALATE, BBP, BENZYL BUTYL PHTHALATE 1,2-BENZENEDICARBOXYLIC ACID, BUTYL PHENYLMETHYL ESTER CAS:85-68-7 RTECS #:TH9990000 Fraction by Wt: 8% Other REC Limits:5 MG/CUM EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:XYLENE, DIMETHYLBENZENE, XYLOL (IARC - GROUP 3) *96-1* CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 4% Other REC Limits:100 PPM OSHA PEL:100 PPM ACGIH TLV:100 PPM, SKIN EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHYL BENZENE *96-1* CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 2% Other REC Limits:100 PPM OSHA PEL:435 MG/CUM ACGIH TLV:434 MG/CUM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:VOLATILE ORGANIC CONTENT: 4.8-6.8 LBS/GAL; 572-811 GM/L RTECS #:9999999VO ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: ANESTHETIC, RESPIRATORY TRACT IRRITANT/NERVOUS SYSTEM DEPRESSION. INGESTION: GI IRRITANT. ASPIRATION OF MATERIAL INTO LUNGS MAY RESULT IN CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. SKIN: IRR ITATION, ABSORPTION. EYES: IRRITATION. REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS MAY CAUSE PERMANENT CNS CHANGES. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, HEADACHES, NAUSEA, LOSS OF CONSCIOUSNESS, VOMITING ======================= First Aid Measures ======================= First Aid:INHALATION: RESTORE BREATHING. REMOVE TO FRESH AIR. KEEP WARM/QUIET. EYES: FLUSH IMMEDIATELY W/COPIOUS AMOUNTS OF RUNNING WATER FOR 15 MINS. SKIN: CLEAN & WASH W/WATER. INGESTION: DON'T INDUCE VOMITIN G. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:-5 TO 5F Lower Limits:0.5 Upper Limits:19 Extinguishing Media:FOAM, CO2, CHEMICAL POWDER Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT W/SCBA. WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. USE WATER TO COOL CLOSED CONTAINERS. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTEME HEAT. APPLICATION TO HOT SURFACES REQUIRES SPECIAL PRECAUTIONS. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. REMOVE ALL POSSIBLE SOURCES OF IGNITION. CONFINE LEAK W/INERT ABSORBENT & CLEAN UP WITH SPARK-PROOF TOOLS. AVOID PROLONGED BREATHING OF VAPORS. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T STORE >120F. STORE LARGE QUANTITIES IN BUILDINGS DESIGNED & PROTECTED AGAINST FLAMMABLE LIQUIDS. USE STATIC LINES WHEN MIXING & TRANSFERRING. Other Precautions:DON'T ALLOW MATERIAL TO FREE FALL MORE THAN FIVE INCHES. FOR INDUSTRIAL USE ONLY. DON'T TAKE INTERNALLY. DON'T FLAME CUT, WELD/BRAZE ON COATED METAL W/O NIOSH/MSHA TC23C RESPIRATOR. AVOID PROLONGED BR EATHING OF VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA TC23C CHEMICAL/MECHANICAL TYPE FILTER SYSTEM TO REMOVE A COMBINATION OF PARTICLES, GAS & VAPORS. USE AN AIR SUPPLIED RESPIRATOR IF NECESSARY. Ventilation:LOCAL EXHAUST/GENERAL MECHANICAL. Supplemental Safety and Health MISUSE BY CONCENTRATING & INHALING THE CONTENTS MAY BE HARMFUL/FATAL. KEEP CONTAINERS TIGHTLY CLOSED. AVOID IGNITION SOURCES. PREVENT PROLONGED SKIN CONTACT TO CONTAMINATED COTHING. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:133-410F Vapor Pres:19-90.86 Vapor Density:>1 Evaporation Rate & Reference:(ETHER=1): <1 Appearance and Odor:LIQUID, VARIOUS COLORS W/AROMATIC ODOR Percent Volatiles by Volume:69-95 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACID, ALKALIES, & OXIDIZERS Stability Condition to Avoid:HEAT, OPEN FLAMES, STATIC ELECTRICITY, SPARKS, ELECTRICAL EQUIPMENT & OTHER IGNITION SOURCES. Hazardous Decomposition Products:CO2, CO, CARBON SMOKE ==================== Disposal Considerations ==================== Waste Disposal Methods:LANDFILL/INCINERATE IN APPROVED FACILITY BY LICENSED CONTRACTOR. DON'T INCINERATE IN CLOSED CONTAINER. DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. UN1263.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GERMI-KLEEN NON-ACID BOWL & BATHROOM DISINFECTANT #1715 Preparer's Name:F.C. CAGE:93607 CAGE:93607 ============= Composition/Information on Ingredients ============= Ingred Name:TETRASODIUM ETHYLENE DIAMINE TETRAACETATE CAS:64-02-8 RTECS #:AH5075000 Other REC Limits:NONE RECOMMENDED Ingred Name:2-BUTOXYETHANOL (SARA 313) CAS:111-76-2 RTECS #:KJ8575000 Other REC Limits:NONE RECOMMENDED OSHA PEL:50 PPM ACGIH TLV:50 PPM Ingred Name:2(2-ETHOXYETHOXY) ETHANOLDIETHYLENE GLYCOL MONOETHYL ETHER CAS:111-90-0 RTECS #:KK8750000 Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT EST.NK Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Explanation of Carcinogenicity:NONE Medical Cond Aggravated by Exposure:NONE ======================= First Aid Measures ======================= First Aid:EYE: FLUSH THOROUGHLY W/WATER >15 MINUTES. GET MEDICAL AID. SKIN: FLUSH THOROUGHLY W/WATER. IF IRRITATION PERSISTS GET MEDICAL AID. INGESTION: DO NOT INDUCE VOMITING. GIVE MILK, EGG WHITE, GELATIN, OR IF NONE OF THESE AVAILABLE LARGE AMOUNTS WATER. GET IMMEDIATE MEDICAL AID. ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:NONE TO BOILING Lower Limits:NOT EST. Upper Limits:NOT EST. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:RECONTAINERIZE BY MOPPIN, WET VACUUM OR USING SUITABLE ABSORBENT. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE BETWEEN 40 & 140F. Other Precautions:KEEP OUT OF REACH OF CHILDREN. FOR SALE TO, USE & STORAGE BY SERVICE PERSONNEL ONLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE Ventilation:NONE Other Protective Equipment:NONE Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Vapor Pres:TO WATER Vapor Density:TO WATER Spec Gravity:0.96 Evaporation Rate & Reference:TO WATER Solubility in Water:COMPLETE Appearance and Odor:GREEN LIQUID, GIANE (TM) FRESH ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS & OXIDIZERS Stability Condition to Avoid:NONE Hazardous Decomposition Products:CARBON OXIDES & AMINES ==================== Disposal Considerations ==================== Waste Disposal Methods:FOLLOW LOCAL, STATE, FEDERAL REGULATIONS.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Preparer's Name:DOD HMIS/DGSC-SSH CAGE:JO772 CAGE:14153 CAGE:JO772 ============= Composition/Information on Ingredients ============= Ingred Name:ASBESTOS, CHRYSOTILE CAS:12001-29-5 RTECS #:CI6478500 OSHA PEL:0.2 FIBERS/CC ACGIH TLV:2 FIBERS/CC; A1;9192 Ingred Name:ASBESTOS & NATURAL/SYNTHETIC RUBBER & STEEL COMPOSITION RTECS #:9999999ZZ Ingred Name:GENERIC "MSDS". SPECIFIC ASBESTOS TYPE NOT KNOWN. ONE CITED IS ASSUMED. INFORMATION BASED ON SEGMENT "M" OF "DLSC TIR" RTECS #:9999999ZZ ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE: NO ACUTE EFFECTS ARE KNOWN; CHRONIC: DUST FROM ABRASIVE ACTIONS(EG. CUTTING, MACHINING, FILING, ETC.) MAYCONTAIN ASBESTOS FIBERS. CHRONIC OVEREXPOSURE TO AIRBORNE FIBERS MAY LEAD TO ASBESTOSIS & MESOTHELIOMA. SMOKINGCOMBINED W/FIBER INHALATION GREATLY INCREASES LUNG CANCER RISK! Explanation of Carcinogenicity:OVEREXPOSURE TO AIRBORNE CONCENTRATIONS OF ASBESTOS MAY LEAD TO ASBESTOSIS AND MESOTHELIOMA. Effects of Overexposure:INHAL: INHALATION OF AIRBORNE DUST CONTAINING ASBESTOS FIBERS ON REPEATED EXPOSURE MAY CAUSE OR CAN LEAD TO ASBESTOSIS/ MESOTHELIOMA; SKIN: N/K; EYE: POTENTIAL IRRITATION FROM AIRBORNE DUST; INGEST: N/K. Medical Cond Aggravated by Exposure:RESPIRATORY DEFICIENCIES DUE TO REPEATED INHALATION OF AIRBORNE FIBERS. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. OBTAIN MEDICAL ADVICE; SKIN: WASH EXPOSED AREA WITH SOAP & WATER; EYE: FLOOD W/ WATER. IF IRRITATION OCCURS, GET MEDICAL ATTN; INGEST: CONSULT A PHYSICIAN; OTHER: CHANGE CLOTHING AS REQUIRED TO AVOIDCARRYING DUST PARTICLES INTO OTHER AREAS ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:MATERIAL IS NOT FLAMMABLE ; USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:COMBUSTION PRODUCTS OF THIS MATERIAL MAY BE TOXIC. USE A SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRES INVOLVING CHEMICAL PRODUCTS. Unusual Fire/Explosion Hazard:NONE KNOWN ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTION. VACUUM OR WET CLEAN IF DUST IS INVOLVED. ANY VACUUM SYSTEM SHOULD BE EQUIPPED W/ AN OUTLET "HEPA" FILTER TO PREVENT REINTRODUCING ASBESTOS FIBERS TO THE ATMOSPHERE. ======================Handling and Storage ====================== Handling and Storage Precautions:HANDLE IN A MATTER TO MINIMIZE FORMATION OR RETENTION OF AIRBORNE DUST. USE PROPER PERSONAL PROTECTION FOR TASK AT HAND. CHECK W/YOUR SAFETY OFFICE!!! Other Precautions:AS MANUFACTURED, LOCKED-IN ASBESTOS DOES NOT PRESENT A HAZARD. ONLY WHEN THE ITEM IS SUBJECTED TO ABRASIVE ACTIONS & DUST IS GENERATED, THEN ASBESTOS FIBERS MAY BE RELEASED & BECOME AIRBORNE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURES EXCEED ESTABLISHED LIMITS, A NIOSH/MSHA APPROVED RESPIRATOR FOR ASBESTOS SHOULD BE USED. CONSULT YOUR SAFETY OFFICE/IH PERSONNEL FOR GUIDANCE FOR THE TASK AT HAND. Ventilation:LOCAL EXHAUST IS RECOMMENDED IN SITUATIONS WHERE DUST IS GENERATED BY ABRASIVE ACTIONS, ABRASION OR OTHER MEANS. Other Protective Equipment:AS REQUIRED FOR TASK AT HAND, AND THE GUIDANCE SET FORTH BY YOUR SAFETY OFFICE OR IH PERSONNEL Work Hygienic Practices:DONOT INHALE DUST CREATED BY ABRADING ACTIONS. USE FULL PROTECTION AGAINST AIRBORNE FIBERS. AVOID AIRBORNE DUST CREATION Supplemental Safety and Health GENERIC "MSDS" CREATED FOR "NSN" IDENTIFIED BY "DISC" AS CONTAINING ASBESTOS.WHEN A MANUFACTURER'S SPECIFIC "MSDS" IS PROVIDED FOR MATERIAL PROCURED UNDER THIS NSN, THIS GENERIC "MSDS" WILL BE REMOVED. ================== Physical/Chemical Properties ================== HCC:T6 Evaporation Rate & Reference:NONE Solubility in Water:NOT SOLUBLE Appearance and Odor:MANUFACTURED COMMODITY DESCRIBED BY LOGISTICS: "ITEM-NAME" Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN Stability Condition to Avoid:NONE KNOWN ==================== Disposal Considerations ==================== Waste Disposal Methods:DUST SHOULD BE HANDLED AS A HAZARDOUS AIR POLLUTANT I/A/W 40CFR61 SUBPART "M" PERTAINING TO ASBESTOS. USE LANDFILLS APPROVED FOR ASBESTOS DISPOSAL. NOTE IF ITEM UNDER CONSIDERATION FOR DISPOSAL IS "FRIABLE OR NON-FRIABLE".
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:URESOLVE PLUS Preparer's Name:JAY W. PARTON CAGE:FO122 CAGE:FO122 CAGE:27908 ============= Composition/Information on Ingredients ============= Ingred Name:2-METHOXYETHANOL (EGME) (SARA III) CAS:109-86-4 RTECS #:KL5775000 Fraction by Wt: 60-80% Other REC Limits:16 PPM OSHA PEL:S, 25 PPM ACGIH TLV:S, 5 PPM; 9192 Ingred Name:POTASSIUM HYDROXIDE (SARA III) CAS:1310-58-3 RTECS #:TT2100000 Fraction by Wt: 2-4% Other REC Limits:2 MG/CUM (CEILING) OSHA PEL:C, 2 MG/M3 ACGIH TLV:C 2 MG/M3; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE/SKIN: IRRITATION. INHALATION: HEADACHE, DIZZINESS, DROWSINESS, FATIGUE, NAUSEA, VOMITING, TREMOR, CONFUSION. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: OVEREXPOSURE MAY CAUSE INJURY TO BONE MARROW & BLOOD CELLS, KIDNEY, LIVER, & TESTES. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN & CALL PHYSICIAN. EYES: FLUSH W/WATER FOR 15 MINS. CALL PHYSICIAN. SKIN: REMOVE CONTAMINATED CLOTHING/FLUSH W/WATER. INGESTION:INDUCE VOMITING. CALL PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:135F Lower Limits:2.5% Upper Limits:19.8% Extinguishing Media:WATER SPRAY, CO2, ALCOHOL FOAM, DRY CHEMICAL Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & FULL PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:WEAR SUITABLE PROTECTIVE EQUIPMENT. SMALL SPILLS SHOULD BE FFLUSHED W/LARGE QUANTITIES OF WATER. LARGES SPILLS SHOULD BE COLLECTED FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T BREATHE VAPOR, USE WITH ADEQUATE VENTILATION. DON'T GET IN EYES, ON SKIN, OR CLOTHING. ACCIDENTAL CONTACT SHOULD BE WASHED AWAY IMMEDIATELY. Other Precautions:KEEP AWAY FROM HEAT/FLAME. KEEP CONTAINER CLOSED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED RESPIRATOR FOR HIGH CONCENTRATIONS. Ventilation:LOCAL EXHAUST: WELL VENTILATION AREA. MECHANICAL: EXHAUST HOOD Other Protective Equipment:IMPERMEABLE APRON Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:256F Vapor Pres:6.2 Vapor Density:2.62 Spec Gravity:0.97 Evaporation Rate & Reference:(BU AC = 1) 0.62 Solubility in Water:COMPLETE Appearance and Odor:BLUE TO GREEN LIQUID, SLIGHT PLEASANT ODOR. Percent Volatiles by Volume:100% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HEAT, FLAME, IGNITION SOURCES Hazardous Decomposition Products:CO, CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE IN A FURNACE WHERE PERMITTED UNDER APPROPRIATE FEDERAL, STATE, AND LOCAL REGULATIONS. COMBUSTIBLE LIQUID.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BARIUM SULFATE BARIMITE XF, BARIMITE UF Preparer's Name:QUALITY ASSURANCE DEPT CAGE:TO910 CAGE:TO910 ============= Composition/Information on Ingredients ============= Ingred Name:BARITE CAS:7727-43-7 RTECS #:CR0600000 Minumum % Wt:94. Maxumum % Wt:100. OSHA PEL:5 MG/M3 TWA (RESP DU ACGIH TLV:10 MG/M3 TOTAL DUST Ingred Name:QUARTZ. CRYSTALLINE SILICA. CAS:14808-60-7 RTECS #:VV7330000 < Wt:.04 OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:BARITE, A NUISANCE DUST. ACUTE EXPOSURE: INHALATION: INHALATION OF FINE BARITE DUST MAY CAUSE IRRITATION OF THE NOSE AND THROAT BY MECHANICAL ACTION. SKIN CONTACT: DIRECT CONTACT MAY CAUSE SLIGHT DRYN ESS, OR MAY CAUSE MILD IRRITATION IF AN ALLERGIC PREDISPOSITION EXISTS. EYE CONTACT: DIRECT CONTACT WITH DUST MAY CAUSE MECHANICAL IRRITATION OF EYES. INGESTION: BARITE IS CONSIDERED TO BE RELATIVELY NON-TOXIC DUE TO NON-ABSORPTION. CHRONIC EXPOSURE: INHALATION: PROLONGED OR REPEATED INHALATION MAY CAUSE BARITOSIS, A BENIGN PNEUMOCONIOSIS. SKIN CONTACT: NO DATA AVAILABLE. EYE CONTACT: NO DATA AVAI LABLE. INGESTION: NO DATA AVAILABLE. Explanation of Carcinogenicity:PRODUCT CONTAINS QUARTZ (CRYSTALLINE SILICA) WHICH IS A KNOWN CARCINOGEN. IT IS HOWEVER PRESENT AT LESS THAN 0.1%. Effects of Overexposure:SEE HEALTH HAZARDS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE FROM EXPOSURE TO FRESH AIR. IF BREATHING HAS STOPPED, PERFORM ARTIFICIAL RESPIRATION, & GET MEDICAL ATTENTION IMMEDIATELY. KEEP PERSON WARM & AT REST. TREAT SYMPTOMATICALLY & SUPPOR TIVELY. SKIN: APPLY COMMON SKIN MOSITURIZERS TO RELIEVE DRYNESS. IRRITATIONS ARE UNCOMMON; HOWEVER, IF IRRIT/REDNESS DEVELOPS, SEEK MEDICAL ATTENTION. BROKEN SKIN MAY BE CLEANED WITH MILD SOAP & WATER . EYES: WASH WITH LARGE AMOUNTS OF WATER OR NORMAL SALINE SOLUTION. IF IRRITATION OR REDNESS DEVELOPS, SEEK MEDICAL ATTENTION. INGEST: TREAT SYMPTOMATICALLY & SUPPORTIVELY. IF VOMIT OCCURS, KEEP HEAD LOWER THAN HIPS TO PREVENT ASPIRATION. ===================== Fire Fighting Measures ===================== Flash Point:NONE. Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:NO SPECIAL PRECAUTIONS INDICATED. Neutralizing Agent:N/P. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE: PRESERVE IN SEALED CONTAINERS TO PREVENT DISPERSION OF DUST IN AIR. OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS WHEN STORING THIS SUBSTANCE. FOR ASSISTANCE DETERMINING PROPER STORAGE OR DISPOSAL PROCEDURES, CONTACT THE DISTRICT DIRECTOR OF THE ENVIRONMENTAL PROTECTION AGENCY. Other Precautions:N/P. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:THE FOLLOWING RESPIRATORS ARE RECOMMENDED BASED ON INFO FOUND IN PHYSICAL DATA, TOXICITY & HEALTH EFFECTS SECTIONS. THEY ARE RANKED IN ORDER FROM MINIMUM TO MAXIMUM RESP PROTECTION. SPECIFIC RESPIRATO R SELECTED MUST BE BASED ON CONTAM LEVELS IN WORK PLACE, THE SPECIFIC OPERATION, MUST NOT EXCEED WORK LIMITS OF RESPIRATOR AND BE NIOSH (ECOLOGICAL INFORMATION) Ventilation:LOCAL EXHAUST OR PROCESS ENCLOSURE VENTILATION TO MEET PUBLISHED EXPOSURE LIMITS. REQUIREE BUT (SUPP DATA) DUST (SUPP DATA) Other Protective Equipment:WHERE THERE IS POSSIBILITY THAT EYE MAY BE EXPOSED TO BULK QUANTITIES/ HIGH CONCENTRATION OF AIR-BORN DUST OF SUBSTANCE, PROVIDE EYEWASH FOUNTAIN MEETING ANSI DESIGN CRITERIA WITHIN IMMEDIATE WORK AREA. Work Hygienic Practices:CLOTHING: PROTECTIVE CLOTHING IS NOT REQUIRED (MFR). Supplemental Safety and Health PHYSICAL/CHEMICAL PROPERTIES (CONT'D): HARDNESS: 2.5 - 3.5 MOHS. TO PREVENT EYE CONTACT WITH BULK QUANTITIES OR HIGH CONCENTRATIONS OF AIR-BORN DUST OF THIS SUBSTANCE (MFR). ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:NOT AVAILABLE. Spec Gravity:4.3 - 4.5 Solubility in Water:INSOLUBLE. Appearance and Odor:WHITE TO TAN COLORED POWDER. ODOR: NONE SPECIFIED BY MANUFACTURER . ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES INCOMPATIBILITIES: WITH POWDERED ALUMINUM, VIOLENTLY EXPLOSIVE; WITH PHOSPHORUS (PRIMED WITH POTASSIUM NITRATE-CALCIUM SILICIDE), IGNITES. Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND PRESSURES. CONDITIONS TO AVOID: N/P. Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE TOXIC AND HAZARDOUS OXIDES OF SULFUR AND BARIUM. Conditions to Avoid Polymerization:HAZARDOUS POLYMERIZATION HAS NOT BEEN REPORTED TO OCCUR UNDER NORMAL TEMPERATURES AND PRESSURES. =================== Toxicological Information=================== Toxicological Information:TOXICITY DATA: TUMORIGENIC DATA (RTECS), MUTAGENIC DATA (RTECS). EXPOSURE LIMIT: BARITE: OSHA TWA TOTAL DUST: 10 MG/M3. ===================== Ecological Information ===================== Ecological:N/P. RESPIRATORY PROTECTION (CONT'D): APPROVED: ANY DUST & MIST RESPIRATOR W/FULL FACEPIECE; ANY AIR PURYFYING FULL FACEPIECE RESPIRATOR W/ HIGH EFFICIENCY PARTICULATE FILTER; ANY POWERED AIR PURYFYIN G RESPIRATOR W/TIGHT FITTING FACEPIECE & HIGH EFFICIENCY PARTICULATE FILTER.; ANY TYPE 'C' SUPPLIED-AIR RESPIRATOR W/FULL FACEPIECE OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE OR WITH A FULL FACEPIECE, HELMET OR HOOD OPERATED IN CONTINUOUS-FLOW MODE; ANY SELF-CONTAINED BREATHING APPARATUS WITH A FULL FACEPIECE OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DRY MATERIAL CAN BE LANDFILLED. WET MATERIAL CAN BE SEWERED, IF QUANTITIES ARE SMALL AND DILUTED ENOUGH THAT SLURRIES OR GELS WILL NOT CAUSE DRAIN SYSTEM BLOCKAGE. OBSERVE ALL FEDERAL, STATE AND LOCA L REGULATIONS WHEN DISPOSING OF THIS SUBSTANCE. BARITE IS NOT CONSIDERED A HAZARDOUS WASTE BY RCR A CRITERIA (40CFR261). =================== MSDS Transport Information =================== Transport Information:D.O.T. CLASS: THIS SUBSTANCE IS NOT REGULATED AS HAZARDOUS MATERIAL BY DOT. ===================== Regulatory Information ===================== SARA Title III Information:BARITE WAS ORIGINALLY SUBJECT TO SECTION 313 REPORTING REQUIREMENTS BECAUSE IT MET THE DEFINITION OF A BARIUM COMPOUND. ON 6/24/94, THE EPA EXEMPTED BARITE FROM REPORTING REQUIREMENTS AFTER REVIEWING AVAILABLE DATA ON THE HEALTH AND ENVIRONMENTAL EFFECTS OF BARITE. REPORTING REQUIREMENTS (40 CFR PART 372.22) ARE RESCINDED. Federal Regulatory Information:ALL INGREDIENTS ARE ON THE TSCA CHEMICAL SUBSTANCE INVENTORY. State Regulatory Information:SUBSTANCES ON THE NEW JERSEY WORKPLACE HAZARDOUS SUBSTANCES LIST PRESENT AT A CONCENTRATION OF 1% OR MORE (0.1% FOR SUBSTANCES IDENTIFIED AS CARCINOGENS, MUTAGENS OR TERATOGENS): QUARTZ, P. 113; BARIT E, P. 14. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TT-P-664C RUST INHIBITING PRIMER CAGE:80592 CAGE:80592 ============= Composition/Information on Ingredients ============= Ingred Name:ZINC CHROMATE CAS:13530-65-9 RTECS #:GB3290000 Fraction by Wt: 4.0% Other REC Limits:0.05MG/M3 OSHA PEL:0.1 MG/M3 (CRO3) ACGIH TLV:0.01MG/M3(CR)A1;9192 Ingred Name:ALKYD Fraction by Wt: OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:LEAD DRIER (OSHA PEL FROM 29CFR 1910.1025) Fraction by Wt: 0.13% Other REC Limits:0.05MG/M3 OSHA PEL:0.05 MG/M3 (PB) ACGIH TLV:0.15 MG/M3 (PB);8990 Ingred Name:ETHYL BENZENE (SARA III) CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 2.1% Other REC Limits:100PPM OSHA PEL:100 PPM/125 STEL ACGIH TLV:100 PPM/125STEL 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 2.2% Other REC Limits:100PPM OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:VM&P NAPHTHA (LIGROINE) CAS:8032-32-4 RTECS #:OI6180000 Fraction by Wt: 24.6% Other REC Limits:300 PPM OSHA PEL:300 PPM/400 STEL ACGIH TLV:300 PPM; 9192 Ingred Name:ISOBUTYL ALCOHOL (SARA III) CAS:78-83-1 RTECS #:NP9625000 Fraction by Wt: 6.3% Other REC Limits:50PPM OSHA PEL:100 PPM ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:N-BUTYL ALCOHOL (SARA III) CAS:71-36-3 RTECS #:EO1400000 Fraction by Wt: 3.7% Other REC Limits:50PPM OSHA PEL:100 PPM ACGIH TLV:S, C 50 PPM; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:N/K Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:SEE SIGNS AND SYMPTOMS OF OVEREXPOSURE SECTION . Explanation of Carcinogenicity:ZINC CHROMATE:ACGIH:SUSPECT HMN CARC.IARC:HMN CARC(GROUP 1);NTP:CHROM-N-CERT CHROM CMPDS:KNOWN CARCINOGEN;OSHA:NO. Effects of Overexposure:IRRITATION TO EYES; NOSE AND THROAT NEAR OR ABOVE 50PPM FROM VAPORS. HIGHER CONCENTRATIONS COULD CAUSE DEATH FROM EXPLOSION OR FROM BREATHING. Medical Cond Aggravated by Exposure:N/K ======================= First Aid Measures ======================= First Aid:EYES:FLUSH IMMED W/PLENTY OF WTR FOR 15MIN AND CALL A PHYSICIAN.INHALATION:REMOVE TO FRESH AIR.IF NOT BREATHING GIVE ARTIFICIAL RESP;PREF MOUTH TO MOUTH.CALL A PHYSICIAN.INGESTION:CALL A PHYSICIAN IMM EDIATELY. DO NOT INDUCE VOMITING. SKIN:WASH THOROUGHLY WITH SOAP AND WATER. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:50F/10C Lower Limits:N/K Upper Limits:N/K Extinguishing Media:FOAM, DRY CHEMICAL, WATER Fire Fighting Procedures:SELF-CONT BREATH APP,WATER FOG TO COOL EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:KEEP AWAY FROM HEAT, SPARKS, FLAME ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION(FLAMES,ELECTRICAL,STATIC/FRICT SPK,HOT SURFACES,ETC.).AVOID BRTH OF VAPORS.VENT AREA.CONT & SCOOP UP SPILL W/NON-SPARK TOOLS,RAGS,ETC.USE INERT ABSORB MATL ON SMALL SPIL LS OR ON RESIDUALS OF LARGE SPILLS. Neutralizing Agent:N/K ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CNTNR CLO & UPRGHT TO PVNT LEAK.AVOID FLM,WELD,SMK,SPK,OPEN LGHT,ETC.AVOID BRTH OF VAPOR/SPR MST.AVOID EYE & SKIN CONTACT. Other Precautions:MAINTAIN GOOD PERSONAL HYGIENE. DO NOT USE IN CONFINED AREAS, TANK/PIT W/OUT ADEQUATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ORGANIC VAPOR CANISTER WHERE OXYGEN CONTENT IS ADEQUATE AND VAPOR CONCENTRATION IS LESS THAN 2% OR USE AIR SUPPLIED FACE MASKS. Ventilation:LOCAL/MECHANICAL EXHAUST Other Protective Equipment:N/K Work Hygienic Practices:SEE OTHER PRECAUTIONS Supplemental Safety and Health PH:N.RT OF ENTRY:FPN ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:N/K Decomp Temp:Decomp Text:N/K Vapor Pres:N/K Vapor Density:N/K Spec Gravity:0.8 pH:N/K-FP Evaporation Rate & Reference:MOD FAST (N-BU-AC=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:RED VISCOUS LIQUID WITH TYPICAL SOLVENT ODOR Percent Volatiles by Volume:63.4 Corrosion Rate: ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES N/K Stability Condition to Avoid:N/K Hazardous Decomposition Products:N/K ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH LOCAL,STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:302 ZINC WIRE CAGE:12673 CAGE:12673 ============= Composition/Information on Ingredients ============= Ingred Name:ZINC (SARA III) CAS:7440-66-6 RTECS #:ZG8600000 Fraction by Wt: 99.99% OSHA PEL:10 MG ZNO/M3 ACGIH TLV:10 MG ZNO/M3; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:TLV: 5 MG/CUM Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:AVOID BREATHING DUST DURING SPRAYING. Explanation of Carcinogenicity:NONE Effects of Overexposure:FOR EXACT PHYSIOLOGICAL EFFECTS REFERENCE SHOULD BE MADE TO AUTHORITATIVE SOURCES SUCH AS "DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS" BY N. IRVING SAX. ============= Exposure Controls/Personal Protection ============= Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:1662F Solubility in Water:INSOLUBLE Appearance and Odor:BLUISH WHITE--NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:W/B ACRYLIC ENAMEL YELLOW, 728Y037 CAGE:04GC9 CAGE:04GC9 CAGE:0RGC9 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANOL, 2-BUTOXY-; (2-BUTOXYETHANOL). VP:0.8 @ 68F CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: 8% OSHA PEL:S, 50 PPM ACGIH TLV:S, 25 PPM Ingred Name:ETHANOL, 2-(2-BUTOXYETHOXY)-; (DIETHYLENE GLYCOL MONOBUTYL ETHER). VP:0.0 @ 68F CAS:112-34-5 RTECS #:KJ9100000 Fraction by Wt: 2% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:PHTHALIC ACID, BENZYL BUTYL ESTER; (BUTYL BENZYL PHTHALATE) (SARA 313) (CERCLA). VP:0.2 @ 302F CAS:85-68-7 RTECS #:TH9990000 Fraction by Wt: <5.0% OSHA PEL:5 MG/M3 (MFR) ACGIH TLV:5 MG/M3 (MFR) EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:BENZOIC ACID, AMMONIUM SALT; (AMMONIUM BENZOATE) (CERCLA) CAS:1863-63-4 RTECS #:DG3378000 Fraction by Wt: <5.0% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:AMMONIUM HYDROXIDE (CERCLA). VP:420.0 @ 60F CAS:1336-21-6 RTECS #:BQ9625000 Fraction by Wt: <5.0% OSHA PEL:N/K ACGIH TLV:25 PPM (MFR) EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHANOL, 2-(2-METHOXYETHOXY)-; (DIETHYLENE GLYCOL MONOMETHYL ETHER). VP:0.1 @ 20F CAS:111-77-3 RTECS #:KL6125000 Fraction by Wt: <0.5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: <5.0% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:VOLATILE ORGANIC CONTENT. COATING:1.99 LB/GL (239 G/L). MATERIAL:0.83 LB/GL (99 G/L) RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ANIMAL STUDIES HAVE CLEARLY DEMONSTRATED DOSE-RELATED ADVERSE EFTS ON THE CNS, HEMATOPOIETIC TISS, BLOOD, KIDNEYS & LIVER ASSOC W/ADMIN OF ETHYLENE GLYCOL MONOBUTYL ETHER (EGBE). (EXTRACTED FROM DHHS (NIOSH) PUB NO. 90-118) . ACUTE:INHAL:CONCENTRATED VAPORS MAY BE HARMFUL. MAY CAUSE HDCH, DIZZ (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:& NAUS. SKIN & EYE CONT:MAY CAUSE IRRIT TO BOTH. SKIN ABSORP:MAY CAUSE IRRIT. INGEST:MAYBE HARMFUL IF SWALLOWED. CHRONIC:NONE LISTED BY MANUFACTURER. Medical Cond Aggravated by Exposure:PRE-EXISTING EYE, SKIN AND RESPIRATORY DISORDER MAY BE AGGRAVATED. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR. EYES:FLUSH IMMED W/LG AMTS OF WATER FOR @ LEAST 15 MINS. SKIN:WASH AFFECTED AREAS W/SOAP & WATER. REMOVE CONTAMD CLTHG. INGEST:DO NOT INDUCE VOMIT. GET MEDICAL ATTENTION IMM EDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:>200F,>93C Lower Limits:0.3% Upper Limits:10.6% Extinguishing Media:FOAM, ALCOHOL FOAM, CO*2, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:MATL WILL NOT SUSTAIN COMBUST UNLESS WATER HAS EVAP. FIRE-EXPOS CNTNRS SHOULD BE COOLED W/WATER TO PVNT PRESS BUILD-UP WHICH COULD RSLT IN CNTNR RUPTURE. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT & PROVIDE VENT. LG SPILLS MAY BE SCOOPED UP W/NON-SPARKING TOOLS. SM SPILLS MAY BE PICKED UP W/ABSORB MATERIALS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM HIGH TEMPERATURES AND OPEN FLAMES. KEEP CONTAINERS TIGHTLY CLOSED. DO NOT TAKE INTERNALLY. AVOID PRLONGED CONT WITH SKIN. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN CASE OF POOR VENTILATION, USE NIOSH/MSHA APPROVED ORGANIC VAPOR MASK. Ventilation:ADEQUATE VOLUME & PATTERN TO KEEP AIR CONTAMINANT CONCENTRATION BELOW CURRENT APPLIC OSHA/ACGIH'S TLV LIMITS. Other Protective Equipment:EYE BATH AND SAFETY SHOWER. Work Hygienic Practices:WASH HANDS BEFORE EATING OR USING WASHROOM. SMOKE IN SMOKING AREAS ONLY. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>195F,>91C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:1.0 (H*2O=1) Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:SOLUBLE Appearance and Odor:YELLOW LIQUID WITH MILD ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:EXCESSIVE HEAT AND OPEN FLAMES. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY YIELD CARBON DIOXIDE AND/OR CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:PLACE IN TIGHTLY CLOSED CONTAINERS. INCINERATE OR DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:9515101-9515108 SPECTRUM SHOULDER PORCELAIN CAGE:16969 CAGE:8T797 CAGE:16969 ============= Composition/Information on Ingredients ============= Ingred Name:CERAMIC FRIT Fraction by Wt: MAJOR ACGIH TLV:10 MG/CUM GLASS DUST ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:DUST MAY ALLOW METALS WITHIN FRIT TO BE LEACHED WHILE IN THE DIGESTIVE TRACT/GLASSY POWDERED MATERIAL CARRIES WITH IT THE DANGER OF POSSIBLE SILICEOUS (DISEASE OF LUNGS)-LIKE EFFECTS. Explanation of Carcinogenicity:NONE Effects of Overexposure:DUST MAY ALLOW METALS WITHIN FRIT TO BE LEACHED WHILE IN THE DIGESTIVE TRACT/GLASSY POWDERED MATERIAL CARRIES WITH IT THE DANGER OF POSSIBLE SILICEOUS (DISEASE OF LUNGS)-LIKE EFFECTS. Medical Cond Aggravated by Exposure:LUNG DISEASE ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE FROM DUSTY AREA. SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/WATER FOR AT LEAST 15 MINUTES. CONSULT PHYSICIAN. ===================== Fire Fighting Measures ===================== Extinguishing Media:NO FIRE HAZARD Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:HANDLE AS NORMAL SOLID WASTE. SCOOP UP & PLACE IN APPROPRIATELY MARKED CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM FOOD & DRINK. WASH HANDS BEFORE EATING. THIS MATERIAL SHOULD BE HANDLED & USED ONLY IN A MANNER CONSISTENT W/THE PRODUCT INSTRUCTIONS. Other Precautions:EFFORTS SHOULD BE MADE TO MINIMIZE EXPOSURE & ENCOURAGE GOOD PERSONAL HYGIENE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED FOR DUSTS & MISTS. Ventilation:USE LOCAL EXHAUST OR OTHER MEANS TO MINIMIZE DUST EXPOSURE. Work Hygienic Practices:ENCOURAGE GOOD PERSONAL HYGIENE. WASH HANDS BEFORE EATING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Solubility in Water:INSOLUBLE Appearance and Odor:POWDER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES HYDROFLUORIC ACID Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE MATERIAL MAY BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE, & LOCAL ENVIRONMENTAL CONTROL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:72828 - KARALLOY BRAZING ALLOY CAGE:GO039 CAGE:5L381 CAGE:GO039 ============= Composition/Information on Ingredients ============= Ingred Name:SUPDAT:TO FUME PLUME, AS WELL AS PRESENCE OF CONTAMS IN ATM (SUCH AS CHLORINATED HYDROCARBON VAPS FROM CLEANING (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:& DEGREASING ACTIVITIES). WHEN ROD IS CONSUMED, FUME & GAS DECOMP PRODS ARE DIFF IN PERCENT & FORM FROM (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:INGS LISTED. FUME & GAS DECOMP PRODS, NOT INGS IN ROD, ARE IMPORTANT. DECOMP PRODS INCL THOSE ORIGINATING(ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:FROM VOLATILIZATION, RXN/OXIDIATION OF MATLS SHOWN IN INGS SECTION PLUS THOSE FROM BASE METAL, COATING, (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:ETC. THESE COMPONENTS ARE VIRTUALLY ALWAYS PRESENT AS COMPLEX CMPDS & NOT AS METALS. REAS EXPECTED FUME (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:CONSTITUENTS WOULD INCL FLUORIDES & COMPLEX OXIDES OF IRON, ALUMINUM, MANGANESE, SILICON, NICKEL, COPPER.(ING 16) RTECS #:9999999ZZ Ingred Name:ING 15:GASEOUS RXN PRODS MAY INCL CARBON MONOXIDE & CARBON DIOXIDE. OZONE & NITROGEN OXIDES MAY BE FORMED BY (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16:RADIATION OF THE ARC. RTECS #:9999999ZZ Ingred Name:EXPLAN OF CARCIN:REPORT ON CARCINS, 1991:ANTIC TO BE CARCIN. HUMAN:LUNGS, NASAL CAVITIES. RTECS #:9999999ZZ Ingred Name:EYE PROT:LENS. AS A RULE OF THUMB, START W/SHADE WHICH IS TOO DARK TO SEE WELD ZONE. THEN GO TO NEXT LIGHTER (ING 20) RTECS #:9999999ZZ Ingred Name:ING 19:SHADE WHICH GIVES OFF SUFFICIENT VIEW OF WELD ZONE. PROVIDE SCREENS & FLASH GOGGS, IF NEC, TO SHIELD OTHERS. RTECS #:9999999ZZ Ingred Name:OTHER PROT EQUIP:INCLUDE ARM PROTECTORS, APRONS, HATS, SHOULDER PROTECTION, AS WELL AS DARK SUBSTANTIAL CLOTHING. RTECS #:9999999ZZ Ingred Name:ZINC (SARA III) CAS:7440-66-6 RTECS #:ZG8600000 OSHA PEL:10 MG/M3 (ZNO) ACGIH TLV:10 MG/M3 (ZNO) EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:IRON (MFR CAS #7440-89-6) CAS:7439-89-6 RTECS #:NO4565500 OSHA PEL:10 MG/M3 ACGIH TLV:5 MG/M3 Ingred Name:MANGANESE (SARA III) CAS:7439-96-5 RTECS #:OO9275000 OSHA PEL:5 MG/M3 DUST, C ACGIH TLV:5 MG/M3 DUST Ingred Name:NICKEL (SARA III) CAS:7440-02-0 RTECS #:QR5950000 OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3 Ingred Name:SILICON CAS:7440-21-3 RTECS #:VW0400000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:TIN (MFR CAS #7440-3-5) CAS:7440-31-5 RTECS #:XP7320000 OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3 Ingred Name:SILVER (SARA III) CAS:7440-22-4 RTECS #:VW3500000 OSHA PEL:0.01 MG/M3 ACGIH TLV:0.1 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ALUMINUM (SARA III) (MFR CAS #7429-90-4) CAS:7429-90-5 RTECS #:BD0330000 OSHA PEL:15 MG/M3 DUST;5 FUME ACGIH TLV:10 MG/M3 DUST Ingred Name:COPPER (SARA III) CAS:7440-50-8 RTECS #:GL5325000 OSHA PEL:0.1MG/M3 FUME;1 DUST ACGIH TLV:0.2MG/M3 FUME EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:FUMES & GASES CAN BE DANGEROUS TO YOUR HEALTH. ACUTE:SHORT-TERM OVEREXPOSURE TO WELDING FUMES MAY RESULT IN DISCOMFORT SUCH AS:DIZZINESS, NAUSEA OR DRYNESS OR IRRITATION OF NOSE, THROAT OR EYES. CHRON IC:LONG-TERM OVEREXPOSURE MAY LEAD TO SIDEROSIS (IRON DEPOSITS IN LUNGS) & IS BELIEVED BY SOME (EFTS OF OVEREXP) Explanation of Carcinogenicity:NICKEL:IARC MONOGRAPHS ON EVALUATION OF CARCIN RISK OF CHEMS TO MAN, VOL 49, PG 257, 1990:GRP 2B. NTP 6TH ANNUAL(ING 18) Effects of Overexposure:HLTH HAZ:INVESTIGATORS TO AFFECT PULMONARY FUNCTION. ARC RAYS CAN INJURE EYES & BURN SKIN. ELECTRIC SHOCK CAN KILL. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:CALL FOR MEDICAL AID. EMPLOY FIRST AID TECHNIQUES RECOMMENDED BY AMERICAN RED CROSS. INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:I MMEDIATELY FLUSH W/POTABLE WATER FOR A MINIMUM OF 15 MINUTES, SEEK ASSISTANCE FROM MD . SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:BRAZING SPARKS CAN IGNITE COMBUSTIBLES. REFER TO ANSI 249.1 FOR FIRE PREVENTION DURING WELDING. ================== Accidental Release Measures ================== Spill Release Procedures:NONE SPECIFIED BY MANUFACTURER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:READ & UNDERSTAND MFR'S INSTRUCTIONS & PRECAUTIONARY LBL ON THIS PROD. SEE ANSI Z-49.1, SAFETY IN WELDING & CUTTING. Other Precautions:TRAIN THE WELDER TO KEEP HIS HEAD OUT OF THE FUMES. TRAIN THE WELDER NOT TO TOUCH LIVE ELECTRICAL PARTS & TO INSULATE HIMSELF FROM WORK & GROUND. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRABLE FUME RESPIRATOR OR AIR SUPPLIED RESPIRATOR WHEN WELDING IN CONFINED SPACE OR WHERE LOCAL EXHAUST OR VENTILATION DOES NOT KEEP EXPOSURE BELOW TLV. Ventilation:USE ENOUGH VENT, LOCAL EXHAUST AT THE ARC, OR BOTH, TO KEEP FUMES & GASES BELOW TLV'S IN WORKER'S BRTHG ZONE & GEN AREA. Other Protective Equipment:WEAR HEAD, HAND & BODY PROT WHICH HELP TO PVNT INJURY FROM RADIA, SPKS & ELEC SHOCK. SEE ANSI Z-49.1. THIS MAY (ING 21) Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health HAZ DECOMP PROD:PROCESS, PROCS & RODS USED. OTHER CNDTNS WHICH ALSO INFLUENCE COMPOSITION & QTY OF FUMES & GASES TO WHICH WORKERS MAY BE EXPOS INCL:COATINGS ON METAL BEING WELDED(SUCH AS PAINT, PLATIN G/GALVANIZATION), NUMBER OF WELDS & VOLOF WORK AREA, QUALITY & AMT OF VENT, POSITION OF WELDER'S HEAD W/RESPECT(ING 10) ================== Physical/Chemical Properties ================== HCC:N1 Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:BRAZING FUMES CANNOT BE SIMPLY CLASSIFIED. COMPOSITION & QTY OF BOTH ARE DEPENDENT UPON METAL BEING BRAZED, (SUPDAT) ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:184 5650,INDUSTREX DEVLPR REPL,PART-C Kit Part:Y CAGE:19139 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 70-75% Ingred Name:GLUTARALDEHYDE-BIS-BISULFITE CAS:7420-89-5 Fraction by Wt: 20-25% Other REC Limits:NONE ESTABLISHED OSHA PEL:NONE ESTABLISHED ACGIH TLV:NONE ESTABLISHED Ingred Name:GLUTARALDEHYDE CAS:111-30-8 RTECS #:MA2450000 Fraction by Wt: 10-15% OSHA PEL:C 0.2 PPM ACGIH TLV:C 0.2 PPM; 9192 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SEE "OVEREXPOSURE SYMPTOM" Effects of Overexposure:INHALE:IRRITNT;EYES:BURNS;SKIN:EXTENDED CONTACT CAUSES IRRITATION/REPEATED CONTACT:ALLERGIC REACTION ======================= First Aid Measures ======================= First Aid:INHALE:REMOVE TO FRESH AIR, GIVE CPR/O*2 IF NEED;EYES:FLUSH W LG AMTS H*2O FOR 15 MIN;SKIN:FLUSH W LG AMTS H*2O;INGEST:RINSE MOUTH; GET IMMEDIATE ATTENTION FOR EYES OR INGEST. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR SELF-CNTND BRTHG APP;H*2O SPRAY COOL CONT. Unusual Fire/Explosion Hazard:CONTAINERS MAY EXPLODE IN HEAT OF FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE UNPROTECTED PERSONS. ELIM IGNITION SOURCES. STOP LEAK. H*2O SPRAY COOL CONT/DIVERT SPILL FROM FIRE/HEAT. PROVIDE VENTILATION. ABSORB W COMMERCIAL ABSORBENT,SHOVEL INTO METAL DRUMS;LG SPILL:DI KE W COMMERCIAL ABSORBENT,PUMP INTO COVERED DRUMS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED,LOW FIRE RISK AREA. PROTECT FROM PHYSICAL DAMAGE. AVOID ANY PHYSICAL CONTACT. KEEP CONTAINERS TIGHTLY CLOSED. Other Precautions:AVOID PROLONGED OR REPEATED CONTACT W CHEMICAL. REMOVE & WASH CONTAMINATED CLOTHING. MAINTAIN STRICT HYGIENE. USE OF NON-ALKALINE(ACID) TYPE HAND CLEANER REDUCES RISK OF ALLERGIC SKIN REACTION ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE APPROVED ORGANIC VAPOR RESPIRATOR IF POOR VENTILATION. Ventilation:MECHANICAL(GEN./LOCAL EXHAUST) Other Protective Equipment:NORMAL FULL WORK CLOTHING COVERING ARMS,LEGS:NO SKIN CONTACT Supplemental Safety and Health KEY1:N1. PART C OF A THREE PART PRODUCT UNDER SAME NSN. ================== Physical/Chemical Properties ================== HCC:F6 Boiling Pt:B.P. Text:>212F,100C Vapor Pres:17 Vapor Density:0.6 Spec Gravity:1.15 pH:3 Solubility in Water:COMPLETE Appearance and Odor:CLEAR TO LIGHT BROWN LIQUID;ALDEHYDE ODOR. Percent Volatiles by Volume:93 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MINERAL ACIDS Stability Condition to Avoid:NONE NOTED Hazardous Decomposition Products:SULFUR DIOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:KEEP IN COVERED DRUMS,PENDING DISPOSAL. HANDLE & DISPOSE IN FULL COMPLIANCE WITH ALL APPLICABLE INTERNATIONAL,FEDERAL,STATE & LOCAL REGULATIONS. MFG SUGGESTS REACT W SODIUM BISULFITE & FLUSH TO SEWER W EXCESS WATER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:857, PAINT REMOVER CAGE:88304 CAGE:78304 CAGE:88304 ============= Composition/Information on Ingredients ============= Ingred Name:METHYLENE CHLORIDE(SARA III) CAS:75-09-2 RTECS #:PA8050000 OSHA PEL:500 PPM/C,1000; Z2 ACGIH TLV:50 PPM, A2; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:PETROLEUM DISTILLATES (NAPHTHA OR RUBBER SOLVENT) CAS:8002-05-9 RTECS #:SE7449000 Fraction by Wt: <1.0% OSHA PEL:400 PPM ACGIH TLV:400 PPM; 8990 ===================== Hazards Identification ===================== Effects of Overexposure:DIZZINESS ======================= First Aid Measures ======================= First Aid:MOVE TO FRESH AIR. SKIN: WASH W/WARM SOAPY WATER & SEEK MD. EYE: FLUSH W/WATER, SEEK MD. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER, CO*2, FOAM Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:ALLOW EVAPORATION OF SOLVENT, THEN FLUSH RESIDUE INTO SANITARY SEWER, MOP AREA DRY. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE BEYOND 105F Other Precautions:USE NORMAL SAFETY PRECAUTIONS FOR HANDLING ALKALINE SOLVENT TYPE PAINT REMOVERS. ============= Exposure Controls/Personal Protection ============= Ventilation:LOCAL EXH, ADEQUATE Other Protective Equipment:RUBBER APRONS Supplemental Safety and Health % VOLATILE BYVOLUME: 70-75%; SPECIFIC GRAVITY: 1.05 - 1.06. ================== Physical/Chemical Properties ================== NRC/State Lic Num:NA Boiling Pt:B.P. Text:105F Evaporation Rate & Reference:1.0 Appearance and Odor:VISCOUS YELLOW LIQ, AMMONIA ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES PAINTED SURFACES, STRONG ACIDS, STRONG ALKALIES Hazardous Decomposition Products:PHOSGENE, FROM EXTREME THERMAL DECOMPOSITION ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IAW FED, STATE, LOCAL REG
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CRAYOLA WASHABLE PAINT, 54-0105 033-PEACH CAGE:85419 CAGE:85419 ============= Composition/Information on Ingredients ============= Ingred Name:CLAY (KAOLIN); (KAOLIN) CAS:1332-58-7 RTECS #:GF1670500 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:2 MG/M3 TDUST Ingred Name:TALC (POWDER), CONTAINING NO ASBESTOS FIBERS CAS:14807-96-6 RTECS #:WW2710000 OSHA PEL:2 MG/M3 RDUST ACGIH TLV:2 MG/M3 RDUST ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: NONE KNOWN. CHRONIC: NONE KNOWN. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. CONTACT A PHYSICIAN. SKIN: WASH THOROUGHLY WITH SOAP AND WATER. INGESTION: DO NOT INDUCE VOMITING. CONTACT A PHYSICIAN OR POISON CONTROL CENTE R. INHALATION: REMOVE PERSON TO FRESH AIR. ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:NONE Upper Limits:NONE Extinguishing Media:WATER, FOAM, CARBON DIOXIDE. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE KNOWN. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE TO CONTAIN SPILL. KEEP OUT OF SEWERS AND WATERCOURSES. ABSORB WITH INERT MATERIAL AND PLACE IN CONTAINER FOR DISPOSAL. FLUSH RESIDUAL WITH COPIOUS AMOUNTS OF WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AT ROOM TEMPERATURE. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NOT REQUIRED. Other Protective Equipment:NOT REQUIRED. Work Hygienic Practices:CLEAN, SAFE WORK PRACTICES. Supplemental Safety and Health SPEC GRAV: 1.19-1.31 (H*2O=1). ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>215F,>102C Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C Vapor Density:<1 Spec Gravity:SUPDAT Evaporation Rate & Reference:<1 (BUTYL ACETATE=1) Solubility in Water:DISPERSES Appearance and Odor:VARIOUS COLORS; NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE CARBON MONOXIDE AND CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:555245 PRK. SHRUB,TREE & EVGRN. 12-6-6 CAGE:PARKR CAGE:PARKR ============= Composition/Information on Ingredients ============= Ingred Name:UREA; CARBAMIDE CAS:57-13-6 RTECS #:YR6250000 Fraction by Wt: 3-61% Ingred Name:AMMONIATED PHOSPHATES Fraction by Wt: 3-61% Ingred Name:POTASSIUM CARBONATE, POTASH, PEARL ASH CAS:584-08-7 RTECS #:TS7750000 Fraction by Wt: 3-61% Ingred Name:INERT INGREDIENTS (TYPE NOT SPECIFIED) Fraction by Wt: 3-61% ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (LAB ANIMAL): 1500 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INGESTION: HARMFUL. SKIN/EYES/MUCOUS MEMBRANES: IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:SKIN/MUCOUS MEMBRANES: IRRITATION. EYES: IRRITATION & BURNS. ======================= First Aid Measures ======================= First Aid:INGESTION: IF CONSCIOUS, INDUCE VOMITING BY GIVING 1 OR 2 GLASSES OF WATER & TOUCH BACK OF THROAT W/FINGER. NEVER GIVE ANYTHING BY MOUTH IF UNCONSCIOUS/CONVULSIONS. EYES: FLUSH W/PLENTY OF WATER. SKIN : REMOVE CONTAMINATED CLOTHING & WASH AFFECTED AREA W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:>400F Extinguishing Media:WATER, FOAM, OR CO2 Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING & SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:HYDROGEN SULFIDE IS A REACTION PRODUCT & IS TOXIC & EXPLOSIVE. SULFUR DUST WILL EXPLODE AT A MINIMUM CONCENTRATION OF 35 G/CUM AIR. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP PRODUCT & REPLACE IN LABELED CONTAINER. USE PRODUCT ACCORDING TO DIRECTIONS FOR USE/DISPOSE OF A DIRECTED ON LABEL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN ITS ORIGINAL LABELED CONTAINER IN COOL, DRY LOCKED PLACE OUT OF REACH OF CHILDREN. DON'T ALLOW BAGS TO BECOME WET. AVOID TEMPS >212F. Other Precautions:DON'T CONTAMINATE WATER, FOOD, OR FEED BY STORAGE OR DISPOSAL. SHELF LIFE: 5 TO 7 YEARS OF GOOD PHYSICAL CONDITION IF STORED PROPERLY. AVOID CONTACT W/SKIN & EYES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF INADEQUATE VENTILATION WHERE DUST CONCENTRATIONS EXCEED RECOMMENDED PEL'S, USE NIOSH APPROVED DUST RESPIRATORS. Ventilation:ADEQUATE Supplemental Safety and Health COMPLETELY EMPTY BAG INTO APPLICATION EQUIPMENT. DISPOSE OF EMPTY BAG IN A SANITARY LANDFILL/INCINERATION/STATE & LOCAL AUTHORITIES BY BURNING. SOLUBILITY: GENERALLY, SLOWLY SOLUBLE IN SOIL. ================== Physical/Chemical Properties ================== Spec Gravity:0.5606-0.8329 pH:5-8 Solubility in Water:SEE SUPP. Appearance and Odor:NATURAL MINERAL GRANULES W/FERTILIZER SALT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES HYDROGEN SULFIDE Stability Condition to Avoid:HEAT >212F Hazardous Decomposition Products:UREA: CYANURIC ACID/AMMONIA/HYDROGEN CYANIDE/NITROGEN OXIDES/BIURET/CO2. SULFUR COATED UREA: SULFUR & NITROGEN OXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:IF PRODUCT CANNOT BE USED ACCORDING TO INSTRUCTIONS EXCESS PRODUCT MAY BE DISPOSED ON SITE/APPROVED WASTE FACILITY. DISPOSE IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS. SEE SUPP
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:70-2009 RUST KILL LIGHT YELLOW CAGE:EO325 CAGE:91708 CAGE:EO325 ============= Composition/Information on Ingredients ============= Ingred Name:ACETONE (SARA 313) (CERCLA) CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 14.12% Other REC Limits:NONE RECOMMENDED OSHA PEL:1000 PPM ACGIH TLV:750PPM/1000STEL;9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ALIPHATIC HYDROCARBON (MS) CAS:8052-41-3 Fraction by Wt: 0-5% Other REC Limits:NONE RECOMMENDED Ingred Name:N-BUTYL ALCOHOL (SARA 313) (CERCLA) CAS:71-36-3 RTECS #:EO1400000 Fraction by Wt: 2.31% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:S, C 50 PPM; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TOLUENE (SARA 313) (CERCLA) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 11.57% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM; Z-2 ACGIH TLV:S, 50 PPM; 9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ALIPHATIC HYDROCARBON CONTAINS INGREDS #11,12. CAS:64742-89-8 Fraction by Wt: 15-20% Other REC Limits:NONE RECOMMENDED Ingred Name:XYLENES (O-,M-,P- ISOMERS) (SARA 313) (CERCLA) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: <8% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:100 PPM/150STEL;9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHYL BENZENE (SARA 313) CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: <2% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:100 PPM/125STEL;9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENES (O-,M-,P- ISOMERS) (SARA 313) (CERCLA), CONTAINS INGRED #14 CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 1.18% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:100 PPM/150STEL;9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHYL BENZENE (SARA 313) CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 18-20% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:100 PPM/125STEL;9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:VOLITILE ORGANIC CONTENT AS LISTED ON MSDS, 603 GM/L. RTECS #:9999999VC Fraction by Wt: NA Other REC Limits:NONE RECOMMENDED Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 14.97% Other REC Limits:NONE RECOMMENDED OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT; 9596 Ingred Name:BUTANE CAS:106-97-8 RTECS #:EJ4200000 Fraction by Wt: 7.24% Other REC Limits:NONE RECOMMENDED OSHA PEL:800 PPM ACGIH TLV:800 PPM; 9596 Ingred Name:ISOBUTANE CAS:75-28-5 RTECS #:TZ4300000 Fraction by Wt: 7.24% Other REC Limits:NONE RECOMMENDED Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 0-5% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9596 Ingred Name:C.I. PIGMENT YELLOW 73 CAS:13515-40-7 Fraction by Wt: 0-5% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:INHAL:ANESTHETIC.IRRIT RESP TRACT,ACUTE NERV SYS DEPRESS CHARACTERIZED BY FOLLOWING PROGRESSIVE STEPS:HEAD,DIZZ,STAGGERING GAIT,CONFUSION,UNCONSC,COMA,ASPHIXIATION.SKIN/EYE CONTACT:PRIMARY IRRIT .CHRONIC:OVEREXPO TO THIS MATL(OR COMPO)HS BEEN SUGGESTED AS CAUSE OF REPRODUCTIVE DISORDERS,CARDIAC/LIV ABNORM,EYE DMG. Explanation of Carcinogenicity:PER MSDS:CARCINOGENICITY:NTP/IARC/OSHA:NO. Effects of Overexposure:ANESTHETIC,IRRIT RESP TRACT,NERVOUS SYS DEPRESSION-HEADACHE,DIZZ,STAGGERING GAIT,CONFUSION,UNCONSC,COMA,ASPHIXIATION. EYE/SKIN IRRIT. REPRODUCTIVE DISORDERS,CARDIAC & LIVER ABNORMALITIES, EYE DAMAGE. Medical Cond Aggravated by Exposure:ASHTMA. RESPIRATORY &/OR SKIN ALLERGIES IN SUSCEPTABLE PERSONS. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR.RESTORE BREATHING.TREAT SYMPTOM.CONSULT DR.SPLASH(EYE):FLUSH IMMED W/LG ATMS OF WATER,INCLUDE UNDER EYELIDS,FOR @LEAST 15MINS.IRRIT PERSISTS CONSULT PHYSICIAN.SPLASH(SKIN):WA SH W/SOAP/WATER.REMOVE CONTAMIN CLOTH.CONSULT DR IF IRRIT PERSISTS.INGEST:CONSULT DR/POISON CNTRL CNTR IMMED.TREAT SYMPTOMATICALLY. ===================== Fire Fighting Measures ===================== Flash Point:-138F,-94C Autoignition Temp:Autoignition Temp Text:NP Lower Limits:0.9 Upper Limits:NP Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG. OSHA:CLASS IA, DOT FLAMMABLE LIQUID. Fire Fighting Procedures:H2O MAY BE INEFFECTIVE;IF USE,FOG NOZZ PREFER.H2O MAY BE USED TO COOL CLSD CNTNR-PREVENT PRESSURE BUILDUP/AUTO-IGN WHEN EXPO TO EXTREME HEAT.FULL PROTECT(SUPPL) Unusual Fire/Explosion Hazard:ISOLATE FROM HEAT/ELECTR EQPMT/SPARKS/OPN FLAME.APPLICATION TO HOT SURFACES REQUIRE SPEC PRECAUT.CLSD CNTNR MAY EXPLO WHEN EXPO TO EXTREME HEAT.DURING (SUPPLE) ================== Accidental Release Measures ================== Spill Release Procedures:LIMIT SPREAD OF SPILL/LEAK.REMOVE ALL SOURCES OF IGNITION.SOAK UP W/INERT ABSORBANT MATL.USE NON-SPARKING TOOLS WHEN REMOVING WET ABSORBENT.SEE OTHER MSDS SECTION FOR REQUIRED PROTECTIVE MEASURES.KEEP MATL OUT OF SEWERS &/OR DRAINS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM EXTREME HEAT/FIRE/OPEN FLAME.STORE IAW OSHA 1910.106.DONT STORE >100F(38C).STORE LG QUANT ONLY IN BLDG DESIGNED TO COMPLY W/1910.106. Other Precautions:DONT HNDLG TIL MFG SAF PRECAUT READ/UNDERSTOOD.STORE IN WELL VENTI AREA.KEEP DR OUT OF DIRECT SUN/TIGHT CLSD/UPRIGHT.DONT STORE/USE NEAR HEAT/SPARK/OPN FLAME.GROUND/BOND WHEN POUR.DONT USE PRESS TO EM PTY-NOT PRESS VESS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:OUTDOORS:USE MECHANICAL FILT RESP WHILE SPRAYING.RESTRICTED VENTI AREA:USE APPROV CHEM/MECH FILT DESIGNED TO REMOVE COMBINATION OF PARTICULATES & VAPORS.CONFINED AREAS:USE APPROVED AIR LINE TYP RESP O R HOODS. Ventilation:PROVIDE VENTI OF SUFFIC VOL/PTRN TO KEEP AIR CONTAM CONCEN BEL VALS.EXHAUS FILT SYS TO AVOID ENVIRO CONTAM.IAW EMISS REG Other Protective Equipment:WEAR CHEM RESIST SHOES.REMOVE/WASH CONTAM CLOTH BEF REUSE.WEAR RUBB/PLAST APRON.CLEAN H2O SOURCE AVAI FOR EYE/SKIN FLUSH Work Hygienic Practices:WASH HANDS BEF EAT/WASHRM USE.SMOKE IN DESIGNATED SMOKING AREAS ONLY.AVOID REP/PROL SKIN CONTACT.LIQ PENETR LEATHER-BURN Supplemental Safety and Health FIREFIGHT:EQPTM +SCBA SHOULD BE USED TO PROT FIGHTER FRM HAZ COMBUST PROD.AVOID BURN LIQ SPREAD W/H2O. FIRE/EXPLO:EMERG CONDITIONS/OVEREXPO MAY CAUSE HEALTH HAZ.SYMPT MAY NOT BE IMMED APPARENT.GET MED ATTN.VAP MAY IGNITE BY STAT ELECT/FRICSPARKS.VAP HEAVIER THAN AIR-TRAVEL DISTANCES TO IGN PT/FLASHBACK.KEEP CNTNR CLSD ================== Physical/Chemical Properties ================== HCC:V3 Boiling Pt:B.P. Text:43.0F,6.1C Melt/Freeze Pt:M.P/F.P Text:NP Decomp Temp:Decomp Text:NP Vapor Pres:NP Vapor Density:>AIR Spec Gravity:NP pH:NP Viscosity:NP Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:NP Appearance and Odor:LIGHT YELLOW Percent Volatiles by Volume:89.98 Corrosion Rate:NP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES PEROXIDES OR STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HEAT,SPARKS,OPEN FLAME. Hazardous Decomposition Products:MAY PRODUCE FUMES WHEN HEAT TO DECOMPO,AS IN WELD OR FIRE.FUMES MAY CONTAIN:CO,CO2,&VARIOUS OTHER HYDROCARBONS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPO OF IAW ALL LOC,STATE,FED REGS.APPROVED LANDFILL,APPROVED HAZ WASTE SITE,INCINERATION.CHEM SUBJ TO REPORT REQMTS SEC 313 SARA TITLE III:ETHYL BENZENE,XYLENE,TOLUENE,N-BUTANOL,ACETONE.CNTNR DISPO IAW APPL LAWS/REGS.DONT GIVE EMPTY DR TO PEOPLE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:140 8731 INDICATOR STOP BATH, CONCENTRATE CAGE:19139 CAGE:0E4P0 CAGE:19139 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:ACETIC ACID (CERCLA) CAS:64-19-7 RTECS #:AF1225000 Fraction by Wt: 85-90% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 PPM ACGIH TLV:10 PPM/15 STEL; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 10-15% Other REC Limits:NONE RECOMMENDED Ingred Name:BROMOCRESOL PURPLE CAS:115-40-2 Fraction by Wt: <0.1% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT): 3.3 G/KG (ACETIC ACID) Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE OVEREXPOSURE TO EXTREMELY HIGH AIRBORNE CONCENTRATIONS OF RESPIRATORY IRRITANTS HAS BEEN ASSOCIATED WITH DEVELOPMENT OF ASTHMA-LIKE REACTIVE AIRWAYS SYNDROME. INHALTION OF VAPOR EXTREMELY IRRITA TING. EYE CONTACT CAUSES SEVERE BURNS. SKIN CONTACT CAUSES SEVERE BURNS. INGESTION MAY CAUSE BURNS OF GI TRACT. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:EYE IRRITATION, RESPIRATORY TRACT IRRITATION, EYE BURNS, SKIN BURNS, GI TRACT BURNS, DEATH. Medical Cond Aggravated by Exposure:ACUTE OVEREXPOSURE TO EXTREMELY HIGH AIRBORNE CONCENTRATIONS OF RESPIRATORY IRRITANTS HAS BEEN ASSOCIATED WITH DEVELOPMENT OF AN ASTHMA-LIKE REACTIVE AIRWAYS SYNDROME IN SUSCEPTIBLE INDIVIDUALS. ======================= First Aid Measures ======================= First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES: WASH OUT IMMEDIATELY WITH WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN: WASH WITH SOAP AND WATER . GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. INGESTION: DO NOT INDUCE VOMITING. GIVE VICTIM A GLASS OF WATER. CALL A PHYSICIAN OR POISON CONTROL CENTER ASAP. NEVER GIVE ANYTHING BY MOUTH IF UNCONSCIOUS. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:128F,53C Lower Limits:NOT GIVEN Upper Limits:NOT GIVEN Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM. Fire Fighting Procedures:FIRE FIGHTERS SHOULD WEAR SELF CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE GEAR. COOL TANKS AND CONTAINERS EXPOSED TO FIRE WITH WATER. Unusual Fire/Explosion Hazard:CLASSIFIED AS COMBUSTIBLE. MATERIAL CONTAINS A COMBUSTIBLE SOLVENT THAT MAY ACCUMULATE IN CONTAINER HEADSPACE. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. MAY REQUIRE NEUTRALIZATION. FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER. OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE TO REMOVERESIDUAL. Neutralizing Agent:NEUTRALIZATION AND SEWERING MAY NOT BE ALLOWED IN SOME STATES AND MUNICIPALITIES ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT BREATHE VAPOR AT CONCENTRATIONS GREATER THAN THE EXPOSURE LIMITS. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. USE ONLY WITH ADEQUATE VENTILATION. Other Precautions:KEEP FROM CONTACT WITH OXIDIZING MATERIALS. KEEP AWAY FROM HEAT AND FLAME. KEEP CONTAINER CLOSED. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE CONCENTRATIONS BELOW RECOMMENDED EXPOSURE LIMITS, AN APPROVED RESPIRATOR MUST BE WORN. RESPIRATOR TYPE: FULL-FACE ORGANIC VAPOR CARTRIDGE. IF RESPIRATO RS ARE USED, A PROGRAM SHOULD BE STARTED Ventilation:GOOD GENERAL VENTILATION, TYPICALLY 10 AIR CHANGES PER HOUR, SHOULD BE USED. RATES SHOULD MATCH CONDITIONS. Other Protective Equipment:CHEMICAL RESISTANT CLOTHING AS NECESSARY TO PREVENT SKIN CONTACT. AN EMERGENCY EYEWASH AND SHOWER SHOULD BE AVAILABLE. Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES. Supplemental Safety and Health EXTREMELY HIGH AIRBORNE CONCENTRATIONS ARE NOT GENERATED DURING NORMAL CONDITIONS OF USE BUT MAY OCCUR FOLLOWING A SPILL. THE POTENTIAL TO GENERATE EXTREMELY HIGH AIRBORNE CONCENTRATIONS IN A SPILL SI TUATIONS DEPENDS UPON PHYSICAL FACTORS SUCH AS THE CONCENTRATION OF THE SOLUTION, VOLUME OF SPILL, VENTILATION RATE. ================== Physical/Chemical Properties ================== HCC:F6 Boiling Pt:B.P. Text:>212F,>100C Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN Vapor Pres:14.6 Vapor Density:1.9 Spec Gravity:1.07 pH:< 2 Evaporation Rate & Reference:NOT GIVEN Solubility in Water:COMPLETE Appearance and Odor:LIGHT YELLOW LIQUID, SHARP VINEGAR ODOR Percent Volatiles by Volume:100 % ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES BASES, STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE OR LOCAL LAWS. MAY REQUIRE NEUTRALIZATION IF PH < 2.0 OR PH > 12.5. DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE ANDLOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:LIDOCAINE HYDROCHLORIDE INJECTION Preparer's Name:GREGORY KOLAR CAGE:24832 CAGE:24832 CAGE:39832 CAGE:0K706 ============= Composition/Information on Ingredients ============= Ingred Name:LIDOCAINE HYDROCHLORIDE CAS:73-78-9 Other REC Limits:NONE RECOMMENDED Ingred Name:METHYLPARABEN CAS:99-76-3 Other REC Limits:NONE RECOMMENDED Ingred Name:WATER FOR INJECTION (NOTE: PH ADJUSTED WITH HYDRCHLORIC ACID AND/OR SODIUM HYDROXIDE.) CAS:7732-18-5 RTECS #:ZC0110000 Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL MOUSE LD50: 220 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE,SKIN,RESPIRATORY IRRITATION,UNUSUALLY SLOW HEARTBEAT,DIFFICULTY BREATHING,SWELLING MAY OCCUR.PRODUCT INTENDED FOR THERAPUTIC USE ONLY WHEN PRESCRIBED BY A PHYSICIAN.POTENTIAL ADVERSE REACTIONS FRO M PRESCRIBED DOSES AND OVERDOSES ARE DESCRIBED IN PACKAGE INSERT.OCCUPATIONAL EXPOSURE HAS NOT BEEN FULLY INVESTIGATED. Effects of Overexposure:EYE,SKIN,RESPIRATORY IRRITATION,UNUSUALLY SLOW HEARTBEAT,DIFFICULTY BREATHING,SWELLING MAY OCCUR.PRODUCT INTENDED FOR THERAPUTIC USE ONLY WHEN PRESCRIBED BY A PHYSICIAN.POTENTIAL ADVERSE REACTIONS FRO M PRESCRIBED DOSES AND OVERDOSES ARE DESCRIBED IN PACKAGE INSERT.OCCUPATIONAL EXPOSURE HAS NOT BEEN FULLY INVESTIGATED. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. FLUSH AREA WITH LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION. INHALATION: MOVE TO FRESH AIR. IF NOT BREATHING GIVE CPR. GET MEDICAL ATTENTION. INGESTION: FLUSH MOUTH OUT WITH WATER IMMEDIATELY. GET MEDICAL ATTENTION. GENERAL: FOR ADDITIONAL INFORMATION SEE THE PRODUCT INSERT. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:>200F,>93C Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE OR FOAM AS APPROPRIATE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:WHEN HEATED TO DECOMPOSITION IT EMITS TOXIC FUMES OF NITROGEN OXIDES (NOX). ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN-UP; WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT. USE ABSORBENT TOWELS OR BOOMS TO CLEAN-UP SPILL. WIPE SURFACES CLEAN AND WASH WITH SOAP AND WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AS A GENERAL RULE, WHEN HANDLING PHARMACEUTICAL PRODUCTS AVOID ALL CONTACT AND INHALATION OF DUST, FUME, MISTS, OR VAPORS ASSOCIATED WITH THE PRODUCT. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WITH SATIFACTORY VENTILATION, RESPIRATORY PROTECTION NOT USUALLY REQUIRED. Ventilation:GENERAL ROOM VENTILATION IS USUALLY SATISFACTORY, USE LOCAL EXHAUST VENTILATION WHEN NECESSARY. Other Protective Equipment:WEAR DISPOSABLE GARMENTS IF DIRECT SKIN CONTACT IS ANTICIPATED. Work Hygienic Practices:WASH AFTER HANDLING AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 pH:5 - 7 Solubility in Water:SOLUBLE(WITH HCL) Appearance and Odor:CLEAR, COLORLESS SOLUTION. ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:PROTECT FROM FREEZING. Hazardous Decomposition Products:WHEN HEATED TO DECOMPOSITION IT EMITS TOXIC FUMES OF NITROGEN OXIDES (NOX). Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:439070 WEST KIT LEV 1 CAGE:1W937 CAGE:1W937 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE GLYCOL, GLYCOL CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: <40% Other REC Limits:10 MG/CUM ACGIH TLV:C 127 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:HUMAN PROTEIN Fraction by Wt: <10% ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 ORAL RAT: 8.54 G/KG ETHYLENE GLYCOL Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: ETHYLENE GLYCOL MAY CAUSE IRRITATION OF MUCOUS MEMBRANES & RESPIRATORY PASSAGES. INGESTION: ETHYLENE GLYCOL MAY CAUSE INTOXICATION & COMA. SKIN: ETHYLENE GLYCOL MAY CAUSE IRRITATION. HUMANPROTEIN SOURCES ARE CAPABLE OF TRANSMITTING INFECTIOUS DISEASE. Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:SKIN: WASH AFFECTED AREAS THOROUGHLY. INGESTION, EYES OR CONTACT W/OPEN WOUND. OBTAIN MEDICAL ATTENTION IN ALL CASES. ================== Accidental Release Measures ================== Spill Release Procedures:HANDLE AS IF CAPABLE OF TRANSMITTING INFECTIOUS DISEASE. ABSORB ON INERT MATERIAL. ======================Handling and Storage ====================== Handling and Storage Precautions:HEAT WILL DEGRADE EFFICACY. HANDLE AS IF CAPABLE OF TRANSMITTING INFECTIOUS DISEASE. Other Precautions:STORE AS INDICATED ON DIRECTION INSERT. FOR IN VITRO DIAGNOSTIC USE ONLY. NOT FOR HUMAN OR ANIMAL USE. HANDLE BROKEN OR ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AS REQUIRED Ventilation:GENERAL IS ACCEPTABLE Other Protective Equipment:EYE BATH Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>100C Vapor Pres:18 Vapor Density:0.6 Spec Gravity:>1 Evaporation Rate & Reference:(WATER = 1): <1 Solubility in Water:COMPLETE Appearance and Odor:AMBER VISCOUS LIQUID, W/SLIGHT ODOR Percent Volatiles by Volume:>75% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS Stability Condition to Avoid:HEAT ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE AS NECESSARY FOR BIOHAZARDOUS MATERIALS. DISPOSE OF IN ACCORDANCE W/APPLICABLE FEDERAL, STATE, & LOCAL LAWS & REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SA 71 SOLVENT BLEND CAGE:7L600 CAGE:7L600 CAGE:0FCC1 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ISOBUTYL KETONE (HEXONE) (SARA 313) (CERCLA) CAS:108-10-1 RTECS #:SA9275000 Fraction by Wt: 14% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:50 PPM/75 STEL; 9495 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA 313) (CERCLA) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 14% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM ACGIH TLV:200 PPM/300STEL;9495 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHYTLENE GLYCOL MONOBUTYL ETHER (2-BUTOXYETHANOL) CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: 12% Other REC Limits:NONE RECOMMENDED OSHA PEL:S, 50 PPM ACGIH TLV:S, 25 PPM; 9495 Ingred Name:ISOPROPANOL (ISOPROPYL ALCOHOL) (SARA 313) CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 10-15% Other REC Limits:NONE RECOMMENDED OSHA PEL:400 PPM ACGIH TLV:400 PPM/500STEL;9495 Ingred Name:APLIPHATIC PETROLEUM DISTILLATES (VM & P NAPHTHA) CAS:64742-89-8 Fraction by Wt: 9% Other REC Limits:NONE RECOMMENDED Ingred Name:NORMAL BUTANOL (N-BUTYL ALCOHOL) (SARA 313) (CERCLA) CAS:71-36-3 RTECS #:EO1400000 Fraction by Wt: 6% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:S, C 50 PPM; 9495 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:PROPYLENE GLYCOL MONOMETHYL ETHER CAS:107-98-2 RTECS #:UB7700000 Fraction by Wt: 13-17% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:100 PPM/150STEL;9495 Ingred Name:XYLENES (O-,M-,P- ISOMERS) (SARA 313) (CERCLA) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 18% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:100 PPM/150STEL;9495 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHYL BENZENE (SARA 313) (AS A COMPONENT OF TECHNICAL GRADE XYLENES) CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 3% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:100 PPM/125STEL;9495 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE:INHALATION MAY CAUSE NASAL & RESPIRATORY IRRITATION & CNS EFFECTS.EXPOSURE CAN CAUSE SKIN & EYE IRRITATION.INGESTION MAY CAUSE GI TRACT IRRITATION.ASPIRATION MAY CAUSE CHEMICAL PNEUMONITIS,WHICH CAN BE FATAL.CHRONIC:PROLONGED/REPEATED EXPOSURE MAY CAUSE CARDIAC ABNORMALITY AND/OR EYE DAMAGE. Explanation of Carcinogenicity:ISOPROPYL ALCOHOL IS LISTED AS A GROUP 3 (INSUFFICIENT HUMAN EVEIDENCE) POTENTIAL CARCINOGEN. Effects of Overexposure:INHALED-COUGHING, SHORTNESS OF BRETAH, DIZZINESS, WEAKNESS, FATUGUE, NAUSEA, HEADACHE, UNCONSCIOUSNESS, POSSIBLE DEATH. EYES-BURNING, TEARING, REDNESS, SWELLING, EYE DAMAGE. SKIN-REDNESS, BURNING, DRY ING, CRACKING, SKIN BURNS, SKIN DAMAGE.INGESTED-NAUSEA, VOMITING, DIARRHEA. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION-REMOVE TO FRESH AIR. RESTORE BREATHING AS REQUIRED. GET MEDICAL ATTENTION IMMEDIATELY. EYE-FLUSH WITH WATER FOR 15 MINUTES, HOLD LIDS OPEN. GET MEDICAL ATTENTION. SKIN-REMOVE CONTAMINATED C LOTHES. WASH WITH SOAP & WATER. SEEK MEDICAL ATTENTION.INGESTION-DO NOT INDUCE VOMITING. NOTHING BY MOUTH IF UNCONSCIOUS. GET MEDICAL ATTENTION IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:10F,-12C Lower Limits:1.0 Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS OPERATED IN POSITIVE PRESSURE DEMAND AND FULL PROTECTIVE GEAR WHEN FIGHTING FIRES. Unusual Fire/Explosion Hazard:HIGHLY VOLATILE-GIVES OFF VAPOR WHICH TRAVELS ALONG GROUND TO SOURCE OF IGNITION AND IGNITE. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL:ABSORB SPILL WITH INERT MATERIAL & PLACE IN A CONTAINER FOR LATER DISPOSAL.LARGE:ELIMINATE ALL SOURCES OF IGNITION.CONTAIN SPILL.KEEP OUT OF SEWERS & WATERCOURSES.PUMP OR VACUUM TRANSFER.ABSORB RESIDUE W/INERT MATERIAL & PLACE IN CONTAINER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. DLA-HMIS: STORE IN A COOL, DRY PLACE AWAY FROM SOURCES OF IGNITION AND STRONG OXIDIZING AGENTS. Other Precautions:CONTAINERS OF THIS PRODUCT MAY BE HAZARDOUS WHEN EMPTIED; SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES. ALL HAZARD PRECAUTIONS MUST BE OBSERVED. DLA-HMIS:USE PROPER BONDING AND GROUNDING PROCEDURE S WHEN TRANSFERRING PRODUCT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED RESPIRATOR OR AN AIR-SUPPLIED RESPIRATOR OR SCBA, AS REQUIRED. USE IN ACCORDANCE WITH 29 CFR 1910.13 4 AND MANUFACTURER'S RECOMMENDATIONS. Ventilation:USE ADEQUATE EXPLOSION-PROOF MECHANICAL VENTILATION OR LOCAL EXHAUST TO MAINTAIN EXPOSURE BELOW TLV(S). Other Protective Equipment:WEAR IMPERVIOUS CLOTHING & BOOTS. DLA-HMIS: EYE WASH STATION & SAFETY SHOWER. Work Hygienic Practices:DLA-HMIS: WASH HANDS AFTER HANDLING AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE. Supplemental Safety and Health SUDDEN RELEASE OF HOT ORGANIC CHEMICAL VAPORS OR MISTS FROM PROCESS EQUIPMENT OPERATING AT ELEVATED TEMPERATURE OR SUDDEN INGRESS OF AIR INTO VACUUM EQUIPMENT MAY RESULT IN IGNITIONS W/O PRESENCE OF O BVIOUS IGNITION SOURCES (AUTOIGNITION). ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:B.P. Text:175F,79C Vapor Pres:70 Vapor Density:>1.0 Spec Gravity:0.836 Evaporation Rate & Reference:<1 (ETHER=1) Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. DLA-HMIS: FLAMMABLE LIQUID. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. DLA-HMIS: AVOID EXPOSURE/CONTACT TO SOURCES OF IGNITION AND INCOMPATIBLE MATERIALS. Hazardous Decomposition Products:VARIOUS HYDROCARBONS, CARBON MONOXIDE AND CARBON DIOXIDE. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL ENVIRONMENTAL REGULATIONS. DLA-HMIS: EPA/RCRA WASTE NUMBER D001 (IGNITEABLE) MAY APPLY TO UNUSED/UNCONTAMINATED PRODUCT.
1
eyes_protection_mandatory
======================================================= NIIN: 01-424-2799 Product ID: NP-6000/7000/8000 SERIES TONER BLACK Cage: EO160 Country: JA Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 01QM9 Box: UNKNOW Cage: EO160 Country: JA Cage: EO274 Country: JA Cage: 1BA63 ======================================================= Item Description Information ======================================================= Item Manager: S9G Item Name: TONER,INDIRECT ELECTROSTATIC PROCESSING Specification Number: UNKNOWN Unit of Issue: EA UI Container Qty: 0 Type of Container: CARTRIDGE ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: CHRONIC:BASED UPON AVAI DATA HUMAN EXPO TO TONER HAS BEEN SHOWN TO CAUSE MIN RESP TRACT IRRIT AS MAY OCCUR W/LG ATMS OF ANY NONTOXIC DUSTS.RESULTS OF 1 ANIMAL STUDY WHERE RATS INHAL TONER THAT WAS 10X MORE RESPIRABLE THAN COMMERC AVAI TONER WERE OBSERVED TO HAVE NO LUNG CHANGES @LOW EXPO.@HI EXPO LEVELS SLIGHT (SUPPL) Explanation Of Carcinogenicity: PER MSDS:CARCINOGENICITY CLASSIFICATION:IARC/ACGIH/NTP/ OSHA:NONE. Signs And Symptions Of Overexposure: EYE TRANSIENT IRRIT. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: INHAL:SYMPTOMATIC MOVE TO FRESH AIR.GET MED ATTN IF SYMPTOMS PERSIST.EYE:ANY MATL THAT CONTACTS EYE SHOULD BE WASHED OUT IMMED W/WATER.GET MED ATTN IF SYMPTOMS OCCUR.SKIN:WASH W/SOAP/WATER.GET MED ATT N IF SYMPTOMS OCCUR.INGEST:DRINK 1-2 GLASSES OF WATER.SEEK MED ATTN. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: SWEEP MATL ONTO PAPER AND PLACE IN FIBER CARTON.DONT USE VACCUUM CLEANER TO CLEANUP SPILLS OF POWDERED TONER.THE FINE PARTICLES CAN CAUSE FIRE OR EXPLOSION. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: MATL HASNT BEEN TESTED FOR ENVIRO EFFECTS.IN SPILL SITUATION MATL MAY BE VISUALLY UNPLEASANT;HOWEVER ITS NOT EXPECTED TOCAUSE ANY ADVERSE ENVIRO EFFECTS.INCINERATE/LANDFILL.CAN BE INCINERATED WHEN IN COMPLIANCE W/LOC REGS.DISCAHR/TREAT/DISPO MAY(SUP) Handling And Storage Precautions: AVOID BREATH DUST.USE W/ADEQUATE VENTI.KEEP FROM CONTACT W/OXIDIZING MATLS.MIN DUST GENERATION/ACCUMULATION. Other Precautions: REF:PAMPHLET #654:PREVENTION OF FIRE/DUST EXPLOSIONS IN CHEMICAL,DYE,PARMACEUTICAL & PLASTICS INDUSTRIES.USE ADEQUATE VENTILATION.KEEP CNTNR CLSD.4 TO 6 ROOM VOLUMES OF AIR EXCHANGED/HR IS SUFFICIENT. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: NA Lower Limits: NA Upper Limits: NA Extinguishing Media: WATER SPRAY, CARBON DIOXIDE (CO2), DRY CHEMICAL. Fire Fighting Procedures: NONE Unusual Fire/Explosion Hazard: TONER MATERIAL, LIKE MOST ORGANIC MATL IN POWDER FORM,IS CAPABLE OF CREATING A DUST EXPLOSION.NON-FLAMM SOLID(ACCORDING TO TEST METHOD OF 16CFR1500.44). ======================================================= Control Measures ======================================================= Respiratory Protection: NONE SHOULD BE NEEDED Ventilation: GOOD VENTILATION(TYPICALLY 4-6 ROOM VOLUMES PER HR)SHOULD BE USED.VENTILATION RATES SHOULD BE MATCHED TO CONDITONS. Other Protective Equipment: WASHING FACILITIES. Work Hygienic Practices: WASH WELL AFT HNDLG.GOOD INDUSTRIAL HYG PRAC SHOULD BE FOLLOWED-INVOLVES PREVENTING EYE CONTACT,MIN SKIN CONTACT/INHAL. Supplemental Safety and Health: HEALTH:DEGREE OF LUNG FIBROSIS OBSERVED DUE TO EXCESSDUST AMTS RETAINED IN LUNGS FOR PROL INTERVAL.INHAL/SKIN:EXPECTED TO BE LOW HAZ FOR RECOMMENDED HNDLG.EYE:NO SPEC HAZ KNOWN.MAY CAUSE TRANSIENT IRR IT.INGEST:EXPECTED TO BE LOW INGEST HAZ. DISPO:BE SUBJ TO FED/STATE/LOC LAWS.SARA/40CFR372:CR III/CMPDS=2%,AS METAL=0.5% ======================================================= Physical/Chemical Properties ======================================================= HCC: N1 M.P/F.P Text: 212F,100C Vapor Pres: NEGLIGIBLE Vapor Density: NA Spec Gravity: 1.4-1.6 PH: NA Evaporation Rate & Reference: NEGLIGIBLE,BUTYLACETATE=1 Solubility in Water: NEGLIGIBLE Appearance and Odor: FINE SOLID POWDER, BLACK COLOR, SLIGHT PLASTIC ODOR Percent Volatiles by Volume: NA ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER. Materials To Avoid: STRONG OXIDIZING AGENTS. Hazardous Decomposition Products: CARBON DIOXIDE, CARBON MONOXIDE.COMBUSTION WILL PRODUCE CARBON DIOXIDE,POSSIBLY TOXIC CHEMS SUCH AS CARBON MONOXIDE. Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Trans ID NO: 136066 Product ID: NP-6000/7000/8000 SERIES TONER BLACK Review Date: 10/27/1997 Net Unit Weight: 1500G Multiple KIT Number: 0 Review IND: Y Unit Of Issue: EA Container QTY: 0 Type Of Container: CARTRIDGE Additional Data: PER MSDS:WT=1500G; DOT SHIPPING NAME:NOT REGUALTED;HAZ CLASS/UN#:NA. ======================================================= Detail DOT Information ======================================================= DOT PSN Code: ZZZ DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail IMO Information ======================================================= IMO PSN Code: ZZZ IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION ======================================================= Detail IATA Information ======================================================= IATA PSN Code: ZZZ IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail AFI Information ======================================================= AFI PSN Code: ZZZ AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= HAZCOM Label ======================================================= Product ID: NP-6000/7000/8000 SERIES TONER BLACK Cage: EO160 Assigned IND: Y Company Name: CANON INC Street: 30-2 SHIRMOMARUKO 3 CHOME OMTA-KU Zipcode: 00000 Country: JA Label Required IND: Y Date Of Label Review: 10/27/1997 Status Code: C Label Date: 10/27/1997 Year Procured: 1997 Origination Code: F Skin Protection IND: YES Signal Word: CAUTION Health Hazard: Slight Contact Hazard: Slight Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: INHAL/SKIN:EXPECTED TO BE LOW HAZ FOR RECOMMENDED HNDLG.EYE:NO SPECIFIC HAZ KNOWN.MAY CAUSE TRANSIENT IRRIT.INGEST:EXPECTED TOB E LOW INGEST HAZ.TARGET ORGANS:EYES.AVOID BREATH DUST.USE W/ADEQUATE VEN TI.KEEP FROM CONTACT W/OXIDIZING MATLS.MIN DUST GENERATION/ACCUMULATION. FIRST AID: INHAL:SYMPTOMATIC MOVE TO FRESH AIR.GET MED ATTN IF SYMPTOMS PERSIST.EYE:ANY MATL THAT CONTACTS EYE SHOULD BE WASHED OUT IMMED W/WATER.GET MED ATTN IF SYMPTOMS OCCUR.SKIN:WASH W/SOAP/WATER.GET MED ATTN IF SYMPTOMS OCCUR.INGEST:DRINK 1-2 GLASSES OF WATER.SEEK MED ATTN. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MOLYSULFIDE (TECHNICAL, TECHNICAL FINE, SUPERFINE) METAL CAGE:019Y6 SYST Contract Num:SP0450-00-M-D480 CAGE:1LFJ4 CAGE:019Y6 ============= Composition/Information on Ingredients ============= Ingred Name:MOLYBDENUM DISULFIDE CAS:1317-33-5 RTECS #:QA4697000 > Wt:98. ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EMERGENCY OVERVIEW: EXPOSURE TO FINE DUST & SMALL PARTICLES IN EXCESS OF THE TLV MAY CAUSE IRRITATION TO EYES, SKIN AND RESPIRATORY SYSTEM Explanation of Carcinogenicity:NO DATA AVAILABLE. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE FROM EXPOSURE AREA TO FRESH AIR IMMEDIATELY. IF BREATHING STOPPED, PERFORM ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING & SHOES IMMEDIATE. WASH AFFECTED AREA W/ SOAP OR MILD DETERGENT, LARGE AMOUNTS OF WATER UNTIL NO EVIDENCE OF CHEMICAL REMAINS. (15-20 MINUTES). GET MED ATTENTION. EYE: WASH EYES IMMEDIATELY WITH LARGE AMOUNTS OF WATER OR NO RMAL SALINE, OCCASIONAL LIFTING UPPER & LOWER LIDS, UNTIL NO EVIDENCE OF CHEMICAL REMAINS (15-20 MINUTES) GET MEDICAL ATTN. INGESTION: IF VOMITING OCCURS, KEEP HEAD LOWER THAN HIPS TO PREVENT ASPIRATI ON. GET MEDICAL ATTN IF NEEDED. ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL, WATER SPRAY OR REGULAR FOAM. FOR LARGER FIRES, USE WATER SPRAY, FOG OR REGULAR FOAM. Fire Fighting Procedures:NO ACUTE HAZARD. MOVE CONTAINER FROM FIRE AREA IF POSSIBLE. AVOID BREATHING VAPORS OR DUSTS; KEEP UPWIND. Unusual Fire/Explosion Hazard:SLIGHT FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE TOXIC OXIDES OF SULFUR. ================== Accidental Release Measures ================== Spill Release Procedures:FOR LARGE SPILLS, SWEEP UP WITH A MINIMUM OF DUSTING & PLACE INTO SUITABLE CLEAN, DRY CONTAINERS FOR RECLAMATION OR LATER DISPOSAL. RESIDUE SHOULD BE CLEANED UP USING A HIGH-EFFICIENCY PARTICULATE FIL TER VACUUM. ======================Handling and Storage ====================== Handling and Storage Precautions:OBSERVE NATIONAL AND REGIONAL PROVISIONS IN FORCE. STORE AWAY FROM INCOMPATIBLE SUBSTANCES. Other Precautions:EMERGENCY EYE WASH: WHERE THERE IS ANY POSSIBILITY THAT AN EMPLOYEE'S EYES MAY BE EXPOSED TO THIS SUBSTANCE, THE EMPLOYER SHOULD PROVIDE AN EYE WASH FOUNTAIN WITHIN THE IMMEDIATE WORK ARE FOR EMERGENC Y USE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE RESPIRATOR SUITABLE FOR LEVELS OF DUST/FUME IN THE WORK ENVIRONMENT. Ventilation:PROVIDE LOCAL EXHAUST VENTILATION AND/OR GENERAL DILUTION VENTILATION TO MEET PUBLISHED EXPOSURE LIMITS. Other Protective Equipment:PROTECTIVE CLOTHING NOT REQUIRED. AVOID REPEATED OR PROLONGED CONTACT WITH THIS SUBSTANCE. EMERGENCY EYE WASH FOUNTAIN WITHIN THE IMMEDIATE WORK AREA FOR EMERGENCY USE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Melt/Freeze Pt:>315.C, 599.F M.P/F.P Text:(OXIDIZES) Vapor Pres:APPROX 0 @20C Spec Gravity:4.80@14C Solubility in Water:INSOLUBLE Appearance and Odor:ODORLESS, DARK GRAY TO BLACK POWDER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES HYDROGEN PEROXIDE: VIGOROUS OR VIOLENT REACTION. OXIDIZERS (STRONG): FIRE AND EXPLOSION HAZARD. POTASSIUM NITRATE: FORMS EXPLOSIVE MIXTURE. Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES & PRESSURES. PREVENT DISPERSION OF DUST IN AIR. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY RELEASE TOXIC &/OR HAZARDOUS GASES. Conditions to Avoid Polymerization:HAZARDOUS POLYMERIZATION HAS NOT BEEN REPORTED TO OCCUR UNDER NORMAL TEMPERATURES & PRESSURES. =================== Toxicological Information=================== Toxicological Information:INHALATION: CHRONIC EXPOSURE: 25 ONE-HOUR EXPOSURES TO 490 MG/M3 CAUSED NO EFFECTS IN ALL THE ANIMALS TESTED EXCEPT ONE WHICH DIED AFTER THE THIRD EXPOSURE. SKIN CONTACT: ACUTE EXPOSURE: DERMATITIS HA S NOT BEEN REPORTED IN EXPOSED WORKERS. INGESTION: CHRONIC EXPOSURE: RATS FED UP TO 500 MG DAILY FOR 44 DAYS SHOWED NO TOXIC SIGNS AND ALL GAINED WEIGHT. ===================== Ecological Information ===================== Ecological:ACUTE AQUATIC TOXICITY: TESTS CONDUCTED IN 1990 AT LEVELS UP TO 750 MG/L POWDERED MBS2 RESULTED IN 0 MORTALITY TO RAINBOW TROUT (SALMO GAIRDNERI). ==================== Disposal Considerations ==================== Waste Disposal Methods:OBSERVE NATIONAL AND REGIONAL PROVISIONS IN FORCE. =================== MSDS Transport Information =================== Transport Information:NO CLASSIFICATION CURRENTLY ASSIGNED. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SILICON ALKYD ENAMEL, B56WZ100 ULTRA WHITE CAGE:54636 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:SOLVENT NAPHTHA (PETROLEUM) MEDIUM ALIPHATIC; (MINERAL SPIRITS). VP:2. CAS:64742-88-7 Fraction by Wt: 18% OSHA PEL:100 PPM (MFR) ACGIH TLV:100 PPM (MFR) Ingred Name:SOLVENT NAPHTHA (PETROLEUM) MEDIUM ALIPHATIC; (MINERAL SPIRITS 140-FLASH). VP:0.5. CAS:64742-88-7 Fraction by Wt: 2% OSHA PEL:100 PPM (MFR) ACGIH TLV:100 PPM (MFR) Ingred Name:XYLENE (SARA 313) (CERCLA). VP:5.9. CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 1% OSHA PEL:100 PPM ACGIH TLV:100 PPM;150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SOLVENT NAPHTHA; (MEDIUM AROMATIC HYDROCARBONS). VP:0.1. CAS:64742-94-5 RTECS #:WF3100000 Fraction by Wt: 2% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:2-HEPTANONE; (METHYL N-AMYL KETONE). VP:70. CAS:110-43-0 RTECS #:MJ5075000 Fraction by Wt: 1% OSHA PEL:100 PPM ACGIH TLV:50 PPM Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 25% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:VOLATILE ORGANIC COMPOUNDS: 2.67 LBS/GAL. RTECS #:9999999VO Ingred Name:SUPP DATA:MAY NOT BE IMMEDIATELY APPARENT. OBTAIN MEDICAL ATTENTION. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP:LEVELS ARE NOT ATTAINABLE IN WORKPLACE. REPORTS HAVE ASSOC RPTD & PRLNG OVEREXP TO SOLVS W/PERM (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:BRAIN & NERV SYS DMG. INTENTIONAL MISUSE BY DELIB CONCENTRATING & INHALING CONTENTS CAN BE HARMFUL/FATAL. (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:WARNING: PRODUCT CONTAINS CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER (CAL PROP 65). RTECS #:9999999ZZ Ingred Name:OTHER PREC:COATING MAY CONTAIN MATLS CLASSIFIED AS NUISANCE PARTICULATES WHICH MAY BE PRESENT AT HAZ LEVELS ONLY(ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:DURING SANDING/ABRADING OF DRIED FILM. IF NOT SPECIFIC DUSTS ARE LISTED, APPLIC LIMS FOR NUISANCE DUSTS (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:ARE ACGIH TLV 10 MG/M3 (TOTAL DUST); OSHA PEL 15 MG/M3 (TOTAL DUST), 5 MG/M3 (RESPIRABLE FRACTION). RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EXPOS MAY BE BY IRRIT &/OR SKIN/EYE CONT, DEPENDING ON CNDTNS OF USE. TO MIN EXPOS, FOLLOW RECS FOR PROPER USE, VENT & PERSONAL PROT EQUIP. ACUTE:IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERV SYS DEP RESS. EXTREME OVEREXP MAY RSLT IN UNCON& POSSIBLY DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD ARE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:INDICATIONS OF EXCESSIVE EXPOS TO VAPS/SPRAY MIST. REDNESS & ITCH/BURNING SENSATION MAY INDICATE EYE/EXCESSIVE SKIN EXPOS. CHRONIC:PRLNG OVEREXP TO SOLV INGS MAY CAUSE ADVERSE EFTS TO LIVER, URINARY & REPRO SYS. RATS EXPOS TO TITANIUM DIOXIDE DUST AT 250 MG/M3 DEVELOPED LUNG CANCER, HOWEVER, SUCH EXPOS (ING 9) Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM & QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE RE-USE. EYES:FLUSH W/LARGE AMOUNTS OFWATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGEST:GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:104F,40C Lower Limits:0.2% Upper Limits:15.3% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER SPRAY MAY BE INEFT. IF WATER IS USED, FOG NOZZ ARE PREF. WATER MAY BE USED TO COOL CLSD CNTNRS TO (SUPDAT) Unusual Fire/Explosion Hazard:COMBUST. KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM HEAT, ELEC EQUIP, SPKS & OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME HEAT. APPLICATION TO (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE & REMOVE W/INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DOL STORAGE CATEGORY - 2. CONTENTS ARE COMBUST. KEEP AWAY FROM HEAT & OPEN FLAME. CONSULT NFPA CODE. USE APPRVD BONDING & GROUNDING PROCS. Other Precautions:KEEP CNTNR CLSD WHEN NOT IN USE. TRANSFER ONLY TO APPRVD CNTNRS W/COMPLETE & APPROP LABELING. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. USE ONLY W/ADEQ VENT. AVOID BRTHG VAP & SPRAY MIST. AVOID CONT W/SKIN & EYES. (ING 12) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW APPLIC LIMS BY VENT, WEAR PROPERLY FITTED NIOSH APPRVD ORG VAP/PARTICULATE RESP FOR PROT AGAINST INGS. WHEN SANDING/ABRADING DRIED FILM, WEAR NIOSH APPRVD DUST/MIST RESP FOR DUST WHICH (SUPDAT) Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF EXPOS TO INGS IS MAINTAINED BELOW APPLIC EXPOS LIMS. (SUPP DATA) Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH HANDS AFTER USING. Supplemental Safety and Health FIRE FIGHT PROC:PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN EXPOS TO EXTREME HEAT. RESP PROT:MAY BE GENERATED FROM PROD, UNDERLYING PAINTS/ABRASIVE. VENT:REFER TO OSHA STD 1910.94, 1910.107, 1910. 108. EXPLO HAZ:HOT SURFS REQS SPECIAL PRECS. DURING EMER CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS(ING 8) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>174F,>79C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:1.26 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:59.4 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM PROD MAY BE HAZ AS DEFINED UNDER RCRA (40 CFR 261). WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE APPLIC EPA HAZ WASTE NUMBER. INCIN IN APPRVD FACILITY. DO NOT INCIN CLSD CNTNR. DISP O F I/A/W FED, STATE & LOC REGS REGARDINGPOLLUTION.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:694 CLEAR MARINE SEALANT CAGE:5D028 CAGE:5D028 CAGE:71984 ============= Composition/Information on Ingredients ============= Ingred Name:SILANE, METHYLTRIACETOXY-; (METHYLTRIACETOXYSILANE) CAS:4253-34-3 RTECS #:VV4500000 Fraction by Wt: 2% OSHA PEL:10 PPM (MFR) ACGIH TLV:10PPM; 15 STEL (MFR) Ingred Name:ETHYLTRIACETOXYSILANE CAS:17689-77-9 Fraction by Wt: 2% OSHA PEL:10 PPM (MFR) ACGIH TLV:10PPM; 15 STEL (MFR) Ingred Name:SILICA, AMORPHOUS CAS:112945-52-5 RTECS #:VV7310000 Fraction by Wt: 8% OSHA PEL:6 MG/M3 (MFR) ACGIH TLV:10 MG/M3 TDUST (MFR) ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: DIRECT CONTACT IRRITATES SLIGHTLY TO MODERATELY WITH REDNESS & SWELLING. SKIN: SINGLE SHORT EXPOSURE (< 24 HRS) MAY IRRITATE. REPEATED PROLONGED CONTACT (24-48 HRS) MAY IRRITATE MODERATELY. INHA L: VAPOR OVEREXPOSURE MAY IRRITATE EYES, NOSE & THROAT. INGEST: SMALL AMOUNTS TRANSFERRED TO MOUTH (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: BY FINGERS DURING USE, ETC., SHOULD NOT INJURE. SWALLOWING LARGE AMOUNTS MAY CAUSE DIGESTIVE DISCOMFORT. NO INJURY FROM DUSTS SHOULD OCCUR DURING REASONABLE USE. IF USE CREATES RESPIRABLE PA RTICLES SOME RESPIRATORY SYSTEM INJURY MAY OCCUR. CURED SEALANT IS NONHAZARDOUS. Medical Cond Aggravated by Exposure:THIS PRODUCT, AS WITH ANY CHMICAL, MAY ENHANCE ALLERGIC CONDITIONS ON CERTAIN PEOPLE. MANUFACTURER DOES NOT KNOW OF ANY MEDICAL CONDITIONS THAT MIGHT BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:INGEST: CALL MD IMMEDIATELY . EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. SKIN: GET MEDICAL ATTENTION IF IRRITATION DEVELOPS. INHAL: REMOVE TO FRESH AIR. ===================== Fire Fighting Measures ===================== Flash Point Method:OC Flash Point:250F,121C Extinguishing Media:WATER FOG, CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NOT KNOWN TO MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE PRODUCT AND USE ABSORBENT MATERIAL TO TAKE CARE OF ANY OIL-LIKE RESIDUES. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE BELOW 90F/32C. USE REASONABLE CARE AND CAUTION. Other Precautions:PROD FORMS ACETIC ACID (HOAC) WHEN EXPOSED TO WATER/HUMID AIR. PROVIDE VENT DURING USE TO CONTROL HOAC EXPOS W/IN 10PPM (CURRENT TLV) OR USE NIOSH/MSHA APPRVD RESP PROT. PREC ARE FOR ROOM TEMP HNDLG. USE @ ELEVATED TEMPS/AEROSOL/ (SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATORY PROTECTION UNLESS LOCAL EXHAUST VENTILATION IS INADEQUATE OR AIR SAMPLING DATA SHOW EXPOSURES ARE WTIHIN TLV & PEL GUIDELINES. SUITABLE RESPIRATOR: NIOSH/MSHA APPRO VED ACID GAS/ORGANIC VAPOR TYPE. Ventilation:MECHANICAL (GENERAL): RECOMMENDED. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:WASHING @ MEALTIME & END OF SHIFT IS ADEQ. REMOVE CONTAMD CLTHG & SHOES AS SOON AS POSS & CLEAN THORO BEFORE REUSE. Supplemental Safety and Health OTHER PREC: SPRAY APPLICATIONS, MAY REQUIRE ADDED PRECAUTIONS. GOOD PRACTICE REQUIRES THAT GROSS AMOUNT OF ANY CHEMICAL BE REMOVED FROM SKIN AS SOON AS PRACTICAL, ESPECIALLY BEFORE EATING OR SMOKING. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>300F,>149C Vapor Pres:<5 @ 77F Vapor Density:>1 @ 77F Spec Gravity:1.04 @ 77F/25C Evaporation Rate & Reference:<1 (ETHER=1) Solubility in Water:< 0.1% Appearance and Odor:CLEAR PASTE; ACETIC ACID-LIKE ODOR. Percent Volatiles by Volume:<5(WT) ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING MATERIAL CAN CAUSE A REACTION. Stability Condition to Avoid:AIR OR MOISTURE CAUSES POLYMERIZATION AND ACETIC ACID. Hazardous Decomposition Products:SILICON DIOXIDE, CARBON DIOXIDE AND TRACES OF INCOMPLETELY BURNED CARBON PRODUCTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:MANUFACTURER SUGGESTS THAT ALL LOCAL, STATE AND FEDERAL REGULATIONS CONCERNING HEALTH & POLLUTION BE REVIEWED TO DETERMINE APPROVED DISPOSAL PROCEDURES. CONTACT MANUFACTURER IF THERE ARE ANY DISPOSAL QUESTIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CARBOWAX PEG 8000, P15510 009 CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:POLY(OXY-1,2-ETHANEDIYL), .ALPHA.-HYDRO-.OMEGA.-HYDROXY- EINECS/ELINCS: UNLISTED. CAS:25322-68-3 RTECS #:TQ3500000 Fraction by Wt: 100% ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (ORAL,RAT)28 GM/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYE: MAY CAUSE MILD EYE IRRITATION. SKIN: LOW HAZARD FOR USUAL INDUSTRIAL HANDLING. INGESTION: MAY CAUSE GASTROINTESTINAL IRRITATION WITH NAUSEA, VOMITING AND DIARRHEA. INHALATION: NO HAZARD EX PECTED IN NORMAL INDUSTRIAL USE. CHRONIC: PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE DERMATITIS. TARGET ORGANS: NONE. Explanation of Carcinogenicity:CAS# 25322-68-3: NOT LISTED BY ACGIH, IARC, NIOSH, NTP, OR OSHA. Effects of Overexposure:SEE HEALTH HAZARDS. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LST 15 MINS, OCCASIONALLY LIFTING UPPER & LOWER LIDS. GET MED AID. SKIN: FLUSH WITH PLENTY OF SOAP AND WATER FOR AT LST 15 MINS WHILE REMOVING CONTA MD CLOTHING & SHOES. GET MED AID IF IRRIT DEVELOPS OR PERSISTS. INGEST: IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER. NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. GET MED A ID. INHAL: REMOVE FROM EXPOSURE TO FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. GET MED AID. NOTES TO PHYS: TREAT SYMPTOMATICALLY & SUPPORTIVELY. ===================== Fire Fighting Measures ===================== Flash Point:=268.C, 514.4F Extinguishing Media:IN CASE OF FIRE, USE WATER, DRY CHEMICAL, CHEMICAL FOAM, OR ALCOHOL-RESISTANT FOAM. Fire Fighting Procedures:AS IN ANY FIRE, WEAR A SELF-CONTAINED BREATHING APPARATUS IN PRESSURE-DEMAND, NIOSH (APPROVED OR EQUIVALENT), AND FULL PROTECTIVE GEAR. Unusual Fire/Explosion Hazard:DUSTS A SUFFICIENT CONCENTRATIONS CAN FORM EXPLOSIVE MIXTURES WITH AIR. DURING A FIRE, IRRITATING AND HIGHLY TOXIC GASES MAY BE GENERATED BY THERMAL DECOMPOSITION OF COMBUSTION. ================== Accidental Release Measures ================== Spill Release Procedures:GENERAL INFORMATION: USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS INDICATED IN EXPOSURE CONTROLS, PERSONAL PROTECTION (SECTION 8). SPILLS/LEAKS: SWEEP UP OR ABSORB MATERIAL, THEN PLACE INTO A SUITABLECLEAN, DRY, CLOSED CONTAINER FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:CAUTION! THIS IS EXPECTED TO BE A LOW HAZARD FOR USUAL INDUSTRIAL HANDLING. MAY CAUSE IRRITATION. USE WITH ADEQUATE VENTILATION. Other Precautions:STORE IN A COOL, DRY PLACE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT TO CONTROL AIRBORNE LEVELS. Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. Supplemental Safety and Health FED REGULATORY INFO: UNDER CWA. OSHA: NONE OF CHEMS IN THIS PROD ARE CONSIDERED HIGHLY HAZ BY OSHA. SECTION 302(RQ): NONE OF CHEMS IN MATL HAVE RQ. SECTION 302(TPQ): NONE OF CHEMS IN PROD HAVE TPQ. OS HA: NONE OF CHEMS IN PROD ARE CONSIDERED HIGH HAZ BY OSHA. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:NOT AVAILABLE Melt/Freeze Pt:=60.C, 140.F Vapor Pres:NOT AVAILABLE Vapor Density:NOT AVAIL Spec Gravity:1.20 pH:NOT AVAIL Viscosity:NOT AVAIL Solubility in Water:SOLUBLE Appearance and Odor:WHITE SOLID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:INCOMPATIBLE MATERIALS. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE. =================== Toxicological Information=================== Toxicological Information:LD50/LC50: CAS# 25322-68-3: ORAL,MOUSE = 34 GM/KG; ORAL, RABBIT: LD50 = 14 GM/KG; ORAL, RAT: DL50 = 28 GM/KG; SKIN, RABBIT: LD50 = >20 GM/KG. EPIDEMIOLOGY, TERATOGENICITY, REPRODUCTIVE EFFECTS, NEUROT OXICITY, MUTAGENICITY, AND OTHER STUDIES: NO DATA AVAILABLE. ===================== Ecological Information ===================== Ecological:ECOTOXICITY, ENVIRONMENTAL FATE, PHYSICAL/CHEMICAL AND OTHER: NOT AVAILABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE, AND LOCAL REGULATIONS. RCRA D-SERIES MAX CONC OF CONTAMINANTS: NONE LISTED. RCRA D-SERIES CHRONIC TOXICITY REFERENCE LEVELS: NONE LISTED. RCRA F, P, & U SERIES: NONE LISTED. =================== MSDS Transport Information =================== Transport Information:NO INFORMATION AVAILABLE. ===================== Regulatory Information ===================== SARA Title III Information:NO CHEMICAL ARE REPORTABLE UNDER SECTION 313. Federal Regulatory Information:TSCA CAS #25322-68-3 IS LISTED ON TSCA INVENTORY. HLTH & SFTY RPTG LIST: NONE OF CHEMS IN PROD ARE UNDER CHEM TEST RULE. SECTON 12B: NONE OF CHEMS ARE LISTED UNDER TSCA SECTION 12B. TSCA SIGNIFICANT N EW USE FULE: NONE OF CHEMS IN MATL HAVESNUR UNDER TSCA. CLEAN AIR ACT: THIS MATL DOES NOT CNTN ANY HAZ AIR POLLUTANTS. THIS MATL DOES NOT CNTN ANY CLASS 1 OZONE DEPLETORS. THIS MATL DOES NOT CNTN ANY CLASS 2 OZONE DEPLETORS. CLEAN WATER ACT: NONE OF CHEMS IN PROD ARE LISTED AS HAZ SUBSTANCES UNDER C WA. NONE OF CHEMS IN PROD ARE LISTED AS TOXIC POLLUTANTS (SUPDAT) State Regulatory Information:CAS# 25322-68-3 CAN BE FOUND ON FOLLOWING STATE RIGHT TO KNOW LISTS: MINNESOTA. CALIFORNIA NO SIGNIFICANT RISK LEVEL: NONE OF CHEMS IN THIS PROD ARE LISTED. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CAT, MIL-C-85285B, TYPE 1, 36375, 03GY292CA Kit Part:Y Preparer's Name:NORM GAUL CAGE:DO188 CAGE:33461 CAGE:DO188 ============= Composition/Information on Ingredients ============= Ingred Name:ALIPHATIC ISOCYANATE (VAPOR PRESSURE 0 MM HG) HEXAMETHYLENE DIISOCYANATE (HDI) (CAS NO. 822-06-02) FREE MONOMER CONTENT* CAS:28182-81-2 Fraction by Wt: 35% Other REC Limits:TVL 1 MG/M3 MOBAY Ingred Name:*LESS THAN 0.7% BASED ON RESIN SOLIDS AT THE TIME OF MANUFACTURE. AFTER 3-6 MO. STORAGE, THE FREE MONOMER CONTENT MAY ** RTECS #:9999999ZZ Other REC Limits:NONE SPECIFIED Ingred Name:**RISE, MAX-1.6%. THE ACGIH HAS PROPOSED A TLV OF 0.005 PPM TWA IN THE NOTICE OF INTENDED CHANGES FOR 1987-88. MOBAY *** RTECS #:9999999ZZ Other REC Limits:NONE SPECIFIED Ingred Name:***RECOMMENDS A CEILING LEVEL OF 0.02 PPM. RTECS #:9999999ZZ Other REC Limits:NONE SPECIFIED Ingred Name:ALIPHATIC ISOCYANATE (VAPOR PRESSURE 0 MM HG) HEXAMETHYLENE DIISOCYANATE (HDI) (CAS NO. 822-06-0), FREE MONOMER **** CAS:28182-81-2 Fraction by Wt: 40% Other REC Limits:NONE SPECIFIED Ingred Name:****CONTENT LESS THAN 0.7% BASED ON RESIN SOLIDS AT TIME OF MANUFACTURE. AFTER 3-6 MO. STORAGE, THE FREE MONOMER***** RTECS #:9999999ZZ Other REC Limits:NONE SPECIFIED Ingred Name:*****CONTENT MAY RISE, MAX-1.6%. THE ACGIH HAS PROPOSED A TLV OF 0.005 PPM IN THE NOTICE OF INTENDED CHANGES FOR****** RTECS #:9999999ZZ Other REC Limits:NONE SPECIFIED Ingred Name:******1987-88. MOBAY RECOMMENDS A CEILING LEVEL OF 0.02 PPM. RTECS #:9999999ZZ Other REC Limits:NONE SPECIFIED Ingred Name:C8&10 AROMATIC HYDROCARBON (VAPOR PRESSURE 3 MM HG) CAS:64742-95-6 Fraction by Wt: <5% Other REC Limits:NONE SPECIFIED Ingred Name:N-BUTYL ACETATE (VAPOR PRESSURE 8.4 MM HG) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: <5% Other REC Limits:NONE SPECIFIED OSHA PEL:150 PPM;200 PPM STEL ACGIH TLV:150 PPM;200 PPM STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHYL 3-ETHOXYPROPIONATE(VAPOR PRESSURE .7 MM HG) CAS:763-69-9 RTECS #:UF3325000 Fraction by Wt: 20% Other REC Limits:NONE SPECIFIED Ingred Name:VOC: 283 G/L RTECS #:9999999VO Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: VAPORS IRRITATING; EYES/NOSE/THROAT. INHALATION MAY CAUSE HEADACHES/DIFFICULT BREATHING/UNCONSCIOUSNESS. CHRONIC: PREVIOUS REPEATED OVER EXPOSURE/SINGLE LARGE DOSE, POSSIBLE DEVELOPMENT OF ISOC YANATE SENSITIZATION CAN CAUSE REACTIONTO LATER EXPOSURE OF ISOCYANATE LEVELS WELL BELOW THE TLV VALUE OF ISOCYANATES. Effects of Overexposure:INHALE: IRRITATE-RSPRTRY TRACT/ACUTE NERVOUS SYSTEM DEPRESSION PROGRESS: HEADACHE/DIZZINESS STAGGERING/CONFUSION/UNCONSCIOUSNESS/COMA. SKIN: IRRITATE-SWELL/REDNESS/DRY/DEFAT/CRACK. EYE: IRRITATE/TEAR/ REDNESS/SWELL/STING. INGEST: IRRITATE/CORROSIVE TO MOUTH/STMCH TISSUE/DIGEST TRACT. CHEM PNEUMONITIS. Medical Cond Aggravated by Exposure:ASTHMA AND ANY OTHER RESPIRATORY DISORDERS. SKIN ALLERGIES, ECZEMA, AND DERMATITIS. ISCOCYANATE SENSITIZATION. ======================= First Aid Measures ======================= First Aid:INHALATION: MOVE TO RISK-FREE AREA. RESTORE BREATHING. ASTHMA-LIKE SYMPTOMS (IMMED/DELAYED BY HRS). MED ATTN. SKIN: REMOVE CONTAMINATED CLOTHING. WASH AREAS W/SOAP/WATER. WASH CONTAMINATED CLOTHING BE FORE REUSE. EYES: FLUSH W/CLEAN LUKEWARM WATER (LOW PRESSURE)-15 MIN, LIFT LIDS. MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. NOTHING BY MOUTH TO AN UNCONSCIOUS PERSON. MEDICAL ATTN. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:76.0F,24.4C Lower Limits:1 Extinguishing Media:FOAM, ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:FULL GEAR W/SELF-CONTAINED BREATHING APPARATUS ON FIREFIGHTERS. WATER TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD-UP/AUTO IGNITION/EXPLOSION. Unusual Fire/Explosion Hazard:CNTNRS CLSD. NO HEAT/SPARKS/ELECTRICAL EQUIPMENT/OPEN FLAME. CLSD CNTNRS MAY EXPLODE W/EXTREME HEAT. APPLIC TO HOT SURFACES--SPECIAL PRECAUTIONS. DECOMP HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:CLEAR AREA. REMOVE ALL SOURCES OF IGNITION (FLAME/SPARK SOURCES/HOT SURFACES). VENTILATE AREA. CONTAIN AND REMOVE WITH INERT ABSORBANT AND NON-SPARKING TOOLS. ======================Handling and Storage ====================== Handling and Storage Precautions:BUILDINGS DESIGNED TO COMPLY WITH OSHA 1910.106. NO STORING NEAR HIGH TEMPERATURES, FIRE, OPEN FLAME, SPARK SOURCES. WELL VENTILATED AREAS. Other Precautions:CONTAINERS TIGHT/UPRIGHT-NO LEAKAGE. NO PROLONGED BREATHING VAPORS/SPRAY MISTS--MAY CAUSE ALLERGIC REACTION. NO CONTACT SKIN/EYES. NO INGESTION. UNDERSTAND MFR'S SAFETY PRECAUTIONS. SUBJECT TO REPORTI NG REQUIREMENTS OF SECTION 313 OF THE* ============= Exposure Controls/Personal Protection ============= Respiratory Protection:APPROVED RESPIRATOR RECOMMENDED FOR ORGANIC VAPOR ENVIRONMENT (AIR PURIFYING OR FRESH AIR SUPPLIED). OBSERVE OSHA REGULATIONS FOR RESPIRATOR USE. VENTILATION TO KEEP EXPOSURE LEVELS BELOW OSHA LIMITS. Ventilation:VENTILATION SUFFICIENT TO KEEP AIRBORNE CONCENTRATIONS OF SOLVENT VAPORS OR MISTS BELOW TLV'S. NO IGNITE SOURCES. Other Protective Equipment:FACE SHEILDS. LONG SLEEVES/LONG LEG CLOTHING IS RECOMMENDED. REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE. Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING, OR USING WASHROOM. SMOKE IN SMOKING AREAS ONLY. Supplemental Safety and Health *SUPERFUND AMENDMENTS REAUTHORIZATION ACT OF 1986 & 40 CFR 372. ================== Physical/Chemical Properties ================== HCC:F5 Boiling Pt:B.P. Text:260 TO 338F Vapor Density:>AIR Spec Gravity:1.08 Viscosity:* Evaporation Rate & Reference:0.15 (X N-BUTYL ACETATE) Solubility in Water:INSOLUBLE Appearance and Odor:AMBER LIQUID WITH SOLVENT ODOR Percent Volatiles by Volume:30.2 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER, AMINES, STRONG BASES, ALCOHOLS, METAL COMPOUNDS AND SURFACE ACTIVE MATERIALS. Stability Condition to Avoid:CONTACT WITH MOISTURE, MATERIAL WHICH REACT WITH ISOCYANATES AND HIGH TEMPERATURES. Hazardous Decomposition Products:BY HIGH HEAT/TEMPERATURES: CARBON MONOXIDE, CARBON DIOXIDE, AND OXIDES OF NITROGEN, TRACES OF HCN AND HDI. ==================== Disposal Considerations ==================== Waste Disposal Methods:IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. DUE TO PRODUCT RESIDUE AND FLAMMABLE VAPOR DO NOT INCINERATE CLOSED CONTAINERS/HANDLE WITH CARE. EPA HAZARDOUS WASTE NUMBER/CODE: D001, F003, F 005.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:75974201 POLYESTER RESIN DION ISO 6631T CAGE:GO898 CAGE:GO898 CAGE:80592 ============= Composition/Information on Ingredients ============= Ingred Name:STYRENE, MONOMER (SARA III) CAS:100-42-5 RTECS #:WL3675000 Fraction by Wt: 50% Other REC Limits:50 PPM OSHA PEL:100 PPM ACGIH TLV:S,50PPM/100STEL;9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:POLYESTER RESIN OSHA PEL:100 MG/CUM ACGIH TLV:100 MG/CUM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION, TEARING, BLURRED VISION, CORNEAL DAMAGE. SKIN: IRRITATION, DAMAGE TO INTERNAL ORGANS. INHALATION: IRRITATION OF RESPIRATORY TRACT, NOSE/THROAT, HEADACHES, DIZZINESS, NAUSEA, WEAKNESS , COLLAPSE, COMA, DEATH, LIVER/KIDNEY DAMAGE/HARMFUL. INGESTION: DIZZINESS, NAUSEA, STOMACH UPSET, & HARMFUL. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES: IRRITATION, TEARING, BLURRED VISION, CORNEAL DAMAGE. SKIN: IRRITATION, DAMAGE TO INTERNAL ORGANS. INHALATION: IRRITATION OF RESPIRATORY TRACT, NOSE/THROAT, HEADACHES, DIZZINESS, NAUSEA, WEAKNESS , COLLAPSE, COMA, DEATH, LIVER/KIDNEY DAMAGE/HARMFUL. INGESTION: DIZZINESS,NAUSEA, STOMACH UPSET, & HARMFUL. Medical Cond Aggravated by Exposure:AILMENTS OF KIDNEY, LIVER, SKIN & RESPIRATORY SYSTEM. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINS. SKIN: WASH THOROUGHLY W/SOAP & WATER. INHALATION: REMOVE FROM EXPOSURE. IF BREATHING HAS STOPPED OR IS DIFFICULT, ADMINISTER ARTIFICIAL RESPI RATION OR OXYGEN AS INDICATED. INGESTION: DON'T INDUCE VOMITING. NOTE TO PHYSICIAN: THERE IS NO SPECIFIC ANTIDOTE FOR EFFECTS FROM OVEREXPOSURE. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:85F Lower Limits:1.1% Upper Limits:6.1% Extinguishing Media:USE CO2, DRY CHEMICAL OR FOAM. Fire Fighting Procedures:WATER MAY BE INEFFECTIVE. WEAR PROTECTIVE EQUIPMENT INCLUDING FULL-FACE SELF-CONTAINED BREATHING APPARATUS. FIRE FIGHTING AT A MAXIMUM DISTANCE/PROTECTED AREAS. Unusual Fire/Explosion Hazard:VAPORS FORM FLAMMABLE/EXPLOSIVE MIXTURES IN AIR, MAY TRAVEL/GROUND TO IGNITION SOURCE & FLASH. POLYMERS MAY FORM IN STORAGE TANK VENT/FLAME/EXPLOSIVE RUPTURING. ================== Accidental Release Measures ================== Spill Release Procedures:STOP LEAK IF NO RISK INVOLVED. STAY UPWIND. SMALL SPILLS: TAKE UP W/SAND OR OTHER NONCOMBUSTIBLE ABSORBENT MATERIAL. FLUSH AREA W/WATER. DIKE LARGE SPILLS FOR LATER DISPOSAL. CONTAIN RUNOFF FROM FIRE CONTROL/DILUTION WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID BREATHING OF VAPORS, MISTS OR FUMES, CONTACT W/SKIN & EYES. KEEP IN A CLOSED, LABELED CONTAINER W/IN A COOL (WELL SHADED), DRY VENTILATED AREA. Other Precautions:PROTECT FROM PHYSICAL DAMAGE. NOT FOR USE OR STORE IN OR AROUND THE HOME. GROUND/BOND DRUMS. DON'T USE PRESSURE TO EMPTY DRUMS. DON'T USE W/O FULLY UNDERSTANDING "REACTIVITY DATA". FLAMMABLE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENTILATION DOESN'T KEEP <TLV/PEL. IF WITHIN OSHA PROTECTION FACTOR, AIR PURIFYING CV/FILTER UNITS OK. Ventilation:PROVIDE SUFFICIENT LOCAL EXHAUST/MECHANICAL VENTILATION IN PATTERN/VOLUME <TLV Other Protective Equipment:RESISTANT PROTECTIVE GARMENTS, APRONS, COVERALLS, BOOTS, ETC. Work Hygienic Practices:REMOVE/WASH CONTAMINATED CLOTHING BEFORE REUSE. OBSERVE GOOD HYGIENE/SAFETY PRACTICES WHEN HANDLING THIS PRODUCT. Supplemental Safety and Health DON'T USE THIS PRODUCT UNTIL MSDS HAS BEEN READ/UNDERSTOOD. DON'T WEAR CONTAMINATED CLOTHING. DISCARD CONTAMINATED FOOTWEAR. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:295F Vapor Pres:4.5 Spec Gravity:0.9-1.2 pH:<7 Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:SLIGHT Appearance and Odor:VISCOUS LIQUID W/A STYRENE ODOR. Percent Volatiles by Volume:20-70% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS, ACIDS, CAUSTIC, METALLIC HALIDES (SALTS), FREE RADICAL CATALYSTS & PEROXIDE. Stability Condition to Avoid:OPEN FLAME & HEAT. Hazardous Decomposition Products:SMOKE, CO, CO2 Conditions to Avoid Polymerization:HEAT, OXIDIZING AGENTS, FREE RADICAL CATALYSTS & PEROXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DOT REPORTABLE QUANTITIES IS 1000 LBS. DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS. LIQUID POLYESTER RESIN WASTE HAVING A FLASH POINT <140F IS A HAZARDOUS WASTE UNDER RCRA HAVING TH E CHARACTERISTIC OF IGNITABILITY-D001. FLAMMABLE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PRO-SEAL 872 B-2 #0872B10 Kit Part:Y CAGE:83574 CAGE:83574 ============= Composition/Information on Ingredients ============= Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 5.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:CALCIUM CARBONATE (MARBLE) (LIMESTONE) CAS:1317-65-3 RTECS #:EV9580000 Fraction by Wt: 20.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:TOLUENE (SARA 313) (CERCLA) (VP = 23) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 10.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM/150 STEL ACGIH TLV:50 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:POLYSULFIDE POLYMER (NON-HAZARDOUS) CAS:68611-50-7 Other REC Limits:NONE RECOMMENDED Ingred Name:ALUMINUM POWDER (SARA 313) CAS:7429-90-5 RTECS #:BD0330000 Fraction by Wt: <5.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 MG/M3 DUST ACGIH TLV:10 MG/M3 DUST Ingred Name:FENOLIC RESIN POWDER NON-HAZARDOUS INGREDIENTS Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT Ingred Name:SILICA DERIVITIVES CAS:67762-90-7 Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE: BURNING, TEARING, REDDENING. SKIN: DRYING, CRACKING, DERMATITIS. INHAL: DIZZINESS, DROWSINESS, FATIGUE, LIVER/KIDNEY DAMAGE. INGEST: DROWSINESS, DIZZINESS, NAUSEA. CHRONIC: DISTURBANCE IN MEMORY, THINKING ABILITY, EMOTIONS, & COORDINATION. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/LUKEWARM WATER FOR 15 MINUTES, CALL DR. SKIN: WASH W/SOAP & WATER, CALL DR. INHAL: REMOVE TO FRESH AIR, CALL DR. INGEST: CALL DR. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:74.0F,23.3C Lower Limits:1.0 Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER. Fire Fighting Procedures:USE AIR SUPPLIED RESPIRATOR. USE WATER TO COOL HEAT EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:HIGH TEMPERATURES MAY CAUSE PRESSURE BUILDUP IN CLOSED CONTAINER. ================== Accidental Release Measures ================== Spill Release Procedures:SCOOP INTO CONTAINERS. CLEANUP RESIDUE W/SUITABLE SOLVENT. CERCLA RQ FOR TOLUENE, 1000 LBS. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. DONT STORE >120F. GROUND/BOND WHEN TRANSPORTING. Other Precautions:EMPTY DRUMS MAY CONTAIN EXPLOSIVE VAPORS. DONT CUT/PUNCTURE/WELD ON/NEAR DRUM. VAPORS ARE >AIR, MAY COLLECT IN LOW/CONFINED AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN APPLYING IN ANY CIRCUMSTANCES LIKELY TO PRODUCE AIRBORNE LEVELS OF HAZARDOUS INGREDIENTS IN EXCESS OF TLV, USE ORGANIC VAPOR CARTRIDGE OR AIR SUPPLIED RESPIRATOR. Ventilation:GENERAL VENT TO MAINTAIN VAPORS BELOW TLV. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING, BEFORE SMOKING OR EATING. AVOID INGESTION. Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Vapor Density:>AIR Spec Gravity:1.46 VOC Pounds/Gallon:66 Evaporation Rate & Reference:NA Appearance and Odor:WHITE PASTE. Percent Volatiles by Volume:15.6 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Hazardous Decomposition Products:OXIDES OF CARBON, SULFUR DIOXIDE, TRACES OF HYDROGEN SULFIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:IN ACCORDANCE W/FEDER/STATE/LOCAL REGULATIONS. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MIL-C-22750 E PART A M1-048, M22750-1X-26595 Kit Part:Y CAGE:DO165 CAGE:DO165 CAGE:5V430 ============= Composition/Information on Ingredients ============= Ingred Name:TOLUENE. VP: 38 CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 5-20% OSHA PEL:100PPM;150PPM STEL ACGIH TLV:50 PPM,S EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:REACTION PRODUCTS OF EPICHLOROHYDRIN & BISPHENOL A CAS:25085-99-8 Fraction by Wt: 20-50% Ingred Name:DILUENT 8 CAS:68609-97-2 Fraction by Wt: 1-5% Ingred Name:2-BUTANONE; (METHYL ETHYL KETONE) (MEK). VP: 71.2 CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 5-20% OSHA PEL:200 PPM;300 PPM STEL ACGIH TLV:200 PPM;300 PPM STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TALC (POWDER) CONTAINING NO ASBESTOS FIBERS; (MAGNESIUM SILICATE HYDRATE) (CONTAINS ING 6 AT 1%-0.1%) CAS:14807-96-6 RTECS #:WW2710000 Fraction by Wt: 5-20% OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3 Ingred Name:CRYSTALLINE SILICA Ingred Name:VOLATILE ORGANICS COMPOUNDS: 203 GPL RTECS #:9999999VO Ingred Name:SUPP DATA: ELEVATED TEMP PROCESS CNDTNS, ESP IN PROCESS OPERATING UNDER VACUUM IF SUBJECTED TO SUDDEN INGRESS OF (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: AIR/OUTSIDE PROCESS EQUIP OPERATING UNDER ELEVATED PRESS IF SUDDEN ESCAPE OF VAPS/MISTS TO ATM OCCURS. (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:ANY PROPOSED USE OF PROD IN ELEVATED TEMP PROCESSES SHOULD BE THORO EVALUATED TO ASSURE THAT SAFE (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: OPERATING CNDTNS ARE ESTABLISHED AND MAINTAINED. RTECS #:9999999ZZ Ingred Name:EXPLAN OF CARCIN: 1991. ANTICIPATED TO BE A CARCINOGEN. RTECS #:9999999ZZ Ingred Name:RESP PROT: AIR SAMPLING TEST. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: OVEREXP MAY PRDCE VARIOUS EFTS, INCL: ACUTE TOX, RSLTG IN HDCH, DIZZ, NAUS, & LOSS OF CONSCIOUSNESS. SEV EYE IRRIT POSS RSLTG IN PERM DAM. IRRITATED MUC MEMB. VOMIT DUE TO INGEST. DEFAT & DRY O F SKIN. SENSIT AFTER RPTD CONT. CHRONIC: RPTS HAVE ASSOC RPTD & PRLNGD OCCUP OVEREXP TO SOLV W/PERM (EFTS OF OVEREXP) Explanation of Carcinogenicity:CRYSTALLINE SILICA: IARC 2A, IARC MONOGRAPHS, SUPPLEMENT, VOL 7, PG 341, 1987. NTP 6TH ANNUAL REPORT ON CARCIN, (ING 12 Effects of Overexposure:HLTH HAZ: BRAIN & NERV SYS DAM. INTENTIONAL MISUSE BY DELIB CONC & INHALING CONTENTS MAY BE HARMFUL/FATAL. NOTE: TOLUENE (CAS # 108-88-3) APPEARS ON NAVY LISTING OF OCCUP CHEM REPROD HAZARDS. SEEK CON SULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZARD LIST INFO & SAFE HNDLG & EXPOS INFO . Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/PLENTY OF CLEAN LUKEWARM LOW PRESS WATER FOR @ LST 15 MIN, OCCAS LIFTING LIDS OPEN. GET MED ATTN. INHAL: REMOVE TO FRESH AIR & PROVIDE OXYGEN IF BRTHG DFCLT. GIVE ARTF RESP IF NOT BRTHG. G ET MED ATTN. KEEP WARM & COMFORTABLE. NEVER GIVE AN UNCON PERSON LIQ. INGEST: CALL PHYS IMMED. ONLY INDUCE VOMIT ON INSTRUCTIONS OF PHYS. IF VOMIT OCCURS SPONT, KEEP HEAD BELOW HIPS TO PVNT(SUPP DATA) ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:22.0F,-5.6C Lower Limits:1.2% Extinguishing Media:FOAM, CARBON DIOXIDE, OR DRY CHEMICAL. Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. WATER MAY BE USED TO KEEP EXPOSED CONTAINERS COOL, AND TO KEEP FLAMMABLE STRUCTURE WET. Unusual Fire/Explosion Hazard:WATER PRESSURE MAY SPREAD A FLAMMABLE LIQUID FIRE. SEALED CONTAINERS MAY EXPLODE IF OVERHEATED. ================== Accidental Release Measures ================== Spill Release Procedures:WARNING-FLAMM. ELIM ALL IGNIT SOURCES. HANDLING EQUIPMENT MUST BE GROUNDED TO PREVENT SPARKING. SOAK UP WITH AN ABSORBENT AND PLACE IN NON-LEAKING CONTAINERS. SEAL TIGHTLY FOR PROPER DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:TREAT AS A HAZARDDOUS-FLAMMABLE MATERIAL. KNOW APPLICABLE D.O.T. REGULATIONS BEFORE ATTEMPTING TO TRANSPORT THIS MATERIAL. Other Precautions:WARNING:HOT ORG CHEM VAPS/MISTS ARE SUSCEPTIBLE TO SUDDEN SPONT COMBUST WHEN MIXED W/AIR. IGNIT MAY OCCUR @ TEMPS BELOW THOSE PUBLISHED AS "AUTOIGNIT" TEMPS. IGNIT TEMP DECR W/INCREASING VAP VOL & VAP /AIR CONTACT TIME & ARE (SUPP DATA) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IMPORTANT-MUST PROVIDE ADEQ VENT TO MAINTAIN VAP CONC BELOW ESTABLISHED TLV LIM AS GIVEN BY OSHA. IN MORE CONFINED AREAS A NIOSH/MSHA APPRVD RESP EQUIPPED W/ORG VAP CARTRIDGE SHOULD BE WORN. WHEN IN D OUBT WEAR APPRVD RESP & ORDER (ING 13) Ventilation:MUST PROVIDE ADEQUATE VENTILATION. Other Protective Equipment:HAVE EYE BATH AND SAFETY SHOWER AVAILABLE. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRST AID PROC: ASPIR OF LIQ INTO LUNGS. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON. SKIN: FLUSH W/WATER WHILE REMOVING CONTAMD CLTHG & SHOES. FOLLOW BY WASHING W/SOAP & WATER. DO NOT REUSE CONTAMD CLTHG/SHOES. IF IRRIT PERSISTS, GET MEDATTN. OTHER PREC:INFLUENCED BY PRESS CHANGES. IGNITE MAY OCCUR @ TYPICAL (ING 8) ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:>174F,>79C Vapor Pres:SEE INGRED Vapor Density:HVR/AIR Spec Gravity:1.168 Evaporation Rate & Reference:3.41(N-BUTYL ACETATE=1) Appearance and Odor:WHITE LIQUID Percent Volatiles by Volume:24.6 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MAY BE INCOMPATIBLE WITH OXIDIZING AGENTS AND STRONG ALKALIES. Stability Condition to Avoid:AVOID HEAT, SPARKS, OPEN FLAMES, AND INCOMPATIBILITIES. Hazardous Decomposition Products:INCOMPLETE COMBUSTION FOR PRODUCTS LIKE THIS MAY GENERATE HIGHLY POISONOUS CARBON MONOXIDE AND OTHER TOXIC GASES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH CURRENT LOCAL, STATE AND FEDERAL REGULATION. CONTACT AN APPROVED DISPOSAL FACILITY.
1
eyes_protection_mandatory
======================================================= NIIN: 01-387-5930 Product ID: CITRUS-KLEEN #1095 Cage: 93607 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 93607 ======================================================= Item Description Information ======================================================= Item Manager: S9G Item Name: CLEANING COMPOUND, SOLVENT-DETERGENT Unit of Issue: CN UI Container Qty: 5 GL CN ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: NO Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: CAUSES SKIN/EYE IRRIT. DO NOT INGEST. HARMFUL IF SWALLOWED. MAY CAUSE SEVERE MUCOSAL DAMAGE & GASTRIC DISTRESS. MAY CAUSE SYSTEMIC INTOXICATION. Medical Cond Aggravated By Exposure: MAY AGGRAVATE EXISTING DERMATITIS & IRRITATE SENSITIVE SKIN. First Aid: EYES: FLUSH W/WATER 15 MIN. GET MED AID. SKIN: THOROUGHLY WASH W/WATER & APPLY CREAM. IF IRRIT PERSISTS, GET MED AID. INGESTION: DON'T INDUCE VOMITING. GIVE MILK, EGG WHITE, GELATIN, WATER. GET IMMEDI ATE MED AID. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: RECONTAINERIZE BY MOPPING, WET VACUUM OR USE SUITABLE ABSORBENT. RINSE REMAINING MATERIAL TO DRAINS. BE CAUTIOUS OF SLIPPERY FLOORS. Waste Disposal Methods: FOLLOW LOCAL, STATE, FEDERAL REGS. Handling And Storage Precautions: STORE BETWEEN 40-120F. Other Precautions: KEEP AWAY FROM CHILDREN. FOR SALE, USE, STORAGE BY SERVICE PERSONNEL ONLY. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: TOC Flash Point Text: NONE TO BOILING Lower Limits: NOT EST. Upper Limits: NOT EST. Unusual Fire/Explosion Hazard: NONE ======================================================= Control Measures ======================================================= Respiratory Protection: GENERALLY NOT REQUIRED. Ventilation: LOCAL. Other Protective Equipment: RUBBER BOOTS SHOULD BE WORN IF WORKING IN STANDING SOLUTIONS. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: 212F,100C Vapor Pres: =WATER Vapor Density: =WATER Spec Gravity: 1.062 PH: 13.5 Evaporation Rate & Reference: =WATER Solubility in Water: COMPLETE Appearance and Odor: ORANGE LIQUID, ORANGE ODOR Percent Volatiles by Volume: 87.0 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Materials To Avoid: ACIDS, OXIDIZERS. Hazardous Decomposition Products: CARBON OXIDES, AMINES. Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Trans ID NO: 132746 Product ID: CITRUS-KLEEN #1095 Review Date: 04/24/1996 Multiple KIT Number: 0 Review IND: Y Unit Of Issue: CN Container QTY: 5 GL CN ======================================================= Detail DOT Information ======================================================= DOT PSN Code: ZZZ DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail IMO Information ======================================================= IMO PSN Code: ZZZ IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION ======================================================= Detail IATA Information ======================================================= IATA PSN Code: ZZZ IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail AFI Information ======================================================= AFI PSN Code: ZZZ AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= HAZCOM Label ======================================================= Product ID: CITRUS-KLEEN #1095 Cage: 93607 Company Name: NATIONAL CHEMICAL LABORATORIES OF PENNSYLVANIA INC Street: 401 N 10TH ST Zipcode: 19123-3803 Label Required IND: Y Date Of Label Review: 12/16/1998 Status Code: C Label Date: 12/16/1998 Origination Code: G Hazard And Precautions: CAUSES SKIN/EYE IRRIT. DO NOT INGEST. HARMFUL IF SWALLOWED. MAY CAUSE SEVERE MUCOSAL DAMAGE & GASTRIC DISTRESS. MAY CAUSE SYSTEMIC INTOXICATION. NK =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SUPERIOR NO.11 CAGE:6F776 CAGE:6F776 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM NITRATE CAS:7631-99-4 RTECS #:WC5600000 Fraction by Wt: 30.0% Ingred Name:SODA ASH CAS:497-19-8 RTECS #:VZ4050000 Fraction by Wt: 30.0% Ingred Name:SODIUM TETRABORATE, DECAHYDRATE CAS:1303-96-4 RTECS #:VZ2275000 Fraction by Wt: 30.0% OSHA PEL:10 MG/M3 ACGIH TLV:5 MG/M3; 9192 ===================== Hazards Identification ===================== Effects of Overexposure:LARGE AMOUNTS TAKEN BY MOUTH MAY HAVE SERIOUS OR EVEN FATAL EFFECTS ======================= First Aid Measures ======================= First Aid:EXTERNALLY:WASH WITH WATER WHEN EXPOSED TO EYES OR SKIN. INTERNALLY:DRINK SEVERAL GLASSES OF WATER OR MILK & CALL MD. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:NONE Fire Fighting Procedures:USE PLENTY OF WATER Unusual Fire/Explosion Hazard:MODERATE, WHEN MIXED WITH ORGANIC MATTER, WILL IGNITE ON FRICTION.EXPLODES WHEN MIXED WITH CYANIDES ================== Accidental Release Measures ================== Spill Release Procedures:WASH WITH WATER MATERIAL IS RELATIVELY HARMLESS EXCEPT ON INGESTION. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM EXTREME HEAT Other Precautions:STORE IN DRY, COOL AREA. WATER OR MOISTURE WILL REDUCE SHELF LIFE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NON-TOXIC, MASK WHEN WORKING OR BRAZING Ventilation:MECHANICAL IS PREFERRED Other Protective Equipment:USUAL & CUSTOMARY Supplemental Safety and Health ITEM IS TYPE "C" OF MIL-F-16136 ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:DECOMPOSED Spec Gravity:2.15 Evaporation Rate & Reference:NEGLIGIBLE Solubility in Water:APPRECIABLE Appearance and Odor:WHITE HYGROSCOPIC POWDER, SLIGHT BITTER TASTE Percent Volatiles by Volume:1.0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REDUCING MATERIALS AT HIGH TEMPERATURES Stability Condition to Avoid:HEATING IN PRESENCE OF CYANIDES OR OTHER REDUCING AGENTS Hazardous Decomposition Products:FMES CONTAIN NITROGEN OXIDES & B2O*3 ==================== Disposal Considerations ==================== Waste Disposal Methods:WASH WITH ABUNDANT WATER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:AWLGRIP LINEAR POLYURETHANE TOPCOAT-GLOSS COLOR BASE CAGE:HO579 CAGE:HO579 CAGE:90608 ============= Composition/Information on Ingredients ============= Ingred Name:ING 18: BREATHE VAPS, SPRAY MIST/SANDING DUSTS. DO NOT GET IN EYES, ON SKIN/ON CLTHG. FOR INDUSTRIAL USE ONLY, (ING 20) RTECS #:9999999ZZ Ingred Name:ING 19: BY PROFESSIONAL, TRAINED PERSONNEL USING PROPER EQUIPMENT. NOT INTENDED FOR SALE TO/USE BY THE GENERAL PUBLIC. RTECS #:9999999ZZ Ingred Name:RESP PROT: CONTROLS SHOULD BE IMPLEMENTED TO REDUCE EXPOSURE. RTECS #:9999999ZZ Ingred Name:VENT: (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV. RTECS #:9999999ZZ Ingred Name:EYE PROT: AND FULL LENGTH FACESHIELD . RTECS #:9999999ZZ Ingred Name:VOLATILE ORGANIC CONTENT (MATERIAL): 475-591 G/L RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:EFTS OF OVEREXP: RSLT IN CNS DEPRESS, HEMORRHAGES INTO VARIOUS VITAL ORGANS HAVE BEEN NOTED, NARCOTIC EFTS HAVE (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: BEEN NOTED, MAY CAUSE INJURY TO KIDNEYS, LIVER & LUNGS, CORNEAL EFTS MAY OCCUR, COMA MAY RSLT FROM (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: OVEREXP. REPORTS HAVE ASSOC RPTD & PRLNG OCCUP OVEREXP TO SOLV W/PERM BRAIN & NERV SYS DMG. INTENTIONAL (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: MISUSE BY DELIBERATELY CONCENTRATING & INHALING CONTENTS MAY BE HARMFUL/FATAL. WARNING! HARMFUL/FATAL IF (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: SWALLOWED. HARMFUL IF INHALED/ABSORBED THRU SKIN. OVEREXP MAY CAUSE BLOOD DISORDERS. BASED ON TESTS W/ (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: LAB ANIMALS, OVEREXP MAY CAUSE REPRO DISORDERS & BIRTH DEFECTS. WARNING! THIS PROD CONTAINS A CHEMICAL (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR REPRODUCTIVE HARM. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: IF BRTHG CEASES, RESTORE USING APPROVED CPR TECHNIQUES, AND SUMMON MEDICAL HELP IMMEDIATELY. RTECS #:9999999ZZ Ingred Name:SPILL PROC: UNTIL CLEAN-UP HAS BEEN COMPLETED. STOP SPILL AT SOURCE, CONTAIN AREA OF SPILL TO PVNT SPREADING, (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14: PUMP LIQ TO SALVAGE TANK. REMAINING LIQ MAY BE ABSORBED W/INERT MATL SUCH AS SAND, CLAY, EARTH/FLOOR (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15: ABSORB & SHOVELED INTO CONTRS W/NON-SPARKING TOOLS. PVNT RUN-OFF TO SEWERS, STREAMS/OTHER BODIES OF (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: WATER. IF RUN-OFF OCCURS, NOTIFY THE PROPER AUTHORITIES AS REQUIRED THAT A SPILL HAS OCCURRED. RTECS #:9999999ZZ Ingred Name:OTHER PREC: & PREC ON LABELS OF ALL PROD BEING BLENDED AS COMBINATION MAY CONTAIN HAZ OF EACH COMPONENT. DO NOT (ING 19) RTECS #:9999999ZZ Ingred Name:2-BUTANONE VP: 70 @ 20C CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 2-5% OSHA PEL:200 PPM ACGIH TLV:200 PPM/300STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHANOL, 2-ETHOXY-, ACETATE; (CELLULOSE ACETATE 2-ETHOXYETHYLETHANOATE) VP: 2 @ 20C CAS:111-15-9 RTECS #:KK8225000 Fraction by Wt: 16-23% OSHA PEL:100 PPM, S ACGIH TLV:5 PPM, S Ingred Name:ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER; (PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE) VP: 4 @ 20C CAS:108-65-6 RTECS #:AI8925000 Fraction by Wt: 9-24% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:XYLENE; (DIMETHYL BENZENE) (SARA 313) (CERCLA) VP: 10 @ 20C CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 1-6% OSHA PEL:100 PPM ACGIH TLV:100 PPM/150STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYE: CAN CAUSE SEV IRRIT, REDNESS, TEARING & BLURRED VISION. SKIN: PRLNG/RPTD CONT CAN CAUSE MOD IRRIT, DEFAT & DERM. SOLV CAN PENETRATE SKIN CAUSING EFTS SIMILAR TO THOSE IDENTIFIED UNDER ACUT E BRTHG SYMP. INHAL: EXCESS INHAL OF VAPS CAN CAUSE NASAL & RESP IRRIT, DIZZ, WEAK, FATG, NAUS, HDCH, (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: POSS UNCON & EVEN ASPHY. MAY ALSO CAUSE TIGHTNESS IN CHEST. INGEST: HARMFUL, CAN CAUSE BURNING SENSATION, SORE THROAT, ABDOM PAIN, NAUS, VOMIT & DIARR. CHRONIC: PRLNG & RPTD BRTHG OF SPRAY M IST &/SANDING DUST OVER PERIOD OF YRS MAY CAUSE DISEASES OF LUNGS. CAN CAUSE IRRIT TO MUC MEMB. HIGH VAPS MAY (ING 6) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN: WASH AREA THORO W/SOAP & WATER. REMOVE SOILED CLTHG. GET MED ASSIST IF IRRIT PERSISTS. WASH CLTHG BEFORE REUSE. EYE: FLUSH W/LGE AMTS OF WATER FOR AT LEAST 15 MIN. GET MED ASSIST. INGEST: GET ME D ATTN IMMED. DO NOT INDUCE VOMIT. ASPIR OF MATL INTO LUNGS CAN CAUSE CHEM PNEUMIT WHICH CAN BE FATAL. INHAL: IF DFCLT BRTHG OBTAIN FRESH AIR. IF CONTINUED DFCLT, SUMMON MED ASSIST IMMED. (ING 13) ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:21.0F,-6.1C Lower Limits:1.10% Extinguishing Media:USE CARBON DIOXIDE, DRY CHEMICAL, FOAM, OR OTHER APPROVED METHOD FOR TREATING A CLASS B FIRE. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . SUMMON PROFESSIONAL FIREFIGHTERS. DURING FIRE, TOX GASES & SMOKE ARE IRRIT PRESENT FROM DECOMP/ (SUP DAT) Unusual Fire/Explosion Hazard:KEEP AWAY FROM HEAT, SPARKS & FLAME. DO NOT SMOKE. EXTING ALL PILOT LIGHTS & TURN OFF ALL SOURCES OF IGNIT, INCL HEATERS, FANS & OTHER NON-EXPLO-PROOF (SUP DAT) ================== Accidental Release Measures ================== Spill Release Procedures:SML SPILL: ABSORB ON INERT MATL SUCH AS PAPER, VERMICULITE, FLOOR ABSORB & TRANSFER TO HOOD. LGE SPILL: ELIM ALL IGNIT SOURCES (FLARES, FLAMES INCL PILOT LIGHTS, ELEC SPARKS). PERS NOT WEARING PROT EQ UIP SHOULD BE EXCLUDED FROM AREA OF SPILL (ING 14) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CLOSURE TIGHT & UPRIGHT TO PVNT LEAKAGE. KEEP CONTR CLSD WHEN NOT IN USE. DO NOT STORE > 120F. DO NOT TRANSFER CONTENTS TO BOTTLES/OTHER(SUP DAT) Other Precautions:CONTRS OF THIS MATL MAY BE HAZ WHEN EMPTIED BECAUSE THEY RETAIN PROD RESIDUES (VAP, LIQ, &/SOLID). ALL HAZ PREC GIVEN IN THIS MSDS MUST BE OBSERVED. IMPORTANT!! THIS PROD MAY BE BLENDED W/OTHER PROD P RIOR TO USE. READ ALL WARNINGS (ING 18) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR APPROP, PROPERLY FITTED RESP (NIOSH/MSHA APPRVD) DURING & AFTER APPLICATION UNLESS AIR MONITORING DEMONSTRATES VAP, MIST & PARTICULATE LEVELS ARE BELOW APPLIC LIM. FOLLOW RESP MFR'S DIRECTIONS FO R RESP USE. ENGINEERING/ADMIN (ING 21) Ventilation:USE ONLY WITH ADEQUATE VENTILATION. MAINTAIN CONTINUOUS FLOW OF FRESH AIR. PROVIDE SUFFICIENT MECHANICAL (ING 22) Other Protective Equipment:SOLVENT IMPERMEABLE CLOTHING AND BOOTS. EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRE FIGHT PROC: COMBUST. CLSD CONTR MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. EXPLO HAZ: ELEC EQUIP, DURING USE & UNTIL ALL VAPS ARE GONE. VAPS MAY IGNITE EXPLO. VAPS MAY SPREAD LONG DIST & BEYOND CL SD DOORS. PVNT BUILD-UP OF VAPS BY MAINTAINING CONTINUOUS FLOW OF FRESH AIR. HNDLG/STOR PREC: UNLABELED CONTAINERS. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>172F,>78C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER Percent Volatiles by Volume:50-63 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES POTASSIUM-TERT-BUTOXIDE, PERMANGENATE, CHLOROFORM, CHLOROSULFONIC ACID, HYDROGEN PEROXIDE, NITRIC ACID. Stability Condition to Avoid:EXCESS HEAT AND/OR OXIDIZING MATERIALS. Hazardous Decomposition Products:MAY DECOMPOSE INTO FUMES CONTAINING CARBON MONOXIDE AND CARBON DIOXIDE. WHEN HEATED TO DECOMPOSITION EMITS TOXIC FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:ALLOW VOLATILE PORTION TO EVAPORATE IN HOOD BEING SURE TO ALLOW SUFFICIENT TIME FOR VAPORS TO COMPLETELY CLEAR HOOD DUCT WORK. DISP OF CONTAMINATED ABSORBENT CONTR & UNUSED CONTENTS I/A/W LOCAL, STATE & FEDERAL REGS. DO NOT INCINERATE CLOSED CONTRS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:140S VINYL ENAMELS,CHASSIS BLACK,DUCO BLACK,VINYL CLEARS Preparer's Name:T R LOUER CAGE:23027 CAGE:90227 CAGE:23027 ============= Composition/Information on Ingredients ============= Ingred Name:ASPHALT FUMES, ASPHALT, CUTBACK ASPHALT (IARC CARCINOGEN GROUP 3) *96-2* CAS:8052-42-4 RTECS #:CI9900000 Other REC Limits:5 MG/CUM ACGIH TLV:5 MG/CUM Ingred Name:GILSONITE Ingred Name:MEDIUM ALIPHATIC NAPHTHA (AROMATIC 100), PARAFFIN-NAPTHANES MINERAL SPIRITS CAS:64742-88-7 Other REC Limits:100 PPM OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:LIGHT ALIPHATIC NAPHTHA, VM & P NAPHTHA, LACOLENE CAS:64742-89-8 OSHA PEL:300 PPM ACGIH TLV:300 PPM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: NOSE & THROAT IRRITATION. REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS MAY CAUSE PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. SKIN: IRRITATION, DERMATITIS & BURNING. EYES: IRRITATION & BURNING. Explanation of Carcinogenicity:NONE Effects of Overexposure:GI DISTRESS, IRRITATION, EYE WATERING, HEADACHES, NAUSEA, DIZZINESS, LOSS OF COORDINATION, BURN. ======================= First Aid Measures ======================= First Aid:INGESTION: CALL PHYSICIAN IMMEDIATELY & HAVE THE NAMES OF INGREDIENTS AVAILABLE. INHALATION: REMOVE TO FRESH AIR. EYES: FLUSH W/PLENTY OF WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER. OBTAIN MEDICAL A TTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:<73F Lower Limits:1 Upper Limits:13.1 Extinguishing Media:WATER SPRAY, FOAM, CO2, DRY CHEMICAL. Fire Fighting Procedures:WEAR FULL PROTECTIVE EQUIPMENT W/SCBA. WATER FROM FOG NOZZLES MAY BE USED TO COOL CLOSED CONTAINERS. Unusual Fire/Explosion Hazard:WHEN HEATED ABOVE THE FLASH POINT, EMITS FLAMMABLE VAPORS WHICH, WHEN MIXED W/AIR, CAN BURN/EXPLOSED. FINE MISTS/SPRAYS MAY BE FLAMMABLE AT TEMP 120F. Other Precautions:DON'T SAND, FLAME CUT, BRAZE/WELD DRY COATING W/O NIOSH/MSHA APPROVED RESPIRATOR/APPROPRIATE VENTILATION. OBSERVE LABEL PRECAUTIONS. DON'T BREATHE VAPORS/MISTS. DON'T PERMIT ANYONE W/O PROTECTION IN T HE PAINTING AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR A PROPERLY FITTED VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA FOR USE W/PAINTS DURING APPLICATION & UNTIL ALL VAPORS & SPRAY MISTS ARE EXHAUSTED. CONFINED SPACES, WEAR A POSITIVE-PRESSURE , SUPPLIED AIR RESPIRATOR (TC-19C). Ventilation:SUFFICIENT VENTILATION Other Protective Equipment:COVERALLS. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING & BEFORE EATING/SMOKING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:129-437F Vapor Density:>1 VOC Grams/Liter:3.7 Evaporation Rate & Reference:(ETHER =1): <1 Solubility in Water:MISCIBLE Percent Volatiles by Volume:61-92 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:HEAT, SPARKS, FLAME & OTHER IGNITION SOURCES. Hazardous Decomposition Products:CO, CO2, SMOKE ==================== Disposal Considerations ==================== Waste Disposal Methods:DON'T ALLOW TO CONTAMINATE GROUND WATER SYSTEMS. INCINERATE ABSORBED MATERIAL IAW/FEDERAL, STATE & LOCAL REGULATIONS. DON'T INCINERATE IN CLOSED CONTAINERS. FLAMMABLE LIQUID, UN1263.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:X306 CAGE:98502 CAGE:98502 ============= Composition/Information on Ingredients ============= Ingred Name:CALCIUM CHROMATE (SARA III) CAS:13765-19-0 RTECS #:GB2750000 Fraction by Wt: < 5% Other REC Limits:NONE SPECIFIED OSHA PEL:0.05 MG CR/M3 ACGIH TLV:0.001 MG/M3;A2, 9394 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:ETHYL BENZENE (SARA III) CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: < 5% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM/125 STEL ACGIH TLV:100 PPM/125STEL 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:LEAD SULFOCHROME CAS:1344-37-2 Fraction by Wt: < 5% Other REC Limits:NONE SPECIFIED Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 10-25% Other REC Limits:NONE SPECIFIED OSHA PEL:200 PPM/300 STEL ACGIH TLV:200 PPM/300STEL 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:METHYL ISOBUTYL KETONE (SARA III) CAS:108-10-1 RTECS #:SA9275000 Fraction by Wt: 5-20% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM/75 STEL ACGIH TLV:50 PPM/75 STEL; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE CAS:108-65-6 RTECS #:AI8295000 Fraction by Wt: < 5% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM ACGIH TLV:100 PPN Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 5-20% Other REC Limits:NONE SPECIFIED OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 5-20% Other REC Limits:NONE SPECIFIED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:TALC (CONTAINING ASBESTOS) CAS:14807-96-6 RTECS #:MW2700000 Fraction by Wt: 15-30% Other REC Limits:NONE SPECIFIED OSHA PEL:0.2 FIBERS/CC ACGIH TLV:0.2 FIBERS/CC; 9192 Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 20-35% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:INHALATION;IRRITATION OF MUCOUS MEMBRANES AND PULMONARY FIBROSIS. EYES;BURNS,REDNESS,CINJUCTIVNESS. SKIN;REDNESS,SWELLING,BURNS POSSIBLE ULCERATIONS.INGESTION;IRRITATION,CHEMICAL BURNS OF THE MOUTH, T HROAT AND ESOPHAGUS AND STOMACH Effects of Overexposure:INHALATION;ASPHYXIATION. EYES; SENSATION OF SEEING HALOS AROUND LIGHTS. SKIN; CRACKING,IRRITATION ANDDERMITITIS. Medical Cond Aggravated by Exposure:NONE GIVEN ======================= First Aid Measures ======================= First Aid:INHALATION;REMOVE TO FRESH AIR,GIVE CPR IF REQUIRED. SKIN;WASH WITH SOAP AND WATER. EYES;FLUSH WITH WATER FOR 15MINUTES GET MEDICAL ATTENTION. INGESTION; DRINK ONE OR TWO GLASSES OF WATER TO DILUTE, D O NOT INDUCE VOMITING,CONSULT PHYSCIAN OR POUSON CONTROL OFFICE IMMEDIATELYTREAT SYMPTOMATICALLY. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:23.0F,-5.0C Lower Limits:1.0 Upper Limits:UNK Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICALS. Fire Fighting Procedures:WATER MAY BE INEFFECTIVE, USE WATER TO COOL CONTAINERS EXPOSED TO FIRE. WEAR SCBA. Unusual Fire/Explosion Hazard:CLOSED CONTAINER MAY EXPLODE WHEN EXPOSED TO FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION,AVOID BREATHING VAPORS, VENTILATE AREAS, REMOVE WITH INERT ABSORBENT. Neutralizing Agent:NA ======================Handling and Storage ====================== Handling and Storage Precautions:STORE OUT OF SUN AND AWAY FROM HEAT,SPARKS AND OPEN FLAMES, CLOSE CONTAINERS AFTER EACH USE. Other Precautions:DO NOT TAKE INTERNALLY, USE APPROVE GROUNDING PROCEDURES, NEVER USE PRESSURE TO EMPTY.DO NOT WELD OR CUT DRUM. READ SAFETY PRECAUTIONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH RESPIRATOR WHERE TLVS ARE EXCEEDED Ventilation:LOCAL TO MAINTAIN TLVS BELOW. Other Protective Equipment:NA Work Hygienic Practices:EWASH HANDS BEFORE EATING,SMOKING OR USING WASHROOM Supplemental Safety and Health NA ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:175F,79C Vapor Pres:UNK Vapor Density:> AIR Spec Gravity:UNK Evaporation Rate & Reference:< ETHER Solubility in Water:UNK Appearance and Odor:GREEN PRIMER Percent Volatiles by Volume:73.4 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NA Stability Condition to Avoid:NA Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, SMOKE, OXIDES OF NITROGEN ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE IN APPROVED FACILITY, DO NOT INCINERATE CLOSED CONTAINERS, DISPOSE IN ACCORDANCE WITH LOCAL, STAE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BATTERY, STORAGE (NICKEL-CADMIUM) CAGE:74025 CAGE:74025 ============= Composition/Information on Ingredients ============= Ingred Name:CADMIUM (SARA III) CAS:7440-43-9 RTECS #:EU9800000 Other REC Limits:NONE SPECIFIED OSHA PEL:SEE 1910.1027 ACGIH TLV:0.01 MG/M3 DUST;9394 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:CADMIUM HYDROXIDE CAS:21041-95-2 Other REC Limits:NONE SPECIFIED OSHA PEL:0.1 MG/M3 (CD FUME) ACGIH TLV:0.05 MG/M3 (CD FUME) Ingred Name:NICKEL (SARA III) CAS:7440-02-0 RTECS #:QR5950000 Other REC Limits:NONE SPECIFIED OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3; 9192 Ingred Name:NICKEL HYDROXIDE (SARA III) CAS:12054-48-7 RTECS #:QR7040000 Other REC Limits:NONE SPECIFIED OSHA PEL:1 MG NI/M3 ACGIH TLV:0.1 MG NI/M3; 9293 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:POTASSIUM HYDROXIDE (SARA III) CAS:1310-58-3 RTECS #:TT2100000 Other REC Limits:NONE SPECIFIED OSHA PEL:C, 2 MG/M3 ACGIH TLV:C 2 MG/M3; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS 225 MG/KG CD(OH)2 Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:POTASSIUM HYDROXIDE: INHALATION OF AIRBORNE DUST OR MIST MAY CAUSE DAMAGE TO THE UPPER RESPIRATORY TRACT AND EVEN TO THE LUNG TISSUE. CADMIUM/CADMIUM HYDROXIDE: MAY CAUSE IRRITATION OF MUCOUS MEMBRANE S. CHRONIC EXPOSURE MAY CAUSE IRREVERSIBLE LUNG INJURY, KIDNEY DISEASE & OTHER ADVERSE EFFECTS. Explanation of Carcinogenicity:NICKEL/NICKEL COMPOUND ARE LISTED AS CARCINOGENIC TO HUMANS BY IARC. Effects of Overexposure:POTASSIUM HYDROXIDE: INHALATION CAN PRODUCE CHEMICAL PNEUMONIA. THIS MATERIAL IS DESTRUCTIVE TO SKIN TISSUE, EYE TISSUE, & MOUTH, THROAT, STOMACH TISSUES. CADMIUM/CADMIUM HYDROXIDE: CAN PRODUCE DRYNES S OF THE MOUTH & THROAT, HEADACHE, NAUSEA & DIZZINESS. INGESTION CAN CAUSE NAUSEA, VOMITING, DIARRHEA & ABDOMINAL CRAMPS Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:POTASSIUM HYDROXIDE: FLUSH EYES FOR 15 MINUTES WITH WATER AND WASH SKIN TISSUE WITH WATER. IF PATIENT IS CONSCIOUS GIVE LARGE QUANTITIES OF WATER. DO NOT INDUCE VOMITING. GET EMERGENCY MEDICAL ATTENTI ON. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE EXTINGUISHING MEDIA APPROPIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:FIRE FIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF CONTAINED BREATHING APPARATUS WITH FULL FACE-PIECE OPERATED IN POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:CONTACT WITH STRONG OXIDOZERS MAY CAUSE FIRE OR EXPLOSION. CADMIUM FUMES OR VAPORS ARE TOXIC AND CAN CAUSE DEATH. ================== Accidental Release Measures ================== Spill Release Procedures:BATTERY AND CELL CASES WILL NORMALLY CONTAIN MATERIALS OF CONCERN. USE INDUSTRIAL ABSORBENT TO COLLECT LIQUID POTASSIUM HYDROXIDE. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT INVERT. AVOID BREAKING, CRUSHING OR OTHERWISE DESTROYING THE PHYSICAL INTEGRITY OF THE CELL OR BATTERY. Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR A DUST OR MIST MASK WHEN HANDLING THE POTASSIUM HYDROXIDE SOLUTION. Ventilation:USE ADEQUATE LOCAL EXHAUST VENTILATION WHEN HANDLING THE LIQUID IN THE BATTERY. Other Protective Equipment:WEAR PROTECTIVE CLOTHING TO MINIMIZE SKIN CONTACT. Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER USE AND BEFORE EATING, DRINKING OR SMOKING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:Z5 Melt/Freeze Pt:M.P/F.P Text:DECOM 300C Solubility in Water:INSOLUBLE Appearance and Odor:NO ODOR. WHITE SALT. (CADMIUM HYDROXIDE) ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENT, NITRATES, NITRIC CAID. Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:CELLS AND BATTERIES MAY BE RTETURNED AT SENDERS EXPENSE TO MARATHON POWER TECHNOLOGIES. DISPOSAL SHALL BE BY APPROVED METHODS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FC2207-FO, COLOR FC2207 OR COLOR PRINTER (SUPDAT) CAGE:CLRCS CAGE:CLRCS ============= Composition/Information on Ingredients ============= Ingred Name:DIMETHYL POLYSILOXANE (NON HAZARDOUS) OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:5,000 MG/KG Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE: TRANSIENT WEAK IRRITATION. SKIN: NON-IRRITANT. INHAL: ESSENTIALLY NON-TOXIC. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN: REMOVE LIQUID FROM SKIN W/A DRY TOWEL AND WASH EXPOSED AREA W/DETERGENT. EYE: IMMED FLUSH WITH WATER FOR AT LEAST 15 MINUTES. INHAL: REMOVE TO FRESH AIR. SUPPORT BRTHG (GIVE O*2/ARTF RESP) (FP N ). INGEST: CALL MD IMMED . ===================== Fire Fighting Measures ===================== Flash Point:>204F,>96C Extinguishing Media:CO*2, DRY CHEMICALS, FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:THIS MATERIAL HAS NO UNUSUAL FIRE/EXPLOSION HAZARDS. ================== Accidental Release Measures ================== Spill Release Procedures:USE ABSORBENT MATERIAL TO COLLECT AND CONTAIN FLUID FOR SALVAGE OR DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NO SPECIAL STORAGE REQUIREMENTS ARE NEEDED FOR SAFETY REASONS. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health MFR TRADE NAME/PART #: CP4007 FUSER OIL. ================== Physical/Chemical Properties ================== Spec Gravity:0.97-0.98 Solubility in Water:NEGLIGIBLE Appearance and Odor:COLORLESS, TRANSPARENT, ODORLESS FLUID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:SIO, CO*2 AND TRACES OF INCOMPLETELY BURNED CARBON PRODUCTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE IN COMPLIANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:P104J CAGE:00656 CAGE:00656 ============= Composition/Information on Ingredients ============= Ingred Name:POLYCHLORINATED BIPHENYLS (PCBS) (SARA III) CAS:1336-36-3 RTECS #:TQ1350000 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Effects of Overexposure:ABSORBED THRU SKIN,LUNGS,INTESTINE.CAUSES CANCER,LIVER,KIDNEY,STOMACH,EYE,HEARING DISORDER(SUP DATA) ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/WATER IMMED.SKIN:WASH W/SOAP IMMED.INHAL:REMOVE TO FRESH AIR.GIVE ART.RESPIR. AS NEEDED.INGEST:GET MEDICAL ATTN.GIVE LARGE QTY OF SALT WATER,INDUCE VOMITING,BUT DO NOT MAKE UNCONSCIOUS PE RSON VOMIT. ================== Accidental Release Measures ================== Spill Release Procedures:USE ABSORBENT & DIKES TO PREVENT RUNOFF.ISOLATE & NOTIFY PROPER AUTHORITIES. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE MUST FOLLOW RCRA REQUIREMENTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SUPPLIED AIR W/FULL FACEPIECE,HELMET OR HOOD Ventilation:LOCAL EXHAUST Other Protective Equipment:FULL CLOTHING TO PREVENT SKIN CONTACT Supplemental Safety and Health OVEREXPOS:CAN CAUSE FORMATION OF CYSTS.CAUSES STILLBIRTHS.IRRITATES EYES,NOSE,THROAT. ================== Physical/Chemical Properties ================== HCC:V1 Appearance and Odor:LIGHT STRAW COLORED LIQUID,AROMATIC ODOR. ================= Stability and Reactivity Data ================= STRONG OXIDIZERS ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-GENERALLY HIGH TEMPERATURE INCINERATION.ONLY APPROVED DISPOSAL OPERATOR PERMITTED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PYROPEL P 84 POLYIMIDE FIBER CAGE:24173 CAGE:24173 ============= Composition/Information on Ingredients ============= Ingred Name:NON HAZARDOUS INGREDIENTS OSHA PEL:5 MG/M3 (MFR) ACGIH TLV:5 MG/M3 (MFR) ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NONE. Explanation of Carcinogenicity:NOT RELEVANT Medical Cond Aggravated by Exposure:NONE. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. SUPPORT BRTHG (GIVE O2/ARTF RESP) . INGEST: CALL MD IMMED . SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER. CALL MD . EYE: IMMED FLUSH WITH POTABLE WATER FOR AMINIMUM OF 15 MIN,SEEK ASSISTANCE FROMMD . ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE, NON-FLAMMABLE MATERIAL, LOI-38. ================== Accidental Release Measures ================== Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED. USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Other Protective Equipment:NONE REQUIRED. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:N1 Melt/Freeze Pt:M.P/F.P Text:NONE Spec Gravity:1.41(H2O=1) Solubility in Water:INSOLUBLE Appearance and Odor:YELLOW FIBROUS SOLID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES LONG TERM EXPOSURE TO CAUSTIC. Hazardous Decomposition Products:NONE KNOWN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL BY LOCAL ACCEPTABLE METHOD FOR NON- HAZARDOUS SOLID MATERIALS. DISPOSE OF I/A/W FEDERAL, STATE AND LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TONER-KYOCERA 1010, 103361-01 CAGE:DUMEC CAGE:DUMEC ============= Composition/Information on Ingredients ============= Ingred Name:STYRENE-ACRYLATE COPOLYMER CAS:25213-39-2 Fraction by Wt: 55-60% Ingred Name:IRON(III) OXIDE; (MAGNITE) CAS:1309-37-1 RTECS #:NO7400000 Fraction by Wt: 35-40% OSHA PEL:10 MG/M3 (FE) ACGIH TLV:5 MG/M3(FE),B2; 9293 Ingred Name:PROPENE POLYMERS; (POLYPROPYLENE) CAS:9003-07-4 RTECS #:UD1842000 Fraction by Wt: 5-10% Ingred Name:METAL COMPLEX AZO DYE. MFR CAS # 84179-66-8 CAS:85179-66-8 Fraction by Wt: <5% Ingred Name:SILICA, AMORPHOUS; (AMORPHOUS SILICA) CAS:7631-86-9 Fraction by Wt: <1% OSHA PEL:6 MG/M3 RDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:CERIUM OXIDE; (METAL OXIDE) CAS:1306-38-3 Fraction by Wt: <1% ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NONE KNOWN. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:NO SYMPTOMS FROM OVEREXPOSURE. Medical Cond Aggravated by Exposure:CHRONIC UNPROTECTED EXPOSURE TO TONER DUST MAY AGGRAVATE BREATHING DIFFICULTIES. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. SKIN: WASH WITH SOAP & WATER. INHAL: REMOVE TO FRESH AIR. INGEST: RINSE MOUTH OUT WITH WATER. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER/FOAM/DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:TONER IS COMBUSTIBLE. EXPLOSIVE LIMITS OF TONER PARTICLES SUSPENDED IN AIR ARE EQUAL TO THOSE OF COAL DUST. ================== Accidental Release Measures ================== Spill Release Procedures:LOOSE TONER CAN BE REMOVED BY USING VACUUM. RESIDUE CAN BE REMOVED WITH SOAP AND COLD WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY PLACE. Other Precautions:NONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE UNDER NORMAL USE. USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NONE. Other Protective Equipment:NONE. Work Hygienic Practices:WASH HANDS WITH SOAP AND WATER BEFORE EATING. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:N1 Melt/Freeze Pt:M.P/F.P Text:194F,90C Spec Gravity:1.1(H*2O=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:BLACK POWDER/FAINT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:NONE. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT INCINERATE-NO SPECIAL TECHNIQUES BEYOND NORMAL PRACTICE. DISPOSAL METH MUST MEET LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:1-CHLORO-2,4-DINITROBENZENE GRADE 1, C6396 CAGE:21076 CAGE:21076 ============= Composition/Information on Ingredients ============= Ingred Name:BENZENE, 1-CHLORO-2,4-DINITRO-; (1-CHLORO-2,4-DINTROBENZENE GRADE I) CAS:97-00-7 RTECS #:CZ0525000 OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (ORAL, RAT) 1070 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: MAY BE FATAL IF INHALED, SWALLOWED OR ABSORBED THROUGH SKIN. CAUSES EYE AND SKIN IRRITATION. MATERIAL IS IRRITATING TO MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. SYMPTOMS OF EXPOSURE MAY INC LUDE BURNING SENSATION, COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA AND (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: VOMITING. ABSORPTION INTO THE BODY LEADS TO THE FORMATION OF METHEMOGLOBIN WHICH IN SUFFICIENT CONCENTRATION CAUSES CYANOSIS. ONSET MAY BE DELAYED 2 TO 4 HOURS OR LONGER. MAY CAUSE ALLERGICRESPIRATORY AND SKIN REACTIONS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST: CALL MD IMMEDIATELY . EYES/SKIN: IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. INHAL: REMOVE TO FRE SH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL MD. WASH CONTAMINATED CLOTHING BEFORE REUSE. ===================== Fire Fighting Measures ===================== Flash Point:367F,186C Lower Limits:2% Upper Limits:22% Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL POWDER, ALCOHOL OR POLYMER FOAM. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA. WEAR NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY RUBBER VENTILATE AREA AND WASH SPILL SI TE AFTER MATERIAL PICKUP IS COMPLETE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP TIGHTLY CLOSED. STORE IN A COOL, DRY PLACE. Other Precautions:DO NOT BREATHE DUST. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE. READILY ABSORBED THROUGH SKIN. HIGHLY TOXIC. SEVERE IRRITANT. STRONG SENSITIZER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:MECHANICAL EXHAUST REQUIRED. Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . WEAR OTHER PROTECTIVE CLOTHING. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:>120F,>49C Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG BASES, STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:TOXIC FUMES OF CARBON MONOXIDE AND CARBON DIOXIDE, NITROGEN OXIDES, HYDROGEN CHLORIDE GAS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL LAWS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:1,2-ETHANEDOIL;GLYCOL CAGE:62910 CAGE:0BEF1 CAGE:0Z8D6 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE GLYCOL (SARA 313) (CERCLA) CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED ACGIH TLV:C 50 PPM,VAPOR; 9495 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL, RAT LD50:4700MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:DANGER!HARMFUL/FATAL IF INGEST.MAY BE HARMFUL IF INHALED.AFFECTS CENTRAL NERVOUS SYTEM.MAY CAUSE IRRIT.INHAL:RM TEMP SUBSTANCE HAS LOW VAP PRESSURE & VAP INHAL UNLIKELY.HIGH CONCEN SYMPTOMS SIMILAR TO ETHYL ALCOHOL INTOXICATION.INGEST:MASSIVE DOSAGE PARALLETL ALCHOL INTOXICATION,VOMIT,HEAD,RAPID RESP/HEART RATE(SUPPLE) Effects of Overexposure:INHAL:DIZZINESS,HEADACHE,SHORTNESS OF BREATH.PULMONARY EDEMA,CENTRAL NERVOUS SYSTEM DEPRESSION. Medical Cond Aggravated by Exposure:PERSONS W/PRE-EXISTING SKIN DISORDERS,EYE PROBLEMS,OR IMPAIRED LIVER,KIDNEY,OR RESP FUNCTION MAY BE MORE SUSCEPTIBLE TO EFFECTS OF THIS SUBSTANCE. ======================= First Aid Measures ======================= First Aid:INGEST:INDUCE VOMIT IMMED BY GIVING 2 GLASSES OF WATER OR MILK & STICKING FINGER DOWN THROAT.NEVER GIVE ANYTHING BY MOUTH IF UNCONSC.CALL DR IMMED.INHAL:REMOVE TO FRESH AIR.NOT BREATH GIVE ART RESP.BR EATH DIFFI GIVE OXY.CALL PHYSICIAN.SKIN:REMOVE ANY CONTAMIN CLOTH.WASH W/PLENTY OF WATER FOR @LEAST 15MINS.IRRIT DEVELOPS GET MED ATTN.EYE:IMMED FLUSH W/PLENTY OF WATER FOR @LEAST 15MINS.CALL DR. ===================== Fire Fighting Measures ===================== Flash Point:=110.C, 230.F Autoignition Temp:=400.C, 752.F Lower Limits:3.2 Upper Limits:15.3 Extinguishing Media:DRY CHEM,FOAM,CO2.WATERSPRAY MAY BE USED TO EXTINGUISH SURROUNDING FIRE/COOL EXPO CNTNR.WATERSPRAY REDUCE FUME/IRRIT GAS Fire Fighting Procedures:IN EVENT OF FIRE WEAR FULL PROTECTIVE CLOTH & NIOSH-APPROVE SELF-CONTAINED BREATH APPARATUS W/FULL FACEPIECE OPERATED IN PRESSURE DEMAND OR OTHER +PRESS MODE. Unusual Fire/Explosion Hazard:SLIGHT TO MODERATE FIRE HAZ WHEN EXPO TO HEAT/FLAMES.ABOVE FLASH PT VAP-AIR MIXTURES ARE EXPLO W/IN FLAMM LIMITS NOTED ABOVE. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE IGN SOURCES.VENTI AREA OF LEAK/SPILL.CLEANUP PERSONNEL MAY REQUIRE PROTECTIVE CLOTH.DIKE.AVOID RUNOFF INTO STORM SEWERS/DITCHES WHICH LEAD TO NATURAL WATERWAYS.ABSORB LIQ SPILLS W/DRY ABSORB ENT.CONTAINERIZE UNUSABLE MATL FOR DISPOSAL.RQ=1LB Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT BREATHE MIST/FUMES.USE W/ADEQUATE VENTILATION.KEEP IN TIGHTLY CLSD CNTNR,STORED IN COOL DRY VENTILATED AREA.PROTECT AGAINST PHYSICAL DMG. Other Precautions:SEPARATE FROM ACIDS & OXIDIZING MATLS.REFER TO ACGIH DOC "INDUSTRIAL VENTIALTION,A MANUAL OF RECOMMENDED PRACT"MOST RECENT EDITION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV EXCEEDED A FULL FACEPIECE CHEM CARTRIDGE RESP MAY BE WORN IN GENERAL UP TO 100X TLV OR MAX USE CONCEN SPEC BY RESP SUPPLIER WHICHEVER IS LESS.ATERNATIVELY SUPPLIED AIR FULL FACEPIECE RESP OR AI RLINED HOOD MAY BE WORN. Ventilation:SYSTEM OF LOC &/OR GEN EXHAU IS RECOMMENDED TO KEEP EMPLOYEE EXPO BEL AIRBORNE EXPO LIMITS.LOC EXHAU VENTI PREFERRED. Other Protective Equipment:MAINTAIN EYE WASH FOUNTAIN & QUICK-DRENCH FACILITIES IN WORKAREA. Work Hygienic Practices:WASH THOROUGHLY AFT HNDLG.LAUNDER CONTAMIN CLOTH BEF REUSE. Supplemental Safety and Health HEALTH HAZ:LOW BLOOD PRESSURE,STUPOR,COLLAPSE,UNCONSC W/CONVUL.DEATH FROM RESP ARREST/CARDIOVASCULAR COLLAPSE.SKIN:MINOR IRRIT,PENETRATION MAY OCCUR.PROLONG CONTACT CAUSE SOFTENING SKIN.EYE:IRRIT,PAIN ,EYE DMG. ================== Physical/Chemical Properties ================== HCC:V5 NRC/State Lic Num:NOT RELEVANT Boiling Pt:=192.8C, 379.F Melt/Freeze Pt:=-12.6C, 9.F Vapor Pres:0.05 @20C Vapor Density:2.14 Spec Gravity:1.1 Evaporation Rate & Reference:<0.002, REF UNK Solubility in Water:MISCIBLE W/WATER. Appearance and Odor:COLORLESS OILY LIQUID, ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS.REACTS VIOLENTLY W/CHLOROSULFONIC ACID,OLEUM,SULFURIC ACID,PERCHLORIC ACID. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CARBON DIOXIDE AND CARBON MONOXIDE MAY FORM WHEN HEATED TO DECOMPOSITION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF CONTAINER & UNUSED CONTENTS IN ACCORDANCE W/FED/STATE/LOCAL REQUIREMENTS.SARA SEC 313 CHEMICALS:ETHYLENE GLYCOL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:METHYL SULFOXIDE, 99+%, M8180-2 CAGE:60928 CAGE:60928 ============= Composition/Information on Ingredients ============= Ingred Name:ING 3:SULFOXIDE DEGRADES GIVING OFF FORMALDEHYDE, METHYL MERCAPTAN, & SULFUR DIOXIDE. RTECS #:9999999ZZ Ingred Name:METHYL SULFOXIDE; (DMSO) CAS:67-68-5 RTECS #:PV6210000 Fraction by Wt: >99% Ingred Name:SUPP DATA: CHLORIDE, MAGNESIUM PERCHLORATE, SILVER FLUORIDE, METHYL BROMIDE, IODINE PENTAFLUORIDE, NITROGEN (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2:PERIODATE, DIBORANE, SODIUM HYDRIDE, PERCHLORIC & PERIODIC ACIDS. WHEN HEATED ABOVE ITS BP METHYL (ING 4) RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:(ORAL,RAT)14500 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: HARMFUL IF SWALLOWED, INHALED, OR ABSORBED THRU SKIN. VAPOR/MIST IS IRRITATING TO THE EYES, MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. CAUSES SKIN IRRITATION. MAY CAUSE ALLERGIC RESPIRATORYAND SKIN REACTIONS. CHRONIC: TARGET ORGAN(S): EYES; SKIN. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: IMMED FLUSH W/COPIOUS AMTS OF WATER FOR @ LST 15 MIN & SEEK MED ADVICE. SKIN: IMMED FLUSH W/COPIOUS AMTS OF WATER FOR @ LST 15 MIN WHILE REMOVING CONTAMD CLTHG & SHOES. WASH CONTAMD CLTHG BEFORE REUSE. INHAL: REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. INGEST: WASH OUT MOUTH PROVIDED PERSON IS CONSCIOUS. CALL A PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:203F,95C Lower Limits:3.5% Upper Limits:63% Extinguishing Media:WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . PREVENT CONTACT WITH SKIN AND EYES. Unusual Fire/Explosion Hazard:FORMS EXPLOSIVE MIXTURES IN AIR. EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR NIOSH/MSHA APPROVED SCBA, RUBBER BOOTS CLOSED CONTAINERS FOR DISPOSAL. VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT BREATHE VAP. AVOID CONT W/EYES/SKIN/CLTHG. READILY ABSORBED THRU SKIN. IRRITANT. KEEP TIGHTLY CLSD. HYGROSCOPIC. STORE IN A COOL DRY PLACE. Other Precautions:SENSITIZER. HARMFUL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:USE ONLY IN A CHEMICAL FUME HOOD. Other Protective Equipment:USE PROTECTIVE CLOTHING & MASK. SAFETY SHOWER AND EYE BATH. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health MATLS TO AVOID: SULFOXIDE (DMSO) UNDERGOES A VIOLENT EXOTHERMIC RXN ON MIXING W/COPPER WOOL & TRICHLOROACETIC ACID. ON MIXING W/POTASSIUM PERMANGANATE IT WLL FLASH INSTANTANEOUSLY. IT REACTS VIOLENTLY WITH: ACID HALIDES, CYANURIC CHLORIDE,SILICON TETRACHLORIDE, PHOSPHORUS TRICHLORIDE & TRIOXIDE, THIONYL (ING 2) ================== Physical/Chemical Properties ================== HCC:T6 Boiling Pt:B.P. Text:372F,189C Melt/Freeze Pt:M.P/F.P Text:65.1F,18.4C Vapor Pres:0.42@20C Vapor Density:2.7 Spec Gravity:1.101 Appearance and Odor:COLORLESS LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACID CHLORIDES; PHOSPHORUS HALIDES; STRONG ACIDS; STRONG OXIDIZING AGENTS; STRONG REDUCING AGENTS. METHYL (SUPP DATA) Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:TOXIC FUMES OF: CARBON MONOXIDE, CARBON DIOXIDE, SULFUR OXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISSOLVE/MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER. DISPOSE OF I/A/W FEDERAL, STATE AND LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ALK-600 CAGE:55208 CAGE:55208 ============= Composition/Information on Ingredients ============= Ingred Name:MFR STATES NO HAZ.COMPONENTS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Effects of Overexposure:EYE:IRR;SKIN:IRR,BURNS,DEFATTING TO SKIN ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/WTR FOR 15MIN;SKIN:WASH W/SOAP&WATER. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:EXTINGUISH WITH AGENT SUITABLE FOR SURROUNDING FIRE Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:NEUTRALIZE W/WEAK ACETIC ACID SOLUTION.ABSORB,AND PLACE IN DISPOSAL CONTAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONT.TIGHTLY CLOSED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE Other Protective Equipment:AS REQD TO PREVENT PROLONGED CONTACT W/SKIN. Supplemental Safety and Health MSDS DATED 04-02-86/PH AS 1S=12;PH @ 10:1 DILUTION=11/ ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:215F,102C Vapor Pres:20. Vapor Density:1. Spec Gravity:1.0 Evaporation Rate & Reference:1.0 (WATER=1) Solubility in Water:COMPLETE Appearance and Odor:THICK,CLEAR LIQUID,MILD ODOR. Percent Volatiles by Volume:80. ================= Stability and Reactivity Data ================= NONE Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW LOCAL,STATE,FED REGS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GLUTAMIC OXALOACETIC TRANSAMINASE CAGE:GO448 CAGE:GO448 ============= Composition/Information on Ingredients ============= Ingred Name:GLUTAMIC-OXALACETIC TRANSAMINASE CAS:9000-97-9 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY CAUSE SKIN, EYE/RESPIRATORY TRACT IRRITATION UPON CONTACT. ALLERGIC REACTIONS IN CERTAIN SENSITIVE INDIVIDUALS MAY DEVELOP. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, ALLERGIC REACTIONS. Medical Cond Aggravated by Exposure:ALLERGIES, ASTHMA. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. EYES/SKIN: WASH THOROUGHLY W/WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:AVOID PHYSICAL CONTACT & DUST DURING REMOVAL. USE NORMAL CLEAN-UP PROCEDURES & WASH THOROUGHLY W/WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR DUST MASK. Ventilation:LOCAL EXHAUST: AS REQUIRED. MECHANICAL (GENERAL): VENT FAN. Supplemental Safety and Health SOLUBILITY IN WATER: POWDERS-APPRECIABLE. LIQUIDS-MISCIBLE. ================== Physical/Chemical Properties ================== Solubility in Water:(SEE SUPP) Appearance and Odor:POWDERS- WHITE TO TAN. LIQUIDS-WHITE TO BROWN. BOTH HAVE TYPICAL ENZYME ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:FLUSH IN SEWERAGE SYSTEM W/WATER IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:48KH33178DP23 DARK GREEN COIL CAGE:0G0J3 CAGE:0G0J3 ============= Composition/Information on Ingredients ============= Ingred Name:BENZIN, NAPHTHA, MINERAL SPIRITS, PETROLEUM NAPHTHA CAS:8030-30-6 RTECS #:DE3030000 Fraction by Wt: 10% Other REC Limits:STEL 400 PPM OSHA PEL:100 PPM ACGIH TLV:300 PPM Ingred Name:XYLENE, DIMETHYLBENZENE, XYLOL (IARC - GROUP 3) *97-4* CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: >5% Other REC Limits:100 PPM OSHA PEL:100 PPM ACGIH TLV:100 PPM, SKIN EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SEC-BUTANOL ALCOHOL *97-4* CAS:78-92-2 RTECS #:EO1750000 Fraction by Wt: >5% Other REC Limits:100 PPM OSHA PEL:150 PPM ACGIH TLV:303 MG/CUM Ingred Name:V M & P NAPHTHA, LIGROINE, MINERAL SPIRITS *97-4* CAS:8032-32-4 RTECS #:OI6180000 Fraction by Wt: >5% Other REC Limits:STEL 400 PPM ACGIH TLV:300 PPM Ingred Name:ACETONE; DIMETHYL KETONE; 2-PROPANONE *97-4* CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 30% OSHA PEL:2400 MG/CUM ACGIH TLV:750 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:PROPANE (DIMETHYLMETHANE)*97-4* CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 10% Other REC Limits:1800 MG/CUM OSHA PEL:1000 PPM ACGIH TLV:SIMPLE ASPHYXIANT Ingred Name:ISOBUTANE, 2-METHYLPROPANE CAS:75-28-5 RTECS #:TZ4300000 Fraction by Wt: 10% Other REC Limits:1000 PPM OSHA PEL:1800 MG/CUM ACGIH TLV:1000 PPM Ingred Name:TOLUENE (IARC CARC- GROUP 3) *97-4* CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: >5% Other REC Limits:375 MG/CUM OSHA PEL:100 PPM ACGIH TLV:100 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:2-BUTOXYETHANOL (ETHYLENE GLYCOL MONOBUTYL ETHER), BUTYL CELLOSOLVE, BUTYL GLYCOL, GLYCOL ETHER EB *97-4* CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: >5% Other REC Limits:25 PPM (SKIN) OSHA PEL:50 PPM (SKIN) ACGIH TLV:25 PPM (SKIN) Ingred Name:PROPYLENE GLYCOL METHYL ETHER (1-METHOXY-2-PROPANOL) PROPYLENE GLYCOL MONO METHYL ETHER *97-4* CAS:107-98-2 RTECS #:UB7700000 Fraction by Wt: >5% Other REC Limits:100 PPM ACGIH TLV:100 PPM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INGESTION: HARMFUL/FATAL. EYES/SKIN: IRRITATION. INHALATION: ANESTHETIC, WILL IRRITATE THE RESPIRATORY TRACT & MAY CAUSE NERVOUS SYSTEM DEPRESSION. REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS MAY CAUS E PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, DROWSINESS, LIGHTHEADEDNESS, HEADACHE, DIZZINESS, STAGGERING, CONFUSION, UNCONSCIOUSNESS, COMA. ======================= First Aid Measures ======================= First Aid:INGESTION: DON'T INDUCE VOMITING. EYES: FLUSH W/LAARGE AMOUNTS OF WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NECESSARY. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:<0F Lower Limits:2.3 Extinguishing Media:CO2, DRY CHEMICAL/FOAM. Fire Fighting Procedures:WATER SPRAY MAY BE INEFFECTIVE BUT MAY BE USED TO COOL CLOSED CONTAINERS. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. WEAR SCBA. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. DON'T APPLY ON HOT SURFACES. AEROSOL CONTAINERS HOLD EXTREMELY FLAMMABLE GAS & LIQUID UNDER PRESSURE ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE SOURCES OF IGNITION & PROVIDE MAXIMUM VENTILATION. EQUIP PERSONAL W/PROPER RESPIRATORY, SKIN & EYE PROTECTION. TAKE UP MATERIAL W/SAWDUST, VERMICULITE/OTHER ABSORBENT MATERIAL & PLACE IN CONTAI NERS FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS & OPEN FLAMES. Other Precautions:TOXIC GASES MAY FORM WHEN PRODUCT IS CONTACTED BY FLAME/HOT SURFACES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH/MSHA APPROVED (TC-23-C) PAINT SPRAY/(TC-19-C) AIR SUPPLIED RESPIRATOR. Ventilation:GENERAL DILUTION/LOCAL EXHAUST IN VOLUME & PATTERN TO KEEP THE CONCENTRATION OF INGREDIENTS BELOW EXPOSURE LIMITS. Other Protective Equipment:PROTECTIVE CLOTHING, APRON. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:<0F Vapor Pres:<78 Vapor Density:>1 Spec Gravity:0.7-0.8 Evaporation Rate & Reference:(BU O AC = 100): <57 Solubility in Water:21-4% Percent Volatiles by Volume:85-96 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ALKALIES, STRONG MINERAL ACIDS & STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HEAT, SPARKS & OPEN FLAMES. Hazardous Decomposition Products:CO, CO2. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. DON'T INCINERATE CLOSED CONTAINERS. UN1954.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CARBON DIOXIDE CAGE:87286 CAGE:0ZGE6 CAGE:0XMLI CAGE:87286 ============= Composition/Information on Ingredients ============= Ingred Name:CARBON DIOXIDE CAS:124-38-9 RTECS #:FF6400000 Fraction by Wt: 100% OSHA PEL:5000 PPM ACGIH TLV:5000PPM/30000STEL;93 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SIMPLE ASPHYXIANT.HIGH CONCENTRATIONS OF CARBON DIOXIDE IN THE AMBIENT AIR CAN REDUCE THE OXYGEN CONTENT NECESSARY TO SUPPORT LIFE.IN THE SOLID PHASE(DRY ICE) CONTACT W/BODY TISSUE WILL PRODUCE COLD B URNS OR FROSTBITE W/IN SEVERAL SECONDS. Explanation of Carcinogenicity:THIS MATERIAL IS NOT LISTED AS A CARCINOGEN BY NTP, IARC, OSHA. Effects of Overexposure:SHORTNESS OF BREATH,HEADACHE,DIZZINESS, WEAKNESS,DROWSINESS & RINGING IN EARS.DRY ICE IN CONTACT W/BODY TISSUE PRODUCES BURNING SENSATION;& FROSTBITE OCCURS W/IN SEVERAL SECONDS. Medical Cond Aggravated by Exposure:CONDITIONS WHICH CAUSE BREATHING DIFFICULTY. ======================= First Aid Measures ======================= First Aid:DO NOT ATTEMPT TO REMOVE AN INDIVIDUAL FROM THE SCENE W/OUT UTILIZING PROPER RESCUE EQUIPMENT OR YOU MAY BECOME A CASUALTY. MOVE VICTIM TO FRESH AIR WHILE KEEPING THEM WARM, DRY & QUIET. IF BREATHING HAS STOPPED PERFORM ARTIFICIAL RESPIRATION. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:MATERIAL IS AN EXTINGUISHING AGENT ITSELF. Fire Fighting Procedures:NONE SPECIFIED BY MANUFACTURER. Unusual Fire/Explosion Hazard:CONFINEMENT OF CARBON DIOXIDE IN VESSELS CONTAINERS OF IMPROPER DESIGN CAN RESULT IN EXPLOSION OR RUPTURE FROM OVER- PRESSURIZATION. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE THE AREA OF THE SPILL OR RELEASE, EMPLOY EMERGENCY FIRST AID PROCEDURES,PROVIDE PLENTY OF FRESH AIR.REMOV DRY ICE RESIDUAL & ALLOW TO SUBLIME IN A SECURED, WELL-VENTILATED AREA & CONTACT THEMANUFACTURER'S SAFETY DEPARTMENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:LIQUID & VAPOR STORAGE CONTAINERS ARE UNDER HIGH PRESSURE.DO NOT MIS-HANDLE OR ABUSE,CNTS.USE ONLY EQUIPMENT DESIGNED FOR CARBON DIOXIDE. Other Precautions:AVOID DIRECT SKIN CONTACT WITH DRY ICE OR VENTING CARBON DIOXIDE LIQ OR VAPOR.USE PROTECTIVE EQUIP & CLOTHING AND GET PROPER TRAINING BEFORE HANDLING CARBON DIOXIDE IN CYLINDERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SELF-CONTAINED BREATHING APPARATUS - USE IN STRICT ACCORDANCE W/THE MANUFACTURER'S RECOMMENDATIONS. Ventilation:FRESH AIR LOCAL EXHAUST/MECHANICAL Other Protective Equipment:SAFETY SHOES, HARD HATS & EAR PROTECTION SHOULD BE WORN WHEN WORKING W/PRESSURIZED CARBON DIOXIDE. Work Hygienic Practices:PERSONS HANDLING CARBON DIOXIDE SHOULD BE FULLY TRAINED IN ADVANCE. Supplemental Safety and Health USE A PROPER PRESSURE REDUCING REGULATOR WHEN CONNECTING CYLINDER TO LOWER PRESSURE < 1500 PSIG. NEVER HEAT CYLINDER TO INCREASE DISCHARGE RATE. KEEP CYLINDERS UPRIGHT AND PROPERLY SECURED IN SECURED AREAS AWAY FROM HIGH TRAFFIC. HAVE ONLYQUALIFIED PERSONNEL REFILL CYLINDERS. ================== Physical/Chemical Properties ================== HCC:G3 Boiling Pt:B.P. Text:-109F,-79C Vapor Pres:1 ATM Vapor Density:1.5 AIR=1 Solubility in Water:90ML/100ML H2O Appearance and Odor:IN SOLID TRANSLUCENT WHITE & ODORLESS.IN GAS & LIQ COLORLESS & ODORLESS. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACTIVE ALKALI METALS(SUCH AS SODIUM, POTASSIUM, MAGNESIUM, ALUMINUM, TITANIUM, ZIRCONIUM), ORGANOMETALLICS, HYDRIDES. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:HEATING ABOVE 1700C CAUSES DECOMPOSITION OF CARBON MONOXIDE & OXYGEN. Conditions to Avoid Polymerization:IT CAUSES VIOLENT POLYMERIZATION OF ACRYLALDEHYDE OR ETHLENEIMINE. ==================== Disposal Considerations ==================== Waste Disposal Methods:ALLOW CARBON DIOXIDE TO RELEASE, SUBLIME OR DISSIPATE IN THE OPEN AIR.AVOID RELEASING IN COURTYARDS OR INDOORS OR ANY AREAS WHERE HEAVY CARBON DIOXIDE VAPORS CAN ACCUMULATE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:WHITE TRAFFIC MARKER BRADY CAT 91521 CAGE:59581 CAGE:1AA96 CAGE:59581 ============= Composition/Information on Ingredients ============= Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 < Wt:20. OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:XYLENE CAS:1330-20-7 RTECS #:ZE2100000 < Wt:15. ACGIH TLV:434 MG/M3;100 PPM ACGIH STEL:651 MG/M3;150 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TOLUOL CAS:108-88-3 RTECS #:XS5250000 < Wt:15. OSHA PEL:SEE TABLE Z-2 ACGIH TLV:188 MG/M3;50 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 < Wt:15. OSHA PEL:1800 MG/M3;1000 PPM Ingred Name:N-BUTANE CAS:106-97-8 RTECS #:EJ4200000 < Wt:10. ACGIH TLV:1900 MG/M3;800 PPM Ingred Name:ETHYL BENZENE CAS:100-41-4 RTECS #:DA0700000 < Wt:5. OSHA PEL:435 MG/M3;100 PPM ACGIH TLV:434 MG/M3;100 PPM ACGIH STEL:543 MG/M3;125 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ACETONE CAS:67-64-1 RTECS #:AL3150000 < Wt:5. OSHA PEL:2400 MG/M3;1000 PPM ACGIH TLV:1780 MG/M3;750 PPM ACGIH STEL:2380 MG/M3;1000 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:METHANOL CAS:67-56-1 RTECS #:PC1400000 < Wt:5. OSHA PEL:260 MG/M3;200 PPM ACGIH TLV:262 MG/M3;200 PPM ACGIH STEL:328 MG/M3;250 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 > Wt:3. Ingred Name:SOYA ALKYD RESIN > Wt:3. ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:EYES: IRRITATING. SKIN: IRRITATION/ALLERGIC REACTIONS ARE POSSIBLE. PROLONGED/REPEATED CONTACT MAY CAUSE DERMATITIS. INHALATION: CYANOSIS MAY RESULT FROM OVEREXPOSURE. MAY BE HARMFUL. INGESTION: MATER IAL MAY BE HARMFUL/FATAL. IRRITATING TO MOUTH, THROAT & STOMACH. OVEREXPOSURE MAY CAUSE POSSIBLE REPRODUCTIVE HAZARD. Effects of Overexposure:IRRITATION, PAIN, TEARING, REDDENING OF EYES, SWELLING, STINGING SENSATION, DEFATTING & DRYING OF SKIN, RASH, HEADACHE, DIZZINESS, NAUSEA, DECREASED BLOOD PRESSURE, CHANGES IN HEART RATE ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH W/PLENTY OF WATER. SKIN: WASH W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NECESSARY. KEEP VICTIM WARM. INGESTION: DON'T INDUCE VOMITING. GIVE A GLASS OFWATER/MILK. NEVER GIVE ANYTHING BY MOUTH IF UNCONSCIOUS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:=-20.C, -4.F Lower Limits:1 Upper Limits:36 Extinguishing Media:WATER FOG, DRY CHEMICAL, CO2, ALCOHOL FOAM, FOAM Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS PRESSURE-DEMAND MSHA/NIOSH APPROVED & FULL PROTECTIVE GEAR. Unusual Fire/Explosion Hazard:CONTAINERS CAN BUILD UP PRESSURE IF EXPOSED TO HEAT/FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB W/INERT MATERIAL; DRY SAND/EARTH, THEN PLACE IN A CHEMICAL WASTE CONTAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS & FLAME. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE A NIOSH/MSHA APPROVED AIR PURIFYING RESPIRATOR W/AN ORGANIC VAPOR CARTRIDGE/CANISTER WHERE AIRBORNE CONCENTRATIONS EXCEED EXPOSURE LIMITS. USE A POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR FOR UNCON TROLLED RELEASES/WHERE EXPOSURE LEVELS ARE NOT KNOWN/WHERE AIR PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE PROTECTION. Ventilation:LOCAL EXHAUST VENTILATION MAY BE NECESSARY TO CONTROL ANY AIR CONTAMINANTS TO W/IN THEIR TLVS DURING THE USE OF THIS PRODUCT. Other Protective Equipment:CHEMICAL SUIT, RUBBER BOOTS, PROTECTIVE CLOTHING/ACID SUIT Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:-44 TO 284F Vapor Pres:40 Vapor Density:>1 Spec Gravity:0.9013 Evaporation Rate & Reference:FASTER THAN ETHER Solubility in Water:SLIGHT Appearance and Odor:LIQUID W/AROMATIC ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:HEAT, SPARKS, FIRE/FLAME ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. ===================== Regulatory Information ===================== SARA Title III Information:SECTION 313: THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS & REAUTHORIZATION ACT OF 1986 & 40 CFR PART 37 2: TOLUOL, ACETONE, XYLENE, METHANOL, ETHYL BENZENE. Federal Regulatory Information:CERCLA-SARA HAZARD CATEGORY: THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA HAZARD CATEGORIES PROMULGATED UNDER SECTIONS 311 & 312 OF THE SUPERFUND AMENDMENT & REAUTHORIZATIN ACT OF 1986 (SARA TI TLE III) & IS CONSIDERED, UNDER APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES: IMMEDIATE HEALTH HAZARD, CHRONIC HEALTH HAZARD, FIRE HAZARD, PRESSURIZED GAS HAZARD. State Regulatory Information:NEW JERSEY RIGHT TO KNOW THE FOLLOWING MATERIALS ARE NON-HAZARDOUS, BUT ARE AMONG THE TOP FIVE COMPONENTS IN THIS PRODUCT: WATER, CALCIUM CARBONATE. PENNSYLVANIA RIGHT TO KNOW: THE FOLLOWING NON-HAZAR DOUS INGREDIENTS ARE PRESENT IN THE PRODUCT AT GREATER THAN 3%: WATER, CALCIUM CARBONATE, ACRYLIC RESIN. CALIFORNIA PROPOSITION 65: WARNING: THE CHEMICALS NOTED BELOW & CONTAINED IN THIS PRODUCT, ARE KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER/BIRTH DEFECTS & OTHER REPRODUCTIVE HARM: TOLUOL. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BENZOIC ANHYDRIDE CRYSTALLINE, B7756 CAGE:21076 CAGE:21076 ============= Composition/Information on Ingredients ============= Ingred Name:BENZOIC ANHYDRIDE CRYSTALLINE CAS:93-97-0 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY BE HARMFUL BY INHALATION, INGESTION, OR SKIN ABSORPTION. CAUSES EYE AND SKIN IRRITATION. MATERIAL IS IRRITATING TO MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. TO THE BEST OF KNOWLEDGE, THE CHEMI CAL, PHYSICAL, AND TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: IMMED FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MIN. SKIN: WASH WITH SOAP AND COPIOUS AMOUNTS OF WATER. INHAL: REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTF RESP. IF BREATHING IS DIF FICULT, GIVE O*2. CALL PHYS. WASH CONTAMINATED CLOTHING BEFORE REUSE. ===================== Fire Fighting Measures ===================== Flash Point:>230F,>110C Extinguishing Media:WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER ALCOHOL OR POLYMER FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT TO PREVENT CONTACT WITH SKIN AND EYES. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE AREA AND WASH SPILL SITE AFTER MATERIA L PICKUP IS COMPLETE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT BREATHE DUST. AVOID CONT W/EYES/SKIN/CLTHG. IRRITANT. KEEP TIGHTLY CLOSED. MOISTURE SENSITIVE. STORE IN COOL DRY PLACE. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:MECHANICAL EXHAUST REQUIRED. Other Protective Equipment:SAFETY SHOWER AND EYE BATH. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:680F,360C Melt/Freeze Pt:M.P/F.P Text:102F,39C Spec Gravity:1.199 Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. MAY DECOMPOSE ON EXPOSURE TO MOIST AIR/H*2O. STRONG ACIDS, STRONG BASES. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:TOXIC FUMES OF: CARBON MONOXIDE AND CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISSOLVE OR MIX MATERIAL WITH COMBUSTIBLE SOLVENT AND BURN IN CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE, AND LOCAL LAWS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TOOLING STONE - T10 CAGE:57593 CAGE:57593 ============= Composition/Information on Ingredients ============= Ingred Name:GYPSUM OSHA PEL: 15 MG/M3 TDUST, 5 RDUST CAS:13397-24-5 RTECS #:MG2360000 OSHA PEL:SEE ING ACGIH TLV:10 MG/M3 TDUST Ingred Name:CALCIUM CARBONATE; (LIMESTONE) OSHA PEL: 15 MG/M3 TDUST, 5 RDUST CAS:1317-65-3 RTECS #:EV9580000 OSHA PEL:SEE ING ACGIH TLV:10 MG/M3 TDUST ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:THIS MATERIAL IS NOT KNOWN TO BE TOXIC. LARGE AMOUNTS OF DUST MAY CAUSE A NUISANCE CONDITION OF COUGHING, SNEEZING AND NASAL IRRITATION. MATERIAL WILL HARDEN IF WET AND RESULT IN BLOCKAGE IF INGESTED. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:INGEST: CALL MD IMMEDIATELY . INHALATION: REMOVE TO FRESH AIR. EYES: RINSE WITH PLENTY OF RUNNING WATER FOR AT LEAST 15 MINUTES. SKIN: WASH THOROUGHLY. ===================== Fire Fighting Measures ===================== Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . NON- COMBUSTIBLE. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP OR VACUUM MATERIAL INTO A WASTE CONTAINER FOR DISPOSAL. AVOID CREATING DUST. WEAR NIOSH/MSHA APPROVED RESPIRATOR IF REQUIRED. DO NOT FLUSH DOWN DRAINS TO AVOID BLOCKAGE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:EXCESSIVE PARTICULATES IN WORKPLACE AIR MUST BE AVOIDED. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR AS REQUIRED FOR NUISANCE DUST. Ventilation:VENTILATE AT MIXER AS REQUIRED. Other Protective Equipment:NONE REQUIRED. Work Hygienic Practices:GOOD FACTORY HOUSEKEEPING PROCEDURES. Supplemental Safety and Health SPEC GRAV: 0.04-2.7 (H2O=1) ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:SUPDAT Solubility in Water:0-0.2% @ 40C Appearance and Odor:LIGHT PINK POWDER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:NONE Hazardous Decomposition Products:CAO, SO3. ==================== Disposal Considerations ==================== Waste Disposal Methods:MAY BE DISPOSED OF AS INERT SOLID IN A SANITARY LANDFILL OR BY OTHER PROCEDURES IN COMPLIANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:RUST SCAT METAL PRIMER 35-153 Preparer's Name:THOMAS E. MAREK CAGE:33200 CAGE:33200 ============= Composition/Information on Ingredients ============= Ingred Name:STODDARD SOLVENT; (MINERAL SPIRITS). VP:2 CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: 26.9% OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:C I PIGMENT YELLOW 36; (ZINC CHROMATE) CAS:37300-23-5 RTECS #:GE4600000 Fraction by Wt: 22.8% OSHA PEL:0.1 MG(CRO3)/M3 ACGIH TLV:0.01 MG(CR)/M3, A1 Ingred Name:VOLATILE ORGANIC CONTENT:3.14 LBS PER GALLON RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE:EYES:CAN CAUSE SEVERE IRRITATION, REDNESS, TEARING, BLURRED VISION. SKIN:PROLONGED OR REPEATED CONTACT CAN CAUSE MODERATE IRRITATION, DEFATTING, DERMATITIS. INHALATION:EXCESSIVE INHAL OF VAPORS CAN CAUSE NASAL & RESPIRATORY IRRITATION, DIZZINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHE, POSSIBLE (EFTS OF OVEREXP) Explanation of Carcinogenicity:ZINC CHROMATE: IARC GROUP 1, SUP 7, P 165, 1987; KNOWN CARCINOGEN, NTP 7TH ANNUAL REPORT, 1994. Effects of Overexposure:HLTH HAZ:UNCONSCIOUSNESS, AND EVEN ASPHYXIATION. INGESTION:CAN CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING, AND DIARRHEA. CHRONIC:ASPIRATION INTO LUNGS CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:SKIN:THORO WASH EXPOSED AREA W/SOAP & WATER. REMOVE CONTAMD CLTHG. LAUNDER CONTAMD CLTHG BEFORE REUSE. EYES:FLUSH W/LG AMTS OF WATER, LIFTING UPPER & LOWER LIDS OCCASNLY, GET MED ATTN. INGEST:DO NOT I NDUCE VOMIT. KEEP PERSON WARM & GET MEDATTN. INHAL:REMOVE TO FRESH AIR. IF BRTHG IS DFCLT, ADMIN OXYG. IF BRTHG HAS STOPPED, APPLY ARTF RESP. KEEP PERSON WARM, QUIET & GET MED ATTN. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:102F,39C Lower Limits:1.0% Upper Limits:6.0% Extinguishing Media:COMBUSTIBLE LIQUID. USE FOAM, DRY CHEMICAL, CARBON DIOXIDE. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA WITH FULL FACEPIECE OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE WHEN FIGHTING FIRES. Unusual Fire/Explosion Hazard:VAPS ARE HVR/AIR & MAY TRAVEL ALONG GROUND/BE MOVED BY VENT & IGNIT BY HEAT PILOT LIGHTS, OTHER FLAMES & IGNIT SOURCES @ LOCATIONS DIST FROM MATL HNDLG POINT. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB LIQUID ON PAPER, VERMICULITE, FLOOR ABSORBANT OR OTHER ABSORBANT MATERIAL AND PICK UP WITH SHOVEL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID PROLONGED OR REPEATED SKIN CONTACT. KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES. Other Precautions:USE WITH ADEQUATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL EXHAUST AS NEEDED TO REMAIN BELOW PEL Other Protective Equipment:BARRIER CREAM. ANSI APPRVD EMERGENCY EYE WASH & DELUGE SHOWER . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:300F,149C Vapor Pres:SEE ING 1 Vapor Density:HVR/AIR Spec Gravity:1.42 (H*2O=1) Evaporation Rate & Reference:70 (ETHER =1) Solubility in Water:NONE Appearance and Odor:YELLOW OPAQUE LIQUID, MINERAL SPRIRITS ODOR. Percent Volatiles by Volume:50.3 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:EXCESSIVE HEAT, SPARKS, OPEN FLAME. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY YIELD CARBON DIOXIDE AND/OR CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE UNDER SAFE CONDITIONS. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SODIUM BICARBONATE, SX0325 CAGE:63612 CAGE:63612 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM BICARBONATE CAS:144-55-8 RTECS #:VZ0950000 = Wt:100. ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (ORAL,RAT) 4220 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:POTENTIAL HEALTH EFFECTS (ACUTE AND CHRONIC). SYMPTOMS OF EXPOSURE: MAY CAUSE EYE IRRITATION. Explanation of Carcinogenicity:THE MATERIAL IS NOT LISTED (IARC,NTP,OSHA) AS CANCER CAUSING AGENT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE INDICATED. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ASSISTANCE IF ANY ADVERSE EFFECTS SHOULD DEVELOP. SKIN: WASH THOROUGHLY WITH SOAP AND WATER. EYES: IMMEDIATELY FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES. INHALATION: REMOVE TO FR ESH AIR; GIVE ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED. INGESTION: GET IMMEDIATE MEDICAL ATTENTION; OF CONSCIOUS, GIVE WATER FREELY. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Extinguishing Media:WATER. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE INDICATED. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA OF ALL UNNECESSARY PERSONNEL. WEAR SUITABLE PROTECTIVE EQUIPMENT LISTED UNDER EXPOSURE/PERSONAL PROTECTION. ELIMINATE ANY IGNITION SOURCES UNTIL AREA IS DETERMINED TO BE FREE FROM EXPLOS ION OR FIRE HAZARDS. CONTAIN THE RELEASE AND ELIMINATE ITS SOURCE, IF THIS CAN BE DONE WITHOUT RISK. TAKE UP & CONTAINERIZE FOR PROPER DISPOSAL AS DESCRIBED UNDER DISPOSAL. (SUPDAT) ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. STORE AT CONTROLLED ROOM TEMPERATURE. Other Precautions:DO NOT GET IN EYES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:MATL SHOULD BE HNDLD OR TRANSFERRED IN AN APPRVD FUME HOOD OR WITH ADEQUATE VENTILATION. Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DO NOT TAKE INTERNALLY. HNDLG CARE GENRLLY IN KEEPING W/SAFE LAB PRACTICES IS RECOMMENDED. Supplemental Safety and Health SPILL RELEASE: COMPLY WITH FEDERAL, STATE, AND LOCAL REGULATIONS ON REPORTING RELEASES. REFER TO REGULATORY INFO FOR REPORTABLE QTY & OTHER REGULATORY DATA. ================== Physical/Chemical Properties ================== Melt/Freeze Pt:=122.C, 251.6F M.P/F.P Text:DECOMPOSES Spec Gravity:2.16 (H*2O =1) Solubility in Water:SOLUBLE Appearance and Odor:WHITE, ODORLESS, CRYSTALLINE POWDER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS. OTHER: REACTS VIOLENTLY WITH AMMONIUM PHOSPHATE, MONOBASIC. Stability Condition to Avoid:NONE INDICATED. Hazardous Decomposition Products:CO*X. =================== Toxicological Information=================== Toxicological Information:ORL-RAT LD50: 4220 MG/KG. TOXICOLOGICAL FINDINGS: TESTS ON LABORATORY ANIMALS INDICATE MATERIAL MAY PRODUCE ADVERSE MUTAGENIC AND REPRODUCTIVE EFFECTS. CITED IN REGISTY OF TOXIC EFFECTS OF CHEMICAL SU BSTANCES (RTECS). ==================== Disposal Considerations ==================== Waste Disposal Methods:MATERIAL DOES NOT HAVE EPA NUMBER AND IS NOT LISTED WASTE, HOWEVER CONSULTATION WITH A PERMITTED WASTE DISPOSAL SITE (TSD) SHOULD BE ACCOMPLISHED. ALWAYS CONTACT PERMITTED WASTE DISPOSER (TSD) TO ASSU RE COMPLIANCE WITH ALL CURRENT LOCAL, STATE AND FEDERAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:DOT PROPER SHIPPING NAME: NON-REGULATED. DOT ID NUMBER: NONE. ===================== Regulatory Information ===================== SARA Title III Information:TSCA STATEMENT: THE CAS NUMBER OF THIS PROD IS LISTED ON THE TSCA INVENTORY. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:THINNER, 3812-S;(FORMERLY KNOWN AS T-3812) CAGE:DO229 CAGE:18873 CAGE:DO229 ============= Composition/Information on Ingredients ============= Ingred Name:ALIPHATIC PETRLOLEUM DISTILLATE Fraction by Wt: 52.0% ACGIH TLV:100 PPM(PER MFR Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 48.0% OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Effects of Overexposure:CAUSES HEADACHE,NAUSEA,IMPAIRMENT OF REACTION TIME AND COORDINATION. ======================= First Aid Measures ======================= First Aid:INHALATION:MOVE TO FRESH AIR TO IMPROVE BREATHING;SKIN:WASH WITH SOAP & WATER.REMOVE CONTAMINATED CLOTHING;EYES:FLUSH WITH WATER FOR AT LEAST 15 MIN.CALL A PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:20-73F (CC) Lower Limits:1.0 Upper Limits:7.0 Extinguishing Media:CO*2, FOAM, DRY CHEM. Fire Fighting Procedures:COOL CLOSED CONTNRS W/H*2O USING FOG NOZZLES. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE UNPROTECTED PERSONS. ELIM IGNITION SOURCES. STOP LEAK. H*2O SPRAY COOL CONT/DIVERT SPILL FROM FIRE/HEAT. PROVIDE VENTILATION. ABSORB W COMMERCIAL ABSORBENT,SHOVEL INTO METAL DRUMS:LG SPILL:DI KE W COMMERCIAL ABSORBENT,PUMP INTO COVERED DRUMS. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT,SPARKS & OPEN FLAMES.CLOSE CONTAINERS AFTER EACH USE.DO NOT STORE ABOVE 120F Other Precautions:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR SMOKING;OBSERVE LABEL PRECAUTIONS;CONTAINERS SHOULD BE GROUNDED WHEN POURING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA RESP TC-23C IF AIR CONTMNANTS CONTROL IS NOT FEASIBLE Ventilation:LOCAL & MECH PROVIDE SUFFICIENT VENT TO KEEP BELOW TLV LEVEL Other Protective Equipment:USE APPROPRIATE INDUSTRIAL HYGIENE PRACTICES. Supplemental Safety and Health MSDS FM MFR DATED:11/24/82;VAPOR PRESSURE 10.00 & VAPOR DENSITY 3.00 NOTED BY MFR ARE OF PRINCIPAL SOLVENT;PREVIOUSLY ITEM IDENTIFIED AS T-3812;EFF 8/10/82,ITEM(FORMULA UNCHGD) CODE IS 3812-S. ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:B.P. Text:212-302F Vapor Pres:UNK Vapor Density:UNK Spec Gravity:0.795 Evaporation Rate & Reference:<1(SLOWR THAN ETHR Solubility in Water:NEGLIGIBLE Appearance and Odor:LIQUID THINNER W/CHARACTERISTIC ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS, CORROSIVES Stability Condition to Avoid:HEAT, IGNITION SOURCES Hazardous Decomposition Products:CO,CO*2,SMOKE ==================== Disposal Considerations ==================== Waste Disposal Methods:KEEP IN COVERED DRUMS,PENDING DISPOSAL. HANDLE & DISPOSE IN FULL COMPLIANCE WITH ALL APPLICABLE INTERNATIONAL,FEDERAL,STATE, & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:5IP CAGE:GO230 CAGE:GO230 CAGE:84021 ============= Composition/Information on Ingredients ============= Ingred Name:CHROMIUM METAL, CHROMIUM, CHROME (SUSPECTED A1 HUMAN CARCINOGEN BY IARC, NTP & ACGIH) CAS:7440-47-3 RTECS #:GB4200000 OSHA PEL:1 MG/CUM (CEILING) ACGIH TLV:0.5 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:MOLYBDENUM (SOLUBLE COMPOUND), LEAD MOLYBDATE CAS:7439-98-7 RTECS #:QA4680000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3; 9293 Ingred Name:SILICON CAS:7440-21-3 RTECS #:VW0400000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:POTASSIUM SILICATE, POTASSIUM METASILICATE *93-1* CAS:1312-76-1 Ingred Name:SODIUM METASILICATE; SODIUM SILICATE; WATER GLASS; DISODIUM SALT SILIC ACID CAS:6834-92-0 RTECS #:VV9275000 Ingred Name:CALCIUM FLUORIDE, FLUORSPAR, CALCIUM DIFLUORIDE, IRTRAN 3, LIPARITE CAS:7789-75-5 RTECS #:EW1760000 Other REC Limits:2.5 MG/CUM (AS F) OSHA PEL:2.5 MG/CUM (AS F) ACGIH TLV:2.5 MG/CUM (AS F) Ingred Name:CALCIUM CARBONATE, DOMOLITE, LIMESTONE, WHITING CAS:1317-65-3 RTECS #:EV9580000 OSHA PEL:15 MG/CUM (DUST) ACGIH TLV:10 MG/CUM (DUST) Ingred Name:TITANIUM DIOXIDE, TIO2 CAS:13463-67-7 RTECS #:XR2275000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:IRON CAS:7439-89-6 RTECS #:NO4565500 ACGIH TLV:5-10 MG/CUM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:IRRITATION OF NOSE, THROAT, EYES. MAY LEAD TO SIDEROSIS WHICH MAY AFFECT PULMONARY FUNCTION. ARC RAYS CAN INJURE EYES & BURN SKIN. ELECTRIC SHOCK CAN KILL. SEE SUPP. Explanation of Carcinogenicity:SEE INGREDIENTS Effects of Overexposure:INHALATION: DIZZINESS, NAUSEA, IRRITATION OF NOSE & THROAT. EYES: IRRITATION. SKIN: DRYNESS & BURNS. Medical Cond Aggravated by Exposure:RESPIRATORY OR ALLERGIC CONDITIONS. ======================= First Aid Measures ======================= First Aid:EMPLOY FIRST AID TECHNIQUES RECOMMENDED BY THE AMERICAN RED CROSS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Unusual Fire/Explosion Hazard:WELDING ARC & SPARKS CAN IGNITE COMBUSTIBLES. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP HEAD OUT OF FUMES, DON'T TOUCH LIVE ELECTRICAL PARTS, INSULATE FROM WORK & GROUND. Other Precautions:TO DETERMINE COMPOSTION & QUANTITY OF FUMES & GASES TO WHICH WORKERS ARE EXPOSED IS TO TAKE AN AIR SAMPLE INSIDE THE WELDERS HELMET OR IN THE BREATHING ZONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE RESPIRABLE FUME RESPIRATOR OR AIR SUPPLIED RESPIRATORY WHEN WELDING IN CONFINED SPACE OR WHERE LOCAL EXHAUST OR VENTILATION DOES NOT KEEP EXPOSURE BELOW TLV. Ventilation:LOCAL EXHAUST AT THE ARC TO KEEP THE FUMES & GASES BELOW THE TLV. Other Protective Equipment:HELMET, ARM PROTECTORS, APRONS, HATS, SHOULDER PROTECTION, DARK SUBSTANTIAL CLOTHING, SCREENS, FLASH Supplemental Safety and Health THE PRODUCT AS SUPPLIED IS NON-HAZARDOUS. HEALTH HAZARDS OCCUR DURING OPERATIONS. THE COMPOSITION & QUANTITY OF WELDING FUMES ARE DEPENDENT ON THE PROCESS, PROCEDURES, MEDIA, CONTAMINENTS IN THE ATMOS PHERE, & ELECTRODES USED. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES SEE SUPP Stability Condition to Avoid:SEE SUPP Hazardous Decomposition Products:CO, CO2, OZONE & NITROGEN OXIDES FORMED BY THE RADIATION FROM ARC. WELDING FUMES - COMPLEX OXIDES FROM THE INGREDIENTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER OR LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE W/FEDERAL, STATE & LOC AL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:1,4-HYDROXYBENZALDEHYDE, O-246 CAGE:84898 CAGE:84898 CAGE:8Y898 ============= Composition/Information on Ingredients ============= Ingred Name:BENZALDEHYDE, P-HYDROXY-; (1.4-HYDROXYBENZALDEHYDE) CAS:123-08-0 RTECS #:CU6475000 OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CONTACT LENSES SHOULD NOT BE WORN IN LABORATORY. ALL CHEMICALS SHOULD BE CONSIDERED HAZARDOUS-AVOID DIRECT PHYSICAL CONTACT! CAN BE HARMFUL IF INHALED, SWALLOWED AND ABSORBED THROUGH THE SKIN. CAN CAU SE EYE AND SKIN IRRITATION. DUST AND/ORVAPS CAN CAUSE IRRIT TO RESP TRACT. CAN BE IRRIT TO MUCOUS MEMBRANES. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:AN ANTIDOTE IS SUBSTANCE INTENDED TO COUNTERACT EFT OF POIS. IT SHOULD BE ADMIN ONLY BY MD/TRAINED EMER PERS. MED ADVICE CAN BE OBTAINED FROM POIS CTL CTR. SKIN:IF NO BURNS HAVE OCCURRED, USE SOAP & W ATER TO CLEANSE SKIN. DO NOT WEAR SHOESOR CLOTHING UNTIL ABSOLUTELY FREE OF ALL CHEM ODORS. INHAL:REMOVE PATIENT TO FRESH AIR. ADMIN OXYG IF PATIENT IS HAVING DFCLTY BRTHG. IF PATIENT HAS (SUP DAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR WATER SPRAY. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA. WEAR APPROPRIATE OSHA-REGULATED EQUIPMENT. VENTILATE AREA. SWEEP UP AND PLACE IN AN APPROPRIATE CONTAINER. HOLD FOR DISPOSAL. WASH CONTAMINATED SURFACES TO REMOVE ANY RESIDUES. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTACT WITH SKIN, EYES AND CLOTHING. KEEP TIGHTLY CLOSED AND STORE IN A COOL, DRY PLACE. STORE UNDER NITROGEN. STORE ONLY W/COMPATIBLE CHEMS. Other Precautions:PERSONS NOT SPECIFICALLY & PROPERLY TRAINED SHOULD NOT HNDL CHEM/ITS CNTNR. PROD IS FURNISHED FOR LAB USE ONLY! MFR'S PRODS MAY NOT BE USED AS DRUGS, COSMETICS, AGRICULTURAL/PESTICIDAL PRODS, FOOD AD DITIVES/AS HOUSEHOLD CHEMS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . USE APPROPRIATE OSHA/MSMA APPROVED SAFETY EQUIPMENT. Ventilation:THIS CHEMICAL SHOULD BE HANDLED ONLY IN A HOOD. Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE SHOWER . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRST AID PROC:STOPPED BREATHING ADMINISTER ARTIFICIAL RESPIRATION. IF PATIENT IS IN CARDIAC ARREST ADMINISTER CPR. CONTINUE LIFE SUPPORTING MEASURES UNTIL MEDICAL ASSISTANCE HAS ARRIVED. GET MEDICAL ATTENTION IF NECESSARY. CONTINUE LIFE SUPPORTING MEASURES UNTIL MED ASSISTANCE HAS ARRIVED. INGEST:CALL MD IMMED . ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:2129F,1165C Solubility in Water:SLIGHTLY SOLUBLE Appearance and Odor:FRUITY, PERFUME LIKE, OR PLEASANT ODOR. BEIGE CRYSTALLINE SOLID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, STRONG BASES, STRONG REDUCING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:DECOMPOSITION LIBERATES TOXIC FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TT-E-2784A CAGE:NO367 CAGE:NO367 CAGE:3F338 ============= Composition/Information on Ingredients ============= Ingred Name:GLYCOL ETHER (VAPOR PRESSURE 25%) CAS:111-77-3 RTECS #:KL6125000 Fraction by Wt: 7.20% Other REC Limits:NONE RECOMMENDED Ingred Name:GLYCOL ETHER (VAPOR PRESSURE 0.1%) CAS:770-35-4 Fraction by Wt: 1.30% Other REC Limits:NONE RECOMMENDED Ingred Name:VOC = 1.46 G/L, NON-EXEMPT SOLVENT PER ADJUSTED GALLON. RTECS #:9999999VO Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE: IRRITATION. SKIN: IRRITATION. INHAL: IRRITATING TO NOSE/THROAT. INGEST:TOXIC. Effects of Overexposure:INHAL: HEADACHE, NAUSEA, VOMITING, DROWSINESS. Medical Cond Aggravated by Exposure:HEART CONDITIONS, ASTHMA. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH W/WATER FOR 15 MINUTES, GET MED AID. SKIN: WASH W/SOAP & WATER. REMOVE CONTAIM CLOTHES. INHAL: GET FRESH AIR. OXGEN IF NEEDED. INGEST: GIVE TWO GLASSES OF WATER. INDUCE VOMIT. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMBLE Extinguishing Media:CO2, FOAM. Fire Fighting Procedures:USE FULL PROTECTIVE GEAR. Unusual Fire/Explosion Hazard:COOL CONTAINERS W/WATER STEAM IN EVENT OF A FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE & CONTAIN. SOAK UP RESIDUE W/ABSORBENT MATERIAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. PROTECT FROM FREEZING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:REQUIRED. Ventilation:REQUIRED. Other Protective Equipment:APRON. Work Hygienic Practices:WASH AFTER HANDLING. Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,156C Vapor Density:>AIR Evaporation Rate & Reference:VALUE NOT STATED Solubility in Water:100% Percent Volatiles by Volume:58.9 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING MATERIALS. Stability Condition to Avoid:HEAT, SPARKS & OPEN FLAME. Hazardous Decomposition Products:CARBON MONOXIDE & UNIDENTIFIED ORGANIC COMPOUNDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN RECKA APPROVED FACILITY.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DETECT-A-LEAK Preparer's Name:T. MARAHARA CAGE:22159 CAGE:22159 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANOL, 2,2'-IMINODI-; (DIETHANOLAMINE) (SARA III) CAS:111-42-2 RTECS #:KL2975000 Fraction by Wt: 0.3% OSHA PEL:3 PPM ACGIH TLV:3 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY BE IRRITATING TO EYES AND SKIN. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES:WASH WITH WATER FOR AT LEAST 15 MINUTES, CALL PHYSICIAN. SKIN:WASH WITH WATER THOROUGHLY. INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O2/ ARTIFICIAL RESP IRATION) . ===================== Fire Fighting Measures ===================== Extinguishing Media:FOAM, CO2, DRY CHEMICAL, WATER Fire Fighting Procedures:NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB MATERIAL WITH DRY-SORB TYPE ABSORBENT, EARTH OR SAND. MAY BE WASHED DOWN WITH WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTACT WITH SKIN AND EYES. Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL EXHAUST Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:221F,105C Spec Gravity:1.01 (H2O=1) pH:7.8 Solubility in Water:MISCIBLE Appearance and Odor:CLEAR. Percent Volatiles by Volume:NIL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:AMMONIA, CO, CO2, FROM THERMAL DECOMPOSITION ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE OR USE SANITARY LAND FILL. BE SURE THAT ALL FEDERAL, STATE, AND LOCAL REGULATIONS ARE OBSERVED.
1
eyes_protection_mandatory
======================================================= Product ID: CRAFT AND FABRIC PAINT,FL1P1-46 Cage: 21546 Resp. Party Other MSDS No.: MSDS #701 ======================================================= Contractor Summary ======================================================= Cage: 21546 ======================================================= Ingredients ======================================================= ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: NO Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: NONE. NONTOXIC. Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. Medical Cond Aggravated By Exposure: ABRASIVE, CAN SCRATCH EYES. First Aid: EYE CONTACT: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. SKIN CONTACT: WASH WITH SOAP AND WATER. INGESTION: CALL PHYSICIAN IMMEDIATELY (FP N). INHALATION: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE OX YGEN OR ARTIFICIAL RESPIRATION) (FP N). ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: CLEAN UP PROPERLY WITH PAPER TOWELS AND WET SPONGE. Waste Disposal Methods: PUT PAPER TOWELS IN TRASH AND RINSE OUT SPONGE. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS (FP N). Handling And Storage Precautions: KEEP CONTAINER SEALED. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: USE APPROPRIATE TECHNIQUES AND MEDIA FOR SURROUNDING FIRE. Fire Fighting Procedures: NONE. WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: MATERIAL CAN SPATTER ABOVE 212F. POLYMER FILM CAN BURN. ======================================================= Control Measures ======================================================= Respiratory Protection: IF SPRAYING, DO NOT INHALE MIST. USE RESPIRATOR THAT IS NIOSH APPROVED FOR SPRAYS AND MISTS. Ventilation: LOCAL EXHAUST: RECOMMENDED. MECHANICAL (GENERAL): RECOMMENDED WHEN SPRAYING. SPECIAL: USE RESPIRATOR WHEN SPRAYING. OTHER: NONE. Other Protective Equipment: NONE NEEDED. ANSI APPROVED EMERGENCY EYEWASH AND DELUGE SHOWER (FP N). Work Hygienic Practices: GOOD HYGIENE PRACTICES SHOULD BE FOLLOWED. ======================================================= Physical/Chemical Properties ======================================================= Boiling Point: =100.C, 212.F Vapor Pres: (MM HG) NOT APPLICABLE Vapor Density: (AIR=1)N/A Spec Gravity: 1.1 (WATER =1) PH: 7.0-9.0 Solubility in Water: INSOLUBLE Appearance and Odor: OPAQUE-COLORED LATEX PAINT. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: WILL NOT OCCUR. ======================================================= Toxicological Information ======================================================= Toxicological Information: CONFORMS TO NONTOXIC ASTMD-4236: PRODUCTS BEARING THE NONTOXIC PRODUCT SEAL ARE CERTIFIED IN A PROGRAM OF TOXICOLOGICAL EVALUATION BY A NATIONALLY RECOGNIZED TOXICOLOGIST TO CONTAIN NO MATERIALS IN SU FFICIENT QUANTITIES TO BE TOXIC OR INJURIOUS TO HUMANS OR TO CAUSE ACUTE OR CHRONIC HEALTH PROBLEMS. THESE PRODUCTS ARE CERTIFIED TO BE LABELED IN ACCORDANCE WITH THE VOLUNTARY CHRONIC HAZARD LABELING STANDARD ASTMD-436. IN ADDITION THERE IS NO PHYSICAL HAZARD AS DEFINED WITHIN 29 CFR PART 1910.1200(C). ======================================================= Ecological Information ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= Other Information: CODES: HEALTH: 0, FIRE: 0, REACTIVITY: 0, PROTECTIVE EQUIPMENT: G (IF SPRAYING). ======================================================= HAZCOM Label ======================================================= Product ID: CRAFT AND FABRIC PAINT,FL1P1-46 Cage: 21546 Company Name: DUNCAN ENTERPRISES Street: 5673 E SHIELDS AVE Zipcode: 93727 Label Required IND: Y Date Of Label Review: 11/03/1999 Status Code: A Origination Code: F Skin Protection IND: YES Signal Word: NONE Respiratory Protection IND: YES Health Hazard: None Contact Hazard: None Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE: NONE. NONTOXIC. CHRONIC: NONE SPECIFIED BY MANUFACTURER (FP N). =======================================================
1
eyes_protection_mandatory
======================================================= Product ID: ACCU-LUBE TB (IN THE TUB) Cage: ITWFL Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 0WD64 Cage: ITWFL ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: NO Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE: NO EFFECTS EXPECTED. HOWEVER, LIKE ANY INDUSTRIAL CHEMICAL PRODUCT, EXERCISE CARE TO AVOID EXCESSIVE EXPOSURE TO PRODUCT. CHRONIC: NONE SPECIFIED BY MANUFACTURER. Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: EYES: FLUSH WITH POTABLE WATER FOR AT LEAST 15 MINUTES. SEE MD (FP N). SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER. SEE MD (FP N). INHALATION: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE OXYGEN OR ARTI FICIAL RESPIRATION) (FP N). INGESTION: CALL MD IMMEDIATELY (FP N). ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: NO SPECIAL PROTECTIVE EQUIPMENT IS REQUIRED FOR CLEANUP PERSONNEL. STOP SPILL AT SOURCE AND DIKE AREA TO PREVENT SPREADING. PUMP LIQUID TO SALVAGE TANK. ABSORB REMAINING LIQUID ON ABSORBENT MATERIAL A ND SHOVEL INTO A SUITABLE CONTAINER. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: INCINERATION IS THE RECOMMENDED DISP METH FOR ALL NON-HAZ CHEM WASTE, ALTHOUGH MATL MAY BE LANDFILLED I/A/W ALL APPLICABLE LOCAL, STATE, AND FEDERAL REGULATIONS. THIS PRODUCT, IF DISPOSED OF, IS NOT C ONSIDERED HAZ WASTE UNDER CURRENT FEDERAL REGS. Handling And Storage Precautions: NONE SPECIFIED BY MANUFACTURER. Other Precautions: NONE SPECIFIED BY MANUFACTURER. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: PMCC Flash Point Text: >200F,>93C Extinguishing Media: WATER FOG, REGULAR FOAM. Fire Fighting Procedures: WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP (FP N). WATER/FOAM MAY CAUSE FROTHING WHICH CAN BE VIOLENT, ESPECIALLY IF SPRAYED INTO CONTRS OF HOT BURNING LIQ. Unusual Fire/Explosion Hazard: NONE. ======================================================= Control Measures ======================================================= Respiratory Protection: USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N). Ventilation: NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment: NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health: NONE SPECIFIED BY MANUFACTURER. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: >425F,>218C Vapor Pres: <1 @ 68F Vapor Density: HVR/AIR Spec Gravity: 0.85 @ 68F PH: 6-7 Solubility in Water: INSOLUBLE Appearance and Odor: LIGHT BLUE SOLID PUSH-UP Percent Volatiles by Volume: <1/10 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER. Materials To Avoid: STRONG OXIDIZING AGENTS WILL CAUSE A VIGOROUS REACTION. Hazardous Decomposition Products: NONE SPECIFIED BY MANUFACTURER. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: ACCU-LUBE TB (IN THE TUB) Cage: ITWFL Company Name: ITW FLUID PRODUCTS GROUP Street: 8501 DELPORT DRIVE Zipcode: 63114 Label Required IND: Y Date Of Label Review: 06/07/1995 Status Code: C Label Date: 06/07/1995 Origination Code: G Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: YES Health Hazard: None Contact Hazard: None Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: COMBUSTIBLE. ACUTE: NO EFFECTS EXPECTED. HOWEVER, LIKE ANY INDUSTRIAL CHEMICAL PRODUCT, EXERCISE CARE TO AVOID EXCESSIVE EXPOSURE TO PRODUCT. CHRONIC: NONE SPECIFIED BY MANUFACTURER. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DELTA HARDENER A4 CAGE:92218 CAGE:05820 CAGE:92218 ============= Composition/Information on Ingredients ============= Ingred Name:ALKLENEAMINE Fraction by Wt: >99% ===================== Hazards Identification ===================== Effects of Overexposure:EYE/SKIN CONTACT:IRRITATION. HEATED VAPORS: IRRITATION OF NOSE,THROAT AND EYES. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH WITH WATER 15 MIN, CALL A MD. SKIN:WASH WITH SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. INGESTION: DO NOT INDUCE VOMITING, GIVE MILK TO DRINK. SEE MD. ===================== Fire Fighting Measures ===================== Flash Point:335F/168C Extinguishing Media:FOAM,CO*2,DRY CHEM OF WATER SPRAY Fire Fighting Procedures:TREAT AS A CLASS B FIRE Unusual Fire/Explosion Hazard:AVOID EXCESSIVE HEAT,SPARKS OR OPEN FLAMES. ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN ALL SPILLS THOROUGHLY. FOR SMALL AMOUNTS,MEK OR ACETONE CAN BE USED. FOR LARGE SPILLS, SCRAPE UP,THEN WASH. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID HEAT & OPEN FLAMES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESP DEVICE IN ACCOR WITH EXPOSURE OF CONCERN. Ventilation:LOCAL EXHAUST Other Protective Equipment:APRON IMPERVIOUS TO SOLVENTS Supplemental Safety and Health PART B OF A TWO PART KIT. VAPOR PRESSURE <0.001 MM/HG ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:435F/223C Vapor Density:7.6 Spec Gravity:1.01 Evaporation Rate & Reference:<0.001 (BUAC) Solubility in Water:COMPLETE Appearance and Odor:WATER WHITE LIQUID. MILD AMINE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES UNCONTROLLED MIXING WITH EPOXY AND STRONG ACIDS. Hazardous Decomposition Products:CARBON MONOXIDE,ALDEHYDES,ACIDS,AND NITROGEN COMPOUNDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT LOCAL CODES
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:KD 2 BLITZ CAGE:KXEST CAGE:KXEST ============= Composition/Information on Ingredients ============= Ingred Name:SILICATE, PORTLAND CEMENT; (PORTLAND CEMENT) CAS:65997-15-1 RTECS #:VV8770000 OSHA PEL:50 MPPCF ACGIH TLV:10 MG/M3 TDUST ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:IRRITATION TO EYES OR SKIN WHEN WORKING WITH POWDER IN MIXED (MORTAR) STATE. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:UNKNOWN. ======================= First Aid Measures ======================= First Aid:EYES:IMMEDIATELY FLUSH W/POTABLE WATER FOR A MINIMUM OF 15 MINUTES, SEEK ASSISTANCE FROM MD . INHALATION:CALL MD. SKIN:WASH WITH WATER. INGESTION:CALL MD. ===================== Fire Fighting Measures ===================== Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . MATERIAL DOES NOT BURN. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . ================== Accidental Release Measures ================== Spill Release Procedures:NORMAL CLEAN-UP. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN USED IN DRY CONDITION (POWDER) USE NIOSH APPROVED RESPIRATOR. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . AS REQUIRED WHEN WORKING W/DRY CEMENT. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Spec Gravity:3.1 (H*2O=1) Solubility in Water:NOT SOLUBLE Appearance and Odor:GRAY POWDER; NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:NORMAL DISPOSAL. OBSERVE CURRENT FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TT-E-2784 Preparer's Name:ONEY FLEMING CAGE:EO326 CAGE:EO326 CAGE:39934 ============= Composition/Information on Ingredients ============= Ingred Name:EKTASOLVE EEH SOLVENT CAS:1559-35-9 RTECS #:KK9625000 Fraction by Wt: 3.32% Other REC Limits:NONE RECOMMENDED Ingred Name:BENZYL ALCOHOL CAS:100-51-6 RTECS #:DN3150000 Fraction by Wt: 3.32% Other REC Limits:NONE RECOMMENDED Ingred Name:DIMETHYLAMINOETHANOL LOW VOE CAS:108-01-0 RTECS #:KK6125000 Fraction by Wt: 0.38% Other REC Limits:NONE RECOMMENDED Ingred Name:NON-HAZARDOUS INGREDIENTS Fraction by Wt: 92.98% Other REC Limits:NONE RECOMMENDED Ingred Name:VOC: 1.8 LB/GL; 211 G/LTR RTECS #:9999999VO Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CAN CAUSE IRRITATION OF RESPIRATORY PASSAGES. Effects of Overexposure:INHALATION OF VAPOR OR MIST CAN CAUSE HEADACHES, NAUSEA, IRRITATION OF NOSE, THROAT, AND LUNGS. EYE CONTACT CAN CAUSE SLIGHT IRRITATION. PROLONGED OR REPEATED SKIN CONTACT CAN CAUSE SLIGHT IRRITATION. Medical Cond Aggravated by Exposure:PRE-EXISTING LUNG DISEASE MAY BE AGGRAVATED BY EXPOSURE. ======================= First Aid Measures ======================= First Aid:EYE CONTACT: FLUSH WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES, CONSULT PHYSICIAN IF IRRITATION PERSISTS. SKIN CONTACT: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER. INGESTION: IF SWALLOWED, GIVE 2 GLASSES OF WATER TO DRINK, CONSULT PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:>212F,>100C Autoignition Temp:Autoignition Temp Text:216 F Lower Limits:NONE Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS (PRESSURE DEMAND MSHA/NIOSH APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR. Unusual Fire/Explosion Hazard:MATERIAL CAN SPLATTER ABOVE 100C. POLYMER FILM CAN BURN. ================== Accidental Release Measures ================== Spill Release Procedures:KEEP SPECTATORS AWAY. FLOOR MAY BE SLIPPERY, USE CARE TO AVOID FALLING. CONTAIN SPILLS WITH INERT MATERIALS (SAND, EARTH). TRANSFER LIQUIDS AND SOLID DIKING MATERIAL TO SEPARATE SUITABLE CONTAINERS FO R RECOVERY/DISPOSAL. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP FROM FREEZING. Other Precautions:DO NOT TAKE INTERNALLY. KEEP AWAY FROM CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:APPROVED MECHANICAL FILTER RESPIRATOR TO REMOVE SOLID AIRBORNE PARTICLES OF OVER SPRAY DURING SPRAY APPLICATION. Ventilation:NORMAL, SUCH AS A FAN Other Protective Equipment:EYE WASH STATION. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212 TO 644F Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C Decomp Temp:Decomp Text:350F,177C Vapor Pres:NONE Vapor Density:> AIR Spec Gravity:1.01 (WATER=1) pH:9 MAX Viscosity:77-95 KU Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:SLIGHT Appearance and Odor:CREAM LIQUID WITH SLIGHT ODOR Percent Volatiles by Volume:60.6 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES THERE ARE NO KNOWN MATERIALS WHICH ARE INCOMPATIBLE WITH THIS PRODUCT. Stability Condition to Avoid:NONE Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY YIELD ACRYLIC MONOMERS. ==================== Disposal Considerations ==================== Waste Disposal Methods:KEEP SPILLS AND CLEANING RUN-OFF OUT OF MUNICIPAL SEWERS AND OPEN BODIES OF WATER. CONSULT FEDERAL, STATE, OR LOCAL AUTHORITIES FOR PROPER DISPOSAL PROCEDURES CONCERNING HEALTH AND ENVIRONMENT.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:METAL CLEANER CAGE:88952 CAGE:88952 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANOL, 2-BUTOXY-; (2-BUTOXYETHANOL) CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: 10% OSHA PEL:50 PPM, S ACGIH TLV:25 PPM, S Ingred Name:PHOSPHORIC ACID CAS:7664-38-2 RTECS #:TB6300000 Fraction by Wt: 30% OSHA PEL:1 MG/M3;3 STEL ACGIH TLV:1 MG/M3;3 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:WATER; (DISTILLED) CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 60% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:IN CONFINED AREAS VAPORS IN HIGH CONCENTRATIONS ARE ANESTHETIC. OVEREXPOSURE MAY RESULT IN LT-HD AND STAGGERING GAIT. IRRITANT TO SKIN, EYES, AND UPPER RESPIRATORY SYSTEM. MIST CAN CAUSE COUGHING, SNE EZING, SALIVATION, AND DFCLT BRTHG. ANIMAL STUDIES HAVE CLEARLY DEMONSTRATED DOSE-RELATED ADVERSE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:EFTS ON CNS, HEMATOPOIETIC TISSUE, BLOOD, KIDNEYS, AND LIVER ASSOC W/ADMIN OF ETHYLENE GLYCOL MONOBUTYL ETHER (EGBE). (EXTRACTED FROM DHHS (NIOSH) PUBLICATION NO. 90-118) . Medical Cond Aggravated by Exposure:MISTS MAY AGGRAVATE PULMONARY DISEASE. LONG TERM SKIN EXPOSURE MAY AGGRAVATE DERMATOSIS. ======================= First Aid Measures ======================= First Aid:SKIN: WASH AFFECTED AREA THORO W/SOAP AND WATER. REMOVE CONTAMD CLTHG AND LAUNDER BEFORE RE-USE. IF IRRITATION PERSISTS, SEEK MED AID. INHAL: REMOVE FROM EXPOSURE AND INTO FRESH AIR. RESTORE BRTHG, IF STOPPED. KEEP WARM AND QUIET. EYES: FLUSH EYE AND UNDER LID W/COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SEEK MED AID. INGEST: CALL MD IMMED . ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:>200F,>93C Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:MAY REACT W/SOME METALS INCLUDING ALUMINUM, MAGNESIUM, AND ZINC RESULTING IN EVOLUTION OF HYDROGEN GAS. ================== Accidental Release Measures ================== Spill Release Procedures:VENT AREA. ABSORB W/ABSORBENT MATERIAL. FLUSH SPILL AREA WITH COPIOUS AMOUNTS OF WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE BELOW 80F(27C). KEEP CONTRS TIGHTLY SEALED. AVOID STORING OR MIXING W/MATERIALS CONTAINING CHLORINE. Other Precautions:AVOID EYE AND SKIN CONTACT. AVOID BREATHING MIST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED SCBA FOR EMERGENCY USE. Ventilation:LOCAL EXHAUST/MECHANICAL(GEN): KEEP BELOW TLV. Other Protective Equipment:RUBBER APRON OR SUITABLE PROTECTIVE CLOTHING. SFTY SHOWER AND EYE WASH STATION AVAILABLE. Work Hygienic Practices:WASH THOROUGHLY AFTER USING. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>212F,>100C Vapor Density:>1 Spec Gravity:1.2(H*2O=1) Evaporation Rate & Reference:<1(BUTYL ACETATE=1) Solubility in Water:COMPLETE Appearance and Odor:AMBER LIQUID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALINE MATERIALS AND MATERIALS CONTAINING CHLORINE. Hazardous Decomposition Products:OXIDES OF PHOSPHORUS, CARBON. ==================== Disposal Considerations ==================== Waste Disposal Methods:NEUTRALIZE SOLID WASTE W/DILUTE ALKALINE MATL & INCINERATE IN APPRVD FACILITY. DISPOSE OF I/A/W LOCAL, STATE, AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HYDROCHLORIC ACID,REAGENT Preparer's Name:DGSC-SHH/HMIS(LEVIEN) CAGE:KO196 CAGE:13873 CAGE:KO196 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROGEN CHLORIDE (HYDROCHLORIC ACID) (SARA III) CAS:7647-01-0 RTECS #:MW4025000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED OSHA PEL:C 5 PPM ACGIH TLV:C 5 PPM; 9394 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:TLV(CEILING) IS 5PPM Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:BURNS ALL EXPOSED TISSUE.INHAL:CAUSES IRRITATION.MAY CAUSE LUNG DAMAGE.INGEST:SEVERE BURNS TO MOUTH,ESOPHAGUS,STOMACH.SKIN:CAUSES BURNS.EYES:CAUSES BURNS. Explanation of Carcinogenicity:THERE ARE NO INGREDIENTS ABOVE 0.1% WHICH ARE IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA. Effects of Overexposure:INHAL:TOOTH EROSION,BURNS,CHOKING.INGEST:PAIN,NAUSEA,VOMITING. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING RESPIRATORY AILMENTS MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH WATER.EYES:FLUSH WITH WATER FOR 15 MINUTES.INHAL:REMOVE TO FRESH AIR.GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED.INGEST:DO NOT INDUCE VOMITING.GET PROMP T QUALIFIED MEDICAL ATTENTION.IF CONSCIOUS,GIVE 1-2 GLASSES OF WATER. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER. Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT.COOL FIRE EXPOSED CONTAINERS WITH WATER FOG. Unusual Fire/Explosion Hazard:CONTACT WITH FLUORINE(HALON!) MAY CAUSE IGNTION ON CONTACT.FIRE CONDITION MAY EVOLVE TOXIC/CORROSIVE FUMES. ================== Accidental Release Measures ================== Spill Release Procedures:COVER WITH SODIUM BICARBONATE OR ,SODA ASH/SLAKED LIME(50:50);MIX;ADD WATER TO FORM A SLURRY;SCOOP SLURRY INTO AN APPROPRIATE CONTAINER FOR DISPOSAL.WASH SPILL SITE WITH SODA ASH SOLUTION. Neutralizing Agent:SODIUM BICARBONATE OR SODA ASH/SLAKED LIME(50:50). ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,DRY,WELL-VENTILATED PLACE.KEEP CONTAINER CLOSED WHEN NOT IN USE.KEEP SEPERATE FROM ACIDS AND ALKALIES. Other Precautions:AVOID CONTACT.DO NOT BREATHE VAPOR.WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE ENVIRONMENTAL CONTROLS ARE LACKING OR IN ENCLOSED SPACES USE EITHER A SELF-CONTAINED BREATHING APPARATUS OR NIOSH/MSHA RESPIRATOR FOR ACID VAPORS. Ventilation:USE IN A FUME HOOD ONLY. Other Protective Equipment:FUME HOOD,LAB COAT.PROVIDE A LOCAL EYE WASH STATION AND QUICK DRENCH SHOWER. Work Hygienic Practices:USE REASONABLE CARE IN HANDLING THIS PRODUCT.WASH HANDS AFTER USE AND BEFORE EATING. Supplemental Safety and Health MSDS GENERATED FOR USE WITH DOD 4160.21-H(PAGE IV-37).MSDS SOURCE:MSDS/FTSS(CCINFO;93-3). ================== Physical/Chemical Properties ================== HCC:C1 Vapor Pres:5320 Vapor Density:1.63 Spec Gravity:1.194 pH:0.1@1N Solubility in Water:MISCIBLE Appearance and Odor:LIQUID,FUMING;COLORLESS;PUNGENT Corrosion Rate:CORROSIV ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES METALS,ACIDS,ALKALIES,PROPLYENE OXIDE,ETHYLENE DIAMINE,METAL ACETYLIDES OR CARBIDES,FLUORINE. Stability Condition to Avoid:WATER,STEAM. Hazardous Decomposition Products:HYDROGEN,CORROSIVE/TOXIC FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GARD ANTI-RUST SAE 15W-40 Preparer's Name:RAYMOND SWAN CAGE:3K676 CAGE:3K676 ============= Composition/Information on Ingredients ============= Ingred Name:HEAVY PARAFFINIC DISTILLATE, SOLVENT EXTRACT CAS:64742-04-7 RTECS #:PY8042500 Other REC Limits:5 MG/M3 OIL MIST Ingred Name:ADDITIVE PACKAGE CONTAINING ZINC, SULFUR, CA, PHOSPHORUS AND NITROGEN. Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT) IS > 5000 MG/KG Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Health Hazards Acute and Chronic:ACUTE-EYES/SKIN:MILDLY IRRITATING TO EYES. PROLONGED OR REPEATED CONTACT WITH SKIN MAY CAUSE MILD IRRITATION AND POSSIBLY DERMATITIS. INHALATION OF MIST MAY CAUSE CHEMICAL PNEUMONITIS. INGESTION:LOW T OXICITY. HAS LAXATIVE EFFECT. CHRONIC-NONE GIVEN. Explanation of Carcinogenicity:NONE SPECIFIED BY MANUFACTURER. Effects of Overexposure:EYES & SKIN:MILD IRRITATION. INHALATION:MAY CAUSE PNEUMONITIS.INGESTION:LAXATIVE. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE TO FRESH AIR.GIVE CPR/OXYGEN IF NEEDED. GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES. GET MEDICAL ATTENTION. SKIN:REMOVE & LAUNDER CONTAMINATED CLOTHING. W ASH SKIN WITH SOAP & WATER. DISCARD SATURATED LEATHER ARTICLES. INGESTION:DO NOT INDUCE VOMITING. SEEK MEDICAL HELP. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:380F,193C Autoignition Temp:Autoignition Temp Text:>250C Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL.DO NOT POINT WATER STREAM DIRECTLY INTO BURNING OIL. Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:USE OF WATER STREAM OR FOAM MAY CAUSE FROTHING AND SPREAD FLAME. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN SPILL. ABSORB WITH INERT ABSORBENT SUCH AS CLAY OR SAND, COMMERCIAL SORBENTS OR RECOVER USING PUMPS. SCOOP UP USED ABSORBENT INTO DRUMS. Neutralizing Agent:NOT APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,WELL VENTILATED AREA. AVOID INHALATION & SKIN CONTACT ESPECIALLY WHEN HANDLING USED OIL. Other Precautions:WASH HANDS BEFORE EATING OR DRINKING. DO NOT REUSE OIL DRUMS, AS THEY RETAIN SOME OIL. DO NOT CUT OR WELD USED OIL DRUMS , THEY MAY EXPLODE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NORMALLY NOT NECESSARY. IF MIST GENERATED BY HEATING, SPRAYING, WEAR APPROVED ORGANIC VAPOR RESPIRATOR SUITABLE FOR OIL MIST. Ventilation:MECHANICAL VENTILATION Other Protective Equipment:EYE WASH STATION. LONG SLEEVE CLOTHING TO MINIMIZE SKIN CONTACT. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:V6 Vapor Pres:<0.0001 Vapor Density:>12 Spec Gravity:0.87 Evaporation Rate & Reference:X1000 SLOWER THAN BU AC Solubility in Water:NIL Appearance and Odor:AMBER VISCOUS LIQUID WITH HYDROCARBON ODOR Percent Volatiles by Volume:NIL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS (PEROXIDES, CHLORINE), STRONG ACIDS Stability Condition to Avoid:EXCESSIVE HEAT, OPEN FLAMES. Hazardous Decomposition Products:OXIDES OF CARBON, NITROGEN, PHOSPHORUS AND SMOKE ON COMBUSTION ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN AN APPROVED LANDFILL SITE OR A LICENSED WASTE RECLAMATION FACILITY. DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CARPET CLEANER (BONBET), 408 CAGE:BETCC CAGE:BETCC ============= Composition/Information on Ingredients ============= Ingred Name:OPTIC BRIGHTENERS; (OPTICAL BRIGHTENERS) Fraction by Wt: 0-5% Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: <100% Ingred Name:ETHANOL, 2-BUTOXY-; (2-BUTOXYETHANOL) CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: 10-15% OSHA PEL:25 PPM, S ACGIH TLV:25 PPM, S Ingred Name:SULFURIC ACID, MONODODECYL ESTER, SODIUM SALT; (DODECYL SULFATE, SODIUM SALT) CAS:151-21-3 RTECS #:WT1050000 Fraction by Wt: 5-10% Ingred Name:TRIPHOSPHORIC ACID, PENTASODIUM SALT; (SODIUM TRIPOLYPHOSPHATE) (SARA III) CAS:7758-29-4 RTECS #:YK4570000 Fraction by Wt: 0-5% EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHANOL, 2,2',2"-NITRILOTRI-; (TRIETHANOLAMINE) CAS:102-71-6 RTECS #:KL9275000 Fraction by Wt: 0-5% ACGIH TLV:0.05 PPM Ingred Name:CYCLOHEXENE, 1-METHYL-4-(1-METHYLETHENYL)-,(R)-; (CITRUS TERPENES) CAS:5989-27-5 RTECS #:GW6360000 Fraction by Wt: 0-5% Ingred Name:GLYCOLS, POLYETHYLENE, MONO (P-NONYLPHENYL) ETHER; (NONIONIC SURFACTANT) CAS:26027-38-3 RTECS #:MD0906000 Fraction by Wt: 0-5% Ingred Name:PERFUME OILS Fraction by Wt: 0-5% Ingred Name:DYE Fraction by Wt: 0-5% ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN: IRRITANT. MAY CAUSE REDDENING, SWELLING & POSSIBLE SKIN DAMAGE. EYES:IRRITANT. LIQUID & MISTS MAY DAMAGE EYES, CAUSING CORNEAL INJURY. INHAL:VAPOR MAY BE IRRITATING TO MUCOUS MEMBRANES IN NOSE, THROAT & LUNGS. HIGH CONC MAY CAUSE HEADACHE & NAUSEA. INGEST:MAY CAUSE HEADACHE, DIZZINESS, NAUSEA,(EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:& DIARRHEA. ANIMAL STUDIES HAVE CLEARLY DEMONSTRATED DOSE-RELATED ADVERSE EFFECTS ON THE CNS, HEMATOPOIETIC TISSUE, BLOOD, KIDNEYS & LIVER ASSOCIATED W/ADMINISTRATION OF ETHYLENE GLYCOL MONOB UTYL ETHER (EGBE). (EXTRACTED FROM DHHS(NIOSH) PUBLICATION NO. 90-118) . Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN:FLUSH W/LARGE QUANTITIES OF WATER. SEEK MEDICAL ATTENTION IF IRRITATION PERSISTS. EYES:FLUSH W/LARGE QUANTITIES OF WATER FOR AT LEAST 15 MINS. SEEK MEDICAL ATTENTION IF IRRITATION PERSISTS. INHAL :GET TO FRESH AIR. SEEK MEDICAL ATTENTION IF SYMPTOMS PERSIST. INGEST:DILUTE W/TWO GLASSES OF WATER. SEEK MEDICAL ATTENTION IMMEDIATELY. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE CONDITIONS . Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NOT APPLICABLE. ================== Accidental Release Measures ================== Spill Release Procedures:MOP UP OR OTHERWISE ABSORB & HOLD FOR DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED DURING STORAGE. FOR INSTITUTIONAL & INDUSTRIAL USE ONLY. USE WITH ADEQUATE VENTILATION. Other Precautions:KEEP OUT OF REACH OF CHILDREN. FOR USE BY TRAINED PERSONNEL ONLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:PROVIDE LOCAL EXHAUST TO KEEP TLV OF INGREDIENTS IN INGREDIENT SECTION BELOW ACCEPTABLE LIMIT. Other Protective Equipment:NOT APPLICABLE. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health PH:8.5-9.5 ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:20 @ 68F Vapor Density:>1 Spec Gravity:1.02 pH:SUPDAT Evaporation Rate & Reference:<1 (WATER=1) Solubility in Water:100% Appearance and Odor:THIN BLUE LIQUID W/PLEASANT ODOR. Percent Volatiles by Volume:>85 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CARBON MONOXIDE & OXIDES OF SULFUR POSSIBLE IF BURNED. ==================== Disposal Considerations ==================== Waste Disposal Methods:ANY METHOD IN ACCORDANCE W/APPLICABLE LAWS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ATOM ARC 7018 0.187 50 LB CAGE:84021 CAGE:84021 ============= Composition/Information on Ingredients ============= Ingred Name:IRON CAS:7439-89-6 RTECS #:NO4565500 Other REC Limits:5MG/M*3 OSHA PEL:10MG/M*3 ACGIH TLV:5MG/M*3 Ingred Name:SILICON CAS:7440-21-3 RTECS #:VW0400000 Other REC Limits:10MG/M*3 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:SODIUM SILICATE CAS:6834-92-0 RTECS #:VV9275000 OSHA PEL:5MG/M*3 (RESP. DUST) ACGIH TLV:0.1MG/M*3(RESP.DUST) Ingred Name:CALCIUM CARBONATE (MARBLE) (LIMESTONE) CAS:1317-65-3 RTECS #:EV9580000 Other REC Limits:10MG/M*3 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9192 Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Other REC Limits:10MG/M*3 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:MANGANESE (SARA III) CAS:7439-96-5 RTECS #:OO9275000 Other REC Limits:5MG/M*3 (C) OSHA PEL:(C) 5 MG/M3 DUST ACGIH TLV:5 MG/M3 DUST 9293 Ingred Name:POTASSIUM SILICATE CAS:1312-76-1 OSHA PEL:5MG/M*3 (RESP.DUST) ACGIH TLV:0.1MG/M*3(RESP.DUST) Ingred Name:CALCIUM FLUORIDE CAS:7789-75-5 RTECS #:EW1760000 Other REC Limits:2.5MG/M*3 OSHA PEL:2.5 MG/M3 (F) ACGIH TLV:2.5 MG/M3 (F); 8990 Ingred Name:POTASSIUM FELDSPAR CAS:7789-75-5 Other REC Limits:10MG/M*3(NUISANCE) OSHA PEL:NOT LISTED ACGIH TLV:NOT LISTED Ingred Name:ZIRCON (ZIRCONIUM IV,SILICATE) CAS:14940-68-2 RTECS #:ZH9000000 Other REC Limits:5MG/M*3 OSHA PEL:5 MG/M3/10 STEL (ZR) ACGIH TLV:5 MG/M3/10 STEL (ZR) ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Health Hazards Acute and Chronic:ACUTE:METALLIC TASTE,NAUSEA,TIGHTNESS OF CHEST,FEVER,DIZZINESS,DRYNESS,IRRITATION OF EYES,NOSE,THROAT. CHRONIC:EXCESSIVE LEVELS MAY CAUSE BRONCHIAL ASTHMA,LUNG FIBROSIS,SIDEROSIS. ARC RAYS CAN INJURY EYES & BURN SKIN. ELECTRIC SHOCK CAN KILL. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:AGGRAVATION OF EXISTING RESPIRATORY OR ALLERGIC CONDITIONS. HIGHER LEVEL OF LUNG RELATED PROBLEMS AMONG SMOKERS. ======================= First Aid Measures ======================= First Aid:REMOVE FROM EXPOSURE & OBTAIN PROMPT MEDICAL ATTENTION. IF NOT BREATHING,GIVE CPR. IF UNCONSCIOUS,GIVE OXYGEN. EMPLOY FIRE AID TECHNIQUES RECOMMENDED BY AMERICAN RED CROSS. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:APPROPRIATE FOR SURROUNDING FIRE. Unusual Fire/Explosion Hazard:WELDING ARCS & SPARKS CAN IGNITE COMBUSTIBLE PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP ANY GRINDING DUST OR WASTE RESIDUE & PLACE IN APPROPRIATE DISPOSAL CONTAINER. ======================Handling and Storage ====================== Other Precautions:TRAIN WELDER TO KEEP HIS HEAD OUT OF THE FUMES. MONITOR AIR TO ENSURE ACCEPTABLE EXPOSURES. AVOID ELECTRICAL SHOCK BY MAINTAINING DRY WORK AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FUME RESPIRATOR OR AIR SUPPLIED RESPIRATOR IN CONFINED SPACES OR WHERE VENTILATION DOES NOT KEEP EXPOSURE BELOW TLV. Ventilation:LOCAL EXHAUST Other Protective Equipment:SUBSTANTIAL DARK CLOTH,ARM PROTECTOR,APRON,HAT,SHOULDER PROTECTION. Work Hygienic Practices:WASH AFTER HANDLING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Appearance and Odor:WELDING RODS 0.187 INCHES DIAMETER BY 14 INCHES LONG. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:FUMES OF METALS & METAL OXIDES,CO,CO*2,NO*2,O*3,FLUORIDES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW FEDERAL,STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PLY-MASTIC EPOXY COATING(044 LINE), 044054(III)PART A Kit Part:Y CAGE:85519 CAGE:85519 ============= Composition/Information on Ingredients ============= Ingred Name:EPOXY RESIN CAS:25085-99-8 Fraction by Wt: 31-60% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SILICA, CRYSTALLINE - QUARTZ CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: 1-10% OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 RDUST;9495 Ingred Name:MICA - SILICATES (< 1% CRYSTALLINE SILICA) CAS:12001-26-2 RTECS #:VV8760000 Fraction by Wt: 31-60% OSHA PEL:20 MPPCF; Z-3 ACGIH TLV:3 MG/M3 RDUST; 9495 Ingred Name:ALUMINUM (SARA 313) CAS:7429-90-5 RTECS #:BD0330000 Fraction by Wt: 1-10% OSHA PEL:15 MG/M3 DUST ACGIH TLV:10 MG/M3 DUST; 9495 Ingred Name:STODDARD SOLVENT; (PETROLEUM DISTILLATE). VP: 2.0 @ 25C. LEL: 1.0% CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: 1-10% OSHA PEL:500 PPM ACGIH TLV:100 PPM; 9495 Ingred Name:ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER; (1-METHOXY 2-PROPANOL ACETATE). VP: 3.8 @ 25C. CAS:108-65-6 RTECS #:AI8925000 Fraction by Wt: 1-10% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:INHAL:IRRIT OF RESP TRACT. PRLNG INHAL MAY LEAD TO FATIGUE, DROW, DIZZ &/OR LT HEAD, HDCH, LACK OF COORDINATION, NAUS, VOMIT, CNS DEPRESS, ANESTHETIC EFT/NARCOSIS. SKIN:IRRIT OF SKIN. PRLNG/RPTD CONT CAN CAUSE DERM, DEFATTING. EYE:IRRIT OFEYES. PRLNG/RPTD CONT CAN CAUSE BLURRED VISION, REDNESS (EFTS OF OVEREXP) Explanation of Carcinogenicity:SILICA:IARC MONOGRAPHS, SUPP. VOL 7, PG 341, 1987: GROUP 2A. NTP 7TH ANNUAL RPT ON CARCIN, 1994: ANTIC TO BE CARCIN. Effects of Overexposure:HLTH HAZ:OF EYES, TEARING OF EYES, SEV EYE IRRIT. INGEST:AMTS INGEST INCIDENTAL TO CONSUMER & INDUS HNDLG ARE NOT LIKELY TO CAUSE INJURY; HOWEVER, INGEST OF LRG AMTS MAY CAUSE LUNG INFLAMM & DMG DUE T O ASPIR OF MATRL INTO LUNGS. NOTICE:RPTS HAVE ASSOC RPTD & PRLNG OCCUP OVER-EXPOS TO SOLV W/PERM BRAIN & NERV (SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED BRTHG. HAVE TRAINED PERSON GIVE OXYGEN IF NEC. GET EMER MED ATTN. SKIN:WASH OFF QUICKLY W/PLENTY OF H*2O, THEN SOAP & H*2O; REMOVE CONTAMD CLTHG. WASH CONTAMD CLTHG BEFORE REUSE. EYE:FLUSH IMMED W/LRG AMTS OF H*2O, ESP UNDER LIDS, FOR AT LEAST 15 MIN. OBTAIN EMER MED TREATMENT. INGESTION:IF SWALLOWED, OBTAIN MEDICAL TREATMENT IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:>105F,>41C Lower Limits:SEE INGS Extinguishing Media:DRY CHEMICAL OR FOAM. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . WATER MAY BE USED TO COOL AND PROTECT EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:CLSD CNTNRS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT/FIRE. VAP CAN FORM EXPLO MIX IN AIR AT ELEVATED TEMPS. MAY DECOMP UNDER FIRE CNDTNS EMITTING IRRIT (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION (FLAME, HOT SURFACES, AND ELECTRICAL, STATIC SPARKS). VENTILATE AREA AND AVOID BREATHING VAPORS. CONTAIN AND REMOVE WITH INERT ABSORBENT MATERIAL USING NON-SPARKING TOOL S. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE IN SUN OR ABOVE 100 DEGREE F. Other Precautions:DO NOT TAKE INTERNALLY. DO NOT WELD/FLAME CUT W/OUT PROPER VENT TO INSURE AREA IS FREE OF FLAMM VAP. DO NOT CUT, PUNTURE/WELD ON/NEAR CNTNR. ENTRANCE INTO CLSD STOR TANKS-USE APPROP RESP/AIRLINE FOR P OSS EXPOS TO SOLV/CHEM FUMES. (SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:CONTROL ENVIRONMENTAL CONCENTRATIONS BELOW APPLICABLE STANDARDS. APPROVED CHEMICAL MECHANICAL FILTER RESPIRATOR DESIGNED TO REMOVE A COMBINATION OF PARTICULATE AND VAPORS (NIOSH/MSHA TC23C OR EQUIVALE NT). Ventilation:ALL APPLICATION AREAS SHOULD BE VENT IN ACCORDANCE W/OSHA REGULATION 29 CFR 1910 DURING USE & UNTIL AREA IS FREE OF VAP. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EXPLO HAZ:&/TOX GASES. EFTS OF OVEREXP:SYS DMG. INTENTIONAL MISUSE BY DELIB CONC & INHALING CONTENTS MAY BE HARMFUL/FATAL. OTHER PREC:RAGS/WASTE-CNTNG OIL BASED PAINT/VARNISH THAT PRESENT LRG AIR-TO-O IL INTERFACE WILL OXIDIZE & MAY IGNITE SPONTANEOUSLY & SHOULD BE PLACED IN METAL CNTNR. KEEP OUT OF REACH OF CHILDREN. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>230F,>110C Vapor Pres:SEE INGS Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:0-14 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS, ACIDS, BASES, AMINES. Stability Condition to Avoid:ELEVATED TEMPERATURES. CONTACT WITH OXIDIZING AGENTS. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HYDRAULIC OILS AW 46 ULTRA GUARD CAGE:FO923 CAGE:FO923 CAGE:0B1N6 ============= Composition/Information on Ingredients ============= Ingred Name:NONHAZARDOUS INGREDIENTS ACGIH TLV:5MG/M3 OIL MIST(MFR) ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:(ORAL,RAT)>5000 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYE: MAY CAUSE IRRITATION. BASED ON DATA FROM OTHER COMPONENTS. SKIN: LUBRICATING OILS ARE GENERALLY CONSIDERED NO MORE THAN MILDLY IRRITATING TO SKIN. PROLONGED AND REPEATED CONTACT MAY LEAD T O VARIOUS SKIN DISORDERS, SUCH AS DERMATITIS, OIL ACNE OR FOLLICULITIS. CHRONIC: SIGNS & SYMPS OF (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: CHRONIC EXPOSURE RESEMBLE THOSE OF ACUTE EXPOSURE. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN: WASH WITH SOAP AND WATER. EYE: FLUSH WITH WATER OR EYEWASH FOR AT LEAST 15 MINUTES. SEE PHYSICIAN IF IRRITATION PERSISTS. INHAL: REMOVE TO FRESH AIR. INGEST: DO NOT INDUCE VOMIT. IN GENERAL, NO TREATMENT IS NECESSARY UNLESS LARGE QTYOF PRODUCT ARE INGESTED. HOWEVER, GET MEDICAL ADVICE. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:>390F,>199C Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, FOAM, HALON, WATER FOG PATTERN. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:NONE SPECIFIED BY MANUFACTURER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM HIGH HEAT AND OPEN FLAME. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health SPEC GRAV: RANGE 0.8762-0.878(H*2O=1). ================== Physical/Chemical Properties ================== Spec Gravity:SUPP DATA Solubility in Water:NEGLIGIBLE Appearance and Odor:LIGHT AMBER COLOR-LUBE OIL ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:AVOID HEAT, OPEN FLAME & OXIDIZING MATERIALS. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL SHOULD BE IN COMPLIANCE WITH FEDERAL, STATE AND LOCAL LAWS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:IMRON S/S-LAB, 5080U CAGE:0ERJ7 CAGE:0ERJ7 CAGE:18873 ============= Composition/Information on Ingredients ============= Ingred Name:ACRYLIC POLYMER VP: NONE CAS:25068-63-7 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TOLUENE (SARA 313) (CERCLA) VP: 36.70 @ 20C CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 2% OSHA PEL:200 PPM ACGIH TLV:50 PPM, S EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ACETIC ACID, ETHYL ESTER; (ETHYL ACETATE) (CERCLA) VP: 76.00 @ 20C CAS:141-78-6 RTECS #:AH5425000 OSHA PEL:400 PPM ACGIH TLV:400 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER; (PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE) VP: 3.70 @ 20C CAS:108-65-6 RTECS #:AI8925000 OSHA PEL:N/K ACGIH TLV:N/K CAS:13463-67-7 RTECS #:XR2275000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:LEAD CHROMATE (VI) OXIDE, VP: NONE CAS:18454-12-1 RTECS #:OF9800000 Fraction by Wt: 2% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:MOLYBDATE ORANGE; (LEAD CHROMATE MOLYBDATE) VP: NONE CAS:12656-85-8 RTECS #:QA4660000 Fraction by Wt: 22% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUP DAT: TITANIUM DIOXIDE: IN A LIFETIME INHAL TEST, LUNG CANCERS WERE FOUND IN SOME RATS EXPOSED TO 250 MG/M3 (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: RESP TITANIUM DUST. ANALYSIS OF TITANIUM DIOXIDE CONCS IN RAT'S LUNGS SHOWED THAT THE LUNG CLEARANCE (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: MECHANISM WAS OVERWHELMED & THAT THE RSLTS AT THE MASSIVE 250 MG/M3 LEVEL ARE NOT RELEVANT TO THE (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: WORKPLACE. LEAD CHROMATE/LEAD CHROMATE MOLYBDATE: OVEREXP TO LEAD MAY CAUSE ADVERSE EFTS TO BLOOD (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: FORMING, NERV, URINARY, REPRO SYS INCL EMBRYOTOX EFTS. SYMPS MAY INCL LOSS OF APPETITE, ANEMIA, DISTURB (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13: OF SLEEP & FATG. LEAD & TOLUENE APPEAR ON THE NAVY OCCUP CHEM REPRO HAZ LIST. SEEK CONSULT FROM APPROP (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14: HEALTH PROFESSIONALS CONCERNING LATEST HAZARD LIST INFORMATION & SAFE HANDLING & EXPOSURE INFORMATION . RTECS #:9999999ZZ Ingred Name:EXPLAN OF CARCIN: MOLYBDATE ORANGE: IARC MONOGRAPHS, VOLUME 49, PAGE 49, 1990: GROUP 1. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHAL: MAY CAUSE NOSE & THROAT IRRIT, NERV SYS DEPRESS W/HDCH, DIZZ, NAUS, STAG GAIT, CONFUSION, UNCON. RPTS HAVE ASSOC RPTD & PRLNG OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS DMG. MAY CAUSE IRRI T/BURNING OF EYES. RPTD/PRLNG LIQ CONT MAY CAUSE SKIN IRRIT W/DISCOMFORT & DERM. TOLUENE: RECURRENT (EFTS OF OVEREXP) Explanation of Carcinogenicity:LEAD CHROMATE: IARC MONO, VOL 49, PG 49, 1990: GROUP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994: KNOWN TO BE CARCIN.(ING 16) Effects of Overexposure:HLTH HAZ: OVEREXP MAY RSLT IN LIVER & KIDNEY INJURY. HIGH AIRBORNE LEVELS HAVE PRDCED IRREG HEART BEATS IN ANIMALS & OCCAS PALPITATIONS IN HUMANS. RATS EXPOSED TO VERY HIGH AIRBORNE LEVELS HAVE EXHIBI TED HIGH FREQUENCY HEARING DEFICITS. THE SIGNIFICANCE OF THIS TO MAN IN UNKNOWN. ETHYL ACETATE: PRLNG & RPTD (SUP DAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP, PREF MOUTH-TO-MOUTH. IF BRTHG DFCLTY PERSISTS/OCCURS LATER, CONSULT MD. EYE: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN. CALL MD. SKIN: WASH W/SOAP & WATER. IF IRRIT OCCURS, CONT MD. INGEST: GI DISTRESS. IN THE UNLIKELY EVENT OF INGEST, CALL IMMED & HAVE NAMES OF INGS AVAIL. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:>20F,>-7C Lower Limits:1.3% Upper Limits:13.1% Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . WATER FROM FOG NOZZLES MAY BE USED TO PREVENT PRESSURE BUILD-UP. Unusual Fire/Explosion Hazard:WHEN HEATED > FLASH POINT, EMITS FLAMMABLE VAPS WHICH, WHEN MIXED W/AIR, CAN BURN/BE EXPLO. FINE MIST/SPRAYS MAY BE FLAMMABLE AT TEMPERATURES < FLASH POINT. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. REMOVE SOURCES OF IGNITION. PREVENT SKIN CONTACT AND BREATHING OF VAPOR. CONFINE AND REMOVE WITH INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:OBSERVE LABEL PRECAUTIONS. KEEP AWAY FROM HEAT, SPARKS AND FLAME. CLOSE CONTAINER AFTER EACH USE. GROUND CONTAINERS WHEN POURING. Other Precautions:DO NOT STORE ABOVE 120F. DO NOT SAND, FLAME CUT, BRAZE OR WELD DRY COATING WITHOUT A NIOSH APPROVED RESPIRATOR OR APPROPRIATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:DO NOT BREATHE VAPS/MISTS. WEAR PROPERLY FITTED VAP/PARTICULATE RESP APPROVED BY NIOSH (TC-23C) FOR USE W/PAINTS DURING APPLICATION & UNTIL ALL VAPORS & SPRAY MISTS ARE EXHAUSTED. FOLLOW RESP MANUFACT URER'S DIRECTIONS FOR RESPIRATOR USE. Ventilation:PROVIDE SUFFICIENT VENT IN VOL & PATTERN TO KEEP CONTAMINANTS BELOW APPLIC OSHA REQS & OTHER SUGGESTED EXPOSURE LIMITS. Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . COVERALLS RECOMMENDED. Work Hygienic Practices:WASH THORO AFTER HANDLING & BEFORE EATING/SMOKING. DO NOT USE PROT CREAMS FOR PROT; MAY BE USED FOR EASE OF CLEAN UP. Supplemental Safety and Health EFTS OF OVEREXP: HIGH EXPOS OF LAB ANIMALS RSLTD IN SECONDARY ANEMIA W/INCR IN WHITE BLOOD CELLS; FATTY DEGENERATION, CLOUDY SWELL & EXCESS OF BLOOD IN VARIOUS ORGANS. PROPYLENE GLYCOL MONOMETHYL ETHE R ACETATE: MAY CAUSE MOD EYE BURNING. RECURRENT OVEREXP MAY RSLT IN LIVER & KIDNEY INJURY. (ING 9) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>169F,>76C Vapor Pres:SEE INGS Vapor Density:HVR/AIR VOC Grams/Liter:5. Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:SYSTEM IN WATER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER Percent Volatiles by Volume:62.5 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE REASONABLY FORESEEABLE. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, SMOKE, OXIDES OF HEAVY METALS REPORTED IN INGREDIENTS SECTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT ALLOW MATERIAL TO CONTAMINATE GROUND WATER SYSTEMS. INCINERATE ABSORBED MATERIAL IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REQUIREMENTS. DO NOT INCINERATE IN CLOSED CONTAINERS. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FLEXON, 3459 Preparer's Name:MARCIA CAGE:3Y342 CAGE:3Y648 CAGE:3Y342 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL SPIRITS CAS:64475-85-0 RTECS #:PY8240000 OSHA PEL:400 PPM ACGIH TLV:400 PPM Ingred Name:LITHIUM GREASE OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:MINERAL OIL, WHITE CAS:8042-47-5 RTECS #:PY8047000 OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3 Ingred Name:SOLVENT NAPHTHA (PETROLEUM) MEDIUM ALIPHATIC CAS:64742-88-7 OSHA PEL:100 PPM ACGIH TLV:100 PPM Ingred Name:PROPELLANT; (PROPELLANT-8HYDROCARBON) OSHA PEL:1000 PPM ACGIH TLV:1000 PPM ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL: HIGH CONCENTRATIONS MAY CAUSE DIZZINESS, DROWSINESS AND THROAT IRRITATION. SKIN: PROLONGED CONTACT MAY IRRITATE/DERMATITIS. INGEST: MAY CAUSE BRONCHOPNEUMONIA OR PULMONARY EDEMA. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:DIZZINESS, DROWSINESS AND THROAT IRRITATION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL: FRESH AIR. IF BREATHING STOPS, PERFORM CPR. CALL MD. EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. IF IRRITATION PERSISTS GET MD ATTENTION. SKIN: WASH WITH SOAP AND WATER. INGEST: DO NOT INDU CE VOMITING. CALL MD. ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:40.0F,4.4C Extinguishing Media:FOAM, DRY CHEMICAL, CO*2. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT. Unusual Fire/Explosion Hazard:AT ELEVATED TEMPERATURES (ABOVE 120F) CONTAINERS MAY RUPTURE, VENT, OR BURST. ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP BY MOPPING OR ABSORBENT MATERIAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE AT TEMPERATURES ABOVE 120F. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:UNDER NORMAL CONDITIONS, NO RESPIRATORY PROTECTION IS REQUIRED. USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN. Ventilation:IF GENERAL VENTILATION IS ADEQUATE, USE LOCAL EXHAUST. Other Protective Equipment:LONG SLEEVES SHOULD BE WORN. EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA. Work Hygienic Practices:STANDARD INDUSTRIAL PRACTICES. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:300F,149C Vapor Pres:55 Spec Gravity:0.769 Solubility in Water:NEGLIGIBLE Appearance and Odor:DARK GREEN LIQUID, CHARACTERISTIC ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:TEMPERATURES ABOVE 120F. Hazardous Decomposition Products:CO, CO*2. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT LOCAL, STATE AND FEDERAL DISPOSAL AUTHORITIES FOR APPROVED PROCEDURES.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FILTROL CLAY PRODUCTS-GRADE 25 CAGE:KO991 CAGE:KO991 CAGE:9B095 ============= Composition/Information on Ingredients ============= Ingred Name:SILICON DIOXIDE,CAS # 7631-86-9,TLV AS TOTAL DUST. RTECS #:VV7320000 Fraction by Wt: 69% ACGIH TLV:30 MG/CUM Ingred Name:ALPHA-ALUMINA (ALUMINUM OXIDE) (EPA LISTS ONLY FIBROUS FORMS) (SARA III) CAS:1344-28-1 RTECS #:BD1200000 Fraction by Wt: 20% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:IRON OXIDE CAS:1309-37-1 RTECS #:NO7400000 Fraction by Wt: 1.75% OSHA PEL:10 MG/M3 (FE) ACGIH TLV:5 MG/M3(FE),B2; 9293 Ingred Name:CALCIUM OXIDE,CAS# 1305-78-8 RTECS #:EN3100000 Fraction by Wt: 3.5% ACGIH TLV:2 MG/CUM Ingred Name:MAGNESIUM OXIDE CAS:1309-48-4 RTECS #:OM3850000 Fraction by Wt: 6.0% OSHA PEL:15 MG/M3 PARTICULATE ACGIH TLV:10 MG/M3;TDUST; 9293 ===================== Hazards Identification ===================== Effects of Overexposure:MAY CAUSE IRRITATION TO RESPIRATORY SYSTEM. ======================= First Aid Measures ======================= First Aid:SKIN:WASH WITH SOAP AND WATER. EYES: FLUSH WITH WATER. INHALED: REMOVE TO FRESH AIR. REMOVE CONTAMINATED CLOTHING. ===================== Fire Fighting Measures ===================== Extinguishing Media:EXTINQUISH W. AGENT SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR SELF-CNTND BRTHG APP Unusual Fire/Explosion Hazard:NONE NOTED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:STOP FLOW OR LEAK.AVOID INHALATION.USE RESPIRATORY PROTECTION.VACUUM UP. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID MATERIAL HANDLING METHODS THAT CREATE DUST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH OR MSHA APPROVED RESPIRATOR FOR PARTICULATES. Ventilation:LOCAL EXHAUST TO CONTROL DUSTY CONDITIONS. Supplemental Safety and Health MELT POINT:1100C.PRODUCT MEETS REQUIREMENTS FOR TYPE I UNDER MIL-D-3464.INGREDIENT INFORMATION PER MFR(KEITH DULANEY.) MAY 29,1984. ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:0.78 Evaporation Rate & Reference:0 Solubility in Water:NEGLIGIBLE Appearance and Odor:CREAM COLORED POWDER-ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:SM & LG SPILL:DEPOSIT IN A POSTED TOXIC SUBSTANCE LANDFILL IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:LC15170 HYDROCHLORIC ACID SOL 1-50% V/V 0.01-6.25N CAGE:0MX47 CAGE:0MX47 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: BALANCE Ingred Name:HYDROGEN CHLORIDE CAS:7647-01-0 RTECS #:MW4025000 Minumum % Wt:1. Maxumum % Wt:50. OSHA PEL:C7 MG/M3;C5 PPM ACGIH STEL:C7.5 MG/M3;C5 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): >90 ML/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:EYES: VAPORS ARE IRRITATING, LIQUID CONTACT MAY RESULT IN CLOUDING OF THE CORNEA, EROSION, CORNEAL OPACIFICATION & LOSS OF THE EYE. SKIN: SEVERE BURNS & ULCERATION. INGESTION: SEVERE DIGESTIVE TRACT B URNS & POSSIBLE DEATH. MAY CAUSE EROSION & PERMANENT TISSUE DESTRUCTION OF THE ESOPHAGUS & DIGESTIVE TRACT. INHALATION: RESPIRATORY TRACT IRRITATION, BURNING IN THE NOSE & THROAT, PULMONARY EDEMA. DEL AYED LUNG EDEMA. PALPITATION, INFLAMMATION, EDEMA OF THE LARYNX & BRONCHI, CHEMICAL PNEUMONITIS & PULMONARY EDEMA. OVEREXPOSURE MAY RESULT IN DENTAL EROSION, JAW NECROSIS, RESPIRATORY DISEASE, DERMATI TIS, CONJUNCTIVITIS, CORNEAL SCARRING. Effects of Overexposure:IRRITATION, CLOUDING OF THE CORNEA, BURNS, BROWN-YELLOW SKIN, SCARRING OF SKIN, ABDOMINAL PAIN, VOMITING, COUGHING, WHEEZING, SHORTNESS OF BREATH, SORE THROAT, INFLAMMATION, FEVER ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH W/PLENTY OF WATER FOR 15 MINS. LIFTING THE UPPER & LOWER LIDS. SKIN: FLUSH W/PLENTY OF SOAP & WATER FOR 15 MINS. INGESTION: DON'T INDUCE VOMITING. IF CONSCIOUS, GIVE 2-4 CUPFUL S OF MILK/WATER. NEVER GIVE ANYTHING BY MOUTH IF UNCONSCIOUS. INHALATION: MOVE TO FRESH AIR IMMEDIATELY. GIVE CPR/OXGEN IF NECESSARY. OBTAIN MEDICAL ATTENTION IN ALL CASES. NOTES TO PHYSICIAN: TREAT S YMPTOMATICALLY & SUPPORTIVELY. ===================== Fire Fighting Measures ===================== Extinguishing Media:SMALL: DRY CHEMICAL, CO2, WATER SPRAY/ALCOHOL-RESISTANT FOAM. LARGE: WATER SPRAY, FOG/ALCOHOL-RESISTANT FOAM Fire Fighting Procedures:WEAR A SELF CONTAINED BREATHING APPARATUS IN PRESSURE-DEMAND, MSHA/NIOSH APPROVED & FULL PROTECTIVE GEAR. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB W/ABSORBENT; VERMICULITE, SAND, FULLERS EARTH & PLACE IN PLASTIC BAGS FOR LATER DISPOSAL. LARGE: NEUTRALIZE W/DILUTE ALKALINE SOLUTIONS OF SODA ASH/LIME. CLEAN UP IMMEDIATELY, OBSERVING PRECAUT IONS IN THE PROTECTIVE EQUIPMENT SECTION. ======================Handling and Storage ====================== Handling and Storage Precautions:USE ONLY IN A WELL VENTILATED AREA. STORE IN A COOL, DRY AREA. STORE IN A TIGHTLY CLOSED CONTAINER. Other Precautions:DON'T GET IN EYES, ON SKIN/ON CLOTHING. DON'T INGEST/INHALE. DON'T ALLOW CONTACT W/WATER. USE CAUTION WHEN OPENING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ALWAYS USE A NIOSH-APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:GENERAL/LOCAL EXHAUST TO KEEP AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS. Other Protective Equipment:PROTECTIVE CLOTHING Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health WASH HANDS BEFORE EATING. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212-227F Melt/Freeze Pt:=0.C, 32.F Vapor Pres:14 Vapor Density:0.7 Spec Gravity:1-1.2 pH:<0 Evaporation Rate & Reference:(ETHER=1): >1 Appearance and Odor:COLORLESS LIQUID W/PUNGENT ODOR AT HIGH CONCENTRATIONS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDANTS, ACIDS, ALCOHOLS, GLYCOLS, BUTYL ALCOHOL, ETHANOL, METHANOL, ETHYLENEGLYCOL, ALDEHYDES, FORMALDEHYDES, CAUSTICS, AMMONIA, AMIDES, AMINES, ETHERS, CYANIDES, ESTERS, BUTYL ACETATE, HYDROXIDES, FLUORIDES, H Stability Condition to Avoid:HIGH TEMPERATURES Hazardous Decomposition Products:HYDROGEN CHLORIDE, HYDROGEN GAS ===================== Ecological Information ===================== Ecological:SUBSTANCE WILL NEUTRALIZE SOIL CARBONATE-BASED COMPONENTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:SHIPPING NAME: HYDROCHLORIC ACID SOLUTION. UN1789. PACKING GROUP II. ===================== Regulatory Information ===================== SARA Title III Information:CERCLA/SARA SECTION 313: THIS MATERIAL CONTAINS HYDROGEN CHLORIDE, WHICH IS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF SARA TITLE III & 40 CFR PART 373. HYDROGEN CHLORIDE IS CONSIDERED HI GHLY HAZARDOUS BY OSHA. Federal Regulatory Information:TSCA: HYDROGEN CHLORIDE/WATER IS LISTED ON THE TSCA INVENTORY LIST. State Regulatory Information:STATE RIGHT TO KNOW: HYDROGEN CHLORIDE CAN BE FOUND ON THE FOLLOWING STATE RIGHT TO KNOW LISTS: CALIFORNIA, NEW JERSEY, FLORIDA, PENNSYLVANIA, MINNESOTA, MASSACHUSETTS. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:451516FB CAGE:06001 CAGE:06001 ============= Composition/Information on Ingredients ============= Ingred Name:POLYCHLORINATED BIPHENYLS (PCBS) (SARA III) CAS:1336-36-3 RTECS #:TQ1350000 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Effects of Overexposure:INHAL:RESP TK IRRIT; SKIN/EYE;IRRIT,INFLAM,CHLORACNE; MAY CAUSE LIVER DAMAGE ======================= First Aid Measures ======================= First Aid:INHAL:RMV TO FRESH AIR. IF NOT BRTHNG GIVE CPR, IF BRTHNG DIFF GIVE OXYGEN. EYE:IMMED FLUSH W/PLENTY OF WATER. SKIN:WASH W/SOAP&WATER. RMV CONTAM CLTHNG&SHOES. INGEST:INDUCE VOMIT. RPT UNTIL VOMIT IS CLEAR. NOTHG BY MOUTH IF UNCONSC. GET MEDICAL ATTN ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:EXTINQUISH W. AGENT SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR CHEMICAL PROTECTIVE SUIT WITH SELF CONTD BRTHG APP. Unusual Fire/Explosion Hazard:MATL IS NON-FLAMMABLE BUT MAY GENERATE TOXIC GASES IN HEAT OF FIRE ================== Accidental Release Measures ================== Spill Release Procedures:EVAC NON-ESSENTL PERSONNEL. VENT SPIL AREA. WEAR PROTECT EQUIPT. STOP LEAK. SOAK UP LIQUID W/NON-REACTIVE MATL (SAND, DIRT, ETC) OR RMV BY DIKE &PUMPING OR OTHER SUITABLE MEANS. CLEAN AREA W/SUITABLE SAFETY SOLVENT. LAUNDER CONTAMINATED CLTHG. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED AREA. PROTECT FROM PHYSICAL DAMAGE.AVOID ANY PHYSICAL CONTACT. KEEP CONTAINERS TIGHTLY CLOSED Other Precautions:CHLORODIPHENYLS MAY ATTACK SOME TYPES OF RUBBER AND PLASTIC. DO NOT USE CONTAMINATED WORK CLOTHING. WASH/SHOWER AFTER EXPOSURE TO PCB'S. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MESA APPR SCBA/AIR SUPP RESPIR. Ventilation:LOCAL EXHAUST TO MAINTN BELOW TLV. Other Protective Equipment:WEAR FULL PROTECTIVE CLOTHING. Supplemental Safety and Health OVEREXPOS:CAN CAUSE FORMATION OF CYSTS,CAUSES STILLBIRTHS.IRRITATES EYES,NOSE THROAT. ================== Physical/Chemical Properties ================== HCC:Z3 Solubility in Water:NEGLIGIBLE Appearance and Odor:PALE YELLOW VISCOUS LIQUID W/HYDROCARBON ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:SEE OTHER PRECAUTIONS Hazardous Decomposition Products:HYROGEN CHLORIDE, CO, & OTHER TOXIC/IRRITATING GASES/FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTROLLED DISPOSAL REQD. GEN. V.HIGH TEMP INCINERATION. IAW ALL LOCAL, STATE, & FEDERAL REGULATIONS. PERMITTED DISPOSAL OPERATOR REQUIRED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HI HEAT ALUMINUM PAINT,1206 CAGE:HO230 CAGE:6F145 CAGE:HO230 ============= Composition/Information on Ingredients ============= Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 35% OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:NAPHTHA (PETROLEUM SPIRITS OR BENZIN) CAS:8030-30-6 RTECS #:SE7555000 Fraction by Wt: 21% OSHA PEL:100 PPM ===================== Hazards Identification ===================== Effects of Overexposure:EYE/SKIN:IRRITATION. VAPOR:CNS DEPRESSION,COORDINATION LOSS. IMPAIR JUDGEMENT,STUPOR,UNCONSCIOUSNESS ======================= First Aid Measures ======================= First Aid:EYE:FLUSH WITH WATER 15 MINUTES,CALL PHYSICIAN.SKIN:REMOVE CONTAMINATED CLOTHING,FLUSH AREA WITH WATER UNTIL IRRIT SUBSIDES. INHALATION:REMOVE FROM EXPOSURE,GIVE ARTIF RESP IF NEEDED,CONSULT PHYSICIAN . INGESTION:DO NOT INDUCE VOMIT,CALL PHYSICIAN ===================== Fire Fighting Measures ===================== Flash Point:81F/27C Lower Limits:1.0 Extinguishing Media:DRY CHEMICAL,FOAM,WATER FOG Fire Fighting Procedures:SELF-CONTAIN BREATH APP, WATER FOG TO COOL EXPOSED CONTAINER Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE FROM PRESSURE BUILD UP WHEN EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:SECURE IGNITION SOURCES,VENTILATE AREA,KEEP PEOPLE AWAY. RECOVER FREE LIQUID,CONTAIN SPILL.ADD ABSORBENT AND PICK UP WITH NON-SPARKING TOOLS. AVOID BREATHING VAPORS. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE. STORE AWAY FROM HEAT OR FLAME OR STORAGE OXIDIZERS. USE WITH ADEQUATE VENTILATION,AVOID BREATHING VAPORS. Other Precautions:GROUND CONTAINERS WHEN POURING,AVOID FREE FALL OF LIQUID IN EXCESS OF A FEW INCHES. DO NOT SMOKE,EAT, WELD,FLAME CUT IN AREA OF USE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESP DEVICE IN ACCORD WITH EXPOSURE OF CONCERN. Ventilation:LOCAL/MECHANICAL WITH EXPLOSION PROOF MOTORS. Other Protective Equipment:FACE SHIELD,CHEM RESISTANT APRON,COVERALLS. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:279F/137C Vapor Density:>1 Evaporation Rate & Reference:<1 (ETHER) Percent Volatiles by Volume:71 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDANTS Hazardous Decomposition Products:CARBON MONOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:COMPLY WITH LOCAL,STATE AND FEDERAL REGULATION.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CITREX, FC153 CAGE:0K209 CAGE:0K209 ============= Composition/Information on Ingredients ============= Ingred Name:2-PROPANOL, 1-BUTOXY-; (GLYCOL ETHER PNB) CAS:5131-66-8 RTECS #:UA7700000 Ingred Name:2-PYRROLIDINONE, 1-METHYL-; (1-METHYLPYRROLIDONE) CAS:872-50-4 RTECS #:UY5790000 Ingred Name:CYCLOHEXENE, 1-METHYL-4-(1-METHYLETHENYL)-(R)-; (D-LIMONENE) CAS:5989-27-5 RTECS #:GW6360000 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CONTACT WITH LIQUID CAN CAUSE EYE IRRITATION, REDNESS, AND TEMPORARY CORNEAL CLOUDING. A SINGLE PROLONGED EXPOSURE TO THE SKIN MAY RESULT IN THE MATERIALS BEING ABSORBED IN HARMFUL AMOUNTS. PROLONGED SKIN CONTACT MAY CAUSE REDNESS, IRRITATION & DEFATTING. EXCESSIVE INHALATION OF VAPORS CAN CAUSE (SEE EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: NASAL & RESPIRATORY IRRITATION, DIZZINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHE, POSSIBLE UNCONSCIOUSNESS, AND ASPHYXIATION. SWALLOWING LARGE AMOUNTS CAN CAUSE GASTROINTESTINAL IRRITATION, NA USEA, VOMITING AND DIARRHEA. ASPIRATIONOF MATERIAL INTO THE LUNGS CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MIN, OCCASIONALLY OPEN UPPER & LOWER LIDS. IF IRRITATION DEVELOPS, CONTACT PHYSICIAN. SKIN: WASH THOROUGHLY WITH SOAP & WATER, IF IRRITATION DEVELOPS, CONSULT PH YSICIAN. INHAL: REMOVE TO FRESH AIR, ASSIST BREATHING AS NECESSARY. INGEST: DO NOT INDUCE VOMITING, SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:150F,66C Lower Limits:1 % Extinguishing Media:REGULAR FOAM, CARBON DIOXIDE OR DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED POSITIVE-PRESSURE, SCBA AND FULL PROTECTIVE EQUIPMENT , COOL CONTAINER WITH SPRAY IF POSSIBLE. Unusual Fire/Explosion Hazard:AUTO IGNITION TEMPERATURE AROUND 460 F. ================== Accidental Release Measures ================== Spill Release Procedures:STOP LEAK AT SOURCE. CONTAIN AND COLLECT MATERIAL, ABSORB RESIDUE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM HEAT OR INCOMPATIBLE CHEMICALS. READ ALL CAUTIONS AND LABELS BEFORE USE. Other Precautions:KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED ORGANIC RESPIRATOR IF EXCESSIVE MIST OR VAPORS ARE CREATED. Ventilation:LOCAL EXHAUST: MAY BE NECESSARY IN SOME CONDITIONS. MECHANICAL (GENERAL): SHOULD BE SUFFICIENT. Other Protective Equipment:BOOTS, COVERALLS, APRONS AS NECESSARY TO PREVENT SKIN CONTACT. Work Hygienic Practices:READ ALL CAUTIONS AND LABELS BEFORE USE. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:V4 Boiling Pt:B.P. Text:340F,171C Vapor Pres:< 2 Vapor Density:4.5 Spec Gravity:0.86 Evaporation Rate & Reference:<0.1 (BUTYL ACETATE=1) Solubility in Water:VERY SLIGHT Appearance and Odor:MILD, AMINE-LIKE ODOR. CLEAR BLEND. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS AND STRONG ACIDS. Stability Condition to Avoid:STRONG OXIDIZING AND ACIDS ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTACT FEDERAL, STATE, COUNTY OR LOCAL ENVIRONMENTAL REGULATOR FOR GUIDANCE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:WELD-ON 717 FOR PVC PLASTIC PIPE Preparer's Name:GEORGE BLANCO CAGE:EO483 CAGE:EO483 CAGE:17510 ============= Composition/Information on Ingredients ============= Ingred Name:POLYVINYL CHLORIDE RESIN (PVC); (NON-HAZARDOUS INGREDIENT) OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:FURAN, TETRAHYDRO-; (TETRAHYDROFURAN (THF)) (CERCLA) CAS:109-99-9 RTECS #:LU5950000 Fraction by Wt: 50-70% OSHA PEL:200 PPM ACGIH TLV:200 PPM/250 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:2-BUTANONE; (METHYL ETHYL KETONE) (SARA 313) (CERCLA) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 10% OSHA PEL:200 PPM ACGIH TLV:200 PPM/300 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:CYCLOHEXANONE (CERCLA) CAS:108-94-1 RTECS #:GW1050000 Fraction by Wt: 5-100% OSHA PEL:50 PPM, S ACGIH TLV:25 PPM, S EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:VOC (AS MANUFACTURED): 786 G/L; MAX VOC EMISSION PER SCAQMD TEST METHOD 316A: 580 G/L RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:RESP PROT: USE IT ONLY FOR A SINGLE SHORT-TERM EXPOS. FOR EMER & OTHER CNDTNS WHERE SHORT TERM EXPOS GUIDELINES (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: MAY BE EXCEEDED, USE A NIOSH APPRVD POSITIVE PRESSURE SCBA. RTECS #:9999999ZZ Ingred Name:VENT: BELOW APPLICABLE EXPOSURE LIMITS SET FORTH IN INGREDIENTS SECTION. USE ONLY EXPLOSION-PROOF VENTILATION EQUIPMENT. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: INHAL: SEV OVEREXP MAY RSLT IN NAUS, DIZZ, HDCH. CAN CAUSE DROW, IRRIT OF EYES & NASAL PASSAGES. SKIN CONT: IRRIT. LIQ CONT MAY REMOVE NATRL SKIN OILS RSLTG IN SKIN IRRIT. DERM MAY OCCUR W/PRLN G CONT. SKIN ABSORPTION: PRLNG/WIDESPREAD EXPOS MAY RSLT IN ABSORPTION OF HARMFUL AMTS OF MATL. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: EYES: OVEREXP MAY RSLT IN SEV INJURY W/CORNEAL/CONJ INFLAMM ON CONT W/LIQ. VAPS SLIGHTLY UNCOMFORTABLE. INGEST: MOD TOX. MAY CAUSE NAUS, VOMIT, DIARR, MENTAL SLUGGISHNESS. CHRONIC: SYMPS OF RESP TRACT IRRIT & DMG TO RESP EPITHELIUM WERE REPORTED IN RATS EXPOSED TO 5000 PPM THF FOR 90 DAYS. (SUP DAT) Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PREEXISTING DISEASE OF THE EYES, SKIN OR RESPIRATORY SYSTEM MAY HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES. ======================= First Aid Measures ======================= First Aid:INHAL: IF OVERCOME BY VAPS, REMOVE TO FRESH AIR & IF BRTHG STOPPED, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. CALL MD. EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN & CALL MD. SKIN: REMOVE C ONTAM CLTHG & SHOES. WASH SKIN W/PLENTYOF WATER FOR AT LEAST 15 MIN. IF IRRIT DEVELOPS, GET MED ATTN. INGEST: GIVE 1-2 GLASSES OF WATER/MILK. DO NOT INDUCE VOMIT. CALL MD/POIS CTL CTR IMMED. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:6F,-14C Lower Limits:2.0% Upper Limits:11.8% Extinguishing Media:ANSUL "PURPLE K" POTASSIUM BICARBONATE DRY CHEMICAL, CARBON DIOXIDE, NATIONAL AER-O-FOAM UNIVERSAL ALCOHOL (SUP DAT) Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP . EVACUATE ENCLOSED AREAS, STAY UPWIND. USE WATER SPRAY TO COOL CONTRS, TO FLUSH SPILLS FROM SOURCE OF (SUP DAT) Unusual Fire/Explosion Hazard:FIRE HAZARD BECAUSE OF LOW FLASH POINT AND HIGH VOLATILITY. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL TO SOURCE OF IGNITION. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMIN ALL IGNIT SOURCES. AVOID BRTHG OF VAPS. KEEP LIQ OUT OF EYES. FLUSH W/LGE AMTS OF WATER. CONTAIN LIQ W/SAND/EARTH. ABSORB W/SAND/NON-FLAMM ABSORB MATL & TRANSFER INTO STEEL DRUMS FOR RECOVERY/D ISP. PVNT LIQ FROM ENTERING DRAINS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN SHADE BETWEEN 40F & 110F. KEEP AWAY FROM HEAT, SPARKS, OPEN FLAME & OTHER SOURCES OF IGNIT. AVOID PRLNG BRTHG OF VAP. USE W/ADEQ VENT. Other Precautions:AVOID CONT W/EYES, SKIN, & CLTHG. TRAIN EMPLOYEES ON ALL SPECIAL HNDLG PROC BEFORE THEY WORK W/THIS PROD. FOLLOW ALL PREC INFO GIVEN ON CONTR LABEL, PROD BULLETINS & MFR SOLV CEMENTING LITERATURE. ALL HNDLG EQUIP SHOULD BE ELEC GROUNDED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ATM LEVELS SHOULD BE MAINTAINED BELOW ESTABLISHED EXPOS LIMS. IF AIRBORNE CONCS EXCEED THOSE LIMS, USE OF NIOSH APPRVD ORG VAP CARTRIDGE RESP W/FULL FACEPIECE IS REC. THE EFFECTIVENESS OF NIOSH APPRVD AIR-PURIFYING RESP IS LIMITED. (ING 6) Ventilation:USE ONLY WITH ADEQUATE VENTILATION. PROVIDE SUFFICIENT VENTILATION IN VOLUME & PATTERN TO KEEP CONTAMINANTS (ING 8) Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . IMPERVIOUS APRON. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health SPEC GRAV: TYPICAL 0.947 +/- 0.040. SOL IN WATER: SOLV PORTION COMPLETELY SOLUBLE IN WATER; RESIN PORTION SEPARATES OUT. EXTING MEDIA: RESIST FOAM, WATER SPRAY. FIRE FIGHT PROC: IGNITION & TO DISPERSE VAPS. EFTS OF OVEREXP: ELEVATION OF SGPT SUGGESTS DISTURB IN LIVER FUNCTION. THE NOEL WAS REPORTED TO BE 200 PPM. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:151F,66C Vapor Pres:143 @ 20C Vapor Density:2.49 Spec Gravity:SUP DAT Evaporation Rate & Reference:>1.0 (BUTYL ACETATE=1) Solubility in Water:SUP DAT Appearance and Odor:WHITE, OPAQUE GRAY OR CLEAR, MEDIUM SYRUPY LIQUID; ETHEREAL ODOR Percent Volatiles by Volume:80-85 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CAUSTICS, AMMONIA, INORGANIC ACIDS, CHLORINATED COMPOUNDS, STRONG OXIDIZERS AND ISOCYANATES. Stability Condition to Avoid:KEEP AWAY FROM HEAT, SPARKS, OPEN FLAME AND OTHER SOURCES OF IGNITION. Hazardous Decomposition Products:WHEN FORCED TO BURN, THIS PRODUCT GIVES OUT CARBON MONOXIDE, CARBON DIOXIDE, HYDROGEN CHLORIDE AND SMOKE. ==================== Disposal Considerations ==================== Waste Disposal Methods:FOLLOW LOCAL, STATE & FEDERAL REGULATIONS. CONSULT DISPOSAL EXPERT. CAN BE DISPOSED OF BY INCINERATION. EXCESSIVE QUANTITIES SHOULD NOT BE PERMITTED TO ENTER DRAINS. EMPTY CONTAINERS SHOULD BE AIR DRI ED BEFORE DISPOSING. HAZARDOUS WASTE CODE: 214.
1
eyes_protection_mandatory
======================================================= Product ID: 25-114, DL PERMATEX PUMICE FORMULA FAST (SUPP DATA) Cage: 7K128 ======================================================= Contractor Summary ======================================================= Cage: 7K128 Cage: 08028 ======================================================= Ingredients ======================================================= RTECS #: 9999999VO OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ----------------------------- Cas: 7732-18-5 RTECS #: ZC0110000 % Wt: 65-75 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 68647-72-3 % Wt: 10-15 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 1332-09-8 % Wt: 5-10 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 68154-97-2 % Wt: 5-10 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 102-71-6 RTECS #: KL9275000 % Wt: 0.1-1 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: LD50:(ORAL,RAT) >5,000 MG/KG Route Of Entry Inds - Inhalation: YES Skin: NO Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: NONE UNDER NORMAL CONDITIONS OF USE. Explanation Of Carcinogenicity: NOT RELEVANT Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. Medical Cond Aggravated By Exposure: NONE KNOWN. First Aid: INGEST: DO NOT INDUCE VOMITING. CALL PHYSICIAN IMMEDIATELY. INHAL: REMOVE TO FRESH AIR. IF SYMPS PERSIST, OBTAIN MEDICAL ATTN. SKIN: FLUSH WITH WATER. EYE: FLUSH WITH WATER FOR AT LEAST 15 MIN. CALL P HYSICIAN IMMEDIATELY. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: RINSE AWAY WITH WATER OR WIPE UP WITH A TOWEL. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: FOLLOW EPA, LOCAL, STATE & FEDERAL REGULATIONS. DISPOSE OF UNCONTAMINATED MATERIAL THROUGH SEWAGE SYSTEM WITH PERMISSION OF THE AUTHORITY RESPONSIBLE FOR THAT SYSTEM. Handling And Storage Precautions: STORAGE: HAND CLEANER SHOULD BE STORED BETWEEN 40-100F IN ORDER TO ENSURE LONG LIFE OF THE EMULSION. Other Precautions: HANDLING: FOLLOW ALL GENERAL SAFETY PRECAUTIONS. KEEP AWAY FROM CHILDREN. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: SCC Flash Point Text: 193F,89C Extinguishing Media: CO*2 AND DRY CHEMICAL POWDER. Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: NONE KNOWN. ======================================================= Control Measures ======================================================= Respiratory Protection: NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N). Ventilation: SOME LOCAL VENTILATION MAY BE DESIRED FOR EXPOSURE IN CONFINED AREAS. Other Protective Equipment: NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health: MFR TRADE NAME/PART NO: ORANGE NATURAL CITRIS HAND CLEANER. ======================================================= Physical/Chemical Properties ======================================================= Spec Gravity: 1.03 PH: 5.5 Solubility in Water: SOLUBLE Appearance and Odor: WHITE LOTION WITH PUMICE, ORANGE SCENT ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER. Materials To Avoid: NONE KNOWN. Hazardous Decomposition Products: IRRITATING ORGANIC VAPORS. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Trans ID NO: 42029 Product ID: 25-114, DL PERMATEX PUMICE FORMULA FAST (SUPP DATA) Review Date: 04/26/1994 Multiple KIT Number: 0 Review IND: Y ======================================================= Detail DOT Information ======================================================= DOT PSN Code: XXX ======================================================= Detail IMO Information ======================================================= IMO PSN Code: XXX ======================================================= Detail IATA Information ======================================================= IATA PSN Code: XXX ======================================================= Detail AFI Information ======================================================= AFI PSN Code: XXX ======================================================= HAZCOM Label ======================================================= Product ID: 25-114, DL PERMATEX PUMICE FORMULA FAST (SUPP DATA) Cage: 7K128 Company Name: LOCTITE CORP Street: 705 N MT RD Zipcode: 06111 Label Required IND: Y Date Of Label Review: 04/26/1994 Status Code: C Label Date: 04/26/1994 Origination Code: G Skin Protection IND: YES Signal Word: NONE Respiratory Protection IND: YES Health Hazard: None Contact Hazard: None Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: STORE BETWEEN 40F AND 100F. ACUTE: NONE LISTED BY MANUFACTURER. CHRONIC: NONE LISTED BY MANUFACTURER. =======================================================
1
eyes_protection_mandatory
======================================================= NIIN: 01-444-1117 Product ID: COUNTER ASSAULT OC-10 (SEE ADDL DATA) Cage: 082C9 ======================================================= Item Description Information ======================================================= Item Manager: S9G Item Name: PEPPER SPRAY Unit of Issue: BX Quantitative Expression: 00000000012EA UI Container Qty: 0 Type of Container: BOX/CANISTERS ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NOT PROVIDED Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: NO Effects of Exposure: EYES: PRODUCT IS AN EYE IRRITANT. TEARING AND REDNESS MAY OCCUR. SKIN: IRRITANT. Explanation Of Carcinogenicity: NOT PROVIDED Signs And Symptions Of Overexposure: EYES: PRODUCT IS AN EYE IRRITANT. TEARING AND REDNESS MAY OCCUR. SKIN: IRRITANT. Medical Cond Aggravated By Exposure: NOT PROVIDED First Aid: EYES: REMOVE CONTACT LENSES. FLUSH EYES WITH LARGE QUANTITIES OF WATER. TIP: IMMERSE FACE AND OPEN EYES IN BASIN OF WATER. SKIN CONTACT: WASH AFFECTED AREA WITH SOAP AND WATER . AVOID TRANSFER TO MORE SENSITIVE AREAS. WASH CONTAMINATED CLOTHING BEFORE REUSE. DO NOT APPLY SALVES OR OTHER SKIN DRESSING WHICH MAY TRAP THE PEPPER AGAINST THE SKIN. INHALATION: MOVE SUBJECT TO FRESH AIR. INGESTION: SEVE RE HEARTBURN SENSATION MAY CAUSE NAUSEA. IF IRRITATION PERSISTS, CONSULT A PHYSICIAN. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: VENTILATE AREA. AVOID PROLONGED BREATHING OF VAPORS. CONFINE SPILL WITH INERT ABSORBERS. WEAR PROTECTIVE EQUIPMENT DURING CLEAN UP. KEEP OUT OF SEWERS, STORM DRAINS, SURFACE WATER AND SOIL. Neutralizing Agent: NOT PROVIDED Waste Disposal Methods: INCINERATE IN AN APPROVED INCINERATOR OR DISPOSE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. Handling And Storage Precautions: STORE IN COOL, DRY AREA, AWAY FROM HIGH TEMPERATURES. WHEN STORING LARGE QUANTITIES, STORE IN BUILDING DESIGNED AND PROTECTED AGAINST FIRE. DO NOT STORE IN DIRECT SUNLIGHT OR ABOVE 120 F. Other Precautions: DO NOT TAKE INTERNALLY. IF INGESTED, DO NOT INDUCE VOMITING. CONSULT A PHYSICIAN. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: NONFLAMMABLE Lower Limits: NOT EST. Upper Limits: NOT EST. Extinguishing Media: THIS MATERIAL IS NON-FLAMMABLE. CARBON DIOXIDE, (ALCOHOL-FOAM), DRY CHEMICAL OR WATER MAY BE INEFFECTIVE. USE WATER TO DISPERSE FUMES, AND TO DILUTE SPILLS. Fire Fighting Procedures: IT IS RECOMMENDED THAT FIREFIGHTERS SHOULD WEAR NIOSH APPROVED, SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. USE WATER SPRAY TO COOL NEARBY CONTAINERS AND STRUCTURES EXPOSED TO FIR E. Unusual Fire/Explosion Hazard: DO NOT EXPOSE TO HEAT OR FLAME, OR STORE ABOVE 120 DEGREES F (49 DEGREES C) AS HIGH INTERNAL PRESSURES MAY CAUSE CYLINDERS TO RUPTURE. ======================================================= Control Measures ======================================================= Respiratory Protection: USE NIOSH/MSHA APPROVED CHEMICAL/MECHANICAL TYPE FILTER SYSTEM TO REMOVE A COMBINATION OF PARTICLES, GAS AND VAPORS. USE AIR LINE, IF NECESSARY. Ventilation: USE ADEQUATE VENTILATION IN VOLUME & PATTERN TO KEEP PEL/TLV BELOW RECOMMENDED LEVEL. GENERAL MECHANICAL VENTILATION SHOULD COMPLY WITH OSHA 1910.94. Other Protective Equipment: PREVENT PROLONGED SKIN CONTACT TO CONTAMINATED CLOTHING. Work Hygienic Practices: NOT PROVIDED Supplemental Safety and Health: NONE ======================================================= Physical/Chemical Properties ======================================================= HCC: V2 NRC/State LIC No: NOT RELEVANT Boiling Point: -26.5C, -15.7F B.P. Text: PROPELLANT M.P/F.P Text: NOT PROVIDED Decomp Text: NOT PROVIDED Vapor Pres: APPROX 96 LBS @ 70F Vapor Density: >1 (AIR=1) Spec Gravity: <1 (WATER=1) Viscosity: NOT PROVIDED Evaporation Rate & Reference: NOT PROVIDED Solubility in Water: 50% APPROX. Appearance and Odor: REDDISH BROWN, PUNGENT ODOR. Percent Volatiles by Volume: 90 APPROX Corrosion Rate: NOT PROVIDED ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: HEAT, OPEN FLAMES, WELDING ARC OR OTHER HIGH TEMPERATURE SOURCES WHICH MAY INDUCE THERMAL DECOMPOSITION. Materials To Avoid: STRONG ACIDS, ALKALIS, OXIDIZING MATERIALS, SODIUM, POTASSIUM, AND MAGNESIUM Hazardous Decomposition Products: NOT PROVIDED Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: WILL NOT OCCUR. ======================================================= Toxicological Information ======================================================= Toxicological Information: NOT PROVIDED ======================================================= Ecological Information ======================================================= Ecological: ZERO OZONE DEPLETING POTENTIAL (DOES NOT CONTAIN CHLORINE). NEGLIGIBLE GLOBAL WARMING POTENTIAL. ======================================================= ======================================================= Transport Information: DOT SHIPPING CLASS: ORM-D CONSUMER COMMODITY. ======================================================= Regulatory Information ======================================================= Sara Title III Information: NOT PROVIDED Federal Regulatory Information: NOT PROVIDED State Regulatory Information: NOT PROVIDED ======================================================= Other Information ======================================================= Other Information: NONE ======================================================= Transportation Information ======================================================= Trans ID NO: 153300 Product ID: COUNTER ASSAULT OC-10 (SEE ADDL DATA) Review Date: 08/28/2000 Tech Entry NOS Shipping Nm: (SOLVENT, ACTIVE INGREDIENT) Net Unit Weight: 12 X 15 OZ Multiple KIT Number: 0 Unit Of Issue: BX Container QTY: 0 Type Of Container: BOX/CANISTERS Additional Data: CONTD FROM PRODUCT ID: PSL230. PER 1999 IATA REGULATIONS, N.O.S. IS NO LONGER USED. DOT CODE PER MSD S. ======================================================= Detail DOT Information ======================================================= DOT PSN Code: DTJ Symbols: D DOT Proper Shipping Name: CONSUMER COMMODITY Hazard Class: ORM-D Label: NONE Non Bulk Pack: 156,306 Bulk Pack: NONE Max Qty Pass: 30KGGROSS Max Qty Cargo: 30KGGROSS Vessel Stow Req: A ======================================================= Detail IMO Information ======================================================= IMO PSN Code: AKD IMO Proper Shipping Name: AEROSOLS o IMDG Page Number: 2102 UN Number: 1950 UN Hazard Class: 2(T) IMO Packaging Group: - Subsidiary Risk Label: T EMS Number: 2-13 MED First Aid Guide NUM: 620 ======================================================= Detail IATA Information ======================================================= IATA PSN Code: ANB IATA UN ID Num: 1950 IATA Proper Shipping Name: AEROSOLS, NON-FLAMMABLE IATA PSN Modifier: (EACH NOT EXCEEDING 1 L CAPACITY) IATA UN Class: 2.2 IATA Label: NON-FLAMMABLE GAS Packing Note Passenger: 203 Max Quant Pass: 75 KG Max Quant Cargo: 150KG Packaging Note Cargo: 203 ======================================================= Detail AFI Information ======================================================= AFI PSN Code: ANB AFI Proper Shipping Name: AEROSOLS, NON-FLAMMABLE, N.O.S. AFI PSN Modifier: ,(EACH NOT EXCEEDING 1L CAPACITY) AFI Hazard Class: 2.2 AFI UN ID NUM: UN1950 Special Provisions: P4 Back Pack Reference: A6.3 ======================================================= HAZCOM Label ======================================================= Product ID: COUNTER ASSAULT OC-10 (SEE ADDL DATA) Cage: 082C9 Company Name: COUNTER ASSAULT Street: 120 INDUSTRY CT Zipcode: 59901 Label Required IND: Y Date Of Label Review: 08/28/2000 Status Code: C MFG Label NO: NOT PROVIDED Label Date: 02/01/2000 Year Procured: 2000 Origination Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: NO Health Hazard: Slight Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: TARGET ORGANS: NONE PROVIDED. WARNING: SEVERE IRRITANT AFFECTING EYES, SKIN AND RESPIRATORY AREAS. KEEP OUT OF REACH OF CHILDREN. IN CASE OF EXTERNAL CONTACT, FLUSH THOROUGHLY WITH WATER. DO NOT RUB. IF SYMPTOMS PERSIST AFTER 45 MINUTES, CALL PHYSICIAN. CONTENTS UNDER PRESSURE. DO NOT STORE ABOVE 120F NOR BELOW 32F. ACTIVE INGREDIENT: 10% OLEORESIN CAPSICUM, RED PEPPER DERIVATIVE. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:330210 PARA-PAK BUFFERED 10% FORMALIN FIXATIVE CAGE:8X084 CAGE:8X084 ============= Composition/Information on Ingredients ============= Ingred Name:FORMALDEHYDE, FORMALIN (SUSPECTED HUMAN CARCINOGEN BY IARC; ACGIH; SUSPECTED CARCINOGEN BY NTP; IARC - GROUP 2A) *96-4* CAS:50-00-0 RTECS #:LP8925000 Fraction by Wt: 4% ACGIH TLV:0.37 MG/CUM IC (2A) EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:METHANOL (METHYL ALCOHOL), COLUMBIAN SPIRITS *96-4* CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: 1% Other REC Limits:200 PPM OSHA PEL:200 PPM ACGIH TLV:200 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:EYES/SKIN: IRRITATION. INGESTION: DEATH. Explanation of Carcinogenicity:SEE INGREDIENTS Effects of Overexposure:IRRITATION, HEADACHE, UNCONSCIOUSNESS, NAUSEA, VOMITING. ======================= First Aid Measures ======================= First Aid:EYES/SKIN: FLUSH W/WATER FOR 15 MINS. INHALATION: REMOVE TO FRESH AIR. GIVE CPR IF NEEDED. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:>200F Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING AREAS. Fire Fighting Procedures:WEAR SCBA & PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB ON PAPER, VERMICULITE. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T EXCEED TLVS. CONTAINERS POTENTIALLY HAZARDOUS WHEN EMPTY. DON'T REUSE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE OSHA APPROVED RESPIRATOR IF TLVS ARE EXCEEDED. Ventilation:GENERAL MECHANICAL VENTILATION IS USUALLY ADEQUATE UNDER NORAMAL USE. Other Protective Equipment:PROTECTIVE CLOTHING. Supplemental Safety and Health PH: 6.8-7.2. ================== Physical/Chemical Properties ================== pH:(SUPP) Solubility in Water:UNLIMITED Appearance and Odor:COLORLESS LIQUID W/PUNGENT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG BASES. Hazardous Decomposition Products:CO2, WATER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:25150/X3S20 XYLENES 96% MIXED ISOMERS W/ETHYL BENZENE CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:XYLENE, DIMETHYLBENZENE, XYLOL (IARC - GROUP 3) *97-4* CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 100% Other REC Limits:100 PPM OSHA PEL:100 PPM ACGIH TLV:100 PPM, SKIN EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): 4300 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: SEVERE IRRITATION. SKIN: IRRITATION/DERMATITIS, ABSORPTION IS SLIGHT. INGESTION: CNS DEPRESSION, KIDNEY & LIVER DAMAGE. GI IRRITATION, ASPIRATION OF MATERIAL INTO THE LUNGS MAY CAUSE CHEMICAL PN EUMONITIS WHICH CAN BE FATAL. INHALATION: CNS EFFECTS/RESPIRATORY TRACT IRRITATION, CHEMICAL PNEUMONITIS/PULMONARY EDEMA Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, REDNESS, DRYNESS, INFLAMMATION, HEADACHE, EXCITEMENT, FATIGUE, NAUSEA, VOMITING, STUPOR, COMA, DIARRHEA, DIZZINESS, UNCONSCIOUSNESS, WEAKNESS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR 15 MINS. SKIN: FLUSH W/PLENTY OF SOAP & WATER FOR 15 MINS. INGESTION: ASPIRATION HAZARD. DON'T INDUCE VOMITING. IF CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:77F Lower Limits:1.1 Upper Limits:7 Extinguishing Media:SMALL: DRY CHEMICAL, CO2, WATER SPRAY/ALCOHOL-RESISTANT FOAM. Fire Fighting Procedures:USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. WEAR A SCBA/MSHA/NIOSH APPROVED/EQUIVALENT & FULL PROTECTIVE GEAR. Unusual Fire/Explosion Hazard:VAPORS CAN TRAVEL TO A SOURCE OF IGNITION & FLASH BACK. AUTOIGNITION TEMP: 860F. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB W/INERT MATERIAL THEN PLACE INTO A CHEMICAL WASTE CONTAINER. REMOVE SOURCES OF IGNITION. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS & FLAME. STORE IN A COOL, DRY, WELL VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES. KEEP CONTAINER TIGHTLY CLOSED. Other Precautions:USE W/ADEQUATE VENTILATION. AVOID CONTACT W/EYES, SKIN/CLOTHING. AVOID INGESTION & INHALATION. KEEP FROM CONTACT W/OXIDIZING MATERIALS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A NIOSH/MSHA APPROVED AIR PURIFYING RESPIRATOR W/AN ORGANIC VAPOR CARTRIDGE/CANISTER MAY BE PERMISSIBLE WHERE AIRBORNE CONCENTRATIONS ARE EXPECTED. Ventilation:GENERAL/LOCAL EXHAUST TO KEEP AIRBORNE CONCENTRATIONS BELOW EXPOSURE LIMITS. Other Protective Equipment:PROTECTIVE CLOTHING. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:284F Melt/Freeze Pt:M.P/F.P Text:-52.6F Vapor Pres:21 Vapor Density:3.66 Spec Gravity:0.862 Evaporation Rate & Reference:(BU AC = 1): 0.6 Solubility in Water:SLIGHT Appearance and Odor:CLEAR COLORLESS LIQUID W/AROMATIC ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES INCOMPATIBLE MATERIALS, STRONG ACIDS, STRONG OXIDIZERS, PLASTICS, RUBBER & COATINGS. Stability Condition to Avoid:HIGH TEMPS, IGNITION SOURCES. Hazardous Decomposition Products:CO, CO2. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:IONAC C-267,NA-38 CAGE:76465 CAGE:0RY73 CAGE:76465 ============= Composition/Information on Ingredients ============= Ingred Name:SULFONATED COPOLYMER OF STYRENE AND DIVINYLBENZENE CAS:69011-20-7 Fraction by Wt: 50 - 60% Other REC Limits:NONE RECOMMENDED Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 40 - 50% Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT) IS UNKNOWN. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN. ACUTE- MAY CAUSE EYE IRRITATION. SKIN CONTACT MAY CAUSE IRRITATION IN SENSITIVE INDIVIDUALS. ESSENTIALLY NON-TOXIC BY INGESTION. INHALATION IS UNLIKELY. CHRONIC- UNKNOWN. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, REDDENING AND ITCHING OF SKIN Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING SKIN DISORDERS MAY BE MORE SUCCEPTIBLE TO THE EFFECTS FROM EXPOSURE TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYE/SKIN:FLUSH WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN. INHALED:UNLIKELY. ORAL: GET MEDICAL ATTENTION IF NEEDED. ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:NOT RELEVANT Upper Limits:NOT RELEVANT Extinguishing Media:WATER FOG, CARBON DIOXIDE, SAND, FOAM/DRY CHEMICAL. WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. AVOID EYE CONTACT. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:VACUUM OR SWEEP UP SPILL. AVOID CREATING DUST. PLACE IN APPROPRIATE CONTAINER FOR DISPOSAL. VENTILATE AREA AND WASH SPILL SITE AFTER PICKUP IS COMPLETE. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM STRONG OXIDIZING AGENTS. KEEP CONTAINER TIGHTLY CLOSED. AVOID FREEZING OR PROLONGED STORAGE ABOVE 50C/122F (CONTAINS WATER). Other Precautions:DO NOT RAISE DUST. AVOID CONTACT WITH EYES, SKIN OR CLOTHING. AVOID INHALATION OF DUST. WASH THOROUGHLY AFTER HANDLING MATERIAL. KEEP OUT OF REACH OF SMALL CHILDREN. DO NOT TAKE INTERNALLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. IF AIRBORNE CONCENTRATION IS HIGH, WEAR A NIOSH-APPROVED DUST RESPIRATOR OR DUST MASK. Ventilation:ROOM VENTILATION IS SUFFICIENT UNDER NORMAL OFFICE CONDITIONS. Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, PROTECTIVE CLOTHING AND/OR UNIFORM Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. WASH BEFORE EATING OR DRINKING. Supplemental Safety and Health DIFFERENT FORMULA. FOR PREVIOUS FORMULATION, SEE PNI A, SAME NSN. ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NOT RELEVANT Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C Vapor Pres:17 (WATER) Vapor Density:0.62;WATER Spec Gravity:1.3 Viscosity:NOT RELEVANT Evaporation Rate & Reference:1 (WATER=1) Solubility in Water:INSOLUBLE Appearance and Odor:SPHERICAL BEADS - ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS SUCH AS NITRIC ACID Stability Condition to Avoid:FREEZING, HEATING ABOVE 50C/122F Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, STYRENE AND DIVINYLBENZENE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. PRODUCT IS NOT HAZARDOUS WASTE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:AS9174000 EA 934NA SYSTEM Kit Part:Y CAGE:33150 CAGE:33564 CAGE:33150 ============= Composition/Information on Ingredients ============= Ingred Name:DIMER FATTY ACIDS, TALL OIL FATTY ACIDS, TRIETHYLENETETRAMINE POLYMER CAS:68082-29-1 Fraction by Wt: 40-70% Ingred Name:DIETHYLENETRIAMINE, ETHYLENEDIAMINE, N-(2-AMINOETHYL) CAS:111-40-0 RTECS #:IE1225000 Fraction by Wt: 10-30% Other REC Limits:4 MG/CUM ACGIH TLV:1 PPM (SKIN) Ingred Name:TRIETHYLENETETRAMINE, EPOXY HARDNER CAS:112-24-3 RTECS #:YE6650000 Fraction by Wt: 5-10% Ingred Name:VOLATILE ORGANIC CONTENT: <10 G/L RTECS #:9999999VO ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): >2000 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN/EYES: IRRITATION. MATERIAL IS CORROSIVE. BRIEF CONTACT MAY CAUSE CHEMICAL BURNS. PROLONGED/REPEATED CONTACT MAY RESULT IN BURNS & POSSIBLE ALLERGIC SENSITIZATION. INHALATION: VAPORS & MISTS WILL IRRITATE NOSE & THROAT. Explanation of Carcinogenicity:NONE Effects of Overexposure:BURNS, IRRITATION, CHEST DISCOMFORT. Medical Cond Aggravated by Exposure:SKIN SENSITIZATION. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/LOTS OF RUNNING WATER FOR 15 MINS. SKIN: WASH THOROUGHLY W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. INGESTION: DRINK PLENTY OF WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL, HALON, WATER SPRAY, FOAM/FOG Fire Fighting Procedures:WEAR SCBA & FULL PROTECTIVE CLOTHING, SUCH AS TURN OUT GEAR. CARTRIDGE RESPIRATORS DON'T PROVIDE ADEQUATE PROTECTION FOR FIRE FIGHTERS/EXOTHERM MITIGATION. Unusual Fire/Explosion Hazard:MAY LIBERATE LARGE QUANTITIES OF DENSE FOUL-SMELLING SMOKE WHICH MAY CONTAIN UNIDENTIFIED TOXIC GASSES. ================== Accidental Release Measures ================== GLASSES. ABSORB W/ABSORBENT MATERIAL SUCH AS VERMICULITE/SAND. SCRAPE UP/SHOVEL INTO DOT-APPROVED WASTE CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:PRODUCT MAY BE STORED AT ROOM TEMP FOR UP TO 12 MONTHS. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. Other Precautions:DON'T CUT, GRIND, WELD/DRILL ON/NEAR THIS CONTAINER. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE, HANDLE EMPTY CONTAINERS AS IF THEY WERE FULL. AVOID MIXING CURING AGENT IN BATCHES GREATER THAN 1 POUND. D ON'T HEAT MIXED ADHESIVE >125F. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A RESPIRATOR EQUIPPED W/ORGANIC VAPOR CARTRIDGE MAY BE APPROPRIATE. Ventilation:LOCAL EXHAUST Other Protective Equipment:SAFETY GLASSES W/SIDE SHIELDS/CHEMICAL Work Hygienic Practices:WASH AFTER HANDLING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:405F Vapor Pres:0 Vapor Density:>1 Spec Gravity:0.96 Solubility in Water:100% Appearance and Odor:AMBER LIQUID W/AMONIACAL ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG LEWIS/MINERAL ACIDS. Stability Condition to Avoid:HEAT, TEMP >125F. Hazardous Decomposition Products:CO, NITROGEN OXIDES, ALDEHYDES, ACIDS & UNDETERMINED ORGANICS. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATION IN AN EPA APPROVED WASTE INCINERATOR IS PREFERRED IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ACETYLENE, ETHYNE, ETHINE CAGE:00742 CAGE:00742 CAGE:5H199 ============= Composition/Information on Ingredients ============= Ingred Name:ACETYLENE CAS:74-86-2 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Explanation of Carcinogenicity:ACETYLENE IS CLASSIFIED AS A SIMPLE ASPHYXIANT AND HAS NO TLV. Effects of Overexposure:HEADACHES, DIZZINESS, SHORTNESS OF BREATH, AND LOSS OF CONSCIOUSNESS MAY OCCUR IF THE GAS IS PRESENT IN QUANTITIES TO DILUTE THE OXYGEN CONCENTRATION IN AIR. SYMPTOMS OF ANOXIA OCCUR ONLY WHEN THE G AS CONCENTRATIONS ARE WITHIN THE FLAMMABLE RANGE & THE MIXTURE HAS NOT IGNITED. ======================= First Aid Measures ======================= First Aid:FIRST DEGREE & MINOR SECOND DEGREE THERMAL BURNS FROM FIRES SHOULD BE IMMERSEDIN COOL WATER FOR 30 MINUTES.MAJOR BURNS SHOULD BE COVERED IN CLEANEST MATERIAL AVAILABLE. SEEK IMMEDIATE AID OF PHYSICI AN.PERSONS SUFFERING FROM LACK OF OXYGENSHOULD BE MOVED TO AREAS W/NORMAL ATMOSPHERE. ASSISTED RESPIRATION AND SUPPLEMENTAL OXYGEN SHOULD BE GIVEN IF VICTIM IS NOT BREATHING. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:OF / -18C Autoignition Temp:Autoignition Temp Text:*** Lower Limits:100 Upper Limits:2.5 Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, HALON Fire Fighting Procedures:STOP GAS FLOW/FIGHT FIRE CONVENTIONALLY. USE WATER SPRAY TO KEEP CYLINDERS/OTHERCONTAINERS COOL IF EXPOSED TO FIRE.KEEP PERSONNEL AWAY SINCE CONTNR CAN RUPTURE. Unusual Fire/Explosion Hazard:IT BURNS W/INTENSELY HOT FLAME.POTENTIAL EXPLOSION HAZARD EXISTS FROM REIGNITIONIF FIRE IS EXTING. W/O SHUTTING OFF ACETYLENE SOURCE. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA TO PREVENT FLAMMABLE MIXTURE FROM FORMING. REMOVE SOURCES OF IGNITION,HEAT,SPARKS, ETC. CAREFULLY REMOVE CYLINDERS W/SLOW LEAK TO A REMOTE OUTDOOR LOCATION. AVOID ENTERING AREA OFFLAMMABLE ATMOSPHERE. ======================Handling and Storage ====================== Handling and Storage Precautions:USE SUITABLE HANDTRUCK.ALWAYS OPEN/CLOSE ACETYLENEVALVES SLOWLY.KEEP CYLINDERS AWAY FROM HEAT SOURCESTORAGE SHOULD NOT BE IN HEAVY TRAFFIC AREAS. Other Precautions:SEGREGATE FULL & EMPTY CYLINDERS. KEEP ACETYLENE CYLINDERS STORAGE AREAS AWAY FROM OXYGEN AND OTHER OXIDIZERS. AVOID DRAGGING,ROLLING,OR SLIDING CYLINDERS. AVOID EXPOSURE TO AREAS WHERE SALT OR OT HER CORROSIVE CHEMICAL ARE PRESENT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:OXYGEN DEFICIENT ATMOSPHERES ARE IN THE FLAMMABLE RANGE. DO NOT ENTER!! RESPIRATORS WILL NOT FUNCTION. Ventilation:NATURAL OR MECHANICAL WHERE GAS IS PRESENT. MECHANICAL VENTILATION FOR ENCLSD AREA MUST MEET NEC REQMENTS FOR CL1,GRP4. Other Protective Equipment:LEATHER SLEEVES, LEATHER APRON AND OTHER STANDARD PROTECTIVEEQUIPMENT FOR CUTTING AND WELDING. Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:**SEE BELOW Vapor Pres:590 PSIA Vapor Density:1 ATM.0681 Spec Gravity:1 ATM 0.906 Solubility in Water:1ATM1.0CUFT/CUFTH2O Appearance and Odor:PURE: COLORLESS & ODORLESS; IMPURITIES IMPART A CHARACTERISTIC GARLIC LIKE ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:NO OXYGEN & HALOGENS. FORMS EXPLOSIVE COMPOUNDS W/COPPER,BRASS,COPPER SALTS, HG & HG SALTS,AG & AG SALTS, & HNO3. Stability Condition to Avoid:NEVER UTILIZE FREE GAS OUTSIDE CYLINDER AT PRESS. <15PSIG. AVOID MECH. SHOUCKS TO CONTNR.NEVER EXPOSE CYLINDER TO HEAT. Hazardous Decomposition Products:ACETYLENE WILL DECOMPOSE INTO ELEMENTAL CARBON AND HYDROGEN UNDER THE ABOVE CONDITIONS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT ATTEMPT TO DISPOSE OF RESIFUAL GASEOUS ACETYLENE IN CYLINDERS. RETURN TO AIR PRODUCTS FOR DISPOSAL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:EP-654 HARDENER Kit Part:Y Preparer's Name:RICHARD L. WHEELER CAGE:IO099 CAGE:22156 CAGE:IO099 ============= Composition/Information on Ingredients ============= Ingred Name:MERCAPTAN MIXTURE Ingred Name:SUPP DATA: VICTIM'S THROAT. KEEP VICTIM'S HEAD BELOW HIPS WHILE VOMITING. GET MEDICAL ATTENTION. RTECS #:9999999ZZ Ingred Name:SPILL PROC:SPILL TO PVNT SPREADING.PUMP LIQ TO SALVAGE TANK. REMAINING LIQ SHOULD BE ABSORB W/VERMICULITE, SAND, (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: SWEEPING CMPD/OTHER ABSORB MATL. SHOVEL INTO CLSD CNTNRS. PVNT RUNOFF TO SEWERS, STREAMS/OTHER BODIES OF (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: WATER. IF RUNOFF OCCURS, NOTIFY PROPER AUTHORITIES AS REQUIRED. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (ORAL) <5,000 MM/KG & >500 MM/KG. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN: SHORT SINGLE EXPOSURE MAY CAUSE A SEVERE BURN AND ALSO MAY CAUSE SIGNIFICANT SENSITIZATION OR ALLERGIC RESPONSE. MAY BE ABSORBED IN MODERATELY TOXIC AMOUNTS. EYES: MAY CAUSE SEVERE BURN WITH POS SIBLE LOSS OF VISION. INHALATION: HAS ADISAGREEABLE ODOR. INGESTION: MAY CAUSE BURNS OF MOUTH, ESOPHAGUS, POSS STOMACH. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:WE DO NOT KNOW OF ANY MEDICAL CONDITIONS THAT MIGHT BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. THIS PRODUCT, AS WITH ANY CHEMICAL, MAY ENHANCE EXISTING ALLERGY CONDITIONS ON CERTAIN PEOPLE. ======================= First Aid Measures ======================= First Aid:SKIN: FLUSH IMMED W/PLENTY OF H*2O,FOLLOWED BY THORO SOAP & H*2O WASH.REMOVE & WASH CONTAM CLTHG BEFORE REUSE. CONTAM LEATHER GOODS SHOULD BE DISCARDED AS THEY CANNOT BE DECONTAM. EYE: IMMED FLUSH W/L RG AMT OF H*2O FOR AT LST 15 MIN, LIFTING UPPER & LOWER LIDS OCCAS. GET IMMED MED ATTN. INHAL: REMOVE TO FRESH AIR IF EFTS OCCUR. CONSULT PHYS. INGEST: DO NOT GIVE LIQ IF VICTIM IS UNCON/VERY (SUPDAT) ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:>200F,>93C Extinguishing Media:CO*2, DRY CHEMICAL AND FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . ADDITIONS OF WATER WILL REDUCE BURNING RATE. Unusual Fire/Explosion Hazard:NO UNUSUAL HAZARDS KNOWN. ================== Accidental Release Measures ================== Spill Release Procedures:SML SPILLS:AVOID SKIN CONT.ABSORB LIQ IN VERMICULITE, SAND, SWEEPING CMPD/OTHER ABSORB MATL & TRANSFER TO CLSD CNTNR.LRG SPILLS: AVOID SKIN CONT. PERSONS NOT WEARING PROT CLTHG SHOULD BE EXCLUDED FROM AREA. STOP SPILL AT SOURCE. DIKE AREA OF (ING 3) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. AVOID EXCESSIVE HEAT OR COLD. AVOID MOISTURE CONTAMINATION. Other Precautions:DANGER! CAUSES SEVERE SKIN BURNS AND MAY BE HARMFUL IF ABSORBED THROUGH SKIN. DO NOT GET ON SKIN OR CLOTHING. DANGER! CAUSES SEVERE EYE BURNS. DO NOT GET IN EYES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOR CONFINED SPACES, OR EMERGENCIES, A NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING APPARATUS OR A FULL-FACE RESPIRATOR IS RECOMMENDED. Ventilation:PROD HAS AN OBJECTIONABLE ODOR, THEREFORE LOC EXHST IS PREF. ROOM EXHST IS ACCEPTABLE IF VAP CONC ARE SUCH THAT (SUPDAT) Other Protective Equipment:CLEAN, BODY COVERING CLTHG, INCL BOOTS DEPENDING ON EXTENT & SEV OF EXPOS LIKELY.WASHING FACILITIES & EYE WASH (SUPDAT) Work Hygienic Practices:WASH THORO AFTER HANDLING. REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE. CONTAM LEATHER GOODS SHOULD BE DISCARDED. Supplemental Safety and Health VENT: ODOR IS ACCEPTABLE. OTHER PROT EQUIP: FOUNTAIN SHOULD BE ACCESSIBLE IN WORK AREA. FIRST AID PROC: DROWSY. OTHERWISE, GIVE NO MORE THAN 2 GLASSES OF H*2O & INDUCE VOMIT BY GIVING 2 TABLESPOONS OFSYRUP OF IPECAC. IF IPECAC IS NOT AVAIL, GIVE 2 GLASSES OF H*2O & INDUCE VOMIT BY TOUCHING FINGER TO BACK OF (ING 2) ================== Physical/Chemical Properties ================== HCC:T4 Boiling Pt:B.P. Text:>300F,>149C Vapor Pres:NIL Vapor Density:>1 Spec Gravity:1.11 Solubility in Water:SLIGHT (0.1 TO 1%) Appearance and Odor:AMBER LIQUID, MERCAPTAN ODOR Percent Volatiles by Volume:NIL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, OXIDIZING MATERIALS. Stability Condition to Avoid:EXCESSIVE HEAT OR MOISTURE CONTAMINATION. Hazardous Decomposition Products:CO, NO*X, AND SO*X. Conditions to Avoid Polymerization:WILL REACT EXOTHERMICALLY WHEN MIXED WITH EPOXY RESINS. ==================== Disposal Considerations ==================== Waste Disposal Methods:LANDFILL OR INCINERATE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:1586 SPEEDY DRY COATINGS CAGE:08882 CAGE:08882 ============= Composition/Information on Ingredients ============= Ingred Name:XYLENE, DIMETHYLBENZENE, XYLOL (IARC - GROUP 3) *97-1* CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 45-60% Other REC Limits:100 PPM OSHA PEL:100 PPM ACGIH TLV:100 PPM, SKIN EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BENZIN, NAPHTHA, MINERAL SPIRITS, PETROLEUM NAPHTHA CAS:8030-30-6 RTECS #:DE3030000 Fraction by Wt: 0-10% Other REC Limits:STEL 400 PPM OSHA PEL:100 PPM ACGIH TLV:300 PPM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Explanation of Carcinogenicity:NONE Effects of Overexposure:HEADACHE, DIZZINESS, STAGGERING GAIT, CONFUSION, UNCONSCIOUSNESS, COMA, IRRITATION ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE FROM EXPOSURE, RESTORE BREATHING. EYES: FLUSH W/WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:81F Lower Limits:0.9 Extinguishing Media:CO2, DRY CHEMICAL/FOAM Fire Fighting Procedures:WEAR SCBA. WATER COOL CONTAINERS TO PREVENT PRESSURE BUILD-UP, FOG NOZZLES PREFERRED. Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. ISOLATE FROM HEAT & OTHER IGNITION SOURCES. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION, VENTILATE AREA & REMOVE W/INERT ABSORBENT & NON-SPARKING TOOLS. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T STORE ABOVE 120F. STORE LARGE QUANTITIES IN BUILDING DESIGNED/PROTECTED FOR STORAGE OF NFPA CLASS II FLAMMABLE LIQUIDS. Other Precautions:CONTAINERS SHOULD BE GROUNDED WHEN POURING. DON'T TAKE INTERNALLY. EMPTY CONTAINERS MAY BE HAZARDOUS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN CONFINED AREAS: USE BUREAU OF MINES APPROVED AIRLINE TYPE RESPIRATOR/HOODS. Ventilation:PROVIDE LOCAL EXHAUST VENTILATION TO KEEP BELOW TLV/LEL. CONTACT. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:244-287F Vapor Density:>1 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:LIQUID Percent Volatiles by Volume:64-71 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:EXTREME HEAT, ELECTRICAL EQUIPMENT, SPARKS/OPEN FLAMES Hazardous Decomposition Products:CO, CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/LOCAL, STATE & FEDERAL REGULATIONS. DON'T INCINERATE CLOSED CONTAINERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DGV P-0731 Preparer's Name:KEITH FREY CAGE:EO374 CAGE:EO374 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM HYDROXIDE (CERCLA) CAS:1310-73-2 RTECS #:WB4900000 Fraction by Wt: 8.00% Other REC Limits:NONE RECOMMENDED OSHA PEL:2 MG/M3 ACGIH TLV:C 2 MG/M3; 9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS NOT KNOWN. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS: EYE, SKIN, RESPIRATORY & GI TRACTS. ACUTE- CORROSIVE TO ALL BODY TISSUES WHICH IT COMES IN CONTACT WITH. INHALATION OF MIST/DUST MAY CAUSE DAMAGE TO RESPIRATORY TRACT. MAY CAUSE PERMANE NT EYE INJURY. MAY CAUSE SKIN BURNS. INGESTION CAN CAUSE BURNS & TISSUE PERFORATION. CHRONIC- DERMATITIS, LUNG DAMAGE. Explanation of Carcinogenicity:NONE Effects of Overexposure:SEVERE IRRITATION, NAUSEA, VOMITING, TEARING, PAIN, EYE, LUNG AND SKIN DAMAGE, BLINDNESS Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS SUCH AS ALLERGIES, ECZEMA MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:GET IMMEDIATE MEDICAL HELP FOR ALL CASES OF EXPOSURE. EYES/SKIN: IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN. INHALED: MOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NECESSARY. ORAL: DO N OT INDUCE VOMITING. IF CONSCIOUS, DRINKLARGE AMOUNT OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF VOMITING OCCURS SPONTANEOUSLY, KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:NOT RELEVANT Upper Limits:NOT RELEVANT Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:MAY FORM HYDROGEN GAS IF ALUMINUM OR ZINC IS PRESENT. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. VENTILATE AREA. ABSORB ON SAND, VERMICULITE OR SIMILAR MATERIAL. PLACE IN AN APPROPRIATE CONTAINER FOR DISPOSAL. WASH CONTAMINATED SPILL AREA WITH DILUTE MINERAL ACID AND WA TER. DO NOT FLUSH TO SEWERS OR WATERWAYS. Neutralizing Agent:DILUTE SULFURIC, NITRIC, HYDROCHLORIC OR PHOSPHORIC ACID ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY AREA AWAY FROM INCOMPATIBLES. KEEP CONTAINER CLOSED WHEN NOT IN USE. Other Precautions:DANGER! CORROSIVE. WASH THOROUGHLY WITH SOAP AND WATER AFTER HANDLING AND BEFORE EATING, DRINKING, SMOKING. KEEP OUT OF REACH OF CHILDREN. DO NOT TAKE INTERNALLY. DO NOT GET IN EYES OR ON SKIN. DO NOT INHALE VAPORS OR SPRAY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY NEEDED. IF EXCESSIVE MISTING IS EXPECTED, WEAR NIOSH-APPROVED VAPOR AND MIST RESPIRATOR (REFER TO 29 CFR 1910.134) Ventilation:GENERAL MECHANICAL VENTILATION IS ADEQUATE FOR NORMAL USE. LOCAL EXHAUST IS RECOMMENDED FOR CONFINED AREAS. Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, PROTECTIVE CLOTHING Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health HCC PER TECHNICAL SUPPORT. ================== Physical/Chemical Properties ================== HCC:B1 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:212F,100C Spec Gravity:1.12 pH:ALKALI Evaporation Rate & Reference:1 (WATER=1) Solubility in Water:COMPLETE Appearance and Odor:CLEAR TO YELLOWISH LIQUID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, FLAMMABLE LIQUIDS, CERTAIN METALS, ORGANIC HALOGENATED COMPOUNDS, NITRO COMPOUNDS Stability Condition to Avoid:NONE Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. CONTRACT WITH A LICENSED WASTE DISPOSAL FACILITY. IT MAY REQUIRE NEUTRALIZATION AND FILTERATION.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CURING AGENT 235-2 CAGE:22121 CAGE:22121 ============= Composition/Information on Ingredients ============= Ingred Name:CURING AGENT; (ALIPHATIC AMINE CURING AGENT) OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:CORROSIVE. SEVERELY IRRITATING TO THE EYES. SEVERE IRRRITATION OF SKIN. CHRONIC:PRE-EXISTING SKIN AND EYE DISODERS MAY BE AGGRAVATED. ROUTES OF EXPOSURE:INHAL:VAPORS ARE IRRITATING AND MAY CAUSE IRRITATION OF THE RESPIRATORY TRACT. INGEST:MODERATE TOXICITY. MAY CAUSE BURNS OF MOUTH AND THROAT. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HEALTH HAZARDS:SKIN ABSORPTION:REPEATED OR PROLONGED EXPOSURE MAY BE HARMFUL. EYE:MODERATE CORNEAL DAMAGE. SKIN:MAY CAUSE CHEMICAL BURNS. MAY DEVELOP ALLERGIC SKIN REACTION. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN AND EYE DISORDERS. ======================= First Aid Measures ======================= First Aid:SKIN:REMOVE CONTAMINATED CLOTHING. WASH FROM SKIN WITH SOAP AND WATER. LAUNDER CLOTHING PRIOR TO RE-USE. EYES:FLUSH WITH WATER FOR AT LEAST 15 MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION . INHAL:REMOVE VICTIM TO FRESH AIR. ADMINISTER OXYGEN IF NECESSARY. INGEST:DO NOT INDUCE VOMITING. GIVE LARGE DOSES OF WATER. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:>200F,>93C Extinguishing Media:WATER SPRAY, FOAM, CO*2, DRY CHEMICAL. Fire Fighting Procedures:AVOID BREATHING SMOKE. WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . COOL FIRE EXPOSED CONTAINERS WITH WATER. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:AVOID CONTACT WITH LIQUID AND VAPORS. WIPE WITH A CLOTH OR COLLECT ON ABSORBENT MATERIAL. LARGE SPILLS:DIKE AND CONTAIN. PUMP OR SHOVEL INTO SALVAGE VESSELS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY AREA IN TIGHTLY CLOSED CONTAINERS. AVOID CONTACT WITH SKIN AND EYES. USE WITH ADEQUATE VENTILATION. Other Precautions:FOR INDUSTRIAL USE ONLY. CORROSIVE. MAY CAUSE SEVERE EYE BURNS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOR EXCESSIVE VAPORS OR TO MAINTAIN BELOW TLV LIMIT. NIOSH/MSHA APPROVED RESPIRATOR FOR ORGANIC VAPORS IN COMPLIANCE WITH 29 CFR 1910.134. Ventilation:LOCAL EXHAUST:YES. MECHANICAL (GENERAL):YES. Other Protective Equipment:FOR PROLONGED EXPOSURE, IMPERVIOUS CLOTHING AND BOOTS TO MINIMIZE PERSONAL CONTACT. EYE-WASH STATION, SAFETY SHOWER. Work Hygienic Practices:USE GOOD HYGIENE PRACTICES. Supplemental Safety and Health EYE PROT: AND FULL LENGTH FACE SHIELD . ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>225F,>107C Vapor Pres:NIL Vapor Density:>1 Spec Gravity:0.95 (H*2O=1) Evaporation Rate & Reference:<1 (BUAC=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR VISCOUS LIQUID. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MINERAL OR ORGANIC ACIDS, STRONG OXIDIZING AGENTS. Stability Condition to Avoid:LARGE MIXTURES WITH EPOXY RESINS IN BULK. CURING PROCESS IS EXOTHERMIC. Hazardous Decomposition Products:OXIDES OF CARBON AND NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:CURE WITH EPOXY RESIN, THEN BURY OR INCINERATE WHERE PERMITTED BY FEDERAL, STATE AND LOCAL REGULATIONS. REMOVE SALVAGE VESSELS TO A WASTE DISPOSAL SITE OPERATING IN COMPLIANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: TANDEM-R HCG Kit Part: Y Cage: FO596 Box: 269006 ======================================================= Preparer Co. when other than Responsible Party Co. ======================================================= Cage: FO596 Assigned Ind: Y Box: 269006 ======================================================= Contractor Summary ======================================================= Cage: 63493 Box: 269006 Cage: FO596 Box: 269006 ======================================================= Ingredients ======================================================= Cas: 26628-22-8 RTECS #: VY8050000 % Wt: 0.1 Other REC Limits: 0.1 PPM ACGIH TLV: C 0.29 MG/CUM EPA Rpt Qty: 1000 LBS DOT Rpt Qty: 1000 LBS ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: NO Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Explanation Of Carcinogenicity: NONE First Aid: EYES/SKIN: IMMEDIATELY FLUSH W/COPIOUS AMOUNTS OF WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: FLUSH DRAINS W/COPIOUS AMOUNTS OF WATER TO PREVENT AZIDE ACCUMULATION. Waste Disposal Methods: DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. Handling And Storage Precautions: STORE IN A COOL, DRY PLACE. REFRIGERATE, UNLESS OTHERWISE SPECIFIED IN KIT INSERT. Other Precautions: AZIDE REACTS W/MANY HEAVY METALS SUCH AS LEAD, COPPER, MERCURY, SILVER & GOLD TO FORM EXPLOSIVE COMPOUNDS. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: DRY CHEMICAL Unusual Fire/Explosion Hazard: CONTACT W/COPPER/LEAD DRAIN PIPES MAY RESULT IN THE FORMATION OF POTENTIALLY EXPLOSIVE AZIDE DEPOSITS. ======================================================= Control Measures ======================================================= Other Protective Equipment: LAB COAT Work Hygienic Practices: REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. ======================================================= Physical/Chemical Properties ======================================================= Spec Gravity: 1.85 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Materials To Avoid: ACIDS, HEAVY METALS; LEAD, COPPER, BROMINE, CARBON DISULFIDE, CHROMYCHLORIDE, DIBROMO MALONITRILE, DIMETHYL SULFATE Hazardous Decomposition Products: SODIUM & OXIDES OF NITROGEN Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: TANDEM-R HCG Cage: FO596 Assigned IND: Y Company Name: HYBRITECH INCORPORATED Street: 11095 TORREYANA ROAD PO Box: 269006 Zipcode: 92126 Label Required IND: Y Date Of Label Review: 12/16/1998 Status Code: C Label Date: 12/16/1998 Origination Code: G Hazard And Precautions: N/K N/K =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CARBON TETRACHLORIDE,ACS CAGE:83628 CAGE:83628 ============= Composition/Information on Ingredients ============= Ingred Name:CARBON TETRACHLORIDE (SARA III) CAS:56-23-5 RTECS #:FG4900000 Fraction by Wt: 100% OSHA PEL:10 PPM ACGIH TLV:S,5PPM/10 STEL,A3 93 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ozone Depleting Chemical:1 ===================== Hazards Identification ===================== Effects of Overexposure:IRRITATES,EYES,NOSE,THROAT;HEADACHE,DIZZINESS,UPSETS STOMACH, DERMATITUS ======================= First Aid Measures ======================= First Aid:INHALATION-REMOVE TO FRESH AIR,KEEP PRONE & WARM.INGESTION-INDUCE VOMITING WITH WARM SALT WATER.REPEAT UNTIL VOMIT IS CLEAR. EYES-WASH WITH PLENTY WARM WATER CALL DOCTOR. GIVE ARTIFICIAL RESPIRATION I F BREATHING IS DIFFICULT. ===================== Fire Fighting Measures ===================== Extinguishing Media:NON FLAMMABLE:USE MEDIA SUITABLE FOR SURROUNDING FIRE Fire Fighting Procedures:SELF-CNTND BRTHG APP;H*2O SPRAY COOL CONT. Unusual Fire/Explosion Hazard:CONTAINERS MAY EXPLODE IN HEAT OF FIRE;TOXIC FUMES(PHOSGENE) MAY BE GENERATED BY FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE UNPROTECTED PERSONS. PROVIDE VENTILATION. STOP LEAK. H*2O SPRAY COOL CONT(IF HOT). SM SPILL: ABSORB W COMMERCIAL ABSORBENT, SHOVEL INTO METAL DRUMS; LG SPILL: DIKE W COMMERCIAL ABSORBENT, PUM P INTO COVERED DRUMS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENT,LOW FIRE RISK AREA. PROTECT FROM PHYSICAL DAMAGE.AVOID ANY PHYSICAL CONTACT. KEEP CONTAINERS TIGHTLY CLOSED. Other Precautions:MAINTAIN STRICT HYGIENE, AVOID PHYSICAL CONTACT, REMOVE & WASH CONTAMINATED CLOTHING. DO NOT BREATH FUMES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSD TLV,NIOSH/MESA APPR SELF-CNTND BRTHG APP (POS PR MODE) Ventilation:MECHANICAL (GENERAL/LOCAL EXHAUST) Other Protective Equipment:FULL WORK CLOTHING TO PREVENT REPEATED OR PROLONGED CONTACT. Supplemental Safety and Health ACGIH 1983-4 LIST A2:SUSPECT OF CARCINOGENIC POTENTIAL FOR MAN STORAGE CODE T4 DESIGNATED DUE TO SUSPECTED RISKS UPON EXPOSURE TO THIS CHEMICAL(1983-4 ACGIH) ================== Physical/Chemical Properties ================== HCC:T3 NRC/State Lic Num:NOT RELEVANT Boiling Pt:=76.1C, 169.F Vapor Pres:100 Vapor Density:5.49 Spec Gravity:1.597 Solubility in Water:NEGLIGIBLE Appearance and Odor:COLORLESS LIQUID-HEAVY ETHERAL ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES EXCESS WATER Stability Condition to Avoid:IGNITION SOURCES,HOT SURFACES,OPEN FLAME,ESCESS MOISTURE. Hazardous Decomposition Products:PHOSGENE & HYDROCARBON PRODUCTS;HYDROCHLORIC ACID. ==================== Disposal Considerations ==================== Waste Disposal Methods:KEEP IN COVERED DRUMS,PENDING DISPOSAL. HANDLE & DISPOSE IN FULL COMPLIANCE WITH ALL APPLICABLE INTERNATIONAL,FEDERAL,STATE, & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:6294 DENT FILLER, COMPONENT B Kit Part:Y Preparer's Name:M WHEELOCK CAGE:16522 CAGE:16522 ============= Composition/Information on Ingredients ============= Ingred Name:DIBENZOYL PEROXIDE(SARA III) CAS:94-36-0 RTECS #:DM8575000 Fraction by Wt: 50% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3--10 HR SHIFT ACGIH TLV:5 MG/M3--10 HR SHIFT ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYE IRRITATION, MINOR SKIN IRRITATION. CHRONIC: NONE KNOWN. Effects of Overexposure:EYES: MAY CAUSE EYE IRRITATION. SKIN: PROLONGED SKIN CONTACT MAY CAUSE SKIN IRRITATION AND REDNESS. INHALATION: MAY CAUSE IRRITATION OF THE NOSE, THROAT, AND LUNG. INGESTION: MAY CAUSE TOXIC EFFECTS. Medical Cond Aggravated by Exposure:NO INFORMATION FOUND ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES & CONTACT A PHYSICIAN. SKIN: WASH IMMEDIATELY WITH SOAP & WATER. CONSULT A PHYSICIAN IF DISCOMFORT DEVELOPS. INHALATION: REMOVE TO FRESH AIR. C ONSULT A PHYSICIAN IF DISCOMFORT PERSISTS. INGESTION: ADMINISTER LARGE QUANTITIES OF WATER IF PERSON IS CONSCIOUS. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IMMEDIAELY CONSULT PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:>200F,>93C Extinguishing Media:WATER FOG OR SPRAY, CO2, DRY CHEMICAL, FOAM Fire Fighting Procedures:EVACUATE AREA AND APPLY WATER FROM A SAFE DISTANCE. Unusual Fire/Explosion Hazard:PEROXIDES AND DECOMPOSIITON PRODUCTS ARE FLAMMABLE AND CAN IGNITE WITH EXPLOSIVE FORCE IF CONFINED. ================== Accidental Release Measures ================== Spill Release Procedures:AVOID CONTACT WITH SKIN. MATERIAL LEFT UNCOVERED COULD INCREASE FIRE HAZARD DUE TO EVAPORATION OF WATER & LEACHING OF PLASTICIZER AWAY FROM BENZOYL PEROXIDE. DIKE TO PREVENT RUNOFF FROM ENTERING DRAIN S, SEWERS, STREAMS, ETC. TRANSFER INTO CONTAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM ALL SOURCES OF HEAT AND IGNITION SUCH AS RADIATORS, STEAM PIPES AND DIRECT SUNLIGHT. DO NOT STORE NEAR COMBUSTIBLES. Other Precautions:DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. DO NOT BREATHE VAPORS. KEEP CONTAINERS CLOSED. KEEP FROM FREEZING. EMPTY CONTAINERS MAY CONTAIN HAZARDOUS RESIDUES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED IF TLVS ARE EXCEEDED Ventilation:MECHANICAL Other Protective Equipment:EYE WASH STATION SHOULD BE AVAILABLE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F3 Decomp Temp:Decomp Text:200F,93C Spec Gravity:1.2+/- 0.15@77F Viscosity:250,000 CPS Solubility in Water:<1% @ 68F Appearance and Odor:RED, SMOOTH PASTE / SLIGHT SWEET ODOR Percent Volatiles by Volume:<20 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:NO STRONG ACIDS, STRONG ALKALIES, STRONG OXIDIZERS Stability Condition to Avoid:AVOID STORAGE ABOVE 100F. Hazardous Decomposition Products:ON DECOMPOSITION, BENOYL PEROXIDE CAN PRODUCE FLAMMABLE AND TOXIC VAPORS AND BIPHENYL (TLV=0.2 PPM). Conditions to Avoid Polymerization:IGNITION SOURCES, TEMPERATURES ABOVE 100F ==================== Disposal Considerations ==================== Waste Disposal Methods:CLEAN UP SMALL SPILLS OR RESIDUE WITH INERT ABSORBENT. PLACE IN DOUBLE POLYETHYLENE BAGS. DISPOSE IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PHOTOSONIC SONICBRITE 300, 15 GAL Preparer's Name:MR. MARSHALL CAGE:63067 CAGE:63067 ============= Composition/Information on Ingredients ============= Ingred Name:WATER, H2O CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: >70% Ingred Name:POTASSIUM PHOSPHATE TRIBASIC, TRIPOTASSIUM PHOSPHATE CAS:7778-53-2 Fraction by Wt: <30% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION, CONJUNCTIVITIS. SKIN: IRRITATION. INGESTION: IRRITATION TO MOUTH, THROAT/GASTROINTESTINAL TRACT, NAUSEA, VOMITING/BURNS TO THE ESOPHAGUS. INHALATION: IRRITATION TO NOSE/THROAT. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES: IRRITATION, CONJUNCTIVITIS. SKIN: IRRITATION. INGESTION: IRRITATION TO MOUTH, THROAT/GASTROINTESTINAL TRACT, NAUSEA, VOMITING/BURNS TO THE ESOPHAGUS. INHALATION: IRRITATION TO NOSE/THROAT. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/LARGE AMOUNTS OF WATER. SKIN: WASH THE EXPOSED AREA W/WATER. INGESTION: DRINK 2 TO 3 GLASSES OF WATER OR MILK. DON'T NEUTRALIZE W/ACID. HEAT OF NEUTRALIZATION MAY GENERATE HEAT THAT MAY RESULT IN PERFORATION. INHALATION: REMOVE FROM EXPOSURE. IF BREATHING IS DIFFICULT. OBTAIN MEDICAL ATTENTION IN ALL CASES. ================== Accidental Release Measures ================== Spill Release Procedures:NEUTRALIZE W/WEAK ACID. DILUTE W/LARGE AMOUNTS OF WATER (1 + 10 RATIO). SEWER DISPOSAL MAY BE SUITABLE UNDER AN APPROVED PERMIT. Neutralizing Agent:WEAK ACID ======================Handling and Storage ====================== Handling and Storage Precautions:STORE THIS PRODUCT AT ROOM TEMPERATURE. READ INSTRUCTIONS BEFORE USING PRODUCT. Other Precautions:CONTACT LENS WEARERS SHOULD WEAR REGULAR GLASSES ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED Ventilation:LOCAL EXHAUST/MECHANICAL: RECOMMENDED Other Protective Equipment:LAB COAT Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>212F Spec Gravity:1.22 pH:12.5 Solubility in Water:COMPLETE Appearance and Odor:CLEAR COLORLESS ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT LOCAL REGULATORY AGENCIES FOR APPROPRIATE WASTE DISPOSAL METHODS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BONDAID ETCHANT S16943 CAGE:LO595 CAGE:97820 CAGE:LO595 ============= Composition/Information on Ingredients ============= Ingred Name:DIETHYLENE GLYCOL DIMETHYL ETHER Fraction by Wt: 86%. Ingred Name:NAPHTHALENE (SARA III) CAS:91-20-3 RTECS #:QJ0525000 Fraction by Wt: 12%. OSHA PEL:10 PPM/15 STEL ACGIH TLV:10 PPM/15 STEL; 9192 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:SODIUM (SARA III) CAS:7440-23-5 RTECS #:VY0686000 Fraction by Wt: 2% ===================== Hazards Identification ===================== Effects of Overexposure:HARMFUL IF SWALLOWED. AVOID PROLONGED EXPOSURE TO SKIN; MAY BE IRRITATING. IRRITATING TO EYES. ======================= First Aid Measures ======================= First Aid:INGESTION:CALL MD. EYES:IMMEDIATELY FLUSH W/WATER AT LEAST 15 MINUTES. CALL MD. SKIN:WASH THOROUGHLY W/SOAP & WATER. ===================== Fire Fighting Measures ===================== Flash Point:158F OC Extinguishing Media:DRY SODA ASH OR CO*2 Fire Fighting Procedures:DO NOT USE WATER OR CHEMICAL EXTINGUISHERS. ================== Accidental Release Measures ================== Spill Release Procedures:IF POSSIBEL LEAVE SPILLED MATERIAL EXPOSED TO AIR. IT WILL REACT W/ATMOSPHERIC MOISTURE AND LOSE STRENGTH. MFR SUGGESTS WATER CAN BE ADDED CAREFULLY. THERE COULD BE A REACTION W/SODIUM, CAUSING FLAMES & SPLASHING. WATER WILL RENDER MTRL HARMLESS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN MOISTURE FREE AREA. DO NOT STORE NEAR OPEN FLAME. Other Precautions:CLOSE SCREW CAP TIGHTLY TO PROTECT FROM MOISTURE, TO PROLONG PRODUCT SHELF LIFE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE Ventilation:GENERAL VENTILATION-YES Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:324 F Vapor Pres:3. Spec Gravity:1.05 Appearance and Odor:BLACK,MILD COAL TAR-"MOTH BALL" ODOR. Percent Volatiles by Volume:35. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER Stability Condition to Avoid:CONTACT W/MOISTURE ==================== Disposal Considerations ==================== Waste Disposal Methods:AFTER BEING FULLY NEUTRALIZED W/WATER IT CAN BE FLUSHED INTO THE SEWER, W/LARGE QUANTITIES OF WATER SUGGESTS MFR. CHECK LOCAL EFFLUENT LAWS. DISPOSE IN ACCORDANCE W/LOCAL, STATE, AND FEDERAL REGULATIO NS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:139 5508,EKTPRNT R-1000 COLR DEVLPR,PART C CAGE:19139 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROXYLAMINE SULFATE;CAS #10039-54-0;(DISSOCIATES TO SULFURIC ACID 5-10%);% WT 5-10% CAS:10039-54-0 RTECS #:NC5425000 Fraction by Wt: 7.5% Ingred Name:AQUEOUS SOLUTION,HAZARD INKNOWN,UNIDENTIFIED;% WT BY DIFFERENCE 92.5% Fraction by Wt: 92.5% ===================== Hazards Identification ===================== Effects of Overexposure:EYES:CAUSES IRRITN;SKIN:MAY CAUSE IRRITN; REPEATD CONTACT W/SKIN MAY CAUSE ALLRGIC REACTION/TOXIC. ======================= First Aid Measures ======================= First Aid:INHALE:REMOVE TO FRESH AIR, GIVE CPR/O2 IF NEED;EYES:FLUSH W LG AMTS H2O FOR 15 MIN;SKIN:FLUSH W LG AMTS H2O;INGEST: RINSE MOUTH. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:CO2, FOAM, DRY CHEM. Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE UNPROTECTED PERSONS. ELIM IGNITION SOURCES. STOP LEAK. H2O SPRAY COOL CONT/DIVERT SPILL FROM FIRE/HEAT. PROVIDE VENTILATION. ABSORB W COMMERCIAL ABSORBENT,SHOVEL INTO METAL DRUMS: LG SPILL:DI KE W COMMERCIAL ABSORBENT,PUMP INTO COVERED DRUMS ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED AREA. PROTECT FROM PHYSICAL DAMAGE.AVOID ANY PHYSICAL CONTACT. KEEP CONTAINERS TIGHTLY CLOSED Other Precautions:NONE KNOWN ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED Ventilation:NO SPECIAL REQUIREMENTS W ADEQUATE VENT. Other Protective Equipment:AS REQUIRED TO PREVENT PROLONGED CONTACT. Supplemental Safety and Health MSDS FM MFR DATED:1/30/79;THIS DATA DESCRIBES PART C OF 3 PART PRODUCT;SEE P/N IND A & B FOR OTHER PARTS,SAME NSN;STORAGE CODE C1 ASSIGNED BECAUSE SOLN GIVES H2S04 ON DISSOCIATION;PH 3.5. KEY1:J1. ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:B.P. Text:>212F/100C Vapor Pres:17 Vapor Density:0.6 Spec Gravity:1.08 Solubility in Water:COMPLETE Appearance and Odor:PINK-PURPLE ODORLESS LIQUID. Percent Volatiles by Volume:91.0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES PER MFR, NONE Hazardous Decomposition Products:PER MFR, NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:KEEP IN COVERED DRUMS,PENDING DISPOSAL. HANDLE & DISPOSE IN FULL COMPLIANCE WITH ALL APPLICABLE INTERNATIONAL,FEDERAL,STATE, & LOCAL REGULATIONS. MFR NOTES,FLUSH TO SEWER W/COPIOUS AMTS OF H2O IAW ALL EXISTING REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SCOTCHCAST 2 CASTING TAPE -2",3",4",5" WIDT CAGE:28156 CAGE:28156 ============= Composition/Information on Ingredients ============= Ingred Name:FIBROUS GLASS CAS:65997-17-3 Fraction by Wt: 55-60% Other REC Limits:NONE SPECIFIED OSHA PEL:5 MG/M3 RDUST Z-3 ACGIH TLV:10 MG/M3(<7 MICRONS) Ingred Name:ISOCYANATE TERMINATED URETHANE PREPOLYMER Fraction by Wt: 30-35% Other REC Limits:NONE SPECIFIED Ingred Name:MODIFIED 4,4'-DIPHENYLMETHANE DIISOCYANATE (MDI) CAS:26447-40-5 Fraction by Wt: 5-10% Other REC Limits:0.02 PPM Ingred Name:AMINE CATALYST Fraction by Wt: 0.1-2.0% Other REC Limits:NONE SPECIFIED Ingred Name:ACID CHLORIDE Fraction by Wt: 0-0.5% Other REC Limits:NONE SPECIFIED Ingred Name:ANTIOXIDANT Fraction by Wt: 0-0.5% Other REC Limits:NONE SPECIFIED Ingred Name:ANTIFOAM Fraction by Wt: 0-0.5% Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 > 5G/KG INGESTION Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES/SKIN: PROLONGED CONTACT CAN CAUSE SLIGHT IRRITATION. AVOID BREATHING OF VAPOR. MANUFACTURER REPORTS THAN UNCURED MATERIAL IS NOT EXPECTED TO BE AN IRRITANT WHEN USED AS DIRECTED. MATERIAL IS NOT EXPECTED TO BE AN INHALATION/INGESTIONHAZARD; HOWEVER, AVOID BREATHING ISOCYANATE VAPORS OR UNCURED MATERIAL CONTACT. Explanation of Carcinogenicity:NONE OF THE CHEMICALS IN THIS PRODUCT IS LISTED BY IARC, NTP OR OSHA AS A CARCINOGEN. Effects of Overexposure:IRRITATION OF EYES/SKIN/RESPIRATORY TRACT. Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF SKIN AND RESPIRATORY DISORDERS MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:EYE: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES. GET MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND WATER. INHALATION: REMOVE TO FRESH AIR. INGESTION:DRINK PLENTY OF WATER. DO NOT INDUCE VOMIT ING. SEEK MEDICAL HELP. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:>220F,>104C Extinguishing Media:USE CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS INCLUDING OXIDES OF NITROGEN AND CARBON MONOXIDE. ================== Accidental Release Measures ================== Spill Release Procedures:CURED PRODUCT MAY BE SCOOPED UP AND DISPOSED AS ORDINARY SOLID WASTE. SOME UNCURED COMPONENTS MAY BE HAZARDOUS - HANDLE WITH CARE. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED AREA AWAY FROM SOURCES OF IGNITION. KEEP CONTAINER CLOSED WHEN NOT IN USE. PROTECT FROM PHYSICAL DAMAGE. Other Precautions:AVOID EXCESSIVE TEMPERATURE OF MATERIAL IN POUCH (40-83F) RECOMMENDED FOR STORAGE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION EXPOSURES BELOW PEL (TLV), USE NIOSH/MSHA APPROVED RESPIRATOR AS PER CURRENT 29 CFR 1910.134, INSTRUCTIONS/WARNINGS AND NIOSH-RESPIRATOR SELECTION. Ventilation:MECHANICAL (GENERAL) VENTILATION IS USUALLY ADEQUATE. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health AVOID EYE/SKIN CONTACT WITH UNCURED MATERIAL. ================== Physical/Chemical Properties ================== HCC:N1 Solubility in Water:NEGLIGIBLE Appearance and Odor:YELLOWISH RESIN IMPREGNATED ON KNIT FIBERGLASS/SLIGHT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, WATER, ALKALI, STRONG BASES. Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, OPEN FLAMES, MOISTURE. Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE, NITROGEN OXIDES AND OTHER POSSIBLE BYPRODUCTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CL HD RED PMS-185-HD Preparer's Name:DICK KARBO CAGE:KAMDD CAGE:KAMDD ============= Composition/Information on Ingredients ============= Ingred Name:BENZENESULFONIC ACID, 5-CHLORO-2-(2-HYDROXY-1-NAPHTHALENYL)AZO-4-METHYL-, BARIUM SALT, PIGMENT RED 53:1 CAS:5160-02-1 RTECS #:DB5500000 Ingred Name:BARIUM (SARA III) CAS:7440-39-3 RTECS #:CQ8370000 Fraction by Wt: 21% OSHA PEL:0.5 MG/M3 ACGIH TLV:0.5 MG/M3; 9192 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN/EYES: IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:SKIN/EYES: IRRITATION. ======================= First Aid Measures ======================= First Aid:EYES: WASH W/WATER UNTIL IRRITATION STOPS. SKIN: WASH AFFECTED AREA W/SOAP & WATER. SEEK MEDICAL ASSISTANCE AS REQUIRED. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:>200F Extinguishing Media:FOAM, CO2, DRY CHEMICAL ================== Accidental Release Measures ================== Spill Release Procedures:FOR SMALL SPILLS: WIPE UP & STORE WIPERS IN UNDERWRITERS APPROVED CONTAINERS. FOR LARGE SPILLS: SCOOP MATERIAL INTO SEALABLE CONTAINERS. WIPE UP REMAINDER & STORE WIPERS IN UNDERWRITERS APPROVED CONTA INERS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN CLOSED CONTAINERS. AVOID CONTACT W/SKIN, EYES, & CLOTHING. WASH HANDS AFTER USE. CHANGE CLOTHING, IF CONTAMINATED. Other Precautions:DON'T CONSUME FOOD OR BEVERAGE WHERE PRODUCT IS USED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED FOR NORMAL OPERATION Ventilation:LOCAL EXHAUST: DESIRABLE Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:470-610F Evaporation Rate & Reference:SLOWER THAN WATER Solubility in Water:INSOLUBLE Appearance and Odor:OILY ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:DM SERIES CAGE:4S875 CAGE:0FGN2 CAGE:1U269 CAGE:4S875 ============= Composition/Information on Ingredients ============= Ingred Name:SULFURIC ACID (SARA III) CAS:7664-93-9 RTECS #:WS5600000 Fraction by Wt: 32-40% Other REC Limits:NONE SPECIFIED OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT) IS 2140 MG/KG (H2SO4) Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: MAY CAUSE IRRITATION OF RESPIRATORY TRACT, EYES, SKIN OR GI TRACT. MAY CAUSE BURNS OF SKIN, EYES, OR GI TRACT. MAY CAUSE CORNEAL DAMAGE OR BLINDNESS. CHRONIC: TOOTH EROSION, INFLAMMATION OF NOS E, THROAT AND BRONCHIAL TUBES. Explanation of Carcinogenicity:THE ELECTROLYTE IS NOT LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN. Effects of Overexposure:INHALATION: BURNING SENSATION IN NOSE, THROAT AND LUNGS, COUGHING, WHEEZING, SHORTNESS OF BREATH. EYES: REDNESS, TEARING, BLURRED VISION, BURNS, SEVERE PAIN. SKIN: SEVERE PAIN, BURNS, REDNESS, RASH, I TCHING. INGESTION: BURNS OF MOUTH, THROAT, AND ESOPHAGUS, SEVERE STOMACH PAIN, NAUSEA, VOMITING. Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS OR WITH A PRE-EXISTING DISEASE INVOLVING THE RESPIRATORY TRACT OR TEETH MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING. GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES HOLDING EYELIDS OPEN. GET PROMPT MEDICAL ATTENTION. SKIN :REMOVE CONTAMINATED CLOTHING. WASH WITHPLENTY OF WATER FOR 15 MINUTES. GET MEDICAL ADVICE. INGESTION:DO NOT INDUCE VOMITING. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE DRY CHEMICAL, CARBON DIOXIDE, FOAM, HALOGEN. Fire Fighting Procedures:USE OF WATER IN EXTINGUISHING BURNING BATTERIES MAY CAUSE SPATTERING DUE TO THE PRESENCE OF MOLTEN LEAD. WEAR SCBA AND FULL PROTECTIVE GEAR. Unusual Fire/Explosion Hazard:AFTER ELECTROLYTE IS ADDED AND BATTERY IS BEING CHARGED, HYDROGEN GAS IS PRODUCED. BATTERY MAY EXPLODE IF HYDROGEN GAS TRAPPED INSIDE THE CASE SHOULD IGNITE. ================== Accidental Release Measures ================== Spill Release Procedures:SHOULD A BATTERY BREAK OPEN, ISOLATE AREA. ELECTROLYTE SHOULD BE ABSORBED WITH A NON-ORGANIC TYPE ABSORBENT SUCH AS DRY SAND OR EARTH. AVOID DILUTION WITH WATER. LEAD SPILLED FROM THE BATTERY SHOULD B E VACUUMED, DO NOT SWEEP OR USE COMPRESSED AIR. Neutralizing Agent:USE SODA ASH OR BAKING SODA TO NEUTRALIZE THE ELECTROLYTE. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID THE USE OF UNINSULATED TOOLS. IF THEY ARE REQUIRED, TAKE CARE NOT TO ELECTRICALLY SHORT THE TERMINALS. REMOVE METAL JEWELRY BEFORE SERVICING. Other Precautions:UNDER NORMAL CONDITIONS OF USE, EXPOSURE TO LEAD OR LEAD CONTAINING COMPOUNDS DOES NOT OCCUR. SHOULD A BATTERY BREAK OPEN AND A LEAD SPILL OCCUR, PRECAUTIONS SHOULD BE TAKEN TO PREVENT LEAD DUST FROM BECOMING AIR BORNE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:UNDER NORMAL CONDITIONS OF USE, RESPIRATORY PROTECTION IS NOT REQUIRED. HOWEVER, IF CONDITIONS ARISE THAT REQUIRE THEIR USE, USE ONLY NIOSH/MSHA RESPIRATORS APPROVED FOR DUST, FUME AND MIST. Ventilation:BATTERY CHARGING AREAS MUST BE ADEQUATELY VENTILATED TO PREVENT HAZARDOUS CONCENTRATIONS OF FLAMMABLE GAS OR ACID MIST. Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER. INDUSTRIAL-TYPE IMPERVIOUS WORK CLOTHING, BOOTS AND APRON AS REQUIRED. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health THIS MSDS REFLECTS DIFFERENT MFG PART OR SERIES DESIGNATOR FROM PART A FOR THIS NSN (CAGE: YUASA). ALSO UPDATES CAGE FOR MANUFACTURER. RQ FOR CERCLA AND SARA III IS 1000 LBS (ELECTROLYTE). MSDS WRITTE N FOR ELECTROLYE- IT IS THE PRIMARY HAZARD DURING NORMAL USE AND HANDLING. ================== Physical/Chemical Properties ================== HCC:Z4 Boiling Pt:=95.C, 203.F B.P. Text:203F,95C Melt/Freeze Pt:M.P/F.P Text:-94F,-70C Vapor Pres:10 Vapor Density:>1 Spec Gravity:1.25-1.29 pH:1 Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1) Solubility in Water:COMPLETE (ACID) Appearance and Odor:NO ODOR. BATTERY CASE IS SEALED. ELECTROLYTE IS CLEAR OILY LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONTACT OF ELECTROLYTE WITH ORGANIC MATERIAL AND COMBUSTIBLES, STRONG ALKALIS, REDUCING AGENTS, STRONG OXIDIZING AGENTS Stability Condition to Avoid:OVERCHARGING, SOURCES OF IGNITION Hazardous Decomposition Products:SULFURIC ACID MIST, SULFUR DIOXIDE AND CARBON MONOXIDE MAY BE RELEASED WHEN ELECTROLYTE DECOMPOSES. ==================== Disposal Considerations ==================== Waste Disposal Methods:BOTH ELECTROLYTE AND SCRAP BATTERIES ARE REGULATED HAZARDOUS WASTE. SCRAP BATTERIES CONTAIN MATERIALS WHICH ARE RECYCLABLE AND MUST BE RETURNED TO AUTHORIZED RECYCLER. ELECTROLYTE SHOULD BE HAULED TO A PERMITTED TREATMENT FACILITY.
1
eyes_protection_mandatory
======================================================= Product ID: NITRIVER 3 NITRITE REAGENT Cage: 4T252 Box: 389 ======================================================= Preparer Co. when other than Responsible Party Co. ======================================================= Cage: 4T252 Box: 907 ======================================================= Contractor Summary ======================================================= Cage: 91224 Box: 389 Cage: 4T252 Box: 907 ======================================================= Ingredients ======================================================= Cas: 36679-96-6 *98-1* % Wt: 5 ------------------------------ Cas: 7778-77-0 % Wt: 85 ------------------------------ Cas: 515-74-2 % Wt: 15 ------------------------------ Cas: 7790-62-7 % Wt: 10 ------------------------------ Cas: 129-96-4 *98-1* % Wt: 5 ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: YES Skin: NO Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: EYES: CORROSIVE, BURNS. SKIN: IRRITATION. INHALATION: RESPIRATORY TRACT IRRITATION. INGESTION: MODERATELY TOXIC, CNS DEPRESSION & KIDNEY DAMAGE. Explanation Of Carcinogenicity: NONE Signs And Symptions Of Overexposure: IRRITATION, BURNS, STOMACH DISTURBANCES, HEARING PROBLEMS. Medical Cond Aggravated By Exposure: PRE-EXISTING EYE, SKIN, HEART & KIDNEY CONDITIONS. First Aid: EYES: FLUSH W/WATER FOR 15 MINS. SKIN: FLUSH W/PLENTY OF WATER. INGESTION: DON'T INDUCE VOMITING. GIVE 1-2 GLASSES OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. INHALATION: REMOVE T O FRESH AIR. GIVE CPR IF NEEDED. OBTAINMEDICAL ATTENTION IN ALL CASES. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: SCOOP MATERIAL INTO A BEAKER & DISSOLVE W/WATER. NEUTRALIZE TO A PH BETWEEN 6 & 9. FLUSH NEUTRALIZED WASTE TO DRAIN W/AN EXCESS OF WATER. Neutralizing Agent: ALKALI/SODA ASH. Waste Disposal Methods: DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. Handling And Storage Precautions: STORE IN A COOL, DRY PLACE. Other Precautions: AVOID CONTACT W/EYES & SKIN. DON'T BREATHE DUST. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: WATER, CO2, DRY CHEMICAL. Unusual Fire/Explosion Hazard: MAY EMIT TOXIC FUMES. ======================================================= Control Measures ======================================================= Ventilation: ADEQUATE Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health: PH OF 5% SOLUTION: 3.2. ======================================================= Physical/Chemical Properties ======================================================= M.P/F.P Text: 435.2F Spec Gravity: 3.12 PH: (SUPP) Solubility in Water: COMPLETE Appearance and Odor: SOLID WHITE POWDER. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: HEAT, MOISTURE. Hazardous Decomposition Products: PHOSPHORUS OXIDES. Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: NITRIVER 3 NITRITE REAGENT Cage: 4T252 Company Name: HACH COMPANY Street: 100 DAYTON RD. PO Box: 907 Zipcode: 50010 Label Required IND: Y Date Of Label Review: 08/11/1993 Status Code: C Label Date: 08/11/1993 Origination Code: F Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: DANGER Health Hazard: Severe Contact Hazard: Severe Fire Hazard: None Reactivity Hazard: Slight Hazard And Precautions: CORROSIVE TO EYES, WET SKIN & RESPIRATORY TRACT. CAUSES BURNS TO MOIST TISSUES. MODERATELY TOXIC BY INGESTION. TARGET ORGANS: EYES, SKIN, & RESPIRATORY TRACT. DIGESTIVE TRACTS, LIVE R. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PR-1436 G SPRAYABLE #1436G168 Kit Part:Y Preparer's Name:SEROJE HARTOONIANI CAGE:83574 CAGE:83574 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM DICHROMATE (SARA 313) (CERCLA) CAS:10588-01-9 RTECS #:HX7700000 Fraction by Wt: 10.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.1 MG/M3 STEL ACGIH TLV:0.05 MG/M3 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:DIMETHYL ACETAMIDE (VP = 2.0) CAS:127-19-5 RTECS #:AB7700000 Fraction by Wt: 25.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 PPM SKIN ACGIH TLV:10 PPM SKIN Ingred Name:CALCIUM DICHROMATE (SARA 313) CAS:14307-33-6 RTECS #:HX7630000 Fraction by Wt: 20.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.1 MG/M3 STEL ACGIH TLV:0.05 MG/M3 AS CR Ingred Name:WATER (NON-HAZARDOUS) CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: NA Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE: BURN/TEAR/RED/TRANSIENT CORNEA INJURY. SKIN: HARMFUL/RAPID ABSORPTION. INHAL: LIVER/KIDNEY DAMAGE. CHRONIC: MAY CAUSE PENETRATING ULCERS TO SKIN/MUCOUS MEMBRANES OF NOSE/PERFORATION OF CARTILAGIN OUS NASAL SEPTUM ======================= First Aid Measures ======================= First Aid:EYE: FLUSH W/LUKE WARM WATER FOR 15 MIN. CALL DR. SKIN: WASH W/SOAP AND WATER. CALL DR. INHAL: REMOVE TO FRESH AIR. GET MED AID. INGEST: CALL DR. ===================== Fire Fighting Measures ===================== Flash Point:>200F,>93C Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER FOG. Fire Fighting Procedures:USE COMPLETE PERSONAL PROTECTION. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE/COVER SPILL W/NONOXIDIZABLE ABSORBENT. SCOOP INTO CONTAINER. SPRINKLE SODIUM THIOSULFATE ON RESIDUE. WORK INTO RESIDUE. CLEAN AREA W/WATER. CERCLA RQ FOR SODIUM DICHROMATE IS 10 LBS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN APPLYING IN ANY CIRCUMSTANCES LIKELY TO PRODUCE AIRBOURNE LEVEL OF HAZARDOUS INGREDIENTS IN EXCESS OF TLV USE ORGANIC VAPOR CARTRIDGE OR AIR-SUPPLIED RESPIRATOR. Ventilation:GENERAL TO MAINTAIN VAPORS BELOW PEL. IMMERSION. PROTECT SKIN W/NITRILE/BUTYL, RUBBER OR POLYETHYLENE APRON OR COVERALLS. Work Hygienic Practices:AVOID ALL SKIN CONTACT. WASH THOROUGHLY AFTER HANDLING/BEFORE SMOKING OR EATING. Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212 TO 331F Vapor Density:>AIR Spec Gravity:1.259 pH:NA Viscosity:20 CP@10 RPM Evaporation Rate & Reference:NOT AVAILABLE Solubility in Water:SLIGHT Appearance and Odor:BROWNISH YELLOW LIQUID Percent Volatiles by Volume:86.7 Corrosion Rate:NA ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES EASILY OXIDIZABLE MATERIALS. Hazardous Decomposition Products:OXIDES OF CARBON & NITROGEN, CHROMIUM COMPOUNDS ==================== Disposal Considerations ==================== Waste Disposal Methods:EPA #D007 HAZ WASTE. DISPOSE IN COMPLIANCE W/FEDERAL & STATE REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CARBON RAISER 215 CAGE:4E133 CAGE:4E133 ============= Composition/Information on Ingredients ============= Ingred Name:CALCINED PETROLEUM COKE CAS:64743-05-1 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: DUST MAY BE ABRASIVE & IRRITATING. INHALATION: OVEREXPOSURE TO DUST MAY RESULT IN CHRONIC BRONCHITIS. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, STINGING SENSATION, REDNESS, COUGHING, SHORTNESS OF BREATH ======================= First Aid Measures ======================= First Aid:INHALATION: MOVE TO FRESH AIR. EYES: WASH W/WATER TO WASH OUT DUST. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:CHEMICAL TYPE PREFERRED. Fire Fighting Procedures:VENTILATION MAY BE REQUIRED. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP/VACUUM. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE OSHA APPROVED RESPIRATOR FOR NUISANCE DUST. Ventilation:LOCAL EXHAUST: TO DUST COLLECTOR. Other Protective Equipment:NONE Work Hygienic Practices:KEEP WORK AREA CLEAN. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:2.07 Solubility in Water:INSOLUBLE Appearance and Odor:GREY TO BLACK W/NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS; PERCHLORATES, PEROXIDES, NITRIC ACID, ESPECIALLY WHEN HEATED. Stability Condition to Avoid:NONE Hazardous Decomposition Products:CO2/CO ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HEAT SHRINKABLE INTERCONNECTIONS WITH (SUPDAT) Preparer's Name:DONNA SEID CAGE:06090 CAGE:06090 ============= Composition/Information on Ingredients ============= Ingred Name:BASE POLYMER MATERIALS (INCLUDING INGS 2-8) RTECS #:9999999ZZ OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:POLYETHYLENE COPOLYMER CAS:9010-77-9 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:OLEFIN COPOLYMER OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:FLUOROPOLYMERS OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:CHLOROPOLYMERS OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:POLYAMIDES OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:POLYESTERS OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SILICONES OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ADHESIVE; (ADHESIVES/MASTICS) OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SOLDER (CONSISTING OF ING 11) OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:METALS OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT:PHOSPHORUS & SULFUR. COMBUST PRODS MAY BE TOX & SHOULD NOT BE INHALED. AT TEMPS THAT MAY BE REACHED IN (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:CASE OF FIRE, DEPENDING ON SOLDER, OXIDE FUMES/PARTICULATES OF ANTIMONY, BISMUTH, LEAD, SILVER/TIN MAY BE RELSD. RTECS #:9999999ZZ Ingred Name:FIRST AID: BRTHG DFCLTY DEVELOPS, O*2 SHOULD BE ADMIN BY QUALIFIED PERS. SEEK IMMED MED ATTN. IF NOT BRTHG, (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14: IMMED BEGIN ARTF RESP. KEEP WARM & QUIET; SEEK IMMED MED ATTN. RTECS #:9999999ZZ Ingred Name:HNDLG/STOR PRECS: IS HEATED TO DECOMP, AS SHOWN BY DARKENING & BROWNING OF SLEEVE. AVOID CNTCT W/MOLTEN MATL. (ING 17) RTECS #:9999999ZZ HANDLED AFTER INSTALLATION. RTECS #:9999999ZZ Ingred Name:OTHER PRECS: FOLLOW APPROP MFR INSTALLATION INSTRUCTIONS & APPLICATN GUIDES TO ENSURE INSTALLATION IS PERFORMED (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18: PROPERLY. ENSURE ANY LOC REQS/LEGISLATION CONCERNING USE OF HAND-HELD ELEC EQUIP ARE OBSERVED. WHEN (ING 20) RTECS #:9999999ZZ Ingred Name:ING 19:USING IR (INFRARED) HEATING DEVICES, OBSERVE SPECIFIC INSTRUCTIONS. DO NOT TOUCH HOT SURFS ON INSTALLATION EQUIP. RTECS #:9999999ZZ IS NEC TO HANDLE GROSSLY OVERHEATED OR FIRE-DAMAGED (ING 22) RTECS #:9999999ZZ CNTCT W/POTENTIALLY CORR INORGANIC ACID RESIDUES. RTECS #:9999999ZZ Ingred Name:EYE PROT: & FULL LENGTH FACESHIELD . RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:EYES/SKIN:CNTCT W/MOLTEN MATL MAY CAUSE THERMAL BURNS. PROD IS NOT EXPECTED TO BE SKIN IRRITANT. NO HARMFUL EFTS EXPECTED FROM SKIN ABSORPTION. INGEST:HIGHLY UNLIKELY. THERE IS INSUFFICIENT INFO AVAIL ON MATL TO PREDICT EFTS FROM INGEST. INHAL:IN COMMON W/MOST ORG MATLS, THERMAL DEGRADATION & (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: COMBUST BYPRODS MAY BE TOX & SHOULD NOT BE INHALED. CHRONIC: NOTE:PROD TESTING HAS SHOWN NO EXPOS TO METAL FUMES FROM SOLDER PRESENT IN PRODS EVEN @ TEMPS WHERE THERMAL DEGRADATION OF TUBING OCCURS. OVERHEATING PROD TO CHARRING/BURNING MAY PRDCE VAPS THAT MAY CAUSE EYE, SKIN, NOSE & THROAT IRRIT. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING EYE, SKIN OR RESPIRATORY DISORDERS (EG ASTHMA CONDITIONS) MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THESE VAPORS. ======================= First Aid Measures ======================= First Aid:EYES:HOLD EYELIDS APART & FLUSH AFFECTED AREA(S) W/CLEAN WATER FOR AT LEAST 15 MIN. SEEK MED ATTN. SKIN:AFTER HNDLG, IT IS GOOD PRACT TO WASH HANDS. IF MOLTEN MATL CNTCTS SKIN, COOL AREA IMMED IN WATE R. DO NOT ATTEMPT TO REMOVE MATL FROM SKIN. TREAT AS BURN & SEEK MED ATTN. INGEST:IF SWALLOWED & SYMPS DEVELOP, SEEK MED ATTN. INHAL:MOVE TO FRESH AIR. IF SYMPS PERSISTS, SEEK MED ATTN. IF (ING 14) ===================== Fire Fighting Measures ===================== Extinguishing Media:CARBON DIOXIDE, WATER, DRY CHEMICAL, FOAM, DRY POWDER. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:TOXIC FUMES MAY EVOLVE IN A FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP AND COLLECT IN SUITABLE CONTAINER FOR DISPOSAL OR REUSE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:FOR PRODS CNTNG THERMOCHROMIC TEMP INDICATOR, DISCONTINUE HEATING AFTER COLOR CHANGES FROM RED TO COLORLESS. AVOID ANY VAPS GIVEN OFF IF PROD (ING 16) Other Precautions:AVOID HEATING PRODS BEYOND TEMPS REQD FOR NORM INSTALLATION. IF PROD CHARS/BURNS, IMMED STOP HEATING. AVOID INHAL FUMES WHICH MAY EVOLVE UNDER SUCH CIRCUMSTANCES. ALLOW ANY VAPS TO DISPERSE & VENT BEF ORE CONTINUING WORK IN AREA. (ING 18) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF INSTALLATION OCCURS IN A CONFINED, UNVENTILATED AREA, NIOSH/MSHA APPROVED RESPIRATORS ARE RECOMMENDED. Ventilation:IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE, ENSURE ADEQUATE VENTILATION DURING INSTALLATION. Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . OSHA, ANSI OR NIOSH GUIDELINES SHOULD BE FOLLOWED. Work Hygienic Practices:DO NOT CONSUME FOOD, BEVERAGES OR TOBACCO IN IMMED WORK AREA. WASH HANDS BEFORE EATING, DRINKING OR SMOKING. Supplemental Safety and Health MFR'S TRADE NAME/PART NO:SOLDER FOR HIGH TEMP WIRE. HAZ DECOMP PRODS:COMBUST BYPRODS DEPEND ON BASE POLYMER USED & MAY INCL BUT ARE NOT LIMITED TO, CO, CO*2, ALDEHYDES, ACETIC ACID, LOW MW HYDROCARBS, SILICON DIOXIDE, HYDROGEN CHLORIDE, HYDROGEN FLUORIDE, HYDROGEN BROMIDE, FLUORO-OLEFINS & OXIDES OF NITROGEN, (ING 12) ================== Physical/Chemical Properties ================== Spec Gravity:6-11 Solubility in Water:INSOLUBLE Appearance and Odor:CLEAR OR BLUE TRANSPARENT PLASTIC SLEEVES WITH A RING OF SOLDER INSERT; NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:AVOID OVERHEATING OF PRODUCT. Hazardous Decomposition Products:AT TEMPS HIGHER THAN RECOM FOR PROPER INSTALLATION, MOST SIGNIFICANTLY IF PROD BURNS, THERMAL DEGRADATION & (SUPDAT) ==================== Disposal Considerations ==================== Waste Disposal Methods:DISP OF I/A/W ALL LOC, STATE & FED REGS. IF THERE ARE LOC REGS COVERING CONTROLLED INCIN OF HALOGENATED MATLS, THEN ALL HALOGEN-CNTNG PRODS WILL BE SUBJECT TO SUCH REGS. REFER TO PROD LITERATURE FOR I DENTIFICATION OF HALOGEN-CNTNG PRODS.
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eyes_protection_mandatory